CN103435195B - A kind of processing method containing acid salt-containing organic wastewater - Google Patents
A kind of processing method containing acid salt-containing organic wastewater Download PDFInfo
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- CN103435195B CN103435195B CN201310366984.0A CN201310366984A CN103435195B CN 103435195 B CN103435195 B CN 103435195B CN 201310366984 A CN201310366984 A CN 201310366984A CN 103435195 B CN103435195 B CN 103435195B
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- waste water
- water
- gained
- containing organic
- desalination
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- 239000002351 wastewater Substances 0.000 title claims abstract description 51
- 150000003839 salts Chemical class 0.000 title claims abstract description 14
- 239000002253 acid Substances 0.000 title claims abstract description 12
- 238000003672 processing method Methods 0.000 title claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- 238000000034 method Methods 0.000 claims abstract description 26
- 230000008569 process Effects 0.000 claims abstract description 21
- 238000010612 desalination reaction Methods 0.000 claims abstract description 14
- 238000000909 electrodialysis Methods 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 8
- 239000010865 sewage Substances 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 4
- 239000007787 solid Substances 0.000 claims abstract description 4
- 238000000151 deposition Methods 0.000 claims abstract description 3
- 238000007599 discharging Methods 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000012528 membrane Substances 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 5
- 239000013505 freshwater Substances 0.000 claims description 4
- 238000004064 recycling Methods 0.000 abstract description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 9
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 8
- 238000004065 wastewater treatment Methods 0.000 description 7
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 150000003505 terpenes Chemical class 0.000 description 5
- 235000007586 terpenes Nutrition 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000010842 industrial wastewater Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003933 environmental pollution control Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000001577 simple distillation Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Landscapes
- Water Treatment By Electricity Or Magnetism (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The invention discloses a kind of processing method containing acid salt-containing organic wastewater, comprise the following steps: the pH value of (a) regulation waste water is to 89；B step (a) is processed the oil proceeded in oil interceptor removal waste water after gained waste water enters depositing reservoir process and divides by ()；C the waste water of gained after step (b) process is processed through pressure filter and is separated by the solid particle in waste water by ()；D step (c) gained waste water is passed through electrodialysis plant by (), obtain the condensed water containing organic desalination water and saliferous；E (), is carried out discharging containing Organic substance desalination water and the situation of saliferous condensed water according to step (d) gained, Treated sewage reusing or after-treatment.The method technological process that the present invention processes waste water is simple, and treatment effeciency is high, and input cost is low, energy-saving and emission-reduction, it is achieved that recycling of waste water.
Description
Technical field
The invention belongs to field of industrial waste water treatment, be specifically related to a kind of processing method containing acid salt-containing organic wastewater.
Background technology
In the industry, the method processing general employing biochemical treatment containing acid salt-containing organic wastewater, the salt of industrial wastewater is dense
Degree height can affect the effect of biochemical treatment, prior art literature: " Techniques and Equipment for Environmental Pollution Control " periodical in 2005, one
The literature research of entitled " high salt concentration influence research to biochemical treatment of industrial wastewater " high salt concentration industrial wastewater is to life
The impact that change processes, when salinity height, sludge activity is suppressed, and COD clearance declines, and reduces the treatment effeciency of waste water.And
And the equipment investment of biochemical treatment is big, the treatment cost of waste water is high.
Summary of the invention
Goal of the invention: the invention aims to solve above-mentioned technical problem, it is provided that a kind of low cost, easy containing acid
The processing method of salt-containing organic wastewater.
Technical scheme: a kind of processing method containing acid salt-containing organic wastewater of the present invention, comprises the following steps:
A the pH value of () regulation waste water is to 8-9；
B step (a) is processed the oil proceeded in oil interceptor removal waste water after gained waste water enters depositing reservoir process and divides by ()；
C the waste water of gained after step (b) process is processed through pressure filter and is separated by the solid particle in waste water by ()；
D step (c) gained waste water is passed through electrodialysis plant by (), obtain the concentration containing organic desalination water and saliferous
Water；
E (), is carried out discharging containing Organic substance desalination water and the situation of saliferous condensed water according to step (d) gained, middle water
Reuse or after-treatment.
Preferably, in described step (a), the pH value sodium hydroxide of waste water regulates.
Preferably, the described electrodialysis plant of described step (c) includes cavity block and the anode membrane of semi-transparent performance, described cavity block and institute
Stating anode membrane alternately to install, under electric field action, cation is become with the anion binding oozed in adjacent anode membrane by cavity block
Salt, and part water discharges (title condensed water) from concentrated phase room, and other composition non-ionic is worn between film along with major part water
Thoroughly discharge (title desalination water), thus by complicated component containing Organic substance, the water of inorganic matter, be separated into main band organic light
Change water and the condensed water of main band inorganic matter.
After electrodialysis process waste water, the disposition about desalination water and condensed water is divided into following several, as shown in the table.
(, with 10 tons as boundary, electrolyte concentration is with 1g/L as boundary, and organic concentration is with 0.3g/L as boundary for wastewater treatment capacity
Limit, more than boundary value, is designated as " greatly ", less than boundary value, is designated as " little " in form in form.)
When wastewater treatment capacity is bigger, during organic concentration height, after electrodialysis process, containing in Organic substance desalination water owing to having
Machine thing content is high, and desalination water, through simple distillation or azeotropic distillation, reclaims Organic substance, and the water steamed is as Treated sewage reusing.
When wastewater treatment capacity is less, during organic concentration height, after electrodialysis process, the desalination water containing Organic substance is due to water
Measuring less, content of organics is high, uses the method for burning disposal to process.
Described Treated sewage reusing refers to that the waste water after processing uses as fresh water (FW), continues to put into identical course of reaction
In, then produce containing acid salt-containing organic wastewater, so, it is achieved that recycling of waste water.
Beneficial effect: a kind of processing method containing acid salt-containing organic wastewater of the present invention, utilizes electrolyte, non-electrolytic
Matter difference electrical property, uses electrodialysis plant, is separated with electrolyte by Organic substance, then carry out subsequent treatment.With prior art
Comparing, the method technological process that the present invention processes waste water is simple, and treatment effeciency is high, and input cost is low, as built a set of biochemical treatment
Device, invests about 1,200,000 yuan, cost for wastewater treatment per ton 80 yuan, and uses the processing method of the present invention, and built processing means is thrown
Provide 200,000 yuan, cost for wastewater treatment per ton 30 yuan.The present invention adequately achieves recycling of waste water, energy-saving and emission-reduction, is conducive to
Enterprise realizes sustainable development.
Accompanying drawing explanation
Fig. 1 is the process chart of the present invention.
Detailed description of the invention
In order to deepen the understanding of the present invention, below in conjunction with embodiment and accompanying drawing, the invention will be further described, should
Embodiment is only used for explaining the present invention, is not intended that limiting the scope of the present invention.
See Fig. 1
Embodiment 1
With Oleum Terebinthinae as raw material, aluminum chloride as catalyst, toluene make the reaction of polymerization terpene resin of solvent, instead
After should terminating, can produce containing toluene, hydrochloric acid, aluminium hydroxide highly acid with water decomposition aluminum chloride and after terpene resin is cleaned multiple times
Waste water, be that the most pending waste water of the sector processes a difficult problem.
Utilize the waste water treatment process of the present invention, in waste water, first add sodium hydroxide, pH is adjusted to 8-9, clarified pond
Enter oil interceptor after process, isolate the toluene of about 95%, then waste water is processed through pressure filter, separate consolidating in waste water
Body granule obtains limpid waste water about 50 tons, containing NaCl1.4g/L, containing toluene 0.086g/L, is passed into an effective filtering surface
Amass as 20m2Electrodialyzer, obtain obtaining condensed water 20 tons after process in enriched chamber, containing NaCl3.3g/L, containing toluene 0.009g/
L, obtains desalination water 30 tons at diluting compartment, containing NaCl0.13g/L, containing toluene 0.137g/L.
Condensed water containing NaCl is after Fruit shell filtering device adsorbs, and the content of toluene can be less than 0.0005g/L, and now COD is
100, reach discharge standard, discharge it into industrial park sewage disposal system (garden drainage requirement COD is less than 200), and desalinate
Water is made washings washing terpene resin back into water wash system and is used.
Embodiment 2
With Oleum Terebinthinae as raw material, aluminum chloride is catalyst, and hexamethylene is solvent, the reaction of polymerization terpene resin,
After reaction terminates, with water decomposition aluminum chloride and can produce after terpene resin is cleaned multiple times containing hexamethylene, hydrochloric acid, aluminium hydroxide strong
Acid waste water, first adds sodium hydroxide in waste water, pH is adjusted to 8-9, and clarified pond enters oil interceptor after processing, and isolates
The hexamethylene of about 95%, then processes waste water through pressure filter, separates the solid particle in waste water and obtain limpid waste water about
1 ton, containing NaCl1.1g/L, containing hexamethylene 0.12g/L, being passed into an effective filtration area is 20m2Electrodialyzer, place
Obtain condensed water 0.5 ton after reason in enriched chamber, containing NaCl2g/L, be difficult to pole in the electric field because of cyclohexane containing hexamethylene 0.001g/L(
Change so concentration is the lowest), obtain desalination water 0.5 ton at diluting compartment, containing NaCl0.2g/L, containing hexamethylene 0.239g/L, because of hexamethylene
Discharge standard is 0.005g/L, and (containing hexamethylene 0.001g/L) containing NaCl condensed water can be directly discharged into garden sewage network, and contains
Hexamethylene desalination water can be injected directly in enterprise has industrial furnace by oneself and burn.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (1)
1. the processing method containing acid salt-containing organic wastewater, it is characterised in that comprise the following steps:
A the pH value of () regulation waste water is to 8-9；
B step (a) is processed the oil proceeded in oil interceptor removal waste water after gained waste water enters depositing reservoir process and divides by ()；
C the waste water of gained after step (b) process is processed through pressure filter and is separated by the solid particle in waste water by ()；
D step (c) gained waste water is passed through electrodialysis plant by (), obtain the condensed water containing organic desalination water and saliferous；
E (), is carried out discharging containing Organic substance desalination water and the situation of saliferous condensed water according to step (d) gained, Treated sewage reusing
Or after-treatment；
In step (a), the pH value sodium hydroxide of waste water regulates；
The described electrodialysis plant of step (c) includes that cavity block and the anode membrane of semi-transparent performance, described cavity block and described anode membrane are alternately installed；
Described Treated sewage reusing refers to that the waste water after processing uses as fresh water (FW).
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310366984.0A CN103435195B (en) | 2013-08-21 | 2013-08-21 | A kind of processing method containing acid salt-containing organic wastewater |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310366984.0A CN103435195B (en) | 2013-08-21 | 2013-08-21 | A kind of processing method containing acid salt-containing organic wastewater |
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| Publication Number | Publication Date |
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| CN103435195A CN103435195A (en) | 2013-12-11 |
| CN103435195B true CN103435195B (en) | 2016-12-28 |
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104151467A (en) * | 2014-08-21 | 2014-11-19 | 梧州市嘉盈树胶有限公司 | Preparation method of terpene resin |
| CN104891722B (en) * | 2015-06-19 | 2016-11-30 | 四川师范大学 | A kind of remove the method for nitrate nitrogen in waste water |
| CN105000727A (en) * | 2015-09-02 | 2015-10-28 | 波鹰(厦门)科技有限公司 | Oil-field wastewater treating and recycling device |
| CN105130069A (en) * | 2015-09-02 | 2015-12-09 | 波鹰(厦门)科技有限公司 | High-salt oil producing waste water treatment and recycling device |
| CN105668936A (en) * | 2016-03-22 | 2016-06-15 | 唐山金利海生物柴油股份有限公司 | Method for treating biodiesel acid water |
| CN107224999B (en) * | 2017-07-14 | 2019-03-01 | 南京大学盐城环保技术与工程研究院 | A kind of resin desorption liquid method of disposal based on electrodialytic technique |
| CN111995191A (en) * | 2020-08-28 | 2020-11-27 | 韶关林和林产科技有限公司 | Terpene resin washing water treatment system and method |
| CN115246692B (en) * | 2021-04-25 | 2023-08-08 | 中国石油化工股份有限公司 | Treatment method of adipic acid production process wastewater |
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| US6346197B1 (en) * | 2000-01-28 | 2002-02-12 | Mckay Creek Technologies Ltd. | Water and wastewater treatment system and process for contaminant removal |
| CN100515957C (en) * | 2005-10-12 | 2009-07-22 | 王凌云 | Waste liquid treatment method and system |
| CN101735181A (en) * | 2008-11-18 | 2010-06-16 | 刘绍凯 | Pollution-free energy-saving new process for producing furfural, acetic acid and active carbon |
| CN102476877B (en) * | 2010-11-29 | 2014-04-09 | 中国科学院大连化学物理研究所 | Silicon-removing and oil-removing composite method of oil-containing sewage for boiler reuse |
| CN103086551B (en) * | 2013-01-22 | 2014-05-21 | 杭州蓝然环境技术有限公司 | Method for preparing acid-base from rare-earth sodium saponification waste water |
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