CN102390933A - Dry grain for crystal throwing brick and method for preparing crystal throwing brick - Google Patents
Dry grain for crystal throwing brick and method for preparing crystal throwing brick Download PDFInfo
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- CN102390933A CN102390933A CN2011102284678A CN201110228467A CN102390933A CN 102390933 A CN102390933 A CN 102390933A CN 2011102284678 A CN2011102284678 A CN 2011102284678A CN 201110228467 A CN201110228467 A CN 201110228467A CN 102390933 A CN102390933 A CN 102390933A
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- brick
- throwing brick
- dry grain
- crystal
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Links
- 239000011449 brick Substances 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title abstract description 9
- 239000013078 crystal Substances 0.000 title abstract 8
- 210000003298 dental enamel Anatomy 0.000 claims description 15
- 238000010304 firing Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 8
- 238000000748 compression moulding Methods 0.000 claims description 7
- 239000004744 fabric Substances 0.000 claims description 7
- 239000011734 sodium Substances 0.000 abstract description 12
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 238000005265 energy consumption Methods 0.000 abstract description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052700 potassium Inorganic materials 0.000 abstract description 3
- 239000011591 potassium Substances 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 3
- 229910052708 sodium Inorganic materials 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 235000013339 cereals Nutrition 0.000 abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 230000004927 fusion Effects 0.000 abstract 1
- 235000011868 grain product Nutrition 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 description 9
- 239000004575 stone Substances 0.000 description 9
- 239000002585 base Substances 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000035807 sensation Effects 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- -1 pottery Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
The invention discloses a dry grain for a crystal throwing brick, comprising the following components of Al2O3, SiO2, K2O, CaO, Na2O, MgO, ZnO, BaO, B2O3 and the like. The invention also discloses a method for preparing the crystal throwing brick by using the dry grain. The crystal throwing brick prepared by using the dry grain for the crystal throwing brick in the invention is sintered at one step, therefore, a biscuitfiring process can be omitted, the energy consumption is greatly reduced, pollution is effectively reduced, the production cost can be reduced by about 15%, and the production benefit can be greatly increased. The produced crystal throwing brick has high glaze transparency and fewer air bubbles. The dry grain for the crystal throwing brick provided by the invention has high initial vitrifying temperature and small high-temperature viscosity, a blank can keep good gas exhaust, the air bubbles can be removed at high temperature as much as possible, the usage temperature of a fusion cake can be adjusted by changing the contents of potassium and sodium, a series of dry grain products can be obtained, and the compatibility of the products is good.
Description
Technical field
The present invention relates to a kind ofly throw brilliant brick with dry granular and use the preparation method of the brilliant brick of throwing of this dry granular.
Background technology
The texture of stone material is soft attractive in appearance serious, and elegant style is in a great variety, is the ideal material of decorating luxurious building, thereby high-grade fine stone material product is " distinguished guest " during many large-scale public spaces, villa big house are decorated always.But stone material is a kind of scarce resource, and high-grade fine stone material a thousand pieces of gold difficulty on market is asked.
Blemish in an otherwise perfect thing be; Lithotome has radioactivity, uses in the interior space not meet the environmental protection life idea, moreover; Because lithotome is exploited from natural rock mass; Formed pattern texture is difficult to nature and is connected, and can't realize the big area paving when therefore using, and is difficult to form unified and complete style.And the exploitation of stone material, not only wasted lot of manpower and material resources, and ecotope has been caused certain injury.
It is the NEW TYPE OF COMPOSITE sheet material that sytull is compounded in brick brick modelled after an antique surface one deck 2-5mm that imitative stone is thrown brilliant brick; It integrates glass, pottery, stone material advantage; Merge glass smelting technology, ceramic tile shaping and crystallization and thermal treatment, polishing, cutting technique in one, sytull piece pellet shop is applied on the ceramic tile base substrate formed compact product structure, clean mark, glittering and translucent through crystallizing and sintering; Stereoscopic sensation is strong, has the sensation as the beautiful matter.Soil pick-up not fully; Maintenance convenient for cleaning, wear resistance, aspects such as surface hardness, folding strength all are superior to granite and marble; Comprise the glass matrix structure again; Its acid-alkali-resistant degree, corrosion resistance all are far more than lithotome, and especially weather resisteant is more outstanding, stand to expose to the weather for a long time also can not fade and weathering.Compare the radiation pollution of lithotome; Imitative stone is thrown brilliant brick does not only have radioactivity; But also avoided the uneven shortcoming of its aberration intensity; Can make the linking harmony and natural more between the different ceramic tiles, not only avoid lithotome to have the shortcoming of flaw, also can be according to the paving of arbitrarily arranging in pairs or groups of individual's hobby.
Because the granularity of frit dry granular is between 20～100 orders, the ulking thickness of dry granular is 1～3mm, can not reach this thickness through drenching glaze or glaze spraying technology, and the transparency does not reach requirement yet.The preparation that at present imitative stone is thrown brilliant brick mainly is to adopt the secondary burning technology, behind the stamp through the high temperature biscuiting after the base substrate upper berth apply one deck glass ceramics frit dry granular, twice firing at low temperatures.
Along with world population increases and Economic development, the resource consumption and the disposal of pollutants of building and operation thereof economize on resources, protect environment, realize building and natural harmony coexistence, are the common issues that the whole world faces.In the face of earth natural resource constantly utilize and non-renewable objective problem, be a big bottleneck on the ceramic boundary of puzzlement.The traditional ceramics industry is very high to the degree of complying with of the resource and the energy, and ceramic industry will really become energy resource and practice thrift friendly type industry, energy-saving and emission-reduction, and consumption reduction is sharp useless etc., and the aspect also shoulders heavy responsibilities.Secondary is fired and is thrown brilliant brick fully, because base substrate will pass through the high temperature biscuiting earlier, again through the low temperature biscuiting; The process for producing bricks of more once painting enamel metal ware is loaded down with trivial details, and energy consumption is bigger, is standard by the kiln of 280 meters factories; The market coal price calculates with 1100 yuan/ton, and kiln is fired every square metre of product and wanted many 4.5 yuan with coal, by 1,000,000 square metres of calculating of YO; Then will increase by 4,500,000 yuan expense, and twice firing also can increase the cost of manual work, place, breakage etc.
Summary of the invention
The object of the present invention is to provide and a kind ofly once burn to throw brilliant brick with dry granular and use the preparation method of the brilliant brick of throwing of this dry granular.
The technical scheme that the present invention taked is:
The brilliant brick of a kind of throwing is used dry granular, by Al
2O
313～20 parts, SiO
256～63 parts, K
20.5～5 part of O, 8～18 parts of CaO, Na
23～6 parts of O, 0.5～3 part of MgO, 0.5～4 part of ZnO, 0～4 part of BaO, B
2O
30～4, Li
20 ~ 2 part of composition of O.
Preferably, the brilliant brick of said throwing with dry granular by Al
2O
314～17 parts, SiO
256～60 parts, K
21～4 part of O, 10～16 parts of CaO, Na
24～6 parts of O, 1～2 part of MgO, 1～4 part of ZnO, 0～2 part of BaO, B
2O
31～3, Li
20 ~ 2 part of composition of O.
A kind of preparation method who once burn to throw brilliant brick, be included in adobe compression moulding after, execute ground-coat enamel, cover-coat enamel, fancy glaze after, the above-mentioned dry granular of cloth one deck, 1150 ℃～1230 ℃ once-firings.
The time of preferably, firing is 60～120 minutes.
The brilliant brick of the throwing of the application of the invention use dry granular, the throwing crystalline substance brick that makes, and once-firing can save high temperature biscuiting process, greatly reduces energy consumption, has reduced pollution effectively, and it is nearly 15% to reduce production costs, and has improved productivity effect greatly.The brilliant brick of the throwing that production obtains, the glaze transparency is high, and bubble is few.
It is high to prepare the used frit initial melting temperature of this dry granular; High-temperature viscosity is little; Both can guarantee that the base substrate exhaust was good, the eliminating bubble that can at high temperature try one's best again, and the content of change potassium and the sodium use temperature that can regulate frit; Obtain a series of dry granular product, and the compatibility performance between product is good.
The brilliant brick of the throwing of the inventive method preparation, owing to be the high temperature once-firing, the brilliant brick product of the throwing of the equal lower temperature twice firing of wear resistance and resistance to acids and bases has significantly raising, and once-firing, less energy consumption, technology is simple.
Embodiment
Below in conjunction with instance, further specify the present invention.
In following examples, if no special instructions, said umber all refers to mass parts.
The melting method of dry granular is following:
Composition according to dry granular takes by weighing raw material, mixes, and founds in 1500～1580 ℃, is crushed to 20～100 orders afterwards.
Embodiment 1
The brilliant brick of a kind of throwing is used dry granular, by Al
2O
313 parts, SiO
260 parts, K
20.5 part of O, 14 parts of CaO, Na
25 parts of O, 1 part of MgO, 0.5 part of ZnO, 2 parts of BaO, B
2O
31 part, Li
22 parts of compositions of O.
Embodiment 2
The brilliant brick of a kind of throwing is used dry granular, by Al
2O
315 parts, SiO
263 parts, K
25 parts of O, 12 parts of CaO, Na
24 parts of O, 0.5 part of MgO, 2 parts of ZnO, B
2O
34 parts, Li
20.3 part of composition of O.
Embodiment 3
The brilliant brick of a kind of throwing is used dry granular, by Al
2O
320 parts, SiO
258 parts, K
23 parts of O, 8 parts of CaO, Na
25 parts of O, 1.5 parts of MgO, 1 part of ZnO, B
2O
34 parts, Li
21.5 parts of compositions of O.
Embodiment 4
The brilliant brick of a kind of throwing is used dry granular, by Al
2O
318 parts, SiO
256 parts, K
22 parts of O, 16 parts of CaO, Na
24 parts of O, 2 parts of MgO, 4 parts of ZnO, 2.5 parts of BaO, B
2O
32, Li
21 part of composition of O.
Embodiment 5
The brilliant brick of a kind of throwing is used dry granular, by Al
2O
316 parts, SiO
262 parts, K
23 parts of O, 11 parts of CaO, Na
26 parts of O, 3 parts of MgO, ZnO2 part, 0.5 part of BaO, B
2O
33 parts of compositions.
Embodiment 6
The brilliant brick of a kind of throwing is used dry granular, by Al
2O
316 parts, SiO
260 parts, K
21.5 parts of O, 15 parts of CaO, Na
24 parts of O, 2.5 parts of MgO, 3 parts of ZnO, 4 parts of BaO, Li
21.5 parts of compositions of O.
Embodiment 7
The brilliant brick of a kind of throwing is used dry granular, by Al
2O
316 parts, SiO
259 parts, K
23 parts of O, 14 parts of CaO, Na
23 parts of O, 2.0 parts of MgO, 2.5 parts of ZnO, 2 parts of BaO, Li
21 part of composition of O.
Embodiment 8
After the adobe compression moulding, execute ground-coat enamel, cover-coat enamel, fancy glaze after, the dry granular of cloth one deck 1.8mm, dry granular is mixed with the mass ratio of embodiment 4 said dry granulars by 1:2 by embodiment 1,1150 ℃, burns till in 120 minutes.
Embodiment 9
After the adobe compression moulding, execute ground-coat enamel, cover-coat enamel, fancy glaze after, the dry granular of cloth one deck 2.3mm, dry granular is mixed with the mass ratio of embodiment 5 said dry granulars by 2:1 by embodiment 2,1180 ℃, burns till in 90 minutes.
Embodiment 10
After the adobe compression moulding, execute ground-coat enamel, cover-coat enamel, fancy glaze after, the dry granular of cloth one deck 2mm, dry granular is mixed with the mass ratio of embodiment 3 said dry granulars by 1:1 by embodiment 1,1200 ℃, burns till in 90 minutes.
Embodiment 11
After the adobe compression moulding, execute ground-coat enamel, cover-coat enamel, fancy glaze after, the dry granular of cloth one deck 2.5mm, dry granular is mixed with the mass ratio of embodiment 4 said dry granulars by 2:3 by embodiment 2,1230 ℃, burns till in 50 minutes.
Embodiment 8～11 prepares and throws brilliant brick structure densification, transparency is high, bubble is few, greatly reduces production energy consumption, and environmental protection is attractive in appearance.
Embodiment 12
After the adobe compression moulding, execute ground-coat enamel, cover-coat enamel, fancy glaze after, the embodiment 6 described dry granulars of cloth one deck 2mm, burnt till in 50 minutes by 1150 ℃.
The brilliant brick of the throwing of the application of the invention use dry granular, can save the sintering procedure of a kiln of biscuiting, and the throwing crystalline substance brick that makes has the energy consumption of greatly reducing, and has reduced pollution effectively, and it is nearly 15% to reduce production costs, and has improved productivity effect greatly.The brilliant brick of the throwing that production obtains, the glaze transparency is high, and bubble is few.
It is high to prepare the used frit initial melting temperature of this dry granular; High-temperature viscosity is little; Both can guarantee that the base substrate exhaust was good, the eliminating bubble that can at high temperature try one's best again, and the content of change potassium and the sodium use temperature that can regulate frit; Obtain a series of dry granular product, and the compatibility performance between product is good.
Claims (4)
1. an once-firing is thrown brilliant brick and is used dry granular, by Al
2O
313～20 parts, SiO
256～63 parts, K
20.5～5 part of O, 8～18 parts of CaO, Na
23～6 parts of O, 0.5～3 part of MgO, 0.5～4 part of ZnO, 0～4 part of BaO, B
2O
30～4, Li
20～2 part of composition of O.
2. a kind of once-firing according to claim 1 is thrown brilliant brick and is used dry granular, by Al
2O
314～17 parts, SiO
256～60 parts, K
21～4 part of O, 10～16 parts of CaO, Na
24～6 parts of O, 1～2 part of MgO, 1～4 part of ZnO, 0～2 part of BaO, B
2O
31～3, Li
20～2 part of composition of O.
3. preparation method who once burn to throw brilliant brick, be included in adobe compression moulding after, execute ground-coat enamel, cover-coat enamel, fancy glaze after, cloth one deck claim 1 or 2 described dry granulars burn till at 1150 ℃～1230 ℃ next time, obtain throwing brilliant brick product.
4. a kind of preparation method who throws brilliant brick according to claim 3, it is characterized in that: product forms for once firing, and firing time is 60～120 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110228467 CN102390933B (en) | 2011-08-10 | 2011-08-10 | Dry grain for crystal throwing brick and method for preparing crystal throwing brick |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110228467 CN102390933B (en) | 2011-08-10 | 2011-08-10 | Dry grain for crystal throwing brick and method for preparing crystal throwing brick |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102390933A true CN102390933A (en) | 2012-03-28 |
| CN102390933B CN102390933B (en) | 2013-11-06 |
Family
ID=45858342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110228467 Active CN102390933B (en) | 2011-08-10 | 2011-08-10 | Dry grain for crystal throwing brick and method for preparing crystal throwing brick |
Country Status (1)
| Country | Link |
|---|---|
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102746031A (en) * | 2012-06-15 | 2012-10-24 | 广东博德精工建材有限公司 | Preparation method of high-fidelity imitation jade microcrystalline glass ceramic composite board |
| CN103467067A (en) * | 2013-08-15 | 2013-12-25 | 淮北市惠尔普建筑陶瓷有限公司 | Polished crystal tile |
| CN103626523A (en) * | 2013-11-26 | 2014-03-12 | 广东金意陶陶瓷有限公司 | Ceramic tile with dry particle glaze-decorated surface and manufacturing method thereof |
| CN103664236A (en) * | 2013-12-18 | 2014-03-26 | 广东金意陶陶瓷有限公司 | Metal fancy glaze as well as whole cast glaze ceramic tile with metal effect and production technology thereof |
| CN105601109A (en) * | 2015-12-23 | 2016-05-25 | 江西宏瑞新材料有限公司 | Frit with high initial melting point and high expansion coefficient and preparation method of frit |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102746031B (en) * | 2012-06-15 | 2013-09-11 | 广东博德精工建材有限公司 | Preparation method of high-fidelity imitation jade microcrystalline glass ceramic composite board |
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| CN103467067A (en) * | 2013-08-15 | 2013-12-25 | 淮北市惠尔普建筑陶瓷有限公司 | Polished crystal tile |
| CN103626523A (en) * | 2013-11-26 | 2014-03-12 | 广东金意陶陶瓷有限公司 | Ceramic tile with dry particle glaze-decorated surface and manufacturing method thereof |
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