CN103416432A - Weeding composition for controlling worst weed and preparation method thereof - Google Patents
Weeding composition for controlling worst weed and preparation method thereof Download PDFInfo
- Publication number
- CN103416432A CN103416432A CN2012101885499A CN201210188549A CN103416432A CN 103416432 A CN103416432 A CN 103416432A CN 2012101885499 A CN2012101885499 A CN 2012101885499A CN 201210188549 A CN201210188549 A CN 201210188549A CN 103416432 A CN103416432 A CN 103416432A
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- Prior art keywords
- glyphosate
- compounds
- chloroquine
- agent
- weed killer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000002360 preparation method Methods 0.000 title claims abstract description 26
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- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 235000008216 herbs Nutrition 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
- 235000008729 phenylalanine Nutrition 0.000 description 1
- 229960005190 phenylalanine Drugs 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
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- 230000000704 physical effect Effects 0.000 description 1
- 230000005080 plant death Effects 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
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- 239000003265 pulping liquor Substances 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- LOAUVZALPPNFOQ-UHFFFAOYSA-N quinaldic acid Chemical compound C1=CC=CC2=NC(C(=O)O)=CC=C21 LOAUVZALPPNFOQ-UHFFFAOYSA-N 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
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- 235000019355 sepiolite Nutrition 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 230000009261 transgenic effect Effects 0.000 description 1
- 229940117013 triethanolamine oleate Drugs 0.000 description 1
- 239000004549 water soluble granule Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a pesticide composition and especially relates to a weeding composition comprising a glyphosate weeding compound and a quinclorac salt and a preparation method thereof. The weeding composition effectively improves effects of preventing and removing worst weed.
Description
Denomination of invention
A kind of Herbicidal combinations and preparation method for controlling malignant weed
Technical field
The present invention relates to a kind of composition pesticide, specifically a kind of combination by glyphosate class herbicides compounds and dichloro quinolinic acid salt and preparation method thereof, said composition has effectively improved the preventive effect for malignant weed.
Technical background
Glyphosate (Glyphosate) belongs to organic phosphates, a kind of interior suction conduction, wide spectrum steriland herbicide, the main interior enol acetonyl shikimene phosphate synthase of plant corpus that suppresses, thereby suppress the conversion of shikimene to phenyl alanine, cruel propylhomoserin and tryptophan, the synthetic of protein is interfered, causes plant death.Glyphosate is to be transmitted to each position of plant after absorbing by cauline leaf, can prevent and kill off the plant of the sections more than 40 such as unifacial leaf and dicotyledonous, annual and perennial, herbs and shrubs.Be combined and lose activity with metal ions such as iron, aluminium very soon after glyphosate buries, seed hiding in soil and edaphon are had no adverse effects.Because glyphosate is combined and passivation with metal ions such as iron, aluminium very soon after the soil contact, lose activity, therefore, can only process as cauline leaf.
Dichloro quinolinic acid is hormone-type quinoline carboxylic acid weed killer herbicide, main by seed, root, stem and the absorption of leaf section of sprouting, and, rapidly to stem and top conductive, is the weeds death, similar to the effect symptom of auxin substance.The characteristics such as it is strong that dichloro quinolinic acid has selectivity, and the amplitude broad in dispenser period is rapid-action, and the residence time in soil is long.Barnyard grass is had to very high preventive effect, can also effectively prevent and kill off Monochoria vaginalis, Chinese celery etc.Can be for cauline leaf and soil treatment.
Because the former medicine of dichloro quinolinic acid is water insoluble, the kind of this weed killer herbicide all is prepared into wetting powder, water dispersible granules and suspending agent and applies on agricultural for a long time.Because the long-term part susceptible weeds of using has produced resistance to dichloro quinolinic acid, reduced preventive effect, therefore add that the solvability of dichloro quinolinic acid in water is low, in use inevitably can produce that dispenser is inhomogeneous, the absorption that is unfavorable for plant, take effect and wait slowly to obtain shortcoming.Along with the continuous progress of technology in recent years, developed gradually the salt series products of dichloro quinolinic acid, it has been prepared into soluble salt by insoluble dichloro quinolinic acid, thereby can be prepared into easily the novel forms such as water solube powder, water-soluble granule.The former medicine of water-soluble dichloro quinolinic acid is easier to be mixed with other weed killer herbicides, obtains larger herbicide spectrum, improves the Absorption of medicine on the weeds blade face, thereby significantly shortens responding time, improves the herbicidal effect of dichloroquinoline acid supplement.
As previously mentioned, due to the glyphosate broad weed-killing spectrum, can effectively kill most weeds, deeply be subject to liking of users, glyphosate has become one of weed killer herbicide of global consumption maximum, also just because of this, and along with the extensive use of glyphosate, add that peasant's dispenser is unreasonable, accelerated the generation of resistance glyphosate weeds.The weeds that develop immunity to drugs to glyphosate in the whole world at present have long awns amaranth, tool knurl amaranth, junglerice, Paspalum conjugatum, eleusine indica, Horseweed Herb, wild pool wormwood artemisia, artemisiifolia, three row artemisiifolias, wimmera ryegrass, Annual Ryegrass, rib grass, painted euphorbia, false Chinese sorghum, class broomcorn millet tail bran grass etc.Except resistant weed, also have the more difficult weeds of preventing and kill off of some glyphosates, as perennial weeds such as meadow pine, corn sow thistle, field thistle, Ji, welted thistle.
Chinese patent application 99809621.0 discloses the Herbicidal combinations for tolerance or resistant rice crops, be mainly used in the noxious plant of controlling in the tolerant rice crop, although disclose the combination of glyphosate (salt) and two chloroquine phosphoric acid in this patent, but the embodiment that does not provide both to combine and definite drug effect data, and it is mainly used for killing the conventional weeds of transgenic rice paddy Crop Species.
Summary of the invention
The invention provides a kind of Herbicidal combinations and preparation method for preventing and treating malignant weed.This Herbicidal combinations is comprised of glyphosate compounds and dichloroquinoline acid compounds; Described glyphosate compounds is glyphosate and/or glyphosate salt compounds.Herbicidal combinations provided by the invention and weed killer herbicide, can effectively prevent and kill off glyphosate is produced to the weeds of resistance and the weeds that glyphosate is difficult to prevent and kill off.
In order to realize the foregoing invention purpose, the invention provides following technical scheme:
The invention provides a kind of Herbicidal combinations, it is comprised of glyphosate compounds and dichloroquinoline acid compounds;
Described glyphosate compounds is glyphosate and/or glyphosate salt compounds.Include but not limited to one or more in glyphosate, sodium glyphosate, glyphosate potassium, ammonium glyphosate, glyphosate isopropyl amine salt, glyphosate dimethylamine salt, glyphosate monomethyl amine salt, glyphosate ethanolamine salt and careless sulphur phosphorus (glyphosate trimethyl mercapto salt).
Described dichloroquinoline acid compounds is two chloroquine phosphoric acid and/or two chloroquine phosphoric acid salt compounds, and wherein two chloroquine phosphoric acid salt compounds include but not limited to one or more in dichloroquinoline acid sodium-salt, quinclorac ammonium salts, dichloroquinoline acid potassium salt etc.
In Herbicidal combinations of the present invention, preferred two chloroquine phosphoric acid salt compounds.
In embodiment more provided by the invention, in Herbicidal combinations provided by the invention, the mass ratio of described glyphosate compounds and described dichloroquinoline acid compounds is 10～95: 1～89.
As preferably, in Herbicidal combinations provided by the invention, the mass ratio of described glyphosate compounds and described dichloroquinoline acid compounds is 20～70: 4～89.
The present invention also provides a kind of weed killer herbicide, and its acceptable auxiliary material in above-mentioned Herbicidal combinations and pesticidal preparations forms, and the mass percent that described Herbicidal combinations accounts for described weed killer herbicide is 10～99%.
As preferably, the mass percent that described Herbicidal combinations accounts for described weed killer herbicide is 18～80%.
Weed killer herbicide of the present invention, wherein in pesticidal preparations, acceptable auxiliary material includes but not limited to one or more the mixture in wetting agent, dispersant, disintegrant, emulsifier, binding agent, stabilizing agent, defoamer, antifreezing agent, preservative, solvent, filler.
Weed killer herbicide of the present invention, include but not limited to soluble powder or granula, aqua, aqueous emulsion, water dispersion granule, tablet, suspending agent, wetting powder etc.
Technical scheme of the present invention realizes with following proposal:
A kind of two chloroquine phosphoric acid classes and glyphosate compounds herbicidal composition soluble powder form and comprise: (% by percentage to the quality)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Wetting agent: 0.1%-10%
Dispersant agent: 0.1%-10%
Surplus supplies 100% with filler
Preparation method: by carrying out mechanical crushing after the above-mentioned raw materials premixed, can obtain soluble powder.
A kind of two chloroquine phosphoric acid classes and glyphosate compounds herbicidal composition soluble granula form and comprise: (% by percentage to the quality)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 0.1-99%
Wetting agent: 0.1-10%
Dispersant: 0.1%-10%
Disintegrant: 0.1%-10%
Surplus supplies 100% with filler
Preparation method: will carry out mechanical crushing after the above-mentioned raw materials premixed, then, by extruding or pan-type pelletizer granulation, can obtain soluble granula.
A kind of two chloroquine phosphoric acid classes and glyphosate compounds herbicidal composition aqua form and comprise: (% by percentage to the quality)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Surfactant: 0.1%-20%
The surplus water supplies 100%
Preparation method: above-mentioned raw materials is stirred in reactor, after raw material dissolves fully, obtain aqua.
A kind of two chloroquine phosphoric acid classes and glyphosate compounds herbicidal composition aqueous emulsion form and comprise: (% by percentage to the quality)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Solvent: 0.1%-50%
Emulsifier: 0.1%-10%
Antifreezing agent: 0.1%-10%
Preservative: 0.1%-10%
Thickener: 0.05%-5%
Defoamer: 0.05%-5%
The surplus water supplies 100%
Preparation method: former medicine is dissolved fully in solvent, after adding emulsifier, antifreezing agent, thickener to stir, with the high-speed shearing machine homogenizer, make finished product simultaneously.
A kind of two chloroquine phosphoric acid classes and glyphosate compounds herbicidal composition water dispersion granule form and comprise: (% by percentage to the quality)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Wetting agent: 0.1%-10%
Dispersant: 0.1-10%
Disintegrant: 0.1%-10%
Binding agent: 0.1-10%
Surplus supplies 100% with filler
Preparation method: by carrying out mechanical crushing after the above-mentioned raw materials premixed, then, with extruder grain or disk granulation, after oven dry, can obtain the moisture dispersible granule.
A kind of two chloroquine phosphoric acid classes and glyphosate compounds herbicidal composition tablet form and comprise: (% by percentage to the quality)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Wetting agent: 0.1%-10%
Dispersant: 0.1%-10%
Lubricant: 0.1%-10%
Disintegrant: 0.1%-10%
Binding agent: 0.1%-10%
Surplus supplies 100% with filler
Preparation method: by carrying out mechanical crushing after the above-mentioned raw materials premixed, use the tablet press machine compressing tablet, can obtain tablet.
A kind of two chloroquine phosphoric acid classes and glyphosate compounds herbicidal composition suspending agent form and comprise: (% by percentage to the quality)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Wetting agent: 0.1%-10%
Dispersant: 0.1%-10%
Antifreezing agent: 0.1%-10%
Preservative: 0.1%-10%
Thickener: 0.05%-5%
Defoamer: 0.05%-5%
The surplus water supplies 100%
The preparation method: by after above-mentioned former medicine, auxiliary agent and water premixed, pour in the lump sand mill into and pulverized, sand milling to granularity meets the requirements, then gets final product to obtain suspending agent through allotment and froth breaking.
A kind of two chloroquine phosphoric acid classes and glyphosate compounds herbicidal composition wetting powder form and comprise: (% by percentage to the quality)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Wetting agent: 0.1%-10%
Dispersant: 0.1%-10%
Surplus supplies 100% with filler
Preparation method: by mechanical crushing after the above-mentioned raw materials premixed, be crushed to granularity and meet the requirements, get final product to obtain wetting powder.
Described wetting agent, can reduce the surface tension of water, makes water be easy to the auxiliary agent of the moistening surface of solids.This liquid is sprayed onto while being subject to the medicine surface, is easy to be subject to medicine surface wettability spread, improves control efficiency, is often surfactant.Surfactant adopts nonionic or anionic surfactant or vegetalitas surfactant.As preferably, in weed killer herbicide of the present invention, wetting agent can for sodium alkyl sulfonate, sodium alkyl sulfate, tea is withered or the natural grass saponin in one or more mixture.
Described dispersant, be divided into two kinds, and a kind of is agricultural chemicals stoste dispersant, is a kind of material with high viscosity characteristic, by mechanism, the pesticide dispersion of melting can be become to the colloid granule, as useless sticky sweet concentrate, spent pulping liquor concentrate; Another kind is the dispersant of pesticidal preparations, can prevent the pulvis flocculation, and powdered pesticide can be disperseed well when spraying.As preferably, in weed killer herbicide provided by the invention, dispersant can be one or more the mixture in polycarboxylate, lignosulfonates, NNO, naphthalene sulfonate, polyacrylic acid, dispersing agent MF, rope uncle SOPA.
Described disintegrant, weed killer herbicide provided by the invention can be used disintegrant commonly used on the market, is preferably one or more the mixture in sodium sulphate, ammonium sulfate, urea, ammonium chloride, calcium chloride, starch, cellulose, citric acid, tartaric acid in the present invention.
Described emulsifier, can make original immiscible two-phase liquid (as oil and water) form the auxiliary agent of opaque or translucent missible oil liquid, as turkey red oil, diglycerol sodium laurate, castor oil polyoxy ethyl ether, the poly-ethyl ether of alkyl phenyl etc., as preferably, in weed killer herbicide provided by the invention, emulsifier can be one or more the mixture in Tween-80, OP-21, agriculture breast 500, agriculture breast 1600.
Described binding agent, can increase the auxiliary agent of agricultural chemicals to surface of solids adhesive performance.After the medicament adhesivity improves, can anti-rainwash, improve the residual effect of agricultural chemicals.Be everlasting in powder pesticide and add the mineral oil that appropriate viscosity is larger, add appropriate gelatinized corn starch, gelatin etc. in the liquor agricultural chemicals.As preferably, in weed killer herbicide provided by the invention, binding agent can be one or more the mixture in lignin, phosphite, methylcellulose, carboxymethyl cellulose.
Described stabilizing agent, stabilizing agent claims again anticoagulant, can prevent that the physical property of pesticidal preparations (wetting powder) from degenerating in storage (suspensibility reduction).As preferably, in weed killer herbicide provided by the invention, stabilizing agent can be one or more the mixture in disodium bicarbonate, oxalic acid, succinic acid, adipic acid, borax, BHT, triethanolamine oleate or epoxidized vegetable oil.
Described defoamer, the present invention can use conventional defoamer on market, and as preferably, in weed killer herbicide provided by the invention, defoamer can be one or more the mixture in silicone based, alcohols.
Described antifreezing agent, the present invention can use conventional antifreezing agent on market, and as preferably, in weed killer herbicide provided by the invention, antifreezing agent can be one or more the mixture in ethylene glycol, glycerine, glycerine.
Described preservative, the present invention can use conventional preservatives on market, and as preferably, in weed killer herbicide provided by the invention, preservative can be one or more the mixture in phenmethylol, formaldehyde, Sodium Benzoate.
Described solvent, general solvent can meet requirement of the present invention at present, can dissolve the auxiliary agent of pesticide original medicine, multiplex in modified milk oils agricultural chemicals, as preferably, in weed killer herbicide provided by the invention, solvent can for water, propyl alcohol, methyl alcohol, dimethylbenzene, toluene, cyclohexane, benzinum, butanols, alkyl how, one or more mixture in ethers, lipid, vegetable oil.
Described filler, as preferably, in weed killer herbicide provided by the invention, filler can be one or more the mixture in urea, ammonium salt, kaolin, clay, talcum, chalk, imvite, atlapulgite, silicate, float stone, sepiolite, corncob, sawdust.
Described surfactant comprises non-ionic surface active agent, anion surfactant and zwitterionic surfactant.As preferably, in weed killer herbicide provided by the invention, surfactant can be one or more the mixture in tallow amine APEO, alkyl glycoside, organic silicon surfactant, fatty alcohol-polyoxyethylene ether, sodium alkyl benzene sulfonate, sodium alkyl sulfate, alpha-olefin sodium sulfonate, amide-type etc.
The single dose that Herbicidal combinations prepared by the present invention and weed killer herbicide and single-activity composition are made relatively, take each active component consumption is criterion calculation, Herbicidal combinations of the present invention and weed killer herbicide can effectively be prevented and kill off the glyphosate resistance weeds in uncultivated area or forest land, can effectively prevent and treat some malignant weeds simultaneously; The weed killer herbicide of glyphosate and dichloro quinolinic acid based composition and preparation thereof, significantly improved taking effect the phase of medicine, enlarged the herbicide spectrum, extended the lasting period of weed killer herbicide, saves and repeat the dispenser cost.
Embodiment
The invention discloses a kind of Herbicidal combinations and weed killer herbicide, those skilled in the art can use for reference this paper content, suitably improve technological parameter and realize.Special needs to be pointed out is, all similar replacements and change apparent to those skilled in the artly, they all are deemed to be included in the present invention.Method of the present invention and application are described by preferred embodiment, the related personnel obviously can be changed methods and applications as herein described or suitably change and combination within not breaking away from content of the present invention, spirit and scope, realizes and apply the technology of the present invention.
In Herbicidal combinations provided by the invention and weed killer herbicide, medicine used and reagent all can be buied by market.It is self-produced that glyphosate or salt and dichloro quinolinic acid or its salt are my company.
Following examples are only in order to further illustrate content of the present invention, but the present invention only limits to absolutely not following these embodiment.In formula, percentage all is weight percentage, and in the following stated weed killer herbicide, glyphosate and two chloroquine phosphate compound content are all in acid.
Embodiment 1 Herbicidal combinations
Accurately take 95% ammonium glyphosate technical product 40.8kg, the former medicine 2.4kg of 96% dichloroquinoline acid sodium-salt, make Herbicidal combinations after mixing.
Embodiment 2 Herbicidal combinations
Accurately take the former medicine 68.0kg of 95% glyphosate isopropyl amine salt, the former medicine 5.7kg of 96% dichloroquinoline acid sodium-salt, make Herbicidal combinations after mixing.
Embodiment 3 Herbicidal combinations
Accurately take 95% glyphosate technicals 75.8kg, the former medicine 8.4kg of 96% dichloroquinoline acid potassium salt, make Herbicidal combinations after mixing.
Embodiment 4 Herbicidal combinations
Accurately take 95% glyphosate technicals 73.7kg, the former medicine 10.5kg of 96% quinclorac ammonium salts, make Herbicidal combinations after mixing.
Embodiment 5 Herbicidal combinations
Accurately take 95% glyphosate technicals 42.2kg, the former medicine 10.5kg of 96% quinclorac ammonium salts, make Herbicidal combinations after mixing.
Embodiment 6 Herbicidal combinations
Accurately take 95% glyphosate technicals 16.5kg, the former medicine 23.5kg of 96% dichloroquinoline acid potassium salt, make Herbicidal combinations after mixing.
Embodiment 7 Herbicidal combinations
Accurately take 95% ammonium glyphosate technical product 1.8kg, the former medicine 8.8kg of 96% quinclorac ammonium salts, make Herbicidal combinations after mixing.
Embodiment 8 Herbicidal combinations
Accurately take 95% glyphosate technicals 75.8kg, the former medicine 8.4kg of 96% dichloro quinolinic acid, make Herbicidal combinations after mixing.
Embodiment 9 weed killer herbicides
The former medicine 40.8kg of 95% glyphosate isopropyl amine salt, the former medicine 2.4kg of 96% dichloroquinoline acid sodium-salt, carbonic hydroammonium 1.2kg, X5308kg, antifreezing agent 1.0kg, water complements to 100kg.
By the above-mentioned raw materials premix, in reactor, strong agitation is rear filling to fully dissolving, the aqua that the mass fraction that makes Herbicidal combinations is 41%.
Embodiment 10 weed killer herbicides
The former medicine 68.0kg of 95% glyphosate isopropyl amine salt, the former medicine 5.7kg of 96% dichloroquinoline acid sodium-salt, carbonic hydroammonium 2.2kg, tallow amine 10.0kg, ammonium sulfate complements to 100kg.
By carrying out mechanical crushing after the above-mentioned raw materials premix, through disk granulation or extruder grain, the soluble granula that the mass fraction that makes Herbicidal combinations is 70%.
Embodiment 11 weed killer herbicides
95% glyphosate technicals 75.8kg, the former medicine 8.4kg of 96% dichloroquinoline acid potassium salt, sodium lignin sulfonate 6.0kg, NNO 5.0kg, lauryl sodium sulfate 2.0kg, kaolin complements to 100kg.
Mechanical crushing will be carried out, the wetting powder that the mass fraction that makes Herbicidal combinations is 80% after the above-mentioned raw materials premixed.
Embodiment 12 weed killer herbicides
95% glyphosate technicals 73.7kg, the former medicine 10.5kg of 96% quinclorac ammonium salts, sodium lignin sulfonate 6.0kg, lauryl sodium sulfate 2.0kg, urea 2.0kg, starch complements to 100kg.
By carrying out mechanical crushing after the above-mentioned raw materials premix, through disk granulation or extruder grain, the water dispersible granules that the mass fraction that makes Herbicidal combinations is 80%.
Embodiment 13 weed killer herbicides
95% glyphosate technicals 42.2kg, the former medicine 10.5kg of 96% quinclorac ammonium salts, D425 7.0kg, EFW 3.5kg, defoamer 0.3kg, ethylene glycol 5.0kg, xanthans 0.3kg, aluminium-magnesium silicate 0.4kg, water complements to 100kg.
To after glyphosate and the former medicine premixed of dichloro quinolinic acid, be added to sand mill, after D425, EFW, ethylene glycol, aluminium-magnesium silicate and defoamer being mixed, together be added in sand mill simultaneously, be crushed to certain granularity through sand mill, add xanthans 0.3kg to mix, filtration, filling, make the suspending agent that composition levels is 50%.
Embodiment 14 weed killer herbicides
95% glyphosate technicals 16.5kg, the former medicine 23.5kg of 96% dichloroquinoline acid potassium salt, dimethylbenzene 15.0kg, agriculture breast 200 5.0kg, antifreezing agent 4.0kg, preservative 4.0kg, water complements to 100kg.
Glyphosate technicals is dissolved in to the diformazan benzo adds emulsifier to form even oil phase, by the former medicine of dichloroquinoline acid potassium salt salt soluble in water, jointly join in oil phase, after adding antifreezing agent, preservative, use high-speed shearing machine emulsification, the aqueous emulsion that the mass fraction that makes Herbicidal combinations is 38%.
Embodiment 15 weed killer herbicides
95% ammonium glyphosate technical product 1.8kg, the former medicine 8.8kg of 96% quinclorac ammonium salts, sodium lignin sulfonate 5.0g, NNO 5.0kg, urea 3.0kg, ammonium chloride 5.0kg, talcum powder 8.0kg, lauryl sodium sulfate 3.0kg, bentonite complements to 100kg.
By after the above-mentioned raw materials premix, carry out air-flow crushing, make with tablet press machine the tablet that the mass fraction of Herbicidal combinations is 10%.
Embodiment 16 weed killer herbicides
Accurately take 95% glyphosate technicals 75.8kg, the former medicine 8.4kg of 96% dichloro quinolinic acid, sodium lignin sulfonate 6.0kg, NNO 5.0kg, lauryl sodium sulfate 2.0kg, kaolin complements to 100kg.
Mechanical crushing will be carried out, the wetting powder that the mass fraction that makes Herbicidal combinations is 80% after the above-mentioned raw materials premixed.
The efficiency test of embodiment 17 Herbicidal combinations provided by the invention to weeds
Test in Zhejiang Hangzhou one wasteland and carry out, wherein, every processing repeats for 4 times, and the community area is 20m
2, the Gong48Ge community, random district group is arranged, and each is processed, and former medicine clear water dissolves and final volume is identical, evenly sprays.Add up respectively all kinds of weeds strain numbers before dispenser, the poisoning situation of 3 days weeds after dispenser, the dead strain number of weeds is added up respectively in dispenser in 10 days, 25 days.The poisoning situation of dispenser weeds after 3 days is in Table 1, and the preventive effect of dispenser after 10 days the results are shown in Table 2, and the preventive effect of dispenser after 25 days the results are shown in Table, and 3.Preventive effect is calculated according to following formula:
Preventive effect (%)=1-(after dispenser, the front weeds strain number of ÷ dispenser is counted in the weeds strain) * 100%.
Table 1 is used the poisoning situation of Herbicidal combinations weeds after 3 days
Table 2 is used Herbicidal combinations preventive effect result after 10 days
Table 3 is used Herbicidal combinations preventive effect result after 25 days
From the field control effectiveness test of table 1, table 2 and table 3, glyphosate is poor to the overall preventive effect of the resistance such as Horseweed Herb, barnyard grass, corn sow thistle, eleusine indica or malignant weed, and quick-acting is poor, and medication is after 25 days, and preventive effect is just basicly stable; Though dichloro quinolinic acid or dichloro quinolinic acid be alone, certain drug effect is arranged, holding effect is poor, and the dispenser overall preventive effect of 25 days is very poor.Herbicidal combinations provided by the invention has significantly shortened effective time, has enlarged the herbicide spectrum.The Herbicidal combinations of embodiment 1 to embodiment 7 preparation is than the Herbicidal combinations of embodiment 8, and effective time is shorter, and the herbicide spectrum is wider; The weeds preventive effect of the Herbicidal combinations of embodiment 1 to embodiment 7 preparation is significantly higher than glyphosate single dose drug effect (P≤0.05), Herbicidal combinations provided by the invention is in the consumption that reduces glyphosate, can enlarge the herbicide spectrum, produce effects is fast, has strengthened herbicidal effect.
The efficiency test of embodiment 18 weed killer herbicides
Test in Zhejiang Hangzhou one wasteland and carry out, wherein, every processing repeats for 4 times, and the community area is 20m
2, the Gong48Ge community, random district group is arranged, and each is processed, and former medicine clear water dissolves and final volume is identical, evenly sprays.Add up respectively all kinds of weeds strain numbers before dispenser, the poisoning situation of 3 days weeds after dispenser, add up respectively the dead strain number of weeds in after dispenser 10 days, 25 days.The poisoning situation of dispenser after 3 days is in Table 4, and the preventive effect of dispenser after 10 days the results are shown in Table 5, and the preventive effect of dispenser after 25 days the results are shown in Table, and 6.Preventive effect is calculated according to following formula:
Preventive effect (%)=1-(after dispenser, the front weeds strain number of ÷ dispenser is counted in the weeds strain) * 100%.
Table 3 is used the poisoning situation of weed killer herbicide weeds after 3 days
Table 4 is used weed killer herbicide preventive effect result after 10 days
Table 6 is used weed killer herbicide preventive effect result after 25 days
From the field control effectiveness test of table 4, table 5 and table 6, glyphosate is poor to the overall preventive effect of the resistance such as Horseweed Herb, barnyard grass, corn sow thistle, eleusine indica or malignant weed, and quick-acting is poor, and medication is after 25 days, and preventive effect is just basicly stable; Though dichloro quinolinic acid or dichloro quinolinic acid be alone, certain drug effect is arranged, holding effect is poor, and the dispenser overall preventive effect of 25 days is very poor.Herbicidal combinations provided by the invention has significantly shortened effective time, has enlarged the herbicide spectrum.The Herbicidal combinations of embodiment 9 to embodiment 15 preparations is than the Herbicidal combinations of embodiment 16, and effective time is shorter, and the herbicide spectrum is wider; The weeds preventive effect of the Herbicidal combinations of embodiment 1 to embodiment 7 preparation is significantly higher than glyphosate single dose drug effect (P≤0.05), Herbicidal combinations provided by the invention is in the consumption that reduces glyphosate, can enlarge the herbicide spectrum, produce effects is fast, has strengthened herbicidal effect.
Claims (17)
1. the Herbicidal combinations of a controlling weeds and dogstail, is characterized in that being comprised of glyphosate compounds and two chloroquine acid compounds.
2. composition according to claim 1, is characterized in that described glyphosate compounds is one or more existence in glyphosate, ammonium glyphosate, glyphosate potassium, sodium glyphosate, glyphosate isopropyl amine salt, glyphosate dimethylamine salt, glyphosate monomethyl amine salt, glyphosate ethanolamine salt and glyphosate trimethyl mercapto salt.
3. composition according to claim 1, is characterized in that described two chloroquine phosphate compounds comprise one or more existence in two chloroquine phosphoric acid, two chloroquine sodium ascorbyl phosphates, two chloroquine ammonium phosphate salts, two chloroquine potassium phosphates.
4. according to claim 1 or 2 or 3 described compositions, the mass ratio that it is characterized in that glyphosate compounds and two chloroquine acid compounds is 10-95: 1-89.
5. composition according to claim 4, the mass ratio that it is characterized in that two chloroquine phosphoric acid salt compounds and glyphosate salt compounds is 20-70: 4-89.
6. a weed killer herbicide, is characterized in that, its acceptable auxiliary material in the described Herbicidal combinations of claim 1 to 5 any one and pesticidal preparations forms, and the mass percent that described Herbicidal combinations accounts for described weed killer herbicide is 10-99%.
7. weed killer herbicide according to claim 6, is characterized in that, the mass percent that described Herbicidal combinations accounts for described weed killer herbicide is 18-80%.
8. weed killer herbicide according to claim 6, is characterized in that, its preparation can be soluble powder, soluble granula, aqua, aqueous emulsion, water dispersion granule, tablet, wetting powder or suspending agent.
9. according to arbitrary described weed killer herbicide in claim 6-8, it is characterized in that acceptable auxiliary material in described pesticidal preparations comprises one or more the mixture in wetting agent, dispersant, disintegrant, emulsifier, binding agent, defoamer, thickener, stabilizing agent, antifreezing agent, preservative, volume, carrier etc.
10. soluble powder according to claim 7, is characterized in that comprising following composition: (mass percent meter %)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Wetting agent: 0.1%-10%
Dispersant: 0.1%-10%
Surplus is supplied with filler.
11. soluble granula according to claim 7 is characterized in that comprising following composition: (mass percent meter %)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 0.1%-99%
Wetting agent: 0.1%-10%
Disintegrant: 0.1%-10%
Dispersant: 0.1%-10%
Its surplus supplies 100% with filler
12. aqua according to claim 7 is characterized in that comprising following composition: (mass percent meter %)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Surfactant: 0.1%-20%
Its surplus water supplies 100%
13. aqueous emulsion according to claim 7 is characterized in that comprising following composition: (mass percent meter %)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Solvent: 0.1%-50%
Emulsifier: 0.1%-10%
Antifreezing agent: 0.1%-10%
Preservative: 0.1%-10%
Thickener: 0.05%-5%
Defoamer: 0.05%-5%
The surplus water supplies 100%
14. water dispersion granule according to claim 7 is characterized in that comprising following composition: (mass percent meter %)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Wetting agent: 0.1%-10%
Dispersant: 0.1-10%
Disintegrant: 0.1%-10%
Binding agent: 0.1-10%
Surplus supplies 100% with filler
15. tablet according to claim 7 is characterized in that comprising following composition: (mass percent meter %)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Wetting agent: 0.1%-10%
Dispersant: 0.1%-10%
Lubricant: 0.1%-10%
Disintegrant: 0.1%-10%
Binding agent: 0.1%-10%
Surplus supplies 100% with filler
16. suspending agent agent according to claim 7 is characterized in that comprising following composition: (mass percent meter %)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Wetting agent: 0.1%-10%
Dispersant: 0.1%-10%
Antifreezing agent: 0.1%-10%
Preservative: 0.1%-10%
Thickener: 0.05%-5%
Defoamer: 0.05%-5%
The surplus water supplies 100%
17. a chloroquine phosphoric acid class and glyphosate compounds herbicidal composition wetting powder form and comprise: (% by percentage to the quality)
Two chloroquine phosphate compound: 0.1%-89%
Glyphosate compounds: 10%-99%
Wetting agent: 0.1%-10%
Dispersant: 0.1%-10%
Surplus supplies 100% with filler.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104871777A (en) * | 2015-05-18 | 2015-09-02 | 中国农业科学院烟草研究所 | Comprehensive repair method for residual quinclorac herbicide in tobacco field |
| CN108271806A (en) * | 2017-11-29 | 2018-07-13 | 池州市农业技术推广中心（池州市菜篮子工程办公室） | A kind of field drum mixed pesticide synergist formula for preventing Horseweed Herb |
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| CN1315832A (en) * | 1998-08-13 | 2001-10-03 | 阿温提斯作物科学有限公司 | Herbicidal composition for tolerant or resistant rice crops |
| CN1803774A (en) * | 2006-01-20 | 2006-07-19 | 浙江新安化工集团股份有限公司 | Dichloro quinolinic acid, its preparation method and solid preparation thereof |
| CN102215695A (en) * | 2008-09-29 | 2011-10-12 | 孟山都技术公司 | Glyphosate formulations containing amidoalkylamine surfactants |
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|---|---|---|---|---|
| EP0494386A1 (en) * | 1991-01-08 | 1992-07-15 | Mycogen Corporation | Novel process and composition for controlling weeds |
| CN1315832A (en) * | 1998-08-13 | 2001-10-03 | 阿温提斯作物科学有限公司 | Herbicidal composition for tolerant or resistant rice crops |
| CN1803774A (en) * | 2006-01-20 | 2006-07-19 | 浙江新安化工集团股份有限公司 | Dichloro quinolinic acid, its preparation method and solid preparation thereof |
| CN102215695A (en) * | 2008-09-29 | 2011-10-12 | 孟山都技术公司 | Glyphosate formulations containing amidoalkylamine surfactants |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104871777A (en) * | 2015-05-18 | 2015-09-02 | 中国农业科学院烟草研究所 | Comprehensive repair method for residual quinclorac herbicide in tobacco field |
| CN104871777B (en) * | 2015-05-18 | 2017-03-29 | 中国农业科学院烟草研究所 | The method for comprehensive repairing of two chloroquine phosphoric acid class herbicide residues in a kind of vega |
| CN108271806A (en) * | 2017-11-29 | 2018-07-13 | 池州市农业技术推广中心（池州市菜篮子工程办公室） | A kind of field drum mixed pesticide synergist formula for preventing Horseweed Herb |
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Application publication date: 20131204 |