CN103075906B - High-pressure heat-storing/or cold-storing device - Google Patents
High-pressure heat-storing/or cold-storing device Download PDFInfo
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- CN103075906B CN103075906B CN201310042467.8A CN201310042467A CN103075906B CN 103075906 B CN103075906 B CN 103075906B CN 201310042467 A CN201310042467 A CN 201310042467A CN 103075906 B CN103075906 B CN 103075906B
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- 238000012546 transfer Methods 0.000 claims abstract description 105
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- 238000010438 heat treatment Methods 0.000 claims abstract description 48
- 239000007787 solid Substances 0.000 claims abstract description 45
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- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 238000004891 communication Methods 0.000 claims description 5
- 238000004321 preservation Methods 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000012774 insulation material Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
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- 239000007789 gas Substances 0.000 claims 1
- 229910052755 nonmetal Inorganic materials 0.000 claims 1
- 238000004146 energy storage Methods 0.000 abstract description 4
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- 239000010410 layer Substances 0.000 description 43
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- 238000000034 method Methods 0.000 description 10
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- 239000011229 interlayer Substances 0.000 description 4
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- 229910000831 Steel Inorganic materials 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000002826 coolant Substances 0.000 description 3
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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E70/00—Other energy conversion or management systems reducing GHG emissions
- Y02E70/30—Systems combining energy storage with energy generation of non-fossil origin
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- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
本发明公开了一种高压储热/储冷装置,用于高/低温热能存储领域。是一种外壳承受高压,由外至内依次为冷却/加热液层、保温层、薄壁内壳和内部的固体储热/冷介质,利用固体材料作为储热/冷介质,高压传热介质流过储热/冷介质表面并发生换热的高压储热/储冷装置。本发明的储热/储冷装置具有承受压力高、造价低、效率高,热能品位高等优点,特别适用于储释热/冷温差大、储释热/冷较频繁的储热和/或储冷的场合。
The invention discloses a high-pressure heat storage/cold storage device, which is used in the field of high/low temperature heat energy storage. It is a kind of shell that bears high pressure. From the outside to the inside, there are cooling/heating liquid layer, insulation layer, thin-walled inner shell and internal solid heat storage/cold medium. Solid materials are used as heat storage/cold medium and high-pressure heat transfer medium. A high-pressure heat storage/cold storage device that flows through the surface of the heat storage/cold medium and exchanges heat. The heat storage/cold storage device of the present invention has the advantages of high pressure resistance, low cost, high efficiency, and high thermal energy grade, and is especially suitable for heat storage and/or storage where the heat/cold temperature difference is large and the heat/cold storage and release are frequent. Cold occasions.
Description
技术领域technical field
本发明涉及高/低温热能储存领域,是一种利用固体储热/冷介质储存高/低温热能并在需要时释放的装置。The invention relates to the field of high/low temperature thermal energy storage, and is a device which utilizes solid heat storage/cold storage medium to store high/low temperature thermal energy and releases it when needed.
背景技术Background technique
本发明公开的一种高压储热/储冷装置可应用于工业过程的余热利用,太阳能/风能热储存,电力调峰热储存,先进压缩空气储能系统等。The high-pressure heat storage/cold storage device disclosed by the invention can be applied to waste heat utilization in industrial processes, solar/wind energy heat storage, power peak shaving heat storage, advanced compressed air energy storage systems, and the like.
储热/冷技术是有效解决热/冷能供求之间在时间与空间上不匹配的矛盾,提高能源利用率的有效手段。其中高压储热/冷技术主要应用于高压条件下的储热和/或储冷,是工业余热利用、太阳能/风能热利用、电力调峰热储存,先进空气储能系统等的关键技术。Heat storage/cold technology is an effective means to effectively solve the contradiction between the supply and demand of heat/cold energy in terms of time and space, and to improve energy utilization. Among them, high-pressure heat storage/cold technology is mainly used for heat storage and/or cold storage under high-pressure conditions, and is a key technology for industrial waste heat utilization, solar/wind energy heat utilization, power peak-shaving heat storage, and advanced air energy storage systems.
目前,常用的高/低温绝热结构有堆积绝热、真空粉末绝热、真空多层堆积绝热和正压堆积绝热等,采用这些绝热结构的绝热储罐和储槽均采用保温层设置在承压罐壁外面的方案,并且通常抗压较低。若采用此类绝热结构制造高压储热/储冷装置,则需要厚壁的压力容器作为罐壳,同时罐壁热容也将大幅增加,使得在储热/冷的过程中需要大量的热/冷能来冷却罐壁,这部分热/冷能却难以回收,会使储热/冷效率大幅降低。另外,这些储罐通常只作为高/低温流体介质储存使用,没有填充固体介质用于储热/冷。At present, commonly used high/low temperature insulation structures include stack insulation, vacuum powder insulation, vacuum multi-layer stack insulation, and positive pressure stack insulation, etc. Insulated storage tanks and storage tanks using these insulation structures are installed on the pressure tank wall with insulation layers Outer programs, and generally less resistant to stress. If such a thermal insulation structure is used to manufacture a high-pressure heat/cold storage device, a thick-walled pressure vessel is required as the tank shell, and the heat capacity of the tank wall will also be greatly increased, so that a large amount of heat/cooling is required in the process of heat/cold storage. Cold energy is used to cool the tank wall, but this part of heat/cooling energy is difficult to recover, which will greatly reduce the efficiency of heat storage/cold storage. In addition, these storage tanks are usually only used as high/low temperature fluid medium storage, and are not filled with solid medium for heat/cold storage.
发明内容Contents of the invention
本发明提供了一种外壳承受高压,由外至内依次为冷却/加热液层、保温层、薄壁内壳和内部的固体储热/冷介质,利用固体材料作为储热/冷介质,高压传热介质流过储热/冷介质表面并发生换热的高压储热/储冷装置。与现有的内承压,外保温的高压储罐相比,具有储热/储冷效率高的特点。The invention provides a shell that withstands high pressure, and from the outside to the inside, there are cooling/heating liquid layer, heat preservation layer, thin-walled inner shell and internal solid heat storage/cold medium, using solid materials as heat storage/cold medium, high pressure A high-pressure heat storage/cold storage device in which the heat transfer medium flows over the surface of the heat storage/cold medium and undergoes heat exchange. Compared with the existing high-pressure storage tanks with internal pressure and external insulation, it has the characteristics of high heat storage/cold storage efficiency.
本发明的技术解决方案是:Technical solution of the present invention is:
一种高压储热/储冷装置,其特征在于,所述高压储热/储冷装置由外到内依次包括厚壁外壳、冷却/加热液层、保温层、薄壁内壳和内壳内部填充的固体储热介质,内、外壳之间设内壳支撑装置;所述内壳的壁厚小于外壳的1/2;所述保温层为孔隙率高、导热系数低的保温材料,保温层与内壳之间设有压力连通装置,使得所述保温层与内壳内部压力相通,厚壁外壳为承受高内压的压力容器;所述冷却/加热液层为内部含有多个通道的夹层结构,各通道中通入循环流动的冷却/加热液,使外壳压力容器内表面均能受到冷却/加热,冷却/加热液层内的液体压力与内壳内部压力保持一致;流体传热介质与固体储热介质相接触,并在固体储热介质表面发生换热。A high-pressure heat storage/cold storage device, characterized in that the high-pressure heat storage/cold storage device sequentially includes a thick-walled outer shell, a cooling/heating liquid layer, an insulation layer, a thin-walled inner shell, and the interior of the inner shell from outside to inside Filled with solid heat storage medium, an inner shell support device is provided between the inner shell and the outer shell; the wall thickness of the inner shell is less than 1/2 of the outer shell; the thermal insulation layer is a thermal insulation material with high porosity and low thermal conductivity, and the thermal insulation layer There is a pressure communication device between the inner shell and the inner shell so that the insulation layer communicates with the internal pressure of the inner shell, and the thick-walled outer shell is a pressure vessel that withstands high internal pressure; the cooling/heating liquid layer is an interlayer with multiple channels inside structure, the circulating cooling/heating liquid is passed into each channel, so that the inner surface of the outer shell pressure vessel can be cooled/heated, and the liquid pressure in the cooling/heating liquid layer is consistent with the internal pressure of the inner shell; the fluid heat transfer medium and The solid heat storage medium is in contact with each other, and heat exchange occurs on the surface of the solid heat storage medium.
所述的高压储热/储冷装置,其特征在于,所述高压储热/储冷装置包括至少一个顶部进料口、至少一个底部排料口、至少一个顶部传热介质管口、至少一个底部传热介质管口,至少一个冷却/加热液顶部管口和一个冷却/加热液底部管口。The high-pressure heat storage/cold storage device is characterized in that the high-pressure heat storage/cold storage device includes at least one top feed port, at least one bottom discharge port, at least one top heat transfer medium nozzle, at least one Bottom heat transfer medium nozzle, at least one cooling/heating fluid top nozzle and one cooling/heating fluid bottom nozzle.
所述冷却/加热液层内部有冷却/加热液不断流动,使外壳温度恒定,以保证压力容器的强度。所述冷却/加热液层为含有多个通道的夹层等结构,保证外壳压力容器内表面均能受到冷却/加热。A cooling/heating liquid flows continuously inside the cooling/heating liquid layer to keep the temperature of the outer shell constant and ensure the strength of the pressure vessel. The cooling/heating liquid layer is a structure such as an interlayer containing multiple channels, so as to ensure that the inner surface of the shell pressure vessel can be cooled/heated.
所述冷却/加热液为水、乙醇、乙二醇、丙醇的其中一种或至少两种的混合物,所述冷却/加热液的循环流动由液泵驱动,其压力与储热/储冷装置内部压力保持一致。The cooling/heating liquid is one or a mixture of at least two of water, ethanol, ethylene glycol, and propanol. The circulating flow of the cooling/heating liquid is driven by a liquid pump, and its pressure is the same as that of heat storage/cooling storage. The internal pressure of the device remains constant.
所述高压储热/储冷装置顶部进料口和顶部传热介质管口可以为同一开口,所述高压储热/储冷装置底部排料口和底部传热介质管口可以为同一开口。The top feed inlet and the top heat transfer medium nozzle of the high-pressure heat storage/cold storage device may be the same opening, and the bottom discharge port and the bottom heat transfer medium nozzle of the high-pressure heat storage/cold storage device may be the same opening.
所述高压储热/储冷装置的薄壁内壳材料为如钢、铝、钛等的金属材料,厚壁外壳材料为如钢、铝、钛等的金属材料或如玻璃钢、预应力混凝土等的非金属材料。The thin-walled inner shell material of the high-pressure heat storage/cold storage device is a metal material such as steel, aluminum, titanium, etc., and the thick-walled shell material is a metal material such as steel, aluminum, titanium, etc. or such as glass fiber reinforced plastic, prestressed concrete, etc. non-metallic materials.
所述高压储热/储冷装置采用管道等方式连接内壳内部与保温夹层,使之压力平衡。The high-pressure heat storage/cold storage device connects the interior of the inner shell with the insulation interlayer by means of pipes to balance the pressure.
所述传热介质为液态、气态或超临界态的空气、氮气、氧气、氦气、氢气、甲烷、水蒸汽等其中一种或至少两种的混合物。The heat transfer medium is one of liquid, gaseous or supercritical air, nitrogen, oxygen, helium, hydrogen, methane, water vapor, etc. or a mixture of at least two of them.
所述固体储热介质为颗粒状或多孔材料,为岩石,矿石,矿渣,混凝土,耐火砖,陶瓷球,金属,封装的相变材料等其中一种或至少两种的混合物。The solid heat storage medium is a granular or porous material, which is one or a mixture of at least two of rocks, ores, slag, concrete, refractory bricks, ceramic balls, metals, and encapsulated phase-change materials.
所述保温层为孔隙率高、导热系数低的保温材料,如岩棉、珠光砂、玻璃纤维毡等其中一种或多种的混合物。The insulation layer is an insulation material with high porosity and low thermal conductivity, such as a mixture of one or more of rock wool, pearlescent sand, and glass fiber felt.
所述压力连通装置为设置在内壳壁面上的开孔或一端与保温层连通、另一端与内壳连通的连接管道,使得所述保温层与内壳内部压力相通,使之压力平衡。优选地,所述通压管道一端与顶部传热介质管口连通、另一端穿过厚壁外壳和冷却/加热液层后与保温层连通。The pressure communication device is an opening on the wall of the inner shell or a connecting pipe with one end communicating with the insulation layer and the other end communicating with the inner shell, so that the pressure inside the insulation layer communicates with the inner shell to balance the pressure. Preferably, one end of the pressure passage communicates with the heat transfer medium nozzle at the top, and the other end communicates with the insulation layer after passing through the thick-walled shell and the cooling/heating liquid layer.
所述内壳支撑装置的支撑方式为圆环形支撑、多点支撑等其中一种或多种,支撑材料可以为性能稳定、导热系数低、抗压强度较高的如钢、钛等金属材料或如玻璃钢、树脂等非金属材料。The support method of the inner shell support device is one or more of circular support, multi-point support, etc., and the support material can be metal materials such as steel and titanium with stable performance, low thermal conductivity, and high compressive strength. Or non-metallic materials such as fiberglass, resin, etc.
优选地,所述固体储热/冷介质为体积热容高、成本低廉、热机械性能稳定、对传热介质吸收渗透率低、孔隙率低、比表面积高的材料。Preferably, the solid heat storage/cold medium is a material with high volumetric heat capacity, low cost, stable thermomechanical performance, low absorption and permeability to heat transfer medium, low porosity, and high specific surface area.
优选地,所述高压储热/储冷装置由上至下设置多个隔热层,该隔热层允许传热介质自由通过,所述隔热层可以减小内部固体储热/冷介质和传热流体的轴向导热。Preferably, the high-pressure heat storage/cold storage device is provided with multiple heat insulation layers from top to bottom, the heat insulation layers allow the heat transfer medium to pass through freely, and the heat insulation layers can reduce the internal solid heat/cold storage medium and Axial conduction of heat transfer fluid.
优选地,所述高压储热/储冷装置的壁壳与保温层之间设置一定厚度的空隙,所述空隙可以提高保温夹层内部的压力传递速度。Preferably, a gap of a certain thickness is provided between the wall shell of the high-pressure heat storage/cold storage device and the insulation layer, and the gap can increase the pressure transmission speed inside the insulation interlayer.
优选地,所述高压储热/储冷装置,内部可以设置一个或多个换热装置以补充热/冷量,换热装置可以为螺旋管束、光滑管管束、翅片管管束或盘管管束的一种或多种混合。Preferably, the high-pressure heat storage/cold storage device can be provided with one or more heat exchange devices inside to supplement the heat/cold capacity, and the heat exchange devices can be spiral tube bundles, smooth tube bundles, finned tube bundles or coil tube bundles one or more mixtures.
优选地,所述高压储热/储冷装置,传热介质进口和/或出口可以设置一个或多个扰流板以使传热流体均匀流入,扰流板可以为多孔板、挡流板等一种或两种混合。Preferably, in the high-pressure heat storage/cold storage device, the inlet and/or outlet of the heat transfer medium may be provided with one or more baffles to allow the heat transfer fluid to flow in evenly, and the baffles may be perforated plates, baffles, etc. One or a mix of both.
作为高压储热装置的使用流程为:The use process as a high-pressure heat storage device is as follows:
预先,关闭底部的储热介质排出口,将固体储热介质通过顶部的进料口填充进高压储热装置内壳中,至预定高度。开动冷却液的液泵,使冷却液在冷却液层内在一定的流速下流动。In advance, the heat storage medium discharge port at the bottom is closed, and the solid heat storage medium is filled into the inner shell of the high-pressure heat storage device through the top feed port to a predetermined height. Start the liquid pump of the coolant to make the coolant flow in the coolant layer at a certain flow rate.
储热时,高温高压传热介质由高压储热装置顶部的传热介质管口进入。经过顶部管口的扰流板后,传热介质均匀向下,通过固体储热介质之间的空隙,经过固体储热介质表面并与之换热,将高温热能传给固体介质;同时传热流体被冷却,由高压储热装置底部的传热介质管口排出。当传热介质的排出温度达到某一设定温度时,认为热能已经储满,关闭传热介质的进入,结束储热。储热过程中,填充床内部温度场形成自上而下的温度分层。When storing heat, the high-temperature and high-pressure heat transfer medium enters through the heat transfer medium nozzle at the top of the high-pressure heat storage device. After passing through the spoiler at the top nozzle, the heat transfer medium goes down evenly, passes through the gap between the solid heat storage medium, passes through the surface of the solid heat storage medium and exchanges heat with it, and transfers high-temperature heat energy to the solid medium; at the same time, heat transfer The fluid is cooled and discharged from the heat transfer medium nozzle at the bottom of the high-pressure heat storage device. When the discharge temperature of the heat transfer medium reaches a certain set temperature, it is considered that the heat energy has been fully stored, and the entry of the heat transfer medium is closed to end the heat storage. During the heat storage process, the temperature field inside the packed bed forms a top-down temperature stratification.
高压储热装置若已经储存一定热量,开始保温阶段时,关闭高压储热装置顶部和底部的传热介质管口。If the high-pressure heat storage device has stored a certain amount of heat, the heat transfer medium nozzles at the top and bottom of the high-pressure heat storage device are closed when the heat preservation stage starts.
释热时,高压传热介质由高压储热装置底部的传热介质管口进入。经过底部管口的扰流板后,传热介质均匀向上,通过固体储热介质之间的空隙,经过固体储热介质表面并与之换热,吸收固体储热介质中的热能;传热流体温度升高,由高压储热装置顶部的传热介质管口排出。当传热介质的排出温度降至某一设定温度时,认为热能释放完毕,结束释热。释热过程中,填充床内部温度场的轴向分层不断向上推移。When releasing heat, the high-pressure heat transfer medium enters through the heat transfer medium nozzle at the bottom of the high-pressure heat storage device. After passing through the spoiler at the bottom nozzle, the heat transfer medium goes upward evenly, passes through the gap between the solid heat storage medium, passes through the surface of the solid heat storage medium and exchanges heat with it, and absorbs the heat energy in the solid heat storage medium; the heat transfer fluid The temperature rises and is discharged from the heat transfer medium nozzle at the top of the high-pressure heat storage device. When the discharge temperature of the heat transfer medium drops to a certain set temperature, it is considered that the heat energy is released and the heat release ends. During the heat release process, the axial stratification of the temperature field inside the packed bed moves upwards continuously.
作为高压储冷装置的使用流程为:The use process as a high-pressure cold storage device is as follows:
预先,关闭底部的储冷介质排出口,将固体储冷介质通过顶部的进料口填充进高压储冷装置内壳中,至预定高度。开动加热液的液泵,使加热液在加热液层内在一定的流速下流动。In advance, the cold storage medium outlet at the bottom is closed, and the solid cold storage medium is filled into the inner shell of the high-pressure cold storage device through the top feeding port to a predetermined height. Start the liquid pump of the heating liquid to make the heating liquid flow in the heating liquid layer at a certain flow rate.
储冷时,低温高压传热介质由高压储冷装置底部的传热介质管口进入。经过底部管口的扰流板后,传热介质均匀向上流动,通过固体储冷介质之间的空隙,经过固体储冷介质表面并与之换热,将低温冷能传给固体介质;传热流体温度升高,由高压储冷装置顶部的传热介质管口排出。当传热流体的排出温度降至某一设定温度时,认为冷能已经储存完毕,结束储冷。储冷过程中,储冷过程中,填充床内部温度场形成自上而下的温度分层。During cold storage, the low-temperature and high-pressure heat transfer medium enters through the heat transfer medium nozzle at the bottom of the high-pressure cold storage device. After passing through the spoiler at the bottom nozzle, the heat transfer medium flows upward evenly, passes through the gap between the solid cold storage medium, passes through the surface of the solid cold storage medium and exchanges heat with it, and transfers low-temperature cold energy to the solid medium; heat transfer The temperature of the fluid rises, and it is discharged from the heat transfer medium nozzle at the top of the high-pressure cold storage device. When the discharge temperature of the heat transfer fluid drops to a certain set temperature, it is considered that the cold energy has been stored, and the cold storage ends. During the cold storage process, the temperature field inside the packed bed forms a top-down temperature stratification.
高压储冷装置若已经储存一定冷量,开始保温阶段时,关闭高压储冷装置顶部和底部的传热介质管口。If the high-pressure cold storage device has stored a certain amount of cold, when the heat preservation stage starts, close the heat transfer medium nozzles at the top and bottom of the high-pressure cold storage device.
释冷时,高压传热介质由高压储冷装置顶部的传热介质管口进入。经过顶部管口的扰流板后,传热介质均匀向下流动,通过固体储冷介质之间的空隙,经过固体储冷介质表面并与之换热,吸收固体储冷介质的低温冷能;传热流体温度降低,由高压储冷装置底部的传热介质管口排出。当传热介质的排出温度升至某一设定温度时,认为冷能已经释放完毕,结束释冷。释冷过程中,填充床内部温度场的轴向分层不断向下推移。When releasing cooling, the high-pressure heat transfer medium enters from the heat transfer medium nozzle at the top of the high-pressure cold storage device. After passing through the spoiler at the top nozzle, the heat transfer medium flows downward evenly, passes through the gap between the solid cold storage medium, passes through the surface of the solid cold storage medium and exchanges heat with it, and absorbs the low-temperature cold energy of the solid cold storage medium; The temperature of the heat transfer fluid decreases, and it is discharged from the heat transfer medium nozzle at the bottom of the high-pressure cold storage device. When the discharge temperature of the heat transfer medium rises to a certain set temperature, it is considered that the cold energy has been released, and the release of cooling is ended. During the cooling process, the axial stratification of the temperature field inside the packed bed moves downward continuously.
本发明的储热/储冷装置具有承受压力高、造价低、效率高,热能品位高等优点,特别适用于储释热/冷温差大、储释较频繁的储热和/或储冷的场合。The heat storage/cold storage device of the present invention has the advantages of high pressure resistance, low cost, high efficiency, and high thermal energy grade, and is especially suitable for heat storage and/or cold storage occasions with large temperature difference between heat storage and release/cold storage and frequent storage and release. .
附图说明Description of drawings
图1为本发明实施例1的结构示意图;Fig. 1 is the structural representation of embodiment 1 of the present invention;
图2为本发明实施例2的结构示意图;Fig. 2 is the structural representation of embodiment 2 of the present invention;
图3为本发明实施例3的结构示意图。Fig. 3 is a schematic structural diagram of Embodiment 3 of the present invention.
具体实施方式Detailed ways
为使本发明的目的、技术方案及优点更加清楚明白,以下参照附图并举实施例,对本发明进一步详细说明。In order to make the object, technical solution and advantages of the present invention clearer, the present invention will be further described in detail below with reference to the accompanying drawings and examples.
实施例1Example 1
如图1所示,为本发明的高压储热/储冷装置实施例1,此实施例中,顶部进料口和顶部传热介质管口为同一开口,底部排料口和底部传热介质管口为同一开口。其中,包括底座1,底部排料口兼底部传热介质管口2,底部多孔挡流板3,内壳支撑装置4,厚壁外壳5,冷却/加热液层6,保温层7,薄壁内壳8,固体储热/冷介质9,顶部多孔挡流板10,顶部进料口兼顶部传热介质管口11,通压管道12,顶部冷却/加热液管口13,底部冷却/加热液管口14。通压管道12一端与顶部传热介质管口11连通、另一端穿过厚壁外壳5和冷却/加热液层6后与保温层7连通。内壳8的壁厚小于外壳5的1/2;保温层7为孔隙率高、导热系数低的保温材料,保温层7与内壳8之间设有压力连通装置,使得所述保温层与内壳之间的通压管道12使得二者内部压力相通,厚壁外壳5为承受高内压的压力容器;冷却/加热液层6为内部含有多个通道的夹层结构,各通道中通入循环流动的冷却/加热液,使外壳压力容器内表面均能受到冷却/加热,所述冷却/加热液的循环流动由液泵驱动,使得冷却/加热液层6内的液体压力与内壳内部压力保持一致;流体传热介质与固体储热介质相接触,并在固体储热介质表面发生换热。本发明的高压储热/储冷器可承受1MPa~40Mpa的高压。As shown in Figure 1, it is Embodiment 1 of the high-pressure heat storage/cold storage device of the present invention. In this embodiment, the top feed port and the top heat transfer medium nozzle are the same opening, and the bottom discharge port and the bottom heat transfer medium The nozzle is the same opening. Among them, including the base 1, the bottom discharge port and the bottom heat transfer medium nozzle 2, the bottom porous baffle 3, the inner shell support device 4, the thick-walled shell 5, the cooling/heating liquid layer 6, the insulation layer 7, the thin-walled Inner shell 8, solid heat storage/cold medium 9, top porous baffle 10, top feed inlet and top heat transfer medium nozzle 11, pressure pipe 12, top cooling/heating liquid nozzle 13, bottom cooling/heating Liquid nozzle 14. One end of the pressure pipe 12 communicates with the top heat transfer medium nozzle 11 , and the other end communicates with the insulation layer 7 after passing through the thick-walled shell 5 and the cooling/heating liquid layer 6 . The wall thickness of the inner shell 8 is less than 1/2 of the outer shell 5; the thermal insulation layer 7 is a thermal insulation material with high porosity and low thermal conductivity, and a pressure communication device is provided between the thermal insulation layer 7 and the inner shell 8, so that the thermal insulation layer and the The pressure pipe 12 between the inner shells makes the internal pressure of the two communicate. The thick-walled outer shell 5 is a pressure vessel that withstands high internal pressure; the cooling/heating liquid layer 6 is a sandwich structure with multiple channels inside, and each channel is passed into The circulating cooling/heating liquid enables the inner surface of the outer shell pressure vessel to be cooled/heated, and the circulating flow of the cooling/heating liquid is driven by a liquid pump, so that the liquid pressure in the cooling/heating liquid layer 6 is the same as that inside the inner shell The pressure remains consistent; the fluid heat transfer medium is in contact with the solid heat storage medium, and heat exchange occurs on the surface of the solid heat storage medium. The high-pressure heat storage/cold storage device of the present invention can withstand a high pressure of 1MPa~40Mpa.
预先,关闭底部的排料口2,将固体储热/冷介质9通过顶部的进料口11填充进高压储热/储冷装置中,至预定高度。开动冷却液的液泵,使冷却液经过底部冷却/加热液管口14进入冷却/加热液层6,传热完毕后由顶部冷却/加热液管口13流出。In advance, the bottom discharge port 2 is closed, and the solid heat/cold storage medium 9 is filled into the high-pressure heat/cold storage device through the top feed port 11 to a predetermined height. Start the liquid pump of the cooling liquid, so that the cooling liquid enters the cooling/heating liquid layer 6 through the bottom cooling/heating liquid nozzle 14, and flows out from the top cooling/heating liquid nozzle 13 after the heat transfer is completed.
储热时,高温高压传热介质由顶部传热介质管口11进入。经过顶部多孔挡流板10后,传热介质均匀向下,将高温热能传给固体储热介质9;同时传热流体被冷却,经高压储热装置底部的传热介质管口2排出。当传热介质的排出温度达到某一设定温度时,认为热能已经储满,关闭传热介质的进入,结束储热。During heat storage, the high-temperature and high-pressure heat transfer medium enters through the top heat transfer medium nozzle 11 . After passing through the porous baffle plate 10 at the top, the heat transfer medium flows downward evenly, transferring high-temperature heat energy to the solid heat storage medium 9; at the same time, the heat transfer fluid is cooled and discharged through the heat transfer medium nozzle 2 at the bottom of the high-pressure heat storage device. When the discharge temperature of the heat transfer medium reaches a certain set temperature, it is considered that the heat energy has been fully stored, and the entry of the heat transfer medium is closed to end the heat storage.
释热时,高压传热介质由高压储热装置底部的传热介质管口2进入。经过底部多孔挡流板3后,传热介质均匀向上,吸收固体储热介质9的热量;传热流体温度升高,经高压储热装置顶部的传热介质管口11排出。当传热介质的排出温度降至某一设定温度时,认为热能已经释放完毕,结束释热。When releasing heat, the high-pressure heat transfer medium enters through the heat transfer medium nozzle 2 at the bottom of the high-pressure heat storage device. After passing through the porous baffle plate 3 at the bottom, the heat transfer medium goes upward evenly, absorbing the heat of the solid heat storage medium 9; the temperature of the heat transfer fluid rises, and it is discharged through the heat transfer medium nozzle 11 at the top of the high-pressure heat storage device. When the discharge temperature of the heat transfer medium drops to a certain set temperature, it is considered that the heat energy has been released and the heat release ends.
作为高压储冷装置储冷时,低温高压传热介质由高压储冷装置底部的传热介质管口2进入。经过底部多孔挡流板3后,传热介质均匀向上流动,将低温冷能传给固体储热介质9;传热流体温度升高,由高压储冷装置顶部的传热介质管口11排出。当传热流体的排出温度降至某一设定温度时,认为冷能已经储存完毕,结束储冷。When used as a high-pressure cold storage device for cold storage, the low-temperature and high-pressure heat transfer medium enters through the heat transfer medium nozzle 2 at the bottom of the high-pressure cold storage device. After passing through the porous baffle plate 3 at the bottom, the heat transfer medium flows upward evenly, transferring low-temperature cold energy to the solid heat storage medium 9; the temperature of the heat transfer fluid rises, and it is discharged from the heat transfer medium nozzle 11 at the top of the high-pressure cold storage device. When the discharge temperature of the heat transfer fluid drops to a certain set temperature, it is considered that the cold energy has been stored, and the cold storage ends.
释冷时,高压传热介质由高压储冷装置顶部的传热介质管口11进入。经过顶部管口的扰流板9后,传热介质均匀向下流动,吸收固体储冷介质9的低温冷能;传热流体温度降低,由高压储冷装置底部的传热介质管口2排出。当传热介质的排出温度升至某一设定温度时,认为高压储冷装置已经释放完毕,结束释冷。When releasing cooling, the high-pressure heat transfer medium enters through the heat transfer medium nozzle 11 on the top of the high-pressure cold storage device. After passing through the spoiler 9 at the top nozzle, the heat transfer medium flows downward evenly to absorb the low-temperature cold energy of the solid cold storage medium 9; the temperature of the heat transfer fluid decreases and is discharged from the heat transfer medium nozzle 2 at the bottom of the high-pressure cold storage device . When the discharge temperature of the heat transfer medium rises to a certain set temperature, it is considered that the high-pressure cold storage device has been released, and the release of cooling is ended.
实施例2Example 2
如图2所示,为本发明的高压储热/储冷装置实施例2,此实施例中顶部进料口和顶部传热介质管口为不同开口,底部排料口和底部传热介质管口为不同开口。其中,包括底座1,底部传热介质管口2,底部多孔挡流板3,内壳支撑装置4,厚壁外壳5,冷却/加热液层6,保温层7,薄壁内壳8,固体储热/冷介质9,顶部多孔挡流板10,顶部传热介质管口11,通压管道12,顶部进料口15,顶部冷却/加热液管口13,底部冷却/加热液管口14,底部排料口16。通压管道12一端与顶部传热介质管口11连通、另一端穿过厚壁外壳5和冷却/加热液层6后与保温层7连通。As shown in Figure 2, it is Embodiment 2 of the high-pressure heat storage/cold storage device of the present invention. In this embodiment, the top feed port and the top heat transfer medium nozzle are different openings, and the bottom discharge port and the bottom heat transfer medium pipe Mouth has different openings. Among them, including base 1, bottom heat transfer medium nozzle 2, bottom porous baffle 3, inner shell support device 4, thick-walled outer shell 5, cooling/heating liquid layer 6, insulation layer 7, thin-walled inner shell 8, solid Heat storage/cold medium 9, top porous baffle 10, top heat transfer medium nozzle 11, pressure pipe 12, top feed inlet 15, top cooling/heating fluid nozzle 13, bottom cooling/heating fluid nozzle 14 , Bottom discharge port 16. One end of the pressure pipe 12 communicates with the top heat transfer medium nozzle 11 , and the other end communicates with the insulation layer 7 after passing through the thick-walled shell 5 and the cooling/heating liquid layer 6 .
预先,关闭底部的排料口2,将固体储热/冷介质9通过顶部的进料口11填充进高压储热/储冷装置中,至预定高度。开动冷却液的液泵,使冷却液经过底部冷却/加热液管口14进入冷却/加热液层6,传热完毕后由顶部冷却/加热液管口13流出。In advance, the bottom discharge port 2 is closed, and the solid heat/cold storage medium 9 is filled into the high-pressure heat/cold storage device through the top feed port 11 to a predetermined height. Start the liquid pump of the cooling liquid, so that the cooling liquid enters the cooling/heating liquid layer 6 through the bottom cooling/heating liquid nozzle 14, and flows out from the top cooling/heating liquid nozzle 13 after the heat transfer is completed.
作为高压储热装置储热时,高温高压传热介质由顶部传热介质管口11进入。经过顶部多孔挡流板10后,传热介质均匀向下,将高温热能传给固体储热介质9;同时传热流体被冷却,由高压储热装置底部的传热介质管口3排出。当传热介质的排出温度达到某一设定温度时,认为热能已经储满,关闭传热介质的进入,结束储热。When used as a high-pressure heat storage device for heat storage, the high-temperature and high-pressure heat transfer medium enters through the top heat transfer medium nozzle 11 . After passing through the porous baffle plate 10 at the top, the heat transfer medium flows downward evenly, transferring high-temperature heat energy to the solid heat storage medium 9; at the same time, the heat transfer fluid is cooled and discharged from the heat transfer medium nozzle 3 at the bottom of the high-pressure heat storage device. When the discharge temperature of the heat transfer medium reaches a certain set temperature, it is considered that the heat energy has been fully stored, and the entry of the heat transfer medium is closed to end the heat storage.
释热时,高压传热介质由高压储热装置底部的传热介质管口2进入。经过底部多孔挡流板3后,传热介质均匀向上,吸收固体储热介质9的热量;传热流体温度升高,由高压储热装置顶部的传热介质管口11排出。当传热介质的排出温度降至某一设定温度时,认为热能已经释放完毕,结束释热。When releasing heat, the high-pressure heat transfer medium enters through the heat transfer medium nozzle 2 at the bottom of the high-pressure heat storage device. After passing through the porous baffle plate 3 at the bottom, the heat transfer medium goes upward evenly, absorbing the heat of the solid heat storage medium 9; the temperature of the heat transfer fluid rises, and it is discharged from the heat transfer medium nozzle 11 at the top of the high-pressure heat storage device. When the discharge temperature of the heat transfer medium drops to a certain set temperature, it is considered that the heat energy has been released and the heat release ends.
作为高压储冷装置储冷时,低温高压传热介质由高压储冷装置底部的传热介质管口2进入。经过底部多孔挡流板3后,传热介质均匀向上流动,将低温冷能传给固体储冷介质9;传热流体温度升高,由高压储冷装置顶部的传热介质管口11排出。当传热流体的排出温度降至某一设定温度时,认为冷能已经储存完毕,结束储冷。When used as a high-pressure cold storage device for cold storage, the low-temperature and high-pressure heat transfer medium enters through the heat transfer medium nozzle 2 at the bottom of the high-pressure cold storage device. After passing through the porous baffle plate 3 at the bottom, the heat transfer medium flows upward evenly, transferring low-temperature cold energy to the solid cold storage medium 9; the temperature of the heat transfer fluid rises, and it is discharged from the heat transfer medium nozzle 11 at the top of the high-pressure cold storage device. When the discharge temperature of the heat transfer fluid drops to a certain set temperature, it is considered that the cold energy has been stored, and the cold storage ends.
释冷时,高压传热介质由高压储冷装置顶部的传热介质管口11进入。经过顶部管口的扰流板10后,传热介质均匀向下流动,吸收固体储冷介质9的低温冷能;传热流体温度降低,由高压储冷装置底部的传热介质管口2排出。当传热介质的排出温度升至某一设定温度时,认为冷能已经释放完毕,结束释冷。When releasing cooling, the high-pressure heat transfer medium enters through the heat transfer medium nozzle 11 on the top of the high-pressure cold storage device. After passing through the spoiler 10 at the top nozzle, the heat transfer medium flows downward evenly to absorb the low-temperature cold energy of the solid cold storage medium 9; the temperature of the heat transfer fluid decreases and is discharged from the heat transfer medium nozzle 2 at the bottom of the high-pressure cold storage device . When the discharge temperature of the heat transfer medium rises to a certain set temperature, it is considered that the cold energy has been released, and the release of cooling is ended.
实施例3Example 3
如图3所示,为本发明的高压储热/储冷装置实施例3,为实例1的改进,此实施例中,高压储热/储冷装置内部在竖直方向上布置换热管/管束。在存储、释放和保温等环节,不同压力的高/低温传热流体可以通过换热管/管束,为内部储热/冷介质补充热/冷量。As shown in Figure 3, it is Embodiment 3 of the high-pressure heat storage/cold storage device of the present invention, which is an improvement of Example 1. In this embodiment, heat exchange tubes/tubes are arranged vertically inside the high-pressure heat/cold storage device control. In the links of storage, release and heat preservation, high/low temperature heat transfer fluids of different pressures can pass through the heat exchange tubes/tube bundles to supplement heat/cold capacity for the internal heat storage/cold medium.
其中,包括底座1,底部排料口兼底部传热介质管口2,底部冷却/加热液管口14,底部多孔挡流板3,内壳支撑装置4,厚壁外壳5,冷却/加热液层6,保温层7,薄壁内壳8,固体储热/冷介质9,顶部多孔挡流板10,顶部进料口兼顶部传热介质管口11,通压管道12,换热管/管束顶部管口19,顶部冷却/加热液管口13,换热管/管束18,换热管/管束底部管口17。通压管道12一端与顶部传热介质管口11连通、另一端穿过厚壁外壳5和冷却/加热液层6后与保温层7连通。Among them, including base 1, bottom discharge port and bottom heat transfer medium nozzle 2, bottom cooling/heating liquid nozzle 14, bottom porous baffle 3, inner shell support device 4, thick-walled outer shell 5, cooling/heating liquid Layer 6, insulation layer 7, thin-walled inner shell 8, solid heat storage/cold medium 9, top porous baffle 10, top inlet and top heat transfer medium nozzle 11, pressure pipe 12, heat exchange tube/ Tube bundle top nozzle 19, top cooling/heating liquid nozzle 13, heat exchange tube/tube bundle 18, heat exchange tube/tube bundle bottom nozzle 17. One end of the pressure pipe 12 communicates with the top heat transfer medium nozzle 11 , and the other end communicates with the insulation layer 7 after passing through the thick-walled shell 5 and the cooling/heating liquid layer 6 .
高压储热/储冷装置的储热/冷过程与实例1相同。The heat storage/cold process of the high-pressure heat storage/cold storage device is the same as that of Example 1.
当需要为高压储热装置内部储热介质补充热量时,额外的传热流体经换热管/管束顶部管口19进入换热管/管束18内部,通过换热管/管束壁面将热能传递给内部固体储热介质9,温度降低后经过换热管/管束底部管口17流出。When it is necessary to supplement heat for the internal heat storage medium of the high-pressure heat storage device, the additional heat transfer fluid enters the inside of the heat exchange tube/tube bundle 18 through the top nozzle 19 of the heat exchange tube/tube bundle, and transfers heat energy to the The internal solid heat storage medium 9 flows out through the nozzle 17 at the bottom of the heat exchange tube/tube bundle after the temperature drops.
当需要为高压储冷装置内部储冷介质补充冷量时,额外的传热流体经换热管/管束底部管口17进入换热管/管束18内部,通过换热管/管束壁面将冷能传递给内部固体储热介质9,温度升高后经过换热管/管束顶部管口19流出。When it is necessary to supplement the cooling capacity of the cold storage medium inside the high-pressure cold storage device, the additional heat transfer fluid enters the inside of the heat exchange tube/tube bundle 18 through the nozzle 17 at the bottom of the heat exchange tube/tube bundle, and transfers the cold energy through the wall of the heat exchange tube/tube bundle Transfer to the internal solid heat storage medium 9, and flow out through the top nozzle 19 of the heat exchange tube/tube bundle after the temperature rises.
以上对发明的具体实施例进行了详细描述,但其只作为范例,本发明并不限制于以上描述的具体实施例。对于本领域技术人员而言,任何对该发明进行的等同修改和替代也都在本发明的范畴之中。因此,在不脱离本发明的精神和范围下所作的均等变换和修改,都应涵盖在本发明的范围内。The specific embodiments of the invention have been described in detail above, but they are only examples, and the present invention is not limited to the specific embodiments described above. For those skilled in the art, any equivalent modifications and substitutions to the present invention are also within the scope of the present invention. Therefore, equivalent changes and modifications made without departing from the spirit and scope of the present invention shall fall within the scope of the present invention.
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