CN102925274A - Optical glass grinding fluid and preparation method thereof - Google Patents
Optical glass grinding fluid and preparation method thereof Download PDFInfo
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- CN102925274A CN102925274A CN2012104447941A CN201210444794A CN102925274A CN 102925274 A CN102925274 A CN 102925274A CN 2012104447941 A CN2012104447941 A CN 2012104447941A CN 201210444794 A CN201210444794 A CN 201210444794A CN 102925274 A CN102925274 A CN 102925274A
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- 238000000227 grinding Methods 0.000 title claims abstract description 48
- 239000012530 fluid Substances 0.000 title claims abstract description 41
- 239000005304 optical glass Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000314 lubricant Substances 0.000 claims abstract description 25
- 239000004094 surface-active agent Substances 0.000 claims abstract description 21
- 229910017053 inorganic salt Inorganic materials 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000013556 antirust agent Substances 0.000 claims abstract description 14
- 238000003756 stirring Methods 0.000 claims abstract description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims abstract 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 16
- 239000002202 Polyethylene glycol Substances 0.000 claims description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims description 14
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- -1 fatty acid ester Chemical class 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 8
- 239000000194 fatty acid Substances 0.000 claims description 8
- 229930195729 fatty acid Natural products 0.000 claims description 8
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 7
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 6
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 239000011780 sodium chloride Substances 0.000 claims description 5
- 229920000289 Polyquaternium Chemical class 0.000 claims description 4
- 150000003863 ammonium salts Chemical group 0.000 claims description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 4
- 101150106031 TRI gene Proteins 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 1
- 238000001816 cooling Methods 0.000 abstract description 6
- 238000004062 sedimentation Methods 0.000 abstract description 6
- 238000004140 cleaning Methods 0.000 abstract description 4
- 239000011521 glass Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 239000002173 cutting fluid Substances 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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Abstract
本发明公开了一种光学玻璃磨削液及其制备方法。所述的一种光学玻璃磨削液按重量百分比计算由9-15%的表面活性剂、8%-12%的防锈剂、3%-7%的润滑剂、0.5%-1%的无机盐、0.3%-0.7%的沉降剂和余量的水组成。其制备方法,即在润滑剂中,依次加入表面活性剂、防锈剂、无机盐、沉降剂及水后,进行搅拌混合均匀,即得光学玻璃磨削液。本发明的光学玻璃磨削液在防锈性、润滑性、冷却性、清洗性方面有很大提高。The invention discloses an optical glass grinding fluid and a preparation method thereof. Described a kind of optical glass grinding fluid is calculated by weight percentage by 9-15% surfactant, 8%-12% antirust agent, 3%-7% lubricant, 0.5%-1% inorganic Salt, 0.3%-0.7% of sedimentation agent and the balance of water. The preparation method is that adding surface active agent, antirust agent, inorganic salt, sedimentation agent and water to the lubricant in sequence, stirring and mixing evenly to obtain the optical glass grinding fluid. The optical glass grinding fluid of the present invention has greatly improved rust resistance, lubricity, cooling performance and cleaning performance.
Description
技术领域 technical field
本发明涉及一种光学玻璃磨削液及其制备方法。 The invention relates to an optical glass grinding fluid and a preparation method thereof.
背景技术 Background technique
玻璃,石英等光学制品在磨削加工时,经常用到水溶性磨削液,由于在磨削过程中产生大量的磨削热和玻璃粉末,因此对玻璃磨削液的冷却性能和清洗性能要求很高,为了提高冷却和清洗性能,磨削液的流量和压力均比较高,加上操作工直接用于接触加工部件,因此要求磨削液无毒无害,气味要小,对皮肤和眼睛的刺激性要低,不产生气雾。 When grinding optical products such as glass and quartz, water-soluble grinding fluid is often used. Since a large amount of grinding heat and glass powder are generated during the grinding process, the cooling performance and cleaning performance of the glass grinding fluid are required Very high, in order to improve the cooling and cleaning performance, the flow rate and pressure of the grinding fluid are relatively high, and the operator is directly used to contact the processing parts, so the grinding fluid is required to be non-toxic and harmless, with a small smell, and it is harmful to the skin and eyes The irritation is low and does not produce aerosol.
目前,光学玻璃,石英行业使用的水溶性磨削液多以聚醚为主要成分,存在冷却性差,气味大,这对操作人员和环境造成不良影响,长期接触会带来操作工健康问题。 At present, the water-soluble grinding fluid used in the optical glass and quartz industries mostly uses polyether as the main component, which has poor cooling performance and strong odor, which has adverse effects on operators and the environment. Long-term exposure will cause health problems for operators.
发明目的purpose of invention
本发明的目的之一是为了解决上述的技术问题而提供了一种光学玻璃磨削液。 One of the objectives of the present invention is to provide an optical glass grinding fluid in order to solve the above-mentioned technical problems.
本发明的目的之二是提供上述的一种光学玻璃磨削液的制备方法。 The second object of the present invention is to provide a method for preparing the above-mentioned optical glass grinding fluid. the
本发明的技术方案 Technical scheme of the present invention
一种光学玻璃磨削液,其中各原料组分按重量百分比计算,其组成及含量如下: A kind of optical glass grinding fluid, wherein each raw material component is calculated by weight percentage, and its composition and content are as follows:
表面活性剂 9%-15% Surfactant 9%-15%
防锈剂 8%-12%
润滑剂 3%-7% Lubricant 3%-7%
无机盐 0.5%-1% Inorganic salt 0.5%-1%
沉降剂 0.3%-0.7% Settore 0.3%-0.7%
余量为水; The remainder is water;
其中所述表面活性剂为聚乙二醇或聚乙二醇脂肪酸酯; Wherein said surfactant is polyethylene glycol or polyethylene glycol fatty acid ester;
所述的防锈剂为单乙醇胺、二乙醇胺及三乙醇胺中的一种或两种以上组成的混合物,优选为二乙醇胺和三乙醇胺; The rust inhibitor is a mixture of one or more of monoethanolamine, diethanolamine and triethanolamine, preferably diethanolamine and triethanolamine;
所述的润滑剂为丙三醇、丙二醇或1,3-丙二醇; Described lubricant is glycerol, propylene glycol or 1,3-propanediol;
所述的无机盐为氯化钠、碳酸钠、碳酸氢钠中的一种或两种以上组成的混合物; The inorganic salt is one or a mixture of two or more of sodium chloride, sodium carbonate, and sodium bicarbonate;
所述的沉降剂为长链烷基双生季铵盐、长链烷基三生季铵盐或聚季铵盐。 The settling agent is long-chain alkyl diquaternary ammonium salt, long-chain alkyl trigene quaternary ammonium salt or polyquaternium salt.
上述的一种光学玻璃磨削液的制备方法,步骤如下: The preparation method of above-mentioned a kind of optical glass grinding fluid, step is as follows:
在润滑剂中,依次加入非离子表面活性剂、防锈剂、无机盐、沉降剂及水后,进行搅拌混合均匀,即得光学玻璃磨削液。 After adding non-ionic surface active agent, anti-rust agent, inorganic salt, sedimentation agent and water into lubricant in sequence, stir and mix evenly to obtain optical glass grinding fluid.
本发明的技术效果 Technical effect of the present invention
本发明的一种光学玻璃磨削液,由于用表面活性剂聚乙二醇,聚乙二醇脂肪酸酯取代了传统的光学玻璃磨削液中的聚醚,因此,本发明的光学玻璃磨削液在润滑性、冷却性、清洗性方面有很大提高。 A kind of optical glass grinding fluid of the present invention, owing to replace the polyether in traditional optical glass grinding fluid with surfactant polyethylene glycol, polyethylene glycol fatty acid ester, therefore, optical glass grinding fluid of the present invention The cutting fluid has greatly improved lubricity, cooling and cleaning properties.
进一步,本发明的一种光学玻璃磨削液,由于添加了沉降剂,因此具有更好的沉降性能。 Furthermore, the optical glass grinding fluid of the present invention has better settling performance due to the addition of a settling agent.
进一步,本发明的一种光学玻璃磨削液中所述的无机盐,对金刚石磨具有良好的化学修锐作用,可以提高玻璃磨削时的磨削效率,所以普遍适用于各种光学玻璃加工。 Further, the inorganic salt described in an optical glass grinding fluid of the present invention has a good chemical sharpening effect on diamond grinding, and can improve the grinding efficiency during glass grinding, so it is generally applicable to various optical glass processing .
进一步,本发明的一种光学玻璃磨削液,由于添加了防锈剂醇胺,润滑剂为丙三醇、丙二醇或1,3-丙二醇,所以在防锈性、润滑性、冷却性能等方面也都具有优越性能。 Further, a kind of optical glass grinding fluid of the present invention, owing to adding antirust agent alcohol amine, lubricant is glycerol, propylene glycol or 1,3-propanediol, so in aspects such as antirust property, lubricity, cooling performance Also have superior performance.
具体实施方式 Detailed ways
下面通过实施例对本发明进一步阐述,但并不限制本发明。 The present invention is further illustrated below by the examples, but the present invention is not limited.
下面各实施例中所用的原料及生产厂家信息如下: The raw materials used in each embodiment below and manufacturer's information are as follows:
表面活性剂:聚乙二醇及聚乙二醇脂肪酸酯,深圳市思利凯贸易有限公司生产; Surfactant: polyethylene glycol and polyethylene glycol fatty acid ester, produced by Shenzhen Silikai Trading Co., Ltd.;
防锈剂:二乙醇胺及三乙醇胺,映泰贸易(上海)有限公司生产; Antirust agent: diethanolamine and triethanolamine, produced by Biostar Trading (Shanghai) Co., Ltd.;
润滑剂:丙三醇、丙二醇及1,3-丙二醇,深圳市一浩化工有限公司生产; Lubricants: glycerol, propylene glycol and 1,3-propanediol, produced by Shenzhen Yihao Chemical Co., Ltd.;
无机盐:氯化钠、碳酸钠及碳酸氢钠,深圳市一浩化工有限公司生产; Inorganic salts: sodium chloride, sodium carbonate and sodium bicarbonate, produced by Shenzhen Yihao Chemical Co., Ltd.;
沉降剂:长链烷基双生季铵盐、长链烷基三生季铵盐或聚季铵盐,上海宏泽化工有限公司生产。 Settling agent: long-chain alkyl geminiquaternary ammonium salt, long-chain alkyl trigene quaternary ammonium salt or polyquaternary ammonium salt, produced by Shanghai Hongze Chemical Co., Ltd.
实施例1Example 1
一种光学玻璃磨削液,其中各原料组分按重量百分比计算,其组成及含量如下: A kind of optical glass grinding fluid, wherein each raw material component is calculated by weight percentage, and its composition and content are as follows:
表面活性剂 9% Surfactant 9%
防锈剂 8%
润滑剂 3% Lubricant 3%
无机盐 0.5%
沉降剂 0.3
水 79.2%; Water 79.2%;
其中所述表面活性剂为聚乙二醇; Wherein said surfactant is polyethylene glycol;
所述的防锈剂为三乙醇胺; Described antirust agent is triethanolamine;
所述的润滑剂为丙三醇; Described lubricant is glycerol;
所述的无机盐为碳酸钠; Described inorganic salt is sodium carbonate;
所述的沉降剂为长链烷基双生季铵盐。 The settling agent is a long-chain alkyl gemini quaternary ammonium salt.
上述的一种光学玻璃磨削液的制备方法,包括如下步骤: The preparation method of above-mentioned a kind of optical glass grinding fluid, comprises the steps:
在润滑剂中,依次加入表面活性剂、防锈剂、无机盐、沉降剂及水后,进行搅拌混合均匀,即得光学玻璃磨削液。 Add surface active agent, antirust agent, inorganic salt, sedimentation agent and water to lubricant in turn, stir and mix evenly to obtain optical glass grinding fluid.
实施例2Example 2
一种光学玻璃磨削液,其中各原料组分按重量百分比计算,其组成及含量如下: A kind of optical glass grinding fluid, wherein each raw material component is calculated by weight percentage, and its composition and content are as follows:
表面活性剂 15% Surfactant 15%
防锈剂 12%
润滑剂 7% Lubricant 7%
无机盐 1%
沉降剂 0.7% 0.7%
水 64.3%; Water 64.3%;
其中所述的表面活性剂为聚乙二醇脂肪酸酯; Wherein said surfactant is polyethylene glycol fatty acid ester;
所述的防锈剂为二乙醇胺; Described antirust agent is diethanolamine;
所述的润滑剂为丙二醇; Described lubricant is propylene glycol;
所述的无机盐为氯化钠; The inorganic salt is sodium chloride;
所述的沉降剂为长链烷基三生季铵盐。 The described settling agent is a long-chain alkyl three-generation quaternary ammonium salt.
上述的一种光学玻璃磨削液的制备方法,包括如下步骤: The preparation method of above-mentioned a kind of optical glass grinding fluid, comprises the steps:
在润滑剂中,依次加入表面活性剂、防锈剂、无机盐、沉降剂及水后,进行搅拌混合均匀,即得光学玻璃磨削液。 Add surface active agent, antirust agent, inorganic salt, sedimentation agent and water to lubricant in turn, stir and mix evenly to obtain optical glass grinding fluid.
实施例3Example 3
一种光学玻璃磨削液,其特征在于所述的光学玻璃磨削液中各原料组分按重量百分比计算,其组成及含量如下: An optical glass grinding fluid, characterized in that each raw material component in the optical glass grinding fluid is calculated by weight percentage, and its composition and content are as follows:
表面活性剂 12.5%
防锈剂 10%
润滑剂 5% Lubricant 5%
无机盐 0.75%
沉降剂 0.5%
水 71.25%; Water 71.25%;
其中所述的表面活性剂为聚乙二醇脂肪酸酯; Wherein said surfactant is polyethylene glycol fatty acid ester;
所述的防锈剂为二乙醇胺; Described antirust agent is diethanolamine;
所述的润滑剂为1,3-丙二醇; Described lubricant is 1,3-propanediol;
所述的无机盐为碳酸氢钠; The inorganic salt is sodium bicarbonate;
所述的沉降剂为聚季铵盐。 The settling agent described is polyquaternium salt.
上述的一种光学玻璃磨削液的制备方法,包括如下步骤: The preparation method of above-mentioned a kind of optical glass grinding fluid, comprises the steps:
在润滑剂中,依次加入表面活性剂、防锈剂、无机盐、沉降剂及水后,进行搅拌混合均匀,即得光学玻璃磨削液。 Add surface active agent, antirust agent, inorganic salt, sedimentation agent and water to lubricant in turn, stir and mix evenly to obtain optical glass grinding fluid.
上述内容仅为本发明构思下的基本说明,而依据本发明的技术方案所作的任何等效变换,均应属于本发明的保护范围。 The above content is only a basic description of the concept of the present invention, and any equivalent transformation made according to the technical solution of the present invention shall belong to the protection scope of the present invention.
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