CN102898231B - Big rounded-grain nitrogen potassium chlorine based binary compound fertilizer and preparation method - Google Patents
Big rounded-grain nitrogen potassium chlorine based binary compound fertilizer and preparation method Download PDFInfo
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- CN102898231B CN102898231B CN201210381367.3A CN201210381367A CN102898231B CN 102898231 B CN102898231 B CN 102898231B CN 201210381367 A CN201210381367 A CN 201210381367A CN 102898231 B CN102898231 B CN 102898231B
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 78
- 150000001875 compounds Chemical class 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- LDFXMGFXFDSLIP-UHFFFAOYSA-N [N].[Cl].[K] Chemical compound [N].[Cl].[K] LDFXMGFXFDSLIP-UHFFFAOYSA-N 0.000 title abstract 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000002245 particle Substances 0.000 claims abstract description 31
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 28
- 235000019270 ammonium chloride Nutrition 0.000 claims abstract description 27
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 238000005469 granulation Methods 0.000 claims description 49
- 230000003179 granulation Effects 0.000 claims description 49
- 239000000463 material Substances 0.000 claims description 16
- 229920000881 Modified starch Polymers 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- 238000005507 spraying Methods 0.000 claims description 8
- 230000002950 deficient Effects 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000003979 granulating agent Substances 0.000 claims description 6
- 238000012216 screening Methods 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 238000013467 fragmentation Methods 0.000 claims description 2
- 238000006062 fragmentation reaction Methods 0.000 claims description 2
- 229930182470 glycoside Natural products 0.000 claims description 2
- 150000002338 glycosides Chemical class 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 11
- 238000004519 manufacturing process Methods 0.000 abstract description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 7
- 239000011591 potassium Substances 0.000 abstract description 7
- 229910052700 potassium Inorganic materials 0.000 abstract description 7
- 239000002689 soil Substances 0.000 abstract description 7
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 6
- 235000015097 nutrients Nutrition 0.000 abstract description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 3
- DHKHZGZAXCWQTA-UHFFFAOYSA-N [N].[K] Chemical compound [N].[K] DHKHZGZAXCWQTA-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 3
- 239000011574 phosphorus Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 239000001103 potassium chloride Substances 0.000 abstract 2
- 235000011164 potassium chloride Nutrition 0.000 abstract 2
- 230000001737 promoting effect Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 6
- 235000016709 nutrition Nutrition 0.000 description 5
- 230000035764 nutrition Effects 0.000 description 5
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 4
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 4
- -1 sulfenyl nitrogen-phosphorus-potassium Nitrogen Chemical compound 0.000 description 3
- WZLMXYBCAZZIRQ-UHFFFAOYSA-N [N].[P].[K] Chemical compound [N].[P].[K] WZLMXYBCAZZIRQ-UHFFFAOYSA-N 0.000 description 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 2
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229930182478 glucoside Natural products 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 235000019837 monoammonium phosphate Nutrition 0.000 description 2
- 239000006012 monoammonium phosphate Substances 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 210000002700 urine Anatomy 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000005696 Diammonium phosphate Substances 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 208000006278 hypochromic anemia Diseases 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Fertilizers (AREA)
Abstract
The invention relates to a big rounded-grain nitrogen potassium chlorine based binary compound fertilizer and a preparation method of the compound fertilizer. Main raw materials of the nitrogen potassium chlorine based binary compound fertilizer are powdery ammonium chloride and powdery potassium chloride, a disk or a drum serve as prilling equipment, a prilling assistant is used for forming the big rounded-grain binary compound fertilizer. The big rounded-grain nitrogen potassium chlorine based binary compound fertilizer is produced, as the prilling and the production are difficult, no similar raw material-shaped nitrogen potassium fertilizer exist in the market at present, and in addition, the fertilizer can meet special requirements for nitrogen and potassium nutrient of region soil containing phosphorus. Compared with an existing manufacture process of the compound fertilizer, the compound fertilizer has the advantages of (1) being low in fertilizer production, (2) being flexible in fertilizer formula, capable of arbitrarily adjusting proportion of the ammonium chloride and the potassium chloride and capable of effectively prilling under effects of the prilling assistant; (3) enabling prilling fertilizers to be high in particle strength and enabling average smashing resisting pressure to be 20-40N; (4) having a wide market; and (5) promoting an additional value of the ammonium chloride and having big profits.
Description
Technical field
The present invention relates to a kind of large round shaped grain shape nitrogen potassium chloro binary compound fertilizer and preparation method, the main raw material of this nitrogen potassium chloro binary compound fertilizer is powdery ammonium chloride and powdery Repone K, adopt disk or drum granulating equipment, utilize granulation aid to make it become large round shaped grain binary compound fertilizer.Make up the blank of this type of fertilizer in the market, meet phosphorous ground region soil to nitrogen, the specific demand of potassium nutrition.
Background technology
Composite fertilizer's quality is various in the market, has diammonium phosphate, the monoammonium phosphate of binary nitrogenous-phosphatic manure, has various chloros, nitro, urine base, sulfenyl nitrogen-phosphorus-potassium Nitrogen, Phosphorus and Potassium.But the binary fertilizer that but there is no nitrogen potassium nutrition, Repone K, ammonium chloride, as a kind of high nutrient simple substance potash fertilizer and simple substance nitrogenous fertilizer, are the indispensable fertilizer varieties of farm crop.
Vast territory and abundant resources in China, the soil characteristic of each region also varies, the phosphorous height of some local soil, this type of soil only needs nitrogen and potassium nutrition, such as Hubei Huang Po, if these local nitrogen phosphorus potassium ternarys of using are fertile, that is exactly a kind of waste, does not also meet the thought of the scientific and reasonable fertilising of China Ministry of Agriculture proposition.
At present, on market, whether there is large round shaped grain binary fertilizer of this type of nitrogen potassium, be mainly because ammonium chloride and Repone K the two all belong to grittiness fertilizer, granulation difficulty, so nitrogen phosphorus potassium unit fertilizer is prepared by adding the better monoammonium phosphate of viscosity by general fertiliser production producer, or composite urea preparation urine base Nitrogen, Phosphorus and Potassium.
In theory, also can mix with powdery ammonium chloride and Repone K, directly use powdered fertilizer, why peasant is unwilling so to have done, and it is bad that reason is exactly powdered fertilizer performance, and fertilising is inconvenient, during granulated fertilizer handling, easily play dirt, long-term storage is very easily lumpd, and is seriously to harden, poor fluidity, during fertilising, be difficult to scatter, cannot realize motor-driven fertilising, simultaneously powdery ammonium chloride and Repone K good water solubility, easily cause the too fast release of nutrient, burn crop to death.
For above-mentioned variety of problems, develop a kind of preparation method of large round shaped grain shape nitrogen potassium chloro binary compound fertilizer, make up the blank of this type of fertilizer in the market, and meet phosphorous soil to nitrogen, the specific demand of potassium nutrition has become the task of top priority.
Summary of the invention
The object of the invention is to make up the blank of this type of fertilizer in the market, meet phosphorous ground region soil to nitrogen, the specific demand of potassium nutrition, overcome because using powdery ammonium chloride and Repone K to mix, directly use powdered fertilizer, cause fertilising inconvenient, during granulated fertilizer handling, easily play dirt, long-term storage is very easily lumpd, and be seriously to harden, poor fluidity, during fertilising, be difficult to scatter, cannot realize motor-driven fertilising, while powdery ammonium chloride and Repone K good water solubility, easily cause the too fast release of nutrient, burn the series of problems such as crop to death, and provide a kind of large round shaped grain shape nitrogen potassium chloro binary compound fertilizer and preparation method, the present invention utilizes existing granulating disc or rotary drum granulator, in ammonium chloride and Repone K, add 5-10 kg/tonne of fertile granulation aid, can complete the preparation of large round shaped grain shape nitrogen potassium chloro binary compound fertilizer, produce granule strength high, fertilizer is being produced, transportation, deposit in process, be difficult for efflorescence.
For achieving the above object, technical scheme of the present invention is:
A kind of large round shaped grain shape nitrogen potassium chloro binary compound fertilizer, it is characterized in that: main raw material is powdery ammonium chloride and powdery Repone K, granulation aid, powdery ammonium chloride and powdery Repone K are mixed, adopt disk or drum granulating equipment, it is 20%-40% solution that granulation aid is mixed with to mass concentration, with atomizing nozzle continuous spraying, on granulation material, make large round shaped grain nitrogen potassium chloro binary compound fertilizer.
The amount that described granulation aid adds is 5-10 ‰ of granulation material total amount.
Described granulation aid, each component by mass percentage, Sumstar 190 20-40%, pre-gelatinized starch 40-60%, wetting agent alkyl glycoside APG 5-20%, each component sum is 100%, and above-mentioned each raw material is mixed and makes granulation aid.
A preparation method for large round shaped grain shape nitrogen potassium chloro binary compound fertilizer, is characterized in that: carry out according to the following steps:
(1) ammonium chloride of powdery is mixed with arbitrary proportion with Repone K; Also can support needs according to difference, allocate a small amount of wilkinite dilution nutrient into;
(2) mixture is put in granulating disc or rotary drum granulator, started granulating equipment;
(3) 5-10 ‰ the granulating agent that accounts for granulation material total amount being mixed with to mass concentration is 20%-40% solution, uses atomizing nozzle continuous spraying on granulation material;
(4) the round shaped grain shape nitrogen potassium chloro binary compound fertilizer particle of making is sent into drying system, be dried;
(5) dried round shaped grain shape nitrogen potassium chloro binary compound fertilizer is entered to screening system, sieve;
(6) qualified particle is packed, defective particle fragmentation enters tablets press as returning charge.
Large the round shaped grain shape nitrogen potassium chloro binary compound fertilizer that utilizes the present invention to make, the advantage of its more existing compound fertilizer production technology:
(1) fertiliser production cost is low.
(2) fertilizer formula is flexible, can adjust arbitrarily ammonium chloride and Repone K ratio, under the effect of granulation aid, and equal effective granulating.
(3) the fertiliser granulates intensity of producing is high, average anti-crushing pressure 20-40N.
(4) there is extensive market.
(5) promote powdery ammonium chloride, the added value of Repone K, has larger profit.
Embodiment
Below provide the present invention to prepare four embodiment of large round shaped grain fertilizer method.
Embodiment 1
Granulation aid be each component by mass percentage, Sumstar 190 30%, pre-gelatinized starch 60%, octadecyl glucosides 10%, mixes above-mentioned each raw material to make granulation aid, Sumstar 190, pre-gelatinized starch, octadecyl glucosides are all bought from market.
Fertilizer type: large round shaped grain shape nitrogen potassium chloro binary compound fertilizer (N-P
20
5-K
2o is 4-0-50)
Granulation process: disc granulation
Granulation fertilizer material formula: powdery Repone K (K
2o>=60) 834 grams
158 grams of powdery ammonium chlorides (N >=25.4),
8 grams of granulation aid
Each component sum is 1000 grams.
Large round shaped grain shape nitrogen potassium chloro N-P
20
5-K
2o is 4-0-50 binary compound fertilizer production technique:
(1) Repone K of 834 grams of powderies is mixed with 158 grams of ammonium chlorides.
(2) mixture is put in granulating disc, started granulating equipment.
(3) 8 grams of granulating agents being mixed with to mass concentration is 20% solution, uses atomizing nozzle continuous spraying on granulation material.
(4) the round shaped grain shape nitrogen potassium chloro binary compound fertilizer particle of making is sent into drying system, be dried.
(5) dried round shaped grain shape nitrogen potassium chloro binary compound fertilizer is entered to screening system, sieve.
(6) qualified particle is packed, defective particle (oversized particles or excessively small-particle) is broken enters tablets press as returning charge.
The anti-crushing pressure that records qualified particle is 40N.
Embodiment 2
Granulation aid be each component by mass percentage, Sumstar 190 20%, pre-gelatinized starch 60%, Alkyl Polyglycoside of Hexadecyl 20%, mixes above-mentioned each raw material to make granulation aid, Sumstar 190, pre-gelatinized starch, Alkyl Polyglycoside of Hexadecyl are all bought from market.
Fertilizer type: large round shaped grain shape nitrogen potassium chloro binary compound fertilizer (N-P
20
5-K
2o is 8-0-40)
Granulation process: disc granulation
Granulation fertilizer material formula: powdery Repone K (K
2o>=60) 669 grams
326 grams of powdery ammonium chlorides (N >=25.4),
5 grams of granulation aid
Each component sum is 1000 grams.
Large round shaped grain shape nitrogen potassium chloro N-P
20
5-K
2o is 8-0-40 binary compound fertilizer production technique:
(1) Repone K of 669 grams of powderies is mixed with 326 grams of ammonium chlorides.
(2) mixture is put in granulating disc, started granulating equipment;
(3) 5 grams of granulating agents being mixed with to mass concentration is 40% solution, uses atomizing nozzle continuous spraying on granulation material.
(4) the round shaped grain shape nitrogen potassium chloro binary compound fertilizer particle of making is sent into drying system, be dried.
(5) dried round shaped grain shape nitrogen potassium chloro binary compound fertilizer is entered to screening system, sieve.
(6) qualified particle is packed, defective particle (oversized particles or excessively small-particle) is broken enters tablets press as returning charge.
The anti-crushing pressure that records qualified particle is 37N.
Embodiment 3
Granulation aid be each component by mass percentage, Sumstar 190 40%, pre-gelatinized starch 55%, Dodecyl Glucoside 5%, mixes above-mentioned each raw material to make granulation aid, Sumstar 190, pre-gelatinized starch, Dodecyl Glucoside are all bought from market.
Fertilizer type: large round shaped grain shape nitrogen potassium chloro binary compound fertilizer (N-P
20
5-K
2o is 12.5-0-30)
Granulation process: disc granulation
Granulation fertilizer material formula: powdery Repone K (K
2o>=60) 500 grams
490 grams of powdery ammonium chlorides (N >=25.4),
10 grams of granulation aid
Each component sum is 1000 grams.
Large round shaped grain shape nitrogen potassium chloro N-P
20
5-K
2o is 12.5-0-30 binary compound fertilizer production technique:
(1) Repone K of 500 grams of powderies is mixed with 490 grams of ammonium chlorides.
(2) mixture is put in granulating disc or rotary drum granulator, started granulating equipment;
(3) 10 grams of granulating agents being mixed with to mass concentration is 30% solution, uses atomizing nozzle continuous spraying on granulation material.
(4) the round shaped grain shape nitrogen potassium chloro binary compound fertilizer particle of making is sent into drying system, be dried.
(5) dried round shaped grain shape nitrogen potassium chloro binary compound fertilizer is entered to screening system, sieve.
(6) qualified particle is packed, defective particle (oversized particles or excessively small-particle) is broken enters tablets press as returning charge.
The anti-crushing pressure that records qualified particle is 36N.
Embodiment 4
Granulation aid be each component by mass percentage, Sumstar 190 40%, pre-gelatinized starch 40%, Dodecyl Glucoside 20%, mixes above-mentioned each raw material to make granulation aid, Sumstar 190, pre-gelatinized starch, Dodecyl Glucoside are all bought from market.
Fertilizer type: large round shaped grain shape nitrogen potassium chloro binary compound fertilizer (N-P
20
5-K
2o is 10-0-30)
Granulation process: drum granulating
Granulation fertilizer material formula: powdery Repone K (K
2o>=60) 500 grams
394 grams of powdery ammonium chlorides (N >=25.4)
100 grams of wilkinites
6 grams of granulation aid
Each component sum is 1000 grams.
Large round shaped grain shape nitrogen potassium chloro N-P
20
5-K
2o is 10-0-30 binary compound fertilizer production technique:
(1) by the Repone K of 500 grams of powderies and 394 grams of ammonium chlorides, and 100 grams of wilkinites mix.
(2) mixture is put in rotary drum granulator, started granulating equipment;
(3) 6 grams of granulating agents being mixed with to mass concentration is 25% solution, uses atomizing nozzle continuous spraying on granulation material.
(4) the round shaped grain shape nitrogen potassium chloro binary compound fertilizer particle of making is sent into drying system, be dried.
(5) dried round shaped grain shape nitrogen potassium chloro binary compound fertilizer is entered to screening system, sieve.
(6) qualified particle is packed, defective particle (oversized particles or excessively small-particle) is broken enters tablets press as returning charge.
The anti-crushing pressure that records qualified particle is 28N.
Claims (2)
1. one kind large round shaped grain shape nitrogen potassium chloro binary compound fertilizer, it is characterized in that: main raw material is powdery ammonium chloride and powdery Repone K, granulation aid, powdery ammonium chloride and powdery Repone K are mixed, adopt disk or drum granulating equipment, it is 20%-40% solution that granulation aid is mixed with to mass concentration, with atomizing nozzle continuous spraying, on granulation material, make large round shaped grain nitrogen potassium chloro binary compound fertilizer;
The amount that described granulation aid adds is 5-10 ‰ of granulation material total amount;
Described granulation aid, each component by mass percentage, Sumstar 190 20-40%, pre-gelatinized starch 40-60%, wetting agent alkyl glycoside APG 5-20%, each component sum is 100%, and above-mentioned each raw material is mixed and makes granulation aid, prepares large round shaped grain shape nitrogen potassium chloro binary compound fertilizer.
2. the preparation method of large round shaped grain shape nitrogen potassium chloro binary compound fertilizer according to claim 1, is characterized in that: carry out according to the following steps:
(1) ammonium chloride of powdery is mixed with arbitrary proportion with Repone K;
(2) mixture is put in granulating disc or rotary drum granulator, started granulating equipment;
(3) 5-10 ‰ the granulating agent that accounts for granulation material total amount being mixed with to mass concentration is 20%-40% solution, uses atomizing nozzle continuous spraying on granulation material;
(4) the round shaped grain shape nitrogen potassium chloro binary compound fertilizer particle of making is sent into drying system, be dried;
(5) dried round shaped grain shape nitrogen potassium chloro binary compound fertilizer is entered to screening system, sieve;
(6) qualified particle is packed, defective particle fragmentation enters tablets press as returning charge.
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|---|---|---|---|
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|---|---|---|---|
| CN201210381367.3A CN102898231B (en) | 2012-10-09 | 2012-10-09 | Big rounded-grain nitrogen potassium chlorine based binary compound fertilizer and preparation method |
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| CN102898231B true CN102898231B (en) | 2014-10-22 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103553800B (en) * | 2013-10-31 | 2014-12-31 | 湖北富邦科技股份有限公司 | Production method of high-concentration potassium chloride pellet |
| CN107935703A (en) * | 2017-12-04 | 2018-04-20 | 中化化肥有限公司成都研发中心 | Urinate base nitro binary compound fertilizer containing nitrogen and potassium production method |
| CN115043686A (en) * | 2022-06-06 | 2022-09-13 | 青海国润农业科技有限公司 | Regular round granular potash fertilizer granulation auxiliary agent and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1377861A (en) * | 2002-04-15 | 2002-11-06 | 葛建华 | High efficiency organic composite fertilizer and preparing method |
| CN1769248A (en) * | 2004-11-05 | 2006-05-10 | 上海化工研究院 | A kind of manufacture method of granular potassium chloride |
| CN102267826A (en) * | 2010-06-01 | 2011-12-07 | 吴绍山 | Composite fertilizer production method utilizing amino acid |
| CN102503634A (en) * | 2011-10-27 | 2012-06-20 | 山西师范大学 | Urea-base compound fertilizer production technique |
-
2012
- 2012-10-09 CN CN201210381367.3A patent/CN102898231B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1377861A (en) * | 2002-04-15 | 2002-11-06 | 葛建华 | High efficiency organic composite fertilizer and preparing method |
| CN1769248A (en) * | 2004-11-05 | 2006-05-10 | 上海化工研究院 | A kind of manufacture method of granular potassium chloride |
| CN102267826A (en) * | 2010-06-01 | 2011-12-07 | 吴绍山 | Composite fertilizer production method utilizing amino acid |
| CN102503634A (en) * | 2011-10-27 | 2012-06-20 | 山西师范大学 | Urea-base compound fertilizer production technique |
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Effective date of registration: 20191022 Address after: 430074 No.288, shendunsan Road, Donghu New Technology Development Zone, Wuhan base, phase I, building a, 1-3 floors, 1, 3 floors, north, Zone C, building a Patentee after: Wuhan He Da Technology Co., Ltd. Address before: 432400, Xiaogan, Hubei City Economic and Technological Development Zone, South Road, No. 1 Patentee before: Hubei Forbon Technology Co., Ltd. |
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