[go: up one dir, main page]

CN103481638B - Printing roller for laser paper printing and manufacturing process thereof - Google Patents

Printing roller for laser paper printing and manufacturing process thereof Download PDF

Info

Publication number
CN103481638B
CN103481638B CN201310447725.0A CN201310447725A CN103481638B CN 103481638 B CN103481638 B CN 103481638B CN 201310447725 A CN201310447725 A CN 201310447725A CN 103481638 B CN103481638 B CN 103481638B
Authority
CN
China
Prior art keywords
engraving
layer
roller body
laser
copper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201310447725.0A
Other languages
Chinese (zh)
Other versions
CN103481638A (en
Inventor
范和喜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongguan Yuncheng Plate Making Co ltd
Original Assignee
Dongguan Yuncheng Plate Making Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongguan Yuncheng Plate Making Co ltd filed Critical Dongguan Yuncheng Plate Making Co ltd
Priority to CN201310447725.0A priority Critical patent/CN103481638B/en
Publication of CN103481638A publication Critical patent/CN103481638A/en
Application granted granted Critical
Publication of CN103481638B publication Critical patent/CN103481638B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Electroplating Methods And Accessories (AREA)

Abstract

本发明涉及凹印版辊技术领域,具体涉及一种用于镭射纸张印刷的版辊及其制作工艺,本发明的制作工艺包括镀铜、包胶、激光雕刻、腐蚀、脱胶和镀铬步骤,本发明的版辊包括辊体,辊体外表面设置有非印刷区域和印刷区域,非印刷区域表面固定连接有镀铜层,印刷区域表面开设有激光雕刻层,镀铜层和激光雕刻层表面均固定连接有镀铬层,激光雕刻层包括第一雕刻层和第二雕刻层,第一雕刻层的雕刻网线数、雕刻网角和第二雕刻层的雕刻网线数、雕刻网角均不相同。本发明通过采用两次雕刻的制作工艺,可以使凹印后的断层位置错位,从而达到印刷层次自然平缓。本发明的制作工艺简单,控制方便,生产效率高。

The present invention relates to the technical field of gravure printing plate rollers, and specifically to a plate roller for laser paper printing and a manufacturing process thereof. The manufacturing process of the present invention includes copper plating, glue coating, laser engraving, corrosion, degumming and chrome plating steps. The plate roller of the present invention includes a roller body, a non-printing area and a printing area are arranged on the outer surface of the roller body, a copper plating layer is fixedly connected to the surface of the non-printing area, a laser engraving layer is provided on the surface of the printing area, and a chrome plating layer is fixedly connected to the surface of the copper plating layer and the laser engraving layer. The laser engraving layer includes a first engraving layer and a second engraving layer, and the number of engraving mesh lines and the engraving mesh angle of the first engraving layer are different from the number of engraving mesh lines and the engraving mesh angle of the second engraving layer. The present invention can dislocate the fault position after gravure printing by adopting a manufacturing process of two engravings, so as to achieve a natural and gentle printing layer. The manufacturing process of the present invention is simple, easy to control, and has high production efficiency.

Description

一种用于镭射纸张印刷的版辊及其制作工艺A version roller for laser paper printing and its manufacturing process

技术领域 technical field

本发明涉及凹印版辊技术领域,具体涉及一种用于镭射纸张印刷的版辊及其制作工艺。 The invention relates to the technical field of gravure plate rolls, in particular to a plate roll for laser paper printing and a manufacturing process thereof.

背景技术 Background technique

目前,国内烟盒、酒盒等消费品的外包装的发展日新月异,外包装的材料如普通的白卡纸、铜版纸已经被逐渐淘汰,现在越来越多的中等消费品外包装已采用光银纸、镭射纸等高等的新型材料,但这些高等材料因表面经过转移或复合导致表面很不容易着墨,尤其是层次版在凹印时出现难看的断层,客户不得已还要采用胶印印刷,但胶印印刷具有成本高、效率低的缺点,严重影响了客户的经济效益,因此,市场上急需一种印刷效率高,生产成本低,不会出现断层的用于镭射纸张印刷的版辊。 At present, the development of the outer packaging of consumer goods such as cigarette boxes and wine boxes in China is changing with each passing day. The outer packaging materials such as ordinary white cardboard and coated paper have been gradually eliminated. Now more and more medium-sized consumer goods have adopted light silver paper for outer packaging. , laser paper and other high-level new materials, but the surface of these high-level materials is not easy to ink due to the transfer or compounding of the surface, especially when the layered plate has ugly faults during gravure printing, customers have to use offset printing, but offset printing It has the disadvantages of high cost and low efficiency, which seriously affects the economic benefits of customers. Therefore, there is an urgent need in the market for a plate roller for laser paper printing with high printing efficiency, low production cost, and no faults.

发明内容 Contents of the invention

为了克服现有技术中存在的缺点和不足,本发明的目的在于提供一种用于镭射纸张印刷的版辊的制作工艺,该工艺步骤简单,控制方便,生产效率高。 In order to overcome the shortcomings and deficiencies in the prior art, the object of the present invention is to provide a manufacturing process for a master roll for laser paper printing, which has simple steps, convenient control and high production efficiency.

本发明的另一目的在于提供一种印刷效率高,生产成本低,不会出现断层的用于镭射纸张印刷的版辊。 Another object of the present invention is to provide a plate roller for laser paper printing with high printing efficiency, low production cost and no breakage.

本发明的目的通过下述技术方案实现:一种用于镭射纸张印刷的版辊的制作工艺,包括如下步骤: The object of the present invention is achieved through the following technical solutions: a manufacturing process for a plate roller for laser paper printing, comprising the steps of:

A、镀铜:将辊体放入装有镀铜液的电镀槽中进行电镀,电流密度为16~18ASF,电镀温度为30~50℃,电镀时间为30~60min,维氏硬度为180~210,镀得铜层的厚度为10~14um; A. Copper plating: Put the roller body into the electroplating tank with copper plating solution for electroplating, the current density is 16~18ASF, the electroplating temperature is 30~50℃, the electroplating time is 30~60min, and the Vickers hardness is 180~ 210, the thickness of the plated copper layer is 10~14um;

B、包胶:将镀铜后的辊体挂起,在辊体外侧均匀地涂覆一层0.05~0.25mm的胶液,涂覆完成后自然晾干30~40min; B. Gluing: hang the copper-plated roller body, and evenly coat a layer of 0.05~0.25mm glue solution on the outside of the roller body, and let it dry naturally for 30~40min after coating;

C、激光雕刻:将包胶晾干后的辊体放入激光雕刻机内,设定雕刻网线数和雕刻网角,按设计好的图案进行激光雕刻,激光雕刻的深度为60~150mm;激光雕刻包括第一次激光雕刻和第二次激光雕刻,第一雕刻的雕刻网线数、雕刻网角和第二雕刻的雕刻网线数、雕刻网角均不相同。 C. Laser engraving: Put the rubber-coated and dried roller body into the laser engraving machine, set the number of engraving mesh lines and engraving mesh angle, and carry out laser engraving according to the designed pattern. The depth of laser engraving is 60~150mm; Engraving includes the first laser engraving and the second laser engraving. The number of engraving screen lines and engraving screen angles of the first engraving are different from those of the second engraving.

D、腐蚀:将雕刻后的辊体放入喷淋式滚筒腐蚀机内,对辊体上的可见铜层进行腐蚀,腐蚀液为波美度在34~38的三氯化铁溶液,腐蚀温度为20~40℃,腐蚀时间为5~20s; D. Corrosion: Put the engraved roller body into a spray drum corrosion machine to corrode the visible copper layer on the roller body. The corrosion solution is ferric chloride solution with a Baume degree of 34~38, and the corrosion temperature The temperature is 20~40℃, and the corrosion time is 5~20s;

E、脱胶:利用工业酒精对腐蚀后的辊体进行脱胶处理; E. Degumming: Use industrial alcohol to degumming the corroded roller body;

F、镀铬:将脱胶后的辊体放入装有镀铬液的电镀槽中进行电镀,电流密度为28~32ASF,电镀温度为50~60℃,电镀时间为5~30min,维氏硬度为800~900,镀得铜铬层的厚度为4~6um。 F. Chromium plating: Put the degummed roller body into an electroplating bath filled with chrome plating solution for electroplating. The current density is 28~32ASF, the electroplating temperature is 50~60°C, the electroplating time is 5~30min, and the Vickers hardness is 800. ~900, the thickness of the copper-chromium layer is 4~6um.

本发明采用的辊体是由无缝钢管制成的辊体。无缝钢管是一种具有中空截面、周边没有接缝的圆形、方形或矩形钢材。无缝钢管是用钢锭或实心管坯经穿孔制成毛管,然后经热轧、冷轧或冷拨制成。无缝钢管具有中空截面,大量用作输送流体的管道,钢管与圆钢等实心钢材相比,在抗弯抗扭强度相同时,重量较轻,是一种经济截面钢材,广泛用于制造结构件和机械零件,如石油钻杆、汽车传动轴、自行车架以及建筑施工中用的钢脚手架等。 The roll body used in the present invention is a roll body made of seamless steel pipe. Seamless steel pipe is a round, square or rectangular steel material with a hollow cross-section and no joints around it. Seamless steel pipes are made of steel ingots or solid tube blanks that are perforated into capillary tubes, and then made by hot rolling, cold rolling or cold drawing. The seamless steel pipe has a hollow section and is widely used as a pipe for conveying fluid. Compared with solid steel such as round steel, the steel pipe is lighter in weight when the bending and torsional strength is the same. It is an economical cross-section steel and is widely used in the manufacture of structures. components and mechanical parts, such as oil drill pipes, automobile drive shafts, bicycle frames, and steel scaffolding used in building construction.

辊体首先要进行镀铜处理,镀铜层是激光雕刻的工作面,所以它的质量必须符合下列要求:铜的纯度高、品粒细;镀层表面应光滑无凹陷、无条纹等;镀层有足够的硬度和韧性。铜层镀好以后,还要经过车磨联合机切削或研磨机研磨抛光机抛光等工序制作,使版辊的直径公差、平行度公差及表面光洁度均达到要求。 The roller body must be copper-plated first, and the copper-plated layer is the working surface of laser engraving, so its quality must meet the following requirements: high purity copper, fine grain; the surface of the coating should be smooth without depressions, no streaks, etc.; Sufficient hardness and toughness. After the copper layer is plated, it needs to be cut by a turning-grinding machine or polished by a grinding machine, grinding and polishing machine, so that the diameter tolerance, parallelism tolerance and surface finish of the plate roller can meet the requirements.

优选的,所述步骤A中,镀铜液由以下原料组成:硫酸铜5~20g/L、乙二胺四乙酸二钠10~30g /L、酒石酸钾钠5~20g/L、甲醛2~5g/L、氢氧化钠10~15g/L、甲醇0.001~0.1g/L和硅酸钠0.1~2g/L;镀铜液的pH 值为12~13;电镀的阳极材料为磷含量在2‰~5‰的铜板。 Preferably, in the step A, the copper plating solution is composed of the following raw materials: copper sulfate 5-20g/L, disodium edetate 10-30g/L, potassium sodium tartrate 5-20g/L, formaldehyde 2~ 5g/L, sodium hydroxide 10~15g/L, methanol 0.001~0.1g/L and sodium silicate 0.1~2g/L; the pH value of the copper plating solution is 12~13; the anode material for electroplating is a phosphorus content of 2 ‰~5‰ copper plate.

镀铜液主要由铜盐、还原剂、络合剂、稳定剂、pH值调节剂和其他添加剂组成。 The copper plating solution is mainly composed of copper salt, reducing agent, complexing agent, stabilizer, pH regulator and other additives.

铜盐的主要作用是提供铜离子,镀铜液中铜盐含量对沉积速度有一定的影响。当溶液的pH值控制在工艺范围内时,提高溶液中的铜含量,沉积速度有所增加,但溶液自然分解的倾向也随之增大。在不含稳定剂的溶液中,宜采用低浓度的镀液;在含有稳定剂的溶液中,铜离子浓度可适当高一些。铜盐浓度对镀层性能的影响不大,但铜盐中的杂质可能对镀层产生很大影响,因此化学镀铜液对铜盐纯度的要求一般较高。从降低成本考虑,本发明采用的铜盐为硫酸铜,纯度为分析纯。 The main function of copper salt is to provide copper ions, and the content of copper salt in the copper plating solution has a certain influence on the deposition rate. When the pH value of the solution is controlled within the technological range, increasing the copper content in the solution increases the deposition rate, but the tendency of the solution to decompose naturally also increases. In the solution without stabilizer, it is advisable to use a low concentration plating solution; in the solution containing stabilizer, the concentration of copper ions can be appropriately higher. The concentration of copper salt has little effect on the performance of the coating, but the impurities in the copper salt may have a great impact on the coating, so the electroless copper plating solution generally requires higher purity of copper salt. Considering cost reduction, the copper salt used in the present invention is copper sulfate, and its purity is analytically pure.

以甲醛作还原剂的化学镀铜溶液是碱性的,为防止铜离子形成氢氧化物沉淀析出,镀液中必须加入络合剂,以使铜离子成为络离子状态。络合剂对于化学镀铜溶液和镀层性能的影响很大,近代化学镀铜溶液中通常添加两种或两种以上的络合剂。本发明采用乙二胺四乙酸二钠作为主络合剂,酒石酸钾钠作为辅助络合剂,由于乙二胺四乙酸二钠稳定镀液的能力比酒石酸钾钠强,但酒石酸钾钠镀液中所得到的镀层外观优于乙二胺四乙酸二钠镀液,两种络合剂配合使用可以提高镀液的稳定性,而且可以提高镀速和镀层质量。 The electroless copper plating solution using formaldehyde as a reducing agent is alkaline. In order to prevent copper ions from forming hydroxides and precipitate out, a complexing agent must be added to the plating solution to make the copper ions become complex ions. The complexing agent has a great influence on the electroless copper plating solution and the performance of the plating layer. Two or more complexing agents are usually added to the modern electroless copper plating solution. The present invention adopts edetate disodium as the main complexing agent, potassium sodium tartrate as the auxiliary complexing agent, because the ability of edetate disodium to stabilize the plating solution is stronger than potassium sodium tartrate, but potassium sodium tartrate plating solution The appearance of the coating obtained in the method is better than that of disodium ethylenediaminetetraacetic acid plating solution. The combination of the two complexing agents can improve the stability of the plating solution, and can improve the plating speed and the quality of the coating.

镀铜液中必须加入还原剂,而甲醛的还原能力随镀液碱性的提高而增加,通常镀铜液在pH值大于11的条件才具有还原铜的能力。镀液的pH值越高,甲醛的还原能力越强,镀速越快。但是如果镀液pH值过高,容易造成镀液的自发分解,降低镀液的稳定性,因此大多数镀铜液的pH值都控制在12左右,本发明的镀铜液pH值为12~13,采用甲醛作为还原剂。 A reducing agent must be added to the copper plating solution, and the reducing ability of formaldehyde increases with the increase of the alkalinity of the plating solution. Usually, the copper plating solution has the ability to reduce copper only when the pH value is greater than 11. The higher the pH value of the plating solution, the stronger the reducing ability of formaldehyde and the faster the plating speed. But if the pH value of the plating solution is too high, it will easily cause the spontaneous decomposition of the plating solution and reduce the stability of the plating solution. Therefore, the pH value of most copper plating solutions is controlled at about 12, and the pH value of the copper plating solution of the present invention is 12~ 13. Using formaldehyde as a reducing agent.

由于化学镀铜的过程是镀液pH值降低的过程,因此必须向镀液中加入pH值调节剂,以维持镀液的pH值在正常的范围内,本发明采用的pH值调节剂为氢氧化钠。 Since the process of electroless copper plating is a process in which the pH value of the plating solution decreases, a pH value regulator must be added to the plating solution to maintain the pH value of the plating solution within the normal range. The pH value regulator used in the present invention is hydrogen sodium oxide.

在化学镀铜的过程中,除铜离子在催化表面进行有效的氧化还原反应,被甲醛还原成金属铜之外,还存在许多副反应。副反应不仅消耗了镀铜液中的有效成分,而且产生的氧化亚铜以极细微的粉末悬浮在镀液中,很难用过滤除去,容易引起镀液分解,若与铜共沉积,则得到的铜沉积层疏松粗糙、与基体结合力差。 In the process of electroless copper plating, in addition to the effective oxidation-reduction reaction of copper ions on the catalytic surface, which is reduced to metallic copper by formaldehyde, there are many side reactions. The side reaction not only consumes the active ingredients in the copper plating solution, but also produces cuprous oxide suspended in the plating solution as a very fine powder, which is difficult to remove by filtration and easily causes the decomposition of the plating solution. If it is co-deposited with copper, it will get The copper deposition layer is loose and rough, and has poor bonding force with the substrate.

针对上述问题,镀铜液中需加入稳定剂以达到稳定镀液和改善镀层质量的作用,本发明采用甲醇作为稳定剂。由于大多数的稳定剂又同时是化学镀铜反应的催化毒化剂,因此,使用稳定剂时,用量的控制是十分重要的。否则,用量多时,会显著降低镀速甚至造成电镀停止。 In view of the above problems, a stabilizer needs to be added in the copper plating solution to stabilize the plating solution and improve the quality of the coating. The present invention uses methanol as the stabilizer. Since most of the stabilizers are also catalytic poisoning agents for the electroless copper plating reaction, it is very important to control the amount of stabilizers when using them. Otherwise, when the amount is too large, the plating speed will be significantly reduced or even the electroplating will stop.

能在稳定镀液的前提下提高铜沉积速度的添加剂称为加速剂或促进剂。为降低化学镀铜溶液的表面张力,改善镀层质量,在化学镀铜溶液中有时也添加某些表面活性剂。本发明采用硅酸钠硅作为添加剂,能够有效的吸附镀液中对镀铜有害的杂质,以及副反应形成的少量铜粉,并且可以通过凝聚作用,使铜粉聚在一起,通过过滤可以快速的过滤掉,可以提高生产上的化学镀铜过程稳定性。 Additives that can increase the copper deposition rate under the premise of stabilizing the plating solution are called accelerators or accelerators. In order to reduce the surface tension of the electroless copper plating solution and improve the quality of the coating, some surfactants are sometimes added to the electroless copper plating solution. The invention uses sodium silicate as an additive, which can effectively absorb impurities harmful to copper plating in the plating solution and a small amount of copper powder formed by side reactions, and can make the copper powder gather together through coagulation, and can be quickly filtered through filtration. Filtering out can improve the stability of the electroless copper plating process on production.

优选的,所述步骤B具体为:将镀铜后的辊体挂起,在辊体外侧套置一个圆形胶片,圆形胶片连接有装有胶液的盒体,在电机10~20Hz功率带动下,圆形胶片沿辊体竖直向下匀速运动,在辊体外侧均匀地涂覆一层0.05~0.25mm的胶液,涂覆完成后自然晾干30~40min。 所述胶液为激光雕刻感光胶。 Preferably, the step B is specifically as follows: hang the copper-plated roller body, place a circular film on the outside of the roller body, the circular film is connected with a box containing glue, and the Driven, the circular film moves vertically downward along the roller body at a constant speed, and evenly coats a layer of 0.05~0.25mm glue solution on the outside of the roller body, and then dries naturally for 30~40 minutes after the coating is completed. The glue solution is photosensitive glue for laser engraving.

优选的,所述步骤C中,图案的设计包括如下步骤: Preferably, in said step C, the design of pattern comprises the following steps:

(1)扫描:选择木材木纹,采用焦距为120mm的高清镜头、输入分辨率为1800~2000dpi对木纹进行扫描,镜头与扫描平台的距离为45~55cm; (1) Scanning: Select the wood grain, use a high-definition lens with a focal length of 120mm, and an input resolution of 1800~2000dpi to scan the wood grain, and the distance between the lens and the scanning platform is 45~55cm;

(2)处理:将扫描后的图像调整分辨率为800~1000dpi,对扫描后的图像进行分色、调色、修版处理;降低分辨率至304.8dpi,得到设计好的图案。 (2) Processing: adjust the scanned image to a resolution of 800~1000dpi, and perform color separation, color correction, and version revision processing on the scanned image; reduce the resolution to 304.8dpi to obtain a designed pattern.

本发明的图像处理采用GMG色彩软件,通过GMG软件在木纹中的应用,能够很好的体现多种专色的木纹效果,更好的体现实木的质感,从而解决了客人为了追求质量而要求的多次返修后的各种浪费。在印刷前能很好的还原实木图文,有效的控制产品质量,打样效果直接达到印刷水平。 The image processing of the present invention adopts GMG color software, and through the application of GMG software in wood grain, it can well reflect the wood grain effect of various spot colors, and better reflect the texture of solid wood, thereby solving the problem of customers seeking quality. All kinds of waste after multiple repairs required. Before printing, it can well restore solid wood graphics, effectively control product quality, and the proofing effect can directly reach the printing level.

优选的,所述步骤C中,激光雕刻的参数为:电机功率为30~50W,辊体转速为700~900r/min,雕刻时间为1~3h,焦距为20~24mm。 Preferably, in the step C, the parameters of the laser engraving are as follows: the motor power is 30-50W, the rotation speed of the roller body is 700-900r/min, the engraving time is 1-3h, and the focal length is 20-24mm.

优选的,所述步骤C中,第一次激光雕刻的雕刻网线数为60~80,雕刻网角为40°,第一次激光雕刻的雕刻网线数为85~105,雕刻网角为37°。 Preferably, in the step C, the number of engraved mesh lines for the first laser engraving is 60-80, the engraved mesh angle is 40°, the engraved mesh lines number for the first laser engraving is 85-105, and the engraved mesh angle is 37° .

更为优选的,当第一次激光雕刻的雕刻网线数为80线、雕刻网角为37°时,第二次激光雕刻的雕刻网线数为105线、雕刻网角为40°;当第一次激光雕刻的雕刻网线数为70线、雕刻网角为37°时,第二次激光雕刻的雕刻网线数为100线、雕刻网角为40°;当第一次激光雕刻的雕刻网线数为60线、雕刻网角为37°时,第二次激光雕刻的雕刻网线数为86线、雕刻网角为40°。 More preferably, when the engraving line number of the first laser engraving is 80 lines and the engraving screen angle is 37°, the engraving line number of the second laser engraving is 105 lines and the engraving screen angle is 40°; when the first When the engraving line number of the first laser engraving is 70 lines and the engraving screen angle is 37°, the engraving line number of the second laser engraving is 100 lines and the engraving screen angle is 40°; when the engraving line number of the first laser engraving is When 60 lines and engraving screen angle are 37°, the number of engraving screen lines for the second laser engraving is 86 lines and engraving screen angle is 40°.

优选的,所述步骤C中,激光雕刻后形成的网穴的横截面呈“凵”字型。 Preferably, in the step C, the cross-section of the cells formed after laser engraving is in the shape of "凵".

传统的激光雕刻后形成的网穴的横截面呈“V” 字型,但“V” 字型网穴的着墨量较小,层次版在凹印时出现难看的断层,本发明采用“凵”字型网穴,着墨量大,能解决凹印时出现断层的问题。更为优选的,激光雕刻后形成的网穴的横截面呈倒“凸”字型,倒“凸”字型的设计使得凹印时,油墨由于张力的作用使得顶角更为圆滑,着墨量大,成产效率高,成本低。 The cross-section of the cells formed after traditional laser engraving is "V"-shaped, but the amount of ink in the "V"-shaped cells is small, and there are ugly faults in the layered plate during gravure printing. The present invention adopts "凵" Font type mesh, large amount of ink, can solve the problem of faults in gravure printing. More preferably, the cross-section of the cells formed after laser engraving is in an inverted "convex" shape. The inverted "convex" shape design makes the top angle of the ink more smooth due to the tension during gravure printing, and the amount of ink Large, high production efficiency and low cost.

由于镀铜层的硬度较差,在印刷时易被刮刀刮伤,因此要在镀铜层的表面镀上一层硬铬层。镀铬需要经过以下步骤:清洗、脱脂、镀铬、抛光。清洗与脱脂的目的是将版面的油脂、脏污去掉,抛光则是为了把镀铬过程中网穴边缘的毛刺打磨掉。凹印版辊表面所镀铬层有很高的硬度及高度的耐磨性和化学稳定性,通过镀铬使印版表面的铜层不受损伤是制作印刷版辊必须的一道程序,而要提高印版的耐印力主要也是提高铬层的硬度。 Due to the poor hardness of the copper plating layer, it is easy to be scratched by the scraper during printing, so a layer of hard chromium layer should be plated on the surface of the copper plating layer. Chrome plating needs to go through the following steps: cleaning, degreasing, chrome plating, polishing. The purpose of cleaning and degreasing is to remove the grease and dirt on the layout, and the purpose of polishing is to polish off the burrs on the edge of the mesh cell during the chrome plating process. The chrome-plated layer on the surface of the gravure plate roller has high hardness, high wear resistance and chemical stability. It is a necessary procedure to make the printing plate roller to prevent the copper layer on the surface of the printing plate from being damaged by chrome plating, and to improve the printing plate The printing resistance of the plate is mainly to improve the hardness of the chrome layer.

优选的,所述步骤F中,镀铬液包括以下重量份的原料:铬酸酐180~220份、氟化钠1~5份、溴酸钾2~6份、硫酸1.8~2.2份和CF-202 2~5份;铬酸酐与硫酸的重量比为100:1~1.3;镀铬液的pH值为1~2;电镀的阳极材料为锡含量在20%~50%、银含量在0.5%~1.5%的铅锡银合金。 Preferably, in the step F, the chromium plating solution includes the following raw materials in parts by weight: 180 to 220 parts of chromic anhydride, 1 to 5 parts of sodium fluoride, 2 to 6 parts of potassium bromate, 1.8 to 2.2 parts of sulfuric acid and 2 to 2 parts of CF-202 5 parts; the weight ratio of chromic anhydride to sulfuric acid is 100:1~1.3; the pH value of the chromium plating solution is 1~2; the anode material for electroplating is tin content 20%~50%, silver content 0.5%~1.5% Lead tin silver alloy.

铬酸酐的用量对镀铬层的硬度有较大影响,在其它工艺条件相同的时候,铬酸酐浓度低时硬度高;但铬酸酐浓度低时,镀铬液变化快,不稳定。 The amount of chromic anhydride has a great influence on the hardness of the chromium plating layer. When the other process conditions are the same, the hardness is high when the concentration of chromic anhydride is low; but when the concentration of chromic anhydride is low, the chromium plating solution changes rapidly and is unstable.

在正常的镀铬工艺规范中,铬酸酐与硫酸的重量比应该保持在100:1,本发明采用的铬酸酐与硫酸的重量比为100:1~1.3,在其它浓度不变时,提高硫酸含量,铬层的硬度也相应增高;但在二者比值为100:1.4时,再提高硫酸含量硬度值又会下降。 In normal chromium plating process specifications, the weight ratio of chromic anhydride to sulfuric acid should be kept at 100:1. The weight ratio of chromic anhydride to sulfuric acid used in the present invention is 100:1~1.3. When other concentrations remain unchanged, increase the sulfuric acid content , the hardness of the chromium layer also increases correspondingly; but when the ratio of the two is 100:1.4, the hardness value will decrease again when the sulfuric acid content is increased.

     CF-202为稀土镀铬添加剂,在金属表面处理工艺中,能优化工艺,改善质量,降低综合成本,效果十分明显,深得广大用户的认可和青睐。兼有除杂功能,减少镀铬故障,稳定低铬镀铬,深镀能力极佳。   CF-202 is a rare earth chrome plating additive. In the metal surface treatment process, it can optimize the process, improve the quality, and reduce the overall cost. The effect is very obvious, and it has won the recognition and favor of the majority of users. It also has the function of removing impurities, reducing chrome plating failures, stable low chrome chrome plating, and excellent deep plating ability.

在正常温度下,铬层硬度随着电流密度的增加而提高,当电流密度达到一定极限时硬度趋向稳定。 At normal temperature, the hardness of the chromium layer increases with the increase of the current density, and the hardness tends to be stable when the current density reaches a certain limit.

在较高温度(50~60℃)下,由稀溶液镀出的铬层比由浓镀液镀出的铬层硬度高15~20%;在较低温度(35~45℃)下,由稀溶液镀出的铬层比由浓镀液镀出的铬层硬度没有多大差别。 At a higher temperature (50-60°C), the hardness of the chromium layer plated from a dilute solution is 15-20% higher than that of a concentrated plating solution; The hardness of the chromium layer plated from the dilute solution is not much different from that of the chromium layer plated from the concentrated solution.

本发明的另一目的通过下述技术方案实现:一种用于镭射纸张印刷的版辊,包括辊体,辊体外表面设置有非印刷区域和印刷区域,非印刷区域表面固定连接有镀铜层,印刷区域表面开设有激光雕刻层,镀铜层和激光雕刻层表面均固定连接有镀铬层,激光雕刻层包括第一雕刻层和第二雕刻层,第一雕刻层的雕刻网线数、雕刻网角和第二雕刻层的雕刻网线数、雕刻网角均不相同。 Another object of the present invention is achieved through the following technical solutions: a plate roller for laser paper printing, comprising a roller body, a non-printing area and a printing area are arranged on the outer surface of the roller body, and a copper-plated layer is fixedly connected to the surface of the non-printing area , the surface of the printing area is provided with a laser engraving layer, and the surface of the copper plating layer and the laser engraving layer are fixedly connected with a chrome plating layer. The number of engraving mesh lines and the engraving mesh angle of the angle and the second engraving layer are different.

优选的,所述镀铜层、激光雕刻层和镀铬层的厚度依次为10~14um、100~150um和4~6um。 Preferably, the thicknesses of the copper plating layer, the laser engraving layer and the chrome plating layer are 10-14um, 100-150um and 4-6um in sequence.

本发明的有益效果在于:本发明的制作工艺包括镀铜、包胶、激光雕刻、腐蚀、脱胶和镀铬步骤,其中,激光雕刻包括第一次激光雕刻和第二次激光雕刻,第一雕刻的雕刻网线数、雕刻网角和第二雕刻的雕刻网线数、雕刻网角均不相同。通过采用两次雕刻的制作工艺,可以使凹印后的断层位置错位,从而达到印刷层次自然平缓。本发明的制作工艺简单,控制方便,生产效率高。 The beneficial effects of the present invention are that: the manufacturing process of the present invention includes the steps of copper plating, encapsulation, laser engraving, corrosion, degumming and chrome plating, wherein the laser engraving includes the first laser engraving and the second laser engraving, and the first engraving The engraving screen line number and engraving screen angle are different from the engraving screen line number and engraving screen angle of the second engraving. By using the two-time engraving process, the position of the fault after the gravure printing can be dislocated, so as to achieve a natural and gentle printing level. The invention has the advantages of simple manufacturing process, convenient control and high production efficiency.

本发明的版辊的第一雕刻层的雕刻网线数、雕刻网角和第二雕刻层的雕刻网线数、雕刻网角均不相同,可以通过凹印的方式解决层次版印刷时的断层问题,通过第一雕刻层和第二雕刻层的重叠印刷,使断层位置错位,从而达到印刷层次自然平缓,印刷效率高,生产成本低。本发明的用于镭射纸张印刷的版辊印刷效率高,生产成本低,不会出现断层。 The engraved line number and engraved screen angle of the first engraved layer of the version roller of the present invention are all different from the engraved screen lines and engraved screen angle of the second engraved layer, which can solve the fault problem during layered plate printing by means of gravure printing. Through overlapping printing of the first engraving layer and the second engraving layer, the position of the fault is dislocated, so that the printing layer is naturally smooth, the printing efficiency is high, and the production cost is low. The plate roller used for laser paper printing of the present invention has high printing efficiency, low production cost and no faults.

附图说明:Description of drawings:

图1是本发明所述版辊的结构示意图。 Fig. 1 is a structural schematic diagram of the plate roller of the present invention.

图2是本发明所述版辊的局部剖视图。 Fig. 2 is a partial cross-sectional view of the plate roll of the present invention.

图3是本发明所述第一激光雕刻层和第二激光雕刻层的俯视图。 Fig. 3 is a top view of the first laser engraving layer and the second laser engraving layer of the present invention.

附图标记为: The reference signs are:

1——辊体 1——roll body

2——非印刷区域 2 - non-printing area

3——印刷区域 3 - printing area

4——镀铜层 4——Copper plating layer

5——激光雕刻层 5—Laser engraving layer

51——第一激光雕刻层 51——The first laser engraving layer

52——第二激光雕刻层 52——Second laser engraving layer

6——镀铬层。 6—Chrome layer.

具体实施方式:Detailed ways:

为了便于本领域技术人员的理解,下面结合实施例对本发明作进一步的说明,实施方式提及的内容并非对本发明的限定。 In order to facilitate the understanding of those skilled in the art, the present invention will be further described below in conjunction with the examples, and the contents mentioned in the embodiments are not intended to limit the present invention.

实施例1 Example 1

一种用于镭射纸张印刷的版辊的制作工艺,包括如下步骤: A manufacturing process for a plate roller for laser paper printing, comprising the following steps:

A、镀铜:将辊体1放入装有镀铜液的电镀槽中进行电镀,电流密度为16ASF,电镀温度为30℃,电镀时间为30min,维氏硬度为180,镀得铜层的厚度为10um;所述步骤A中,镀铜液由以下原料组成:硫酸铜5g/L、乙二胺四乙酸二钠10g /L、酒石酸钾钠5g/L、甲醛2g/L、氢氧化钠10g/L、甲醇0.001g/L和硅酸钠0.1g/L;镀铜液的pH 值为12;电镀的阳极材料为磷含量在2‰的铜板; A. Copper plating: put the roller body 1 into an electroplating bath equipped with a copper plating solution for electroplating, the current density is 16ASF, the electroplating temperature is 30°C, the electroplating time is 30min, the Vickers hardness is 180, and the copper layer is plated The thickness is 10um; in the step A, the copper plating solution is composed of the following raw materials: copper sulfate 5g/L, disodium edetate 10g/L, potassium sodium tartrate 5g/L, formaldehyde 2g/L, sodium hydroxide 10g/L, methanol 0.001g/L and sodium silicate 0.1g/L; the pH value of the copper plating solution is 12; the anode material for electroplating is a copper plate with a phosphorus content of 2‰;

B、包胶:将镀铜后的辊体1挂起,在辊体1外侧套置一个圆形胶片,圆形胶片连接有装有胶液的盒体,在电机10Hz功率带动下,圆形胶片沿辊体1竖直向下匀速运动,在辊体1外侧均匀地涂覆一层0.05mm的胶液,涂覆完成后自然晾干30min; B. Glue wrapping: hang the copper-plated roller body 1, and set a circular film on the outside of the roller body 1. The circular film is connected with a box containing glue. Driven by the power of the motor at 10Hz, the circular film The film moves vertically downward along the roller body 1 at a constant speed, and evenly coats a layer of 0.05mm glue solution on the outside of the roller body 1, and dries naturally for 30 minutes after the coating is completed;

C、激光雕刻:将包胶晾干后的辊体1放入激光雕刻机内,设定雕刻网线数和雕刻网角,按设计好的图案进行激光雕刻,激光雕刻的深度为60mm;所述步骤C中,图案的设计包括如下步骤: C. Laser engraving: put the roller body 1 after the rubber coating has dried into the laser engraving machine, set the number of engraving screen lines and engraving screen angle, and carry out laser engraving according to the designed pattern. The depth of laser engraving is 60mm; In step C, the design of pattern comprises the following steps:

(1)扫描:选择木材木纹,采用焦距为120mm的高清镜头、输入分辨率为1800dpi对木纹进行扫描,镜头与扫描平台的距离为45cm; (1) Scanning: Select the wood grain, use a high-definition lens with a focal length of 120mm, and an input resolution of 1800dpi to scan the wood grain, and the distance between the lens and the scanning platform is 45cm;

(2)处理:将扫描后的图像调整分辨率为800dpi,对扫描后的图像进行分色、调色、修版处理;降低分辨率至304.8dpi,得到设计好的图案。 (2) Processing: Adjust the resolution of the scanned image to 800dpi, and perform color separation, color correction, and revision processing on the scanned image; reduce the resolution to 304.8dpi to obtain the designed pattern.

所述步骤C中,激光雕刻的参数为:电机功率为30W,辊体1转速为700r/min,雕刻时间为1h,焦距为20 mm; In the step C, the parameters of the laser engraving are: the motor power is 30W, the rotation speed of the roller body 1 is 700r/min, the engraving time is 1h, and the focal length is 20mm;

所述步骤C中,第一次激光雕刻的雕刻网线数为80线、雕刻网角为37°,第二次激光雕刻的雕刻网线数为105线、雕刻网角为40°; In the described step C, the number of engraved screen lines of the first laser engraving is 80 lines, and the engraving screen angle is 37 °, and the number of engraving screen lines of the second laser engraving is 105 lines, and the engraving screen angle is 40 °;

所述步骤C中,激光雕刻后形成的网穴的横截面呈“凵”字型; In the step C, the cross section of the cell formed after laser engraving is in the shape of "凵";

D、腐蚀:将雕刻后的辊体1放入喷淋式滚筒腐蚀机内,对辊体1上的可见铜层进行腐蚀,腐蚀液为波美度在34的三氯化铁溶液,腐蚀温度为20℃,腐蚀时间为5s; D. Corrosion: put the engraved roller body 1 into a spray drum corrosion machine, and corrode the visible copper layer on the roller body 1. The corrosion solution is a ferric chloride solution with a Baume degree of 34, and the corrosion temperature is at 20°C, and the corrosion time is 5s;

E、脱胶:利用工业酒精对腐蚀后的辊体1进行脱胶处理; E, degumming: use industrial alcohol to degumming the corroded roller body 1;

F、镀铬6:将脱胶后的辊体1放入装有镀铬6液的电镀槽中进行电镀,电流密度为28ASF,电镀温度为50℃,电镀时间为5min,维氏硬度为800,镀得铜铬层的厚度为4um;所述步骤F中,镀铬6液包括以下重量份的原料:铬酸酐180份、氟化钠1份、溴酸钾2份、硫酸1.8份和CF-202 2份;铬酸酐与硫酸的重量比为100:1;镀铬6液的pH值为1;电镀的阳极材料为锡含量在20%、银含量在0.5%的铅锡银合金。 F, chrome plating 6: Put the degummed roller body 1 into the electroplating tank equipped with chrome plating solution 6 for electroplating, the current density is 28ASF, the electroplating temperature is 50°C, the electroplating time is 5min, and the Vickers hardness is 800. The thickness of copper chromium layer is 4um; In described step F, 6 liquids of chromium plating comprise the raw material of following weight portion: chromic anhydride 180 parts, sodium fluoride 1 part, potassium bromate 2 parts, sulfuric acid 1.8 parts and CF-202 2 parts; The weight ratio of acid anhydride to sulfuric acid is 100:1; the pH value of the chrome plating liquid 6 is 1; the anode material of electroplating is a lead-tin-silver alloy with a tin content of 20% and a silver content of 0.5%.

一种用于镭射纸张印刷的版辊,包括辊体1,辊体1表面设置有非印刷区域2和印刷区域3,非印刷区域32表面固定连接有镀铜层4,印刷区域3表面开设有激光雕刻层5,镀铜层4和激光雕刻层5表面均固定连接有镀铬6层,激光雕刻层5包括第一雕刻层51和第二雕刻层52,第一雕刻层51的雕刻网线数、雕刻网角和第二雕刻层52的雕刻网线数、雕刻网角均不相同。所述镀铜层4、激光雕刻层5和镀铬6层的厚度依次为10um、100um和4um。 A version roller for laser paper printing, comprising a roller body 1, the surface of the roller body 1 is provided with a non-printing area 2 and a printing area 3, the surface of the non-printing area 32 is fixedly connected with a copper-plated layer 4, and the surface of the printing area 3 is provided with Laser engraving layer 5, copper plating layer 4 and laser engraving layer 5 surfaces are all fixedly connected with 6 layers of chrome plating, laser engraving layer 5 comprises first engraving layer 51 and second engraving layer 52, the engraving line number of first engraving layer 51, The engraved mesh angle is different from the engraved mesh line number and the engraved mesh angle of the second engraved layer 52 . The thicknesses of the copper plating layer 4, the laser engraving layer 5 and the chrome plating layer 6 are 10um, 100um and 4um in sequence.

实施例2 Example 2

一种用于镭射纸张印刷的版辊的制作工艺,包括如下步骤: A manufacturing process for a plate roller for laser paper printing, comprising the following steps:

A、镀铜:将辊体1放入装有镀铜液的电镀槽中进行电镀,电流密度为17ASF,电镀温度为40℃,电镀时间为45min,维氏硬度为195,镀得铜层的厚度为12um;所述步骤A中,镀铜液由以下原料组成:硫酸铜12g/L、乙二胺四乙酸二钠20g /L、酒石酸钾钠12g/L、甲醛3.5g/L、氢氧化钠12.5g/L、甲醇0.05g/L和硅酸钠1g/L;镀铜液的pH 值为12.5;电镀的阳极材料为磷含量在3‰的铜板; A. Copper plating: Put the roller body 1 into an electroplating tank equipped with a copper plating solution for electroplating. The current density is 17ASF, the electroplating temperature is 40°C, the electroplating time is 45min, and the Vickers hardness is 195. The copper layer is plated. Thickness is 12um; In described step A, copper plating liquid is made up of following raw material: copper sulfate 12g/L, disodium edetate 20g/L, potassium sodium tartrate 12g/L, formaldehyde 3.5g/L, hydroxide Sodium 12.5g/L, methanol 0.05g/L and sodium silicate 1g/L; the pH value of the copper plating solution is 12.5; the anode material for electroplating is a copper plate with a phosphorus content of 3‰;

B、包胶:将镀铜后的辊体1挂起,在辊体1外侧套置一个圆形胶片,圆形胶片连接有装有胶液的盒体,在电机15Hz功率带动下,圆形胶片沿辊体1竖直向下匀速运动,在辊体1外侧均匀地涂覆一层0.15mm的胶液,涂覆完成后自然晾干35min; B. Glue coating: hang the copper-plated roller body 1, and set a circular film on the outside of the roller body 1. The circular film is connected with a box containing glue. Driven by the power of the motor at 15Hz, the circular film The film moves vertically downward along the roller body 1 at a constant speed, and evenly coats a layer of 0.15mm glue solution on the outside of the roller body 1, and dries naturally for 35 minutes after the coating is completed;

C、激光雕刻:将包胶晾干后的辊体1放入激光雕刻机内,设定雕刻网线数和雕刻网角,按设计好的图案进行激光雕刻,激光雕刻的深度为120mm;所述步骤C中,图案的设计包括如下步骤: C. Laser engraving: Put the dried roll body 1 into the laser engraving machine, set the number of engraving mesh lines and the engraving mesh angle, and carry out laser engraving according to the designed pattern. The depth of laser engraving is 120mm; In step C, the design of pattern comprises the following steps:

(1)扫描:选择木材木纹,采用焦距为120mm的高清镜头、输入分辨率为1900dpi对木纹进行扫描,镜头与扫描平台的距离为50cm; (1) Scanning: Select the wood grain, use a high-definition lens with a focal length of 120mm, and an input resolution of 1900dpi to scan the wood grain, and the distance between the lens and the scanning platform is 50cm;

(2)处理:将扫描后的图像调整分辨率为900dpi,对扫描后的图像进行分色、调色、修版处理;降低分辨率至304.8dpi,得到设计好的图案。 (2) Processing: Adjust the resolution of the scanned image to 900dpi, and perform color separation, color correction, and version revision processing on the scanned image; reduce the resolution to 304.8dpi to obtain the designed pattern.

所述步骤C中,激光雕刻的参数为:电机功率为40W,辊体1转速为800r/min,雕刻时间为2h,焦距为22 mm; In the step C, the parameters of the laser engraving are: the motor power is 40W, the rotation speed of the roller body 1 is 800r/min, the engraving time is 2h, and the focal length is 22 mm;

所述步骤C中,第一次激光雕刻的雕刻网线数为70线、雕刻网角为37°,第二次激光雕刻的雕刻网线数为100线、雕刻网角为40°; In the step C, the engraving line number of the first laser engraving is 70 lines, the engraving screen angle is 37 °, the engraving line number of the second laser engraving is 100 lines, and the engraving screen angle is 40 °;

所述步骤C中,激光雕刻后形成的网穴的横截面呈“凵”字型; In the step C, the cross section of the cell formed after laser engraving is in the shape of "凵";

D、腐蚀:将雕刻后的辊体1放入喷淋式滚筒腐蚀机内,对辊体1上的可见铜层进行腐蚀,腐蚀液为波美度在36的三氯化铁溶液,腐蚀温度为30℃,腐蚀时间为12s; D. Corrosion: put the engraved roller body 1 into the spray drum corrosion machine, and corrode the visible copper layer on the roller body 1. The corrosion solution is a ferric chloride solution with a Baume degree of 36, and the corrosion temperature is The temperature is 30℃, and the corrosion time is 12s;

E、脱胶:利用工业酒精对腐蚀后的辊体1进行脱胶处理; E, degumming: use industrial alcohol to degumming the corroded roller body 1;

F、镀铬6:将脱胶后的辊体1放入装有镀铬6液的电镀槽中进行电镀,电流密度为30ASF,电镀温度为55℃,电镀时间为15min,维氏硬度为850,镀得铜铬层的厚度为5um;所述步骤F中,镀铬6液包括以下重量份的原料:铬酸酐200份、氟化钠2.5份、溴酸钾4份、硫酸2.2份和CF-202 3份;铬酸酐与硫酸的重量比为100:1.1;镀铬6液的pH值为1.5;电镀的阳极材料为锡含量在35%、银含量在1%的铅锡银合金。 F. Chromium plating 6: Put the degummed roller body 1 into an electroplating tank equipped with chrome plating solution 6 for electroplating. The current density is 30ASF, the electroplating temperature is 55°C, the electroplating time is 15min, and the Vickers hardness is 850. The thickness of copper chromium layer is 5um; In described step F, 6 liquids of chrome plating comprise the raw material of following weight portion: 200 parts of chromic anhydride, 2.5 parts of sodium fluoride, 4 parts of potassium bromate, 2.2 parts of sulfuric acid and 3 parts of CF-202; The weight ratio of acid anhydride to sulfuric acid is 100:1.1; the pH value of the chromium plating liquid 6 is 1.5; the anode material of electroplating is a lead-tin-silver alloy with a tin content of 35% and a silver content of 1%.

一种用于镭射纸张印刷的版辊,包括辊体1,辊体1表面设置有非印刷区域32和印刷区域3,非印刷区域32表面固定连接有镀铜层4,印刷区域3表面开设有激光雕刻层5,镀铜层4和激光雕刻层5表面均固定连接有镀铬6层,激光雕刻层5包括第一雕刻层51和第二雕刻层52,第一雕刻层51的雕刻网线数、雕刻网角和第二雕刻层52的雕刻网线数、雕刻网角均不相同。所述镀铜层4、激光雕刻层5和镀铬6层的厚度依次为12um、120um和5um。 A version roller for laser paper printing, comprising a roller body 1, the surface of the roller body 1 is provided with a non-printing area 32 and a printing area 3, the surface of the non-printing area 32 is fixedly connected with a copper-plated layer 4, and the surface of the printing area 3 is provided with Laser engraving layer 5, copper plating layer 4 and laser engraving layer 5 surfaces are all fixedly connected with 6 layers of chrome plating, laser engraving layer 5 comprises first engraving layer 51 and second engraving layer 52, the engraving line number of first engraving layer 51, The engraved mesh angle is different from the engraved mesh line number and the engraved mesh angle of the second engraved layer 52 . The thicknesses of the copper plating layer 4, the laser engraving layer 5 and the chrome plating layer 6 are 12um, 120um and 5um in sequence.

实施例3 Example 3

一种用于镭射纸张印刷的版辊的制作工艺,包括如下步骤: A manufacturing process for a plate roller for laser paper printing, comprising the following steps:

A、镀铜:将辊体1放入装有镀铜液的电镀槽中进行电镀,电流密度为18ASF,电镀温度为50℃,电镀时间为60min,维氏硬度为210,镀得铜层的厚度为14um;所述步骤A中,镀铜液由以下原料组成:硫酸铜20g/L、乙二胺四乙酸二钠30g /L、酒石酸钾钠20g/L、甲醛5g/L、氢氧化钠15g/L、甲醇0.1g/L和硅酸钠2g/L;镀铜液的pH 值为13;电镀的阳极材料为磷含量在5‰的铜板; A. Copper plating: put the roller body 1 into an electroplating tank equipped with a copper plating solution for electroplating, the current density is 18ASF, the electroplating temperature is 50°C, the electroplating time is 60min, the Vickers hardness is 210, and the copper layer is plated The thickness is 14um; in the step A, the copper plating solution is composed of the following raw materials: copper sulfate 20g/L, disodium edetate 30g/L, potassium sodium tartrate 20g/L, formaldehyde 5g/L, sodium hydroxide 15g/L, methanol 0.1g/L and sodium silicate 2g/L; the pH value of the copper plating solution is 13; the anode material for electroplating is a copper plate with a phosphorus content of 5‰;

B、包胶:将镀铜后的辊体1挂起,在辊体1外侧套置一个圆形胶片,圆形胶片连接有装有胶液的盒体,在电机20Hz功率带动下,圆形胶片沿辊体1竖直向下匀速运动,在辊体1外侧均匀地涂覆一层0.25mm的胶液,涂覆完成后自然晾干40min; B. Gluing: hang the copper-plated roller body 1, and set a circular film on the outside of the roller body 1. The circular film is connected with a box containing glue. Driven by the power of the motor at 20Hz, the circular film The film moves vertically downward along the roller body 1 at a constant speed, and evenly coats a layer of 0.25mm glue solution on the outside of the roller body 1, and dries naturally for 40 minutes after the coating is completed;

C、激光雕刻:将包胶晾干后的辊体1放入激光雕刻机内,设定雕刻网线数和雕刻网角,按设计好的图案进行激光雕刻,激光雕刻的深度为150mm;所述步骤C中,图案的设计包括如下步骤: C. Laser engraving: Put the rubber-covered roller body 1 into the laser engraving machine, set the number of engraving mesh lines and engraving mesh angle, and carry out laser engraving according to the designed pattern. The depth of laser engraving is 150mm; In step C, the design of pattern comprises the following steps:

(1)扫描:选择木材木纹,采用焦距为120mm的高清镜头、输入分辨率为2000dpi对木纹进行扫描,镜头与扫描平台的距离为45~55cm; (1) Scanning: Select the wood grain, use a high-definition lens with a focal length of 120mm, and an input resolution of 2000dpi to scan the wood grain, and the distance between the lens and the scanning platform is 45~55cm;

(2)处理:将扫描后的图像调整分辨率为1000dpi,对扫描后的图像进行分色、调色、修版处理;降低分辨率至304.8dpi,得到设计好的图案。 (2) Processing: Adjust the resolution of the scanned image to 1000dpi, and perform color separation, color correction, and version revision processing on the scanned image; reduce the resolution to 304.8dpi to obtain the designed pattern.

所述步骤C中,激光雕刻的参数为:电机功率为50W,辊体1转速为900r/min,雕刻时间为3h,焦距为24 mm; In the step C, the parameters of the laser engraving are: the motor power is 50W, the rotation speed of the roller body 1 is 900r/min, the engraving time is 3h, and the focal length is 24mm;

所述步骤C中,第一次激光雕刻的雕刻网线数为60线、雕刻网角为37°,第二次激光雕刻的雕刻网线数为86线、雕刻网角为40°; In the step C, the engraving line number of the first laser engraving is 60 lines, the engraving screen angle is 37 °, the engraving line number of the second laser engraving is 86 lines, and the engraving screen angle is 40 °;

所述步骤C中,激光雕刻后形成的网穴的横截面呈“凵”字型; In the step C, the cross section of the cell formed after laser engraving is in the shape of "凵";

D、腐蚀:将雕刻后的辊体1放入喷淋式滚筒腐蚀机内,对辊体1上的可见铜层进行腐蚀,腐蚀液为波美度在38的三氯化铁溶液,腐蚀温度为40℃,腐蚀时间为20s; D. Corrosion: put the engraved roller body 1 into a spray drum corrosion machine, and corrode the visible copper layer on the roller body 1. The corrosion solution is a ferric chloride solution with a Baume degree of 38, and the corrosion temperature is 40℃, corrosion time is 20s;

E、脱胶:利用工业酒精对腐蚀后的辊体1进行脱胶处理; E, degumming: use industrial alcohol to degumming the corroded roller body 1;

F、镀铬6:将脱胶后的辊体1放入装有镀铬6液的电镀槽中进行电镀,电流密度为32ASF,电镀温度为60℃,电镀时间为30min,维氏硬度为900,镀得铜铬层的厚度为14um。所述步骤F中,镀铬6液包括以下重量份的原料:铬酸酐180份、氟化钠5份、溴酸钾6份、硫酸2.2份和CF-202 5份;铬酸酐与硫酸的重量比为100:1.2;镀铬6液的pH值为2;电镀的阳极材料为锡含量在50%、银含量在1.5%的铅锡银合金。 F, chrome plating 6: put the degummed roller body 1 into the electroplating tank equipped with chrome plating solution 6 for electroplating, the current density is 32ASF, the electroplating temperature is 60°C, the electroplating time is 30min, and the Vickers hardness is 900. The thickness of the copper chrome layer is 14um. In described step F, 6 parts of chrome-plating liquids comprise the raw material of following weight portion: chromic anhydride 180 parts, sodium fluoride 5 parts, potassium bromate 6 parts, sulfuric acid 2.2 parts and CF-202 5 parts; The weight ratio of chromic anhydride and sulfuric acid is 100 : 1.2; the pH value of the chrome-plating solution 6 is 2; the anode material of the electroplating is a lead-tin-silver alloy with a tin content of 50% and a silver content of 1.5%.

一种用于镭射纸张印刷的版辊,包括辊体1,辊体1表面设置有非印刷区域32和印刷区域3,非印刷区域32表面固定连接有镀铜层4,印刷区域3表面开设有激光雕刻层5,镀铜层4和激光雕刻层5表面均固定连接有镀铬6层,激光雕刻层5包括第一雕刻层51和第二雕刻层52,第一雕刻层51的雕刻网线数、雕刻网角和第二雕刻层52的雕刻网线数、雕刻网角均不相同。所述镀铜层4、激光雕刻层5和镀铬6层的厚度依次为14um、150um和6um。 A version roller for laser paper printing, comprising a roller body 1, the surface of the roller body 1 is provided with a non-printing area 32 and a printing area 3, the surface of the non-printing area 32 is fixedly connected with a copper-plated layer 4, and the surface of the printing area 3 is provided with Laser engraving layer 5, copper plating layer 4 and laser engraving layer 5 surfaces are all fixedly connected with 6 layers of chrome plating, laser engraving layer 5 comprises first engraving layer 51 and second engraving layer 52, the engraving line number of first engraving layer 51, The engraved mesh angle is different from the engraved mesh line number and the engraved mesh angle of the second engraved layer 52 . The thicknesses of the copper plating layer 4, the laser engraving layer 5 and the chrome plating layer 6 are 14um, 150um and 6um in sequence.

上述实施例为本发明较佳的实现方案,除此之外,本发明还可以其它方式实现,在不脱离本发明构思的前提下任何显而易见的替换均在本发明的保护范围之内。 The above-mentioned embodiments are preferred implementation solutions of the present invention. In addition, the present invention can also be realized in other ways, and any obvious replacements are within the protection scope of the present invention without departing from the concept of the present invention.

Claims (6)

1.一种用于镭射纸张印刷的版辊的制作工艺,其特征在于:包括如下步骤: 1. A manufacturing process for a plate roller for laser paper printing, characterized in that: comprising the steps: A、镀铜:将辊体放入装有镀铜液的电镀槽中进行电镀,电流密度为16~18ASF,电镀温度为30~50℃,电镀时间为30~60min,维氏硬度为180~210,镀得铜层的厚度为10~14um; A. Copper plating: Put the roller body into the electroplating tank with copper plating solution for electroplating, the current density is 16~18ASF, the electroplating temperature is 30~50℃, the electroplating time is 30~60min, and the Vickers hardness is 180~ 210, the thickness of the plated copper layer is 10~14um; 所述步骤A中,镀铜液由以下原料组成:硫酸铜5~20g/L、乙二胺四乙酸二钠10~30g /L、酒石酸钾钠5~20g/L、甲醛2~5g/L、氢氧化钠10~15g/L、甲醇0.001~0.1g/L和硅酸钠0.1~2g/L;镀铜液的pH 值为12~13;电镀的阳极材料为磷含量在2‰~5‰的铜板; In the step A, the copper plating solution is composed of the following raw materials: copper sulfate 5-20g/L, disodium edetate 10-30g/L, potassium sodium tartrate 5-20g/L, formaldehyde 2-5g/L , sodium hydroxide 10~15g/L, methanol 0.001~0.1g/L and sodium silicate 0.1~2g/L; the pH value of the copper plating solution is 12~13; the anode material for electroplating has a phosphorus content of 2‰~5 ‰ copper plate; B、包胶:将镀铜后的辊体挂起,在辊体外侧均匀地涂覆一层0.05~0.25mm的胶液,涂覆完成后自然晾干30~40min; B. Gluing: hang the copper-plated roller body, and evenly coat a layer of 0.05~0.25mm glue solution on the outside of the roller body, and let it dry naturally for 30~40min after coating; C、激光雕刻:将包胶晾干后的辊体放入激光雕刻机内,设定雕刻网线数和雕刻网角,按设计好的图案进行激光雕刻,激光雕刻的深度为60~150mm;激光雕刻包括第一次激光雕刻和第二次激光雕刻,第一雕刻的雕刻网线数、雕刻网角和第二雕刻的雕刻网线数、雕刻网角均不相同; C. Laser engraving: Put the rubber-coated and dried roller body into the laser engraving machine, set the number of engraving mesh lines and engraving mesh angle, and carry out laser engraving according to the designed pattern. The depth of laser engraving is 60~150mm; Engraving includes the first laser engraving and the second laser engraving. The number of engraving screen lines and engraving screen angles of the first engraving are different from those of the second engraving; 所述步骤C中,第一次激光雕刻的雕刻网线数为60~80,雕刻网角为40°,第二次激光雕刻的雕刻网线数为85~105,雕刻网角为37°; In the step C, the engraving line number of the first laser engraving is 60-80, the engraving screen angle is 40°, the engraving line number of the second laser engraving is 85-105, and the engraving screen angle is 37 °; 所述步骤C中,激光雕刻后形成的网穴的横截面呈倒“凸”字型; In the step C, the cross-section of the cells formed after laser engraving is in an inverted "convex" shape; D、腐蚀:将雕刻后的辊体放入喷淋式滚筒腐蚀机内,对辊体上的可见铜层进行腐蚀,腐蚀液为波美度在34~36的三氯化铁溶液,腐蚀温度为20~40℃,腐蚀时间为5~20s; D. Corrosion: Put the engraved roller body into a spray drum corrosion machine to corrode the visible copper layer on the roller body. The corrosion solution is a ferric chloride solution with a Baume degree of 34~36, and the corrosion temperature The temperature is 20~40℃, and the corrosion time is 5~20s; E、脱胶:利用工业酒精对腐蚀后的辊体进行脱胶处理; E. Degumming: Use industrial alcohol to degumming the corroded roller body; F、镀铬:将脱胶后的辊体放入装有镀铬液的电镀槽中进行电镀,电流密度为28~32ASF,电镀温度为50~55℃,电镀时间为5~15min,维氏硬度为800~900,镀得铬层的厚度为4~6um; F. Chromium plating: Put the degummed roller body into an electroplating tank filled with chrome plating solution for electroplating. The current density is 28~32ASF, the electroplating temperature is 50~55°C, the electroplating time is 5~15min, and the Vickers hardness is 800. ~900, the thickness of the chromium layer is 4~6um; 所述步骤F中,镀铬液包括以下重量份的原料:铬酸酐180~220份、氟化钠1~5份、溴酸钾2~6份、硫酸1.8~2.2份和CF-202 2~5份;铬酸酐与硫酸的重量比为100:1~1.3;镀铬液的pH值为1~2;电镀的阳极材料为锡含量在20%~50%、银含量在0.5%~1.5%的铅锡银合金。 In the step F, the chromium plating solution includes the following raw materials in parts by weight: 180 to 220 parts of chromic anhydride, 1 to 5 parts of sodium fluoride, 2 to 6 parts of potassium bromate, 1.8 to 2.2 parts of sulfuric acid and 2 to 5 parts of CF-202; The weight ratio of chromic anhydride to sulfuric acid is 100:1~1.3; the pH value of the chromium plating solution is 1~2; the anode material for electroplating is lead-tin-silver with a tin content of 20%~50% and a silver content of 0.5%~1.5%. alloy. 2.根据权利要求1所述的一种用于镭射纸张印刷的版辊的制作工艺,其特征在于:所述步骤B具体为:将镀铜后的辊体挂起,在辊体外侧套置一个圆形胶片,圆形胶片连接有装有胶液的盒体,在电机10~20Hz功率带动下,圆形胶片沿辊体竖直向下匀速运动,在辊体外侧均匀地涂覆一层0.05~0.25mm的胶液,涂覆完成后自然晾干30~40min。 2. The manufacturing process of a forme roller for laser paper printing according to claim 1, characterized in that: the step B specifically includes: hanging the copper-plated roller body and nesting it on the outside of the roller body A circular film, the circular film is connected with a box filled with glue, driven by the power of the motor at 10~20Hz, the circular film moves vertically downward along the roller body at a constant speed, and evenly coats a layer on the outside of the roller body 0.05~0.25mm glue, dry naturally for 30~40min after coating. 3.根据权利要求1所述的一种用于镭射纸张印刷的版辊的制作工艺,其特征在于:所述步骤C中,图案的设计包括如下步骤: 3. A manufacturing process for a plate roller for laser paper printing according to claim 1, characterized in that: in the step C, the design of the pattern comprises the following steps: (1)扫描:选择木材木纹,采用焦距为120mm的高清镜头、输入分辨率为1800~2000dpi对木纹进行扫描,镜头与扫描平台的距离为45~55cm; (1) Scanning: Select the wood grain, use a high-definition lens with a focal length of 120mm, and an input resolution of 1800~2000dpi to scan the wood grain, and the distance between the lens and the scanning platform is 45~55cm; (2)处理:将扫描后的图像调整分辨率为800~1000dpi,对扫描后的图像进行分色、调色、修版处理;降低分辨率至304.8dpi,得到设计好的图案。 (2) Processing: adjust the scanned image to a resolution of 800~1000dpi, and perform color separation, color correction, and version revision processing on the scanned image; reduce the resolution to 304.8dpi to obtain a designed pattern. 4.根据权利要求1所述的一种用于镭射纸张印刷的版辊的制作工艺,其特征在于:所述步骤C中,激光雕刻的参数为:电机功率为30~50W,辊体转速为700~900r/min,雕刻时间为1~3h,焦距为20~24mm。 4. The manufacturing process of a forme roller for laser paper printing according to claim 1, characterized in that: in the step C, the parameters of the laser engraving are: the motor power is 30~50W, and the rotation speed of the roller body is 700~900r/min, engraving time is 1~3h, focal length is 20~24mm. 5.如权利要求1~4任一项所述的一种用于镭射纸张印刷的版辊的制作工艺制得的版辊,包括辊体,其特征在于:辊体外表面设置有非印刷区域和印刷区域,非印刷区域表面固定连接有镀铜层,印刷区域表面开设有激光雕刻层,镀铜层和激光雕刻层表面均固定连接有镀铬层,激光雕刻层包括第一雕刻层和第二雕刻层,第一雕刻层的雕刻网线数、雕刻网角和第二雕刻层的雕刻网线数、雕刻网角均不相同。 5. A kind of forme roller that is used for the manufacturing process of the forme roller of laser paper printing according to any one of claims 1 to 4, comprising a roller body, is characterized in that: the outer surface of the roller body is provided with a non-printing area and In the printing area, the surface of the non-printing area is fixedly connected with a copper plating layer, and the surface of the printing area is provided with a laser engraving layer. Both the surface of the copper plating layer and the laser engraving layer are fixedly connected with a chrome plating layer. The number of engraving screen lines and engraving screen angles of the first engraving layer are different from those of the second engraving layer. 6.根据权利要求5所述的一种用于镭射纸张印刷的版辊,其特征在于:所述镀铜层、激光雕刻层和镀铬层的厚度依次为10~14um、100~150um和4~6um。 6. A plate roller for laser paper printing according to claim 5, characterized in that: the thicknesses of the copper plating layer, the laser engraving layer and the chrome plating layer are 10~14um, 100~150um and 4~ 6um.
CN201310447725.0A 2013-09-27 2013-09-27 Printing roller for laser paper printing and manufacturing process thereof Expired - Fee Related CN103481638B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310447725.0A CN103481638B (en) 2013-09-27 2013-09-27 Printing roller for laser paper printing and manufacturing process thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310447725.0A CN103481638B (en) 2013-09-27 2013-09-27 Printing roller for laser paper printing and manufacturing process thereof

Publications (2)

Publication Number Publication Date
CN103481638A CN103481638A (en) 2014-01-01
CN103481638B true CN103481638B (en) 2015-05-13

Family

ID=49822388

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310447725.0A Expired - Fee Related CN103481638B (en) 2013-09-27 2013-09-27 Printing roller for laser paper printing and manufacturing process thereof

Country Status (1)

Country Link
CN (1) CN103481638B (en)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103818098B (en) * 2014-01-28 2015-09-23 太仓丽盛制版有限公司 The evaluation method of technique roller technological parameter
CN104442181B (en) * 2014-10-30 2017-06-13 杭州天元诚达装饰材料有限公司 A kind of artificial wood grain paper high
CN104476939B (en) * 2014-12-25 2017-07-14 东莞运城制版有限公司 The chrome-plating method and keeping method of a kind of roller
CN104476938A (en) * 2014-12-25 2015-04-01 东莞运城制版有限公司 A manufacturing process of plate rollers with patterns of different shades
CN104726910B (en) * 2015-02-03 2017-04-12 龙游运城压纹制版有限公司 Electroplating process for protection of embossing roller chromium layer
CN104626786B (en) * 2015-02-11 2017-10-17 上海运安制版有限公司 A kind of homogeneous corrosion method of laser version roller
CN107206825B (en) * 2015-04-14 2019-06-28 株式会社新克 The manufacturing method of gravure cylinder and its manufacturing method and printed article
CN105397426B (en) * 2015-12-16 2018-07-03 东莞运城制版有限公司 A kind of roller and its manufacture craft for the shallow embossing of internal lining paper
CN105862442A (en) * 2016-04-06 2016-08-17 龙游运申制版有限公司 Moisture curing device and solution thereof
CN106364247A (en) * 2016-08-31 2017-02-01 上海众邦制版科技有限公司 Manufacturing method of non-woven foaming imitation PVC deep embossing hand carving
CN107031170B (en) * 2017-03-30 2019-06-04 绍兴青运激光制版有限公司 A kind of production method of high light film version
CN107020793B (en) * 2017-03-30 2019-03-22 绍兴青运激光制版有限公司 A kind of printing preparation process of roller
CN107287628B (en) * 2017-05-10 2019-04-12 南通天鸿镭射科技有限公司 A kind of manufacture craft with surface optical diffusion microstructural mold roller
CN107175890A (en) * 2017-05-10 2017-09-19 上海运城制版有限公司 A kind of laser aufhellung roller and its manufacture method
CN107351518A (en) * 2017-06-16 2017-11-17 江苏欧钛克复合材料技术有限公司 A kind of high-strength light gravure printing roller and its processing method
CN107443875A (en) * 2017-07-18 2017-12-08 龙游运城压纹制版有限公司 A kind of preparation technology of gravure printing roller
CN107696678A (en) * 2017-10-30 2018-02-16 桐城运城制版有限公司 A kind of preparation technology of gravure printing roller
CN107878003A (en) * 2017-12-20 2018-04-06 武汉红金龙印务股份有限公司 A kind of durable quantitative water supply roller
CN109109457B (en) * 2018-08-03 2022-05-24 常州龙润激光科技有限公司 Anilox roll and manufacturing method thereof
CN109402690A (en) * 2018-12-12 2019-03-01 东莞市同欣表面处理科技有限公司 A kind of layers of copper activator and the preparation method and application thereof method
CN111347758B (en) * 2020-04-28 2022-03-08 景德镇陶瓷大学 Gravure printing process and equipment for paper packaging box
CN113664461A (en) * 2020-05-13 2021-11-19 光群雷射科技股份有限公司 Manufacturing method of baking resistant roller
CN111730953B (en) * 2020-06-02 2022-05-06 泉州运城制版有限公司 Laser etching gravure plate making process
JP7296348B2 (en) * 2020-09-18 2023-06-22 日立グローバルライフソリューションズ株式会社 washing machine
CN112647100B (en) * 2020-11-27 2022-03-22 江阴市羽项汽车饰件有限公司 Ultra-environment-friendly interior graphic display process
CN112874127B (en) * 2021-01-08 2021-10-01 黄山精工凹印制版有限公司 Process method for preparing seamless laser mould pressing roller
CN112848642A (en) * 2021-01-08 2021-05-28 黄山精工凹印制版有限公司 Manufacturing method of high-precision gravure printing roller
CN112873920B (en) * 2021-01-08 2021-10-22 黄山精工凹印制版有限公司 Processing technology for preparing seamless laser packaging film
CN115874260B (en) * 2021-09-28 2024-11-01 宝钢金属有限公司 Preparation method of magnesium alloy etching plate and magnesium alloy etching liquid
CN114618740A (en) * 2022-03-07 2022-06-14 山东膜丽东方新材料科技有限公司 A coating roller and its processing method
CN115635763A (en) * 2022-05-16 2023-01-24 东莞运城制版有限公司 Plate making process of gravure plate roller
CN116653057B (en) * 2023-05-26 2025-05-16 广东耀东华集团有限公司 Production process of facing artificial board with accurate alignment patterns

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6158340A (en) * 1996-03-14 2000-12-12 Rotoincisa S.R.L. Process for preparing removable metal sleeves for gravure printing machines
CN101402275A (en) * 2008-10-16 2009-04-08 泉州运城制版有限公司 Method for manufacturing gravure printing roller with electronic carving method
CN102015190A (en) * 2008-05-16 2011-04-13 卡巴-乔利有限公司 Method and system for manufacturing intaglio printing plates for the production of security papers
CN102152600A (en) * 2010-12-09 2011-08-17 黄山精工凹印制版有限公司 Method for producing high-definition laser gravure plate roller
CN102229279A (en) * 2011-04-15 2011-11-02 北京罗赛尔科技有限公司 Method for implementing multilevel high-accuracy sleeve-carving platemaking of special roller
CN102935755A (en) * 2012-11-22 2013-02-20 武汉东运制版有限公司 Method for engraving gravure grinding roller by laser

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002166519A (en) * 2000-11-29 2002-06-11 Fuji Electric Co Ltd Screen printing plate manufacturing method and manufacturing apparatus

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6158340A (en) * 1996-03-14 2000-12-12 Rotoincisa S.R.L. Process for preparing removable metal sleeves for gravure printing machines
CN102015190A (en) * 2008-05-16 2011-04-13 卡巴-乔利有限公司 Method and system for manufacturing intaglio printing plates for the production of security papers
CN101402275A (en) * 2008-10-16 2009-04-08 泉州运城制版有限公司 Method for manufacturing gravure printing roller with electronic carving method
CN102152600A (en) * 2010-12-09 2011-08-17 黄山精工凹印制版有限公司 Method for producing high-definition laser gravure plate roller
CN102229279A (en) * 2011-04-15 2011-11-02 北京罗赛尔科技有限公司 Method for implementing multilevel high-accuracy sleeve-carving platemaking of special roller
CN102935755A (en) * 2012-11-22 2013-02-20 武汉东运制版有限公司 Method for engraving gravure grinding roller by laser

Also Published As

Publication number Publication date
CN103481638A (en) 2014-01-01

Similar Documents

Publication Publication Date Title
CN103481638B (en) Printing roller for laser paper printing and manufacturing process thereof
CN201901705U (en) Aluminum alloy surface pretreatment system capable of combining four working tanks into one, totally recycling medicament and realizing zero discharge of waste water
CN102978022A (en) Phosphorus-free foam-free low-temperature steel plate surface cleaning agent and preparation method thereof
CN112111761A (en) A kind of electrolyte of high elongation electrolytic copper foil and its application
CN114346600A (en) Production process of lead frame copper strip for high-end manufacturing industry
WO2022061948A1 (en) Insoluble anode methyl sulfonic acid coating low-lead content tin plate production method and device
CN201793745U (en) Etching waste liquid regeneration and copper recovery processing system
CN109023488B (en) A kind of micro-crack hard chromium composite coating and preparation method thereof
CN201737744U (en) Processing device realizing reduction of electroplating rinse-wastewater and double-membrane multipoint separate recycling
CN207918989U (en) Zinc-plated automatic barrel plating production line
CN107620078A (en) Environment-friendly metal processes aqueous cleaning agent
CN113522968A (en) Method for improving surface cleanliness of steel for automobile panel
CN116732458A (en) Preparation method of tinned steel plate
CN113445039B (en) Zinc surface chromium-free passivation solution and passivation method
CN105063706A (en) Pretreatment method for chemical nickel-plated diamond micro-powder
CN201737779U (en) Electroplating cleaning wastewater emission reduction and porous sub-quality recycling treatment device
CN107604413B (en) A kind of sealing agent for CTP plate material sealing and using method thereof
CN208733228U (en) A kind of oxidation unit of printing PS editions
CN108705887B (en) Manufacturing method of gravure roller containing zinc coating
CN207916255U (en) A kind of roller of additional cooling cleaning function
CN202090074U (en) Water-receiving device of foil producing machine
CN202151606U (en) Anti-splash coating roller for color coating unit
CN204608186U (en) A kind of raw paper tinsel water container
CN103726062A (en) Pickling process of high-strength steel plate
CN103602975B (en) Metallic high temperature turns blue (blackout) process for cleanly preparing

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150513

Termination date: 20170927