CN103411884B - A kind of reference transmission dispersion sensitivity spectrum line detector - Google Patents
A kind of reference transmission dispersion sensitivity spectrum line detector Download PDFInfo
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Abstract
本发明涉及一种参比透射色散敏感谱线检测装置,可有效解决测试仪加工、装配精度要求高,造价高,体积大,测量时间长,抗干扰能力差的问题,其解决的技术方案是,包括箱体、线阵CCD传感模块和线性光敏二极管,箱体上部装有遮光罩,箱体内中间装有透明器皿,透明器皿左方装有发光二极管,线性光敏二极管经光导纤维与发光二极管相连,透明器皿右方装有光阑,光阑右方装有色散光栅,色散光栅上方装有线阵CCD传感模块,发光二级管与驱动电路相连,线性光敏二极管与第二处理器相连,线阵CCD传感模块与第一处理器相连,本发明结构巧妙,制造工艺简单,使用方便,可有效解决测试仪加工、装配精度要求高,造价高,体积大,测量时间长,抗干扰能力差的问题。
The invention relates to a reference transmission dispersion-sensitive spectral line detection device, which can effectively solve the problems of high processing and assembly precision requirements, high cost, large volume, long measurement time and poor anti-interference ability of the tester. The technical solution is: , including a box, a linear array CCD sensor module and a linear photodiode, a shading cover is installed on the upper part of the box, a transparent vessel is installed in the middle of the box, and a light-emitting diode is installed on the left side of the transparent vessel. Connected, a diaphragm is installed on the right side of the transparent vessel, a dispersion grating is installed on the right side of the diaphragm, a linear array CCD sensor module is installed above the dispersion grating, the light-emitting diode is connected to the driving circuit, and the linear photodiode is connected to the second processor. The linear array CCD sensing module is connected with the first processor. The invention has ingenious structure, simple manufacturing process and convenient use, and can effectively solve the tester processing and assembly precision requirements, high cost, large volume, long measurement time, and anti-interference ability. bad question.
Description
一、技术领域1. Technical field
本发明涉及液体光谱测量领域,特别是一种参比透射色散敏感谱线检测装置。The invention relates to the field of liquid spectrum measurement, in particular to a reference transmission dispersion sensitive spectral line detection device.
二、背景技术2. Background technology
目前,在某些液体残留物质检测方法是采用液相分光光度计中,由于在测量过程中存在分光器件的旋转运动或线性运动,以实现色散扫描,所以,测试仪加工、装配精度要求苛刻,对测量环境振动、水平稳定度、温湿度等条件要求很高,通常,仪器设备造价昂贵,体积庞大,测量时间长,抗干扰能力差,只能在实验室条件下工作。虽然也出现了一些基于色敏传感器的测试仪,改善了分光光度计测量过程中需要色散器件转动扫描的缺陷,但对于光源由于供电不稳定、温度变化、发光效率衰减等造成的发光强度不稳定,导致测量的精度低,一致性差的问题没有很好的解决,特别是针对要求谱线分布的测量,更是无能为力。因此,提供能很好的满足各种复杂现场测试使用的要求,特别对于一些突发事件或自然灾害现场的应急快速检试方法与装置,显得尤为重要At present, in some liquid residual substance detection methods, liquid phase spectrophotometers are used. Due to the rotational movement or linear movement of the spectroscopic device during the measurement process to achieve dispersion scanning, the processing and assembly accuracy of the tester is demanding. The requirements for measuring environmental vibration, horizontal stability, temperature and humidity are very high. Usually, the equipment is expensive, bulky, long measurement time, poor anti-interference ability, and can only work under laboratory conditions. Although some testers based on color-sensitive sensors have also appeared, which have improved the defect that the dispersion device needs to be rotated and scanned during the measurement process of the spectrophotometer, but the luminous intensity of the light source is unstable due to unstable power supply, temperature change, and luminous efficiency attenuation. , leading to low measurement accuracy and poor consistency, the problems have not been well resolved, especially for the measurement that requires spectral line distribution, there is nothing we can do. Therefore, it is particularly important to provide emergency quick test methods and devices that can well meet the requirements of various complex field tests, especially for some emergencies or natural disasters.
三、发明内容3. Contents of the invention
针对上述情况,为克服现有技术之缺陷,本发明之目的就是提供一种参比透射色散敏感谱线检测装置,可有效解决测试仪加工、装配精度要求高,造价高,体积大,测量时间长,抗干扰能力差的问题。In view of the above situation, in order to overcome the defects of the prior art, the purpose of the present invention is to provide a reference transmission dispersion sensitive spectral line detection device, which can effectively solve the tester processing and assembly precision requirements, high cost, large volume, and measurement time. Long, poor anti-interference ability.
其解决的技术方案是,包括箱体、线阵CCD传感模块和线性光敏二极管,箱体上部装有遮光罩,箱体内中间装有透明器皿,透明器皿左方装有发光二极管,线性光敏二极管经光导纤维与发光二极管相连,透明器皿右方装有光阑,光阑右方装有色散光栅,色散光栅上方装有线阵CCD传感模块,光阑和发光二极管的中心在同一轴线上,色散光栅反光面与透明器皿的右端面对应并与光阑的水平轴线成135度夹角;发光二级管与驱动电路相连,线性光敏二极管与第二处理器相连,线阵CCD传感模块与第一处理器相连,第一处理器和第二处理器分别与第三处理器相连,第三处理器与第四处理器相连,第四处理器与显示器相连。The technical solution is to include a box body, a linear array CCD sensor module and a linear photodiode. It is connected with the light-emitting diode through the optical fiber. The right side of the transparent vessel is equipped with a diaphragm, and the right side of the diaphragm is equipped with a dispersion grating. A linear array CCD sensor module is installed above the dispersion grating. The center of the diaphragm and the light-emitting diode are on the same axis. The reflective surface of the grating corresponds to the right end face of the transparent vessel and forms an angle of 135 degrees with the horizontal axis of the diaphragm; the light-emitting diode is connected with the driving circuit, the linear photodiode is connected with the second processor, and the linear array CCD sensor module is connected with the second processor. The first processor is connected, the first processor and the second processor are respectively connected with the third processor, the third processor is connected with the fourth processor, and the fourth processor is connected with the display.
所说的第一处理器、第二处理器、第三处理器和第四处理器为单片机。Said first processor, second processor, third processor and fourth processor are single-chip microcomputers.
本发明结构巧妙,制造工艺简单,使用方便,可有效解决测试仪加工、装配精度要求高,造价高,体积大,测量时间长,抗干扰能力差的问题。The invention has ingenious structure, simple manufacturing process and convenient use, and can effectively solve the problems of high processing and assembly precision requirements, high cost, large volume, long measurement time and poor anti-interference ability of the tester.
四、附图说明4. Description of drawings
图1为本发明结构示意图。Fig. 1 is a schematic diagram of the structure of the present invention.
图2为本发明光学测量原理示意图。Fig. 2 is a schematic diagram of the optical measurement principle of the present invention.
五、具体实施方式5. Specific implementation
以下结合附图对本发明的具体实施方式做进一步详细说明。The specific implementation manners of the present invention will be described in further detail below in conjunction with the accompanying drawings.
由图1、图2给出,本发明装置包括箱体、线阵CCD传感模块和线性光敏二极管,箱体1上部装有遮光罩3,箱体1内中间装有透明器皿5,透明器皿5左方装有发光二极管2,线性光敏二极管4经光导纤维15与发光二极管2相连,透明器皿5右方装有光阑7,光阑7右方装有色散光栅8,色散光栅8上方装有线阵CCD传感模块6,光阑7和发光二极管2的中心在同一轴线上,色散光栅8反光面与透明器皿5的右端面对应并与光阑7的水平轴线成135度夹角;发光二级管2与驱动电路相连9,线性光敏二极管4与第二处理器10相连,线阵CCD传感模块6与第一处理器11相连,第一处理器11和第二处理器10分别与第三处理器12相连,第三处理器12与第四处理器13相连,第四处理器13与显示器14相连。Provided by Fig. 1 and Fig. 2, the device of the present invention comprises a box body, a linear array CCD sensor module and a linear photodiode, a light shield 3 is installed on the top of the box body 1, a transparent vessel 5 is housed in the middle of the box body 1, and the transparent vessel The left side of 5 is equipped with light-emitting diode 2, the linear photosensitive diode 4 is connected with light-emitting diode 2 through optical fiber 15, the right side of transparent vessel 5 is equipped with diaphragm 7, the right side of diaphragm 7 is equipped with dispersion grating 8, and the top of dispersion grating 8 is equipped with The linear array CCD sensor module 6, the center of the diaphragm 7 and the light emitting diode 2 are on the same axis, the reflective surface of the dispersion grating 8 corresponds to the right end face of the transparent vessel 5 and forms an included angle of 135 degrees with the horizontal axis of the diaphragm 7; The light-emitting diode 2 is connected to the drive circuit 9, the linear photodiode 4 is connected to the second processor 10, the linear array CCD sensing module 6 is connected to the first processor 11, and the first processor 11 and the second processor 10 are respectively It is connected to the third processor 12 , the third processor 12 is connected to the fourth processor 13 , and the fourth processor 13 is connected to the display 14 .
所说的第一处理器11、第二处理器10、第三处理器12和第四处理器13为单片机。Said first processor 11, second processor 10, third processor 12 and fourth processor 13 are single-chip microcomputers.
本发明的使用情况是:The usage situation of the present invention is:
发光二级管2发出光,透明器皿5里的液体和光导纤维15同时接受光,经过透明器皿5里的液体的光通过光阑7照射在色散光栅8上,经色散光栅8反射后照到线阵CCD传感模块6,线阵CCD传感模块6把信号传到第一处理器11中,经处理后得到的Vi,传到第三处理器12;光导纤维15接受的光到线性光敏二极管4,转成信号传到第二处理器10中,经处理后得到实测发光强度E2,传到第三处理器12,第三处理器12通过对实测发光强度E2进行修正得到修正系数,然后对线阵CCD传感模块6各像素点Vi的实测值进行修正,修正后的经第四处理器13的线性化在显示屏14显示。The light-emitting diode 2 emits light, and the liquid in the transparent vessel 5 and the optical fiber 15 receive the light at the same time. The light passing through the liquid in the transparent vessel 5 is irradiated on the dispersion grating 8 through the diaphragm 7, and then shines on the dispersion grating 8 after being reflected by the dispersion grating 8. The linear array CCD sensing module 6, the linear array CCD sensing module 6 transmits the signal to the first processor 11, and the V i obtained after processing is transmitted to the third processor 12; the light received by the optical fiber 15 is sent to the linear The photosensitive diode 4 is converted into a signal and transmitted to the second processor 10. After processing, the measured luminous intensity E 2 is obtained and transmitted to the third processor 12. The third processor 12 corrects the measured luminous intensity E 2 coefficient, and then correct the actual measured value of each pixel V i of the linear CCD sensor module 6 , and the corrected linearization by the fourth processor 13 is displayed on the display screen 14 .
计算公式如下:Calculated as follows:
对于像素为N的线阵CCD,上式中的i=1~N,其中For a linear array CCD with N pixels, i=1~N in the above formula, where
Si-被测液体第i像素的灰度值标值,为检测结果;S i - the gray scale value of the i-th pixel of the measured liquid, which is the detection result;
Ki-被测液体第i像素的色谱吸收系数,为已知值;K i - the chromatographic absorption coefficient of the i-th pixel of the measured liquid, which is a known value;
Vi-CCD传感器第i像素的输出灰度值,为实测值;V i - the output gray value of the i-th pixel of the CCD sensor, which is the measured value;
E1-标准光源光强度,为已知值;E 1 - the light intensity of the standard light source, which is a known value;
E2-实测光源光强度,为实测值;E 2 - the measured light intensity of the light source, which is the measured value;
I1-对应标准光源光强度时,线性光敏二极管4的光电流,为已知值;I 1 -when corresponding to the light intensity of the standard light source, the photocurrent of the linear photodiode 4 is a known value;
I2-对应实测光源光强度时,线性光敏二极管4的光电流,为实测值。I 2 -the photocurrent of the linear photodiode 4 corresponding to the measured light intensity of the light source, which is the measured value.
本发明由于采用色散光栅加线阵CCD传感模块替代传统的扫描色散结构,使得整个测量过程无需机械转动扫描,因而大大提高了仪器的环境适用性和测量的稳定性,同时,由于两种光谱测量的结构与方法不同,前者在信号采集和数据处理速度上远高与后者,普通的单次色度测量时间小于2秒。Because the present invention uses a dispersion grating plus a linear array CCD sensing module to replace the traditional scanning dispersion structure, the entire measurement process does not require mechanical rotation and scanning, thus greatly improving the environmental applicability and measurement stability of the instrument. At the same time, due to the two spectral The measurement structure and method are different. The former is much faster than the latter in terms of signal acquisition and data processing speed, and the ordinary single chromaticity measurement time is less than 2 seconds.
本发明结构巧妙,制造工艺简单,使用方便,可有效解决测试仪加工、装配精度要求高,造价高,体积大,测量时间长,抗干扰能力差的问题。The invention has ingenious structure, simple manufacturing process and convenient use, and can effectively solve the problems of high processing and assembly precision requirements, high cost, large volume, long measurement time and poor anti-interference ability of the tester.
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