CN103451647A - Preparation method for centrifugal self-propagating ceramic/alloy double-compound wear-resistant tube - Google Patents
Preparation method for centrifugal self-propagating ceramic/alloy double-compound wear-resistant tube Download PDFInfo
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- CN103451647A CN103451647A CN2013103064693A CN201310306469A CN103451647A CN 103451647 A CN103451647 A CN 103451647A CN 2013103064693 A CN2013103064693 A CN 2013103064693A CN 201310306469 A CN201310306469 A CN 201310306469A CN 103451647 A CN103451647 A CN 103451647A
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- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 38
- 239000000956 alloy Substances 0.000 title claims abstract description 38
- 239000000919 ceramic Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 23
- 239000010959 steel Substances 0.000 claims abstract description 23
- 239000002131 composite material Substances 0.000 claims abstract description 22
- 238000005524 ceramic coating Methods 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 4
- 238000007788 roughening Methods 0.000 claims abstract description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims abstract 5
- 238000005488 sandblasting Methods 0.000 claims abstract 2
- 238000002844 melting Methods 0.000 claims description 11
- 230000008018 melting Effects 0.000 claims description 11
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 6
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 description 9
- 238000003892 spreading Methods 0.000 description 8
- 238000003466 welding Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000703 high-speed centrifugation Methods 0.000 description 1
- 239000011158 industrial composite Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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- Rigid Pipes And Flexible Pipes (AREA)
- Laminated Bodies (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
本发明公开了一种离心自蔓延陶瓷/合金双复合耐磨管的制备方法，对钢管内表面进行喷砂除锈、粗化处理；将Al+Fe2O3体系的自蔓延粉料放入钢管中；将钢管置于离心机上，开动离心机，待转速稳定后，点火引发自蔓延反应；待钢管内部的Al2O3陶瓷内衬层半凝固状态时，将熔融的耐磨合金浇注入Al2O3陶瓷内衬复合钢管内，使熔融的耐磨合金在离心力的作用下，涂覆于Al2O3陶瓷涂层上形成耐磨合金层，形成陶瓷/合金双复合耐磨管。本发明工艺简单，制造的产品耐磨、耐蚀性强。
The invention discloses a preparation method of a centrifugal self-propagating ceramic/alloy double composite wear-resistant pipe. The inner surface of the steel pipe is subjected to sandblasting, derusting and roughening treatment; the self-propagating powder of the Al+Fe 2 O 3 system is put into In the steel pipe; put the steel pipe on the centrifuge, start the centrifuge, and after the speed is stable, ignite to trigger the self-propagating reaction; when the Al 2 O 3 ceramic lining layer inside the steel pipe is semi-solidified, pour the molten wear-resistant alloy into the In the Al 2 O 3 ceramic-lined composite steel pipe, the molten wear-resistant alloy is coated on the Al 2 O 3 ceramic coating under the action of centrifugal force to form a wear-resistant alloy layer, forming a ceramic/alloy double composite wear-resistant pipe. The process of the invention is simple, and the manufactured product has strong wear resistance and corrosion resistance.
Description
Technical field
The present invention relates to a kind of centrifugal preparation method from spreading pottery/alloy double composite wear-resistant tube.
Background technology
In industrialization of the country construction process, need a large amount of abrasion-proof pipes to be used for transporting the resources such as ore, oil.Because stupalith has the characteristics such as wear resistant corrosion resistant is high temperature resistant, the lining coating of Chang Zuowei stainless steel tube, form ceramic-lined composite steel tube.
Industrial composite pipe with ceramic lining commonly used has several as follows at present: paster wear-resistant pipe, spot welding assembling caliper type wear-resistant pipe, centrifugal from spreading composite pipe with ceramic lining.The alumina ceramic plate that the paster wear-resistant pipe adopts viscose glue will have radian sticks on inner-walls of duct, forms the pipeline wearing layer.This kind of abrasion-proof pipe manufacture craft is simple, and wear resisting property is better, but alumina ceramic plate relies on viscose glue to be connected with the pipeline matrix, and bonding strength is not high, and environment for use is no more than 150 ℃ usually, and fabrication cycle is long, and these have all limited the application of paster wear-resistant pipe.Spot welding assembling caliper type wear-resistant pipe is to utilize high temperature resistant powerful viscose glue that the alumina ceramic plate of middle with hole is sticked on to inner-walls of duct, and the points of engagement Welding sees through aperture pottery is welded on to steel pipe inner wall securely simultaneously.For the protection solder joint, the above screws on the pottery block again.This kind of production technique has increased the bonding strength of pottery with the pipeline matrix, but the technique relative complex, fabrication cycle is longer, and cost is higher.All relate to artificial subsides porcelain in the manufacturing processed of paster wear-resistant pipe and spot welding assembling caliper type wear-resistant pipe, so the diameter of the abrasion-proof pipe of made is usually larger, the production of small-bore abrasion-proof pipe in being not suitable for.Centrifugal is the composite pipe that adopts " synthesize-high-speed centrifugation technology of self propagating high temperature " to manufacture from spreading composite pipe with ceramic lining, form ceramic layer and the transition layer of even thickness under high temperature and high speed, the manufacture of small-bore wear-resistant pipe in being applicable to, and, under the working temperature of 850-900 ℃, pottery still can not drop.In the serious wear industries such as straight tube, elbow, bend pipe, threeway, result of use is very good.But, because self-propagating reaction usually completed and reacts comparatively violent in several seconds, the gas in ceramic droplet is difficult to get rid of, and causes the ceramic coating surface pore more, the wear-resisting and erosion resistance of wear-resistant pipe is had to certain influence.
Summary of the invention
The object of the present invention is to provide a kind of technique simple, the centrifugal preparation method from spreading pottery/alloy double composite wear-resistant tube that the product of manufacture is wear-resisting, solidity to corrosion is strong.
Technical solution of the present invention is:
A kind of centrifugal preparation method from spreading pottery/alloy double composite wear-resistant tube, is characterized in that: comprise the following steps: steel pipe internal-surface is carried out to derusting by sandblast, roughening treatment; By Al+Fe
2o
3certainly the powder that spreads of system is put into steel pipe; Steel pipe is placed on whizzer, starts whizzer, after stabilization of speed, igniting causes self-propagating reaction; Treat the Al of steel duct
2o
3during ceramic lining half curdled appearance, the wear resistant alloy of melting is poured into to Al
2o
3in ceramic-lined composite steel tube, make the wear resistant alloy of melting under the effect of centrifugal force, be coated on Al
2o
3form wear-resistant alloy layer on ceramic coating, form pottery/alloy double composite wear-resistant tube.
Described wear resistant alloy is low melting point wear resistant alloy Fe50 or TN-62.
The present invention adopts and to carry out the coating of low melting point wear resistant alloy at ceramic lining under the state in partly solidifying, and prevents the ceramic layer cracking that is heated; At ceramic lining surface-coated low melting point wear-resistant alloy layer, can make hole and the crackle on the alloy fill ceramic coating surface of melting on the one hand, improve the erosion resistance of multiple-unit tube, on the other hand, can greatly improve the centrifugal wear resisting property from spreading composite pipe with ceramic lining of tradition, extend the work-ing life of multiple-unit tube.Present method is simply effective, workable, prepared in small-bore pottery/alloy double composite wear-resistant tube can be applicable to the fields such as electric power, mine, chemical industry.
The accompanying drawing explanation
Below in conjunction with drawings and Examples, the invention will be further described.
Fig. 1 is the centrifugal schematic diagram from spreading the standby ceramic lining of legal system in the present invention.
Fig. 2 is the schematic diagram that in the present invention, centrifuging prepares wear-resistant alloy layer.
Fig. 3 is the prepared pottery of the present invention/alloy double composite wear-resistant tube schematic diagram.
Reference numeral in figure
Whizzer 1, clamping device 2, steel pipe 3, steady rest 4, ceramic lining 5, protection end cap 6, spread portfire 7, refractory materials 8, cast gate 9, wear resistant alloy 10, steel pipe matrix 11, transition layer 12, ceramic layer 13, low melting point wear-resistant alloy layer 14 certainly.
Embodiment
Steel pipe 3 internal surfaces are carried out to derusting by sandblast, roughening treatment.By Al+Fe
2o
3certainly the powder that spreads of system is put into steel pipe.Steel pipe is placed on whizzer, starts whizzer, after stabilization of speed, igniting causes self-propagating reaction.Treat the Al of steel duct
2o
3during ceramic lining half curdled appearance, the wear resistant alloy of melting is poured into to Al
2o
3in ceramic-lined composite steel tube, make the wear resistant alloy of melting under the effect of centrifugal force, evenly be coated on Al
2o
3form the thick wear-resistant alloy layer of 1-2mm on ceramic coating, form pottery/alloy double composite wear-resistant tube.
Wear resistant alloy is the low melting point wear resistant alloys such as Fe50, TN-62.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310306469.3A CN103451647B (en) | 2013-07-22 | 2013-07-22 | Preparation method for centrifugal self-propagating ceramic/alloy double-compound wear-resistant tube |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310306469.3A CN103451647B (en) | 2013-07-22 | 2013-07-22 | Preparation method for centrifugal self-propagating ceramic/alloy double-compound wear-resistant tube |
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| Publication Number | Publication Date |
|---|---|
| CN103451647A true CN103451647A (en) | 2013-12-18 |
| CN103451647B CN103451647B (en) | 2015-04-15 |
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|---|---|---|---|
| CN201310306469.3A Active CN103451647B (en) | 2013-07-22 | 2013-07-22 | Preparation method for centrifugal self-propagating ceramic/alloy double-compound wear-resistant tube |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105002494A (en) * | 2015-06-29 | 2015-10-28 | 常州江南冶金科技有限公司 | Silicon-aluminum alloy composite pipeline |
| CN105333238A (en) * | 2015-08-26 | 2016-02-17 | 杨永利 | Metal ceramic composite oil tube formed by remanufacturing waste oil tube and waste oil tube remanufacturing technology |
| CN105478786A (en) * | 2015-11-26 | 2016-04-13 | 中国石油天然气股份有限公司 | Is suitable for CO2Processing technology of driven ceramic coating air-proof oil well pump cylinder |
| CN106869813A (en) * | 2017-01-20 | 2017-06-20 | 杨永利 | A kind of anti-sulphur oil pipe overall structure of glazing cermet and its processing method |
| CN107584091A (en) * | 2017-09-27 | 2018-01-16 | 安徽工程大学 | A kind of centrifugal casting pipe mould restorative procedure of near-net-shape |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107930230A (en) * | 2017-12-02 | 2018-04-20 | 大禹节水（天津）有限公司 | A kind of wear-resisting sandstone centrifugal filter and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5983753A (en) * | 1982-11-01 | 1984-05-15 | Hitachi Metals Ltd | Manufacturing method of composite cylinder for plastic molding |
| US4510988A (en) * | 1981-08-21 | 1985-04-16 | Kubota Ltd. | Tube for thermal cracking or reforming hydrocarbon and manufacturing method thereof |
| JPH0925582A (en) * | 1996-08-05 | 1997-01-28 | Dai Ichi High Frequency Co Ltd | Production of pipe lined with metal on inside surface |
| CN1624311A (en) * | 2004-12-11 | 2005-06-08 | 董宽志 | Manufacturing method of laminated gradient composite ceramic cylinder jacket |
| CN101774801A (en) * | 2010-02-04 | 2010-07-14 | 南通大学 | Reactive material for preparing ceramic composite steel pipe by adopting self-propagating high-temperature synthesis |
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2013
- 2013-07-22 CN CN201310306469.3A patent/CN103451647B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4510988A (en) * | 1981-08-21 | 1985-04-16 | Kubota Ltd. | Tube for thermal cracking or reforming hydrocarbon and manufacturing method thereof |
| JPS5983753A (en) * | 1982-11-01 | 1984-05-15 | Hitachi Metals Ltd | Manufacturing method of composite cylinder for plastic molding |
| JPH0925582A (en) * | 1996-08-05 | 1997-01-28 | Dai Ichi High Frequency Co Ltd | Production of pipe lined with metal on inside surface |
| CN1624311A (en) * | 2004-12-11 | 2005-06-08 | 董宽志 | Manufacturing method of laminated gradient composite ceramic cylinder jacket |
| CN101774801A (en) * | 2010-02-04 | 2010-07-14 | 南通大学 | Reactive material for preparing ceramic composite steel pipe by adopting self-propagating high-temperature synthesis |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105002494A (en) * | 2015-06-29 | 2015-10-28 | 常州江南冶金科技有限公司 | Silicon-aluminum alloy composite pipeline |
| CN105002494B (en) * | 2015-06-29 | 2017-11-24 | 常州江南冶金科技有限公司 | Silico-aluminum composite material conduit |
| CN105333238A (en) * | 2015-08-26 | 2016-02-17 | 杨永利 | Metal ceramic composite oil tube formed by remanufacturing waste oil tube and waste oil tube remanufacturing technology |
| CN105333238B (en) * | 2015-08-26 | 2024-06-04 | 杨永利 | Metal-ceramic composite oil pipe remanufactured from waste oil pipe and its remanufacturing process |
| CN105478786A (en) * | 2015-11-26 | 2016-04-13 | 中国石油天然气股份有限公司 | Is suitable for CO2Processing technology of driven ceramic coating air-proof oil well pump cylinder |
| CN106869813A (en) * | 2017-01-20 | 2017-06-20 | 杨永利 | A kind of anti-sulphur oil pipe overall structure of glazing cermet and its processing method |
| CN107584091A (en) * | 2017-09-27 | 2018-01-16 | 安徽工程大学 | A kind of centrifugal casting pipe mould restorative procedure of near-net-shape |
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| Publication number | Publication date |
|---|---|
| CN103451647B (en) | 2015-04-15 |
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Effective date of registration: 20200110 Address after: No.759, Yongda Road, Gangzha District, Nantong City, Jiangsu Province Patentee after: NANTONG GAOXIN WEARABLE TECHNOLOGY Co.,Ltd. Address before: 226019 Jiangsu city of Nantong province sik Road No. 9 Patentee before: Nantong University |
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Denomination of invention: Preparation method of centrifugal self propagating ceramic / alloy double composite wear-resistant pipe Effective date of registration: 20211117 Granted publication date: 20150415 Pledgee: Nantong Jiangsu rural commercial bank Limited by Share Ltd. Pledgor: NANTONG GAOXIN WEARABLE TECHNOLOGY Co.,Ltd. Registration number: Y2021980012668 |
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Date of cancellation: 20221027 Granted publication date: 20150415 Pledgee: Nantong Jiangsu rural commercial bank Limited by Share Ltd. Pledgor: NANTONG GAOXIN WEARABLE TECHNOLOGY Co.,Ltd. Registration number: Y2021980012668 |
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