CN102835414A - Composition containing sulfoxaflor and amide pesticides - Google Patents
Composition containing sulfoxaflor and amide pesticides Download PDFInfo
- Publication number
- CN102835414A CN102835414A CN2012103653496A CN201210365349A CN102835414A CN 102835414 A CN102835414 A CN 102835414A CN 2012103653496 A CN2012103653496 A CN 2012103653496A CN 201210365349 A CN201210365349 A CN 201210365349A CN 102835414 A CN102835414 A CN 102835414A
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- Prior art keywords
- amide
- composition
- active component
- worm amine
- fluorine
- Prior art date
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a composition containing sulfoxaflor and amide pesticides. The composition is composed of active ingredient, auxiliaries and excipients; the weight percent of the active ingredient in the composition is 2-50%; the active ingredient is composed of A and B active components; the active component A is sulfoxaflor; the active component B is selected from any one of tolfenpyrad or cyantraniliprole, and the weight ratio of the active component A to the active component B is 1:50 to 50:1. Grain crop and industrial crop are subjected to pest control by the composition; the problems that the pesticide with a single active ingredient is narrow in a control spectrum in pest control of agriculture, the insect pest easily generates resistance, and food and environment are polluted due to excessive dosage are solved; the composition has the advantages of being convenient to process, low in cost, good in pesticide effect, long in persistent effect, and high in synergetic effect; the environmental pollution can be reduced; the pesticide utilization rate is improved, and the application amount of the pesticides is reduced.
Description
Technical field
The invention belongs to insect chemical control technical field, be specifically related to contain fluorine pyridine worm amine nitrile and amide-type insecticide composition.
Background technology
Fluorine pyridine worm amine nitrile is by the agricultural development of new insecticide of Tao Shi benefit, English name: sulfoxaflor, chemical name: [1-6-(trifluoromethyl) pyridin-3-yl] ethyl]-λ 4-sulfydryl cyanamide, molecular formula is C
10H
10F
3N
3OS; Molecular weight: 277.27; CAS: [946578-00-3]; CIPAC No:820; Structural formula:
The mode of action of fluorine pyridine worm amine nitrile is to activate the acetylcholinergic receptor of insect; But the mode that acts on acceptor is different and novel; Homoptera pest such as aphid, plant hopper etc. had excellent insecticidal activity; And have efficient, quick-acting, low toxicity, low-residual, interior absorption is good, the duration long, to advantages such as non-target organism safety; Be applicable to tree fruit, grape, vegetables, cotton, paddy rice, cereal and big legume crop, can effectively kill insects such as aphid, scale insect, plant hopper, aleyrodid, fleahopper and thrips.
The azoles insect amide is a novel pyrazole heterocyclic insecticidal/acaricidal agent, and English name is Tolfenpyrad, and molecular formula is C
21H
22ClN
3O
2, chemical name is 4-chloro-3-ethyl-1-methyl-N-{ [4-(4-methylphenoxy) phenyl]-methyl }-1H pyrazoles-5-carboxylic acid amides, chemical structural formula does
The azoles insect amide has active height, acts on the advantage fast, that the lasting period is long, insecticidal spectrum is wide; And have extremely ovum concurrently, press down food, suppress to lay eggs and bactericidal action; It is all effective to various Lepidopteras, Semiptera, beetle order, Hymenoptera, diptera, thrips and mite class, and the mechanism of action is passed on the complex I of system for the electronics that hinders in the mitochondrial metabolic system, is hindered thereby electronics is passed on; Insect can not be provided and storing energy, be called as the mitochondria electronics and pass on complex Inhibitors (METI).
The cyanogen insect amide English name is Cyantraniliprole; Trade name is CyazypyrTM; Test code number is DPX-HGW86; Chemical name is 3-bromo-N-(4-cyanic acid-2-methyl-6-(amino-carbonyl) phenyl)-1-(3-chloropyridine-2-yl)-1H-pyrazoles-5-carboxylic acid amides, is the novel O-formammidotiazol-benzamide insecticide that du pont company develops, and its chemical structural formula does
Cyanogen insect amide belongs to insect ryania acceptor inhibitor; Mainly calcium ion release shows and tags and stomach poison function in the striated muscle through inducing insect ryania receptor modulators and the smooth muscle cell; Can be used for the control of various crop insects such as paddy rice, vegetables, cotton, beet; Especially the control to various lepidoptera pests and sucking pest has special efficacy; Its control efficiency is remarkable in other commercialization insecticide varieties that use in the current production, and there is not cross resistance in other insecticides.Therefore, cyanogen insect amide is described as efficient pesticides of new generation in the world.
At present, because the popularization of single agent product makes insect strengthen just gradually the active component pesticide resistance.For the control of insect that is prone to produce resistance on the agricultural; Main way is that exploitation and existing kind do not have composite between new component or the existing pesticide species of cross resistance; The former is because required development cost is high, the cycle is long, and at present development rate far away less than the speed of pest resistance to insecticide generation.Therefore, being mixed for the different existing pesticide species of the mechanism of action is best selection.If reasonable mixture ratio then can produce significant synergistic effect, make field control effect significantly be superior to the effect of each single agent.Usually there is certain defective in the insecticide that contains the single-activity composition on agricultural insect pests control; Continuous several times is used and is not only made insect be easy to generate pesticide resistance; And be prone to cause pollution, can overcome above shortcoming through rationally being mixed between the pesticide active ingredient to food and environment.The reasonably composite simultaneously synergistic effect that active ingredient is produced can improve preventive effect, reduces effective ingredient consumption, practices thrift cost, delays the drug-fast generation of insect, and then can alleviate even avoid the pollution of agricultural chemicals to food and environment.
Summary of the invention
The objective of the invention is problem to above-mentioned use single-activity ingredients for preventing and treating insect existence; A kind of fluorine-containing pyridine worm amine nitrile and amide-type insecticide composition are provided; Reduce medicament usage amount and frequency of utilization, reduce environmental pressure, and delay the generation of pest resistance to insecticide.
The present invention realizes that the technical scheme that above-mentioned purpose is taked is: a kind of fluorine-containing pyridine worm amine nitrile and amide-type insecticide composition; Form by active ingredient, auxiliary agent and excipient; Wherein, the weight percent content that active ingredient accounts for composition is 2～50%, and active ingredient is made up of A and two kinds of active components of B; Active component A is a fluorine pyridine worm amine nitrile, and active component B is selected from any in azoles insect amide or the cyanogen insect amide; The weight ratio of active component A and active component B is 1:50～50:1.
The weight percent content that described active ingredient accounts for composition is preferably 5～30%, and the weight ratio of active component A and active component B is preferably 1:25～25:1.
Described auxiliary agent is an AEO; Castor oil polyoxyethylene ether; APES; The phenethyl phenol polyethenoxy ether; Phenethyl phenol polyethenoxy formaldehyde condensation products; Phenethyl phenol polyethenoxy ether polyethenoxy ether; Alkylaryl polyoxyethylene polyoxypropylene ether; Aliphatic alcohol polyoxyvinethene phosphate; The APES phosphate; Phenethyl phenol polyethenoxy ether phosphate; Alkylaryl polyoxyethylene polyoxypropylene ether phosphate; Methyl naphthalene sulfonate formaldehyde condensate; The nekal formaldehyde condensation products; Alkylphenol-polyethenoxy formaldehyde condensation products sulphate; The aliphatic alcohol polyethenoxy polyethenoxy ether; Sodium lignin sulfonate; Calcium dodecyl benzene sulfonate; Lauryl sodium sulfate; The combination of one or more in calcium lignosulfonate or the Negel.
Described excipient is acetone, cyclohexanone, trimethylbenzene, xylol, o-dichlorohenzene, methyl-propyl benzene, methyl naphthalene, acetophenone, ethanol, ethylene glycol, glycerine, phenmethylol, methyl-sulfoxide, N-Methyl pyrrolidone, N; Dinethylformamide, DMAC N,N, deionized water, water, glycerine, soybean oil, cottonseed oil, rapeseed oil, castor oil, corn oil, turpentine oil, methyl oleate, ethyl oleate, organosilicon, Sodium Benzoate, xanthans, draw back one or more the combination in powder, sodium carboxymethylcellulose, sodium carboxymethyl starch, sodium alginate, Magnesiumaluminumsilicate, N-methyl acetyl sodium taurocholate, white carbon, bentonite or the attapulgite.
Described fluorine-containing pyridine worm amine nitrile and amide-type insecticide composition are mixed with soluble liquid, ultra low volume liquids, aqueous emulsion, microemulsion, missible oil, suspending agent, wetting powder or water dispersible granules.
The processing technology of fluorine-containing pyridine worm amine nitrile of the present invention and the various preparations of amide-type insecticide composition is known.
(1) processing of missible oil, soluble liquid, ultra low volume liquids:
Press formula rate, active component is dissolved in the excipient, add auxiliary agent, mix and get final product.
(2) processing of aqueous emulsion, microemulsion:
Oil phase preparation: press formula rate, active component is dissolved in the excipient, add auxiliary agent, mix.
Water preparation: water-soluble component and water are mixed.
Oil phase is added in aqueous phase or the water adding oil phase, and the limit edged stirs, and makes aqueous emulsion or microemulsion.
(3) processing of wetting powder, water dispersible granules
Active component, auxiliary agent and excipient are mixed behind comminution by gas stream at the mixed wetting powder that gets in proportion.
Active component, auxiliary agent and excipient are mixed through comminution by gas stream in proportion; Add entry then, through kneading, granulation, drying, screening makes the water dispersible granules product; The powder that maybe will pulverize is water spray, granulation, drying in the fluidized granulating machine, go out sieve behind the machine the water dispersible granules product.
(4) processing of suspending agent
After active component, auxiliary agent and mixed with excipients, through high speed shear, the husky mill of wet method back is crossed and is filtered the suspending agent product.
Fluorine-containing pyridine worm amine nitrile of the present invention and amide-type insecticide composition; The target crop that is used to prevent and treat is cereal crops or economic crops, comprises paddy rice, wheat, sugarcane, banana, rubber, cotton, tea tree, oranges and tangerines, apple, hawthorn, peach, tomato, eggplant, capsicum, lettuce, celery, wild cabbage, Kidney bean, broad bean, cowpea, pea, cucumber, pumpkin or watermelon.
Fluorine-containing pyridine worm amine nitrile of the present invention and amide-type insecticide composition, the insect that is used to prevent and treat comprise rice leaf roller, brown planthopper, white-backed planthopper, small brown rice planthopper, striped rice borer, rice thrips, rice gall midge, rice leafhopper, rice leafhopper, rice spider rafter stinkbug, resemble the star stinkbug, green rice bug resembles, red must fleahopper, rice negatively mixes that worm, rice tube water snout moth's larva, oryza chinensis, Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, tangerine lyonetid, the thin moth of tea, striped flea-beetle, beans dive that fly, the cured a red-spotted lizard in angle, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, golden thistle horse, oranges and tangerines golden thistle horse, soybean pod gall-midge or tomato Liriomyza.
Fluorine-containing pyridine worm amine nitrile of the present invention is compared with common insecticides with the amide-type insecticide composition, has the following advantages: 1, compare with single agent, target pest is had obvious synergistic effect, can significantly improve control efficiency; 2, can reduce the agricultural chemicals usage amount, reduce the residual of environmental pollution and agricultural product; 3, can delay the pesticide resistance of target pest to single insecticide; 4, have the advantage that desinsection speed is fast, the lasting period is long concurrently, compare, can reduce cost with single medicament.
Embodiment
Degree of the present invention except that stated is arranged, is weight percent content.
The indoor joint toxicity measuring test of fluorine pyridine worm amine nitrile and azoles insect amide
Fluorine pyridine worm amine nitrile and azoles insect amide are made into the binary built agent as mixture 1～mixture 9 by active ingredient part by weight 100:1,50:1,25:1,5:1,1:1,1:5,1:25,1:50,1:100 mixing respectively; Fluorine pyridine worm amine nitrile and two kinds of single agent of azoles insect amide and mixture 1～mixture 9 are respectively diluted 10 concentration from 20ppm according to the geometric ratio gradient, handle with clear water and make blank; Supplying the examination insect is rice leaf roller 3 instar larvaes; Employing is soaked the seedling method and is measured, and the rice seedling immersion liquid was taken out after 15 seconds, with the blotting paper suction go unnecessary soup or air-dry after; Place the test tube of diameter 3cm, long 25cm; Insert the examination worm then, investigated dead borer population respectively, and calculated lethality, virulence and co-toxicity coefficient in 48 hours.
Measure the result and see table 1; Show from measuring the result: fluorine pyridine worm amine nitrile and azoles insect amide are hybridly prepared into the binary built agent by active ingredient part by weight 100:1,50:1,25:1,5:1,1:1,1:5,1:25,1:50,1:100; Co-toxicity coefficient to rice leaf roller 3 instar larvaes is respectively 100.4,134.2,215.0,255.6,313.6,190.0,158.4,121.0,103.5; Show that fluorine pyridine worm amine nitrile and azoles insect amide all have synergistic effect in the composite back of 50:1～1:50 ratio to rice leaf roller, wherein when the two in particularly remarkable after 25:1～the 1:25 ratio is composite to the synergistic effect of rice leaf roller.
Table 1 fluorine pyridine worm amine nitrile and the indoor joint toxicity measuring result of azoles insect amide (48 hours)
The indoor joint toxicity measuring test of fluorine pyridine worm amine nitrile and cyanogen insect amide
Fluorine pyridine worm amine nitrile and cyanogen insect amide are made into the binary built agent as mixture 10～mixture 18 by active ingredient part by weight 100:1,50:1,25:1,5:1,1:1,1:5,1:25,1:50,1:100 mixing respectively; Fluorine pyridine worm amine nitrile and two kinds of single agent of cyanogen insect amide and mixture 10～mixture 18 are respectively diluted 10 concentration from 20ppm according to the geometric ratio gradient, handle with clear water and make blank; Supplying the examination insect is cabbage caterpillar 3 instar larvaes, adopts dip method to measure, and investigates dead borer population respectively, and calculates lethality, virulence and co-toxicity coefficient in 24 hours.
Measure the result and see table 2; Show from measuring the result: fluorine pyridine worm amine nitrile and cyanogen insect amide are hybridly prepared into the binary built agent by active ingredient part by weight 100:1,50:1,25:1,5:1,1:1,1:5,1:25,1:50,1:100; Co-toxicity coefficient to cabbage caterpillar 3 instar larvaes is respectively 114.1,166.1,209.9,228.4,264.8,238.7,257.8,159.1,106.4; Show that fluorine pyridine worm amine nitrile and cyanogen insect amide all have synergistic effect in the composite back of 50:1～1:50 ratio to cabbage caterpillar, wherein when the two in particularly remarkable after 25:1～the 1:25 ratio is composite to the synergistic effect of cabbage caterpillar.
Table 2 fluorine pyridine worm amine nitrile and the indoor joint toxicity measuring result of cyanogen insect amide (24 hours)
| Medicament | The toxicity regression formula | Correlation coefficient | LC50（mg/L） | Co-toxicity coefficient |
| Fluorine pyridine worm amine nitrile | Y=1.5772x+4.8602 | 0.9977 | 1.23 | / |
| Cyanogen insect amide | Y=1.7060x+5.2567 | 0.9845 | 0.71 | / |
| Mixture 10 | Y=1.9990x+4.9391 | 0.9846 | 1.07 | 114.1 |
| Mixture 11 | Y=1.5446x+5.2101 | 0.9934 | 0.73 | 166.1 |
| Mixture 12 | Y=1.5462x+5.3785 | 0.9801 | 0.57 | 209.9 |
| Mixture 13 | Y=2.1638x+5.6889 | 0.9839 | 0.48 | 228.4 |
| Mixture 14 | Y=1.7630x+5.8357 | 0.9957 | 0.34 | 264.8 |
| Mixture 15 | Y=1.3993x+5.6888 | 0.9755 | 0.32 | 238.7 |
| Mixture 16 | Y=1.9331x+6.0592 | 0.9977 | 0.28 | 257.8 |
| Mixture 17 | Y=2.4077x+5.8278 | 0.9962 | 0.45 | 159.1 |
| Mixture 18 | Y=2.0165x+5.3531 | 0.9807 | 0.67 | 106.4 |
Embodiment 1～9
Formula for a product is as shown in table 3, and sequence number 1#～9# is respectively embodiment 1～9, and all is prepared into missible oil.
Table 3 cream preparation embodiment
Embodiment 10～18
Formula for a product is as shown in table 4, and sequence number 10#～18# is respectively embodiment 10～18, and all is prepared into ultra low volume liquids.
Table 4 ultra low volume liquids FORMULATION EXAMPLE
Embodiment 19～27
Formula for a product is as shown in table 5, and sequence number 19#～27# is respectively embodiment 19～27, and all is prepared into aqueous emulsion.
Table 5 aqueous emulsion FORMULATION EXAMPLE
Embodiment 28～36
Formula for a product is as shown in table 6, and sequence number 28#～36# is respectively embodiment 28～36, and all is prepared into microemulsion.
Table 6 microemulsion formulation embodiment
Embodiment 37～45
Formula for a product is as shown in table 7, and sequence number 37#～45# is respectively embodiment 37～45, and all is prepared into soluble liquid.
Table 7 soluble liquid FORMULATION EXAMPLE
Embodiment 46～54
Formula for a product is as shown in table 8, and sequence number 46#～54# is respectively embodiment 46～54, and all is prepared into wetting powder.
Table 8 wetting powder FORMULATION EXAMPLE
Embodiment 55～63
Formula for a product is as shown in table 9, and sequence number 55#～63# is respectively embodiment 55～63, and all is prepared into soluble granula.
Table 9 soluble granula FORMULATION EXAMPLE
Embodiment 64～72
Formula for a product is as shown in table 10, and sequence number 64#～72# is respectively embodiment 64～72, and all is prepared into suspending agent.
Table 10 suspending agent FORMULATION EXAMPLE
Product application implementation example 1
Fluorine pyridine worm amine nitrile and azoles insect amide complex composition are to the control efficiency of rice leaf roller
The test site is located at certain rice field of Yongxiu County, Nanchang, and 19 processing are established in test, each three times repetitions, and district's group is arranged at random.Spraying time is in July, 2011, every 667m
2Convert 45 kilograms in water, contain when sending out in rice leaf roller and adopt the power spraye dispenser, adopted five point samplings investigation insect pest situation in 3 days, 7 days and 15 days behind the medicine, calculate control efficiency; Select for use 3% fluorine pyridine worm amine nitrile missible oil, 5% azoles insect amide missible oil and 200g/L chlorine worm benzoyl suspending agent to be the contrast medicament; The result is as shown in table 11; Behind fluorine pyridine worm amine nitrile and the azoles insect amide complex composition medicine 3 days, 7 days, 15 days all high, also high simultaneously to the preventive effect of rice leaf roller than 200g/L chlorine worm benzoyl suspending agent preventive effect than 3% fluorine pyridine worm amine nitrile missible oil and two kinds of single agent of 5% azoles insect amide missible oil.
Table 11 fluorine pyridine worm amine nitrile and azoles insect amide complex composition are to the control efficiency of rice leaf roller
Product application implementation example 2
Fluorine pyridine worm amine nitrile and cyanogen insect amide complex composition are to the control efficiency of diamond-back moth
The test site is located at Shaanxi Yang Ling field of vegetables, and 19 processing are established in test, each three times repetitions, and district's group is arranged at random.Spraying time is in July, 2011, every 667m
2Convert 45 kilograms in water, contain when sending out in diamond-back moth and adopt the power spraye dispenser, adopted five point samplings investigation insect pest situation in 3 days, 7 days and 15 days behind the medicine, calculate control efficiency; Select for use 3% fluorine pyridine worm amine nitrile missible oil, 5% cyanogen insect amide missible oil and 1.8% abamectin emulsifiable concentrate to be the contrast medicament; The result is as shown in table 12; Behind fluorine pyridine worm amine nitrile and the azoles insect amide complex composition medicine 3 days, 7 days, 15 days all high, also high simultaneously to the preventive effect of diamond-back moth than 1.8% abamectin emulsifiable concentrate preventive effect than 3% fluorine pyridine worm amine nitrile missible oil and two kinds of single agent of 5% cyanogen insect amide missible oil.
Table 12 fluorine pyridine worm amine nitrile and cyanogen insect amide complex composition are to the control efficiency of diamond-back moth
Claims (5)
1. fluorine-containing pyridine worm amine nitrile and amide-type insecticide composition; Form by active ingredient, auxiliary agent and excipient; It is characterized in that the weight percent content that active ingredient accounts for composition is 2～50%, active ingredient is made up of A and two kinds of active components of B; Active component A is a fluorine pyridine worm amine nitrile, and active component B is selected from any in azoles insect amide or the cyanogen insect amide; The weight ratio of active component A and active component B is 1:50～50:1.
2. fluorine-containing pyridine worm amine nitrile according to claim 1 and amide-type insecticide composition is characterized in that the weight percent content that described active ingredient accounts for composition is 5～30%, and the weight ratio of active component A and active component B is 1:25～25:1.
3. fluorine-containing pyridine worm amine nitrile according to claim 1 and 2 and amide-type insecticide composition; It is characterized in that described auxiliary agent is one or more the combination in AEO, castor oil polyoxyethylene ether, APES, phenethyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy formaldehyde condensation products, phenethyl phenol polyethenoxy ether polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, APES phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, methyl naphthalene sulfonate formaldehyde condensate, nekal formaldehyde condensation products, alkylphenol-polyethenoxy formaldehyde condensation products sulphate, aliphatic alcohol polyethenoxy polyethenoxy ether, sodium lignin sulfonate, calcium dodecyl benzene sulfonate, lauryl sodium sulfate, calcium lignosulfonate or the Negel.
4. fluorine-containing pyridine worm amine nitrile according to claim 1 and 2 and amide-type insecticide composition; It is characterized in that; Described excipient is acetone, cyclohexanone, trimethylbenzene, xylol, o-dichlorohenzene, methyl-propyl benzene, methyl naphthalene, acetophenone, ethanol, ethylene glycol, glycerine, phenmethylol, methyl-sulfoxide, N-Methyl pyrrolidone, N; Dinethylformamide, DMAC N,N, deionized water, water, glycerine, soybean oil, cottonseed oil, rapeseed oil, castor oil, corn oil, turpentine oil, methyl oleate, ethyl oleate, organosilicon, Sodium Benzoate, xanthans, draw back one or more the combination in powder, sodium carboxymethylcellulose, sodium carboxymethyl starch, sodium alginate, Magnesiumaluminumsilicate, N-methyl acetyl sodium taurocholate, white carbon, bentonite or the attapulgite.
5. fluorine-containing pyridine worm amine nitrile according to claim 1 and 2 and amide-type insecticide composition; It is characterized in that described composition is mixed with soluble liquid, ultra low volume liquids, aqueous emulsion, microemulsion, missible oil, suspending agent, wetting powder or water dispersible granules.
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