CN102372997A - Paint using poly(fatty acid) vinyl ether as film-forming material - Google Patents
Paint using poly(fatty acid) vinyl ether as film-forming material Download PDFInfo
- Publication number
- CN102372997A CN102372997A CN2011103075985A CN201110307598A CN102372997A CN 102372997 A CN102372997 A CN 102372997A CN 2011103075985 A CN2011103075985 A CN 2011103075985A CN 201110307598 A CN201110307598 A CN 201110307598A CN 102372997 A CN102372997 A CN 102372997A
- Authority
- CN
- China
- Prior art keywords
- fatty acid
- vinyl ether
- paint
- coating
- compsn according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 title claims abstract description 10
- 239000003973 paint Substances 0.000 title abstract description 5
- -1 poly(fatty acid) Polymers 0.000 title abstract description 4
- 239000000463 material Substances 0.000 title description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 8
- 229930195729 fatty acid Natural products 0.000 claims description 8
- 239000000194 fatty acid Substances 0.000 claims description 8
- 150000004665 fatty acids Chemical class 0.000 claims description 8
- 229920000223 polyglycerol Polymers 0.000 claims description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 4
- 230000002785 anti-thrombosis Effects 0.000 claims description 4
- 229960004676 antithrombotic agent Drugs 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 238000012674 dispersion polymerization Methods 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 239000008199 coating composition Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 230000003287 optical effect Effects 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 abstract description 2
- 239000002952 polymeric resin Substances 0.000 abstract 2
- 229920003002 synthetic resin Polymers 0.000 abstract 2
- 239000003146 anticoagulant agent Substances 0.000 abstract 1
- 229940127219 anticoagulant drug Drugs 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 20
- 239000011248 coating agent Substances 0.000 description 19
- 238000000034 method Methods 0.000 description 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000012767 functional filler Substances 0.000 description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a paint composite which comprises the following components by weight percent: 30-40% of water dispersible polymer resin, 20-30% of pigment and filler, 0.04-0.09% of stabilizer, 0.05-0.08% of dispersant, 0.1-2% of anticoagulant, 0.06-0.07% of defoaming agent, 1-15% of pH regulator and the balance of water, wherein the water dispersible polymer resin is C20-25 poly(fatty acid) vinyl ether. The paint is environmentally-friendly and can eliminate environmental pollutions.
Description
Technical field
The present invention relates to a kind of coating, particularly relate to the coating that a kind of film forming matter is the polyglycerol fatty acid Vinyl Ether.
Background technology
Along with national economy and high-tech development, except that universal, urgent to the increasing demand of speciality coating to the requirement of coating.In the protective system, peroxide ethene coating, epoxypaint, oxygen sulfonated polyethylene coating etc. are all held concurrently or are existed, but respectively deficiency are arranged.Peroxide ethene coating came out at the beginning of the seventies, and this coating has certain preservative activity, but because bigger molecular weight, leveling characteristics is undesirable; Solid content is low, generally has only 14～18%, the paint film density difference, and viscosity is also very low; Have only 20～50 seconds, its sticking power is also bad, and paint film is prone to come off.
Along with the raising of global environmental consciousness, people are urgent further to the demand of functional environment-friendly coating.Through adopting the water-based and the powder coating of low volatility, wherein add the nano functional filler of safety non-toxic, be the effective means that reduces source of pollution, coating is extended more forward in the mankind's effect.Coating must be considered its usefulness and toxicity problem with sterilant, and security is an important factor of considering use value.At present; The sterilant that coating adopts mainly contains organic bactericides such as substituted arene class, heterogeneous ring compound, aminated compounds and organometallic compound; The antimicrobial nano filler compare with organic antibacterial agent have high security, slow-releasing is good, preferable weather resistance is arranged, broad spectrum antibacterial is arranged, be difficult for developing immunity to drugs, good heat resistance, easy to process; Most importantly be to use coating that this nano functional filler processes not only can organic foreign odors such as thiomethyl alcohol of generations such as the formaldehyde of generations such as new building materials, caking agent, acetaldehyde that smoking produces, family's dust be decomposed under UV-irradiation to eliminate; And can decompose oil content and organically surface contamination, can effectively improve the quality of human health life.
Summary of the invention
To the deficiency of prior art, one of the object of the invention is to provide a kind of good leveling property, sticking power coating good, environmental protection.
The present invention has synthesized a kind of water dispersion of polyglycerol fatty acid Vinyl Ether particularly according to polymkeric substance and the mutual dispersive principle of water, and its preparation method is the compound method of general this area; So long as it is just passable to prepare this material; Find after deliberation, contain the coating of the water dispersion of polyglycerol fatty acid Vinyl Ether, the water-borne coatings that its leveling characteristics, sticking power etc. are all more general is excellent; Its mechanism possibly be best carbochain; Especially suitable carbonatoms, like 10-40,20-25 carbon atom particularly.
According to aforementioned purpose and other content, concrete coating of the present invention is formed as follows:
1, a kind of coating composition, form by the component of following weight per-cent:
Aqueous dispersion polymerization resin 30-40
Color stuffing 20-30
Stablizer 0.04-0.09
Dispersion agent 0.05-0.08
Antithrombotics 0.1-2
Skimmer 0.06-0.07
PH regulator agent 1-15
Excess water
It is characterized in that: described aqueous dispersion polymerization resin is the polyglycerol fatty acid Vinyl Ether with 20-25 carbon atom.
Described color stuffing is a calcium carbonate superfine powder, the mixture of at least a and titanium dioxide optical catalyst of zinc oxide, and the content of titanium oxide is no less than 38% of color stuffing TV.
Described pH regulator agent is an ammoniacal liquor.
Described skimmer is a POLYPROPYLENE GLYCOL.
Described antithrombotics is a vinyl alcohol.
Embodiment
Embodiment one
Polyglycerol fatty acid Vinyl Ether water dispersion 40
Lime carbonate and photocatalysis titanium dioxide 25
Stablizer 0.09
Dispersion agent 0.05
Vinyl alcohol 2
POLYPROPYLENE GLYCOL 0.07
Ammoniacal liquor 8
Excess water.
Embodiment 2:
Polyglycerol fatty acid Vinyl Ether water dispersion 30
Lime carbonate and photocatalysis titanium dioxide 30
Stablizer 0.09
Dispersion agent 0.05
Vinyl alcohol 2
POLYPROPYLENE GLYCOL 0.07
Ammoniacal liquor 15
Excess water.
Coating of the present invention, it is with low cost, wide adaptability, environment-protecting asepsis, cohesive force is 2 times of like product, good leveling property is suitable for large-scale promotion and uses.
Applicant's statement; The present invention explains detailed process equipment of the present invention and technical process through the foregoing description; But the present invention is not limited to above-mentioned detailed process equipment and technical process, does not mean that promptly the present invention must rely on above-mentioned detailed process equipment and technical process could be implemented.The person of ordinary skill in the field should understand, and to any improvement of the present invention, to the interpolation of the equivalence replacement of each raw material of product of the present invention and ancillary component, the selection of concrete mode etc., all drops within protection scope of the present invention and the open scope.
Claims (5)
1. coating composition, form by the component of following weight per-cent:
Aqueous dispersion polymerization resin 30-40
Color stuffing 20-30
Stablizer 0.04-0.09
Dispersion agent 0.05-0.08
Antithrombotics 0.1-2
Skimmer 0.06-0.07
PH regulator agent 1-15
Excess water
It is characterized in that: described aqueous dispersion polymerization resin is the polyglycerol fatty acid Vinyl Ether with 20-25 carbon atom.
2. compsn according to claim 1, described color stuffing are calcium carbonate superfine powder, the mixture of at least a and titanium dioxide optical catalyst of zinc oxide, and the content of titanium oxide is no less than 38% of color stuffing TV.
3. compsn according to claim 1, described pH regulator agent is an ammoniacal liquor.
4. compsn according to claim 1, described skimmer are POLYPROPYLENE GLYCOL.
5. compsn according to claim 1, described antithrombotics are vinyl alcohol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103075985A CN102372997A (en) | 2011-10-11 | 2011-10-11 | Paint using poly(fatty acid) vinyl ether as film-forming material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103075985A CN102372997A (en) | 2011-10-11 | 2011-10-11 | Paint using poly(fatty acid) vinyl ether as film-forming material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102372997A true CN102372997A (en) | 2012-03-14 |
Family
ID=45792243
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011103075985A Pending CN102372997A (en) | 2011-10-11 | 2011-10-11 | Paint using poly(fatty acid) vinyl ether as film-forming material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102372997A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5981425A (en) * | 1998-04-14 | 1999-11-09 | Agency Of Industrial Science & Tech. | Photocatalyst-containing coating composition |
| CN1454944A (en) * | 2002-04-29 | 2003-11-12 | 北京化大天瑞纳米材料技术有限公司 | Antibacterial water-based coating composition |
| CN1483002A (en) * | 2000-12-28 | 2004-03-17 | �Ѻ͵繤��ʽ���� | highly active photocatalyst |
| CN101784619A (en) * | 2007-08-28 | 2010-07-21 | 巴斯夫欧洲公司 | photoactive tio2 in coating materials |
-
2011
- 2011-10-11 CN CN2011103075985A patent/CN102372997A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5981425A (en) * | 1998-04-14 | 1999-11-09 | Agency Of Industrial Science & Tech. | Photocatalyst-containing coating composition |
| CN1483002A (en) * | 2000-12-28 | 2004-03-17 | �Ѻ͵繤��ʽ���� | highly active photocatalyst |
| CN1454944A (en) * | 2002-04-29 | 2003-11-12 | 北京化大天瑞纳米材料技术有限公司 | Antibacterial water-based coating composition |
| CN101784619A (en) * | 2007-08-28 | 2010-07-21 | 巴斯夫欧洲公司 | photoactive tio2 in coating materials |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103131313B (en) | Compound type photocatalyst air purification aqueous inner wall paint and preparation method thereof | |
| CN102329539A (en) | Interior wall coating and preparation method thereof | |
| CN102702889A (en) | Anti-bacterial water-based paint and preparation method thereof | |
| CN101921521A (en) | Nano-titanium water-based coating having long-acting resistance to formaldehyde | |
| CN103525212A (en) | Internal wall environment-friendly coating capable of releasing negative air ions | |
| CN105315727A (en) | Ecological type multi-functional inorganic dry powder paint capable of releasing negative oxygen ions | |
| CN102675990A (en) | Biodegradable odorless emulsion paint and preparation method thereof | |
| CN102532977A (en) | Composite multifunctional health paint mate and preparation method thereof | |
| CN105017906A (en) | Water-in-water multi-color water paint and preparation method thereof | |
| CN104629566A (en) | Antibacterial anion paint | |
| CN103571289A (en) | Research and development of scrubbing-resistant odor-removal paint for internal walls | |
| CN101974270A (en) | Antibiotic waterproof coating | |
| CN104263155A (en) | Environmental-friendly waterborne coating for building inner wall decoration and preparation process of environmental-friendly waterborne coating | |
| CN107353732A (en) | A kind of nanometer organic water borne coating and preparation method thereof | |
| CN106084918A (en) | A kind of Multifunctional environmental protection paint | |
| CN102372997A (en) | Paint using poly(fatty acid) vinyl ether as film-forming material | |
| CN104789061A (en) | Multifunctional interior wall coating | |
| CN101440239A (en) | Composite nano-paint for inner wall | |
| CN111423783A (en) | Antibacterial odor-removing water-based environment-friendly building coating and preparation method thereof | |
| CN104629511A (en) | Novel nano-antibacterial water-based paint and preparation method thereof | |
| CN102140296A (en) | Abrasion-resistant woodenware coating | |
| CN105754425A (en) | Formaldehyde-adsorbing waterborne environment-friendly coating | |
| CN102140289A (en) | Environmentally friendly woodware paint | |
| CN102382528A (en) | Preparation method of paint with film forming substance of poly aliphatic acid vinyl ether | |
| CN103614021A (en) | Development of high-property inner wall environment-friendly coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120314 |
|
| RJ01 | Rejection of invention patent application after publication |