CN103374314A - Dispensing adhesive agent for connection of mosaics and production process - Google Patents
Dispensing adhesive agent for connection of mosaics and production process Download PDFInfo
- Publication number
- CN103374314A CN103374314A CN2012101059361A CN201210105936A CN103374314A CN 103374314 A CN103374314 A CN 103374314A CN 2012101059361 A CN2012101059361 A CN 2012101059361A CN 201210105936 A CN201210105936 A CN 201210105936A CN 103374314 A CN103374314 A CN 103374314A
- Authority
- CN
- China
- Prior art keywords
- agent
- phthalate
- mosaic
- adhesive agent
- point glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 66
- 229920005989 resin Polymers 0.000 claims abstract description 34
- 239000011347 resin Substances 0.000 claims abstract description 34
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 15
- 239000013008 thixotropic agent Substances 0.000 claims abstract description 15
- 239000007822 coupling agent Substances 0.000 claims abstract description 14
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 13
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 12
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 44
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 44
- 239000003292 glue Substances 0.000 claims description 37
- 229920000642 polymer Polymers 0.000 claims description 33
- 230000008878 coupling Effects 0.000 claims description 19
- 238000010168 coupling process Methods 0.000 claims description 19
- 238000005859 coupling reaction Methods 0.000 claims description 19
- 150000002148 esters Chemical class 0.000 claims description 16
- 239000004814 polyurethane Substances 0.000 claims description 15
- 229920002635 polyurethane Polymers 0.000 claims description 15
- 239000003381 stabilizer Substances 0.000 claims description 14
- 239000004902 Softening Agent Substances 0.000 claims description 13
- -1 2-ethylhexyl Chemical group 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 12
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 11
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 claims description 10
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 10
- 239000004593 Epoxy Substances 0.000 claims description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 10
- WHIVNJATOVLWBW-UHFFFAOYSA-N n-butan-2-ylidenehydroxylamine Chemical compound CCC(C)=NO WHIVNJATOVLWBW-UHFFFAOYSA-N 0.000 claims description 10
- MQHNKCZKNAJROC-UHFFFAOYSA-N dipropyl phthalate Chemical compound CCCOC(=O)C1=CC=CC=C1C(=O)OCCC MQHNKCZKNAJROC-UHFFFAOYSA-N 0.000 claims description 9
- 229920000728 polyester Polymers 0.000 claims description 9
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 8
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 claims description 8
- WYNCHZVNFNFDNH-UHFFFAOYSA-N Oxazolidine Chemical compound C1COCN1 WYNCHZVNFNFDNH-UHFFFAOYSA-N 0.000 claims description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 7
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 7
- 239000011976 maleic acid Substances 0.000 claims description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 7
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 6
- KCXZNSGUUQJJTR-UHFFFAOYSA-N Di-n-hexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC KCXZNSGUUQJJTR-UHFFFAOYSA-N 0.000 claims description 6
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000292 calcium oxide Substances 0.000 claims description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 6
- 238000007334 copolymerization reaction Methods 0.000 claims description 6
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims description 6
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 claims description 6
- IPKKHRVROFYTEK-UHFFFAOYSA-N dipentyl phthalate Chemical compound CCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCC IPKKHRVROFYTEK-UHFFFAOYSA-N 0.000 claims description 6
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 claims description 6
- 239000013638 trimer Substances 0.000 claims description 6
- SDXAWLJRERMRKF-UHFFFAOYSA-N 3,5-dimethyl-1h-pyrazole Chemical compound CC=1C=C(C)NN=1 SDXAWLJRERMRKF-UHFFFAOYSA-N 0.000 claims description 5
- IHLDEDLAZNFOJB-UHFFFAOYSA-N 6-octoxy-6-oxohexanoic acid Chemical compound CCCCCCCCOC(=O)CCCCC(O)=O IHLDEDLAZNFOJB-UHFFFAOYSA-N 0.000 claims description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical group CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 4
- VLJQDHDVZJXNQL-UHFFFAOYSA-N 4-methyl-n-(oxomethylidene)benzenesulfonamide Chemical compound CC1=CC=C(S(=O)(=O)N=C=O)C=C1 VLJQDHDVZJXNQL-UHFFFAOYSA-N 0.000 claims description 4
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 claims description 4
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 4
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 4
- LUZSPGQEISANPO-UHFFFAOYSA-N butyltin Chemical compound CCCC[Sn] LUZSPGQEISANPO-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000003350 kerosene Substances 0.000 claims description 4
- 235000012424 soybean oil Nutrition 0.000 claims description 4
- 239000003549 soybean oil Substances 0.000 claims description 4
- IMYZYCNQZDBZBQ-SJORKVTESA-N (9S,10R)-epoxyoctadecanoic acid Chemical compound CCCCCCCC[C@H]1O[C@H]1CCCCCCCC(O)=O IMYZYCNQZDBZBQ-SJORKVTESA-N 0.000 claims description 3
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical class CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 3
- WOYWLLHHWAMFCB-UHFFFAOYSA-N 2-ethylhexyl acetate Chemical compound CCCCC(CC)COC(C)=O WOYWLLHHWAMFCB-UHFFFAOYSA-N 0.000 claims description 3
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- VOWAEIGWURALJQ-UHFFFAOYSA-N Dicyclohexyl phthalate Chemical compound C=1C=CC=C(C(=O)OC2CCCCC2)C=1C(=O)OC1CCCCC1 VOWAEIGWURALJQ-UHFFFAOYSA-N 0.000 claims description 3
- QWDBCIAVABMJPP-UHFFFAOYSA-N Diisopropyl phthalate Chemical compound CC(C)OC(=O)C1=CC=CC=C1C(=O)OC(C)C QWDBCIAVABMJPP-UHFFFAOYSA-N 0.000 claims description 3
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 3
- WRQNANDWMGAFTP-UHFFFAOYSA-N Methylacetoacetic acid Chemical compound COC(=O)CC(C)=O WRQNANDWMGAFTP-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 claims description 3
- 239000004964 aerogel Substances 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- BVFSYZFXJYAPQJ-UHFFFAOYSA-N butyl(oxo)tin Chemical compound CCCC[Sn]=O BVFSYZFXJYAPQJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- SHYSNLBEJADGAC-UHFFFAOYSA-N decanedioic acid;propane-1,1-diol Chemical compound CCC(O)O.OC(=O)CCCCCCCCC(O)=O SHYSNLBEJADGAC-UHFFFAOYSA-N 0.000 claims description 3
- WCRDXYSYPCEIAK-UHFFFAOYSA-N dibutylstannane Chemical compound CCCC[SnH2]CCCC WCRDXYSYPCEIAK-UHFFFAOYSA-N 0.000 claims description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 3
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 3
- 125000005442 diisocyanate group Chemical group 0.000 claims description 3
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 claims description 3
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 claims description 3
- 229960001826 dimethylphthalate Drugs 0.000 claims description 3
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 claims description 3
- XWVQUJDBOICHGH-UHFFFAOYSA-N dioctyl nonanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCC(=O)OCCCCCCCC XWVQUJDBOICHGH-UHFFFAOYSA-N 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000006735 epoxidation reaction Methods 0.000 claims description 3
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- PRZYKDRCYOLTQA-UHFFFAOYSA-N methyl 2,5,11,14,18-pentachlorooctadecanoate Chemical compound COC(=O)C(Cl)CCC(Cl)CCCCCC(Cl)CCC(Cl)CCCCCl PRZYKDRCYOLTQA-UHFFFAOYSA-N 0.000 claims description 3
- VNBLTKHUCJLFSB-UHFFFAOYSA-N n-(trimethoxysilylmethyl)aniline Chemical compound CO[Si](OC)(OC)CNC1=CC=CC=C1 VNBLTKHUCJLFSB-UHFFFAOYSA-N 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 3
- FIBARIGPBPUBHC-UHFFFAOYSA-N octyl 8-(3-octyloxiran-2-yl)octanoate Chemical compound CCCCCCCCOC(=O)CCCCCCCC1OC1CCCCCCCC FIBARIGPBPUBHC-UHFFFAOYSA-N 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 3
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- 125000003396 thiol group Chemical class [H]S* 0.000 claims description 3
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 3
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims description 3
- 125000005591 trimellitate group Chemical group 0.000 claims description 3
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 claims description 3
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 13
- 239000000123 paper Substances 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 8
- 239000004014 plasticizer Substances 0.000 abstract description 3
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 2
- 229920001730 Moisture cure polyurethane Polymers 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000012760 heat stabilizer Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 8
- 229920002554 vinyl polymer Polymers 0.000 description 8
- 239000000758 substrate Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 238000010276 construction Methods 0.000 description 4
- 239000004568 cement Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 238000009835 boiling Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 210000003660 reticulum Anatomy 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a dispensing adhesive agent for connection of mosaics and a production process. The adhesive agent comprises, by weight, 20%-30% of plasticizers, 18%-33% of polyvinyl chloride paste resins, 0.5%-2% of curing agents, 1.0%-12% of endcapped polyurethane prepolymers, 6%-13% of nano calcium carbonate, 3%-16% of heavy calcium carbonate, 3%-23% of calcite powder, 0.1%-1% of coupling agents, 0.3%-4.5% of heat stabilizers, 0.2%-6% of water-removal agents, 0.4%-1.8% of thixotropic agents and 0%-2% of diluents. The adhesive agent for connection of mosaics does not need base materials such as paper, silk screens and the like, has excellent water resistance and can raise the bonding strength of mosaics.
Description
Technical field
The present invention relates to a kind of mosaic and become coupling point glue adhesive agent and manufacture craft thereof.
Background technology
Present domestic mosaic will paste or net pastes and reach into the connection purpose by paper, and the tackiness agent that uses is white glue with vinyl mostly, water-fast weather-proof, weather resistance is not good enough.White glue with vinyl own or other existing tackiness agent can not reach the purpose that connects into connection, realize integrated connection by kraft paper, plastic wire or glass fiber mesh.Tackiness agent own just plays the effect of bonding mosaic block and base material (kraft paper, plastic wire or glass fiber mesh).It is that first-generation mosaic becomes the connection technology that paper pastes mosaic, and it is that s-generation mosaic becomes the connection technology that net pastes mosaic, and there are many deficiencies in the tackiness agent in upper two generations:
(1) in upper two generations, become the coupling tackiness agent, cannot make separately the direct Cheng Lian of mosaic, just can Cheng Lian by papery or silk screen base material, and tackiness agent just plays bonding effect (mosaic is in the same place with substrate bonding).
(2) upper two generation the tackiness agent water tolerance bad, common water tolerance, in boiling water (under the standard environment 100 ℃), lost cementability in 5～10 minutes or bonding strength obviously decays, under room temperature state, wet-heat resisting, moisture resistance is bad, and is higher for the mosaic storage request of Cheng Lianhou, and mosaic particle detachment phenomenon occurs easily.
(3) upper two generation tackiness agent for after the mosaic Cheng Lian, have a strong impact on the construction effect of mosaic.First-generation paper pastes mosaic, when the buildings such as decorated wall surface, must before smearing, remove gap-filling glue the front paper substrates, this moment mosaic particle and cement or the bonding solid state that do not reach of glue for tile, extracted by paper substrates easily, have a strong impact on construction effect and quality, the while paper substrates absorbs easily moisture and shrinkage phenomenon occurs, cause mosaic particle slit uneven, also have a strong impact on decorative effect and construction speed.S-generation net pastes mosaic, because the mosaic back side will bond together with white glue with vinyl by plastic wire or glass fiber mesh, causes the mosaic back side to be coated with the white glue with vinyl of a large amount of areas, and fibrous reticulum and white glue with vinyl area are above 60%.Have a strong impact on the wetting contact of mosaic particle and cement or glue for tile, thus the bonding strength when impact is constructed.Cause mosaic to come off from metope or buildings easily, especially occur easily potential safety hazard during external decoration of high-rise building.
Summary of the invention
Primary and foremost purpose of the present invention is to provide a kind of base materials such as papery, silk screen that do not need, and have splendid water tolerance, and can improve the mosaic one-tenth connection tackiness agent of mosaic bonding strength, and its manufacture craft is provided, for achieving the above object, the technical solution used in the present invention is:
A kind of mosaic becomes coupling point glue adhesive agent, comprises by mass percentage: softening agent 20%～33%; Pvc resin paste grade 18%～33%; Solidifying agent 0.5%～2%; Blocked polyurethane performed polymer 1.0%～12%; Nano-calcium carbonate 6%～13%; Water-ground limestone 3%～16%; Calcite in powder 3%～23%; Coupling agent 0.1%～1%; Thermo-stabilizer 0.3%～4.5%; Water-removal agent 0.2%～6%; Thixotropic agent 0.4%～1.8%; Thinner 0%～2%.
Preferably, mosaic becomes the connection tackiness agent to comprise by mass percentage: softening agent 22%～31%; Pvc resin paste grade 22%～30%; Solidifying agent 1.2%～1.8%; Blocked polyurethane performed polymer 5%～9%; Nano-calcium carbonate 10%～12%; Water-ground limestone 5%～8%; Calcite in powder 11%～18%; Coupling agent 0.3%～0.6%; Thermo-stabilizer 0.6%～3.2%; Water-removal agent 1.6%～4%; Thixotropic agent 0.8%～1.4%; Thinner 0%～2%.
Preferably, described softening agent is dibutyl phthalate, dioctyl phthalate (DOP), butyl benzyl phthalate, Di Iso Decyl Phthalate. diisononyl phthalate, phthalic acid two (2-ethylhexyl) ester, diethyl phthalate, dipropyl phthalate, diisopropyl phthalate, diisobutyl phthalate, Octyl adipate, dioctyl azelate, dioctyl sebacate, diamyl phthalate, dinoctyl phthalate, dimethyl phthalate, epoxy soybean oil, the epoxy Toenol 1140, the epoxyoleic acid butyl ester, octyl epoxy stearate, the epoxidation tri-glyceride, the epoxy tetrahydro-2-ethylhexyl phthalate, dihexyl phthalate, dicyclohexyl phthalate, trioctyl trimellitate, the own ester of tri trimellitate, pyromellitic acid four ester dimixo-octyl phthalates, 2-nonyl-phthalate ester, the hexanodioic acid propanediol polyester, the sebacic acid propanediol polyester, phthalic acid polyester, Vanay, the glycol ether benzoic ether, clorafin, methyl pentachlorostearate wherein two or three.
Preferably, described pvc resin paste grade is K value scope at 60～90 homopolymerization pvc resin paste grade, K value scope at 60～90 copolymerization pvc resin paste grade, one or both in the blending pvc resin paste grade.
Preferably, described solidifying agent is a kind of in the TDI-TMP affixture that makes of tolylene diisocyanate and TriMethylolPropane(TMP) reaction, hexamethylene diisocyanate (HDI) biuret, hexamethylene diisocyanate (HDI) tripolymer, toluene diisocyanate trimer, isophorone diisocyanate trimer, castor oil polyhydric alcohol diisocyanate prepolymer, Abietyl modified Viscotrol C glyceryl alcohol type (TDI) prepolymer, the Versamid.
Preferably, described blocked polyurethane performed polymer is 3, a kind of in hexamethylene diisocyanate (HDI) the tripolymer performed polymer of hexamethylene diisocyanate (HDI) the tripolymer performed polymer of hexamethylene diisocyanate (HDI) performed polymer of 5-dimethyl pyrazole end-blocking, 3，5-dimethylpyrazole end-blocking, hexamethylene diisocyanate (HDI) performed polymer of methyl ethyl ketoxime end-blocking, methyl ethyl ketoxime end-blocking, the tolylene diisocyanate performed polymer of methyl ethyl ketoxime end-blocking.
Preferably, described coupling agent is γ-aminopropyl triethoxysilane, γ-(2, the 3-glycidoxy) a kind of in propyl trimethoxy silicane, γ-mercaptopropyl trimethoxysilane, two-(γ-triethoxyl silane propyl group) tetrasulfide, γ-diethylenetriamine base propyl-triethoxysilicane, anilinomethyl trimethoxy silane, β-(3,4-epoxycyclohexyl) ethyl trimethoxy silane.
Preferably, described thermo-stabilizer is one or both in zinc oxide, stearate acid calcium, Zinic stearas, dibutyl tin laurate, dibutyl tin laurate mixture, Bis(lauroyloxy)dioctyltin, maleic acid ester butyl tin, maleic acid ester tin octylate, mercaptan butyl mixture, mercapto machine 2-ethyl hexyl ethanoate one/dibutyl tin, dibutyltin oxide (Dibutyltin oxide), the monobutyltin oxide.
Preferably, described water-removal agent be in monocycle oxazolidine, bicyclo oxazolidine, calcium oxide, the p-methylphenyl sulfonyl isocyanate one or both.
Preferably, described thixotropic agent is a kind of in wilkinite, organobentonite, white rouge aerogel, the aerosil.
Preferably, described thinner is a kind of in diethylene glycol dimethyl ether, methyl aceto acetate, solvent kerosene, the glycol dimethyl ether.
And a kind of mosaic becomes the manufacture craft of coupling point glue adhesive agent, may further comprise the steps:
Accurately taking by weighing softening agent, solidifying agent, coupling agent, thermo-stabilizer, water-removal agent and thixotropic agent mixes;
Add nano-calcium carbonate, water-ground limestone, calcite in powder control temperature 30 ℃ of following dispersing and mixing one hour;
Add pvc resin paste grade, blocked polyurethane performed polymer control temperature 30 ℃ of following dispersing and mixing one hour;
Mix rear placement stable slaking in 24 hours;
Add thinner adjusting viscosity state, the discharging packing.
Mosaic provided by the invention becomes connection tackiness agent and manufacture craft thereof to have following characteristics:
(1) tackiness agent of the present invention can use separately, makes mosaic Cheng Lian, does not need the base materials such as papery, silk screen.
(2) tackiness agent of the present invention has splendid water tolerance, water tolerance be front two generation mosaic become 60 to 120 times of coupling white glue with vinyl, can keep good cohesive force in 10 hours in the boiling water.This tackiness agent has good weathering resistance, solvent resistance, resistance to acids and bases simultaneously.To the mosaic storage condition require far below front two generation mosaic become the coupling white glue with vinyl, and guarantee that the mosaic particle does not come off.
By the bonding mosaic back side very small area and very little facade area, the assurance mosaic back side has 92% adhesive-free area when (3) becoming the connection mosaic owing to this tackiness agent of use.Therefore the front need not paper substrates, can not occur not removing front base material operation when paper substrates makes moist the phenomenon of shrinking and construction, has improved operating efficiency and quality, the shortcoming that also can not exist the mosaic particle to extract.Guarantee the mosaic particle back side 92% glue-free area when this tackiness agent is bonding simultaneously, therefore also do not exist s-generation net subsides mosaic fibrous reticulum and white glue with vinyl area to surpass 60%.Have a strong impact on the wetting contact of mosaic particle and cement or glue for tile, thus the bonding strength when impact is constructed.The phenomenon that causes mosaic to come off from metope or buildings easily.
(4) shape that this tackiness agent can the arbitrary combination mosaic, and the mixed bonding Cheng Lian that takes of unlike material mosaic.Simultaneously bonding strength be higher than front two generation the mosaic tackiness agent
(5) the mosaic particle gap of this tackiness agent Cheng Lianhou can not change, and guarantees the aesthetics of mosaic.This be since tackiness agent of the present invention have fabulous water-fast, weather-proof, high strength, high tenacity, outstanding mosaic constancy.
(6) use of this tackiness agent can improve mosaic manufacturer efficient, and efficient doubles.Because this tackiness agent can be put gum forming or screen printing moulding by point gum machine, therefore improved the technique that domestic paper pasted and netted the manual pasting that pastes, production efficiency doubles.
Embodiment
The below will describe the present invention in detail by specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Mosaic provided by the invention becomes the connection adhesive components as follows:
1, softening agent: dibutyl phthalate, dioctyl phthalate (DOP), butyl benzyl phthalate, Di Iso Decyl Phthalate. diisononyl phthalate, phthalic acid two (2-ethylhexyl) ester, diethyl phthalate, dipropyl phthalate, diisopropyl phthalate, diisobutyl phthalate, Octyl adipate, dioctyl azelate, dioctyl sebacate, diamyl phthalate, dinoctyl phthalate, dimethyl phthalate, epoxy soybean oil, the epoxy Toenol 1140, the epoxyoleic acid butyl ester, octyl epoxy stearate, the epoxidation tri-glyceride, the epoxy tetrahydro-2-ethylhexyl phthalate, dihexyl phthalate, dicyclohexyl phthalate, trioctyl trimellitate, the own ester of tri trimellitate, pyromellitic acid four ester dimixo-octyl phthalates, 2-nonyl-phthalate ester, the hexanodioic acid propanediol polyester, the sebacic acid propanediol polyester, phthalic acid polyester, Vanay, the glycol ether benzoic ether, clorafin, methyl pentachlorostearate wherein two or three.Content range is 20%-33%, and optimized scope is 22%-31%.It is 20% less with respect to the pvc resin paste grade group component that content is lower than, and when the pvc resin paste grade component was lower than 18% situation and occurs simultaneously, one-tenth film toughness and the toughness of this tackiness agent reduce greatly, and was not good for independent connection mosaic particle performance.When plasticizer components content surpasses 33%, the pvc resin paste grade component is too much relatively, and simultaneously the pvc resin paste grade component is 18% or when being lower than 18%, the serious superfluous cementability that affects this tackiness agent and mosaic of plasticizer components, the pvc resin paste grade component reaches 33% or when surpassing 33%, force of cohesion is greater than mosaic bonding interface power after the tackiness agent film forming, and this moment, adhesiveproperties was also bad.
2, pvc resin paste grade: K value scope at 60～90 homopolymerization pvc resin paste grade, K value scope at 60～90 copolymerization pvc resin paste grade, one or both in the blending pvc resin paste grade.Optimum is one or both in homopolymerization pvc resin paste grade (K value scope is at 65-70), the copolymerization pvc resin paste grade (K value scope is at 65-80), content range 18%-33%, optimized scope 22%-30%.The adhesive solidification film forming was not fine and close when content was lower than 18%, caused water tolerance to descend, and this moment, the intensity of glue was also lower, was not suitable for mosaic Cheng Lian.When content greater than 33% the time, can cause the adhesive solidification film forming after toughness descend, also be not suitable for and mosaic Cheng Lian.
3, solidifying agent: a kind of in the TDI-TMP affixture that the reaction of tolylene diisocyanate and TriMethylolPropane(TMP) makes, hexamethylene diisocyanate (HDI) biuret, hexamethylene diisocyanate (HDI) tripolymer, toluene diisocyanate trimer, isophorone diisocyanate trimer, castor oil polyhydric alcohol diisocyanate prepolymer, Abietyl modified Viscotrol C glyceryl alcohol type (TDI) prepolymer, the Versamid.Content range 0.5%-2%, optimum content range 1.2%-1.8%, content is lower than 0.5% and causes the curing of blocked polyurethane performed polymer component incomplete, be unfavorable for that mosaic becomes connection bonding, when the content that surpasses 2%, it is too fast to cause blocked polyurethane performed polymer component to be solidified, and is unfavorable for the toughness of tackiness agent, causes toughness to descend.
4, blocked polyurethane performed polymer: 3, a kind of in hexamethylene diisocyanate (HDI) the tripolymer performed polymer of hexamethylene diisocyanate (HDI) the tripolymer performed polymer of hexamethylene diisocyanate (HDI) performed polymer of 5-dimethyl pyrazole end-blocking, 3，5-dimethylpyrazole end-blocking, hexamethylene diisocyanate (HDI) performed polymer of methyl ethyl ketoxime end-blocking, methyl ethyl ketoxime end-blocking, the tolylene diisocyanate performed polymer of methyl ethyl ketoxime end-blocking.Content range 1.0%-12%, optimized scope 5%-9%.This component plays bonding effect, and when content was lower than 1.0%, bonding force was not good, and when content was higher than 12%, the manufacturing cost of tackiness agent was too high.
5, nano-calcium carbonate: content range 6%-13%, optimized scope 10%-12%.
6, water-ground limestone: content range 3%-16%, optimized scope 5%-8%.
7, calcite in powder: content range 3%-23%, optimized scope 11%-18%.
5,6,7 three components play modifying function, and consumption too much affects intensity and the toughness of tackiness agent, the very few rising that also can cause manufacturing cost of consumption simultaneously.
8, coupling agent: γ-aminopropyl triethoxysilane, γ-(2, the 3-glycidoxy) a kind of in propyl trimethoxy silicane, γ-mercaptopropyl trimethoxysilane, two-(γ-triethoxyl silane propyl group) tetrasulfide, γ-diethylenetriamine base propyl-triethoxysilicane, anilinomethyl trimethoxy silane, β-(3,4-epoxycyclohexyl) ethyl trimethoxy silane.Content range 0.1%-1%, optimized scope 0.3%-0.6%.Water tolerance when content is lower than 0.1% behind the adhesive solidification is bad, can affect the compactness of glued membrane when being higher than 1% during baking-curing, and is same influential to the water tolerance of glue.
9, thermo-stabilizer: one or both in zinc oxide, stearate acid calcium, Zinic stearas, dibutyl tin laurate, dibutyl tin laurate mixture, Bis(lauroyloxy)dioctyltin, maleic acid ester butyl tin, maleic acid ester tin octylate, mercaptan butyl mixture, mercapto machine 2-ethyl hexyl ethanoate one/dibutyl tin, dibutyltin oxide (Dibutyltin oxide), the monobutyltin oxide.Content comprises 0.3%-4.5%, optimized scope 0.6%-3.2%.Content toasts heat-resisting capacity of decomposition and descends when being lower than 0.3% glue film forming, excessive little to the heat decomposition resistance lifting when being higher than 4.5% content, causes the waste of thermo-stabilizer.
10, water-removal agent: in monocycle oxazolidine, bicyclo oxazolidine, calcium oxide, the p-methylphenyl sulfonyl isocyanate one or both.Content range 0.2%-6%, optimized scope 1.6%-4%.Water removal effect was bad when water-removal agent was lower than 0.2%, also had moisture entrapment, affected curing and the storage of glue.Greater than 6% the time, when storing, cause again the very easily moisture in the absorbing air of glue, affect equally curing and the storage of glue.
11, thixotropic agent: a kind of in wilkinite, organobentonite, white rouge aerogel, the aerosil.Content range 0.4%-1.8%, optimized scope 0.8%-1.4%.The thixotroping ability of glue was bad when thixotropic agent was lower than 0.4%, trickled easily during baking, and glue is from the trickling of particle gap to positive when causing mosaic to become connection, and it is attractive in appearance to affect the Marseille.Addition tackiness agent viscosity greater than 1.8% time is too high, is unfavorable for a glue or brush application.
12, thinner: a kind of in diethylene glycol dimethyl ether, methyl aceto acetate, solvent kerosene, the glycol dimethyl ether.Content range 0%-2%.
In the said components:
1,2 components mainly play filming function, can make this tackiness agent reach the effect of independent connection mosaic.
3,4 components play bonding effect, make this tackiness agent can be bonding mosaic surface (back side), play the attaching surface effect.
5,6,7 components play the Modification effect, and purpose makes this tackiness agent reach certain degree of hardness, intensity, plays simultaneously the effect that reduces the cost.
8 components play the increase water tolerance, improve simultaneously cohesive force.
9 components play and improve polyvinyl chloride heat resistanceheat resistant degradation property, guarantee the mechanical property of glued membrane.
10 components play removes the micro-moisture that contains in above-mentioned each material, guarantees the stability in storage of tackiness agent.
11 components play the heat resistanceheat resistant flow of regulating tackiness agent.
12 components play the viscosity of regulating tackiness agent, improve the workability of tackiness agent.
Embodiment 1
Prescription one (the prescription total mass is 100g)
(1) softening agent: dibutyl phthalate content 5g, dioctyl phthalate (DOP) 12g, Octyl adipate 10g
(2) pvc resin paste grade: homopolymerization pvc resin paste grade (the K value is 70) 12g
Copolymerization pvc resin paste grade (the K value is 75) 13g
(3) solidifying agent: hexamethylene diisocyanate (HDI) tripolymer 1.5g
(4) blocked polyurethane performed polymer: the tolylene diisocyanate performed polymer 5.0g of methyl ethyl ketoxime end-blocking
(5) nano-calcium carbonate: 10g
(6) water-ground limestone: 8g
(7) calcite in powder: 18g
(8) coupling agent: γ-(2,3-glycidoxy) propyl trimethoxy silicane 0.5g
(9) thermo-stabilizer: zinc oxide 0.6g, dibutyl tin laurate 1.0g
(10) water-removal agent: bicyclo oxazolidine 0.2g, calcium oxide 1.0g
(11) thixotropic agent: aerosil 1.2g
(12) thinner: solvent kerosene 1.0g
After this formulation examples was even by dispersing and mixing, slaking was after 24 hours, and bonding mosaic becomes the connection mosaic to be of a size of 300mm*300mm, and the mosaic particle is that ceramic mosaic is of a size of 47mm*47mm, and detected result is:
Satisfy mosaic from above-mentioned detected result and become the connection requirement.
Embodiment 2
Prescription two (the prescription total mass is 100g)
(1) softening agent: butyl benzyl phthalate 10g, Di Iso Decyl Phthalate 5g,
Octyl adipate 7g;
(2) pvc resin paste grade: homopolymerization pvc resin paste grade (the K value is 75) 18g
(3) solidifying agent: the TDI-TMP affixture 1.2g that tolylene diisocyanate and TriMethylolPropane(TMP) reaction make
(4) blocked polyurethane performed polymer: the hexamethylene diisocyanate of 3，5-dimethylpyrazole end-blocking (HDI) tripolymer performed polymer 6g
(5) nano-calcium carbonate: 13g
(6) water-ground limestone: 12g
(7) calcite in powder: 23g
(8) coupling agent: γ-aminopropyl triethoxysilane 0.3g
(9) thermo-stabilizer: maleic acid ester butyl tin 1.2g
(10) water-removal agent: calcium oxide 2.0g
(11) thixotropic agent: aerosil 1.3g
(12) thinner: 0g
After this formulation examples was even by dispersing and mixing, slaking was after 24 hours, and bonding mosaic becomes the connection mosaic to be of a size of 300mm*300mm, and the mosaic particle is that ceramic mosaic is of a size of 47mm*47mm, and detected result is:
Satisfy mosaic from above-mentioned detected result and become the connection requirement.
Embodiment 3
Prescription three (the prescription total mass is 100g)
(1) softening agent: epoxy soybean oil 8g, butyl benzyl phthalate 15g, dioctyl phthalate (DOP) 8g
(2) pvc resin paste grade: copolymerization pvc resin paste grade 30g
(3) solidifying agent: hexamethylene diisocyanate (HDI) biuret 1.8g
(4) blocked polyurethane performed polymer: the hexamethylene diisocyanate of 3，5-dimethylpyrazole end-blocking (HDI) performed polymer 9g
(5) nano-calcium carbonate: 10g
(6) water-ground limestone: 3g
(7) calcite in powder: 4g
(8) coupling agent: γ-(2,3-glycidoxy) propyl trimethoxy silicane 0.6g
(9) thermo-stabilizer: zinc oxide 1.2g
Dibutyltin oxide (Dibutyltin oxide) 2.0g
(10) water-removal agent: calcium oxide 5g, p-methylphenyl sulfonyl isocyanate 1.0g
(11) thixotropic agent: aerosil 1.4g
(12) thinner: 0g
After this formulation examples was even by dispersing and mixing, slaking was after 24 hours, and bonding mosaic becomes the connection mosaic to be of a size of 300mm*300mm, and the mosaic particle is that ceramic mosaic is of a size of 47mm*47mm, and detected result is:
Satisfy mosaic from above-mentioned detected result and become the connection requirement.
Embodiment 4
A kind of mosaic becomes the manufacture craft of connection tackiness agent, may further comprise the steps:
1, accurately taking by weighing softening agent, solidifying agent, coupling agent, thermo-stabilizer, water-removal agent and thixotropic agent mixes;
2, add nano-calcium carbonate, water-ground limestone, calcite in powder control temperature 30 ℃ of following dispersing and mixing one hour;
3, add pvc resin paste grade, blocked polyurethane performed polymer control temperature 30 ℃ of following dispersing and mixing one hour;
4, mix rear placement stable slaking in 24 hours;
5, add thinner adjusting viscosity state, the discharging packing.
More than technical scheme that the embodiment of the invention is provided be described in detail, used specific case herein principle and the embodiment of the embodiment of the invention are set forth, the explanation of above embodiment is only applicable to help to understand the principle of the embodiment of the invention; Simultaneously, for one of ordinary skill in the art, according to the embodiment of the invention, all will change on embodiment and range of application, in sum, this description should not be construed as limitation of the present invention.
Claims (12)
1. a mosaic becomes coupling point glue adhesive agent, it is characterized in that comprising by mass percentage:
Softening agent 20%～33%; Pvc resin paste grade 18%～33%;
Solidifying agent 0.5%～2%; Blocked polyurethane performed polymer 1.0%～12%;
Nano-calcium carbonate 6%～13%; Water-ground limestone 3%～16%;
Calcite in powder 3%～23%; Coupling agent 0.1%～1%;
Thermo-stabilizer 0.3%～4.5%; Water-removal agent 0.2%～6%;
Thixotropic agent 0.4%～1.8%; Thinner 0%～2%.
2. mosaic according to claim 1 becomes coupling point glue adhesive agent, it is characterized in that comprising by mass percentage:
Softening agent 22%～31%; Pvc resin paste grade 22%～30%;
Solidifying agent 1.2%～1.8%; Blocked polyurethane performed polymer 5%～9%;
Nano-calcium carbonate 10%～12%; Water-ground limestone 5%～8%;
Calcite in powder 11%～18%; Coupling agent 0.3%～0.6%;
Thermo-stabilizer 0.6%～3.2%; Water-removal agent 1.6%～4%;
Thixotropic agent 0.8%～1.4%; Thinner 0%～2%.
3. mosaic according to claim 1 becomes coupling point glue adhesive agent, it is characterized in that:
Described softening agent is dibutyl phthalate, dioctyl phthalate (DOP), butyl benzyl phthalate, Di Iso Decyl Phthalate. diisononyl phthalate, phthalic acid two (2-ethylhexyl) ester, diethyl phthalate, dipropyl phthalate, diisopropyl phthalate, diisobutyl phthalate, Octyl adipate, dioctyl azelate, dioctyl sebacate, diamyl phthalate, dinoctyl phthalate, dimethyl phthalate, epoxy soybean oil, the epoxy Toenol 1140, the epoxyoleic acid butyl ester, octyl epoxy stearate, the epoxidation tri-glyceride, the epoxy tetrahydro-2-ethylhexyl phthalate, dihexyl phthalate, dicyclohexyl phthalate, trioctyl trimellitate, the own ester of tri trimellitate, pyromellitic acid four ester dimixo-octyl phthalates, 2-nonyl-phthalate ester, the hexanodioic acid propanediol polyester, the sebacic acid propanediol polyester, phthalic acid polyester, Vanay, the glycol ether benzoic ether, clorafin, methyl pentachlorostearate wherein two or three.
4. mosaic according to claim 1 becomes coupling point glue adhesive agent, it is characterized in that:
Described pvc resin paste grade is K value scope at 60～90 homopolymerization pvc resin paste grade, K value scope at 60～90 copolymerization pvc resin paste grade, one or both in the blending pvc resin paste grade.
5. mosaic according to claim 1 becomes coupling point glue adhesive agent, it is characterized in that:
Described solidifying agent is a kind of in the TDI-TMP affixture that makes of tolylene diisocyanate and TriMethylolPropane(TMP) reaction, hexamethylene diisocyanate (HDI) biuret, hexamethylene diisocyanate (HDI) tripolymer, toluene diisocyanate trimer, isophorone diisocyanate trimer, castor oil polyhydric alcohol diisocyanate prepolymer, Abietyl modified Viscotrol C glyceryl alcohol type (TDI) prepolymer, the Versamid.
6. mosaic according to claim 1 becomes coupling point glue adhesive agent, it is characterized in that:
Described blocked polyurethane performed polymer is 3, a kind of in hexamethylene diisocyanate (HDI) the tripolymer performed polymer of hexamethylene diisocyanate (HDI) the tripolymer performed polymer of hexamethylene diisocyanate (HDI) performed polymer of 5-dimethyl pyrazole end-blocking, 3，5-dimethylpyrazole end-blocking, hexamethylene diisocyanate (HDI) performed polymer of methyl ethyl ketoxime end-blocking, methyl ethyl ketoxime end-blocking, the tolylene diisocyanate performed polymer of methyl ethyl ketoxime end-blocking.
7. mosaic according to claim 1 becomes coupling point glue adhesive agent, it is characterized in that:
Described coupling agent is γ-aminopropyl triethoxysilane, γ-(2, the 3-glycidoxy) a kind of in propyl trimethoxy silicane, γ-mercaptopropyl trimethoxysilane, two-(γ-triethoxyl silane propyl group) tetrasulfide, γ-diethylenetriamine base propyl-triethoxysilicane, anilinomethyl trimethoxy silane, β-(3,4-epoxycyclohexyl) ethyl trimethoxy silane.
8. mosaic according to claim 1 becomes coupling point glue adhesive agent, it is characterized in that:
Described thermo-stabilizer is one or both in zinc oxide, stearate acid calcium, Zinic stearas, dibutyl tin laurate, dibutyl tin laurate mixture, Bis(lauroyloxy)dioctyltin, maleic acid ester butyl tin, maleic acid ester tin octylate, mercaptan butyl mixture, mercapto machine 2-ethyl hexyl ethanoate one/dibutyl tin, dibutyltin oxide (Dibutyltin oxide), the monobutyltin oxide.
9. mosaic according to claim 1 becomes coupling point glue adhesive agent, it is characterized in that:
Described water-removal agent be in monocycle oxazolidine, bicyclo oxazolidine, calcium oxide, the p-methylphenyl sulfonyl isocyanate one or both.
10. mosaic according to claim 1 becomes coupling point glue adhesive agent, it is characterized in that:
Described thixotropic agent is a kind of in wilkinite, organobentonite, white rouge aerogel, the aerosil.
11. mosaic according to claim 1 becomes coupling point glue adhesive agent, it is characterized in that:
Described thinner is a kind of in diethylene glycol dimethyl ether, methyl aceto acetate, solvent kerosene, the glycol dimethyl ether.
12. a mosaic becomes the manufacture craft of coupling point glue adhesive agent, it is characterized in that may further comprise the steps:
Accurately taking by weighing softening agent, solidifying agent, coupling agent, thermo-stabilizer, water-removal agent and thixotropic agent mixes;
Add nano-calcium carbonate, water-ground limestone, calcite in powder control temperature 30 ℃ of following dispersing and mixing one hour;
Add pvc resin paste grade, blocked polyurethane performed polymer control temperature 30 ℃ of following dispersing and mixing one hour;
Mix rear placement stable slaking in 24 hours;
Add thinner adjusting viscosity state, the discharging packing.
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| CN104004474A (en) * | 2014-05-26 | 2014-08-27 | 芜湖市华泰实业有限公司 | Filter element adhesive for filter element connection |
| CN106118549A (en) * | 2016-07-21 | 2016-11-16 | 柳州市五源科技有限公司 | Solid gum |
| CN107699162A (en) * | 2017-09-08 | 2018-02-16 | 张家港爱科思汽车配件有限公司 | A kind of weld seam glue |
| CN110511717A (en) * | 2019-10-12 | 2019-11-29 | 广东莱尔新材料科技股份有限公司 | A kind of wafer with protection film adhesive and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104004474A (en) * | 2014-05-26 | 2014-08-27 | 芜湖市华泰实业有限公司 | Filter element adhesive for filter element connection |
| CN106118549A (en) * | 2016-07-21 | 2016-11-16 | 柳州市五源科技有限公司 | Solid gum |
| CN107699162A (en) * | 2017-09-08 | 2018-02-16 | 张家港爱科思汽车配件有限公司 | A kind of weld seam glue |
| CN110511717A (en) * | 2019-10-12 | 2019-11-29 | 广东莱尔新材料科技股份有限公司 | A kind of wafer with protection film adhesive and preparation method thereof |
| CN110511717B (en) * | 2019-10-12 | 2021-05-04 | 广东莱尔新材料科技股份有限公司 | Adhesive for wafer protective film and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103374314B (en) | 2015-06-10 |
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