CN103039458A - Insecticidal composition containing tolfenpxrad and pyridalyl and application thereof - Google Patents
Insecticidal composition containing tolfenpxrad and pyridalyl and application thereof Download PDFInfo
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- CN103039458A CN103039458A CN2011103156605A CN201110315660A CN103039458A CN 103039458 A CN103039458 A CN 103039458A CN 2011103156605 A CN2011103156605 A CN 2011103156605A CN 201110315660 A CN201110315660 A CN 201110315660A CN 103039458 A CN103039458 A CN 103039458A
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- pyridalyl
- tolfenpyrad
- insecticidal compositions
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Abstract
The invention belongs to the field of agricultural chemicals and discloses an insecticidal composition containing tolfenpxrad and pyridalyl and an application thereof. The insecticidal composition takes the tolfenpxrad and the pyridalyl as main active ingredients, wherein the weight ratio of the tolfenpxrad to the pyridalyl is (0.1-80):(0.5-80). The insecticidal composition has the effects of expanding a control spectrum and realizing synergy, can reduce the cost of medication, can be prepared into missible oil, wettable powder, micro-emulsion, aqueous emulsion, suspension and water dispersible granules, and can be used for controlling lepidoptera, homoptera, hymenoptera, coleoptera and other various pests.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of Pesticidal combination and application thereof that contains Tolfenpyrad and pyridalyl.
Background technology
Tolfenpyrad (Tolfenpyrad), chemical name: 4-chloro-3-ethyl-1-methyl-N-{[4-(4-methylphenoxy) phenyl]-methyl }-1H pyrazoles-5-carboxylic acid amides, be the off-white color pressed powder, density (25 ℃): 1.18g/cm, vapour pressure (25 ℃):＜5 * 10Pa.Solvability (25 ℃): water 0.037mg/L, n-hexane 7.41g/L, toluene 366g/L, methyl alcohol 59.6g/L.Distribution coefficient (n-octyl alcohol/water) (25 ℃): log Pow 5.61.Structural formula is:
The acute toxicity of Tolfenpyrad preparation is: rat oral LD50102 (hero), 83 (female) mg/kg; Its mouse oral LD50104 (hero), 108 (female) mg/kg.Acute dermal toxicity is relatively low, to rat, mouse LD50 all＞2000mg/kg.Lagophthalmos eyeball and skin there is moderate spread effect.
Tolfenpyrad is the novel pyrazole heterocyclic insecticidal/acaricidal agent of former Mitsubishi chemical company (its agricultural chemicals partly now belong to Japanese agricultural chemicals company) exploitation, its main mechanism is the oxidative phosphorylation that stops insect, also has ovicidal, presses down food, oviposition deterrence and bactericidal action.
Pyridalyl (Pyridalyl) has another name called fluoroform pyrrole ether, No. 1, wide side, the U.S. effect of speed, chemical name: 2-[3-[2,6-two chloro-4-[(3,3-two chloro-2-acrylic) the oxygen base] phenoxy group] propoxyl group]-5-(trifluoromethyl) pyrimidine, structural formula is:
Pyridalyl is the pesticide product that the sumitomo chemical company of Tokyo is developed, and it has and has the diverse structure of insecticide now, and the many lepidoptera pests on vegetables and the cotton are had remarkable insecticidal activity.Have simultaneously and tag and stomach poison function, opposite with its high activity, because pyridalyl is very little on various arthropodan impacts.Thereby fabulous protection the target crop.Test shows with other insecticide without cross resistance.
Often there is defective in the insecticide variety that contains single component in the agricultural chemicals control of insect: use is developed immunity to drugs easily continuously, and insecticidal spectrum is narrow, can not provide comprehensive protection for crop, and peasant's drug cost is high.By two kinds or the coming year various active components be combined in to a certain extent the above-mentioned shortcoming of to a certain extent customer service.Have two kinds of synergistic effect or the combination of two or more active components and be mixed, can improve preventive effect, reduce active ingredient ground dosage, save cost, slow down pest resistance occur, and can the expanding prevention spectrum, play that many worms are double to be controlled, reduce peasant's use cost.
Summary of the invention
The purpose of this invention is to provide a kind of Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl, said composition can be used for preventing and treating the various agricultural insect.
Another object of the present invention provides the application of this Synergistic insecticidal compositions.
The present invention adopts following technical scheme:
A kind of Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl, it is take Tolfenpyrad and pyridalyl as main active ingredient, wherein, the weight ratio of Tolfenpyrad and pyridalyl is 0.1～80: 0.5～80, be preferably 1～60: 1～70, more preferably 1～30: 1～30, particularly preferably 1: 1～12.The effective ingredient of above-mentioned Insecticidal combinations is present in the composition with the synergy effective dose.
At the Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl of the present invention, the two weight percentage in this Synergistic insecticidal compositions of Tolfenpyrad and pyridalyl is 2%～80%, is preferably 8%～60%, and optimum is 20%～40%.
Any auxiliary agent that the above-mentioned Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl allows on take Tolfenpyrad and pyridalyl as main active ingredient (active component) and agricultural chemicals is mixed with any one formulation.The preferred pulvis of described formulation, wetting powder, suspending agent, missible oil or water dispersion granule.
Described auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy third rare block compound (such as farming breast 33
#), polyoxyethylene nonylphenol ether, cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (such as propane diols), deionized water etc.Above auxiliary agent can alone or and usefulness.
Application in the insecticidal materials of the above-mentioned Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl one or more insects in preparation control Lepidoptera, Homoptera, Hymenoptera or coleoptera.Especially the effect in the insecticidal materials of preparation control rice fulgorid or snout moth's larva is remarkable.
The application of Synergistic insecticidal compositions in preparing the insecticidal materials of preventing and treating one or more insects in Lepidoptera, Homoptera, Hymenoptera, thrips or the coleoptera that contains Tolfenpyrad and pyridalyl of the present invention.
The preferably application in the insecticidal materials of one or more insects in preparation control cotton cotton bollworm, beet armyworm, onion thrips, rice fulgorid or snout moth's larva of Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl of the present invention.
Pesticidal combination of the present invention compared with prior art, produce following beneficial effect: (1) is compared with single dose, said composition has obvious synergistic function to the control of Lepidoptera, Homoptera, Hymenoptera insect, has significantly improved control efficiency; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost; (3) alternative high-toxic pesticide, and significantly reduce the field dosage, effective environmental contamination reduction and residue of pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with the Tolfenpyrad single dose, produce and the use cost reduction; (6) suppress insect to the resistance enhancing of agricultural chemicals.
Embodiment
Embodiments of the invention are the methods that adopt indoor bioassay and field trial to combine.First by indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage; On this basis, carry out again field trial.
Embodiment 1:
Taking by weighing Tolfenpyrad, pyridalyl, to adopt the conventional formulation method to be mixed with main active ingredient weight percentage by different proportion be 30% Tolfenpyrad pyridalyl missible oil.Concrete ratio sees Table 1.
Adopt feed to add malicious method and measure Tolfenpyrad and pyridalyl and composite sample thereof to the virulence of cotton cotton bollworm, every processing repeats 3 times, and every concentration is processed 30, uses LC
50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 1 Tolfenpyrad, pyridalyl and composite sample thereof are to toxicity test and the co-toxicity coefficient of cotton cotton bollworm
Data show in the table, and Tolfenpyrad and pyridalyl are mixed and rear the cotton cotton bollworm are had synergistic effect, and four listed in table proportioning co-toxicity coefficients are all much larger than 120, so Tolfenpyrad and pyridalyl are mixed and have significant synergistic function.The synergistic function maximum that wherein is mixed when the ratio of pyridalyl and Tolfenpyrad is 2: 1 and kills the cotton cotton bollworm, co-toxicity coefficient is 192.32.
Embodiment 2:
Taking by weighing Tolfenpyrad, pyridalyl, to adopt the conventional formulation method to be mixed with main active ingredient weight percentage by different proportion be 30% Tolfenpyrad pyridalyl missible oil.Concrete ratio sees Table 2.
Adopt rice stem infusion process to measure Tolfenpyrad and pyridalyl and composite sample thereof to the virulence of onion thrips, every processing repeats 3 times, uses LC
50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 2 Tolfenpyrad, pyridalyl and composite sample thereof are to toxicity test and the co-toxicity coefficient of onion thrips
Data show in the table, and Tolfenpyrad and pyridalyl are mixed and rear onion thrips are had synergistic effect, and four listed in table proportioning co-toxicity coefficients are all much larger than 120, so Tolfenpyrad and pyridalyl are mixed and have significant synergistic function.The synergistic function maximum that wherein is mixed when the ratio of Tolfenpyrad and pyridalyl is 1: 5 and kills onion thrips, co-toxicity coefficient is 220.14.
Embodiment 3:
Take by weighing 5g Tolfenpyrad, 20g pyridalyl, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 25% Tolfenpyrad pyridalyl missible oil.
Adopt present embodiment institute sample product to carry out the field trial of control in field cotton cotton bollworm, the contrast medicament is 15% Tolfenpyrad EC and 30% pyridalyl WDG, and concrete consumption sees Table 3, every mu of water consumption is 30kg, looks into 7 days behind the medicine 3 days, 14 days, 28 days results, result of the test sees Table 3:
Table 3 example 3 samples are to the field test results of cotton cotton bollworm
3 pairs of cotton cotton bollworms of example have fabulous quick-acting as can be seen from Table 3, and the lasting period is more intense, in the field performance well, are the outstanding medicaments of control cotton cotton bollworm.
Embodiment 4:
Adopt 3 sample product of embodiment to carry out the field trial of control in field onion thrips, the contrast medicament is 15% Tolfenpyrad EC and 30% pyridalyl WDG, and concrete consumption sees Table 4, every mu of water consumption is 30kg, looks into 7 days behind the medicine 3 days, 14 days, 28 days results, result of the test sees Table 4:
Table 4 example 3 samples are to the field test results of onion thrips
Example 3 samples have fabulous effect to onion thrips as can be seen from Table 4, and the lasting period is long, in the field performance well, are the outstanding medicaments that prevents onion thrips.
Show through indoor synergism test mensuration: by Tolfenpyrad and pyridalyl built agent cotton cotton bollworm and onion thrips are all had significant synergistic insecticidal action; Field control effectiveness test shows that equally also all built agents of the present invention all are significantly higher than the effect of corresponding single dose agricultural chemicals to the insecticidal effect of cotton cotton bollworm and onion thrips.
Embodiment 5:
Take by weighing 0.2g Tolfenpyrad, 20g pyridalyl, lignin 10g, Negel 2g, add to 100g with kaolin, above raw material is mixed in micronizer, form main active ingredient weight percentage and be 20.2% Tolfenpyrad pyridalyl wetting powder.
Embodiment 6:
Take by weighing 78g Tolfenpyrad, 0.5g pyridalyl, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, dimethylbenzene and add to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 78.5% Tolfenpyrad pyridalyl missible oil.
Embodiment 7:
Take by weighing 2g Tolfenpyrad, 10g pyridalyl, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butanol 3g, the dimethylbenzene of 30g and the pyrrolidones of 20g, the xanthans of 0.1g, all the other waters are supplied 100g, n-butanol and water-soluble solution form water, and all the other component mix and blends form oil phase, slowly water are added in the oil phase under the clipper effect and go, and continue to shear 10～30 minutes, form main active ingredient weight percentage and be 12% Tolfenpyrad pyridalyl aqueous emulsion.
Embodiment 8:
Take by weighing 10g Tolfenpyrad, 30g pyridalyl, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, the solvent xylene of 30g and the pyrrolidones of 15g, all the other waters complement to 100g, former medicine, solvent, emulsifier, cosolvent mix and blend form homogeneous phase transparent solution, then slowly add entry and stir to form clear solution, be main active ingredient weight percentage and be 40% Tolfenpyrad pyridalyl microemulsion.
Embodiment 9:
Take by weighing 4g Tolfenpyrad, 4g pyridalyl, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 8% Tolfenpyrad pyridalyl missible oil.
Embodiment 10:
Take by weighing 3g Tolfenpyrad, 30g pyridalyl, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, water is supplied 100g, and the main active ingredient weight percentage of formation is 33% Tolfenpyrad pyridalyl suspending agent under the effect of sand mill.
Embodiment 11:
Take by weighing 5g Tolfenpyrad, 60g pyridalyl, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 65% Tolfenpyrad pyridalyl missible oil.
Embodiment 12:
Take by weighing 45g Tolfenpyrad, 5g pyridalyl, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 28g, it is 50% Tolfenpyrad pyridalyl water dispersible granules that above raw material is formed main active ingredient weight percentage by the method for water dispersion granule.
Embodiment 13:
Take by weighing 25g Tolfenpyrad, 25g pyridalyl, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 50% Tolfenpyrad pyridalyl missible oil.
Claims (10)
1. Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl is characterized in that this Synergistic insecticidal compositions take Tolfenpyrad and pyridalyl as main active ingredient, and wherein, the weight ratio of Tolfenpyrad and pyridalyl is 0.1～80: 0.5～80.
2. the Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl according to claim 1 is characterized in that the effective ingredient Tolfenpyrad of this Pesticidal combination and the weight ratio of pyridalyl are 1～60: 1～70.
3. the Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl according to claim 2 is characterized in that the effective ingredient Tolfenpyrad of this Pesticidal combination and the weight ratio of pyridalyl are 1～30: 1～30, preferred 1: 12.
4. the Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl according to claim 1 is characterized in that the two weight percentage in this Synergistic insecticidal compositions of Tolfenpyrad and pyridalyl is 2%～80%.
5. the Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl according to claim 4 is characterized in that the two weight percentage in this Synergistic insecticidal compositions of Tolfenpyrad and pyridalyl is 8%～60%.
6. the Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl according to claim 5 is characterized in that the two weight percentage in this Synergistic insecticidal compositions of Tolfenpyrad and pyridalyl is 20%～40%.
7. the Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl according to claim 1 is characterized in that any auxiliary agent that allows on this Synergistic insecticidal compositions is take Tolfenpyrad and pyridalyl as main active ingredient and agricultural chemicals is mixed with any one formulation.
8. the Synergistic insecticidal compositions that contains Tolfenpyrad and pyridalyl according to claim 7 is characterized in that described formulation is missible oil, wetting powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
9. the application of Synergistic insecticidal compositions in preparing the insecticidal materials of preventing and treating one or more insects in Lepidoptera, Homoptera, Hymenoptera, thrips or the coleoptera that contains Tolfenpyrad and pyridalyl claimed in claim 1.
10. application according to claim 9 is characterized in that containing the application of Synergistic insecticidal compositions in preparing the insecticidal materials of preventing and treating one or more insects in cotton cotton bollworm, beet armyworm, onion thrips, rice fulgorid or the snout moth's larva of Tolfenpyrad and pyridalyl.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103210924A (en) * | 2013-03-25 | 2013-07-24 | 广东中迅农科股份有限公司 | Insecticidal composition of tolfenpyrad and pyridalyl |
| CN103355306A (en) * | 2012-03-27 | 2013-10-23 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing pyridalyl and amide |
| CN113349212A (en) * | 2021-07-08 | 2021-09-07 | 合肥巨卓农业技术开发有限公司 | Composition containing pyridalyl and tebuconazole |
| CN117694350A (en) * | 2022-01-13 | 2024-03-15 | 青岛海利尔生物科技有限公司 | A kind of insecticidal composition containing fluantraniliprole |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1209798A (en) * | 1996-01-30 | 1999-03-03 | 住友化学工业株式会社 | Dihalopropene compounds, their use as insecticides/acaricides and intermediates for their production |
| JP2006131516A (en) * | 2004-11-04 | 2006-05-25 | Nippon Nohyaku Co Ltd | Pest control composition and method of using the same |
-
2011
- 2011-10-17 CN CN2011103156605A patent/CN103039458A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1209798A (en) * | 1996-01-30 | 1999-03-03 | 住友化学工业株式会社 | Dihalopropene compounds, their use as insecticides/acaricides and intermediates for their production |
| JP2006131516A (en) * | 2004-11-04 | 2006-05-25 | Nippon Nohyaku Co Ltd | Pest control composition and method of using the same |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103355306A (en) * | 2012-03-27 | 2013-10-23 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing pyridalyl and amide |
| CN103210924A (en) * | 2013-03-25 | 2013-07-24 | 广东中迅农科股份有限公司 | Insecticidal composition of tolfenpyrad and pyridalyl |
| CN113349212A (en) * | 2021-07-08 | 2021-09-07 | 合肥巨卓农业技术开发有限公司 | Composition containing pyridalyl and tebuconazole |
| CN117694350A (en) * | 2022-01-13 | 2024-03-15 | 青岛海利尔生物科技有限公司 | A kind of insecticidal composition containing fluantraniliprole |
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Application publication date: 20130417 |