CN102492541B - Method for extracting rose hip oil by supercritical carbon dioxide - Google Patents
Method for extracting rose hip oil by supercritical carbon dioxide Download PDFInfo
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- CN102492541B CN102492541B CN 201110414776 CN201110414776A CN102492541B CN 102492541 B CN102492541 B CN 102492541B CN 201110414776 CN201110414776 CN 201110414776 CN 201110414776 A CN201110414776 A CN 201110414776A CN 102492541 B CN102492541 B CN 102492541B
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- carbon dioxide
- rose hip
- hip oil
- extraction
- supercritical carbon
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000010667 rosehip oil Substances 0.000 title claims abstract description 25
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 18
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title claims abstract description 14
- 238000000605 extraction Methods 0.000 claims abstract description 26
- 238000001291 vacuum drying Methods 0.000 claims abstract description 6
- 238000010298 pulverizing process Methods 0.000 claims description 7
- 239000000284 extract Substances 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 238000011068 loading method Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract description 5
- 241000220317 Rosa Species 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003814 drug Substances 0.000 abstract description 3
- 235000013305 food Nutrition 0.000 abstract description 3
- 239000003921 oil Substances 0.000 abstract description 2
- 238000000926 separation method Methods 0.000 abstract 3
- 241000196324 Embryophyta Species 0.000 abstract 1
- 230000032683 aging Effects 0.000 abstract 1
- 150000001413 amino acids Chemical class 0.000 abstract 1
- 239000002537 cosmetic Substances 0.000 abstract 1
- 238000012856 packing Methods 0.000 abstract 1
- 238000005728 strengthening Methods 0.000 abstract 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 abstract 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 abstract 1
- 235000021050 feed intake Nutrition 0.000 description 4
- 241000109365 Rosa arkansana Species 0.000 description 3
- 235000005066 Rosa arkansana Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 235000021022 fresh fruits Nutrition 0.000 description 3
- 238000000638 solvent extraction Methods 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 1
- 208000006770 Ascorbic Acid Deficiency Diseases 0.000 description 1
- 208000024172 Cardiovascular disease Diseases 0.000 description 1
- 241000628997 Flos Species 0.000 description 1
- 102000004895 Lipoproteins Human genes 0.000 description 1
- 108090001030 Lipoproteins Proteins 0.000 description 1
- 235000016607 Rosa bella Nutrition 0.000 description 1
- 241000914162 Rosa bella Species 0.000 description 1
- 235000004789 Rosa xanthina Nutrition 0.000 description 1
- 241000220222 Rosaceae Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 206010047623 Vitamin C deficiency Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000005906 menstruation Effects 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 208000010233 scurvy Diseases 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008347 soybean phospholipid Substances 0.000 description 1
- 210000000952 spleen Anatomy 0.000 description 1
- 238000003815 supercritical carbon dioxide extraction Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
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- Fats And Perfumes (AREA)
- Medicines Containing Plant Substances (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
The invention provides a method for extracting rose hip oil by supercritical carbon dioxide. The following percentages all refer to weight percentages. The method for extracting rose hip oil by supercritical carbon dioxide includes the drying step, the smashing step, the feeding step and the extracting step, and specifically, the method includes the following steps: drying rose hips by a vacuum drying oven and controlling moisture within a range from 4% to 10%, smashing the dried rose hips and controlling smashing degree within a range from 30 to 70 meshes, packing the smashed rose hips into an extraction kettle, wherein feeding coefficient ranges from 70% to 90%. Extraction conditions include the extraction temperature ranging from 40 DEG C to 55 DEG C, the pressure ranging from 25MPa to 35MPa, the first separation temperature ranging from 45 DEG C to 65 DEG C, the pressure ranging from 7MPa to 15MPa, the second separation temperature ranging from 30 DEG C to 45 DEG C, the pressure ranging from 4MPa to 6MPa, flow rate of carbon dioxide ranging from 180kg/h to 260kg/h and extraction time ranging from 2.5 hours to 4.5 hours, and rose hip oil is discharged from a first separation outlet. The rose hip oil extracted by the supercritical carbon dioxide is natural plant refined oil having curative effect, contains seventeen kinds of amino acid and a great quantity of advanced unsaturated fatty acid, has effects of strengthening original cells, accelerating the growth of new cells and preventing skin ageing and the like and can be used in food, medicine, healthcare products and cosmetics.
Description
Technical field
The invention belongs to Vegetable oil lipoprotein extractive technique field, be specifically related to a kind of method of extracting rose hip oil by supercritical carbon dioxide.
Background technology
Fructus Rosae Davuricae, the formal name used at school Flos rosae multiflorae has another name called rose hip, and Rosa bella fruit belongs to the Rosaceae, is distributed widely in Heilungkiang and the ground such as on the south Xing'anling mountains.This fruit is warm in nature, and flavor acid is nutritious, among the peoplely searches for food in a large number or is used for making tea, steeping in wine etc." Chinese medicine voluminous dictionary " calls it that invigorating the spleen is regulated the flow of vital energy, the effect of nourishing blood for regulating menstruation.USSR (Union of Soviet Socialist Republics) the 8th, nine editions pharmacopeia are also recorded, and are used for the treatment of vitamin C deficiency.Recent year studies show that in a large number its effect such as anti-ageing, prevention and cure of cardiovascular disease in addition.
At present Fructus Rosae Davuricae just as a kind of natural health medicine by pay attention to day by day and extensive exploitation.Having occurred on market by this fruit juice is protective foods and the nourishing drink of main development, clinical injection liquid and the oral liquid of having developed take Fructus Rosae Davuricae as raw material.Extracting rose hip oil is comparatively rare on the market at present, and common extracting rose hip oil utilizes squeezing or solvent extraction technology to make.
Summary of the invention
At present common extracting rose hip oil utilizes squeezing or solvent extraction technology to make, the object of the invention is to utilize supercritical carbon dioxide extraction method, a kind of method of extracting rose hip oil by supercritical carbon dioxide is provided, it is many that the extracting rose hip oil of extraction has overcome pressed oil impurity, contains the shortcomings such as dissolvent residual after solvent extraction.The extracting rose hip oil yield that extracts is high, and impurity is low, there is no the advantages such as dissolvent residual,
The technical solution used in the present invention is summarized as follows:
Fructus Rosae Davuricae is adopted the vacuum drying oven oven dry, and moisture controlled is dried rear raw material pulverizing 4～10%, degree of grinding installs to the raw material after pulverizing in extraction kettle at 30～70 orders, and batch charging coefficient is 70～90%, extraction conditions is: 40～55 ℃ of extraction temperature, pressure 25～35MPa; Separate 45～65 ℃ of temperature, pressure 7～15MPa; Separate 30～45 ℃ of two temperature, pressure 4～6MPa; Carbon dioxide flow is 180～260kg/h, and extraction time 2.5～4.5 hours separates an outlet and is extracting rose hip oil.
The invention provides a kind of method of extracting rose hip oil by supercritical carbon dioxide, be characterised in that to comprise oven dry, pulverize, feed intake, extract four steps:
(1). oven dry: the wild rose fresh fruit is put into vacuum drying oven, and 45～60 ℃ of bake out temperatures are opened vacuum, and moisture controlled is 4～10%.
(2). pulverize: the Fructus Rosae Davuricae after drying is pulverized, and degree of grinding is at 30～70 orders.
(3). feed intake: the material after pulverizing drops in extraction kettle, and batch charging coefficient is 70～90%.
(4). extraction: 40～55 ℃ of extraction temperature, pressure 25～35MPa; Separate 45～65 ℃ of temperature, pressure 7～15MPa; Separate 30～45 ℃ of two temperature, pressure 4～6MPa; Carbon dioxide flow is 180～260kg/h, and extraction time 2.5～4.5 hours separates an outlet and is extracting rose hip oil.
Embodiment
The present invention is further illustrated below in conjunction with specific embodiment.
Embodiment 1
The method of the present embodiment extracting rose hip oil by supercritical carbon dioxide comprises the steps:
(1). oven dry: wild rose fresh fruit 10kg is put into vacuum drying oven, and 60 ℃ of bake out temperatures are opened vacuum, and moisture controlled oven dry 6% time finishes.
(2). pulverize: the Fructus Rosae Davuricae after drying is pulverized, and degree of grinding is at 40 orders.
(3). feed intake: the material after pulverizing drops in extraction kettle, and batch charging coefficient is 90%.
(4). extraction: 50 ℃ of extraction temperature, pressure 28MPa; Separate 55 ℃ of temperature, pressure 9MPa; Separate 35 ℃ of two temperature, pressure 5MPa; Carbon dioxide flow is 180kg/h, and extraction time 3 hours separates an outlet and is extracting rose hip oil.Extract extracting rose hip oil 300g.
Embodiment 2
The manufacture method of the present embodiment soybean phospholipid pressed candies comprises the steps:
(1). oven dry: wild rose fresh fruit 8.6kg is put into vacuum drying oven, and 60 ℃ of bake out temperatures are opened vacuum, and moisture controlled is 8%.
(2). pulverize: the Fructus Rosae Davuricae after drying is pulverized, and degree of grinding is at 50 orders.
(3). feed intake: the material after pulverizing drops in extraction kettle, and batch charging coefficient is 85%.
(4). extraction: 45 ℃ of extraction temperature, pressure 30MPa; Separate a temperature 60 C, pressure 12MPa; Separate two temperature 45 Cs, pressure 6MPa; Carbon dioxide flow is 200kg/h, and extraction time 3.5 hours separates an outlet and is extracting rose hip oil.Extract extracting rose hip oil 280.5g.
Claims (2)
1. the method for an extracting rose hip oil by supercritical carbon dioxide, following per-cent all is weight percentage, it is characterized in that the extracting rose hip oil by supercritical carbon dioxide step comprises oven dry, pulverizes, feeds intake, extracts four steps, be specially: Fructus Rosae Davuricae is adopted the vacuum drying oven oven dry, moisture controlled is 4～10%, raw material pulverizing after oven dry, degree of grinding is at 30～70 orders, raw material after pulverizing is installed in extraction kettle, batch charging coefficient is 70～90%, extraction conditions is: 40～55 ℃ of extraction temperature, pressure 25～35MPa; Separate 45～65 ℃ of temperature, pressure 7～15MPa; Separate 30～45 ℃ of two temperature, pressure 4～6MPa; Carbon dioxide flow is 180～260kg/h, and extraction time 2.5～4.5 hours separates an outlet and is extracting rose hip oil.
2. according to the method for extracting rose hip oil by supercritical carbon dioxide claimed in claim 1, it is characterized in that described batch charging coefficient is the actual weight of loading of extraction kettle and all fills the ratio of weight of material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110414776 CN102492541B (en) | 2011-12-13 | 2011-12-13 | Method for extracting rose hip oil by supercritical carbon dioxide |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110414776 CN102492541B (en) | 2011-12-13 | 2011-12-13 | Method for extracting rose hip oil by supercritical carbon dioxide |
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| CN102492541A CN102492541A (en) | 2012-06-13 |
| CN102492541B true CN102492541B (en) | 2013-05-15 |
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| CN 201110414776 Active CN102492541B (en) | 2011-12-13 | 2011-12-13 | Method for extracting rose hip oil by supercritical carbon dioxide |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102888280A (en) * | 2012-10-16 | 2013-01-23 | 九三粮油工业集团有限公司 | Method for extracting lilac essential oil |
| CN104982933B (en) * | 2015-07-06 | 2017-08-25 | 中国农业大学 | A kind of preparation method of rose fruit seed oil microcapsule |
| CN105273842A (en) * | 2015-11-17 | 2016-01-27 | 鹰潭中投科技有限公司 | Preparation method of rose perfume |
| CN109010133A (en) * | 2018-09-10 | 2018-12-18 | 深圳市仙迪化妆品有限公司 | A kind of molten rose berry extract of oil and application |
| CN110042001A (en) * | 2019-05-05 | 2019-07-23 | 黑龙江省睿墨笛科技有限责任公司 | A kind of post-processing approach of wild rose fruit seed oil |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1167776C (en) * | 2001-11-16 | 2004-09-22 | 苏珣 | Application of CO2 supercritical extraction technique to extract rose oil |
| CN1557521A (en) * | 2004-01-19 | 2004-12-29 | 中 孟 | Extraction method of wild rose under supercritical CO2 condition |
| CN101343594A (en) * | 2007-07-14 | 2009-01-14 | 周志忠 | Preparation method for rose hip or seed oil |
| CN102234587A (en) * | 2010-04-21 | 2011-11-09 | 龚之森 | Rose essential oil and preparation process thereof |
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