CN103070176A - Sterilizing composition containing prothioconazole and syp-1620 - Google Patents
Sterilizing composition containing prothioconazole and syp-1620 Download PDFInfo
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- CN103070176A CN103070176A CN2013100571412A CN201310057141A CN103070176A CN 103070176 A CN103070176 A CN 103070176A CN 2013100571412 A CN2013100571412 A CN 2013100571412A CN 201310057141 A CN201310057141 A CN 201310057141A CN 103070176 A CN103070176 A CN 103070176A
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- Prior art keywords
- prothioconazoles
- powdery mildew
- syp
- alkene oxime
- oxime amine
- Prior art date
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- MNHVNIJQQRJYDH-UHFFFAOYSA-N 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1=CNC(=S)N1CC(C1(Cl)CC1)(O)CC1=CC=CC=C1Cl MNHVNIJQQRJYDH-UHFFFAOYSA-N 0.000 title abstract 5
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a sterilizing composition containing prothioconazole and syp-1620. The active ingredients of the sterilizing composition are prepared by performing binary combination on the prothioconazole and the syp-1620, wherein the mass ratio of the prothioconazole to the syp-1620 is (1-40):(40-1); and a preparation comprises 1-80 percent by mass of the prothioconazole and the syp-1620 serving as active ingredients and the balance of auxiliary ingredients which are allowed to be used and accepted in pesticides. The sterilizing composition is in the dosage forms of emulsifiable concentrates, suspending agents, wettable powder, water dispersible granules, aqueous emulsions and microemulsions, and is mainly applied to prevention and control of a plurality of diseases such as wheat stripe rust, wheat powdery mildew, wheat sharp eyespot, rice sheath blight, false smut, powdery mildew of cucumber, cucumber downy mildew, grape downy mildew, apple alternaria leaf spot, apple powdery mildew, sigatoka, tomato early blight, pear scab, powdery mildew of strawberry, rust of sunflower and the like.
Description
Technical field
The present invention relates to the agriculture chemical compounding technical field, particularly relate to a kind of bactericidal composition that contains prothioconazoles and alkene oxime amine.
Background technology
Prothioconazoles is a kind of New-type wide-spectrum triazolinthione series bactericidal agent of Beyer Co., Ltd's development, and prothioconazoles toxicity is low, and without teratogenesis, the mutagenesis type, to embryo's avirulence, to human and environment safety.Prothioconazoles is mainly used in preventing and treating cereal crop as numerous diseases such as wheat, barley, rape, peanut, paddy rice and legume crops.Almost all wheat class diseases are had to good control efficiency, as the powdery mildew of Wheat and barley, banded sclerotial blight, fusarium wilt, leaf spot, rust, stalk break, net blotch, moire disease etc.Can also prevent and treat the soil-borne disease of oily Lay and peanut, as stalk break, and main foliage disease, as gray mold, black spot, brown spot, balck shank, stalk break and rust etc.
The chemical name of alkene oxime amine: (E, E, E)-N-methyl-2-[((((1-methyl-3-(2,, 6 ,-dichlorophenyl)-the 2-acrylic) imino group) the oxygen base) methyl) phenyl]-the 2-methoxyimino acetic amide.The alkene oxime amine fungicidal spectrum is wide, activity is high, have prevention and therapeutic action, with environmental organism, good compatibility is arranged, the plurality of plant diseases caused by mastigomycetes, zygomycete, sac fungi, basidiomycetes and imperfect fungus is had to good control efficiency, to powdery mildew, rust control efficiency brilliance.Can be used for preventing and treating the plurality of plant diseases such as wheat rust, wheat powdery mildew, rice sheath blight disease, false smut, powdery mildew of cucumber, cucumber downy mildew, downy mildew of garpe, alternaria leaf spot of apple, apple mildew, sigatoka, early blight of tomato, pear scab, powdery mildew of strawberry, rust of sunflower., plant growth proterties and quality are improved significantly simultaneously, and can improve output.
Using chemical agent is the most effectively means of controlling plant diseases.But long-term use single chemical bactericide continuously high dose, easily cause the problems such as residual, the environmental pollution of medicament and anti-pesticide resistance fungi development.Reasonably chemical bactericide is composite or be mixed and have the expansion fungicidal spectrum, improve control efficiency, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, delay Antifungal resistance and the positive characteristics such as drug-fast generation and development, bactericide compounded is one of the effective method the most addressed the above problem.Exploitation new product bactericide price is constantly soaring, and by contrast, exploitation is efficient with research, low toxicity, low-residual composite be mixed there is small investment, the lead time is short and be subject to domestic and international attention, the numerous and confused dynamics that develops that strengthens.We filter out prothioconazoles and alkene oxime amine and carry out compositely on the basis of lab screening and field trial, have obvious synergistic effect.And there is no at present the people about the composite bactericidal composition of prothioconazoles and alkene oxime amine and application reported.
Summary of the invention
Based on above situation, the object of the invention is to provide a kind of new and effective pesticide sterilizing composite.Be mainly used in preventing and treating the multiple diseases such as wheat rust, wheat powdery mildew, wheat sharp eyespot, rice sheath blight disease, false smut, powdery mildew of cucumber, cucumber downy mildew, downy mildew of garpe, alternaria leaf spot of apple, apple mildew, sigatoka, early blight of tomato, pear scab, powdery mildew of strawberry, rust of sunflower.
Technical scheme of the present invention realizes by following measures:
A kind of bactericidal composition that contains prothioconazoles and alkene oxime amine, two yuan of the active ingredient prothioconazoles of this bactericidal composition and alkene oxime amines are composite, and all the other are auxiliary element.In wherein said Pesticidal combination, the mass ratio of active ingredient prothioconazoles and alkene oxime amine is 1～40: 40～1, described bactericidal composition of the present invention is through the toxicity test experimental verification, the mass ratio of prothioconazoles and alkene oxime amine is 1～40: 40～1 o'clock, and synergistic effect is better.
The formulations of pesticide that described bactericidal composition of the present invention can be prepared are missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion.Wherein active ingredient prothioconazoles and the alkene oxime amine gross mass in preparation accounts for 1%～80% of the whole quality of the pharmaceutical preparations, while wherein accounting for 15%-50%, and toxicity and the residual balance preferably that reaches, cost is also lower.
The specific embodiments of the formulations of pesticide that bactericidal composition of the present invention is mixed with is as follows:
Described bactericidal composition is cream preparation, and the mass fraction of component is: 1～40 part of prothioconazoles; 1～40 part of alkene oxime amine; 10～30 parts of conventional emulsifiers; 20～50 parts of conventional solvents; 1～5 part of conventional synergist.The concrete production stage of this cream preparation adds emulsifier, the synergist rear oily liquids that becomes transparent and homogeneous that stirs again for first active ingredient prothioconazoles and alkene oxime amine being added in solvent after dissolving fully, filling, can be made into the cream preparation of the present composition.
Described bactericidal composition is suspending agent, and the mass fraction of component is: 1～40 part of prothioconazoles; 1～40 part of alkene oxime amine; 5～20 parts of dispersants; 1～5 part of antifreezing agent; 0.1～2 part of thickener; 0.1～0.8 part of defoamer; 0～10 part of penetrating agent; 0.1～5 part of pH value conditioning agent; Water, surplus.The concrete production stage of this suspending agent is for first mixing other auxiliary agents, mix through high speed shear, add active ingredient prothioconazoles and alkene oxime amine, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, can be made into the suspending agent preparation of the present composition.
Described bactericidal composition is wetting powder, and the mass fraction of component is: 1～40 part of prothioconazoles; 1～40 part of alkene oxime amine; 3～10 parts of dispersants; 1～5 part of wetting agent; Filler, surplus.The concrete production stage of this wetting powder is: by above-mentioned formula, the active ingredient prothioconazoles is mixed with alkene oxime amine and dispersant, wetting agent and filler, uniform stirring in stirred tank, mixing after airslide disintegrating mill, can be made into the wetting powder of the present composition.
Described bactericidal composition is water dispersible granules, and the mass fraction of component is: 1～40 part of prothioconazoles; 1～40 part of alkene oxime amine; 3～10 parts of dispersants; 1～10 part of wetting agent; 1～5 part of disintegrant; Filler, surplus.The concrete production stage of this water dispersible granules is: by above-mentioned formula, the active ingredient prothioconazoles is mixed with alkene oxime amine and dispersant, wetting agent, disintegrant and filler, with micro jet, pulverize, through mediating, then add in the fluidized bed prilling dryer and carry out granulation, drying, screening by sample analysis, can be made into the water dispersible granules of the present composition.
Described bactericidal composition is aqueous emulsion, and the mass fraction of component is: 1～40 part of prothioconazoles; 1～40 part of alkene oxime amine; 3～30 parts of emulsifier; 5～15 parts of solvents; 2～15 parts of stabilizing agents; 1～5 part of antifreezing agent; 0.1～8 part of defoamer; 0.2～2 part of thickener; Water, surplus.The concrete production stage of this aqueous emulsion is: at first prothioconazoles and alkene oxime amine, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes into uniform water; When the reactor high speed stirs, oil phase is added to water, slowly add water until reach the phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type, can be made into the aqueous emulsion of the present composition.
Described bactericidal composition is microemulsion, and the mass fraction of component is: 1～40 part of prothioconazoles, 1～40 part of alkene oxime amine, 10～30 parts of emulsifier, 1～8 part of antifreezing agent, 0.5～10 part of stabilizing agent, 20～50 parts of conventional solvent cosolvents.Prothioconazoles and alkene oxime amine are dissolved fully with cosolvent, then add other compositions such as emulsifier, antifreezing agent stabilizing agent, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Wherein above-described emulsifier is selected from calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, the alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, any or more than one any mixtures than forming in polyoxyethylene aliphatic alcohol ether.
Described solvent is dimethylbenzene or biodiesel, toluene, and diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), one or more in the water equal solvent are arbitrarily than the mixture formed.
Described dispersant is selected from polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene methyl ether condensate sulfate, the alkylsulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, aliphatic amine polyoxyethylene ether, one or more in the fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, and Nekal BX, moistening bleeding agent F, alkylbenzenesulfonate polyoxyethylene triphen is phosphenylic acid salt dimly, spaonin powder, silkworm excrement, one or more in the soapberry powder.
Described disintegrant is selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, one or more in sodium bicarbonate.
Described thickener is selected from xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate, in polyvinyl alcohol one or more.
Described stabilizing agent is selected from sodium citrate, a kind of in resorcinol.
Described antifreezing agent is selected from ethylene glycol, propane diols, one or more in glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20the saturated fat acid compounds, C
8-10one or more of fatty alcohol.
Described filler is selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, one or more in precipitated calcium carbonate.
The present invention be take the composite bactericide that prothioconazoles and alkene oxime amine be active ingredient and is had obvious synergistic effect, delays the drug-fast generation in key, and has reduced to become to produce cost and use cost, can be used for the improvement of resistance disease.Be mainly used in preventing and treating the multiple diseases such as wheat rust, wheat powdery mildew, wheat sharp eyespot, rice sheath blight disease, false smut, powdery mildew of cucumber, cucumber downy mildew, downy mildew of garpe, alternaria leaf spot of apple, apple mildew, sigatoka, early blight of tomato, pear scab, powdery mildew of strawberry, rust of sunflower.
Embodiment
For making technical scheme of the present invention, purpose and advantage are clearer, and the present invention describes with following specific embodiment, but the present invention is not limited to these examples.The mode that effect experiment of the present invention adopts indoor biometrics and field trial to combine, if no special instructions, the ratio of below mentioning is all ratio of quality and the number of copies.
Embodiment: prothioconazoles proportioning co-toxicity experiments different from alkene oxime amine.
1.1 reagent agent
The former medicine of 96% prothioconazoles, the former medicine of 95% alkene oxime amine, above-mentioned former medicine provides by research and development department of extra large rel medicine company limited company.
1.2 test target
Never executed prothioconazoles and alkene oxime amine from Shouguang, Shandong and cucumber of the same type gathers and separates potted plantly, for the examination cucumber variety: Chang Chun Mi Ci.
1.3 test method
1.3.1 medicament preparation
First use the former medicine of acetone solution, according to the result of preliminary experiment, two appropriate former medicines are made into to different proportionings, then it is stand-by with acetone, each processing to be diluted to respectively to some concentration gradients.
Susceptible cucumber variety Chang Chun Mi Ci cultivation, in pot for growing seedlings, is placed in to greenhouse and cultivates, and plant grows to three to four leaf after dates, gathers the blade of identical leaf age, for cultivation and the mensuration of powdery mildew of cucumber bacterium.
1.3.2 the cultivation of powdery mildew of cucumber bacterium and the preparation of spore suspension
The powdery mildew of cucumber bacterium adopts the plants method to cultivate under 20 ℃, the condition of 12h alternation of light and darkness, and every 30 d turn culture 1 time.During inoculation, with the conidium on sterile water wash-out incidence of leaf, being mixed with spore concentration is l * 10
6the suspension of individual/mL.
1.3.3 strains tested sensitivity testing
Adopt leaf dish moisturizing method to carry out toxicity test.First the blade of collection is prepared into to the leaf dish that diameter is 1.5cm, mix at random, be placed in respectively the series concentration liquid configured and soak lh, 50 leaf dishes of each concentration, test is with the blank that is treated to of adding medicine not, after soaking end, leaf faces up and puts on the blotting paper wetting in identical liquor strength, liquid on the leaf dish is blotted, the spore suspension l0L prepared is inoculated in to leaf dish central authorities, after room temperature is placed 5 min, is placed under 20 ℃, the condition of 1 2h alternation of light and darkness and cultivates, measure the onset area on the leaf dish after 10d, calculate EC
50.
On the basis of preliminary experiment, respectively single dose prothioconazoles and alkene oxime amine are carried out to toxicity test in order to upper method, the two EC
50value is respectively 4.13 ㎎/l and 3.97 ㎎/l
The percentage that accounts for the leaf disc area according to lesion area is divided sick level
0 grade: anosis;
1 grade: the sorus area accounts for below 5% of whole leaf area;
3 grades: the sorus area accounts for below the 6%-10% of whole leaf area;
5 grades: the sorus area accounts for below the 11%-20% of whole leaf area;
7 grades: the sorus area accounts for below the 21%-50% of whole leaf area;
9 grades: the sorus area accounts for more than 50% of whole leaf area;
1.3.4 mixture toxicity test and interpretation of result
Carry out the toxicity test of mixture according to mixed ratio by single dose toxicity test method.
If contrast lethality<5%, do not proofread and correct, the contrast lethality, between 5%-20%, is proofreaied and correct by formula 2, the contrast lethality > 20%, test need be reformed.
The logarithm value of drug concentration (mg/L) of take is independent variable x, and the probability value of corrected mortality of take is dependent variable y, sets up respectively the virulence regression equation formula, adopts DPS software to calculate the EC of single dose and each proportioning mixture
50calculate co-toxicity coefficient (CTC) according to the abundant method of Sun Yun.Co-toxicity coefficient CTC, computing formula is as follows: (take prothioconazoles as the standard medicament, its toxicity index is 100):
The LC of the toxicity index of alkene oxime amine (TI)=prothioconazoles
50the LC of/alkene oxime amine
50* 100
The LC of the true toxicity index (ATI) of M=prothioconazoles
50the LC of/M
50* 100
The TI of the TI of the theoretical toxicity index (TTI) of M=prothioconazoles * P prothioconazoles+alkene oxime amine * P alkene oxime amine
The TTI of the ATI/M of the co-toxicity coefficient of M (CTC)=M * 100
In formula:
M is prothioconazoles and the mixture of the different proportionings of alkene oxime amine
The P prothioconazoles is prothioconazoles shared ratio in mixture
The P alkene oxime amine is alkene oxime amine shared ratio in mixture
2.1 toxicity test result
Table 1 prothioconazoles and the alkene oxime amine toxicity test to powdery mildew of cucumber
As can be seen from the table, the result of the test of different proportion proportioning shows, in the active ingredient ratio, dilutes respectively and all shows stronger synergistic effect, wherein take prothioconazoles: alkene oxime amine is synergistic effect the best as 24:24 the time, and its co-toxicity coefficient is 180.39.Suggestion is carried out further field control effectiveness test to suitable proportion 24:24 left and right mixture preparation, to estimate its field practical application effect.
3 field trials are prevented and treated powdery mildew of cucumber, the experimental result of wheat powdery mildew
3.1 field trial is prevented and treated powdery mildew of cucumber
3.1.1 test method
Test is at 4 points of Pingdu City cucumber Di，Mei community, Shandong investigation, and every some investigation 2 strains, put down in writing occurring degree by staging, and grade scale is as follows:
0 grade: anosis;
1 grade: the sorus area accounts for below 5% of whole leaf area;
3 grades: the sorus area accounts for below the 6%-10% of whole leaf area;
5 grades: the sorus area accounts for below the 11%-20% of whole leaf area;
7 grades: the sorus area accounts for below the 21%-50% of whole leaf area;
9 grades: the sorus area accounts for more than 50% of whole leaf area.
3.1.2 control time and number of times
Test is investigated 4 times altogether, and radix investigation before medicine is investigated after 7 days, 7 days for the second time and medicine after medicine for the first time in 15 days.
3.1.3 drug effect computational methods
Sick leaf rate (%)=sick number of sheets/investigate total number of sheets * 100
Disease index=∑ (the sick numbers of sheets at different levels * relative level numerical value)/(investigating total number of sheets * 9) * 100
Control efficiency (%)=(disease index after disease index before 1-(blank district medicine * treatment region medicine)/(disease index before disease index after blank district medicine * treatment region medicine)) * 100.
3.1.4 poisoning investigation method
After dispenser, whether continuous 15d range estimation medicament has poisoning to crop.
3.1.5 result of the test and analysis
Each processes the effect of preventing and treating powdery mildew of cucumber.(table 2)
Each processes the effect of preventing and treating powdery mildew of cucumber table 2
As shown in Table 2 48% prothioconazoles and alkene oxime amine with 24:24 ratio composite bactericide for powdery mildew of cucumber control successful higher than prothioconazoles and alkene oxime amine single dose, bactericidal effect increases progressively with the increase of dosage.According to the field range estimation, in the test dose scope, plant growth is normal, and the poisoning phenomenon to cucumber does not all appear in each treatment agent, illustrates that it is safe to cucumber.Advise that the bactericide different from the mechanism of action mixes use to delay the drug-fast generation of germ.
3.2 the preventive effect of field trial to wheat powdery mildew
3.2.1 basic condition experimental field:
Experimental field be located at Henan, select the medium wheat paddock of occurring degree for experimental field, soil fertility is medium, and irrigation and drainage are convenient.Dispenser weather on the same day is clear to cloudy, 11 ℃ of mean temperature of air, relative moisture 81%, 2～3 grades of southerlies; After one week, be fine day, 18.2 ℃ of mean temperature of air, relative moisture 60%, 2～3 grades of southerlies.
3.2.2 spraying time and method
At the 1st medicine of wheat powdery mildew their early stage spray, spray medicine for the second time after 10d, spray altogether 2 times.Adopt 3WBS-16 knapsack sprayer (operating pressure 0.2～0.3MPa), according to the per hectare amount of liquid medicine, 750L carries out foliar spray.
3.2.3 pilot survey and data are processed
Investigation state of an illness radix before medicine, test is investigated 3 times altogether, i.e. disease index investigation before medicine, preventive effect investigation in 10 days after the 1st medicine, 10 days and preventive effect investigation in 20 days after 2 medicines.
3.2.4 drug effect computational methods
Sick leaf rate (%)=sick number of sheets/investigate total number of sheets * 100
Disease index=∑ (the sick numbers of sheets at different levels * relative level numerical value)/(investigating total number of sheets * 9) * 100
Control efficiency (%)=(disease index after disease index before 1-(blank district medicine * treatment region medicine)/(disease index before disease index after blank district medicine * treatment region medicine)) * 100.
3.2.5 poisoning investigation method
After dispenser, whether continuous 7d range estimation medicament has poisoning to crop.
3.2.6 experimental result and analysis
Table 3 is respectively organized the test effect that test medicine is processed the control wheat powdery mildew
Interpretation of result:
As shown in Table 3,48% prothioconazoles and alkene oxime amine are more remarkable with the effect of 24:24 ratio compositional bactericidal agent for preventing and treating wheat powdery mildew, and the effect of complex preparation significantly is better than two kinds of single doses, according to field, estimate, in the test dose scope, plant growth is normal, and the poisoning phenomenon to wheat does not all appear in each treatment agent, not only significantly improve the effect for wheat powdery mildew, and further extended its lasting period.
In sum, the bactericidal composition that the present invention contains prothioconazoles and alkene oxime amine, powdery mildew of cucumber and wheat powdery mildew are had to good control efficiency, and it is to the target crop safety.Complex preparation has not only improved preventive effect, and has enlarged fungicidal spectrum, so this compounded combination tool in production practices is of great significance.
Claims (4)
1. a bactericidal composition that contains prothioconazoles and alkene oxime amine, it is characterized in that: the active ingredient of this bactericidal composition is prothioconazoles and alkene oxime amine binary built, all the other are auxiliary element, and wherein the mass ratio of active ingredient prothioconazoles and alkene oxime amine is 1～40: 40～1.
2. bactericidal composition according to claim 1, it is characterized in that: prothioconazoles and the alkene oxime amine gross weight in preparation accounts for 1%～80% of the whole quality of the pharmaceutical preparations.
3. bactericidal composition according to claim 2, it is characterized in that: prothioconazoles and the alkene oxime amine gross weight in preparation accounts for 15%～50% of the whole quality of the pharmaceutical preparations.
4. according to claim 1 or 2 or 3 described bactericidal compositions, it is characterized in that: the formulation of this bactericidal composition is missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion
.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104604881A (en) * | 2013-11-05 | 2015-05-13 | 南京华洲药业有限公司 | Sterilization composition containing fluazinam and prothioconazole as well as application thereof |
| CN112823628A (en) * | 2019-11-21 | 2021-05-21 | 沈阳中化农药化工研发有限公司 | Seed treatment agent containing active component of alkene oxime amine and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1309897A (en) * | 2000-02-24 | 2001-08-29 | 沈阳化工研究院 | Unsaturated oximino ether bactericide |
| WO2002012172A1 (en) * | 2000-08-08 | 2002-02-14 | Dow Agrosciences Llc | Unsaturated oxime ethers and their use as fungicides |
| CN1596644A (en) * | 2003-09-19 | 2005-03-23 | 沈阳化工研究院 | Bacteridal composition containing alkene oxime amine and triazole kind compound |
| CN102972410A (en) * | 2012-12-18 | 2013-03-20 | 广西农喜作物科学有限公司 | Pesticide composition containing prothioconazole and methoxyl acrylic ester bactericides |
-
2013
- 2013-02-25 CN CN2013100571412A patent/CN103070176A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1309897A (en) * | 2000-02-24 | 2001-08-29 | 沈阳化工研究院 | Unsaturated oximino ether bactericide |
| WO2002012172A1 (en) * | 2000-08-08 | 2002-02-14 | Dow Agrosciences Llc | Unsaturated oxime ethers and their use as fungicides |
| CN1596644A (en) * | 2003-09-19 | 2005-03-23 | 沈阳化工研究院 | Bacteridal composition containing alkene oxime amine and triazole kind compound |
| CN102972410A (en) * | 2012-12-18 | 2013-03-20 | 广西农喜作物科学有限公司 | Pesticide composition containing prothioconazole and methoxyl acrylic ester bactericides |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104604881A (en) * | 2013-11-05 | 2015-05-13 | 南京华洲药业有限公司 | Sterilization composition containing fluazinam and prothioconazole as well as application thereof |
| CN104604881B (en) * | 2013-11-05 | 2016-08-17 | 南京华洲药业有限公司 | A kind of containing fluazinam and the bactericidal composition of prothioconazoles and application thereof |
| CN112823628A (en) * | 2019-11-21 | 2021-05-21 | 沈阳中化农药化工研发有限公司 | Seed treatment agent containing active component of alkene oxime amine and application thereof |
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