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CN102390972A - Micro-pore magnesite foam concrete - Google Patents

Micro-pore magnesite foam concrete Download PDF

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Publication number
CN102390972A
CN102390972A CN2011102256377A CN201110225637A CN102390972A CN 102390972 A CN102390972 A CN 102390972A CN 2011102256377 A CN2011102256377 A CN 2011102256377A CN 201110225637 A CN201110225637 A CN 201110225637A CN 102390972 A CN102390972 A CN 102390972A
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China
Prior art keywords
magnesite
magnesium chloride
foam concrete
manganese dioxide
insulating
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Pending
Application number
CN2011102256377A
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Chinese (zh)
Inventor
山发寿
杜庆贵
朱仲汉
山发录
山发财
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Individual
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Individual
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Publication date
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Priority to CN2011102256377A priority Critical patent/CN102390972A/en
Publication of CN102390972A publication Critical patent/CN102390972A/en
Pending legal-status Critical Current

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Abstract

The invention belongs to the technical field of building energy conservation and provides a solid magnesite foam concrete wallboard and a production technology of a building block, wherein the solid magnesite foam concrete wallboard is light in weight, high in strength and excellent in heat-insulating and sound-insulating effects. The solid magnesite foam concrete wallboard consists of 15-60% of magnesium oxide, 5-15% of magnesium chloride, 15-25% of water, 15-45% of inorganic padding, 0.5-1.5% of gas-generating agent, 0.01-0.1% of foaming agent, 0-1% of short fiber and a reinforcing material. The production technology provided by the invention has the advantages that: 1) the weight of the magnesite foam concrete can be controlled according to applications; 2) the shape of the magnesite foam concrete can be changed according to the applications; 3) more than 95% of micro-pore magnesite foam concrete has a bubble diameter between 0.1mm and 1mm, the bubble sealing property is excellent, bubbles are not communicated with one another, halogen reduction is avoided, the water resistance is excellent, the weight is light, the strength is high, the shock resistance is strong, and the heat-insulating and sound-insulating effects are excellent; 4) the padding can be selected according to a local condition by taking wastes and residues of a local factory, deposited materials in a river and a lake and the like as raw materials; and 5) production is convenient, energy is saved, environment is protected, and a wall building-block, a door core plate, a fireproof plate, a partition plate, a heat-insulating plate and a sound-insulating and sound-absorbing material can be manufactured.

Description

Micropore magnesite foamed concrete
Technical field
The invention belongs to the energy-saving building technology field; The making method that relates to a kind of magnesite foamed concrete relates in particular to a kind of microvoid structure concrete, and the bubble closure is good; Be not communicated with mutually; Characteristics that not only have anti-anti-halogen, water resisting property, resistance to deformation, and light weight, intensity are high, heat insulation and all good solid magnesite foamed concrete plates of soundproof effect and the production technology method of building block.
Background technology
In the building, light material receives market favor in modern times, and particularly light lath and building block, construction save time, laborsaving, have load little, save advantage such as floor area of building.Therefore, be widely used in reconstruction project, the indoor partition wall of Highrise buildings etc.; At present; Light trabs in construction market manufacturing and use has many kinds; But main raw is hole, the GRC garden batten processed by cement, gypsum, light concrete, vegetable fibre, foamed cement, silicon magnesium, GRC square hole batten etc.; But these battens still can not effectively lower unit weight, and incubation and thermal insulation function is not obvious, and moisture-sensitive, the dry existence with after strain, some plate are used shortcomings such as variety of raw material is many, cost is high and making method is complicated, throughput is low.
Summary of the invention
The present invention utilizes magnesia cement to have strong, high-strength, fast with fixed attention, characteristics such as cohesive force is strong, wear-resisting, fire prevention morning, to defective that exists in the prior art and deficiency.The present invention provide a kind of fine particle of suiting measures to local conditions to make full use of for factory's discharging be main various solid dusts, slag and mine tailing or for various drifts, dust storm stores, the loess that forms in the rivers,lakes and seas be that the various settlings of main argillaceous mineral are as starting material; Produce easy, energy-conserving and environment-protective; Light weight; Heat insulation, soundproof effect is superior, the making method of micropore magnesite foamed concrete is following:
1, raw material is formed (weight %):
1. Natural manganese dioxide 15-60%: the active oxidation magnesium dust of processing by magnesite, dolomite calcination or magnesium chloride pyrolysis etc.;
2. magnesium chloride 5-15%: for bischofite, halogen sheet, Magnesium Chloride Anhydrous or contain the aqueous solution of magnesium chloride;
3. water 15-25%: tap water, river or well water;
4. mineral filler 15-45%: for various solid dusts, slag and the mine tailing of factory's discharging or for various drifts, dust storm stores, the loess that forms in the rivers,lakes and seas is the various settlings of main argillaceous mineral;
5. foaming agent 0.5-1.5%: ydrogen peroxide 50 or aluminium powder, aluminium cream;
6. foaming agent 0.01-0.1%: be Z 150PH or rosined soap class tensio-active agent or whipping agent;
7. staple fibre 0-2.5%: alkali-free or middle alkali glass staple fibre or agricultural crop straw, rice husk or sawdust short fiber of plant for pulverizing;
8. strongthener: middle alkali fiber cloth, non-woven fabrics layer 2-4 or bamboo bar, bamboo chip 3-8 root.
2, production technique:
1. form after Natural manganese dioxide, mineral filler and the staple fibre mixing by above-mentioned 1 raw material, add stirrer and stir, process the Natural manganese dioxide batch mixing;
2. after placing pond or other container to add water in magnesium chloride by the raw material composition, fully stir and make the magnesium chloride dissolving, process magnesium chloride brine;
3. in being placed with the stirrer of 1. Natural manganese dioxide batch mixing, adding magnesium chloride brine stirs and processes the magnesia cement slip;
4. in the magnesia cement slip stirrer that is placed with 3., adding foaming agent, foaming agent stir, and process the magnesite foam mud;
5. with steam piano or alternate manner magnesite foam mud is 4. injected building block mould, floating upper surface is processed walling unit after the maintenance; Or in spread the mould bottom surface alkali fiber cloth or non-woven fabrics; With steam piano or alternate manner magnesite foam mud is 4. injected mould then; In foam mud, add bamboo bar, bamboo chip muscle material as required, alkali fiber cloth or non-woven fabrics in magnesite foam mud end face is spread at last, and be pressed in the magnesite foam mud middle alkali fiber cloth or non-woven fabrics floating; Various wallboards or sheet material are processed in the maintenance moulding.
3, product advantage
1. the intensity of micropore magnesite foamed concrete plate and building block and weight can be controlled according to purposes, and unit weight is 300-800Kg ∕ m 3, ultimate compression strength is 0.5-5Mpa;
2. shape, length, width and the thickness of micropore magnesite foamed concrete plate can change according to purposes, and thickness of slab can be controlled between the 20-400mm; Can make the heat insulating board of door panel, decorative sheet, various partition plate, exterior wall, roofing; The materials for wall of various temperature canopies and roof boarding; The inner, external wall and the roofing heat insulating material that also can be used for various refrigerations, freezing storehouse;
3. the structure of micropore magnesite foamed concrete plate and building block is made up of the bubble of Φ 0.1-1mm; The bubble closure is good; Be not communicated with mutually, not only have the characteristics of anti-anti-halogen, water resisting property, resistance to deformation, and light weight, intensity is high, shock resistance is strong; Have extraordinary heat insulation (thermal conductivity can reach 0.076W/mK), soundproof effect, can make various heat insulation and sound absorbent materials;
4. main raw material(s) can suit measures to local conditions to make full use of the drift that forms in solid slag, dust or dust storm stores, loess and the rivers,lakes and seas of solid waste, factory discharging in mine; Produce easy, energy-conserving and environment-protective.
 
Embodiment one
1, following table is that wallboard raw material of the present invention is formed instance:
Raw material Case study on implementation 1 Case study on implementation 2 Case study on implementation 3 Case study on implementation 4 Case study on implementation 5
Natural manganese dioxide (%) 51.0 41.6 28.6 30.0 18.3
Bischofite (%) 17.0 15.3 14.3 17.6 16.5
Water (%) 20.0 21.0 27.4 22.4 18.5
Loess (%) 10.0 20.0 28.6 28.8 45.8
Ydrogen peroxide 50 (%) 1.0 1.0 1.0 1.2 0.9
Whipping agent (%) 0.1 0.1 0.1 0.1 0.1
Staple glass fibre (%) 0.1 0.1 0.1 0.1 0.1
Strongthener Grid cloth Grid cloth Grid cloth Grid cloth Grid cloth
Remarks Natural manganese dioxide is by dolomite calcination powder, MgO 2Content is 23%. Natural manganese dioxide is by dolomite calcination powder, MgO 2Content is 23%. Natural manganese dioxide is light burnt powder, MgO 2Content is 75%. Natural manganese dioxide is light burnt powder, MgO 2Content is 88%. Natural manganese dioxide is light burnt powder, MgO 2Content is 88%.
2, following is wallboard process implementing step:
1. Natural manganese dioxide, mineral filler, staple glass fibre are added the stirrer stirring and make it even, process the Natural manganese dioxide batch mixing;
2. placing small-sized pond to add water bischofite fully stirs and makes magnesium chloride dissolving, process magnesium chloride brine;
3. adding magnesium chloride brine 2. fully stirs and processes the magnesia cement slip in the stirrer that is placed with Natural manganese dioxide batch mixing 1.;
4. ydrogen peroxide 50, whipping agent are joined in the magnesia cement slip stirrer 3., fully stirring makes it even, processes the magnesite foam mud;
5. alkali fiber Gridding cloth in spread the mould bottom surface, then with steam piano 4. the magnesite foam mud inject mould, alkali fiber Gridding cloth in magnesite foam mud end face is spread, and middle alkali fiber cloth is pressed in the magnesite foam mud floating maintains moulding.
Embodiment two
1, following table is that building block raw material of the present invention is formed instance:
Raw material Case study on implementation 1 Case study on implementation 2 Case study on implementation 3 Case study on implementation 4
Natural manganese dioxide (%) 46.0 38.3 30.0 18.3
Bischofite (%) 16.0 15.3 17.6 16.5
Water (%) 20.6 21.3 22.4 18.5
Loess (%) 15.3 23.0 28.8 45.8
Ydrogen peroxide 50 (%) 1.0 1.0 1.2 0.9
Whipping agent (%) 0.1 0.1 0.1 0.1
Staple fibre (%) 0.1 0.1 0 0
Remarks Natural manganese dioxide forms MgO by dolomite calcination 2Content is 23%. Natural manganese dioxide forms MgO by dolomite calcination 2Content is 23%. Natural manganese dioxide is light burnt powder, MgO 2Content is 88%. Natural manganese dioxide is light burnt powder, MgO 2Content is 88%.
2, following is building block process implementing step:
1. Natural manganese dioxide, mineral filler, staple fibre are added the stirrer stirring and make it even, process the Natural manganese dioxide batch mixing;
2. placing small-sized pond to add water bischofite fully stirs and makes magnesium chloride dissolving, process magnesium chloride brine;
3. adding magnesium chloride brine 2. fully stirs and processes the magnesia cement slip in the stirrer that is placed with Natural manganese dioxide batch mixing 1.;
4. ydrogen peroxide 50, whipping agent are joined in the stirrer of the magnesia cement slip that is placed with 3., stirring makes it even, processes the magnesite foam mud;
5. with steam piano that magnesite foam mud injection mould 4. is floating, the maintenance moulding.

Claims (3)

1. micropore magnesite foamed concrete is characterized in that being made up of the raw material of following weight ratio:
Natural manganese dioxide 15-60%, magnesium chloride 5-15%, water 15-25%, mineral filler 15-45%, foaming agent 0.5-1.5%, foaming agent 0.01-0.1%, staple fibre 0-1% and strongthener.
2. the making method of micropore magnesite foamed concrete as claimed in claim 1 is characterized in that described making method comprises the steps:
1. the raw material of foundation above-mentioned 1 composition stirs Natural manganese dioxide, mineral filler, staple fibre adding stirrer, processes the Natural manganese dioxide batch mixing;
2. placing pond or other container to add entry in magnesium chloride by 1 raw material proportion of composing stirs and makes the magnesium chloride dissolving, process magnesium chloride brine;
3. in being placed with the stirrer of 1. Natural manganese dioxide batch mixing, adding 2. magnesium chloride brine stirs and processes the magnesia cement slip;
4. foaming agent, foaming agent are joined and be placed with 3. in the magnesia cement slip stirrer, fully stir and make it even, process the magnesite foam mud;
5. with steam piano or alternate manner magnesite foam mud is 4. injected mould, process magnesite foamed concrete wallboard or building block, and can in foam mud, add the intensity of fiberglass gridding cloth, bamboo bar, bamboo chip muscle material enhancing partition plate as required.
3. micropore magnesite foamed concrete according to claim 1 is characterized in that:
Natural manganese dioxide: the active oxidation magnesium dust of processing through pyrolysis through calcining or magnesium chloride by magnesite, rhombspar;
Magnesium chloride: bischofite, halogen sheet, Magnesium Chloride Anhydrous or contain the aqueous solution of magnesium chloride;
Mineral filler: the fine particle that discharges for factory is main various solid dusts, slag and mine tailing or is that various drifts, dust storm stores, the loess that forms in the rivers,lakes and seas is the various settlings of master's argillaceous mineral;
Foaming agent: industrial ydrogen peroxide 50 or aluminium powder, aluminium cream;
Foaming agent: Z 150PH, rosined soap class tensio-active agent or whipping agent;
Strongthener: be middle alkali fiber cloth, non-woven fabrics or bamboo bar, bamboo chip.
CN2011102256377A 2011-08-08 2011-08-08 Micro-pore magnesite foam concrete Pending CN102390972A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN2011102256377A CN102390972A (en) 2011-08-08 2011-08-08 Micro-pore magnesite foam concrete

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CN102390972A true CN102390972A (en) 2012-03-28

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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102643064A (en) * 2012-04-16 2012-08-22 湟源科美新型材料有限公司 Energy-saving fireproof insulation board and manufacturing method thereof
CN103011750A (en) * 2012-12-17 2013-04-03 天津大学 Organic-inorganic composite light-weight and high-strength baseplate and preparation method thereof
CN103113081A (en) * 2012-03-29 2013-05-22 刘丰 Microbubble magnesia cement internal/external wallboard and preparation method thereof
CN103449791A (en) * 2013-07-16 2013-12-18 汪永辉 Foam light partition board and preparation method of same
CN104086153A (en) * 2014-06-30 2014-10-08 江苏新光环保工程有限公司 Magnesite sound absorption brick
CN104130006A (en) * 2014-08-04 2014-11-05 马鞍山十七冶工程科技有限责任公司 Straw fiber reinforced foam concrete and preparation method thereof
CN104129959A (en) * 2014-08-04 2014-11-05 马鞍山十七冶工程科技有限责任公司 Self-heat-insulation light weight wallboard containing hollow ceramsites and preparation method thereof
CN104446313A (en) * 2014-11-27 2015-03-25 中国科学院青海盐湖研究所 Magnesium oxysulfate cement coating for exterior walls and preparation method of coating
CN105174996A (en) * 2015-07-15 2015-12-23 徐高强 Lightweight environmental protection glass magnesium board
CN105198369A (en) * 2015-10-10 2015-12-30 田万春 Fireproof, heat-retaining and decorative integrated plate for straw walls and preparation method of integrated plate
CN105367121A (en) * 2015-12-03 2016-03-02 中国科学院青海盐湖研究所 Magnesium cement-based foamed concrete block and preparation method therefor
CN106882949A (en) * 2015-12-15 2017-06-23 万智慧 A kind of magnesite board of high intensity and preparation method thereof
CN107435417A (en) * 2017-06-20 2017-12-05 中国华西企业有限公司 Roofing foam concrete construction
CN107660467A (en) * 2017-09-30 2018-02-06 李均裕 A kind of cowboying method
CN108218385A (en) * 2018-03-26 2018-06-29 济南大学 Partition wall batten with dust storm preparation and preparation method thereof
CN109680599A (en) * 2017-07-02 2019-04-26 陈佑生 A kind of bridge pinner
CN110282941A (en) * 2019-05-29 2019-09-27 昌鑫生态科技(陕西)有限公司 Utilize the technology of Industrial Solid Waste processing environmental friendly material
CN110315781A (en) * 2019-06-30 2019-10-11 德州瑞拓通风设备有限公司 A kind of glass-magnesium composite plate waste recovery reuse method and products thereof
CN111423166A (en) * 2020-03-23 2020-07-17 南京林业大学 A kind of chopped bamboo reinforced concrete and processing method thereof
CN113443882A (en) * 2021-07-20 2021-09-28 吉林省优瑞佳新型建筑材料有限公司 Light-weight aerogel

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1034862C (en) * 1990-03-23 1997-05-14 中国建筑材料科学研究院房建材料与混凝土研究所 Production method of silicon-magnesium aerated hollow light partition board

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1034862C (en) * 1990-03-23 1997-05-14 中国建筑材料科学研究院房建材料与混凝土研究所 Production method of silicon-magnesium aerated hollow light partition board

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103113081A (en) * 2012-03-29 2013-05-22 刘丰 Microbubble magnesia cement internal/external wallboard and preparation method thereof
CN102643064B (en) * 2012-04-16 2013-12-18 湟源科美新型材料有限公司 Energy-saving fireproof insulation board and manufacturing method thereof
CN102643064A (en) * 2012-04-16 2012-08-22 湟源科美新型材料有限公司 Energy-saving fireproof insulation board and manufacturing method thereof
CN103011750A (en) * 2012-12-17 2013-04-03 天津大学 Organic-inorganic composite light-weight and high-strength baseplate and preparation method thereof
CN103449791B (en) * 2013-07-16 2016-01-20 汪永辉 A kind of Foam light partition board and preparation method thereof
CN103449791A (en) * 2013-07-16 2013-12-18 汪永辉 Foam light partition board and preparation method of same
CN104086153A (en) * 2014-06-30 2014-10-08 江苏新光环保工程有限公司 Magnesite sound absorption brick
CN104086153B (en) * 2014-06-30 2016-09-14 江苏新光环保工程有限公司 A kind of magnesite acoustic tile
CN104130006A (en) * 2014-08-04 2014-11-05 马鞍山十七冶工程科技有限责任公司 Straw fiber reinforced foam concrete and preparation method thereof
CN104130006B (en) * 2014-08-04 2015-09-23 马鞍山十七冶工程科技有限责任公司 The foamed concrete that a kind of stalk fibre strengthens and preparation method
CN104129959B (en) * 2014-08-04 2016-02-24 马鞍山十七冶工程科技有限责任公司 A kind of self-insulating light wallboard containing hollow haydite and preparation method
CN104129959A (en) * 2014-08-04 2014-11-05 马鞍山十七冶工程科技有限责任公司 Self-heat-insulation light weight wallboard containing hollow ceramsites and preparation method thereof
CN104446313A (en) * 2014-11-27 2015-03-25 中国科学院青海盐湖研究所 Magnesium oxysulfate cement coating for exterior walls and preparation method of coating
CN105174996A (en) * 2015-07-15 2015-12-23 徐高强 Lightweight environmental protection glass magnesium board
CN105198369A (en) * 2015-10-10 2015-12-30 田万春 Fireproof, heat-retaining and decorative integrated plate for straw walls and preparation method of integrated plate
CN105367121A (en) * 2015-12-03 2016-03-02 中国科学院青海盐湖研究所 Magnesium cement-based foamed concrete block and preparation method therefor
CN106882949A (en) * 2015-12-15 2017-06-23 万智慧 A kind of magnesite board of high intensity and preparation method thereof
CN107435417A (en) * 2017-06-20 2017-12-05 中国华西企业有限公司 Roofing foam concrete construction
CN109680599A (en) * 2017-07-02 2019-04-26 陈佑生 A kind of bridge pinner
CN107660467A (en) * 2017-09-30 2018-02-06 李均裕 A kind of cowboying method
CN108218385A (en) * 2018-03-26 2018-06-29 济南大学 Partition wall batten with dust storm preparation and preparation method thereof
CN108218385B (en) * 2018-03-26 2020-09-01 济南大学 Partition wall slats prepared with wind-blown sand and preparation method thereof
CN110282941A (en) * 2019-05-29 2019-09-27 昌鑫生态科技(陕西)有限公司 Utilize the technology of Industrial Solid Waste processing environmental friendly material
CN110315781A (en) * 2019-06-30 2019-10-11 德州瑞拓通风设备有限公司 A kind of glass-magnesium composite plate waste recovery reuse method and products thereof
CN111423166A (en) * 2020-03-23 2020-07-17 南京林业大学 A kind of chopped bamboo reinforced concrete and processing method thereof
CN113443882A (en) * 2021-07-20 2021-09-28 吉林省优瑞佳新型建筑材料有限公司 Light-weight aerogel

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Application publication date: 20120328