CN103421557B - A kind of multifunctional fuel oil additive - Google Patents
A kind of multifunctional fuel oil additive Download PDFInfo
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- CN103421557B CN103421557B CN201310303126.1A CN201310303126A CN103421557B CN 103421557 B CN103421557 B CN 103421557B CN 201310303126 A CN201310303126 A CN 201310303126A CN 103421557 B CN103421557 B CN 103421557B
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- fuel oil
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- oil additive
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- 239000003747 fuel oil additive Substances 0.000 title claims abstract description 18
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 28
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 19
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 16
- 239000001488 sodium phosphate Substances 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 16
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000000654 additive Substances 0.000 abstract description 23
- 230000000996 additive effect Effects 0.000 abstract description 23
- 239000003112 inhibitor Substances 0.000 abstract description 19
- 230000003068 static effect Effects 0.000 abstract description 10
- 239000003517 fume Substances 0.000 abstract description 9
- 230000003647 oxidation Effects 0.000 abstract description 9
- 238000007254 oxidation reaction Methods 0.000 abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052799 carbon Inorganic materials 0.000 abstract description 8
- 239000003502 gasoline Substances 0.000 abstract description 8
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract description 8
- 239000002245 particle Substances 0.000 abstract description 8
- 239000000295 fuel oil Substances 0.000 abstract description 7
- 239000000779 smoke Substances 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 3
- 235000011008 sodium phosphates Nutrition 0.000 description 14
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 12
- 239000000446 fuel Substances 0.000 description 12
- 229910052748 manganese Inorganic materials 0.000 description 12
- 239000011572 manganese Substances 0.000 description 12
- 239000003921 oil Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 9
- PFNFFQXMRSDOHW-UHFFFAOYSA-N spermine Chemical compound NCCCNCCCCNCCCN PFNFFQXMRSDOHW-UHFFFAOYSA-N 0.000 description 8
- MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical compound CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 description 6
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 4
- 229910000397 disodium phosphate Inorganic materials 0.000 description 4
- 235000019800 disodium phosphate Nutrition 0.000 description 4
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 4
- 229940063675 spermine Drugs 0.000 description 4
- 239000013543 active substance Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 3
- 239000013585 weight reducing agent Substances 0.000 description 3
- 150000004805 acidic polysaccharides Chemical class 0.000 description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 102000039446 nucleic acids Human genes 0.000 description 2
- 108020004707 nucleic acids Proteins 0.000 description 2
- 150000007523 nucleic acids Chemical class 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 229920002683 Glycosaminoglycan Polymers 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920001284 acidic polysaccharide Polymers 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003444 phase transfer catalyst Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention belongs to additive technology field, particularly relate to a kind of multifunctional fuel oil additive, it is made up of following component by mass: octane promoter 10-15 part, oxidation inhibitor 5-10 part, static inhibitor 5-10 part, FLOW IMPROVERS 10-20 part, fuel oil additive prepared by the present invention is for different fuel oil, it is the highest can reduce smoke evacuation fume amount decrement 36.4%, reduces uncombined carbon particle weight 48.1%, reduces CO quantity discharged 47.7%, rate of economizing gasoline improves 40.0%.
Description
technical field:
The invention belongs to additive technology field, particularly relate to a kind of multifunctional fuel oil additive.
background technology:
In order to save energy, improve the combustion position of oil fuel, in oil fuel, often add additive to improve some some performance of oil fuel.Fuel dope and petroleum additive, be mainly used in gasoline, diesel oil, kerosene and oil fuel.By effect point, mainly contain octane promoter, oxidation inhibitor, metal passivator, static inhibitor, wear-resistant rust-preventive agent, FLOW IMPROVERS etc., phosphoric acid salt or phosphate derivative are the main components of fuel dope, both can play wear-resistant rust inhibition, can play again anti-oxidant, anti-aging effect.
In recent years, people do extensive work for the research of fuel oil additive.But most additive improves some character of oil fuel really to a certain extent, but their function singlenesses, and can only improve a certain performance of oil fuel, other performances for oil fuel do not improve.So development one has multi-functional composite additive and just seems particularly important.At present, research and develop a large amount of fuel oil additives, but, but report is rarely had for compound fuel oil additive.
Summary of the invention
The object of the invention is to solve the shortcoming first having fuel oil additive function singleness, and invention a kind of multifunction additive, this additive be by several organism and inorganics allotment synthesis there is multi-functional fuel oil additive.This additive can make the smoke evacuation flue dust of oil fuel significantly reduce, and uncombined carbon particle significantly reduces, and CO quantity discharged reduces, and this additive not only greatly can reduce environmental pollution, and can improve rate of economizing gasoline.
Technical scheme of the present invention: multifunctional type fuel oil additive of the present invention, is made up of following component by mass:
Octane promoter 10-15 part, oxidation inhibitor 5-10 part, static inhibitor 5-10 part, FLOW IMPROVERS 10-20 part.
Octane promoter: the rare manganese tricarbonyl of methyl ring penta 2, tetraethyllead, ferrocene, octane promoter used in the present invention be above-mentioned any one.
Oxidation inhibitor: dialkyl diphenylamine, tetraethylenepentamine, spermine, oxidation inhibitor used in the present invention be above-mentioned any one.
Static inhibitor: sodium phosphate, sodium hydrogen phosphate, static inhibitor used in the present invention be above-mentioned any one.
FLOW IMPROVERS: cetyl trimethylammonium bromide, benzene sulfonic acid sodium salt, FLOW IMPROVERS used in the present invention be above-mentioned any one.
Optimize, above-mentioned octane promoter is: the rare manganese tricarbonyl of methyl ring penta 2;
Oxidation inhibitor is: dialkyl diphenylamine;
Static inhibitor is: sodium phosphate;
FLOW IMPROVERS: cetyl trimethylammonium bromide.
More excellent: the rare manganese tricarbonyl of methyl ring penta 2 15 parts;
Dialkyl diphenylamine 10 parts;
Sodium phosphate 10 parts;
Cetyl trimethylammonium bromide 15 parts.
The preparation method of above-mentioned a kind of multifunctional fuel oil additive, it comprises the steps:
(1) in the reactor being full of nitrogen, octane promoter is added: 10-15 part and static inhibitor: 5-10 part stirred at ambient temperature 15 minutes;
(2) cool to 0-5 DEG C, add oxidation inhibitor while stirring: 5-10 part and FLOW IMPROVERS: 10-20 part stirs 5 minutes;
(3) be warmed up to room temperature, continue stirring 15 minutes.
Optimize, the preparation method of above-mentioned a kind of multifunctional fuel oil additive, it comprises the steps:
(1) in the reactor being full of nitrogen, add the rare manganese tricarbonyl of methyl ring penta 2 15 parts and sodium phosphate 10 parts of stirred at ambient temperature 15 minutes;
(2) cool to 0 DEG C, add dialkyl diphenylamine 10 parts while stirring and stir 5 minutes with cetyl trimethylammonium bromide 15 parts;
(3) be warmed up to room temperature, continue stirring 15 minutes.
Static inhibitor can reduce material or product surface resistance and volume resistance, and appropriateness improves electroconductibility in order to avoid electrostatic accumulation is caused danger; Oxidation inhibitor can prevent fuel oil viscosity from rising; Flow ability modifying agent of the present invention can improve the surfactivity of oil fuel, oil fuel is made to obtain composition dispersion, improve its efficiency of combustion, reduce CO quantity discharged, but and the flow ability modifying agent of not all or tensio-active agent, Sodium dodecylbenzene sulfonate etc. as conventional in petrochemical complex all cannot be applied in the present invention, and with the palmityl trimethyl ammonium chloride of cetyl trimethylammonium bromide structural similitude for time of the present invention, also without this effect.
Cetyl trimethylammonium bromide in white or Light yellow crystals body to Powdered, be soluble in Virahol, water soluble, during concussion, produce a large amount of foam, can have good coordinating with positively charged ion, nonionic, amphoterics.There is excellent infiltration, softening, emulsification, antistatic, the performance such as biological degradability and sterilization.This product chemical stability is good, heat-resisting, fast light, withstand voltage, strong alkali-acid resistance.Purposes this product is natural, synthetic rubber, silicone oil and asphalt emulsifier, the static inhibitor of synthon, natural fiber and glass fibre, softening agent, the amendment of hair conditioner, phase-transfer catalyst, emulsion pore forming material, tensio-active agent, analytical reagent, terylene real silk agent, leather fat, it is also for soldering flux, solder paster plays Action of Surfactant in producing, active strong, to bright spot, rosin joint, weldering electricity full (CTMAB), energy dissolved cell film, it is a kind of cationic detergent, there is the characteristic of precipitate nucleic acids and acidic polysaccharide from the solution of low ionic strength, under these conditions, protein and neutral saccharan are still stayed in solution, in the solution of high ionic strength, saccharan beyond CTMAB and protein and most of acidic polysaccharide forms mixture, just can not precipitate nucleic acids.Therefore, CTMAB may be used for from producing the organism of mucopolysaccharide in a large number as prepared purify DNA plant and some Gram-negative bacteria (comprising some strain of E.coli).
And in above-mentioned introduction, and no-trump cetyl trimethylammonium bromide is used for petrochemical industry, is not more applied in the tensio-active agent of chemical field.
The invention has the beneficial effects as follows: fuel oil additive prepared by the present invention is for different fuel oil, and it is the highest can reduce smoke evacuation fume amount decrement 36.4%, reduces uncombined carbon particle weight 48.1%, reduces CO quantity discharged 47.7%, rate of economizing gasoline improves 40.0%.
Embodiment
In order to understand technical scheme of the present invention better, be described in detail further below by way of specific embodiment.
A preparation method for multifunctional fuel oil additive, it comprises the steps:
(1) in the reactor being full of nitrogen, octane promoter is added: 10-15g and static inhibitor: 5-10g stirred at ambient temperature 15 minutes;
(2) cool to 0 DEG C, add oxidation inhibitor while stirring: 5-10g and FLOW IMPROVERS: 10-20g stirs 5 minutes;
(3) be warmed up to room temperature, continue stirring 15 minutes.
If following embodiment is without specified otherwise, all prepare by above-mentioned steps.
embodiment 1
Take methyl ring penta 2 rare manganese tricarbonyl 10g, dialkyl diphenylamine 5g, sodium phosphate 5g, cetyl trimethylammonium bromide 10g.Preparation additive A.
embodiment 2
Take methyl ring penta 2 rare manganese tricarbonyl 15g, dialkyl diphenylamine 10g, sodium phosphate 10g, cetyl trimethylammonium bromide 20g.Prepare additive B.
Embodiment 3
Take methyl ring penta 2 rare manganese tricarbonyl 15g, dialkyl diphenylamine 10g, sodium phosphate 10g, cetyl trimethylammonium bromide 15g.Preparation addition of C.
embodiment 4
Take tetraethyllead 10g, tetraethylenepentamine 5g, sodium phosphate 5g, benzene sulfonic acid sodium salt 10g.Prepare additive D.
embodiment 5
Take ferrocene 10g, spermine 5g, sodium hydrogen phosphate 5g, benzene sulfonic acid sodium salt 10g, prepare additive E.
embodiment 6
Take ferrocene 15g, spermine 10g, sodium hydrogen phosphate 10g, benzene sulfonic acid sodium salt 10g, prepare additive F.
embodiment 7
Take tetraethyllead 10g, tetraethylenepentamine 5g, sodium phosphate 5g, benzene sulfonic acid sodium salt 20g, prepare additive G.
Comparative example 1
Take methyl ring penta 2 rare manganese tricarbonyl 15g, dialkyl diphenylamine 10g, sodium phosphate 10g, palmityl trimethyl ammonium chloride 15g, prepare additive H.
Comparative example 2
Take ferrocene 15g, spermine 10g, sodium hydrogen phosphate 10g, Sodium dodecylbenzene sulfonate 10g, prepare additive I.
testing example 1
Take 1g additive A respectively, B, C, D, E, F, G, H add in the different fuel oil sample of 10kg, respectively with fume amount reduction of discharging fume, uncombined carbon particle weight reduction, CO quantity discharged reduction, rate of economizing gasoline increase rate test the effect (the results are shown in Table 1) of multifunction additive of the present invention as judgement criteria.
From upper table 1, be optimum proportioning described in embodiment 3, fuel oil additive prepared by the present invention is for different fuel oil, and it is the highest can reduce smoke evacuation fume amount decrement 36.4%, reduce uncombined carbon particle weight 48.1%, reduce CO quantity discharged 47.7%, rate of economizing gasoline improves 40.0%.
And for the proportioning described in embodiment 3, do the experiment of following preparation method.
Embodiment 8
To take methyl ring penta 2 rare manganese tricarbonyl 15g, dialkyl diphenylamine 10g, sodium phosphate 10g, cetyl trimethylammonium bromide 15g adds in reaction vessel, and stirring at room temperature mixes, preparation addition of C 1.
Embodiment 9
Add in the reactor being full of nitrogen, methyl ring penta 2 rare manganese tricarbonyl 15g, dialkyl diphenylamine 10g, sodium phosphate 10g, cetyl trimethylammonium bromide 15g adds in reaction vessel, and stirring at room temperature mixes, preparation addition of C 2.
Embodiment 10
Add in the reactor being full of nitrogen, dialkyl diphenylamine 10g and cetyl trimethylammonium bromide 15g stirs after 5 minutes and adds the rare manganese tricarbonyl 15g of methyl ring penta 2, sodium phosphate 10g at 0 DEG C, is warmed up to stirring at room temperature and within 30 minutes, adds preparation addition of C 3.
testing example 2
Take 1g addition of C 1 respectively, C2, C3 add in the different fuel oil sample of 10kg, respectively with fume amount reduction of discharging fume, uncombined carbon particle weight reduction, CO quantity discharged reduction, rate of economizing gasoline increase rate test the effect (the results are shown in Table 2) of multifunction additive of the present invention as judgement criteria.
From upper table 2, formula of the present invention only just can reach effect of the present invention under preparation method of the present invention, if cannot reach effect of the present invention not to the utmost after parameter such as change temperature and order etc., and effect is very poor.
Embodiment 11
Get separately that methyl ring penta 2 rare manganese tricarbonyl 1g(is designated as a), sodium phosphate 1g(is designated as b), dialkyl diphenylamine 1g(is designated as c) to be designated as with cetyl trimethylammonium bromide 1g(and d) adds in the different fuel oil sample of 10kg not to discharge fume fume amount reduction, uncombined carbon particle weight reduction, CO quantity discharged reduction, rate of economizing gasoline increase rate test the effect (the results are shown in Table 3) of multifunction additive of the present invention as judgement criteria.
As shown in Table 3, during a certain component of independent interpolation, all cannot reach the effect of above-mentioned additive, be not simply said components is summed up yet, the present invention is the synergy by above-mentioned 4 kinds of components, and collaborate reaches and reduces exhaust smoke level, uncombined carbon particle weight, CO quantity discharged and oil consumption.
Claims (2)
1. a multifunctional fuel oil additive, is made up of following component by weight:
Methyl cyclopentyl-dialkyl-tricarbon manganium 15 parts, dialkyl diphenylamine 10 parts, sodium phosphate 10 parts, cetyl trimethylammonium bromide 15 parts.
2. the preparation method of a kind of multifunctional fuel oil additive according to claim 1, it comprises the steps:
(1) in the reactor being full of nitrogen, add methyl cyclopentyl-dialkyl-tricarbon manganium 15 parts and sodium phosphate 10 parts of stirred at ambient temperature 15 minutes;
(2) cool to 0 DEG C, add dialkyl diphenylamine 10 parts while stirring and stir 5 minutes with cetyl trimethylammonium bromide 15 parts;
(3) be warmed up to room temperature, continue stirring 15 minutes.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310303126.1A CN103421557B (en) | 2013-07-18 | 2013-07-18 | A kind of multifunctional fuel oil additive |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310303126.1A CN103421557B (en) | 2013-07-18 | 2013-07-18 | A kind of multifunctional fuel oil additive |
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| Publication Number | Publication Date |
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| CN103421557A CN103421557A (en) | 2013-12-04 |
| CN103421557B true CN103421557B (en) | 2015-09-16 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108977238B (en) * | 2018-07-30 | 2021-01-19 | 天沐蓝(山东)能源有限公司 | Preparation method of fuel oil additive |
| CN108977240A (en) * | 2018-08-17 | 2018-12-11 | 杭州中齐新材料科技有限公司 | A kind of energy-saving environmental-protection petrol additive and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1227256A (en) * | 1998-02-25 | 1999-09-01 | 那学方 | Coal saving powder |
| CN101126038A (en) * | 2007-09-29 | 2008-02-20 | 山东大学 | Microemulsion Diesel Additive and Its Application |
| CN101343578A (en) * | 2007-07-10 | 2009-01-14 | 雅富顿公司 | Fuel composition comprising a nitrogen-containing compound |
-
2013
- 2013-07-18 CN CN201310303126.1A patent/CN103421557B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1227256A (en) * | 1998-02-25 | 1999-09-01 | 那学方 | Coal saving powder |
| CN101343578A (en) * | 2007-07-10 | 2009-01-14 | 雅富顿公司 | Fuel composition comprising a nitrogen-containing compound |
| CN101126038A (en) * | 2007-09-29 | 2008-02-20 | 山东大学 | Microemulsion Diesel Additive and Its Application |
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| CN103421557A (en) | 2013-12-04 |
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