CN103039456A - Synergistic insecticidal composition containing tolfenpxrad and S-fenvalerate and application thereof - Google Patents
Synergistic insecticidal composition containing tolfenpxrad and S-fenvalerate and application thereof Download PDFInfo
- Publication number
- CN103039456A CN103039456A CN2011103150100A CN201110315010A CN103039456A CN 103039456 A CN103039456 A CN 103039456A CN 2011103150100 A CN2011103150100 A CN 2011103150100A CN 201110315010 A CN201110315010 A CN 201110315010A CN 103039456 A CN103039456 A CN 103039456A
- Authority
- CN
- China
- Prior art keywords
- sumicidin
- tolfenpyrad
- synergistic insecticidal
- insecticidal compositions
- synergistic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 41
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 34
- 239000004480 active ingredient Substances 0.000 claims abstract description 18
- 239000003905 agrochemical Substances 0.000 claims abstract description 8
- 241000258937 Hemiptera Species 0.000 claims abstract description 5
- 241000257303 Hymenoptera Species 0.000 claims abstract description 5
- 241000255777 Lepidoptera Species 0.000 claims abstract description 5
- 241000254173 Coleoptera Species 0.000 claims abstract description 4
- 239000000839 emulsion Substances 0.000 claims abstract description 3
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 3
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 claims description 70
- 241000255967 Helicoverpa zea Species 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 229920000742 Cotton Polymers 0.000 claims description 13
- 241000500437 Plutella xylostella Species 0.000 claims description 13
- 241000238631 Hexapoda Species 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- 238000009472 formulation Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 4
- 241000256247 Spodoptera exigua Species 0.000 claims description 3
- 241000339374 Thrips tabaci Species 0.000 claims description 3
- 241001414989 Thysanoptera Species 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- 230000000361 pesticidal effect Effects 0.000 claims description 3
- 239000000375 suspending agent Substances 0.000 claims description 3
- 238000009736 wetting Methods 0.000 claims description 3
- 241000176086 Sogatella furcifera Species 0.000 claims description 2
- 210000004894 snout Anatomy 0.000 claims description 2
- 239000003814 drug Substances 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 8
- 229940079593 drug Drugs 0.000 abstract description 5
- 241000607479 Yersinia pestis Species 0.000 abstract description 4
- 238000001228 spectrum Methods 0.000 abstract description 3
- 239000004562 water dispersible granule Substances 0.000 abstract description 2
- 239000003921 oil Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- -1 polyoxyethylene Polymers 0.000 description 16
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 15
- 238000000034 method Methods 0.000 description 13
- 238000005303 weighing Methods 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 5
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Aalpha Natural products C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 238000004166 bioassay Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 150000004040 pyrrolidinones Chemical class 0.000 description 2
- 231100000820 toxicity test Toxicity 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- UUIPAJHTKDSSOK-UHFFFAOYSA-N (2-nonylphenyl) dihydrogen phosphate Chemical compound CCCCCCCCCC1=CC=CC=C1OP(O)(O)=O UUIPAJHTKDSSOK-UHFFFAOYSA-N 0.000 description 1
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- 208000019300 CLIPPERS Diseases 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000005895 Esfenvalerate Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 241000256602 Isoptera Species 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 241000255969 Pieris brassicae Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 231100000293 acute skin toxicity Toxicity 0.000 description 1
- 231100000403 acute toxicity Toxicity 0.000 description 1
- 230000007059 acute toxicity Effects 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 210000005252 bulbus oculi Anatomy 0.000 description 1
- 208000021930 chronic lymphocytic inflammation with pontine perivascular enhancement responsive to steroids Diseases 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- NYPJDWWKZLNGGM-RPWUZVMVSA-N esfenvalerate Chemical compound C=1C([C@@H](C#N)OC(=O)[C@@H](C(C)C)C=2C=CC(Cl)=CC=2)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-RPWUZVMVSA-N 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 206010023683 lagophthalmos Diseases 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- UUIQMZJEGPQKFD-UHFFFAOYSA-N n-butyric acid methyl ester Natural products CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 description 1
- 231100000194 ovacidal Toxicity 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 230000017448 oviposition Effects 0.000 description 1
- 230000010627 oxidative phosphorylation Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the field of agricultural chemicals and discloses a synergistic insecticidal composition containing tolfenpxrad and S-fenvalerate and an application thereof. The insecticidal composition takes the tolfenpxrad and the S-fenvalerate as main active ingredients, wherein the weight ratio of the tolfenpxrad to the S-fenvalerate is (0.1-80):(0.5-80). The insecticidal composition has the effects of expanding a control spectrum and realizing synergy, can reduce the cost of medication, can be prepared into missible oil, wettable powder, micro-emulsion, aqueous emulsion, suspension and water dispersible granules, and can be used for preparing insecticidal medicaments for controlling lepidoptera, homoptera, hymenoptera, coleoptera and other various pests.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of Synergistic insecticidal compositions and application thereof that contains Tolfenpyrad and S-sumicidin.
Background technology
Tolfenpyrad (Tolfenpyrad), chemical name: 4-chloro-3-ethyl-1-methyl-N-{[4-(4-methylphenoxy) phenyl]-methyl }-1H pyrazoles-5-carboxylic acid amides, be the off-white color pressed powder, density (25 ℃): 1.18g/cm, vapour pressure (25 ℃):＜5 * 10Pa.Solvability (25 ℃): water 0.037mg/L, n-hexane 7.41g/L, toluene 366g/L, methyl alcohol 59.6g/L.Distribution coefficient (n-octyl alcohol/water) (25 ℃): log Pow 5.61.Structural formula is:
The acute toxicity of Tolfenpyrad preparation is: rat oral LD50 102 (hero), 83 (female) mg/kg; Its mouse oral LD50104 (hero), 108 (female) mg/kg.Acute dermal toxicity is relatively low, to rat, mouse LD50 all＞2000mg/kg.Lagophthalmos eyeball and skin there is moderate spread effect.
Tolfenpyrad is the novel pyrazole heterocyclic insecticidal/acaricidal agent of former Mitsubishi chemical company (its agricultural chemicals partly now belong to Japanese agricultural chemicals company) exploitation, its main mechanism is the oxidative phosphorylation that stops insect, also has ovicidal, presses down food, oviposition deterrence and bactericidal action.
S-sumicidin (esfenvalerate) has another name called to come the good fortune spirit, the termite spirit, and chemical name: S-alpha-cyano-3-phenoxy benzyl (S)-2 (4-chlorphenyl)-3 Methylbutanoic acid ester, structural formula is:
The S-sumicidin is the higher pyrethroid insecticides of a kind of activity, and different from sumicidin is that it only contains cis-isomer.But biocidal activity exceeds about 4 times than sumicidin, thereby using dosage is low.
Often there is defective in the insecticide variety that contains single component in the agricultural chemicals control of insect: use is developed immunity to drugs easily continuously, and insecticidal spectrum is narrow, can not provide comprehensive protection for crop, and peasant's drug cost is high.Being combined in to a certain extent and can overcoming to a certain extent above-mentioned shortcoming by two kinds or various active components in the coming year.Have two kinds of synergistic effect or the combination of two or more active components and be mixed, can improve preventive effect, reduce active ingredient ground dosage, save cost, slow down pest resistance occur, and can the expanding prevention spectrum, play that many worms are double to be controlled, reduce peasant's use cost.
Summary of the invention
The purpose of this invention is to provide a kind of Synergistic insecticidal compositions that contains Tolfenpyrad and S-sumicidin, said composition can be used for preventing and treating the various agricultural insect, for example control vegetables diamond-back moth, cabbage caterpillar, control cotton cotton bollworm, beet armyworm and onion thrips etc. can also be used for, the effect that a drug is prevented and treated dissimilar insects can be reached.
Another object of the present invention provides the Synergistic insecticidal compositions that contains Tolfenpyrad and S-sumicidin and prevents and treats application in the insecticidal materials of one or more insects in resistance Lepidoptera, Homoptera, Hymenoptera or the coleoptera in preparation.
The present invention adopts following technical scheme:
A kind of Synergistic insecticidal compositions that contains Tolfenpyrad and S-sumicidin, it is take Tolfenpyrad and S-sumicidin as main active ingredient, and wherein, the weight ratio of Tolfenpyrad and S-sumicidin is 0.1～80: 0.5～80, be preferably 1～60: 1～70, more preferably 1～30: 1～30.The effective ingredient of above-mentioned Insecticidal combinations is present in the composition with the synergy effective dose.
At the Synergistic insecticidal compositions that contains Tolfenpyrad and S-sumicidin of the present invention, the two gross weight percentage composition in this Synergistic insecticidal compositions of Tolfenpyrad and S-sumicidin is 2%～80%, is preferably 8%～60%, and optimum is 20%～40%.
The auxiliary material that described Synergistic insecticidal compositions allows on take Tolfenpyrad and S-sumicidin as main active ingredient and agricultural chemicals is mixed with any one formulation.The preferred pulvis of described formulation, wetting powder, suspending agent, missible oil and water dispersion granule.
Described auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy third rare block compound (such as farming breast 33
#), polyoxyethylene nonylphenol ether etc., perhaps cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (such as propane diols), deionized water etc.Above auxiliary agent and the upper auxiliary material that allows of other agriculturals can alone or also be used.
Application in the insecticidal materials of Synergistic insecticidal compositions of the present invention one or more insects in preparation control Lepidoptera, Homoptera, Hymenoptera, thrips or coleoptera, the preferably application in the insecticidal materials of one or more insects in preparation control cotton cotton bollworm, beet armyworm, onion thrips rice fulgorid or snout moth's larva is particularly preferably in the application in the insecticidal materials of preparation control cotton bollworm and diamond-back moth.
Pesticidal combination of the present invention compared with prior art, produce following beneficial effect: (1) is compared with single dose, said composition has obvious synergistic function to the control of Lepidoptera, Homoptera, Hymenoptera, thrips or coleopteran pest, has obviously improved control efficiency; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost; (3) alternative high-toxic pesticide, and significantly reduce the field dosage, effective environmental contamination reduction and residue of pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with the Tolfenpyrad single dose, produce and the use cost reduction; (6) suppress insect to the resistance enhancing of agricultural chemicals.
Embodiment
Embodiments of the invention are the methods that adopt indoor bioassay and field trial to combine.First by indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage; On this basis, carry out again field trial.
Embodiment 1:
Taking by weighing Tolfenpyrad, S-sumicidin, to adopt the conventional formulation method to be mixed with main active ingredient weight percentage by different proportion be 30% Tolfenpyrad S-fenvalerate missible oil.Concrete ratio sees Table 1.
Adopt feed to add malicious method and measure Tolfenpyrad and S-sumicidin and composite sample thereof to the virulence of cotton cotton bollworm, every processing repeats 3 times, and every concentration is processed 30, uses LC
50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 1 Tolfenpyrad, S-sumicidin and composite sample thereof are to toxicity test and the co-toxicity coefficient of cotton cotton bollworm
Data show in the table, and Tolfenpyrad and S-sumicidin are mixed and rear the cotton cotton bollworm are had synergistic effect, and four listed in table proportioning co-toxicity coefficients are all greater than 120, so Tolfenpyrad and S-sumicidin are mixed and have significant synergistic function.The synergistic function maximum that wherein is mixed when the ratio of S-sumicidin and Tolfenpyrad is 10: 1 and kills the cotton cotton bollworm, co-toxicity coefficient is 138.6
Embodiment 2:
Taking by weighing Tolfenpyrad, S-sumicidin, to adopt the conventional formulation method to be mixed with main active ingredient weight percentage by different proportion be 30% Tolfenpyrad S-fenvalerate missible oil.Concrete ratio sees Table 2.
Adopt infusion process to measure Tolfenpyrad and S-sumicidin and composite sample thereof to the virulence of diamond-back moth, every processing repeats 3 times, uses LC
50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 2 Tolfenpyrad, S-sumicidin and composite sample thereof are to toxicity test and the co-toxicity coefficient of diamond-back moth
Data show in the table, and Tolfenpyrad and S-sumicidin are mixed and rear diamond-back moth are had synergistic effect, and four listed in table proportioning co-toxicity coefficients are all much larger than 120, so Tolfenpyrad and S-sumicidin are mixed and have significant synergies.The synergistic effect maximum that wherein is mixed when the ratio of Tolfenpyrad and S-sumicidin is 1: 5 and kills diamond-back moth, co-toxicity coefficient is 184.9.
Embodiment 3:
Take by weighing 5g Tolfenpyrad, 20g S-sumicidin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 25% Tolfenpyrad S-fenvalerate missible oil.
Adopt 3 sample product of embodiment to carry out the field trial of control in field cotton cotton bollworm, the contrast medicament is 15% Tolfenpyrad EC and 5%S-sumicidin EC, concrete consumption sees Table 3, and with clear water as blank, every mu of water consumption is 30kg, looks into behind the medicine 3 days, 7 days, 14 days, 28 days results, result of the test sees Table 3:
Table 3 example 3 samples are to the field test results of cotton cotton bollworm
3 pairs of cotton cotton bollworms of example have fabulous quick-acting as can be seen from Table 3, and the lasting period is more intense, in the field performance well, are the outstanding medicaments of control cotton cotton bollworm.
Embodiment 4:
Adopt 3 sample product of embodiment to carry out the field trial of control in field vegetables diamond-back moth, the contrast medicament is 15% Tolfenpyrad EC and 5%S-sumicidin EC, and with clear water as blank, concrete consumption sees Table 4, and every mu of water consumption is 30kg, looks into behind the medicine 3 days, 7 days, 14 days, 28 days results, result of the test sees Table 4:
Table 4 example 3 samples are to the field test results of diamond-back moth
Example 3 samples have fabulous effect to diamond-back moth as can be seen from Table 4, and the lasting period is long, in the field performance well, are the outstanding medicaments that prevents diamond-back moth.
Show through indoor synergism test mensuration: by Tolfenpyrad and the agent of S-fenvalerate built cotton cotton bollworm and diamond-back moth are all had significant synergistic insecticidal action; Field control effectiveness test shows that equally also all built agents of the present invention all are significantly higher than the effect of corresponding single dose agricultural chemicals to the insecticidal effect of cotton cotton bollworm and diamond-back moth.
Embodiment 5:
Take by weighing 0.2g Tolfenpyrad, 20gS-sumicidin, lignin 10g, Negel 2g, add to 100g with kaolin, above raw material is mixed in micronizer, form main active ingredient weight percentage and be 20.2% Tolfenpyrad S-sumicidin wetting powder.
Embodiment 6:
Take by weighing 78g Tolfenpyrad, 0.5gS-sumicidin, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, dimethylbenzene and add to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 78.5% Tolfenpyrad S-fenvalerate missible oil.
Embodiment 7:
Take by weighing 2g Tolfenpyrad, 10gS-sumicidin, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butanol 3g, the dimethylbenzene of 30g and the pyrrolidones of 20g, the xanthans of 0.1g, all the other waters are supplied 100g, n-butanol and water-soluble solution form water, and all the other component mix and blends form oil phase, slowly water are added in the oil phase under the clipper effect and go, and continue to shear 10～30 minutes, form main active ingredient weight percentage and be 12% Tolfenpyrad S-fenvalerate aqueous emulsion.
Embodiment 8:
Take by weighing 10g Tolfenpyrad, 30gS-sumicidin, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, the solvent xylene of 30g and the pyrrolidones of 15g, all the other waters complement to 100g, former medicine, solvent, emulsifier, cosolvent mix and blend form homogeneous phase transparent solution, then slowly add entry and stir to form clear solution, be main active ingredient weight percentage and be 40% Tolfenpyrad S-fenvalerate microemulsion.
Embodiment 9:
Take by weighing 4g Tolfenpyrad, 4gS-sumicidin, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 8% Tolfenpyrad S-fenvalerate missible oil.
Embodiment 10:
Take by weighing 3g Tolfenpyrad, 30gS-sumicidin, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, water is supplied 100g, and the main active ingredient weight percentage of formation is 33% Tolfenpyrad S-sumicidin suspending agent under the effect of sand mill.
Embodiment 11:
Take by weighing 5g Tolfenpyrad, 60gS-sumicidin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 65% Tolfenpyrad S-fenvalerate missible oil.
Embodiment 12:
Take by weighing 45g Tolfenpyrad, 5gS-sumicidin, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 28g, it is 50% Tolfenpyrad S-sumicidin water dispersible granules that above raw material is formed main active ingredient weight percentage by the method for water dispersion granule.
Embodiment 13:
Take by weighing 25g Tolfenpyrad, 25gS-sumicidin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 50% Tolfenpyrad S-fenvalerate missible oil.
Claims (10)
1. Synergistic insecticidal compositions that contains Tolfenpyrad and S-sumicidin, it is characterized in that this Synergistic insecticidal compositions is take Tolfenpyrad and S-sumicidin as main active ingredient, wherein, the weight ratio of described Tolfenpyrad and described S-sumicidin is 0.1～80: 0.5～80.
2. the Synergistic insecticidal compositions that contains Tolfenpyrad and S-sumicidin according to claim 1 is characterized in that the effective ingredient Tolfenpyrad of described Pesticidal combination and the weight ratio of S-sumicidin are 1～60: 1～70.
3. the Synergistic insecticidal compositions that contains Tolfenpyrad and S-sumicidin according to claim 2 is characterized in that the effective ingredient Tolfenpyrad of described Pesticidal combination and the weight ratio of S-sumicidin are 1～30: 1～30, preferred 1: 12.
4. the Synergistic insecticidal compositions that contains Tolfenpyrad and S-sumicidin according to claim 1 is characterized in that the two gross weight percentage composition in described Synergistic insecticidal compositions of described Tolfenpyrad and described S-sumicidin is 2%～80%.
5. the Synergistic insecticidal compositions that contains Tolfenpyrad and S-sumicidin according to claim 4 is characterized in that the two gross weight percentage composition in described Synergistic insecticidal compositions of described Tolfenpyrad and described S-sumicidin is 8%～60%.
6. the Synergistic insecticidal compositions that contains Tolfenpyrad and S-sumicidin according to claim 1 is characterized in that the two gross weight percentage composition in described Synergistic insecticidal compositions of described Tolfenpyrad and described S-sumicidin is 20%～40%.
7. the Synergistic insecticidal compositions that contains Tolfenpyrad and S-sumicidin according to claim 1 is characterized in that the auxiliary agent that allows on described Synergistic insecticidal compositions is take Tolfenpyrad and S-sumicidin as main active ingredient and agricultural chemicals is mixed with any one formulation.
8. the Synergistic insecticidal compositions that contains Tolfenpyrad and S-sumicidin according to claim 7 is characterized in that described formulation is missible oil, wetting powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
9. the application of Synergistic insecticidal compositions in preparing the insecticidal materials of preventing and treating one or more insects in Lepidoptera, Homoptera, Hymenoptera, thrips or the coleoptera that contains Tolfenpyrad and S-sumicidin claimed in claim 1.
10. application according to claim 9, it is characterized in that containing the application of Synergistic insecticidal compositions in preparing the insecticidal materials of preventing and treating one or more insects in cotton cotton bollworm, beet armyworm, onion thrips, rice fulgorid or the snout moth's larva of Tolfenpyrad and S-sumicidin, preferably the application in the insecticidal materials of preparation control cotton bollworm and diamond-back moth.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110315010.0A CN103039456B (en) | 2011-10-17 | 2011-10-17 | Synergistic insecticidal composition containing tolfenpxrad and S-fenvalerate and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110315010.0A CN103039456B (en) | 2011-10-17 | 2011-10-17 | Synergistic insecticidal composition containing tolfenpxrad and S-fenvalerate and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103039456A true CN103039456A (en) | 2013-04-17 |
| CN103039456B CN103039456B (en) | 2014-12-17 |
Family
ID=48052503
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110315010.0A Active CN103039456B (en) | 2011-10-17 | 2011-10-17 | Synergistic insecticidal composition containing tolfenpxrad and S-fenvalerate and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103039456B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105851049A (en) * | 2016-05-06 | 2016-08-17 | 烟台图文马克化工科技有限公司 | Insecticide for controlling Phenacoccus solenopsis Tinsley |
| CN109984136A (en) * | 2019-04-09 | 2019-07-09 | 江西正邦作物保护有限公司 | A kind of Pesticidal combination containing Tolfenpyrad and ES- bioallethrin |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006131516A (en) * | 2004-11-04 | 2006-05-25 | Nippon Nohyaku Co Ltd | Pest control composition and method of using the same |
| CN1875712A (en) * | 2005-06-06 | 2006-12-13 | 南京第一农药有限公司 | S-fenvalerate aqueous emulsion and preparation process thereof |
| CN101658178A (en) * | 2009-07-22 | 2010-03-03 | 深圳诺普信农化股份有限公司 | Synergistic insecticidal composition |
| CN101669478A (en) * | 2009-10-13 | 2010-03-17 | 深圳诺普信农化股份有限公司 | Pesticide combination |
| CN101690494A (en) * | 2009-07-15 | 2010-04-07 | 深圳诺普信农化股份有限公司 | Synergistic pesticide composition and use thereof |
-
2011
- 2011-10-17 CN CN201110315010.0A patent/CN103039456B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006131516A (en) * | 2004-11-04 | 2006-05-25 | Nippon Nohyaku Co Ltd | Pest control composition and method of using the same |
| CN1875712A (en) * | 2005-06-06 | 2006-12-13 | 南京第一农药有限公司 | S-fenvalerate aqueous emulsion and preparation process thereof |
| CN101690494A (en) * | 2009-07-15 | 2010-04-07 | 深圳诺普信农化股份有限公司 | Synergistic pesticide composition and use thereof |
| CN101658178A (en) * | 2009-07-22 | 2010-03-03 | 深圳诺普信农化股份有限公司 | Synergistic insecticidal composition |
| CN101669478A (en) * | 2009-10-13 | 2010-03-17 | 深圳诺普信农化股份有限公司 | Pesticide combination |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105851049A (en) * | 2016-05-06 | 2016-08-17 | 烟台图文马克化工科技有限公司 | Insecticide for controlling Phenacoccus solenopsis Tinsley |
| CN109984136A (en) * | 2019-04-09 | 2019-07-09 | 江西正邦作物保护有限公司 | A kind of Pesticidal combination containing Tolfenpyrad and ES- bioallethrin |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103039456B (en) | 2014-12-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103621535A (en) | Synergistic insect disinfestation composition containing clothianidin and chlorantraniliprole, and application thereof | |
| CN103039457B (en) | Synergistic insecticidal composition containing tolfenpxrad and flubendiamide and application thereof | |
| CN103039458A (en) | Insecticidal composition containing tolfenpxrad and pyridalyl and application thereof | |
| CN103053534B (en) | Synergistic insecticidal composition containing tolfenpyrad and chlorantraniliprole and application | |
| CN103621546A (en) | Synergistic insecticidal composition containing clothianidin and imidacloprid and applications thereof | |
| CN103039500A (en) | Synergistic insecticidal composition containing tolfenpxrad and cyfloxylate and application thereof | |
| CN103039456B (en) | Synergistic insecticidal composition containing tolfenpxrad and S-fenvalerate and application thereof | |
| CN103053594A (en) | Synergistic insecticidal composition containing tolfenpyrad and theta-cypermethrin and its application | |
| CN103621532A (en) | Synergistic insecticidal composition containing thiamethoxam and tolfenpyrad and application thereof | |
| CN103053593A (en) | Synergistic insecticidal composition containing Tolfenpyrad and fenpropathrin and its application | |
| CN103651497A (en) | Synergistic insecticidal composition containing clothianidin and flubendiamide and application of synergistic insecticidal composition | |
| CN103053577A (en) | Synergistic insecticidal composition containing tolfenpyrad and indoxacarb and application | |
| CN103053595A (en) | Synergistic insecticidal composition containing tolfenpyrad and beta-cyfluthrin and application | |
| CN103053596A (en) | Synergistic insecticidal composition containing tolfenpyrad and cypermethrin and application | |
| CN103039475A (en) | Synergistic insecticidal composition containing tolfenpxrad and chlorfluazuron and application thereof | |
| CN103039455B (en) | Synergistic insecticidal composition containing tolfenpxrad and flonicamid and application thereof | |
| CN105475339B (en) | A kind of Synergistic insecticidal compositions and its application containing propargite and cycloprothrin | |
| CN103053592A (en) | Synergistic insecticidal composition containing Tolfenpyrad and alpha-cypermethrin and its application | |
| CN103621540B (en) | Synergistic insecticidal composition containing clothianidin and chlorfluazuron and applications thereof | |
| CN103053536A (en) | Synergistic insecticidal composition containing tolfenpyrad and ethofenprox and application | |
| CN103621538A (en) | Synergistic insecticidal composition containing clothianidin and imidaclothiz and applications thereof | |
| CN103053570A (en) | Synergistic insecticidal composition containing tolfenpyrad and metaflumizone and application | |
| CN103621537A (en) | Synergistic insecticidal composition containing clothianidin and banleptm and applications thereof | |
| CN103621541A (en) | Synergistic insecticidal composition containing clothianidin and tolfenpyrad and applications thereof | |
| CN103053535A (en) | Synergistic insecticidal composition containing tolfenpyrad and fenvalerate and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180516 Address after: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Co-patentee after: Nanjing Redsun Co., Ltd. Patentee after: Nanjing Huazhou Pharmaceutical Co., Ltd. Address before: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Patentee before: Nanjing Huazhou Pharmaceutical Co., Ltd. |