CN103483766A - High-strength glass composition - Google Patents
High-strength glass composition Download PDFInfo
- Publication number
- CN103483766A CN103483766A CN201310462066.8A CN201310462066A CN103483766A CN 103483766 A CN103483766 A CN 103483766A CN 201310462066 A CN201310462066 A CN 201310462066A CN 103483766 A CN103483766 A CN 103483766A
- Authority
- CN
- China
- Prior art keywords
- parts
- glass composition
- unsaturated polyester
- rosin
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 13
- 239000000203 mixture Substances 0.000 title claims abstract description 12
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 8
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 7
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 7
- 239000003063 flame retardant Substances 0.000 claims abstract description 7
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000835 fiber Substances 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 235000012254 magnesium hydroxide Nutrition 0.000 claims description 6
- 125000005375 organosiloxane group Chemical group 0.000 claims description 6
- 229920003987 resole Polymers 0.000 claims description 6
- 238000004513 sizing Methods 0.000 claims description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 7
- 239000011152 fibreglass Substances 0.000 abstract description 5
- -1 phenolic aldehyde Chemical class 0.000 abstract description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 238000005452 bending Methods 0.000 abstract 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
The invention discloses a high-strength glass composition which is characterized by comprising raw materials in parts by weight as follows: 50-70 parts of phenolic resin, 3-5 parts of rosin water, 10-18 parts of UPR (unsaturated polyester resin), 5-10 parts of organic siloxane, 8-12 parts of magnesium hydrate, 4-8 parts of a fire retardant, 7-10 parts of reinforced fibers, 7-11 parts of acrylonitrile, 2-8 parts of a stabilizing agent and 6-8 parts of an adhesive. The high-temperature-resistant phenolic aldehyde fiberglass reinforced plastic material has the characteristics of good heat resistance, convenience in forming and the like. The bending strength is larger than 96MPa through test, and the material can resist to be roasted in a drying oven at a temperature of 280 DGE C for 13 hours.
Description
Technical field
The invention belongs to the duroplastic moulding materials technical field, be specifically related to a kind of high-intensity glass composition.
Background technology
High temperature resistance phenolic aldehyde glass reinforced plastic is used to make refractory materials.But because the fire resistance rating of common phenolic fiberglass reinforced plastics material is low, thereby, in the urgent need to developing the phenolic fiberglass reinforced plastics material that a kind of fire resistance rating is high, existing glass material can't meet existing social needs.
Summary of the invention
For the deficiencies in the prior art, technical problem to be solved by this invention is, provides that a kind of resistance toheat is good, convenient formation and high-intensity glass composition that intensity is desirable.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of high-intensity glass composition is characterized in that, raw material by following weight part is made: resol 50-70 part, rosin 3-5 part, unsaturated polyester resin 10-18 part, organo-siloxane 5-10 part, magnesium hydroxide 8-12 part, fire retardant 4-8 part, fortifying fibre 7-10 part, vinyl cyanide 7-11 part, stablizer 2-8 part, sizing agent 6-10 part.
Above-mentioned high-intensity glass composition, it is characterized in that, made by the raw material of following weight part: 60 parts, resol, 4 parts, rosin, 15 parts of unsaturated polyester resins, 7 parts of organo-siloxanes, 10 parts of magnesium hydroxides, 6 parts of fire retardants, 8 parts of fortifying fibres, 9 parts of vinyl cyanide, 5 parts of stablizers, 8 parts of sizing agents.
The high-intensity glass composition of the present invention advantage be: resistant to elevated temperatures phenolic fiberglass reinforced plastics material provided by the invention has the characteristics such as resistance toheat is good, convenient formation.Through test, flexural strength is greater than 96MPa, can toast 13 hours by anti-280 ℃ of baking ovens.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
A kind of high-intensity glass composition, it is characterized in that, made by the raw material of following weight part: resol 50-70 part, rosin 3-5 part, unsaturated polyester resin 10-18 part, organo-siloxane 5-10 part, magnesium hydroxide 8-12 part, fire retardant 4-8 part, fortifying fibre 7-10 part, vinyl cyanide 7-11 part, stablizer 2-8 part, sizing agent 6-10 part.
Optimum embodiment of the present invention:
A kind of high-intensity glass composition, is characterized in that, by the raw material of following weight part, made: 60 parts, resol, 4 parts, rosin, 15 parts of unsaturated polyester resins, 7 parts of organo-siloxanes, 10 parts of magnesium hydroxides, 6 parts of fire retardants, 8 parts of fortifying fibres, 9 parts of vinyl cyanide, 5 parts of stablizers, 8 parts of sizing agents.
Certainly, above-mentioned explanation is not limitation of the present invention, and the present invention also is not limited to above-mentioned giving an example; those skilled in the art; in essential scope of the present invention, the variation of making, change, interpolation or replacement, all should belong to protection scope of the present invention.
Claims (2)
1. a high-intensity glass composition, it is characterized in that, made by the raw material of following weight part: resol 50-70 part, rosin 3-5 part, unsaturated polyester resin 10-18 part, organo-siloxane 5-10 part, magnesium hydroxide 8-12 part, fire retardant 4-8 part, fortifying fibre 7-10 part, vinyl cyanide 7-11 part, stablizer 2-8 part, sizing agent 6-10 part.
2. according to the described high-intensity glass composition of claim 1, it is characterized in that, made by the raw material of following weight part: 60 parts, resol, 4 parts, rosin, 15 parts of unsaturated polyester resins, 7 parts of organo-siloxanes, 10 parts of magnesium hydroxides, 6 parts of fire retardants, 8 parts of fortifying fibres, 9 parts of vinyl cyanide, 5 parts of stablizers, 8 parts of sizing agents.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310462066.8A CN103483766A (en) | 2013-10-02 | 2013-10-02 | High-strength glass composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310462066.8A CN103483766A (en) | 2013-10-02 | 2013-10-02 | High-strength glass composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103483766A true CN103483766A (en) | 2014-01-01 |
Family
ID=49824389
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310462066.8A Pending CN103483766A (en) | 2013-10-02 | 2013-10-02 | High-strength glass composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103483766A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103788608A (en) * | 2014-01-15 | 2014-05-14 | 芜湖市宝艺游乐科技设备有限公司 | A kind of modified fiberglass composite coating material and preparation method thereof |
| CN107418134A (en) * | 2017-05-14 | 2017-12-01 | 南通德瑞森复合材料有限公司 | A kind of high strength glass fibre reinforced grid material |
-
2013
- 2013-10-02 CN CN201310462066.8A patent/CN103483766A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103788608A (en) * | 2014-01-15 | 2014-05-14 | 芜湖市宝艺游乐科技设备有限公司 | A kind of modified fiberglass composite coating material and preparation method thereof |
| CN107418134A (en) * | 2017-05-14 | 2017-12-01 | 南通德瑞森复合材料有限公司 | A kind of high strength glass fibre reinforced grid material |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140101 |
|
| WD01 | Invention patent application deemed withdrawn after publication |