CN102636264A - Novel hydrogen atom spectrum tester and measuring method - Google Patents
Novel hydrogen atom spectrum tester and measuring method Download PDFInfo
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 title claims abstract description 23
- 238000001228 spectrum Methods 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 52
- 239000001257 hydrogen Substances 0.000 claims description 51
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 46
- CPBQJMYROZQQJC-UHFFFAOYSA-N helium neon Chemical compound [He].[Ne] CPBQJMYROZQQJC-UHFFFAOYSA-N 0.000 claims description 32
- 230000003595 spectral effect Effects 0.000 claims description 29
- 230000003287 optical effect Effects 0.000 claims description 22
- 238000002474 experimental method Methods 0.000 claims description 14
- 239000006185 dispersion Substances 0.000 claims description 6
- 238000001675 atomic spectrum Methods 0.000 claims description 5
- 230000007547 defect Effects 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 238000000559 atomic spectroscopy Methods 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
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Abstract
Description
技术领域 technical field
本发明涉及一种测量氢原子光谱的实验仪器,具体的说是涉及一种利用双光束光路来实现氢原子光谱测量的实验仪器,主要应用于氢原子可见光谱线的测量。 The invention relates to an experimental instrument for measuring the hydrogen atom spectrum, in particular to an experimental instrument for realizing the hydrogen atom spectrum measurement by using a double-beam optical path, which is mainly used in the measurement of the hydrogen atom's visible spectral lines. the
背景技术 Background technique
原子光谱是研究原子结构的一种重要方法,每一种原子都有其特定的线状光谱。其中,氢原子的光谱最为简单并且具有明显的规律。1885年,巴尔末总结了人们对氢光谱测量的结果,发现了氢光谱的规律,成为检验原子理论可靠性的标准和测量其他基本物理常数的依据。因此,测定氢原子可见光谱线的波长对认识原子的分离能级以及光谱规律有重要的作用。 Atomic spectroscopy is an important method to study atomic structure, and each atom has its own specific line spectrum. Among them, the spectrum of hydrogen atom is the simplest and has obvious rules. In 1885, Ballmer summarized the results of people's hydrogen spectrum measurement and discovered the law of hydrogen spectrum, which became the standard for testing the reliability of atomic theory and the basis for measuring other basic physical constants. Therefore, the determination of the wavelength of the visible spectral lines of the hydrogen atom plays an important role in understanding the separation energy level of the atom and the law of the spectrum. the
在现有的氢原子可见光谱线波长的测量中,最常用的方法是利用氦氖灯的5条红谱线作为光谱标尺,采用读谱仪测出5条氦氖红谱线和氢红线的位置;利用最小二乘法进行拟合得到氢原子红谱线的波长。但在现有的氢原子光谱测量仪器中,氦氖灯和氢灯是单光束入射系统,共用同一激励电源,一次实验需要对氦氖灯和氢灯依次轮换4次。而由于激励电源为几千伏特的高压电源,多次换灯使得该实验存在较大的安全隐患。此外,多次换灯使得实验效率低下。 In the existing measurement of the wavelength of the visible spectral lines of hydrogen atoms, the most commonly used method is to use the five red spectral lines of the helium-neon lamp as a spectral scale, and use a spectrometer to measure the distance between the five helium-neon red spectral lines and the hydrogen red line. position; the wavelength of the red line of the hydrogen atom was obtained by fitting using the least squares method. However, in the existing hydrogen atomic spectrometry instruments, the helium-neon lamp and the hydrogen lamp are a single-beam incident system and share the same excitation power supply. One experiment needs to alternate the helium-neon lamp and the hydrogen lamp four times. However, because the excitation power supply is a high-voltage power supply of several thousand volts, the experiment has a greater potential safety hazard due to repeated lamp changes. In addition, multiple lamp changes make the experiment inefficient. the
综上分析可知,在现有公开的背景技术中,发展一种原理简单、安全高效的新型氢原子光谱实验仪是一个待解决的技术难题。 From the above analysis, it can be seen that in the existing disclosed background technology, it is a technical problem to be solved to develop a new type of hydrogen atomic spectrometer experiment instrument with simple principle, safety and high efficiency. the
发明内容 Contents of the invention
本发明的目的是为解决上述技术问题的不足,提供一种新型的氢原子光谱实验仪器,该发明具有无需换灯、操作简单、安全高效的优点。 The object of the present invention is to solve the above-mentioned technical problems and provide a novel hydrogen atomic spectroscopy experimental instrument, which has the advantages of no need to change lamps, simple operation, safety and high efficiency. the
本发明为解决上述技术问题的不足,所采用的技术方案是:一种新型氢原子光谱实验仪,其特征在于:由光束入射系统、平行光管系统、色散系统和接收系统四部分构成; In order to solve the deficiencies of the above-mentioned technical problems, the technical solution adopted by the present invention is: a novel hydrogen atom spectroscopic experiment instrument, which is characterized in that it consists of four parts: a beam incident system, a collimator system, a dispersion system and a receiving system;
所述的光束入射系统为双光束入射系统,由两支相互垂直的光路构成,一支光路为主光轴光路,依次放置氦氖灯、会聚透镜I、分束镜、滤光片和会聚透镜III,所述的分束镜位于会聚透镜I的焦平面上,另一支光路依次放置氢灯、会聚透镜II,会聚透镜II与分束镜间的距离为会聚透镜II的焦距; The beam incidence system is a double beam incidence system, which is composed of two mutually perpendicular optical paths, one optical path is the main optical axis optical path, and a helium-neon lamp, a converging lens I, a beam splitter, an optical filter and a converging lens are placed in sequence III, the beam splitter is located on the focal plane of the converging lens I, and another optical path is placed with a hydrogen lamp and a converging lens II in sequence, and the distance between the converging lens II and the beam splitting mirror is the focal length of the converging lens II;
所述的氢灯发出的光线经会聚透镜II后照射在分束镜上,经分束镜反射后与所述的氦氖灯发出的光线经分束镜透射后汇合,再依次照射在滤光片和会聚透镜III上; The light emitted by the hydrogen lamp is irradiated on the beam splitter after passing through the converging lens II, after being reflected by the beam splitter, it merges with the light emitted by the He-Ne lamp after being transmitted through the beam splitter, and then sequentially irradiated on the filter sheet and converging lens III;
所述的平行光管系统包括狭缝和准直镜,狭缝设置在会聚透镜III的出射光路上,准直镜使从狭缝透过的光线变成平行光,狭缝位于会聚透镜III的焦平面上; The collimator system includes a slit and a collimating mirror, the slit is arranged on the outgoing light path of the converging lens III, the collimating mirror makes the light passing through the slit into parallel light, and the slit is located at the converging lens III on the focal plane;
所述的色散系统由恒偏向棱镜构成,恒偏向棱镜设置在准直镜的出射光路上,恒偏向棱镜的设置位置使射入恒偏向棱镜的光束内的最小偏向角单色光的入射光束和出射光束的夹角为90°; The dispersion system is composed of a constant deflection prism, the constant deflection prism is arranged on the outgoing light path of the collimator, and the setting position of the constant deflection prism makes the incident beam of the minimum deflection angle monochromatic light in the beam of the constant deflection prism and The included angle of the outgoing beam is 90°;
所述的接收系统由出射物镜、读谱物镜和螺旋测微目镜构成,从恒偏向棱镜射出的出射光束依次经过出射物镜和读谱物镜射在螺旋测微目镜上,螺旋测微目镜置于读谱物镜的焦平面上。 The receiving system is composed of an exit objective lens, a spectrum reading objective lens and a spiral micrometer eyepiece. The outgoing light beam emitted from the constant deflection prism passes through the exit objective lens and the spectrum reading objective lens in turn and shoots on the spiral micrometer eyepiece. The spiral micrometer eyepiece is placed on the reading in the focal plane of the spectral objective.
本发明所述的滤光片的透过光波长范围为600nm-700nm。 The transmitted light wavelength range of the optical filter of the present invention is 600nm-700nm. the
一种新型氢原子光谱实验仪的测量方法, A new measuring method of hydrogen atomic spectrometer,
步骤一、调节恒偏向棱镜,使符合最小偏向角条件的单色光的入射光束和出射光束的夹角为90°; Step 1. Adjust the constant deflection prism so that the angle between the incident beam and the outgoing beam of the monochromatic light meeting the minimum deflection angle condition is 90°;
步骤二、点燃氦氖灯,调整会聚透镜I和会聚透镜III的位置,使氦氖灯发出的光线射入狭缝; Step 2, light the helium-neon lamp, adjust the positions of the converging lens I and the converging lens III, so that the light emitted by the helium-neon lamp enters the slit;
步骤三、调整螺旋测微目镜,使氦氖谱线的红光谱区调节至视场中央; Step 3. Adjust the spiral micrometer eyepiece so that the red spectral region of the He-Ne spectral line is adjusted to the center of the field of view;
步骤四、关闭氦氖灯,点燃氢灯,调整会聚透镜II的位置,使氢灯发出的光线射入狭缝;调节螺旋测微目镜使氢红线清晰,把螺旋测微目镜的十字叉丝交点对准氢红线; Step 4. Turn off the helium-neon lamp, ignite the hydrogen lamp, adjust the position of the converging lens II so that the light emitted by the hydrogen lamp enters the slit; adjust the spiral micrometer eyepiece to make the hydrogen red line clear, and place the intersection of the crosshairs of the spiral micrometer eyepiece Align the hydrogen red line;
步骤五、再次点燃氦氖灯,依次记录氢红线左侧相邻的两条氦氖谱线位置、氢红线位置、氢红线谱线左侧相邻的三条氦氖谱线位置;测量谱线位置时使螺旋测微目镜的鼓轮自左至右沿一个方向转动,消除空程差; Step 5. Light the helium-neon lamp again, and record the positions of the two adjacent helium-neon spectral lines on the left side of the hydrogen red line, the position of the hydrogen red line, and the positions of the three adjacent helium-neon spectral lines on the left side of the hydrogen red line; measure the position of the spectral lines At the same time, the drum of the spiral micrometer eyepiece rotates in one direction from left to right to eliminate the gap difference;
步骤六、最后,通过最小二乘的曲线拟合方法,计算出待测氢原子光谱巴耳末系中可见光红谱线的波长。 Step 6. Finally, the wavelength of the visible red line in the Balmer system of the hydrogen atomic spectrum to be measured is calculated by the least squares curve fitting method. the
与现有技术相比,本发明的优点:本发明装置是一种新型氢原子光谱实验仪,具有原理简单、操作安全、快捷高效的特点。本发明具有突出的实质性特点和显著进步,可应用于氢原子光谱的测定。 Compared with the prior art, the present invention has the advantages that the device of the present invention is a new type of hydrogen atomic spectrometer experiment instrument, which has the characteristics of simple principle, safe operation, quickness and high efficiency. The invention has outstanding substantive features and remarkable progress, and can be applied to the determination of hydrogen atomic spectrum. the
附图说明 Description of drawings
下面结合附图对本发明的具体实施方式作进一步详细的说明。 The specific implementation manners of the present invention will be further described in detail below in conjunction with the accompanying drawings. the
附图1为现有氢原子光谱实验仪装置原理图; Accompanying drawing 1 is the schematic diagram of existing hydrogen atom spectrometer experiment apparatus;
附图2为本发明所公开的测量装置原理图。 Accompanying drawing 2 is the schematic diagram of the measuring device disclosed by the present invention.
其中,100-灯架;110-氦氖灯;120-氢灯;210-会聚透镜I;211-会聚透镜II;310-半反半透镜;410-滤光片;212-会聚透镜III;510-狭缝;610-准直镜;710-恒偏向棱镜;213-出射物镜;214-读谱物镜;810-螺旋测微目镜。 Among them, 100-light stand; 110-helium-neon lamp; 120-hydrogen lamp; 210-converging lens I; 211-converging lens II; 310-half mirror; 410-filter; 212-converging lens III; -slit; 610-collimator; 710-constant deflection prism; 213-exit objective; 214-spectrum reading objective; 810-spiral micrometer eyepiece. the
具体实施方式 Detailed ways
附图1为现有氢原子光谱实验仪装置原理图;其光束入射系统为单光束入射系统,由灯架100和会聚透镜III构成,灯架100上放置氢灯和氦氖灯;由于采用的是单光束入射系统,在实验过程中,需要依次轮换点亮氢灯和氦氖灯,一次实验需要4次换灯过程,并且氦氖灯的5条红谱线和氢红线不能同时在螺旋测微目镜810上显示;所以,现有技术存在安全隐患,实验效率低的缺点。
Accompanying drawing 1 is the device schematic diagram of existing hydrogen atomic spectrometer experiment instrument; Its beam incident system is a single beam incident system, is made of
附图2为为本发明所公开的测量装置原理图,一种新型氢原子光谱实验仪,由光束入射系统、平行光管系统、色散系统和接收系统四部分构成;其中,光束入射系统为双光束入射系统,由两支相互垂直的光路构成,一支光路为主光轴光路,依次放置氦氖灯110、会聚透镜I210、分束镜310、滤光片410、会聚透镜III212;所述的分束镜310位于会聚透镜I210的焦平面上; Accompanying drawing 2 is the schematic diagram of the measuring device disclosed by the present invention, a novel hydrogen atom spectrometer, which is composed of four parts: a beam incident system, a collimator system, a dispersion system and a receiving system; wherein, the beam incident system is a double The beam incident system is composed of two mutually perpendicular optical paths, one optical path is the main optical axis optical path, and the helium-neon lamp 110, the converging lens I210, the beam splitter 310, the optical filter 410, and the converging lens III212 are placed in sequence; The beam splitter 310 is located on the focal plane of the converging lens 1210;
另一支光路依次放置氢灯120、会聚透镜II211;所述的会聚透镜II211与分束镜310间的距离为会聚透镜II211的焦距;所述的氢灯120发出的光线经会聚透镜II211后照射在分束镜310上,经分束镜310反射后与所述的氦氖灯110发出的光线经分束镜310透射后汇合,再依次照射在滤光片410和会聚透镜III212上;所述的滤光片410的透过光波长范围为600nm-700nm; The other optical path places the hydrogen lamp 120 and the converging lens II211 in turn; the distance between the converging lens II211 and the beam splitter 310 is the focal length of the converging lens II211; the light emitted by the hydrogen lamp 120 is irradiated by the converging lens II211 On the beam splitter 310, after being reflected by the beam splitter 310, the light emitted by the helium-neon lamp 110 merges after being transmitted by the beam splitter 310, and then sequentially irradiates on the optical filter 410 and the converging lens III212; The wavelength range of the transmitted light of the optical filter 410 is 600nm-700nm;
所述的平行光管系统包括狭缝510和准直镜610,准直镜610的作用是使从狭缝510透过的光线变成平行光;所述的狭缝510位于会聚透镜III212的焦平面上;
The collimator system includes a
所述的色散系统由恒偏向棱镜710构成,其作用是将光束分解,使不同波长的单色光束沿不同的方向射出;符合最小偏向角条件的单色光,其入射光束和出射光束的夹角为90°;
The dispersion system is composed of a
所述的接收系统由出射物镜213、读谱物镜214和螺旋测微目镜810构成,所述的螺旋测微目镜810置于读谱物镜214的焦平面上。
The receiving system is composed of the
本发明装置的使用过程,其具体步骤如下: The use process of device of the present invention, its concrete steps are as follows:
1、调节恒偏向棱镜710,使符合最小偏向角条件的单色光的入射光束和出射光束的夹角为90°;
1. Adjust the
2、点燃氦氖灯110,调整会聚透镜I210和会聚透镜III212的位置,使氦氖灯110发出的光线射入狭缝510;
2. Light the helium-neon lamp 110, adjust the positions of the converging lens I210 and the converging lens III212, so that the light emitted by the helium-neon lamp 110 enters the
3、调整螺旋测微目镜810,使氦氖谱线的红光谱区调节至视场中央;
3. Adjust the
4、关闭氦氖灯110,点燃氢灯120,调整会聚透镜II211的位置,使氢灯120发出的光线射入狭缝510;调节螺旋测微目镜810使氢红线清晰,把螺旋测微目镜810的十字叉丝交点对准氢红线;
4. Turn off the helium-neon lamp 110, light the hydrogen lamp 120, adjust the position of the converging lens II211, so that the light emitted by the hydrogen lamp 120 enters the
5、再次点燃氦氖灯110,依次记录氢红线左侧相邻的两条氦氖谱线位置、氢红线位置、氢红线谱线左侧相邻的三条氦氖谱线位置;测量谱线位置时使螺旋测微目镜810的鼓轮自左至右沿一个方向转动,消除空程差;
5. Light the helium-neon lamp 110 again, and record the positions of the two adjacent helium-neon spectral lines on the left side of the hydrogen red line, the position of the hydrogen red line, and the positions of the three adjacent helium-neon spectral lines on the left side of the hydrogen red line; measure the position of the spectral lines At the same time, the drum of the
6、最后,通过最小二乘的曲线拟合方法,计算出待测氢原子光谱巴耳末系中可见光红谱线的波长。 6. Finally, the wavelength of the visible red line in the Balmer system of the hydrogen atomic spectrum to be measured is calculated by the least squares curve fitting method.
本发明的工作原理是: The working principle of the present invention is:
氢原子光谱的实验公式为 The experimental formula for hydrogen atomic spectrum is
(1) (1)
式中,l为谱线波长,RH实=10967758.306 m-1为里德伯常数实验值。 In the formula, l is the wavelength of the spectral line, and R H = 10967758.306 m -1 is the experimental value of the Rydberg constant.
当氢原子中电子从高能级向低能级跃迁时,就发出光线。其满足玻尔光谱理论公式, When electrons in a hydrogen atom transition from a higher energy level to a lower energy level, light is emitted. It satisfies the theoretical formula of Bohr spectrum,
(2) (2)
其中,m=9.11×10-31kg为电子静止质量,e0=8.85×10-12F×m-1为真空电容率,h=6.63×10-34J×s为普朗克常数,c=3×108m×s-1为真空中光速,RH理=10973731.534 m-1为里德伯常数的理论值。 Among them, m=9.11×10 -31 kg is the electronic rest mass, e 0 =8.85×10 -12 F×m -1 is the vacuum permittivity, h=6.63×10 -34 J×s is Planck’s constant, c =3×10 8 m×s -1 is the speed of light in vacuum, R H = 10973731.534 m -1 is the theoretical value of Rydberg constant.
在式(1)和式(2)中,不同的k对应不同的线系,不同的n对应同一线系中不同的谱线。本发明实验仪测定在可见光谱内巴耳末系的氢红线(对应k=2, n=3)的波长。 In formula (1) and formula (2), different k corresponds to different line systems, and different n corresponds to different spectral lines in the same line system. The experimental instrument of the present invention measures the wavelength of the hydrogen red line (corresponding to k =2, n =3) of the Balmer system in the visible spectrum.
由于光谱线位置的测量值是相对的,所以必须用已知波长的谱线作为基准。本发明的基准是氦氖灯的五条红谱线,在螺旋测微目镜上观察,从左至右其波长分别为l1=667.8276nm、l2=659.8953nm、l3=653.2880nm、l4=650.6530nm、l5=640.2250nm;待测氢红线(波长设为lH)的位置恰好位于l2和l3之间; Since the measured values of spectral line positions are relative, spectral lines of known wavelengths must be used as a reference. The benchmark of the present invention is the five red spectral lines of the helium-neon lamp. Observed on the spiral micrometer eyepiece, the wavelengths from left to right are l 1 =667.8276nm, l 2 =659.8953nm, l 3 =653.2880nm, l 4 =650.6530nm, l 5 =640.2250nm; the position of the hydrogen red line to be measured (wavelength set as l H ) is exactly between l 2 and l 3 ;
实验中利用螺旋测微目镜自左至右依次读出谱线l1、l2、lH、l3、l4、l5对应的位置y1、y2、yH、y3、y4、y5; In the experiment, the positions y 1 , y 2 , y H , y 3 , y 4 corresponding to the spectral lines l 1 , l 2 , l H , l 3 , l 4 , and l 5 were sequentially read from left to right by using the spiral micrometer eyepiece , y 5 ;
已知谱线位置y与波长l间满足如下关系, It is known that the relationship between the position y of the spectral line and the wavelength l satisfies the following relationship,
(3) (3)
其中、、l0为常数,这三个常数由氦氖五条红谱线的位置(y1、y2、y3、y4、y5)与波长(l1、l2、l3、l4、l5)通过最小二乘的曲线拟合方法来确定; in , , l 0 are constants, these three constants are composed of the positions (y 1 , y 2 , y 3 , y 4 , y 5 ) and wavelengths (l 1 , l 2 , l 3 , l 4 , l 5 ) determined by least squares curve fitting method;
然后,将氢红线的位置yH代入式(3),最终求得氢红线波长lH的数值。 Then, the position y H of the hydrogen red line is substituted into formula (3), and finally the value of the wavelength l H of the hydrogen red line is obtained.
经实验表明:本发明装置可快速、高效实现对氢原子光谱的测定;该发明装置具有原理简单、安全高效的特点,适合于氢原子光谱的测定。 Experiments show that the device of the invention can quickly and efficiently realize the determination of the hydrogen atom spectrum; the invention device has the characteristics of simple principle, safety and high efficiency, and is suitable for the determination of the hydrogen atom spectrum. the
the
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