CN103367250A - Segmenting method of device wafer - Google Patents
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Abstract
本发明提供一种器件晶片的分割方法,当通过扩张延展片而将内部形成有改性层的器件晶片以改性层为起点分割为多个器件时,能够减少器件品质的降低并且降低给后续工序带来障碍的可能。一种分割方法,在进行了将延展片粘贴于器件晶片(1)的背面(1b)的粘贴步骤、和沿着分割预定线(2)照射具有透射性的波长的激光光束(L)以在器件晶片内形成改性层(1c)的改性层形成步骤后,具有扩张延展片(11)以改性层为起点将器件晶片分割为一个个器件(3)的分割步骤,在该分割方法中,具有在进行分割步骤前用水溶性的保护膜(5)覆盖器件晶片的表面(1a)的保护膜覆盖步骤,在分割步骤后还具有通过清洗来去除保护膜的保护膜去除步骤。
The invention provides a method for dividing a device wafer. When a device wafer with a modified layer formed inside is divided into multiple devices starting from the modified layer by expanding the extended sheet, it can reduce the degradation of device quality and reduce the cost to subsequent devices. The process may cause obstacles. A division method, after performing a sticking step of sticking a spread sheet to the back surface (1b) of a device wafer (1), and irradiating a laser beam (L) having a transmittance wavelength along a line to be divided (2) to After the modified layer forming step of forming the modified layer (1c) in the device wafer, there is a division step of dividing the device wafer into individual devices (3) with the expansion sheet (11) starting from the modified layer. The method includes a protective film covering step of covering the surface (1a) of the device wafer with a water-soluble protective film (5) before the dividing step, and a protective film removing step of removing the protective film by cleaning after the dividing step.
Description
技术领域technical field
本发明涉及在用交叉的多条分割预定线划分出的各区域形成有器件的器件晶片的分割方法。The present invention relates to a method for dividing a device wafer in which devices are formed in regions divided by a plurality of intersecting dividing lines.
背景技术Background technique
例如半导体器件是通过这样的工艺制造的:通过格子状的分割预定线在由硅或砷化镓等半导体构成的晶片表面划分出多个矩形的器件区域,在这些器件区域形成具有由IC(Integrated circuit,集成电路)或LSI(Large Scale Integration,大规模集成电路)等构成的电子电路的器件,接下来,实施了磨削晶片的背面以将晶片薄化为预定厚度等预定的处理后,将晶片分割为一个个器件。分割这种器件晶片一般是用切割刀片来切断器件晶片的方法,但是近年也采用了这样的激光加工方法:对器件晶片照射具有透射性的波长的激光光束而在内部形成了改性层后,对器件晶片施加外力从而以改性层为起点割断器件晶片来进行分割(专利文献1等)。For example, semiconductor devices are manufactured through such a process: a plurality of rectangular device regions are divided on the surface of a wafer made of semiconductors such as silicon or gallium arsenide through grid-shaped dividing lines, and devices with IC (Integrated IC) are formed in these device regions. circuit, integrated circuit) or LSI (Large Scale Integration, large-scale integrated circuit) and other electronic circuit devices, then, after performing predetermined processing such as grinding the back of the wafer to thin the wafer to a predetermined thickness, the Wafers are separated into individual devices. Separation of such a device wafer is generally performed by cutting the device wafer with a dicing blade. However, in recent years, a laser processing method has also been adopted in which a modified layer is formed inside the device wafer by irradiating it with a laser beam having a wavelength that is transparent. The device wafer is divided by applying an external force to the device wafer starting from the reformed layer (
现有技术文献prior art literature
专利文献1:日本特开2009-277778号公报Patent Document 1: Japanese Patent Laid-Open No. 2009-277778
发明内容Contents of the invention
然而,在如上所述分割了器件晶片时,有从分割面产生分割屑的情况,当该分割屑附着于器件,会使器件品质降低,而且导致以下问题:在后续工序的焊接(bonding,结合)或包装(packaging)中带来障碍。However, when the device wafer is divided as described above, there are cases where slitting chips are generated from the slicing surface. When the slitting chips adhere to the device, the quality of the device will be reduced, and the following problems will be caused: welding (bonding, combining) in the subsequent process. ) or packaging (packaging) to bring obstacles.
本发明是鉴于上述事情而做出的发明,其主要技术课题是提供一种分割方法,当通过扩张延展片而将内部形成有改性层的器件晶片以改性层为起点分割为多个器件时,能够减少器件品质降低并且减少给后续工序带来障碍的可能。The present invention was made in view of the above, and its main technical task is to provide a method for dividing a device wafer having a modified layer formed therein into a plurality of devices by expanding a stretched sheet. , it is possible to reduce the degradation of device quality and reduce the possibility of causing obstacles to subsequent processes.
本发明器件晶片的分割方法是是在用交叉的多条分割预定线划分出的各区域形成有器件的器件晶片的分割方法,其特征在于,具有:粘贴步骤,将器件晶片的背面粘贴于延展片;改性层形成步骤,在实施该粘贴步骤前或实施该粘贴步骤后,沿着器件晶片的分割预定线对器件晶片照射相对于器件晶片具有透射性的波长的激光光束,在器件晶片形成沿着该分割预定线的改性层;以及分割步骤,在实施了上述粘贴步骤和上述改性层形成步骤后,通过扩张粘贴有器件晶片的上述延展片来对器件晶片施加外力,从而以上述改性层为起点沿着上述分割预定线来分割器件晶片,上述器件晶片的分割方法还具有:保护膜覆盖步骤,至少在实施上述分割步骤前,用水溶性的保护膜覆盖器件晶片的表面;以及保护膜去除步骤,在实施了上述分割步骤后,通过清洗去除上述保护膜。The method for dividing a device wafer of the present invention is a method for dividing a device wafer in which devices are formed in each area divided by a plurality of intersecting predetermined dividing lines, and is characterized in that it has: a sticking step, sticking the back surface of the device wafer on an extended sheet; modified layer forming step, before implementing the pasting step or after implementing the pasting step, the device wafer is irradiated with a laser beam of a wavelength that is transmissive relative to the device wafer along the planned division line of the device wafer, and formed on the device wafer the modified layer along the dividing line; and a dividing step, after performing the above-mentioned pasting step and the above-mentioned modified layer forming step, applying an external force to the device wafer by expanding the above-mentioned extended sheet pasted with the device wafer, so that the above-mentioned The modified layer is used as a starting point to divide the device wafer along the above-mentioned predetermined division line, and the above-mentioned method for dividing the device wafer also includes: a protective film covering step, at least before implementing the above-mentioned dividing step, covering the surface of the device wafer with a water-soluble protective film; and In the protective film removal step, the protective film is removed by washing after the above-mentioned dividing step is performed.
本发明中,在实施分割步骤前在保护膜覆盖步骤中用水溶性的保护膜来覆盖器件晶片的表面,然后,通过分割步骤来分割器件晶片。因此,在分割步骤中产生的分割屑附着于保护膜,通过后面的保护膜去除步骤,分割屑与保护膜一起被去除。因此,能够减少器件品质的降低并且减少给后续工序带来障碍的可能。In the present invention, the surface of the device wafer is covered with a water-soluble protective film in the protective film covering step before the dividing step, and then the device wafer is divided by the dividing step. Therefore, the division chips generated in the division step are attached to the protective film, and the division chips are removed together with the protective film in the subsequent protective film removal step. Therefore, it is possible to reduce the degradation of device quality and reduce the possibility of causing troubles in subsequent processes.
根据本发明,具有提供如下的分割方法的效果:当通过扩张延展片而将内部形成有改性层的器件晶片以改性层为起点分割为多个器件时,能够减少器件品质的降低并且减少给后续工序带来障碍的可能。According to the present invention, there is an effect of providing a division method in which when a device wafer having a modified layer formed therein is divided into a plurality of devices starting from the modified layer by expanding the stretched sheet, it is possible to reduce degradation in device quality and reduce The possibility of bringing obstacles to the subsequent process.
附图说明Description of drawings
图1是表示本发明一实施方式的分割方法的粘贴步骤的立体图。FIG. 1 is a perspective view showing a pasting step of a division method according to an embodiment of the present invention.
图2是表示在上述粘贴步骤中将器件晶片的背面粘贴到带框架的延展片的状态的剖视图。Fig. 2 is a cross-sectional view showing a state where the back surface of the device wafer is bonded to the stretch sheet with a frame in the bonding step.
图3是表示适于实施一实施方式的分割方法的改性层形成步骤的激光加工装置的整体立体图。3 is an overall perspective view showing a laser processing apparatus suitable for carrying out a modified layer forming step of the division method according to one embodiment.
图4是表示进行上述改性层形成步骤的状态的侧视图。Fig. 4 is a side view showing a state in which the above-mentioned modified layer forming step is performed.
图5是表示上述改性层形成步骤的细节的剖视图。Fig. 5 is a cross-sectional view showing details of the modification layer forming step described above.
图6是表示通过膜形成装置来进行一实施方式的分割方法的保护膜覆盖步骤的状态的侧视图。6 is a side view showing a state where a protective film covering step of the dividing method according to one embodiment is performed by a film forming apparatus.
图7是表示通过上述保护膜覆盖步骤在器件晶片的表面覆盖了保护膜的状态的剖视图。7 is a cross-sectional view showing a state where the surface of the device wafer is covered with a protective film in the protective film covering step.
图8是表示一实施方式的分割方法的分割步骤的剖视图,(a)表示分割器件晶片前,(b)表示分割器件晶片后。8 is a cross-sectional view showing a dividing step of a dividing method according to an embodiment, (a) showing before dividing the device wafer, and (b) showing after dividing the device wafer.
图9是表示通过膜形成装置进行一实施方式的分割方法的保护膜去除步骤的状态的侧视图。9 is a side view showing a state in which a protective film removal step of the dividing method according to one embodiment is performed by a film forming apparatus.
图10是表示通过上述保护去除膜步骤从器件的表面去除了保护膜的状态的剖视图。FIG. 10 is a cross-sectional view showing a state where the protective film has been removed from the surface of the device by the protective film removing step described above.
标号说明Label description
1 器件晶片1 device wafer
1a 器件晶片的表面1a The surface of the device wafer
1b 器件晶片的背面1b The back side of the device wafer
1c 改性层1c modified layer
2 分割预定线2 split reservation line
3 器件(器件区域)3 Device (device area)
5 保护膜5 protective film
11 延展片11 extension piece
L 激光光束L laser beam
具体实施方式Detailed ways
以下,参照附图来对本发明的一实施方式进行说明。Hereinafter, an embodiment of the present invention will be described with reference to the drawings.
(1)器件晶片(1) Device wafer
图1和图2的标号1表示在一实施方式的分割方法中被分割的圆板状的器件晶片。该器件晶片1是以厚度为例如数百μm左右的半导体材料(硅或砷化镓等)为基板,通过格子状的分割预定线2在该器件晶片1的表面1a划分出多个矩形的器件区域3。并且在各器件区域3中形成有由IC或LSI等构成的电子电路。以下说明中将形成有电子电子电路的器件区域3简称为器件3。本实施方式是沿着分割预定线2分割器件晶片1,得到一个个器件3的方法,按照以下的步骤顺序进行。
首先,如图1和图2所示,将器件晶片1的背面与粘贴于环状框架10的延展片11粘贴,器件晶片1成为露出表面1a的状态(粘贴步骤)。延展片(expand sheet)11是在聚氯乙烯或聚烯烃等具有伸缩性的合成树脂片等基础材料的一面形成有树脂制的粘着层的片,框架10是由不锈钢板等具有刚性的金属板构成的框架。延展片11配设成覆盖在框架10内侧的空间,并经粘着层粘贴于框架10的一面(单面)。器件晶片1的背面1b以器件晶片1与框架10构成同心状的方式粘贴于延展片11的粘着层。在搬送时等隔着框架10和延展片11处理器件晶片1。First, as shown in FIGS. 1 and 2 , the back surface of the
接下来,在上述粘贴步骤后,沿着分割预定线2对器件晶片1照射具有透射性的波长的激光光束,在器件晶片1内形成沿着分割预定线2的改性层(改性层形成步骤)。改性层形成步骤能够通过图3所示的激光加工装置20来进行,以下,对激光加工装置20进行说明。Next, after the above-mentioned pasting step, the
(2)激光加工装置(2) Laser processing device
激光加工装置20具有基台21,在该基台21上设置有能够在水平的X轴方向和Y轴方向自如地移动的XY移动工作台22。在该XY移动工作台22设置有用于保持器件晶片1的卡盘工作台51。在卡盘工作台51的上方配设有用于朝向保持于卡盘工作台51的器件晶片1照射激光光束的激光照射构件60的照射部62,且照射部62配设为与卡盘工作台51对置的状态。The
XY移动工作台22由X轴基座30与的Y轴基座40的组合构成,所述X轴基座30能够在X轴方向上自如移动地设置在基台21上,所述Y轴基座40能够在Y轴方向上自如移动地设置在该X轴基座30上。X轴基座30能够自如滑动地安装于一对平行的导轨31,通过用马达32使滚珠丝杠(ball screw)33工作的X轴驱动机构34来使X轴基座30在X轴方向移动,所述一对平行的导轨31固定在基台21上且在X轴方向延伸。另一方面,Y轴基座40能够自如滑动地安装于一对平行的导轨41,通过用马达42使滚珠丝杠43工作的Y轴驱动机构44来使Y轴基座40在Y轴方向移动,上述一对平行的导轨41固定于X轴基座30上且在Y轴方向延伸。The XY mobile table 22 is composed of a combination of an
圆筒状的卡盘基座50支撑在Y轴基座40的上表面,并且能够以Z轴方向(上下方向)为旋转轴自如旋转,卡盘工作台51同心状地固定于该卡盘基座50上。卡盘工作台51是通过真空吸引作用吸附保持器件晶片1的一般众所周知的真空式卡盘工作台。卡盘工作台51通过未图示的旋转驱动构件被与卡盘基座50一体地旋转驱动。在卡盘工作台51的周围在互相分离180°的位置配设有一对夹紧器52,该一对夹紧器52能够自如装卸地保持上述框架10。该夹紧器52经支索(stay)(参照图4)53安装于卡盘基座50。The cylindrical chuck base 50 is supported on the upper surface of the Y-axis base 40, and can freely rotate around the Z-axis direction (up-down direction), and the chuck table 51 is concentrically fixed to the chuck base. Seat 50. The chuck table 51 is a generally well-known vacuum type chuck table that absorbs and holds the
在XY移动工作台22中,X轴基座30在X轴方向移动时为沿着器件晶片1的分割预定线2照射激光光束的加工进给。并且,通过Y轴基座40在Y轴方向移动,进行切换照射激光光束的对象分割预定线2的分度进给。另外,加工进给方向和分度进给方向也可以设定为相反,即,Y轴方向为加工进给方向,X轴方向为分度进给方向,没有限定。In the XY moving table 22 , when the
激光照射构件60具有朝向卡盘工作台51的上方沿Y轴方向延伸的长方体状的壳体61,在该壳体61的末端设置有上述照射部62。壳体61以能够沿着铅直方向(Z轴方向)上下移动的方式设置于柱23,该柱23立设于基台21,通过收纳于柱23内的未图示的上下驱动构件使壳体61上下移动。The
激光照射构件60的壳体61内收纳有:由YAG或YVO等脉冲激光器构成的振荡出激光光束的激光振荡单元、以及用于调整该激光光束的输出的输出调整单元等(省略图示),通过该激光振荡单元振荡出的激光光束从照射部62朝向下方照射。The
壳体61的末端的照射部62的附近,固定有用于检测器件晶片1的分割预定线2的校正(alignment)构件70。校正构件70具有用于拍摄器件晶片1的照相机71,校正构件70根据用照相机71获得的图像来检测(校正)分割预定线2。An
(3)改性层的形成(3) Formation of modified layer
以上是激光加工装置20的结构,利用该激光加工装置20如下所述地在器件晶片1的内部形成改性层。The above is the structure of the
首先,将器件晶片1经延展片11装载到激光加工装置20的卡盘工作台51,并利用真空吸引作用吸附保持于卡盘工作台51。器件晶片1在露出背面1b的状态下保持于卡盘工作台51上。另外,通过夹紧器52保持框架10。Firstly, the
然后,在通过校正构件70检测出分割预定线2的位置后,如图4和图5所示,针对器件晶片1,从激光照射构件60的照射部62使激光光束L的聚光点定位到器件晶片1的内部并沿着检测出的预定分割线2使激光光束L进行扫描。Then, after the position of the planned
激光光束L是相对于器件晶片1具有透射性的波长的脉冲激光,例如,为以下条件的激光光束。The laser beam L is a pulsed laser beam having a wavelength that is transparent to the
·波长:1064nm脉冲激光Wavelength: 1064nm pulsed laser
·重复频率:100kHz· Repetition frequency: 100kHz
·平均输出:1.5W· Average output: 1.5W
如图5所示,激光加工时的激光光束L从表面1a入射并聚光于器件晶片1内,由此,在器件晶片1的内部形成有沿着分割预定线2的改性层1c。改性层1c以一定的层厚形成于距离器件晶片1的表面1a一定深度的位置。改性层1c具有比器件晶片1内的其他部分强度低的特性。As shown in FIG. 5 , the laser beam L during laser processing is incident from the
通过使卡盘工作台51旋转来与加工进给平行地设定分割预定线2,并使卡盘工作台51在X轴方向移动的加工进给来利用激光加工装置20沿着分割预定线2进行激光光束的扫描。图4的箭头B是激光加工时卡盘工作台51的移动方向,照射部62随之在箭头A方向相对地进行加工进给。这时加工进给速度例如是400mm/s左右。另外,通过使卡盘工作台51在Y轴方向移动的分度进给来切换照射激光光束的分割预定线2。由此,在器件晶片1内形成有沿着所有的分割预定线2的改性层1c。By rotating the chuck table 51 to set the
通过以上结束针对器件晶片1的改性层形成步骤,接着将器件晶片1从激光加工装置20搬出,通过图6所示的膜形成装置80用水溶性的保护膜覆盖器件晶片1的表面1a(保护膜覆盖步骤)。以下,对膜形成装置80进行说明。The modified layer forming step for the
(4)膜形成装置(4) Film forming device
膜形成装置80是这样的形式的装置:从树脂供给喷嘴(nozzle)83向保持于装置壳体81内的圆板状的旋转工作台82上的器件晶片1的上表面即表面1a滴下液状树脂P,并实施旋转涂布。The
装置壳体81由向上开口且在中心形成有孔811a的圆筒状的壳体主体811、和堵塞壳体主体811的孔811a的罩812构成,马达84的驱动轴85从下方贯通罩812。旋转工作台82的中心固定于突出到装置壳体81内的驱动轴85的上端,被支撑成通过马达84的驱动能够水平旋转。The
器件晶片1经延展片11装载到旋转工作台82的上表面,并利用真空吸引作用吸附保持于旋转工作台82的上表面。在旋转工作台82的周缘部安装有多个离心夹紧器86,通过离心夹紧器86来保持框架10,通过旋转工作台82的旋转而产生离心力时,该多个离心夹紧器86以从上方按住框架10的方式工作。The
树脂供给喷嘴83能够回转地支撑在壳体主体811的底部,通过回转能够将末端的树脂供给口831定位于旋转工作台82的中心的正上方。另外,装置壳体81内具有清洗液供给喷嘴87,该清洗液喷嘴87和树脂供给喷嘴83是同样的结构并能够回转,从定位于旋转工作台82的中心的正上方的末端清洗液供给口871向下方供给清洗液W(参照图9)。The
(5)保护膜的形成(5) Formation of protective film
在保护膜覆盖步骤中,经延展片11将器件晶片1保持在旋转工作台82上,使旋转工作台82旋转驱动,用离心夹紧器86来保持框架10。然后,从树脂供给喷嘴83的树脂供给口831向自转状态的器件晶片1的表面1a的中心滴下树脂P。向表面1a滴下的树脂P通过离心力的作用旋转涂布于表面1a整个面,形成有如图7所示的树脂P制成的保护膜5。另外,在进行保护膜覆盖步骤时,清洗液供给喷嘴87退避至壳体主体811的内周面附近。In the protective film covering step, the
作为为了形成保护膜5而使用的水溶性树脂P,优选使用聚乙烯醇(polyvinylalcohol,PVA)、聚乙烯乙二醇(polyethylene glycol,PEG)、聚氧化乙烯(polyethyleneoxide,PEO)等水溶性涂层(resist)。As the water-soluble resin P used to form the
在器件晶片1的表面1a形成了预定膜厚(例如数μm左右)的保护膜5之后,结束保护膜覆盖步骤,从膜形成装置80搬走器件晶片1。然后,通过图8所示的扩展装置90来扩张延展片11,对器件晶片1施加外力,以改性层1c为起点沿着预定分割线2分割器件晶片1(分割步骤)。以下,对分割步骤中的器件晶片1的分割方法进行说明。After the
(6)器件晶片的分割(6) Segmentation of device wafers
扩展装置90具有用于装载器件晶片1的圆筒状的装载鼓轮(drum)91。在装载鼓轮91的周围与该装载鼓轮91同心状地配设有环状的保持工作台92,在保持工作台92设置有多个从上方按压保持框架10的可动夹紧器93。并且,保持工作台92为通过多个气缸(air cylinder)94被支撑为能够升降的结构。The
如图8的(a)所示,在分割步骤中,经延展片11将器件晶片1装载到扩展装置90的装载鼓轮91上,并且将框架10装载到上升的保持工作台92上,并通过可动夹紧器93从上按压保持框架10。在该安置状态下,延展片11以及器件晶片1是水平的,接下来,如图8的(b)所示,通过气缸94使保持工作台92下降。于是保持工作台92上的延展片11向放射方向扩张,以形成于器件晶片1内的改性层1c为起点来割断粘贴在延展片11上的器件晶片1。由此器件晶片1被分割为芯片状的多个器件3。As shown in (a) of FIG. 8 , in the dividing step, the
(7)保护膜的去除(7) Removal of protective film
将器件晶片1分割成一个个器件3后结束分割步骤,接下来,通过上述膜形成装置80来清洗去除保护膜5(保护膜去除步骤)。After the
在保护膜去除步骤中,如图9所示,将分割出的多个器件3为粘贴于延展片11的状态的器件晶片1再次安置于膜形成装置80,向器件晶片1的表面供给清洗液W。In the protective film removal step, as shown in FIG. 9 , the
供给清洗液W时,使树脂供给喷嘴83退避到壳体主体811的内周面附近,并且使清洗液供给喷嘴87回转将清洗液供给口871定位到旋转工作台82的中心的正上方。然后,一边从清洗液供给口871吐出清洗液W一边使旋转工作台82旋转。清洗液W被供给至自转状态的器件晶片1的中心,并通过离心力而遍布于器件晶片1的整个表面,水溶性的保护膜5被清洗液W熔化而去除。或者,还可以一边使清洗液供给喷嘴87往复回转一边供给清洗液W,这时由于直接向器件晶片1的整个表面供给清洗液W,所以能够高效去除保护膜5。由此,如图10所示去除覆盖各器件3的表面的保护膜5。When supplying the cleaning liquid W, the
从各器件3的表面去除了保护膜5后,结束保护膜去除步骤。然后,转移到从延展片11一个一个地剥离器件3并进行拾取的拾取步骤。After the
以上是本实施方式的分割方法,根据本实施方式,在实施分割步骤前在保护膜覆盖步骤中用水溶性的保护膜5来覆盖器件晶片1的表面1a,然后,通过分割步骤将器件晶片1分割为多个器件3。在分割步骤中存在从分割出的器件3的断裂面产生分割屑的情况,而该分割屑在没有保护膜5的情况下由于器件晶片1移动或产生静电而附着于器件晶片1的表面1a。但是,如本实施方式所述,若在器件晶片1的表面1a覆盖保护膜5,则分割屑附着于保护膜5上。然后,通过保护膜去除步骤去除保护膜5,由此附着于保护膜5上的分割屑随保护膜5一起被去除。因此,能够降低拾取后的器件3的品质受分割屑的影响而降低这样的不良情况,并且能够减少给后续工序带来障碍的可能。The above is the dividing method of the present embodiment. According to the present embodiment, the
另外,在上述实施方式中,按粘贴步骤、改性层形成步骤、保护膜覆盖步骤、分割步骤、以及保护膜去除步骤的顺序来进行本发明的各步骤,但是在本发明中粘贴步骤和改性层形成步骤的顺序是任意的,也可以与上述实施方式相反地在改性层形成步骤后进行粘贴步骤。另外,保护膜覆盖步骤也可以在粘贴步骤的前或后,或者改性层形成步骤前实施,但是优选在即将开始分割步骤之前实施。In addition, in the above-mentioned embodiment, each step of the present invention is performed in the order of the sticking step, the modified layer forming step, the protective film covering step, the dividing step, and the protective film removing step, but in the present invention, the sticking step and the modified The order of the permanent layer forming step is arbitrary, and the sticking step may be performed after the modifying layer forming step contrary to the above embodiment. In addition, the protective film covering step may be carried out before or after the pasting step, or before the modified layer forming step, but it is preferably carried out immediately before the dividing step.
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