CN102815972A - Method for manufacturing metallic-crystal enameled brick - Google Patents
Method for manufacturing metallic-crystal enameled brick Download PDFInfo
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- CN102815972A CN102815972A CN2012102793973A CN201210279397A CN102815972A CN 102815972 A CN102815972 A CN 102815972A CN 2012102793973 A CN2012102793973 A CN 2012102793973A CN 201210279397 A CN201210279397 A CN 201210279397A CN 102815972 A CN102815972 A CN 102815972A
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- glaze
- coat enamel
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- crystal
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Abstract
The invention discloses a method for manufacturing a metallic-crystal enameled brick, which comprises base enamel 1, printing enamel 2 and metallic-crystal enamel 3, wherein the method comprises the following technical procedures: spraying the base enamel on a crude brick billet so as to form the base enamel 1; printing the printing enamel 2 on the base enamel 1; coating the metallic-crystal enamel 3 on the outer surface which is printed by the printing enamel 2; polishing and washing edges; and processing one-time bake in a kiln so as to obtain a product. According to benefit effect of the method, the method is characterized by natural crystallization effect, positionable crystal body, controllable crystallization effect, one-time and quick bake and working time conservation and can be widely applied to methods for manufacturing each metallic-crystal glaze ceramic tile.
Description
Technical field
The invention belongs to ceramic tile class manufacturing technology field, relate in particular to a kind of method of manufacture of metallic crystal vitreous brick.
Background technology
The quality of metal glaze face brick quite has the demeanour of metal, and the appearance dye-in-the-wood cruel flavour is compared with common ceramics, and its weathering resistance, corrosion resistant ability are stronger, and is for a long time long new.Its surface can be processed into multicolour such as golden yellow, silvery white, blue, black, and gloss is glorious and resplendent, gives firm luxurious sensation, receives the favor in market, is the leading product of current home market.
The metallic crystal glaze has been used on the surface of metal glaze face brick, and the component of metallic crystal glaze and ME directly determine the visual appearance and the physical chemistry attribute of metal glaze face brick, is also determining it to receive favor and degree salable.In the manufacturing techniques available, like application number 200710035665.6, name is called a kind of Chinese patent of making method of golden metal glaze material.This technology relates to a kind of making method of golden metal glaze material, and after this glaze burnt till in 1160～1200 ℃ of oxidizing atmospheres fast, glaze was golden yellow under the ordinary ray irradiation.Comprise borax and zinc, lithium, three kinds of carbonate of barium in its metallic crystal glaze, also be added with quartzy and potassium felspar sand and a small amount of clay and some tinting materials.Manufacture craft is, earlier borax and carbonate processed frit, after frit is pulverized again with quartz and potassium felspar sand, clay and tinting material ball milling are to passing through 250 mesh sieves.This technological weak point is: metallic crystal glazed brick effect is single, and poor stability, pattern and pattern be nature not, and the size of xln and color are difficult to control.
Summary of the invention
The technical problem that the present invention will solve is: to plan as a whole research and development with the weak point of prior art, propose a kind of new ceramic tile method of manufacture, it can not only address the deficiencies of the prior art, and also has other many useful effects.
In order to solve the problems of the technologies described above; A kind of technical scheme of the present invention is: a kind of method of manufacture of metallic crystal vitreous brick, comprise ground-coat enamel 1, and also comprise screen printing glaze 2; Metallic crystal glaze 3, and comprise following technical process: the spray ground-coat enamel forms described ground-coat enamel 1 in living adobe; Printing screen printing glaze 2 on described ground-coat enamel 1; At the described outside surface metallize crystalline glaze 3 that is printed on screen printing glaze 2,, advance kiln then and once fire and form through the edging side washing.
The system component of above-mentioned metallic crystal glaze 3 is: SiO
2: 35-45%; Al
2O
3: 3-5%; Fe
2O
3: 8-15%; P
2O
5: 12-18%; CaO:0-5%; MgO:10-15%; K
2O and/or Na
2O:1-4%; CO
2: 5-10%
Above-mentioned screen printing glaze 2 is for comprising the powder of different metal or alkali metal, and fineness is less than 44 microns, and it is printed on the described ground-coat enamel 1 through silk screen or roller, and ground-coat enamel 1 is for comprising the mixture of calcium magnesium and sial content.
Through above-mentioned technical process, beneficial effect of the present invention is: 1, crystallization effect nature.Metallic crystal glaze of the prior art is difficult to its crystallographic dimension of control and color with burning till and the altering a great deal of other conditions, and the present invention can control crystallographic dimension and color through this kind technical process, and crystallization effect is appeared naturally; 2, xln can be located.Through type metal element or the different screen printing glaze of the alkali metal amount of being rich in, can locate and separate out different crystal, according to the different pattern requirement, print screen printing glaze of different nature, thereby reach desired locating effect; 3, crystallization effect is controlled.Ground-coat enamel is the mixture of different calcium magnesium and sial content, thereby can control the crystallization effect of metallic crystal glaze through changing the ground-coat enamel composition.4, once burn till fast, save man-hour.The present invention once burns till fast, need not biscuiting, and is time saving and energy saving, and cost is effectively reduced, and production efficiency is able to promote.
Because above-mentioned beneficial effect, the present invention is in the making method of various metallic crystal glazed ceramic wall tiles.
Description of drawings
Fig. 1 is the process flow sheet of an embodiment of the present invention.
Embodiment
Below in conjunction with accompanying drawing and with the form of embodiment practical implementation of the present invention is described in further detail.
Embodiment 1:
As shown in Figure 1, the spray ground-coat enamel forms described ground-coat enamel 1 in living adobe earlier; Printing screen printing glaze 2 on ground-coat enamel 1; Be printed on the outside surface metallize crystalline glaze 3 of screen printing glaze 2,, advancing kiln then and once fire and form through the edging side washing.
The component of the metallic crystal glaze 3 in the present embodiment is: SiO
2: 40%; Al
2O
3: 5%; Fe
2O
3: 15 %; P
2O
5: 18%; MgO:15%; K
2O:1 %; Na
2O:1%; CO
2: 5 %.
Need to prove above-mentioned CO
2In industry be commonly called as to burn and lose, be meant the air-loss that the metallic crystal glaze produced in the treating processes in early stage, because the non-content involved in the present invention of this treating processes is not described in detail, follow-up embodiment also together.
Screen printing glaze 2 in the present embodiment is for comprising the powder of metallic elements (occupying proportion is 80%) such as MAGNESIUM METAL 99, aluminium, titanium; Its fineness is 43 microns; On described ground-coat enamel 1, ground-coat enamel 1 is for comprising the mixture of calcium magnesium and sial content (occupying proportion is 50%) through silk screen printing for it.In the component of screen printing glaze 2 and ground-coat enamel 1, other 20% and 50% is that general ceramic tile is prepared burden, and like the base powder etc., repeats no more at this.
Edging side washing in the present embodiment is that ceramic tile is made the general procedure in the class, repeats no more.Advance kiln then and once fire and form, 1200 ℃ of the firing temperatures of kiln, the time is 60 minutes.
Embodiment 2:
As shown in Figure 1, the spray ground-coat enamel forms described ground-coat enamel 1 in living adobe earlier; Printing screen printing glaze 2 on ground-coat enamel 1; Be printed on the outside surface metallize crystalline glaze 3 of screen printing glaze 2,, advancing kiln then and once fire and form through the edging side washing.
The component of the metallic crystal glaze 3 in the present embodiment is: SiO
2: 35%; Al
2O
3: 3%; Fe
2O
3: 14.5%; P
2O
5: 14%; CaO:5%; MgO:14.5%; K
2O:4%; CO
2: 10%.
Screen printing glaze 2 in the present embodiment is for comprising the powder of metallic elements (occupying proportion is 85%) such as MAGNESIUM METAL 99, aluminium, titanium; Its fineness is 30 microns; It is printed on the described ground-coat enamel 1 through roller, and ground-coat enamel 1 is for comprising the mixture of calcium magnesium and sial content (occupying proportion is 40%).In the component of screen printing glaze 2 and ground-coat enamel 1, other 15% and 60% is that general ceramic tile is prepared burden, and like the base powder etc., repeats no more at this.
Edging side washing in the present embodiment is that ceramic tile is made the general procedure in the class, repeats no more.Advance kiln then and once fire and form, 1150 ℃ of the firing temperatures of kiln, the time is 50 minutes.
Embodiment 3:
As shown in Figure 1, the spray ground-coat enamel forms described ground-coat enamel 1 in living adobe earlier; Printing screen printing glaze 2 on ground-coat enamel 1; Be printed on the outside surface metallize crystalline glaze 3 of screen printing glaze 2,, advancing kiln then and once fire and form through the edging side washing.
The component of the metallic crystal glaze 3 in the present embodiment is: SiO
2: 39%; Al
2O
3: 4%; Fe
2O
3: 13%; P
2O
5: 12%; CaO:4.5%; MgO:14.5%; Na
2O:4%; CO
2: 9%.
Screen printing glaze 2 in the present embodiment is for comprising Na
2O, K
2The powder of alkali metals such as O (occupying proportion is 75%), its fineness is 20 microns, and it is printed on the described ground-coat enamel 1 through roller, and ground-coat enamel 1 is for comprising the mixture of calcium magnesium and sial content (occupying proportion is 60%).In the component of screen printing glaze 2 and ground-coat enamel 1, other 25% and 40% is that general ceramic tile is prepared burden, and like the base powder etc., repeats no more at this.
Edging side washing in the present embodiment is that ceramic tile is made the general procedure in the class, repeats no more.Advance kiln then and once fire and form, 1250 ℃ of the firing temperatures of kiln, the time is 70 minutes.
Embodiment 4:
As shown in Figure 1, the spray ground-coat enamel forms described ground-coat enamel 1 in living adobe earlier; Printing screen printing glaze 2 on ground-coat enamel 1; Be printed on the outside surface metallize crystalline glaze 3 of screen printing glaze 2,, advancing kiln then and once fire and form through the edging side washing.
The component of the metallic crystal glaze 3 in the present embodiment is: SiO
2: 39.5%; Al
2O
3: 5%; Fe
2O
3: 8%; P
2O
5: 17.5%; CaO:4%; MgO:15%; K
2O:1 %; Na
2O:1%; CO
2: 9 %.
Screen printing glaze 2 in the present embodiment is for comprising Na
2O, K
2The powder of alkali metals such as O (occupying proportion is 82%), its fineness is 10 microns, on described ground-coat enamel 1, ground-coat enamel 1 is for comprising the mixture of calcium magnesium and sial content (occupying proportion is 55%) through silk screen printing for it.In the component of screen printing glaze 2 and ground-coat enamel 1, other 18% and 45% is that general ceramic tile is prepared burden, and like the base powder etc., repeats no more at this.
Edging side washing in the present embodiment is that ceramic tile is made the general procedure in the class, repeats no more.Advance kiln then and once fire and form, 1220 ℃ of the firing temperatures of kiln, the time is 65 minutes.
Claims (5)
1. the method for manufacture of a metallic crystal vitreous brick comprises ground-coat enamel (1), also comprises screen printing glaze (2), metallic crystal glaze (3), and comprise following technical process: the spray ground-coat enamel forms described ground-coat enamel (1) in living adobe; Go up printing screen printing glaze (2) at described ground-coat enamel (1); At the described adobe surface metallize crystalline glaze (3) that is printed on screen printing glaze (2),, advance kiln then and once fire and form through the edging side washing.
2. the method for manufacture of a kind of metallic crystal vitreous brick according to claim 1 is characterized in that: the system component of said metallic crystal glaze (3) is: SiO
2: 35-45%; Al
2O
3: 3-5%; Fe
2O
3: 8-15%; P
2O
5: 12-18%; CaO:0-5%; MgO:10-15%; K
2O and/or Na
2O:1-4%; CO
2: 5-10%.
3. the method for manufacture of a kind of metallic crystal vitreous brick according to claim 1 is characterized in that: described screen printing glaze (2)
For comprising the powder of different metal or alkali metal, fineness is less than 44 microns.
4. the method for manufacture of a kind of metallic crystal vitreous brick according to claim 1 is characterized in that: described ground-coat enamel (1)
For comprising the mixture of calcium magnesium and sial content.
5. the method for manufacture of a kind of metallic crystal vitreous brick according to claim 3 is characterized in that: described screen printing glaze (2)
Be printed on the described ground-coat enamel (1) through silk screen or roller.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102793973A CN102815972A (en) | 2012-08-06 | 2012-08-06 | Method for manufacturing metallic-crystal enameled brick |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102793973A CN102815972A (en) | 2012-08-06 | 2012-08-06 | Method for manufacturing metallic-crystal enameled brick |
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| Publication Number | Publication Date |
|---|---|
| CN102815972A true CN102815972A (en) | 2012-12-12 |
Family
ID=47300476
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012102793973A Pending CN102815972A (en) | 2012-08-06 | 2012-08-06 | Method for manufacturing metallic-crystal enameled brick |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103102181A (en) * | 2012-12-19 | 2013-05-15 | 广东东鹏控股股份有限公司 | Method for preparing flash glazed wall tile |
| CN106810229A (en) * | 2017-01-25 | 2017-06-09 | 欧阳琦 | The preparation technology and metal glaze carpet brick of a kind of metal glaze carpet brick |
| CN107417108A (en) * | 2017-06-02 | 2017-12-01 | 东莞市唯美陶瓷工业园有限公司 | A kind of screen printing glaze and its preparation method and application |
| CN109455933A (en) * | 2018-12-19 | 2019-03-12 | 蒙娜丽莎集团股份有限公司 | A kind of crystalline glaze and use Ceramic Tiles made from the crystalline glaze |
| CN109455934A (en) * | 2018-12-19 | 2019-03-12 | 蒙娜丽莎集团股份有限公司 | Color decorative effect Ceramic Tiles of a kind of stream and preparation method thereof |
Citations (5)
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|---|---|---|---|---|
| CN101314549A (en) * | 2007-05-29 | 2008-12-03 | 卡塔罗尼安-阿拉贡斯矿业公司 | Metallic glaze composition |
| CN101407434A (en) * | 2008-08-26 | 2009-04-15 | 陈明辉 | Method for producing wall and ground brick by using pearl mica pigment |
| CN102303970A (en) * | 2011-07-08 | 2012-01-04 | 晋江恒达陶瓷有限公司 | Method for producing metal enamelled bricks |
| CN102329153A (en) * | 2011-07-08 | 2012-01-25 | 晋江恒达陶瓷有限公司 | Method for producing embossed ceramic tile |
| CN102515872A (en) * | 2011-12-09 | 2012-06-27 | 霍镰泉 | Metallic glaze ceramic tile and preparation method thereof |
-
2012
- 2012-08-06 CN CN2012102793973A patent/CN102815972A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101314549A (en) * | 2007-05-29 | 2008-12-03 | 卡塔罗尼安-阿拉贡斯矿业公司 | Metallic glaze composition |
| CN101407434A (en) * | 2008-08-26 | 2009-04-15 | 陈明辉 | Method for producing wall and ground brick by using pearl mica pigment |
| CN102303970A (en) * | 2011-07-08 | 2012-01-04 | 晋江恒达陶瓷有限公司 | Method for producing metal enamelled bricks |
| CN102329153A (en) * | 2011-07-08 | 2012-01-25 | 晋江恒达陶瓷有限公司 | Method for producing embossed ceramic tile |
| CN102515872A (en) * | 2011-12-09 | 2012-06-27 | 霍镰泉 | Metallic glaze ceramic tile and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103102181A (en) * | 2012-12-19 | 2013-05-15 | 广东东鹏控股股份有限公司 | Method for preparing flash glazed wall tile |
| CN103102181B (en) * | 2012-12-19 | 2015-01-21 | 广东东鹏陶瓷股份有限公司 | Method for preparing flash glazed wall tile |
| CN106810229A (en) * | 2017-01-25 | 2017-06-09 | 欧阳琦 | The preparation technology and metal glaze carpet brick of a kind of metal glaze carpet brick |
| CN106810229B (en) * | 2017-01-25 | 2020-02-11 | 欧阳琦 | Preparation process of metal glaze carpet brick and metal glaze carpet brick |
| CN107417108A (en) * | 2017-06-02 | 2017-12-01 | 东莞市唯美陶瓷工业园有限公司 | A kind of screen printing glaze and its preparation method and application |
| CN107417108B (en) * | 2017-06-02 | 2019-12-24 | 东莞市唯美陶瓷工业园有限公司 | Printing glaze and preparation method and application thereof |
| CN109455933A (en) * | 2018-12-19 | 2019-03-12 | 蒙娜丽莎集团股份有限公司 | A kind of crystalline glaze and use Ceramic Tiles made from the crystalline glaze |
| CN109455934A (en) * | 2018-12-19 | 2019-03-12 | 蒙娜丽莎集团股份有限公司 | Color decorative effect Ceramic Tiles of a kind of stream and preparation method thereof |
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Application publication date: 20121212 |