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CN103481596B - Temperable blue low radiation energy-saving glass - Google Patents

Temperable blue low radiation energy-saving glass Download PDF

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Publication number
CN103481596B
CN103481596B CN201310463806.XA CN201310463806A CN103481596B CN 103481596 B CN103481596 B CN 103481596B CN 201310463806 A CN201310463806 A CN 201310463806A CN 103481596 B CN103481596 B CN 103481596B
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China
Prior art keywords
layer
glass
low radiation
thickness
silicon nitride
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CN201310463806.XA
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CN103481596A (en
Inventor
李建根
徐伯永
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Chengdu CSG Glass Co Ltd
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Chengdu CSG Glass Co Ltd
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Priority to CN201310463806.XA priority Critical patent/CN103481596B/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3644Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3626Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3657Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
    • C03C17/366Low-emissivity or solar control coatings

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

The invention discloses a temperable blue low radiation energy-saving glass, the glass film structure of which comprises, in order: a glass substrate, a first layer of priming silicon nitride, a second layer of nickel-cadmium, a third layer of functional silver, a fourth layer of protective nickel-cadmium, a fifth layer of medium aluminum zinc oxide, a sixth layer of antireflection titanium oxide, and a seventh layer of silicon nitride. The low radiation glass prepared by the invention has a beautiful appearance of blue glass, suitable natural light transmittance and reflectivity. Most importantly, the low radiation glass prepared by the invention has the potential of remote processing, can undergo film coating first and then undergo cutting and tempering processing, thus greatly improving the production efficiency.

Description

One can the blue Low emissivity energy-saving glass of tempering
Technical field
The present invention relates to a kind of low emissivity glass, particularly a kind of blueness can tempered and low-radiation energy-saving glass.
Background technology
Low emissivity energy-saving glass (LOW-E glass), its production technology is on high-quality float glass process substrate, be coated with the assembly of thin films that multilayer is functional layer with silver (Ag).At present, off-line Low emissivity energy-saving glass processing mode is divided into two kinds: one is first by former for float glass process cutting, edging, and then tempering plated film, makes double glazing.One is direct plated film in former of float glass process, then adopts the mode such as cutting, edging tempering to process as required.
Existing technology production outward appearance blue tinted glass is add appropriate metallic cobalt (Co) ion by float glass to obtain mostly, and this float glass advantage is can strange land processing, and shortcoming is that energy saving is not so good as low emissivity glass.And the glass of outward appearance blueness is reached by plated film adjustable colors, its advantage is that energy-efficient performance is good, can obtain the better glass appearance of texture, and shortcoming to realize strange land processing, and production efficiency is relatively low.Further, blue float glass is by absorbing other visible ray, can only present blueness, so more blue through color ratio through blue light.
Summary of the invention
The object of the invention is to overcome blue cobalt glass in prior art and not there is Low emissivity energy-saving effect, and the low emissivity glass of existing imitative black appearance is difficult to the defect of strange land processing, provides a kind of blue low emissivity glass.The invention provides a kind of blueness can tempered and low-radiation energy-saving glass, and it can carry out the processing such as edging, tempering in strange land.
In order to realize foregoing invention object, the invention provides following technical scheme:
A kind of low radiation coated glass; it is characterized in that, this glass film layers structure is followed successively by: glass substrate, ground floor prime coat silicon nitride layer, second layer nicr layer, third layer functional layer silver layer, the 4th layer of protective layer nicr layer, layer 5 dielectric layer zinc aluminium oxide layer, layer 6 antireflection layer titanium oxide layer, layer 7 silicon nitride layer.
Described low radiation coated glass adopts off-line magnetron sputtering plating to make.
Described ground floor prime coat silicon nitride (SiNx) thickness between 10nm to 50nm,
The thickness of described second layer nickel chromium triangle (NiCr) between 2nm to 8nm,
The thickness of described third layer functional layer (Ag) layer between 4nm to 9nm,
The thickness range of described 4th layer of protective layer nickel chromium triangle (NiCr) between 2nm to 7nm,
The thickness range of described layer 5 dielectric layer zinc oxide aluminum (AZO) between 0nm to 15nm,
Described layer 6 antireflection layer titanium oxide (TiOx) thickness between 5nm to 25nm,
The thickness range of described layer 7 silicon nitride (SiNx) is between 15nm to 45nm.
Ground floor bottoming dielectric layer improves the adhesive force of rete effects on surface; Second layer nickel chromium triangle NiCr, promotes the adhesive force of Ag layer in rete, improves the oxidation resistance of Ag layer; Third layer functional layer, Ag layer can reflect away the heat radiation in most of solar energy, plays Low emissivity energy-saving effect; 4th layer of protective layer, nickel chromium triangle NiCr or chromium Cr layer can defencive function layer Ag layer not by follow-up coating process and process thereafter be oxidized, lose effect; Layer 5 dielectric layer zinc oxide aluminum, can starvation and other materials, protect inner rete from erosion, improve the performance of the resistance to chemical attack of film system and mechanical friction, can play the effect of adjustable colors simultaneously.The major function of layer 6 antireflection layer titanium oxide is protective film.Layer 7 silicon nitride have very strong anticorrosive, resistance to mechanical scratches, the performance of high temperature resistance can protect inner layer film system.
Adopt the low emissivity glass that said sequence rete is coated with, regulate thicknesses of layers, can change between rete the transmission of visible ray, absorption and reflect ratio.When the known different thin-film material of optical principle combines, visible ray can be made by after rete, and reverberation interferes phenomenon.Inventor finds to select above-mentioned film material inadvertently, carry out plated film in a certain order, within the scope of above-mentioned thicknesses of layers, regulate the thickness of film, the reflection that the natural daylight of each wavelength period can be made to obtain being suitable for, transmittance, glass shows the outward appearance of the blueness of fashion.
Further, within the scope of this, regulate each layer thickness of film system, can also further strengthen blue light wave reflection ratio, reduce the reflection of other band of light, thus present the blueness of fashion beauty more, possess and to add the similar appearance colour of blue glass that cobalt ions obtains with float glass process in former, the manufacture for commercial blue low emissivity glass provides another kind of solution.The glass that the present invention prepares also has good low radiance, and the outstanding infrared reflection shown as in sunshine strengthens, and natural daylight visible light part is good through ratio, has more excellent energy-saving effect compared with general low emissivity glass.The more important thing is that low emissivity glass prepared by the present invention possesses the potentiality of strange land processing simultaneously, can first plated film, rear cutting, tempering processing.Solve the strange land processing problems of blue coated low-emissivity glass, greatly improve the production efficiency of blue low emissivity glass.
Regulate outward appearance to reflect by the present invention and present blueness, it is more neutral through color ratio, more meets the requirement of building Visual Aesthetics.So this invention can realize the black appearance with better texture, greatly enhance productivity simultaneously, meet different customer demand.
Compared with prior art, beneficial effect of the present invention: the reflectivity R of the low emissivity glass that this invention manufactures is from 8% to 30%, b* scope from-11 to-20, and transmitance is from 40% to 65%.Note: b* (champac degree, the more negative color of its value is more blue)
Accompanying drawing illustrates:
Fig. 1 is the structural representation of coated low-emissivity glass
Mark in figure: 1-glass substrate, 2-ground floor prime coat silicon nitride layer, 3-second layer nicr layer; 4-third layer functional layer silver layer, 5-the 4th layer of protective layer nicr layer, 6-layer 5 dielectric layer zinc aluminium oxide layer; 7-layer 6 antireflection layer titanium oxide layer, 8-layer 7 silicon nitride layer.
Detailed description of the invention
In the present invention, a*, b* are psychometric chroma, + a* represents red, and-a* represents green, and+b* represents yellow,-b* represents blue, T%: percent transmission, a*t: the red green degree of transmitted light, b*t: through pure champac degree, R% represents light reflection percentage, a*g: the red green degree of reflection ray, b*g: the champac degree of reflection ray, U factor represents heat transfer coefficient, and Sc represents shading coefficient.
Below in conjunction with test example and detailed description of the invention, the present invention is described in further detail.But this should be interpreted as that the scope of the above-mentioned theme of the present invention is only limitted to following embodiment, all technology realized based on content of the present invention all belong to scope of the present invention.
Embodiment 1
Utilize vacuum off-line magnetic-controlled sputtering coating equipment; on 6mm high-quality float-glass substrate; plated film successively from inside to outside: ground floor prime coat silicon nitride 16nm; the thickness of second layer nickel chromium triangle NiCr is at 7.3nm; the thickness of third layer functional layer Ag layer is at 7.6nm; the thickness range of the 4th layer of protective layer nickel chromium triangle NiCr is at 4.7nm; layer 5 subtracts the thickness range of dielectric layer zinc oxide aluminum AZO at 3.3nm; layer 6 antireflection layer titanium oxide TiOx thickness is between 18nm, and the thickness range of layer 7 silicon nitride SiNx is at 21nm.
Embodiment 2-3
Embodiment 2-3 implementation process is with embodiment 1, and plated film series of strata thickness sees the following form, and Biao Zhongge layer thickness unit is nanometer.
The each layer thickness of the blue low emissivity glass of table 1Low-E
Performance test
Measure above-described embodiment according to GB/T 18915.1-2002 and obtain the optical parametric after Low emissivity blue tinted glass tempering, contrast commercially available 6mm blue tinted glass product, the results are shown in Table 2.
With float glass process blue optical parameter comparison after table 2LOW-E blue tinted glass steel
In table 2 data, a* represents red green degree, and the more negative color of its value is greener; B* represents champac degree, and the more negative color of its value is more blue.In table, data show, visible light transmissivity and the blue float glass of the low emissivity glass of embodiment 1 preparation are close, and outdoor sightingpiston color is beautiful blueness, through look close to neutral, compared with plating low-radiation film with the blue cobalt glass of commercially available 6mm, visible light transmissivity is close, and energy-efficient performance is better.Be simultaneously that neutrality meets Visual Aesthetics demand through look.The effect of blue cobalt glass plating low-radiation film copied by simple glass, significantly reduces the production cost of low emissivity glass, remains again the fashion appeal of coloured glass plating low-radiation film simultaneously, reaches re-set target of the present invention.
The blue low emissivity glass of the preparation of Example 1, cuts, and tempering processing.What the present invention was coated with low-emission coatedly shows good stability, completes tempering processing smoothly.And obtain the tempered and low-radiation glass of stable performance.

Claims (4)

1. a low radiation coated glass, is characterized in that, this glass film layers structure is followed successively by:
Glass substrate, ground floor prime coat silicon nitride layer, second layer nicr layer, third layer functional layer silver layer, the 4th layer of protective layer nicr layer, layer 5 dielectric layer zinc aluminium oxide layer, layer 6 antireflection layer titanium oxide layer, layer 7 silicon nitride layer;
The thickness of described second layer nicr layer is 2-8nm;
The thickness of described third layer functional layer silver layer is 4-9nm;
The thickness of described 4th layer of protective layer nicr layer is 2-7nm;
The thickness of described layer 5 dielectric layer zinc aluminium oxide layer is 0-15nm;
Described layer 6 antireflection layer titanium oxide layer thickness is 5-25nm.
2. low radiation coated glass according to claim 1, is characterized in that, described low radiation coated glass adopts off-line magnetron sputtering plating to make.
3. low radiation coated glass according to claim 1, it is characterized in that, described ground floor prime coat silicon nitride layer thickness is between 10nm to 50nm.
4. low radiation coated glass according to claim 1, it is characterized in that, the thickness range of described layer 7 silicon nitride layer is between 15nm to 45nm.
CN201310463806.XA 2013-10-08 2013-10-08 Temperable blue low radiation energy-saving glass Active CN103481596B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107471785A (en) * 2016-06-08 2017-12-15 四川南玻节能玻璃有限公司 A kind of double silver low radiation energy-saving glass of high-performance

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108101383B (en) * 2018-02-27 2024-02-13 四川南玻节能玻璃有限公司 Temperable Low-E energy-saving glass

Family Cites Families (7)

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Publication number Priority date Publication date Assignee Title
US7597962B2 (en) * 2005-06-07 2009-10-06 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Coated article with IR reflecting layer and method of making same
CN100595172C (en) * 2006-10-19 2010-03-24 林嘉宏 Low radiation coated glass capable of being toughened and its production process
US8734920B2 (en) * 2009-04-29 2014-05-27 Guardian Industries Corp. Coated article with low-E coating having titanium oxide layer and/or NiCr based layer(s) to improve color values and/or transmission, and method of making same
CN202242180U (en) * 2011-09-02 2012-05-30 北京物华天宝镀膜科技有限公司 Off-line temperable high-transmittance clean color low-radiation coated glass
CN102848653B (en) * 2012-08-31 2015-04-08 东莞南玻工程玻璃有限公司 Temperable glassware plated with low-radiation coating film
CN103144381B (en) * 2013-04-10 2015-09-02 四川南玻节能玻璃有限公司 A kind of green low radiation energy-saving glass
CN203600723U (en) * 2013-10-08 2014-05-21 四川南玻节能玻璃有限公司 Blue toughened low-radiation and energy-saving glass

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107471785A (en) * 2016-06-08 2017-12-15 四川南玻节能玻璃有限公司 A kind of double silver low radiation energy-saving glass of high-performance

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Inventor after: Li Jiangen

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