CN102907437A - Emulsifiable powder of preparation of Cyprodinil and triazole fungicide - Google Patents
Emulsifiable powder of preparation of Cyprodinil and triazole fungicide Download PDFInfo
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- CN102907437A CN102907437A CN201210465642XA CN201210465642A CN102907437A CN 102907437 A CN102907437 A CN 102907437A CN 201210465642X A CN201210465642X A CN 201210465642XA CN 201210465642 A CN201210465642 A CN 201210465642A CN 102907437 A CN102907437 A CN 102907437A
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- Prior art keywords
- cyprodinil
- dispersant
- emulsified powder
- agent
- powder
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- 150000003852 triazoles Chemical class 0.000 title claims abstract 8
- 239000005758 Cyprodinil Substances 0.000 title claims abstract 6
- HAORKNGNJCEJBX-UHFFFAOYSA-N cyprodinil Chemical compound N=1C(C)=CC(C2CC2)=NC=1NC1=CC=CC=C1 HAORKNGNJCEJBX-UHFFFAOYSA-N 0.000 title claims abstract 6
- 230000000855 fungicidal effect Effects 0.000 title abstract 7
- 239000000417 fungicide Substances 0.000 title abstract 7
- 239000004499 emulsifiable powder Substances 0.000 title abstract 5
- 238000002360 preparation method Methods 0.000 title abstract 2
- 239000002270 dispersing agent Substances 0.000 claims abstract 12
- 239000003995 emulsifying agent Substances 0.000 claims abstract 4
- 239000002904 solvent Substances 0.000 claims abstract 4
- 239000000080 wetting agent Substances 0.000 claims abstract 4
- 239000000375 suspending agent Substances 0.000 claims abstract 3
- 239000000843 powder Substances 0.000 claims 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- 210000000481 breast Anatomy 0.000 claims 3
- -1 carbon alcohols Chemical class 0.000 claims 3
- 238000009313 farming Methods 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 2
- 239000003899 bactericide agent Substances 0.000 claims 2
- 229920005551 calcium lignosulfonate Polymers 0.000 claims 2
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims 2
- ZMYFCFLJBGAQRS-IRXDYDNUSA-N (2R,3S)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@@]1(CN2N=CN=C2)[C@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IRXDYDNUSA-N 0.000 claims 1
- JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 claims 1
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims 1
- 239000005995 Aluminium silicate Substances 0.000 claims 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 1
- GSNUFIFRDBKVIE-UHFFFAOYSA-N DMF Natural products CC1=CC=C(C)O1 GSNUFIFRDBKVIE-UHFFFAOYSA-N 0.000 claims 1
- 239000005760 Difenoconazole Substances 0.000 claims 1
- 239000005767 Epoxiconazole Substances 0.000 claims 1
- 239000005787 Flutriafol Substances 0.000 claims 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims 1
- 239000005822 Propiconazole Substances 0.000 claims 1
- 229920002472 Starch Polymers 0.000 claims 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims 1
- 229930006000 Sucrose Natural products 0.000 claims 1
- 239000005839 Tebuconazole Substances 0.000 claims 1
- 235000012211 aluminium silicate Nutrition 0.000 claims 1
- 229960000892 attapulgite Drugs 0.000 claims 1
- 150000003851 azoles Chemical class 0.000 claims 1
- 239000000440 bentonite Substances 0.000 claims 1
- 229910000278 bentonite Inorganic materials 0.000 claims 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000006229 carbon black Substances 0.000 claims 1
- 239000001768 carboxy methyl cellulose Substances 0.000 claims 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 claims 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 1
- 229920000609 methyl cellulose Polymers 0.000 claims 1
- 239000001923 methylcellulose Substances 0.000 claims 1
- 229910052625 palygorskite Inorganic materials 0.000 claims 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims 1
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 claims 1
- 239000000661 sodium alginate Substances 0.000 claims 1
- 235000010413 sodium alginate Nutrition 0.000 claims 1
- 229940005550 sodium alginate Drugs 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 239000008107 starch Substances 0.000 claims 1
- 235000019698 starch Nutrition 0.000 claims 1
- 239000005720 sucrose Substances 0.000 claims 1
- 229920001285 xanthan gum Polymers 0.000 claims 1
- 238000000034 method Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000004480 active ingredient Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an emulsifiable powder of a preparation of Cyprodinil and triazole fungicide, which is a pesticide fungicide taking a Cyprodinil active compound and a triazole fungicide as active ingredients, and the dosage formation can be emulsifiable powder. The emulsifiable powder comprises the following components by mass percent: 5-60% of collarium, 5-60% of triazole fungicide, 0-5% of solvent, 0.5-0.10% of dispersing agent, 0.5-30% of emulsifier, 0-8% of wetting agent, 0.1-5% of suspending agent and the balance of carriers. Because of the reasonable matching of the components of the emulsifiable powder in the invention, especially the added proper amount of emulsifier, the Cyprodinil and triazole fungicide can be guaranteed to be in an emulsifiable state in the water during using, so that the pesticide effects of the Cyprodinil and triazole fungicide can be given into a full play, and the contained organic solvent is much less than missible oil and emulsion in water, the environmental pollution is small, the storage and transportation safety is good, the process is simple and the process cost is low.
Description
Technical field
The invention belongs to formulations of pesticide manufacture field, the novel form that relates to the triazole bactericidal agent complex preparations such as disinfectant use in agriculture cyprodinil and own azoles alcohol, Tebuconazole, Flutriafol, propiconazole, Difenoconazole, epoxiconazole, prothioconazoles, specifically, but the present invention relates to the emulsified powder of a kind of cyprodinil and triazole bactericidal agent complex preparation.
Background technology
The chemical name of cyprodinil (Cyprodinil) is: 4-cyclopropyl-6-methyl-N-phenyl pyrimidine-2-amine; belong to the aminopyrimidine bactericide; have protection, treatment, blade penetrates and the root systemic activity, is the methionine biosynthesis inhibitor, with triazole bactericidal agent without cross resistance.Cyprodinil has formulation products at present mainly take the water dispersion granule formulation as main, but the water dispersion granule formulation is compared the cost of material height much with this preparation.
Common feature is to contain hydroxyl (ketone group), substituted-phenyl and 1,2,4-triazole group compound on the main chain on the triazole bactericidal agent chemical constitution.This class medicament is except to the oomycetes non-activity in the Mastigomycotina, and the pathogen of Ascomycotina, Basidiomycotina and Deuteromycotina is all had activity, and its mechanism of action is damaged somatic cells film function for to affect the sterols biosynthesis.Triazole bactericidal agent is used widely at pesticide field at present, and its preparation formulation kind is also a lot, is generally missible oil, wetting powder, suspending agent, water dispersion granule etc., and mainly there is following shortcoming in these formulations:
Suspending agent, water dispersion granule are compared the cost of material height with this preparation, the suspending agent poor stability should not be stored;
The organic solvent contents such as the dimethylbenzene in the missible oil are relatively high, and environmental pollution is serious, and the transportation storing stability is poor.
Summary of the invention
The objective of the invention is: but cyprodinil that a kind of safety, environmental protection, stable storage, drug effect be higher than other common formulations and the emulsified powder of triazole bactericidal agent complex preparation are provided.
Be to realize the object of the invention, but the invention provides the emulsified powder of a kind of cyprodinil and triazole bactericidal agent complex preparation, it is the agriculture chemicals fungicide take the former medicine of cyprodinil and the former medicine of triazole bactericidal agent as active ingredient, but its formulation is emulsified powder.
But each component and mass percent thereof that emulsified powder of the present invention comprises are: cyprodinil 5%-60%; Triazole bactericidal agent 5%-60%; Solvent 0%-5%; Dispersant 0.5%-10%; Emulsifier 0.5%-30%; Wetting agent 0%-8%; Suspending agent 0.1%-5%; Surplus is carrier.
Described triazole bactericidal agent is one or more in own azoles alcohol, Tebuconazole, Flutriafol, propiconazole, Difenoconazole, epoxiconazole, the prothioconazoles.
Described solvent is solvent naphtha, a kind of in ten four carbon alcohols, dimethylbenzene, toluene, cyclohexanone, DMF, the alkyl pyrrolidone, and solvent quality is relatively less, therefore can reduce oxious component in the solvent to environment.
Described dispersant is a kind of among sodium lignin sulfonate, calcium lignosulfonate, Dispersant MF, dispersing agent C NF, dispersant NNO, the dispersant S, and dispersant helps each component is uniformly dispersed.
Described emulsifier is one or more in farming breast 100, farming breast 500, farming breast 600, the Nongru-700, emulsifier can guarantee that active ingredient cyprodinil and triazole bactericidal agent can reach emulsified state in use in water, so that cyprodinil and triazole bactericidal agent drug effect are not fully exerted.
Described wetting agent is one or more in bay alcohol radical sodium sulphate, neopelex, lauryl sodium sulfate, the wetting agent jfc, wetting agent is by reducing material surface tension force tension force or interfacial tension, makes that substance is more abundant to be mixed with solvent and other components.
Described suspending agent is one or more in methylcellulose, carboxymethyl cellulose, xanthans, sodium alginate, industrial starch, the sucrose, suspending agent can increase settling velocity or the increase particulate hydrophilic additives of viscosity to reduce particulate of dispersion medium, makes dispersion medium be difficult for precipitating.
Described carrier is one or more in diatomite, bentonite, kaolin, attapulgite, White Carbon black, precipitated calcium carbonate, the potter's clay.
But in the emulsified powder of above-mentioned cyprodinil and triazole bactericidal agent complex preparation, preferred dispersants is sodium lignin sulfonate or Dispersant MF; Emulsifier is the combination of farming breast 500, farming breast 600, Nongru-700; Wetting agent is lauryl sodium sulfate or wetting agent jfc; Suspending agent is carboxymethyl cellulose or xanthans; Carrier is potter's clay and White Carbon black.
Technique effect of the present invention is: but the present invention is emulsified powder, because each component collocation rationally, the an amount of emulsifier of particularly allocating into guarantees that more its active ingredient cyprodinil and triazole bactericidal agent can reach emulsified state in use in water, so that cyprodinil and triazole bactericidal agent drug effect are not fully exerted, drug effect (seeing Table 5) when the general formulation that its drug effect of evidence is better than single dose cyprodinil water dispersion granule and triazole bactericidal agent is used with, and contained organic solvent is far less than missible oil and aqueous emulsion, environmental pollution is little, it is good to store with Transport Safety, processing technology is simple, and processing cost is low; And wetting powder, water dispersion granule difficult emulsification in water can not guarantee that the active ingredient in the preparation is not fully exerted, and suspending agent then not only cost of material is high, and poor storage stability.
Embodiment
Below in conjunction with embodiment the present invention is described specifically, the raw materials used industrial goods that all meet the pesticide industry requirement can be buied from market among the embodiment.
But the emulsified powder of cyprodinil of the present invention and triazole bactericidal agent complex preparation, it is the disinfectant use in agriculture take cyprodinil and the former medicine of triazole bactericidal agent as active ingredient, but its formulation is emulsified powder.
But each component and the mass percent thereof that consist of the emulsified powder of cyprodinil and triazole bactericidal agent complex preparation are: cyprodinil 5%-60%; Triazole bactericidal agent 5%-60%; Solvent 0%-5%; Dispersant 0.5%-10%; Emulsifier 0.5%-30%; Wetting agent 0%-8%; Suspending agent 0.1%-5%; Surplus is carrier.
But embodiment 1 preparation 25% cyprodinil propiconazole emulsified powder
(1) prescription sees Table 1
Table 1
(2) preparation
Press each component of formula ratio weighing of table 1, then put into container for stirring and mix, pulverize with airslide disintegrating mill, the control final size is 45 μ m, but packing namely makes the present invention's 25% cyprodinil propiconazole emulsified powder.
Embodiment 2 preparations 45% cyprodinil difenoconazole emulsible powder
(1) prescription sees Table 2
Table 2
(2) preparation
Press each component of formula ratio weighing of table 2, then put into container for stirring and mix, pulverize with airslide disintegrating mill, the control final size is 45 μ m, and packing namely makes the present invention's 45% cyprodinil difenoconazole emulsible powder.
But the own azoles alcohol of embodiment 3 preparation 10% cyprodinils emulsified powder
(1) prescription sees Table 3
Table 3
(3) preparation
Press each component of formula ratio weighing of table 3, then put into container for stirring and mix, pulverize with airslide disintegrating mill, the control final size is 45 μ m, but packing namely makes the own azoles alcohol of the present invention's 10% cyprodinil emulsified powder.
Be crushed on the solids fraction that granularity is 45 μ m but be adsorbed on after the cyprodinil of the present invention of Preparation Example 1-3 and the emulsified powder of triazole bactericidal agent complex preparation also can adopt the liquid composition in will filling a prescription to mix as the case may be; Be adsorbed on the carrier after liquid composition mixes in perhaps will filling a prescription, then pulverize again with after other solids fractions mix, make it granularity and reach 45 μ m.But the performance of prepared the present invention's emulsified powder is not affected by the preparation method.
But embodiment 4 detects the dispersion stabilization of the emulsified powder of cyprodinil of the present invention and triazole bactericidal agent complex preparation
But the dispersion stabilization of emulsified powder detects by the dispersion stabilization in the FAO standard (MT180) method and can reach following requirement:
At 30 ± 2 ℃, 1: 200 in mass ratio, but with the emulsified powder of cyprodinil and triazole bactericidal agent complex preparation with after CIPAC standard water D dilution and stirring, place the container with scale to detect, the initial precipitation object amasss≤0.5mL, and cream (or oil slick)≤0.5mL is floated on top; Place redispersibility after 2 hours: sediment volume≤0.5mL, cream (or oil slick)≤0.5mL is floated on top; The results are shown in table 4.
Table 4
Embodiment 5 tests of pesticide effectiveness (preventing and treating rice sheath blight disease)
The present invention's 45% cyprodinil difenoconazole emulsible powder that adopts embodiment 2 to make mixes use and carries out the test of pesticide effectiveness with 25% Difenoconazole missible oil and 50% cyprodinil water dispersion granule, its active ingredient mu consumption is identical, the results are shown in table 5.
Table 5
Result by table 5 can find out, the preventive effect that the preventive effect of 45% cyprodinil difenoconazole emulsible powder of the present invention (embodiment 2) is higher than 25% Difenoconazole missible oil and 50% cyprodinil water dispersion granule when using with.
But the emulsified powder novel form that the present invention is disinfectant use in agriculture to open up has good drug efficacy, uses and transportation safety, be beneficial to the configuration of preservation and packaging container, transportation and easy to carry, environmental pollution is little, the advantages such as processing technology is simple, and processing cost is low have promotional value; But the control efficiency of the emulsified powder of cyprodinil of the present invention and triazole bactericidal agent complex preparation all is better than other formulations of cyprodinil and triazole bactericidal agent.
Obviously, above-described embodiment only is for example of the present invention clearly is described, and is not to be restriction to embodiments of the present invention.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here need not also can't give all embodiments exhaustive.And these belong to apparent variation or the change that spirit of the present invention extended out and still are among protection scope of the present invention.
Claims (9)
1. but an emulsified powder is characterized in that each component and mass percent thereof that it comprises are: cyprodinil 5%-60%; Triazole bactericidal agent 5%-60%; Solvent 0%-5%; Dispersant 0.5%-10%; Emulsifier 0.5%-30%; Wetting agent 0%-8%; Suspending agent 0.1%-5%; Surplus is carrier.
2. but emulsified powder as claimed in claim 1, it is characterized in that: described triazole bactericidal agent is one or more in own azoles alcohol, Tebuconazole, Flutriafol, propiconazole, Difenoconazole, epoxiconazole, the prothioconazoles.
3. but emulsified powder as claimed in claim 1 or 2, it is characterized in that: described solvent is: a kind of in solvent naphtha, ten four carbon alcohols, dimethylbenzene, toluene, cyclohexanone, DMF, the alkyl pyrrolidone.
4. but emulsified powder as claimed in claim 1 or 2 is characterized in that: described dispersant is a kind of among sodium lignin sulfonate, calcium lignosulfonate, Dispersant MF, dispersing agent C NF, dispersant NNO, the dispersant S.
5. but emulsified powder as claimed in claim 1 or 2 is characterized in that: described emulsifier is in farming breast 100, farming breast 500, farming breast 600, the Nongru-700 one or more.
6. but emulsified powder as claimed in claim 1 or 2, it is characterized in that: described wetting agent is one or more in bay alcohol radical sodium sulphate, neopelex, lauryl sodium sulfate, the wetting agent jfc.
7. but emulsified powder as claimed in claim 1 or 2, it is characterized in that: described suspending agent is one or more in methylcellulose, carboxymethyl cellulose, xanthans, sodium alginate, industrial starch, the sucrose.
8. but emulsified powder as claimed in claim 1 or 2, it is characterized in that: described carrier is one or more in diatomite, bentonite, kaolin, attapulgite, White Carbon black, precipitated calcium carbonate, the potter's clay.
9. but emulsified powder as claimed in claim 3 is characterized in that: described dispersant is a kind of among sodium lignin sulfonate, calcium lignosulfonate, Dispersant MF, dispersing agent C NF, dispersant NNO, the dispersant S.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210465642XA CN102907437A (en) | 2012-11-19 | 2012-11-19 | Emulsifiable powder of preparation of Cyprodinil and triazole fungicide |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210465642XA CN102907437A (en) | 2012-11-19 | 2012-11-19 | Emulsifiable powder of preparation of Cyprodinil and triazole fungicide |
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| CN201210465642XA Pending CN102907437A (en) | 2012-11-19 | 2012-11-19 | Emulsifiable powder of preparation of Cyprodinil and triazole fungicide |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104642334A (en) * | 2013-11-15 | 2015-05-27 | 南京华洲药业有限公司 | Prothioconazole and cyprodinil-containing sterilization composition and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101632361A (en) * | 2009-08-18 | 2010-01-27 | 江苏丰登农药有限公司 | Difenoconazole Emulsifiable Powder |
| CN101642129A (en) * | 2009-06-20 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Sterilization composite |
-
2012
- 2012-11-19 CN CN201210465642XA patent/CN102907437A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101642129A (en) * | 2009-06-20 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Sterilization composite |
| CN101632361A (en) * | 2009-08-18 | 2010-01-27 | 江苏丰登农药有限公司 | Difenoconazole Emulsifiable Powder |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104642334A (en) * | 2013-11-15 | 2015-05-27 | 南京华洲药业有限公司 | Prothioconazole and cyprodinil-containing sterilization composition and application thereof |
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Application publication date: 20130206 |