CN103060093A - Fragrance-invigorating and moisture-retention particles in cigarette and their preparation method and use - Google Patents
Fragrance-invigorating and moisture-retention particles in cigarette and their preparation method and use Download PDFInfo
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- CN103060093A CN103060093A CN201210585262XA CN201210585262A CN103060093A CN 103060093 A CN103060093 A CN 103060093A CN 201210585262X A CN201210585262X A CN 201210585262XA CN 201210585262 A CN201210585262 A CN 201210585262A CN 103060093 A CN103060093 A CN 103060093A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 45
- 235000013599 spices Nutrition 0.000 claims abstract description 43
- 150000007524 organic acids Chemical class 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 22
- 238000002156 mixing Methods 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
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- 238000000576 coating method Methods 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 229920000620 organic polymer Polymers 0.000 claims abstract description 4
- 238000012216 screening Methods 0.000 claims abstract description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 27
- 238000005303 weighing Methods 0.000 claims description 20
- 239000007787 solid Substances 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 16
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 12
- 238000007711 solidification Methods 0.000 claims description 12
- 230000008023 solidification Effects 0.000 claims description 12
- 239000007921 spray Substances 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 10
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims description 9
- 238000007599 discharging Methods 0.000 claims description 9
- 229940016286 microcrystalline cellulose Drugs 0.000 claims description 9
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- 239000008108 microcrystalline cellulose Substances 0.000 claims description 9
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 229940095064 tartrate Drugs 0.000 claims description 7
- 238000004945 emulsification Methods 0.000 claims description 6
- 235000017550 sodium carbonate Nutrition 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- 230000008901 benefit Effects 0.000 claims description 4
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 4
- -1 poly(lactic acid) Polymers 0.000 claims description 4
- 229920002301 cellulose acetate Polymers 0.000 claims description 3
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 235000005985 organic acids Nutrition 0.000 claims description 2
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 2
- 235000015320 potassium carbonate Nutrition 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 abstract description 10
- 238000005469 granulation Methods 0.000 abstract description 10
- 230000003179 granulation Effects 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003546 flue gas Substances 0.000 abstract description 4
- 238000005253 cladding Methods 0.000 abstract 1
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 230000000391 smoking effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 17
- 229920001800 Shellac Polymers 0.000 description 15
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 15
- 229940113147 shellac Drugs 0.000 description 15
- 239000004208 shellac Substances 0.000 description 15
- 235000013874 shellac Nutrition 0.000 description 15
- 238000001694 spray drying Methods 0.000 description 8
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 7
- 239000002131 composite material Substances 0.000 description 7
- 239000000661 sodium alginate Substances 0.000 description 7
- 235000010413 sodium alginate Nutrition 0.000 description 7
- 229940005550 sodium alginate Drugs 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000000796 flavoring agent Substances 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 6
- 239000011246 composite particle Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 241000208125 Nicotiana Species 0.000 description 3
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 235000013355 food flavoring agent Nutrition 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000233855 Orchidaceae Species 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 238000010669 acid-base reaction Methods 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 235000013736 caramel Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
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- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Fats And Perfumes (AREA)
Abstract
The invention relates to fragrance-invigorating and moisture-retention particles in the cigarette and their preparation method and use. The preparation method utilizes a release base material and an organic polymer skeleton as main raw materials and comprises the processes of mixing, cladding, granulation, drying and screening. Through the preparation method, the fragrance-invigorating and moisture-retention particles in the cigarette can be obtained and can be released proactively. The release base material is prepared from an organic acid and a release matrix material. An adopted fragrance-invigorating curing agent comprises an anhydrous solvent, the organic polymer skeleton and spice. The preparation method comprises rotation coating, drying and screening. After contacting mainstream flue gas, the fragrance-invigorating and moisture-retention particles proactively and slowly release the spice and produce water. The fragrance-invigorating and moisture-retention particles can react stably and persistently, can reinforce a cigarette style and smoking quality and has a moisture retention effect.
Description
[technical field]
The invention belongs to the cigarette material technical field, the preparation method and its usage of the fragrant humectation particle of the benefit of particularly adding in the cigarette filter.
[background technology]
The lowering harm and decreasing coking problem is one of countries tobacco sixty-four dollar question.The first half of the year in 2011 whole nation cigarette list props up the weighted mean tar content and drops to below 11 milligrams, and part cigarette product tar content has dropped to below 10 milligrams.Also not rare on 5 milligrams the cigarette market, the cigarette of 1 milligram even 0.1 milligram also comes out.
For reaching the purpose of reducing tar and reducing harm, the technology industries such as filter tip, the fine composite filter of paper/vinegar, natural permeable degree tipping paper, online laser boring have been introduced.In the time of their effective objectionable constituent that reduce in the cigarette smoke, also can be so that corresponding reduction be followed in the aspects such as original suction flavor of cigarette, mouthfeel, physiological strength.Especially the loss of fragrance matter and perfume quantity in the cigarette, easily make taste lose original style, this just need to carry out part and remedy by adding other spices, and one of effect of perfuming is when reducing cigarette harm, remedy the loss of fragrance, provide satisfied product to the human consumer.
Chinese invention patent 200710098075 discloses a kind of manufacturing technology of cigarette filter tip rod capable, it is characterized in that this cigarette filter tip rod capable (being called for short the CAPF filter stick) adopts acetate fibre paper (being called for short CAP paper) as filling filtering material.The CAPF filter stick refers to the various filter stick for cigarettes that adopt CAP paper to make, comprises the filter stick for cigarettes of CAPF filter stick and other kinds composite filter after compound.The CAPF filter stick applies glycerine triacetate or other cellulose acetate softening agent in the moulding process of filter stick except repertoire and external appearance characteristic with paper filter stick, its filter bar can be " curing ", also can be " non-curing ".
Chinese invention patent 201210017865 discloses a kind of sodium alginate particulate and cigarette with filter tip for cigarette filter.This sodium alginate particulate prepares by the following method: viscosity is mixed with sodium alginate soln less than the sodium alginate of 200mpa.s, then add essence and flavoring agent, prepare the sodium alginate particle by dropping method again, final drying namely obtains the sodium alginate particulate.Essence and flavoring agent can be added in the filter tip by this sodium alginate particulate, avoid the Pintsch process of essence and flavoring agent to produce objectionable impurities, can increase the fragrance in the cigarette sucking process simultaneously.
Chinese invention patent 201010239046.0 discloses a kind of novel flavoring filter tip, choose diameter and cause fragrant particle in the 20-40 purpose, by the mouth rod forming machine, in every millimeter mouth rod tow, add equably 3 milligrams and describedly cause fragrant particle, make function mouth rod, described function mouth rod and the excellent Length Ratio by 10: 15 of base are rolled into flavoring filter tip by composite molding machine; Describedly cause fragrant particle and formed in tablets press take aluminosilicate as carrier by weight by following component: 4 parts of cloud and mist absolute oil; 1.5 parts of oak moss absolutes; 0.5 part of tree orchid essential oil; 4 parts of voitols; 15 parts of caramel colorants; 65 parts of propylene glycol; 10 parts in water.Flavoring filter tip of the present invention can make cigarette flavouring material increase on year-on-year basis 17.7%, and the fragrance integrate score increases by 10% on year-on-year basis, and flavoring filter tip length ratio qualification rate reaches 100%.
[summary of the invention]
The inventor utilizes organic acid acid and carbonate mixture to meet water reaction Heat of Formation or CO through research
2With the mechanism of water, set up flue gas Active Compensation system; Heat and CO
2Can take the essence that is added in the soda acid particle out of reach flavor compensating effect when overflowing, the generation of water has then increased the effect that the moisture in the flue gas reaches humectation; Because the aerosol that the fragrance that overflows and moisture form and the similarity of flue gas make compensation effect more obvious.
For this reason, the invention provides the preparation method who mends fragrant humectation particle in a kind of cigarette, step is as follows:
A, preparation discharge base-material: get the organic acid of 1:2 ~ 3:2 and discharge bed material with weight ratio score another name, and for subsequent use;
B, preparation spice solution: take by weighing anhydrous solvent and the spices of 4:1 ~ 9:1 in weight ratio, mix through emulsification or dissolving, obtain spice solution; Described spices is Zimbabwe's extract;
C, preparation solid spice: take by weighing described spice solution and the organic acid of 1:5 ~ 1:20 and discharge bed material in weight ratio, spice solution is sprayed on the described organic acid the air-dry solid spice that obtains;
D, preparation spray solidification agent: take by weighing dehydrated alcohol and the lac of 4:1 ~ 19:1 in weight ratio, dissolving mixes, and obtains the spray solidification agent;
E, organic acid powder preparation: the solid spice of step c and the spray solidification agent of steps d are coated, obtain the organic acid powder; The quality that the coating ratio satisfies the lac in the described spray solidification agent be in the solid spice organic acid quality 4%;
F, release bed material particle: the release bed material of step a and the spray solidification agent of d step are coated, obtain discharging the bed material particle; The coating ratio satisfies the quality of the lac in the described spray solidification agent for discharging 4% of bed material quality;
H, batch mixing: with the release bed material particle of the organic acid powder of step e and step f with ... ratio mixes, then compressing tablet, pulverizing are granulated again to add the vehicle Microcrystalline Cellulose, then dry in baking oven, again the screening choose particle diameter at 18～100 orders with interior product, namely get the fragrant humectation particle of described benefit.
In the present invention, described organic acid is selected from one or more organic acids in Citric Acid, citric acid, tartrate and/or the oxysuccinic acid.
In the present invention, described release bed material is selected from one or more release bed materials of sodium bicarbonate, saleratus, yellow soda ash, Quilonum Retard and/or salt of wormwood.
Preferably, described release base-material and organic acid powder are sieved, choose the above particle of particle diameter 40 orders.
In the present invention, the described organic polymer skeleton of step e is selected from cellulose acetate and/or poly(lactic acid).
In the present invention, described anhydrous solvent is dehydrated alcohol and/or anhydrous propylene glycol.
In the present invention, the quality of described vehicle Microcrystalline Cellulose is described organic acid powder and discharges 10% of bed material particle total mass.
Preferably, the emulsification of step b is ultrasonic emulsification.
The cigarette filter application of lac coatedparticles in cigarette filter that the present invention also provides aforesaid method to obtain, preferably with the cigarette filter length-gauge, the addition of described perfuming particle is 0.5-35mg/mm, the compound 0.5-3.4mg/mm of tow particularly preferably, the compound 15-35mg/mm of cavity.
In the present invention, Zimbabwe's tobacco extract is the product that can buy acquisition on the market, for example Zimbabwe's tobacco extract of Huabao Edible Essence ﹠ Condiment's sale.
In the present invention, coating is undertaken by flat die rolling granulator, for example selects the Shandong Zibo star to be full of the flat die rolling granulator that Mechanology Inc. manufactures.
Similarly, the particle for preparing of the present invention can also be applied to that binary is compound, in the tri compound, cavity composite filter.
Method of the present invention is simple, cost of manufacture is lower, and gained perfuming particle has consolidation homogeneous, the mellow and full advantage such as smooth.The cigarette filter that utilizes the inventive method to prepare has nontoxic with material.Slowly disintegration after particle and the main flume effect produces CO
2Can carry out the active perfuming, can guarantee that fragrance unity, acid-base reaction stable and the suction flavor produce water and reach the humectation effect as the perfuming carrier with water.
[description of drawings]
Fig. 1 is preparation method's schema of the present invention.
[embodiment]
Can understand better the present invention by following embodiment.
Embodiment 1
Take by weighing tartrate 180g, sodium bicarbonate 120g, for subsequent use.
Take by weighing Zimbabwe extract 3g and with dehydrated alcohol 12g it is dissolved, obtain spice solution.
With air-dry behind tartrate and the spice solution mixing homogeneous, obtain air-dry compound.
Take by weighing the 12g lac and be dissolved in the 228g dehydrated alcohol, obtain shellac solution 240g.
With air-dry compound and shellac solution 144g spraying drying, obtain solid spice.
With sodium bicarbonate 120g and shellac solution 96g spraying drying, obtain discharging the bed material particle.
With solid spice and release bed material particle mixing homogeneous; gross weight 300g; add and to mix homogeneous, compressing tablet behind the Microcrystalline Cellulose 30g, pulverize again granulation, the particle that drying is complete sieves to be chosen 20 to 40 orders and is initiatively release type with interior material and mends fragrant humectation particle.
Gained active release type is mended fragrant humectation particle and is applied to the composite particles filter stick formation by addition 2mg/mm, makes binary compound filter candle.Select the finished cigarettes of quality between 0.880-0.900g, remove original filter stick, then the complete active release type particle filter stick of tipping preparation places cigarette 22 ℃, the balance 48h of thermostatic constant wet chamber of 60% humidity.In the spacious environment of smoothness, 22 ℃ of room temperatures, humidity 60% that ventilates, estimate under the environment again.Evaluation result is seen specification sheets subordinate list 1.
Embodiment 2
Take by weighing citric acid 30g, tartrate 20g, Citric Acid 50g, sodium bicarbonate 120g, yellow soda ash 80g, for subsequent use.
It is for subsequent use with its dissolving with dehydrated alcohol 54g to take by weighing Zimbabwe extract 6g, obtains the 60g spice solution.
With air-dry behind organic acid and the spice solution mixing homogeneous, obtain air-dry compound.
Take by weighing the 12g lac and be dissolved in the 48g dehydrated alcohol, obtain the 60g shellac solution.
With air-dry compound and shellac solution 20g spray drying granulation, obtain solid spice.
With sodium bicarbonate 120g and yellow soda ash 80g mixing homogeneous, with shellac solution 40g spray-drying process, obtain discharging the bed material particle.
With solid spice and release bed material particle mixing homogeneous, mix homogeneous, compressing tablet behind the interpolation Microcrystalline Cellulose 30g, pulverize again granulation.The particle that drying is complete sieves to be chosen 20 to 40 orders and is initiatively release type with interior material and mends fragrant particle.
The gained particle is applied to the composite particles filter stick formation by addition 2mg/mm, makes binary compound filter candle.Select the finished cigarettes of quality between 0.880-0.900g, produce red plum board such as Yunnan Yuxi Cigarette Factory, remove original filter stick, the active release type particle filter stick that the tipping preparation is complete.Then cigarette is placed 22 ℃, the balance 48h of thermostatic constant wet chamber of 60% humidity.In the spacious environment of smoothness, 22 ℃ of room temperatures, humidity 60% that ventilates, estimate under the environment again.Evaluation result is seen specification sheets subordinate list 1.
Embodiment 3
Take by weighing citric acid 70g, Citric Acid 80g, yellow soda ash 50g, Quilonum Retard 100g, for subsequent use.
Take by weighing Zimbabwe extract 5g and with dehydrated alcohol 25g it is dissolved, obtain spice solution.
With air-dry behind organic acid and the spice solution mixing homogeneous, obtain air-dry compound.
Get the 12g lac and be dissolved in the 108g dehydrated alcohol, obtain shellac solution.
With the compound after air-dry and shellac solution 60g spray drying granulation, obtain solid spice.
With yellow soda ash 50g, Quilonum Retard 100g mixing homogeneous with shellac solution 60g spray-drying process, obtains discharging the bed material particle.
With solid spice and release bed material particle mixing homogeneous, mix homogeneous, compressing tablet behind the interpolation Microcrystalline Cellulose 30g, pulverize again granulation.The particle that drying is complete sieves to be chosen 20 to 40 orders and is initiatively release type with interior material and mends fragrant particle.
The gained particle is applied to the composite particles filter stick formation by addition 20mg/mm, makes ternary cavity composite filter.Select the finished cigarettes of quality between 0.880-0.900g, remove original filter stick, the active release type particle filter stick that the tipping preparation is complete.Then cigarette is placed 22 ℃, the balance 48h of thermostatic constant wet chamber of 60% humidity.In the spacious environment of smoothness, 22 ℃ of room temperatures, humidity 60% that ventilates, estimate under the environment again.Evaluation result is seen specification sheets subordinate list 1.
Embodiment 4
Take by weighing citric acid 50g, tartrate 100g, saleratus 150g, for subsequent use.
It is for subsequent use with its dissolving with propylene glycol 10g, alcohol 8g to take by weighing Zimbabwe's extract (alcohol extracting part) 3g, obtains spice solution.
With air-dry behind organic acid and the spice solution mixing homogeneous, obtain compound.
Take by weighing the 12g lac and be dissolved in the 168g dehydrated alcohol, obtain shellac solution.
With the compound after air-dry and shellac solution 90g spray drying granulation, obtain solid spice.
With saleratus 150g, with shellac solution 90g spray-drying process, obtain discharging the bed material particle.
With solid spice and release bed material particle mixing homogeneous, mix homogeneous, compressing tablet behind the interpolation Microcrystalline Cellulose 30g, pulverize again granulation.The particle that drying is complete sieves to be chosen 40 to 60 orders and is initiatively release type with interior material and mends fragrant particle.
The gained particle is applied to the composite particles filter stick formation by addition 25mg/mm, makes ternary cavity composite filter.Select the finished cigarettes of quality between 0.880-0.900g, remove original filter stick, the active release type particle filter stick that the tipping preparation is complete.Then cigarette is placed 22 ℃, the balance 48h of thermostatic constant wet chamber of 60% humidity.In the spacious environment of smoothness, 22 ℃ of room temperatures, humidity 60% that ventilates, estimate under the environment again.Evaluation result is seen specification sheets subordinate list 1.
Embodiment 5
Take by weighing tartrate 140g, sodium bicarbonate 160g, for subsequent use.
It is for subsequent use with its dissolving with alcohol 25g to take by weighing Zimbabwe's extract (alcohol extracting part) 5g, obtains spice solution.
With air-dry behind organic acid and the spice solution mixing homogeneous, obtain compound.
Take by weighing the 12g lac and be dissolved in the 108g dehydrated alcohol, obtain shellac solution.
With the compound after air-dry and shellac solution 56g spray drying granulation, obtain solid spice.
With sodium bicarbonate 160g, with shellac solution 64g spray-drying process, obtain discharging the bed material particle.
With solid spice and release bed material particle mixing homogeneous, mix homogeneous, compressing tablet behind the interpolation Microcrystalline Cellulose 30g, pulverize again granulation.The particle that drying is complete sieves to be chosen 20 to 40 orders and is initiatively release type with interior material and mends fragrant particle.
The gained particle is applied to the composite particles filter stick formation by addition 20mg/mm, makes ternary cavity composite filter.
Select the finished cigarettes of quality between 0.880-0.900g, remove original filter stick, then the complete active release type particle filter stick of tipping preparation places cigarette 22 ℃, the balance 48h of thermostatic constant wet chamber of 60% humidity.In the spacious environment of smoothness, 22 ℃ of room temperatures, humidity 60% that ventilates, estimate under the environment again.Evaluation result is seen specification sheets subordinate list 1.
Subordinate list 1
Claims (10)
1. mend the preparation method of fragrant humectation particle in the cigarette, it is characterized in that step is as follows:
A, preparation discharge base-material: get the organic acid of 1:2 ~ 3:2 and discharge bed material with weight ratio score another name, and for subsequent use;
B, preparation spice solution: take by weighing anhydrous solvent and the spices of 4:1 ~ 9:1 in weight ratio, mix through emulsification or dissolving, obtain spice solution; Described spices is Zimbabwe's extract;
C, preparation solid spice: take by weighing described spice solution and the organic acid of 1:5 ~ 1:20 and discharge bed material in weight ratio, spice solution is sprayed on the described organic acid the air-dry solid spice that obtains;
D, preparation spray solidification agent: take by weighing dehydrated alcohol and the lac of 4:1 ~ 19:1 in weight ratio, dissolving mixes, and obtains the spray solidification agent;
E, organic acid powder preparation: the solid spice of step c and the spray solidification agent of steps d are coated, obtain the organic acid powder; The quality that the coating ratio satisfies the lac in the described spray solidification agent be in the solid spice organic acid quality 4%;
F, release bed material particle: the release bed material of step a and the spray solidification agent of d step are coated, obtain discharging the bed material particle; The coating ratio satisfies the quality of the lac in the described spray solidification agent for discharging 4% of bed material quality;
H, batch mixing: the organic acid powder of step e and the release bed material particle of step f are mixed; then compressing tablet, pulverizing are granulated again to add the vehicle Microcrystalline Cellulose; then dry in baking oven, again screening choose particle diameter at 18～100 orders with interior product, namely get the fragrant humectation particle of described benefit.
2. method according to claim 1 is characterized in that described organic acid is selected from one or more organic acids in Citric Acid, citric acid, tartrate and/or the oxysuccinic acid.
3. method according to claim 1 is characterized in that described release bed material is selected from one or more release bed materials of sodium bicarbonate, saleratus, yellow soda ash, Quilonum Retard and/or salt of wormwood.
4. method according to claim 1 and 2 is characterized in that described release base-material and organic acid powder are sieved, and chooses the above particle of particle diameter 40 orders.
5. method according to claim 1 is characterized in that the described organic polymer skeleton of step e is selected from cellulose acetate and/or poly(lactic acid).
6. method according to claim 1 is characterized in that described anhydrous solvent is dehydrated alcohol and/or anhydrous propylene glycol.
7. method according to claim 1, the quality that it is characterized in that described vehicle Microcrystalline Cellulose are described organic acid powder and discharge 10% of bed material particle total mass.
8. method according to claim 1, the emulsification that it is characterized in that step b is ultrasonic emulsification.
9. the cigarette filter that obtains of the described method of claim 1-8 is with the application of lac coatedparticles in cigarette filter.
10. the cigarette filter that obtains of the described method of claim 1-9 is characterized in that with the cigarette filter length-gauge that with the application of lac coatedparticles in cigarette filter the addition of described perfuming particle is 0.5-35mg/mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210585262.XA CN103060093B (en) | 2012-12-28 | 2012-12-28 | Fragrance-invigorating and moisture-retention particles in cigarette and their preparation method and use |
Applications Claiming Priority (1)
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| CN104856223A (en) * | 2015-04-29 | 2015-08-26 | 湖北中烟工业有限责任公司 | Tobacco solid fragrant bead and preparation method of same |
| CN106235391A (en) * | 2016-10-20 | 2016-12-21 | 云南瑞升烟草技术（集团）有限公司 | The preparation method of tobacco flavor compensating particles and the application in reconstituted tobacco thereof |
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| CN114133983A (en) * | 2021-12-01 | 2022-03-04 | 广西中烟工业有限责任公司 | Flavor-enhancing spice, slow-release fragrance-carrying granule and preparation method and application thereof |
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| CN104856223A (en) * | 2015-04-29 | 2015-08-26 | 湖北中烟工业有限责任公司 | Tobacco solid fragrant bead and preparation method of same |
| CN106235391A (en) * | 2016-10-20 | 2016-12-21 | 云南瑞升烟草技术（集团）有限公司 | The preparation method of tobacco flavor compensating particles and the application in reconstituted tobacco thereof |
| CN107455790A (en) * | 2017-07-31 | 2017-12-12 | 云南中烟新材料科技有限公司 | A kind of plant powder material restructuring particle and its processing technology |
| CN107455790B (en) * | 2017-07-31 | 2019-01-11 | 云南中烟新材料科技有限公司 | A kind of plant powder material recombination particle and its processing technology |
| CN109497609B (en) * | 2018-12-12 | 2021-02-02 | 湖北中烟工业有限责任公司 | Cigarette holder rod containing cooling agent and capable of being heated and not combusted |
| CN109497612A (en) * | 2018-12-12 | 2019-03-22 | 湖北中烟工业有限责任公司 | A kind of heating with tea perfume is not burnt cigarette filter tip |
| CN109497609A (en) * | 2018-12-12 | 2019-03-22 | 湖北中烟工业有限责任公司 | A kind of heating containing coolant agent is not burnt cigarette filter tip |
| CN109497613A (en) * | 2018-12-12 | 2019-03-22 | 湖北中烟工业有限责任公司 | It is a kind of for heating the mouth stick for the cigarette that do not burn |
| CN109497612B (en) * | 2018-12-12 | 2021-03-16 | 湖北中烟工业有限责任公司 | A heat-not-burn cigarette holder with tea aroma |
| CN110801049A (en) * | 2019-11-07 | 2020-02-18 | 云南中烟工业有限责任公司 | Cigarette filter tip aroma sustained-release particles and preparation method thereof |
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| CN114133983A (en) * | 2021-12-01 | 2022-03-04 | 广西中烟工业有限责任公司 | Flavor-enhancing spice, slow-release fragrance-carrying granule and preparation method and application thereof |
| CN115316705A (en) * | 2022-09-14 | 2022-11-11 | 广东中烟工业有限责任公司 | Preparation method of colored slow-release fragrant bead, product and application thereof |
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Address after: 850000 Lhasa economic and Technological Development Zone, Tibet autonomous region, road, investment building, Patentee after: HUABAO FLAVOURS & FRAGRANCES CO.,LTD. Address before: 850000 Lhasa economic and Technological Development Zone, Tibet autonomous region, road, investment building, Patentee before: Huabao flavor Ltd. |
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Address after: 850000 Lhasa economic and Technological Development Zone, Tibet autonomous region, road, investment building, Patentee after: Huabao flavor Ltd. Address before: 201821 Yecheng Road, Shanghai, No. 1299, No. Patentee before: Huabao Flavours & Fragrances Co.,Ltd |
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Effective date of registration: 20170123 Address after: 650503 Yunnan province Kunming city Kunming high tech Zone Jinpu rural Metro high-tech industrial base A6-2 Patentee after: YUNNAN XINYUN TECHNOLOGY DEVELOPMENT Co.,Ltd. Address before: 850000 Lhasa economic and Technological Development Zone, Tibet autonomous region, road, investment building, Patentee before: HUABAO FLAVOURS & FRAGRANCES CO.,LTD. |
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Effective date of registration: 20241008 Address after: 335003 Longgang Standard Plant, No. 6, Feiying Road, Longgang Industrial Park, High tech Industrial Development Zone, Yingtan City, Jiangxi Province Patentee after: JIANGXI HUABAO XINHUI TECHNOLOGY Co.,Ltd. Country or region after: China Address before: 650503 new high tech industrial base A6-2, majinpu Township, Kunming high tech Zone, Kunming City, Yunnan Province Patentee before: YUNNAN XINYUN TECHNOLOGY DEVELOPMENT Co.,Ltd. Country or region before: China |