CN103200927A - 水包油型乳化化妆品 - Google Patents
水包油型乳化化妆品 Download PDFInfo
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- CN103200927A CN103200927A CN2012800004317A CN201280000431A CN103200927A CN 103200927 A CN103200927 A CN 103200927A CN 2012800004317 A CN2012800004317 A CN 2012800004317A CN 201280000431 A CN201280000431 A CN 201280000431A CN 103200927 A CN103200927 A CN 103200927A
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Abstract
本发明提供紧致感优异、柔和度和保湿效果也优异的水包油型乳化化妆品。本发明的水包油型乳化化妆品的特征在于：含有以下的(A)～(F)成分，且(C)成分全量中非极性油分的混合量为30%以下。(A)0.1～5质量%的数均分子量为2000～3000的氢化聚异丁烯；(B)0.1～不足1质量%的高级醇；(C)1～25质量%的油性成分；(D)0.3～5质量%的表面活性剂；(E)0.05～5质量%的水溶性增稠剂；(F)水性成分。
Description
相关申请
本申请主张于2011年9月30日申请的日本国专利申请2011-217339号的优先权，其内容引用于此。
技术领域
本发明涉及水包油型乳化化妆品，特别是涉及紧致感优异、柔和度和保湿效果也优异的水包油型乳化化妆品。
背景技术
关于水包油型乳化化妆品，近年来人们要求其赋予肌肤紧致感(皮肤不松弛、不发胀、具有适度的弹力的使用感)。
以往，作为赋予紧致感的物质，使用高分子等。例如，已知通过将硬脂酸十八烷酯与氢化聚异丁烯等烃结合使用而具有紧致感的乳化化妆品(专利文献1)。但是，由于为了体现保湿效果或其他使用感而混合的保湿剂或油分的作用，有时紧致感会减弱。
已知混合有氢化聚异丁烯和特定量的高级醇的皮肤化妆品(专利文献2)。还已知混合有聚丁烯等高粘稠性油剂的水包油型乳化化妆品(专利文献3)。但上述化妆品在紧致感方面均无法满足要求。
现有技术文献
专利文献
专利文献1：日本特开2010-235472号公报；
专利文献2：日本特开2010-6726号公报；
专利文献3：日本特开2007-261971号公报。
发明内容
发明所要解决的课题
本发明鉴于上述现有技术课题而进行，其目的在于：提供紧致感优异、柔和度和保湿效果也优异的水包油型乳化化妆品。
解决课题的方法
本发明人等为了解决上述问题进行了深入研究，结果发现：通过混合特定量的氢化聚异丁烯和少量的高级醇，并制成水包油型乳化化妆品，可以兼具紧致感和柔和度，从而完成了本发明。
即，本发明的水包油型乳化化妆品，其特征在于：包含以下的(A)～(F)成分，且(C)成分总量中非极性油分的混合量为30%以下，
(A) 0.1～5质量%的数均分子量为2000～3000的氢化聚异丁烯；
(B) 0.1～不足1质量%的高级醇；
(C) 1～25质量%的油性成分；
(D) 0.3～5质量%的表面活性剂；
(E) 0.05～5质量%的水溶性增稠剂；
(F) 水性成分。
上述水包油型乳化化妆品优选25℃下的粘度为50000 mPa·s以下。
上述水包油型乳化化妆品优选在(C)成分中包含油溶性药物。
发明效果
本发明的水包油型乳化化妆品包含：含有氢化聚异丁烯和少量的高级醇的油性成分、表面活性剂和含有水溶性增稠剂的水性成分，可以提供紧致感优异、柔和度和保湿效果也优异的水包油型乳化化妆品。
具体实施方式
本发明的水包油型乳化化妆品由(A)氢化聚异丁烯、(B)高级醇、(C)油性成分、(D)表面活性剂、(E)水溶性增稠剂和(F)水性成分构成。
以下，对各成分进行详述。
((A) 氢化聚异丁烯)
(A)氢化聚异丁烯是将异丁烯和正丁烯共聚后进行氢化而得到的烃混合物。本发明中使用的氢化聚异丁烯可以使用化妆品中通常使用的氢化聚异丁烯。
氢化聚异丁烯的数均分子量必需是2000～3000。若数均分子量太小，则有时紧致感会不充分。若数均分子量太大，则有时铺展会变重等，给使用感带来影响。
本发明的水包油型乳化化妆品中(A)氢化聚异丁烯的混合量相对于化妆品总量必需是0.1～5质量%。(A)成分的混合量优选为0.5质量%以上。若不足0.1质量%，则无法充分地得到紧致感。另外，(A)成分的混合量优选为3质量%以下。若超过5质量%，则在柔和度和无发粘感方面差。
((B)高级醇)
本发明的水包油型乳化化妆品中所混合的(B)高级醇是碳原子数为6以上的醇。
作为高级醇，例如有山萮醇、十八烷醇、鲸蜡醇、肉豆蔻醇、十八醇十六醇混合物等。
本发明的水包油型乳化化妆品中(B)高级醇的混合量相对于化妆品总量必须0.1～不足1质量%。(B)成分的混合量优选为0.3质量%以上。若不足0.1质量%，则无法获得柔和度和保湿效果。另外，(B)成分的混合量优选为0.8质量%以下。若为1质量%以上，则存在无法得到紧致感的倾向。
((C)油性成分)
(C)油性成分是指化妆品中通常可以使用的除(A)成分和(B)成分以外的油性成分。
作为上述(C)油性成分，例如有硅油分、极性油分、非极性油分等液体油分、固体油分、半固体油分、油溶性紫外线吸收剂等。
作为硅油分，可以列举：二甲基聚硅氧烷、甲基苯基聚硅氧烷、甲基氢聚硅氧烷等链状硅油；八甲基环四硅氧烷、十甲基环戊硅氧烷、十二甲基环六硅氧烷等环状硅油等。
作为极性油分，例如有二异硬脂酸甘油酯、苹果酸二异十八烷酯、新戊酸三丙二醇酯、三2-乙基己酸甘油酯、辛酸鲸蜡酯、月桂酸己酯、肉豆蔻酸异丙酯、棕榈酸辛酯、硬脂酸异鲸蜡酯、异硬脂酸异丙酯、异棕榈酸辛酯、异硬脂酸异癸酯、琥珀酸2-乙基己酯、癸二酸二乙酯、乙基己酸鲸蜡酯等酯油等。
作为非极性油分，例如有液体石蜡、角鲨烷、角鲨烯、石蜡、异十六烷等烃油等。
作为固体油分，例如有：可可脂、椰子油、马油、氢化椰子油、棕榈油、牛油、羊油、氢化蓖麻油等固体油脂；石蜡(直链烃)、微晶蜡(支链饱和烃)、地蜡、木蜡、费-托石蜡等烃类；蜂蜡、巴西棕榈蜡、小烛树蜡、米糠蜡(米ぬかロウ)、鲸蜡、霍霍巴油、米蜡(ヌカロウ)、褐煤蜡、木棉蜡、月桂蜡、紫胶蜡、蔗蜡、羊毛脂脂肪酸异丙酯、月桂酸己酯、还原羊毛脂、硬质羊毛脂、POE羊毛脂醇醚、POE羊毛脂醇乙酸酯、POE胆固醇醚、羊毛脂脂肪酸聚乙二醇酯、POE氢化羊毛脂醇醚等蜡类；肉豆蔻酸、棕榈酸、硬脂酸、山萮酸等高级脂肪酸等。
作为半固体油分，例如有：凡士林、羊毛脂、牛油果油(シア脂)、部分氢化椰子油等植物油；部分氢化霍霍巴油、双-二甘油多酰基己二酸酯-2、四(山萮酸/苯甲酸/乙基己酸)季戊四醇酯、澳洲坚果籽油聚甘油-6-酯类山萮酸酯、(植物甾醇/山萮醇)二聚二亚油酸酯、双季戊四醇六羟基硬脂酸酯等。
作为油溶性紫外线吸收剂，例如有：对甲氧基肉桂酸辛酯、对甲氧基肉桂酸异丙酯、二对甲氧基肉桂酸单-2-乙基己酸甘油酯等肉桂酸系紫外线吸收剂；对氨基苯甲酸等苯甲酸系紫外线吸收剂；氨茴酸甲酯等氨茴酸系紫外线吸收剂；水杨酸辛酯、水杨酸苯酯等水杨酸系紫外线吸收剂；4-叔丁基-4’-甲氧基苯甲酰基甲烷、2-乙基己基2-氰基-3,3-二苯基丙烯酸酯等。
作为(C)油性成分，优选包含油溶性药物。
作为油溶性药物，例如有维生素A (视黄醇)、维生素D、维生素E、维生素K以及它们的衍生物等油溶性维生素类(维生素A油、棕榈酸视黄醇酯等)、维生素C或熊果苷等水溶性药物的油溶性衍生物(维生素C棕榈酸酯等)、油溶性植物提取物、油溶性香料、表面进行了疏水化处理的物质、环孢菌素等。
本发明的水包油型乳化化妆品中(C)油性成分的混合量相对于化妆品总量必须是1～25质量%。若(C)成分的混合量不足1质量%，则保湿感、柔和度差，产生发粘感。若超过25质量%，则变得油腻。
在本发明中，非极性油分的混合量相对于(C)成分总量必需是30%以下，优选为20%以下。若(C)成分中非极性油分的混合量相对于(C)成分总量超过30%，则有时在紧致感和无发粘感方面差。
另一方面，关于极性油分，在更具效果方面，优选混合极性(IOB)高的油分。特别是通过混合IOB值为0.3以上的油分，可以获得非常优异的紧致感。
((D)表面活性剂)
(D)表面活性剂可以使用化妆品中通常可使用的表面活性剂。
作为表面活性剂，特别优选使用HLB为5以上的表面活性剂。HLB小于5的表面活性剂的亲油性高，有时难以得到稳定的水包油型乳化化妆品。
需要说明的是，上述HLB值可以通过以HLB＝7+11.7·log (MW/MO) (其中，MW表示亲水基部分的分子量，MO表示亲油基部分的分子量)表示的川上式算出。
作为上述表面活性剂，例如有非离子性表面活性剂、阴离子性表面活性剂等。
作为非离子性表面活性剂，例如有聚氧乙烯脂肪酸醚、聚氧乙烯脂肪酸酯、聚氧乙烯烷基醚、聚氧乙烯聚氧丙烯烷基醚、聚氧乙烯烷基苯基醚、聚氧乙烯胆甾醇醚、聚氧乙烯植物甾醇醚、聚氧乙烯聚氧丙烯植物甾醇醚、聚氧乙烯氢化蓖麻油、聚氧乙烯脱水山梨糖醇脂肪酸酯、聚氧乙烯山梨糖醇脂肪酸酯、聚氧乙烯脂肪酸甘油酯、聚甘油脂肪酸酯、蔗糖脂肪酸酯等。
作为阴离子性表面活性剂，例如有脂肪酸皂、N-酰基谷氨酸盐、酰基牛磺酸盐、酰基烷基牛磺酸盐、高级烷基硫酸酯盐、烷基醚硫酸酯盐、N-酰基肌氨酸盐、高级脂肪酰胺磺酸盐、磷酸酯盐、磺基琥珀酸盐、烷基苯磺酸盐等。
本发明的水包油型乳化化妆品中(D)表面活性剂的混合量相对于化妆品总量必须是0.3～5质量%。若(D)成分的混合量不足0.3质量%，则稳定性差。若超过5质量%，则使用感差。
((E)水溶性增稠剂)
本发明所混合的(E)水溶性增稠剂为化妆品中通常可以使用的水溶性增稠剂。
作为水溶性增稠剂，例如有：阿拉伯胶、黄蓍胶、半乳聚糖、槐树豆胶、瓜尔胶、刺梧桐胶、卡拉胶、黄原胶、果胶、琼脂、榅桲籽(榅桲)、藻胶体(褐藻提取物)等植物系高分子；葡聚糖、琥珀酰聚糖、普鲁兰多糖等微生物系高分子；胶原、酪蛋白、白蛋白、明胶等动物系高分子；淀粉(大米淀粉、玉米淀粉、马铃薯淀粉、小麦淀粉)、羧甲基淀粉、甲基羟丙基淀粉等淀粉系高分子等。
此外，还可以列举：甲基纤维素、硝基纤维素、乙基纤维素、甲基羟丙基纤维素、羟乙基纤维素、纤维素硫酸钠、羟丙基纤维素、羧甲基纤维素钠、结晶纤维素、纤维素粉末等纤维素系高分子等；海藻酸钠、海藻酸丙二醇酯等海藻酸系高分子等。
进一步可以列举：聚乙烯甲醚、羧基乙烯基聚合物等乙烯基系高分子；聚氧乙烯系高分子；聚氧乙烯聚氧丙烯共聚物系高分子；聚丙烯酸乙酯、聚丙烯酰胺等丙烯酸系高分子；聚乙烯亚胺、阳离子聚合物、膨润土、硅酸铝镁、合成粘土、锂蒙脱石、硅酸酐等无机系水溶性高分子；PEG-240/癸基十四醇聚醚-20(デシルテトラデセス-20)/六亚甲基二异氰酸酯共聚物、(二甲基丙烯酰胺/丙烯酰基二甲基牛磺酸钠)交联共聚物、(丙烯酸钠/丙烯酰基二甲基牛磺酸)共聚物、(丙烯酸烷基酯/硬脂醇聚醚-20甲基丙烯酸酯)共聚物、(丙烯酰基二甲基牛磺酸铵/VP)共聚物等。
本发明的水包油型乳化化妆品中(E)水溶性增稠剂的混合量相对于化妆品总量必须是0.05～5质量%。若(E)成分的混合量不足0.05质量%，则稳定性差。若超过5质量%，则使用感差。
((F)水性成分)
(F)水性成分是指化妆品中通常可以使用的除(E)成分以外的水性成分。
作为上述(F)水性成分，例如有保湿剂、金属离子封闭剂、抗氧剂、水溶性紫外线吸收剂、水溶性药物等。
作为保湿剂，例如有1,3-丁二醇、聚乙二醇、丙二醇、二丙二醇、己二醇、甘油、二甘油、木糖醇、麦芽糖醇、麦芽糖、D-甘露醇等。
作为金属离子封闭剂，例如有依地酸钠盐、偏磷酸钠、磷酸等。
作为抗氧剂，例如有：抗坏血酸、二丁基羟基甲苯、丁基羟基茴香醚等。
作为水溶性紫外线吸收剂，例如有：2-羟基-4-甲氧基二苯甲酮-5-磺酸等二苯甲酮系紫外线吸收剂；尿刊酸(ウロカニン酸)、苯基苯并咪唑磺酸等。
作为水溶性药物，例如有：肌醇、盐酸吡哆醇、烟酸苄酯、烟酰胺、烟酸dl-α-生育酚、抗坏血酸磷酸镁、抗坏血酸2-葡糖苷、dl-α-生育酚2-L抗坏血酸磷酸二酯钾盐、泛酸、生物素等维生素类；尿囊素、甘菊蓝等抗炎药；熊果苷、4-甲氧基水杨酸或其盐、氨甲环酸或其衍生物等美白剂；单宁酸等收敛剂；氯化溶菌酶、盐酸吡哆醇、深海胶原蛋白等。
上述药物除了以游离状态使用以外，可成盐的药物可以以酸式盐或碱式盐的形式使用，而具有羧酸基的药物可以以其酯的形式使用。
本发明的水包油型乳化化妆品中(F)水性成分的混合量相对于化妆品总量优选59～96质量%。
需要说明的是，在不损及本发明效果的范围内，可以混合微粒氧化钛、微粒氧化锌等粉末成分作为其他成分。
本发明的水包油型乳化化妆品优选粘度为50000mPa·s以下。本发明中，粘度是指常温(25℃)下使用粘度计测定的值。若粘度太高，则有时使用感差。
本发明的水包油型乳化化妆品可以广泛用于以往应用于外皮的化妆品。例如有乳液、凝胶、美容液、霜剂、化妆基底、粉底、眼线笔、染睫毛油等。
实施例
以下，列举实施例以进一步详述本发明，但本发明并不受实施例的任何限定。只要没有特别记载，则混合量以相对于混合有该成分的体系的质量%表示。
在说明实施例之前，对本发明中采用的试验的评价方法进行说明。
评价(1)：稳定性
将在25℃和40℃下保存1个月的试样的硬度和外观与刚刚制备后进行比较，评价稳定性。
A＊：在任一种保存条件下，硬度的下降均为10%以下，且没有确认到外观的变化；
A：在任一种保存条件下均没有确认到外观的变化，但只有在40℃下保存的试样确认到10%以上的硬度变化；
B*：在任一种保存条件下均没有确认到外观的变化，但确认到10%以上的硬度变化；
B：在外观方面确认到水或油的轻微分离；
C：1个月以内在外观方面确认到水或油的分离。
评价(2)：紧致感
10名专业评审员在面部涂抹试样，评价涂抹后的使用感。
A*：9名以上的评审员回答为具有紧致感；
A：7名以上且不足9名的评审员回答为具有紧致感；
B：5名以上且不足7名的评审员回答为具有紧致感；
C：不足5名的评审员回答为具有紧致感。
评价(3)：无发粘感
10名专业评审员在面部涂抹试样，评价涂抹后的使用感。
A*：9名以上的评审员回答为无发粘感；
A：7名以上且不足9名的评审员回答为无发粘感；
B：5名以上且不足7名的评审员回答为无发粘感；
C：不足5名的评审员回答为无发粘感。
评价(4)：柔和度
10名专业评审员在面部涂抹试样，评价涂抹后的使用感。
A*：9名以上的评审员回答为肌肤柔和；
A：7名以上且不足9名的评审员回答为肌肤柔和；
B：5名以上且不足7名的评审员回答为肌肤柔和；
C：不足5名的评审员回答为肌肤柔和。
评价(5)：保湿效果
10名专业评审员在面部涂抹试样，评价涂抹后的使用感。
A*：9名以上的评审员回答为具有保湿效果；
A：7名以上且不足9名的评审员回答为具有保湿效果；
B：5名以上且不足7名的评审员回答为具有保湿效果；
C：不足5名的评审员回答为具有保湿效果。
迄今为止，本发明人等发现：在油包水型乳化化妆品中，作为与肌肤的亲和性高、且具紧致感的成分，混合氢化聚异丁烯是有效的。
因此，对向水包油型乳化化妆品中混合氢化聚异丁烯进行了研究。本发明人等按照下述表1所示的混合组成，通过常规方法制备了水包油型乳化化妆品(霜剂)。然后，对于各试样，按照上述评分标准就评价项目(1)～(5)进行评价。结果见表1。
[表1]
*1：脱臭聚丁烯P 200SH (日兴リカ公司制、数均分子量为3000)
在作为水包油型乳化化妆品的试验例1-1中混合了氢化聚异丁烯而得到的试验例1-2、1-3中，紧致感和保湿效果有少许提高。但是，可知特别是在紧致感方面无法充分满足要求。
因此，本发明人等利用常规方法制备了混合有氢化聚异丁烯、并改变了结合使用的高级醇量的由下述表2所示的混合组成形成的水包油型乳化化妆品(霜剂)。然后，对于各试样，按照上述评分标准就评价项目(1)～(5)进行评价。结果见表2。
[表2]
由试验例2-3～2-5可知：若在混合有氢化聚异丁烯的水包油型乳化化妆品中混合少量的高级醇，则可以得到紧致感优异的化妆品。而且，柔和度和保湿效果也优异。
但是，在未混合高级醇的试验例2-2中，柔和度差，保湿效果也存在改善的空间。
还可知：若增加高级醇的混合量，则给紧致感带来影响。
因此，在本发明的含有(A)氢化聚异丁烯的水包油型乳化化妆品中，必须含有0.1～1不足质量%的(B)高级醇。
接下来，对(A)氢化聚异丁烯的混合量进行研究。本发明人等利用常规方法制备改变了氢化聚异丁烯的混合量的、由下述表3所示的混合组成形成的水包油型乳化化妆品(霜剂)。然后，对于各试样，按照上述评分标准就评价项目(1)～(5)进行评价。结果见表3。
[表3]
根据表3，在适量混合了(A)成分的试验例3-1、3-2、2-4、3-3中，紧致感及使用感等优异。
因此，本发明的水包油型乳化化妆品中(A)氢化聚异丁烯的混合量必须是0.1～5质量%。
接下来，对油分的组成进行进一步的研究。本发明人等利用常规方法制备由下述表4所示的混合组成形成的水包油型乳化化妆品(霜剂)。然后，对于各试样，按照上述评分标准就评价项目(1)～(5)进行评价。结果见表4。
[表4]
由表4可知：若作为非极性油的角鲨烷的混合量增加，则无法得到可以满足紧致感和无发粘感的水包油型乳化化妆品。
因此，在本发明的水包油型乳化化妆品中，(C)成分总量中非极性油分必须是30%以下。
此外，比较试验例2-4和试验例4-5时可知：若将IOB高的极性油分的一部分置换成IOB低的极性油分，则紧致感得到少许抑制。因此，在更具效果方面，优选混合极性(IOB)高的极性油分。
接下来，对乳化体系进行研究。本发明人等利用常规方法制备下述试验例5-1的油包水型乳化化妆品(霜剂)。然后，对于各试样，按照上述评分标准就评价项目(1)～(5)进行评价。结果见表5。
[表5]
由表5可知：在作为油包水型乳化化妆品的试验例5-1中，紧致感及柔和度差。
因此，本发明的组成的乳化化妆品必须是水包油型乳化体系。
以下，列举本发明的水包油型乳化化妆品的配方例。本发明并不限于该配方例。
配方例1 乳液
非极性油分量/(C)成分量：25.0%
粘度(ビスメトロン粘度计、VDA型、12rpm、转子No.3；测定温度25℃)：4500mPa·s
(制备方法)
将(5)～(12)加热混合，进行油相的均匀分散。将(1)～(4)加热混合，制备水相。向上述水相中添加已加热的油相，使用均质器调整乳化颗粒，边搅拌边冷却，制备目标乳液。
所得乳液的稳定性良好，具有紧致感、肌肤的柔和度均优异的使用感。
配方例2 凝胶
非极性油分量/(C)成分量：18.2%
粘度(ビスメトロン粘度计、VDA型、12rpm、转子No.3；测定温度25℃)：34600mPa·s
(制备方法)
将(5)～(13)加热混合，进行油相的均匀分散。将(1)～(4)加热混合，制备水相。向上述水相中添加已加热的油相，使用均质器调整乳化颗粒，边搅拌边冷却，制备目标凝胶。
所得凝胶的稳定性良好，具有紧致感、肌肤的柔和度均优异的使用感。
配方例3 美容液
非极性油分量/(C)成分量：23.1%
粘度(ビスメトロン粘度计、VDA型、12rpm、转子No.3；测定温度25℃)：7900mPa·s
(制备方法)
将(6)～(15)加热混合，进行油相的均匀分散。将(1)～(5)加热混合，制备水相。向上述水相中添加已加热的油相，使用均质器调整乳化颗粒，边搅拌边冷却，制备目标美容液。
所得美容液的稳定性良好，具有紧致感、肌肤的柔和度均优异的使用感。
Claims (3)
1. 水包油型乳化化妆品，其特征在于：包含下述(A)～(F)成分，且(C)成分总量中非极性油分的混合量为30%以下，
(A) 0.1～5质量%的数均分子量为2000～3000的氢化聚异丁烯；
(B) 0.1～不足1质量%的高级醇；
(C) 1～25质量%的油性成分；
(D) 0.3～5质量%的表面活性剂；
(E) 0.05～5质量%的水溶性增稠剂；
(F) 水性成分。
2. 权利要求1所述的水包油型乳化化妆品，其特征在于：25℃下的粘度为50000 mPa·s以下。
3. 权利要求1或2所述的水包油型乳化化妆品，其特征在于：(C)成分中包含油溶性药物。
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- 2012-04-04 ES ES12837089.7T patent/ES2610580T3/es active Active
- 2012-04-04 JP JP2013535957A patent/JP5972271B2/ja active Active
- 2012-04-04 CN CN2012800004317A patent/CN103200927A/zh active Pending
- 2012-04-04 US US14/347,328 patent/US9956148B2/en active Active
- 2012-04-04 KR KR1020147007944A patent/KR101910695B1/ko not_active Expired - Fee Related
- 2012-04-04 EP EP12837089.7A patent/EP2762128B1/en active Active
- 2012-04-04 RU RU2014115278/15A patent/RU2600030C2/ru not_active IP Right Cessation
- 2012-04-04 WO PCT/JP2012/059166 patent/WO2013046770A1/ja active Application Filing
- 2012-04-04 CN CN201910099698.XA patent/CN109908027A/zh active Pending
- 2012-04-20 TW TW101114090A patent/TWI549693B/zh not_active IP Right Cessation
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| JP2009102281A (ja) * | 2007-10-25 | 2009-05-14 | Shiseido Co Ltd | 水中油型乳化化粧料 |
| JP2010006726A (ja) * | 2008-06-25 | 2010-01-14 | Kao Corp | 皮膚化粧料 |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107007480A (zh) * | 2015-11-30 | 2017-08-04 | 富士胶片株式会社 | 凝胶状水包油型乳化组合物、皮肤外用剂以及水包油型乳化组合物的制造方法 |
| CN107007480B (zh) * | 2015-11-30 | 2021-08-17 | 富士胶片株式会社 | 凝胶状水包油型乳化组合物、皮肤外用剂以及水包油型乳化组合物的制造方法 |
| CN109414380A (zh) * | 2016-06-29 | 2019-03-01 | 株式会社资生堂 | 水包油型乳化唇用化妆品 |
| CN109414380B (zh) * | 2016-06-29 | 2021-09-17 | 株式会社资生堂 | 水包油型乳化唇用化妆品 |
| CN111050739A (zh) * | 2018-03-30 | 2020-04-21 | 株式会社漫丹 | 凝胶状化妆料 |
Also Published As
| Publication number | Publication date |
|---|---|
| US9956148B2 (en) | 2018-05-01 |
| US20140235732A1 (en) | 2014-08-21 |
| JP5972271B2 (ja) | 2016-08-17 |
| RU2600030C2 (ru) | 2016-10-20 |
| EP2762128B1 (en) | 2016-11-02 |
| TW201313249A (zh) | 2013-04-01 |
| EP2762128A4 (en) | 2015-04-29 |
| EP2762128A1 (en) | 2014-08-06 |
| RU2014115278A (ru) | 2015-11-10 |
| KR20140072057A (ko) | 2014-06-12 |
| TWI549693B (zh) | 2016-09-21 |
| WO2013046770A1 (ja) | 2013-04-04 |
| CN109908027A (zh) | 2019-06-21 |
| KR101910695B1 (ko) | 2018-10-22 |
| JPWO2013046770A1 (ja) | 2015-03-26 |
| ES2610580T3 (es) | 2017-04-28 |
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