CN102815757B - Seawater desalination apparatus - Google Patents
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Abstract
本发明涉及一种海水淡化装置,包括空气增湿塔和空气脱湿塔,空气增湿塔和空气脱湿塔的上部相互连通;空气增湿塔包括加热列管、向空气增湿塔提供空气的鼓风装置、进水口、与所述进水口连通的布水管和供空气增湿塔中的海水排出的海水排出口,加热列管的两端分别设有输入热力发电厂乏蒸汽的热源入口及输出乏蒸汽的热源出口;空气脱湿塔内设有冷却列管及淡水排出口,冷却列管的两端分别设有入水口及出水口。上述海水淡化的装置能有效利用热力发电厂的余热制造淡水,使海水淡化的成本大幅度降低。
The invention relates to a seawater desalination device, comprising an air humidification tower and an air dehumidification tower, the upper parts of the air humidification tower and the air dehumidification tower communicate with each other; The air blowing device, the water inlet, the water distribution pipe connected with the water inlet and the seawater discharge outlet for the seawater in the air humidification tower are discharged, and the two ends of the heating tube are respectively provided with heat source inlets for inputting the exhaust steam of the thermal power plant And the heat source outlet for outputting exhausted steam; the air dehumidification tower is equipped with cooling tubes and fresh water outlets, and the two ends of the cooling tubes are respectively equipped with water inlets and water outlets. The above seawater desalination device can effectively use the waste heat of the thermal power plant to produce fresh water, so that the cost of seawater desalination is greatly reduced.
Description
技术领域technical field
本发明属于水处理技术领域,尤其涉及海水淡化装置。The invention belongs to the technical field of water treatment, in particular to a seawater desalination device.
背景技术Background technique
由于淡水资源的缺乏,海水淡化的技术受到广泛的关注。由于盐水变成淡水,是一个熵减少过程,不可能自发进行,现有的海水淡化方法如蒸馏法、反渗透法、电渗析法等,都需要消耗大量的能量,这样就使得海水淡化的经济成本过高,不利于广泛应用。Due to the lack of fresh water resources, seawater desalination technology has received extensive attention. Since salt water becomes fresh water, it is an entropy reduction process, which cannot be carried out spontaneously. Existing seawater desalination methods such as distillation, reverse osmosis, electrodialysis, etc., all need to consume a lot of energy, which makes seawater desalination economical. The cost is too high, which is not conducive to wide application.
如图1所示,是现有的热力发电厂的工作原理图,热力发电厂在发电时,根据热力学第二定律,锅炉里的燃料燃烧产生的热量只有部分转换为电力,而乏蒸汽在冷凝时,放出的热量占了燃烧燃放热量的50%以上,这是巨大的余热。目前与600MW发电机组配套的锅炉蒸发量为2008t/h,一般每千克蒸汽在蒸汽器中冷凝时释放的汽化潜热为2383~2424kj/kg,因此凝汽器冷凝时所释放的热量约为1.145*109kcal/h(1cal=4.1840J),每小时可使约11万吨冷却水升温10℃,这一巨大的热源使火电厂排放的冷却水温度至少升高8℃以上。因此,如果能将热力发电厂的余热用于海水淡化,使废热有效利用,就能使淡化的成本大幅度降低。As shown in Figure 1, it is the working principle diagram of the existing thermal power plant. When the thermal power plant generates electricity, according to the second law of thermodynamics, only part of the heat generated by the combustion of fuel in the boiler is converted into electricity, and the exhausted steam is condensed When burning, the heat released accounts for more than 50% of the heat of combustion and discharge, which is a huge waste heat. At present, the evaporation capacity of the boiler matched with the 600MW generating set is 2008t/h. Generally, the latent heat of vaporization released when each kilogram of steam is condensed in the steamer is 2383-2424kj/kg, so the heat released by the condenser when condensed is about 1.145* 109kcal/h (1cal=4.1840J), it can raise the temperature of about 110,000 tons of cooling water by 10°C per hour. This huge heat source can raise the temperature of cooling water discharged from thermal power plants by at least 8°C. Therefore, if the waste heat of the thermal power plant can be used for seawater desalination and the waste heat can be effectively utilized, the cost of desalination can be greatly reduced.
发明内容Contents of the invention
本发明所要解决的技术问题在于提供一种利用发电厂乏蒸汽的余热进行海水淡化的装置。The technical problem to be solved by the present invention is to provide a device for desalination of seawater by using the waste heat of exhausted steam in a power plant.
本发明是这样实现的,提供一种海水淡化装置,包括空气增湿塔和空气脱湿塔,所述空气增湿塔和空气脱湿塔的上部相互连通;所述空气增湿塔包括加热列管、向空气增湿塔提供空气的鼓风装置、进水口、与所述进水口连通的布水管和供所述空气增湿塔中的海水排出的海水排出口,所述加热列管的两端分别设有输入热力发电厂乏蒸汽的热源入口及输出所述乏蒸汽的热源出口;所述空气脱湿塔内设有冷却列管及淡水排出口,所述冷却列管的两端分别设有入水口及出水口;所述热源出口与一汽水分离装置相连通,所述汽水分离装置与发电厂的冷凝器相连通;所述空气脱湿塔的下方部位还设有排气孔;所述空气脱湿塔上的排气孔与所述鼓风装置的进气口相连通;所述入水口输入深处海水,所述出水口与空气增湿塔上的进水口相连通,或者排放。The present invention is achieved by providing a seawater desalination device, including an air humidification tower and an air dehumidification tower, and the upper parts of the air humidification tower and the air dehumidification tower communicate with each other; the air humidification tower includes a heating column pipe, a blower device that provides air to the air humidification tower, a water inlet, a water distribution pipe communicated with the water inlet, and a seawater discharge outlet for the seawater in the air humidification tower to discharge, and the two heating tubes The heat source inlet for inputting the exhausted steam of the thermal power plant and the heat source outlet for outputting the exhausted steam are respectively provided at the ends; cooling tubes and fresh water outlets are arranged in the air dehumidification tower, and the two ends of the cooling tubes are respectively set There is a water inlet and a water outlet; the outlet of the heat source is connected with a steam-water separation device, and the steam-water separation device is connected with the condenser of the power plant; the lower part of the air dehumidification tower is also provided with an exhaust hole; the The exhaust hole on the air dehumidification tower is connected with the air inlet of the blowing device; the water inlet is input with deep sea water, and the water outlet is connected with the water inlet on the air humidification tower, or discharged .
进一步地,所述空气增湿塔中的进水口和海水排出口分别位于所述空气增湿塔的上方部位及下方部位。Further, the water inlet and the seawater outlet in the air humidification tower are respectively located at the upper part and the lower part of the air humidification tower.
进一步地,所述空气增湿塔还包括安装在所述布水管上的喷头,所述布水管位于所述空气增湿塔内部的上方部位。Further, the air humidification tower further includes a spray head installed on the water distribution pipe, and the water distribution pipe is located at an upper part inside the air humidification tower.
进一步地,所述空气增湿塔的加热列管包括导管和安装在所述导管上的加热翅片。Further, the heating tube of the air humidification tower includes a conduit and heating fins installed on the conduit.
进一步地,所述热源入口和热源出口分别位于所述空气增湿塔的上方部位及下方部位;所述热源入口输入热力发电厂乏蒸汽。Further, the heat source inlet and the heat source outlet are respectively located at the upper part and the lower part of the air humidification tower; the heat source inlet is input into the exhaust steam of the thermal power plant.
进一步地,所述空气脱湿塔的冷却列管包括导管和安装在所述导管上的散热翅片。Further, the cooling tubes of the air dehumidification tower include conduits and cooling fins installed on the conduits.
进一步地,所述入水口和出水口分别位于所述空气脱湿塔的下方部位及上方部位。Further, the water inlet and the water outlet are respectively located at the lower part and the upper part of the air dehumidification tower.
进一步地,所述淡水排出口位于所述空气脱湿塔的下方部位或底部。Further, the fresh water outlet is located at the lower part or bottom of the air dehumidification tower.
进一步地,所述空气增湿塔表面和空气脱湿塔表面均设有保温层。Further, the surface of the air humidification tower and the surface of the air dehumidification tower are both provided with insulation layers.
与现有技术相比,本发明海水淡化的装置能有效利用热力发电厂的余热制造淡水,使海水淡化的成本大幅度降低。Compared with the prior art, the seawater desalination device of the present invention can effectively utilize the waste heat of a thermal power plant to produce fresh water, thereby greatly reducing the cost of seawater desalination.
附图说明Description of drawings
图1为现有的热力发电厂工作原理图;Fig. 1 is the working principle diagram of existing thermal power plant;
图2是本发明一较佳实施例的工作原理图;Fig. 2 is a working principle diagram of a preferred embodiment of the present invention;
图3是本发明一较佳实施例的结构原理图。Fig. 3 is a structural principle diagram of a preferred embodiment of the present invention.
具体实施方式Detailed ways
为了使本发明所要解决的技术问题、技术方案及有益效果更加清楚明白,以下结合附图及实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。In order to make the technical problems, technical solutions and beneficial effects to be solved by the present invention clearer, the present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention.
本发明在已有的热力发电厂的基础上进行改造,如图2所示,是本发明的工作原理图,在不影响热力发电厂正常运行的前提下,从汽轮机排出的乏蒸汽中分出一股用于本发明海水淡化装置的海水淡化。图2中,左边部分为现有的热力发电厂的设备及工作原理,而增湿塔、脱湿塔部分为本发明的海水淡化装置。The present invention is transformed on the basis of the existing thermal power plant, as shown in Figure 2, which is the working principle diagram of the present invention, under the premise of not affecting the normal operation of the thermal power plant, the waste steam discharged from the steam turbine is separated One is used for seawater desalination of the seawater desalination device of the present invention. In Fig. 2, the left part is the equipment and working principle of the existing thermal power plant, and the humidifying tower and the dehumidifying tower part are the seawater desalination device of the present invention.
具体地,如图2和图3所示,是本发明的一较佳实施例,该海水淡化装置包括空气增湿塔100和空气脱湿塔200,空气增湿塔100和空气脱湿塔200的上部相互连通。Specifically, as shown in Figure 2 and Figure 3, it is a preferred embodiment of the present invention, the seawater desalination device includes an air humidification tower 100 and an air dehumidification tower 200, and the air humidification tower 100 and the air dehumidification tower 200 The upper part is connected with each other.
空气增湿塔100包括进水口101、布水管102、喷头103、鼓风装置104、海水排出口105和加热列管106。布水管102及喷头103位于空气增湿塔100内部的上方部位,并且与进水口101相连通,本实施例中,输入进水口101的海水可以是海面海水或者是空气脱湿塔冷却列管出水口排出的冷却海水。鼓风装置104位于空气增湿塔100的下方部位,海水排出口105设于空气增湿塔100的底部或下方部位。加热列管106设于空气增湿塔100内部,加热列管106包括导管和安装在导管上的散热翅片(图中未标示),加热列管106上端设有热源入口1061,下端设有热源出口1062,加热列管106的热源为发电厂汽轮机分出的乏蒸汽,乏蒸汽从上至下地流经加热列管106,使加热列管106外面的海水与空气的温度升高,海水蒸发,空气的湿度增加,形成较高温度(例如70°C左右)的饱和热湿空气。此外,空气增湿塔100表面还设有保温层107,用于防止空气增湿塔内的温度降低。The air humidification tower 100 includes a water inlet 101 , a water distribution pipe 102 , a spray head 103 , an air blast device 104 , a seawater outlet 105 and a heating tube 106 . The water distribution pipe 102 and the nozzle 103 are located at the upper part inside the air humidification tower 100, and communicate with the water inlet 101. In this embodiment, the seawater input into the water inlet 101 can be sea surface seawater or the cooling tube of the air dehumidification tower. Cooled seawater discharged from the nozzle. The air blowing device 104 is located at the lower portion of the air humidification tower 100 , and the seawater outlet 105 is provided at the bottom or lower portion of the air humidification tower 100 . The heating tube 106 is located inside the air humidification tower 100. The heating tube 106 includes a conduit and heat dissipation fins (not shown in the figure) installed on the conduit. The upper end of the heating tube 106 is provided with a heat source inlet 1061, and the lower end is provided with a heat source. Outlet 1062, the heat source of the heating tube 106 is the exhausted steam from the steam turbine of the power plant, and the exhausted steam flows through the heating tube 106 from top to bottom, so that the temperature of the seawater and air outside the heating tube 106 rises, and the seawater evaporates. The humidity of the air increases, forming saturated hot and humid air with a higher temperature (for example, about 70°C). In addition, an insulation layer 107 is provided on the surface of the air humidification tower 100 to prevent the temperature inside the air humidification tower from dropping.
空气脱湿塔200内部设有冷却列管201和淡水排出口202。冷却列管201包括导管和安装在导管上的散热翅片(图中未标示),冷却列管201下方设有入水口2011,上方设有出水口2012,本实施例中,冷却列管内的冷却介质可以是海面海水或者是深处冷海水(最好是深处冷海水,因其温度低,温差大,淡水产量高),深处冷海水具体可以通过水泵等装置取得或通过其他现有技术取得。海水从入水口2011进入,自下而上地流经冷却列管201,使冷却列管外来自空气增湿塔饱和热湿空气冷却,饱和热湿空气中的水蒸气冷凝成为露水,汇集成淡水,从淡水出口排出。淡水排出口202位于空气脱湿塔200的下方部位或底部。空气脱湿塔200表面设有保温层203,用于防止空气脱湿塔内的温度升高。此外,空气脱湿塔200的下方还设有排气孔204。The inside of the air dehumidification tower 200 is provided with cooling tubes 201 and a fresh water outlet 202 . The cooling tube 201 includes a conduit and cooling fins (not shown in the figure) installed on the conduit. The cooling tube 201 is provided with a water inlet 2011 below and a water outlet 2012 above. In this embodiment, the cooling in the cooling tube The medium can be sea surface seawater or deep cold seawater (preferably deep cold seawater, because of its low temperature, large temperature difference, and high freshwater yield), and deep cold seawater can be obtained by means of pumps or other existing technologies obtain. Seawater enters from the water inlet 2011 and flows through the cooling tubes 201 from bottom to top, so that the saturated hot and humid air from the air humidification tower outside the cooling tubes is cooled, and the water vapor in the saturated hot and humid air is condensed into dew and collected into fresh water , discharged from the fresh water outlet. The fresh water outlet 202 is located at the lower part or the bottom of the air dehumidification tower 200 . The surface of the air dehumidification tower 200 is provided with an insulation layer 203 for preventing the temperature inside the air dehumidification tower from rising. In addition, an exhaust hole 204 is provided below the air dehumidification tower 200 .
上述海水淡化装置在制备淡水时,海水从进水口101进入空气增湿塔100内的布水管102,由喷头103喷洒于空气增湿塔100内,并与鼓风装置104鼓进来的空气接触,使空气增湿塔100内的空气湿度增加,达到饱和,通过加热列管的加热,使海水蒸发,形成较高温度的饱和热湿空气,塔内的饱和热湿空气在鼓风装置104的带动下,由空气增湿塔100进入空气脱湿塔200内,饱和热湿空气在空气脱湿塔200内被冷却列管201冷却后变成露水,汇集成淡水从淡水排出口202流出。When the above-mentioned seawater desalination device prepares fresh water, seawater enters the water distribution pipe 102 in the air humidification tower 100 from the water inlet 101, is sprayed in the air humidification tower 100 by the nozzle 103, and contacts with the air blown in by the blower device 104, The air humidity in the air humidification tower 100 is increased to reach saturation, and the seawater is evaporated through the heating of the heating tubes to form saturated hot and humid air at a higher temperature. The saturated hot and humid air in the tower is driven by the blower device 104 Next, from the air humidification tower 100 into the air dehumidification tower 200, the saturated hot humid air is cooled by the cooling tube 201 in the air dehumidification tower 200, and then turns into dew, which is collected into fresh water and flows out from the fresh water outlet 202.
上述增湿塔100内未蒸发掉的海水从海水排出口105中排出。The unevaporated seawater in the humidification tower 100 is discharged from the seawater discharge port 105 .
为了更好地实现资源循环利用,上述热源出口1062可与一汽水分离装置300相连通,汽水分离装置300同时与发电厂的冷凝器相连通。这样,从加热列管106的热源出口1062排出的乏蒸汽经过汽水分离装置进行汽水分离后,得到空气和冷凝水,得到的空气可循环到热力发电厂的冷凝器中,得到的冷凝水可回收再利用。In order to better realize resource recycling, the above-mentioned heat source outlet 1062 can be connected with a steam-water separation device 300, and the steam-water separation device 300 is also connected with the condenser of the power plant. In this way, after the exhaust steam discharged from the heat source outlet 1062 of the heating tube 106 passes through the steam-water separation device for steam-water separation, air and condensed water are obtained, and the obtained air can be circulated to the condenser of the thermal power plant, and the obtained condensed water can be recovered. Reuse.
此外,上述脱湿塔200上的排气孔204可与鼓风装置104的进气口相连通。这样,空气脱湿塔200内的空气从排气孔204排出后可循环到鼓风装置104的进气口,从而循环吹入增湿塔100内。脱湿塔200上的出水口2012可与增湿塔100上的进水口101相连通。这样,从冷却列管201出水口2012排出的海水,可进入空气增湿塔100的进水口101再次利用,有利于提高进入空气增湿塔内海水的温度,增加饱和热湿空气的温度,提高淡水产量。In addition, the exhaust hole 204 on the dehumidification tower 200 can communicate with the air inlet of the air blowing device 104 . In this way, the air in the air dehumidification tower 200 can be circulated to the air inlet of the air blowing device 104 after being exhausted from the exhaust hole 204 , so as to be circulated and blown into the humidification tower 100 . The water outlet 2012 on the dehumidification tower 200 can communicate with the water inlet 101 on the humidification tower 100 . In this way, the seawater discharged from the water outlet 2012 of the cooling tube 201 can enter the water inlet 101 of the air humidification tower 100 for reuse, which is conducive to improving the temperature of seawater entering the air humidification tower, increasing the temperature of saturated hot and humid air, and improving Freshwater production.
下面,根据上述的海水淡化装置,举几个实际应用例进行说明,下表中所列出的多个温度及相对湿度条件下空气的绝对湿度值及焓值均来自【空气的湿焓图】:Next, according to the above-mentioned seawater desalination device, a few practical application examples are given to illustrate. The absolute humidity and enthalpy of the air under the conditions of multiple temperatures and relative humidity listed in the table below are all from the [air humidity enthalpy diagram] :
例1:路线A→B1。假定海面空气温度为30℃,空气相对湿度为60%,此时状态点在表1中的A点,绝对湿度为16克/KG干空气,焓为71KJ/KG干空气。这时,假如用深处海水将这空气冷却到B1点,即假定冷却到15℃,(绝对湿度为10.5克/KG干空气),将产生16-10.5=5.5克露水,即淡水。这就是说,利用了深处海水这个冷原,不消耗能量(提升、输送海水、空气的能量除外),就可以得到淡水。Example 1: Route A→B1. Assume that the sea surface air temperature is 30°C and the relative air humidity is 60%. At this time, the state point is at point A in Table 1, the absolute humidity is 16 grams/KG dry air, and the enthalpy is 71KJ/KG dry air. At this time, if the air is cooled to point B1 with deep sea water, that is, assuming that it is cooled to 15°C, (absolute humidity is 10.5 grams/KG dry air), 16-10.5=5.5 grams of dew will be produced, i.e. fresh water. That is to say, by utilizing the cold source of deep seawater, fresh water can be obtained without consuming energy (except for lifting, transporting seawater, and air energy).
例2:路线A→B2→B1。假定用30℃海水增湿空气,使之来饱和。不外加热量,状态将沿着等焓线移动到饱和线(相对湿度100%线)交点B2点,温度将降到24℃(绝对湿度为18.5克/KG干空气)。这时,假如用深处海水将之冷却到B1点,即假定冷却到15℃,将产生18.5-10.5=8克淡水。这就是说,利用了深处海水这个冷原,再加增湿空气过程,不消耗能量,就可以得到比上述例1多的淡水。Example 2: Route A→B2→B1. Assume that the air is humidified and saturated with 30°C seawater. But heat, the state will move along the isenthalpy line to the intersection point B2 of the saturation line (relative humidity 100% line), and the temperature will drop to 24°C (absolute humidity is 18.5 grams/KG dry air). At this time, if it is cooled to point B1 with deep sea water, that is, assuming that it is cooled to 15° C., 18.5-10.5=8 grams of fresh water will be produced. That is to say, by utilizing the cold source of deep seawater and adding humidified air process, without consuming energy, more fresh water than the above example 1 can be obtained.
例3:路线A→B3→B2→B1。还假定用30℃海水增湿空气,使空气来饱和;同时,海水有比较大的热量,使空气基本上不降温,形成30℃的饱和空气,即到达表1中的B3点(绝对湿度为27克/KG干空气)。再将之冷却,越过B2到B1,将得到27-10.5=16.5克淡水,比上述例2的产量增加。这就是说,再用海面海水作为热源来加热被增湿的空气,就可以得到比上述例2更多的淡水。Example 3: Route A→B3→B2→B1. It is also assumed that 30°C seawater is used to humidify the air to saturate the air; at the same time, seawater has relatively large heat, so that the air basically does not cool down, forming saturated air at 30°C, that is, reaching point B3 in Table 1 (absolute humidity is 27 g/KG dry air). It is cooled again, cross B2 to B1, will obtain 27-10.5=16.5 gram of fresh water, increase than the output of above-mentioned example 2. That is to say, more fresh water than above-mentioned example 2 can be obtained by heating the humidified air with sea water as a heat source.
例4:路线A→B4→B3→B2→B1。以上三种路线,是不外加热源的情况,现在假定另有热源,例如发电厂的乏蒸汽、太阳能或其他热源,使空气温度同时提高,这时,再假定空气温度到达35℃,即达到表1中的B4点(绝对湿度36克/KG干空气)。这时假如用30℃海水来冷却,假定冷却到了30℃,B3点,得到淡水36-27=9克。可是,假如是用深处海水将之冷却,越过B3点、B2点到B1点,将产生淡水36-10.5=25.2克,是9克的2.8倍。Example 4: Route A→B4→B3→B2→B1. The above three routes are not the case of the heating source. Now assume that there are other heat sources, such as exhaust steam in power plants, solar energy or other heat sources, so that the air temperature increases at the same time. At this time, assume that the air temperature reaches 35 ° C, that is, the surface Point B4 in 1 (absolute humidity 36 grams/KG dry air). If at this moment, cool with 30 ℃ of seawater, assume that it is cooled to 30 ℃, B3 point, obtain fresh water 36-27=9 grams. But, if be to cool it with deep seawater, cross B3 point, B2 point to B1 point, will produce fresh water 36-10.5=25.2 grams, be 2.8 times of 9 grams.
综上所述,本发明海水淡化的装置能有效利用热力发电厂的余热制造淡水,使海水淡化的成本大幅度降低。To sum up, the seawater desalination device of the present invention can effectively utilize the waste heat of a thermal power plant to produce fresh water, thereby greatly reducing the cost of seawater desalination.
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present invention should be included in the protection of the present invention. within range.
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