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CN102338960A - 2D/3D image switching display device - Google Patents

2D/3D image switching display device Download PDF

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Publication number
CN102338960A
CN102338960A CN2010102386554A CN201010238655A CN102338960A CN 102338960 A CN102338960 A CN 102338960A CN 2010102386554 A CN2010102386554 A CN 2010102386554A CN 201010238655 A CN201010238655 A CN 201010238655A CN 102338960 A CN102338960 A CN 102338960A
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image
display device
electrochromic layer
switching display
transparent conductive
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叶裕洲
王昭懿
宋启贤
江敏慧
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J Touch Corp
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J Touch Corp
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Abstract

A2D/3D image switches over the display device, including the image display element and combines the image switching over the unit on its surface, the image switching over the unit includes the first transparent base plate and second transparent base plate, and its surface has corresponding first transparent conductive component and second transparent conductive component separately, and there are electrochromic layers and electrolyte layers in the first transparent base plate and second transparent base plate, therefore, when the image display element changes from the display of the planar image to the display of the stereoscopic image, turn on electrically by the first, second transparent conductive component, make the electrochromic layer change from transparent to dark shade area, make the stereoscopic image divided into left eye image and right eye image, when the naked eye receives, will not produce the line of overlapping; when the structure is used for displaying the three-dimensional image, the three-dimensional image can be directly displayed without additionally using a parallax barrier shielding device, the image switching unit can carry out different shielding angle switching according to the image direction of the image display unit, and the three-dimensional image can be observed in all directions of the device.

Description

2D/3D影像切换显示装置2D/3D image switching display device

技术领域 technical field

一种“影像切换显示装置”,特别是指一种具有切换2D影像或3D影像显示状态的2D/3D影像切换显示装置。An "image switching display device" particularly refers to a 2D/3D image switching display device capable of switching between 2D image and 3D image display states.

背景技术 Background technique

目前所熟知的立体影像显示技术,其原理是利用双眼视差(Binoculardisparity),经左右眼分别接收不同影像,最后在大脑融合成一立体影像。在裸眼立体显示技术中,依其结构大致可分为柱状透镜(Lenticular)及光屏障式(Barrier)两种,上述两种结构各有其优缺点,其中柱状透镜是由许多细长直条的凸透镜沿一轴方向连续排列,利用光学折射的原理来产生左右眼的不同视图,相较于光屏障式,因其是利用光的折射来达到分光的目的,所以光较无损失、亮度佳,但在透镜结构的边缘处有其折射限制而使折射效果不佳,或是由于制作柱状透镜时的误差,透镜表面不易平整等因素,会有杂散光的产生,造成部分模糊的立体影像,而影响整体3D影像的显示效果;另外,光屏障式是利用整列的屏障物来限制某些角度的光射出,只让某些角度的视图影像分别传送至左右眼以产生立体影像,相较于柱状透镜,其单眼影像较为清晰,但其先天结构特征,则会导致整体影像的亮度降低、影像解析度下降等缺陷。The current well-known stereoscopic image display technology is based on the principle of using binocular disparity to receive different images through the left and right eyes, and finally fuse them into a stereoscopic image in the brain. In naked-eye stereoscopic display technology, according to its structure, it can be roughly divided into two types: lenticular lens and barrier type. The above two structures have their own advantages and disadvantages. Convex lenses are arranged continuously along one axis, and use the principle of optical refraction to produce different views of the left and right eyes. Compared with the light barrier type, because it uses the refraction of light to achieve the purpose of splitting light, there is no loss of light and good brightness. However, there are refraction restrictions at the edge of the lens structure, so that the refraction effect is not good, or due to factors such as errors in the production of lenticular lenses, and the lens surface is not easy to be flat, there will be stray light, resulting in partially blurred three-dimensional images, and It affects the display effect of the overall 3D image; in addition, the light barrier type uses a whole row of barriers to limit the light emission at certain angles, and only allows the view images at certain angles to be transmitted to the left and right eyes respectively to generate a stereoscopic image. The monocular image of the lens is relatively clear, but its inherent structural characteristics will lead to defects such as reduced brightness of the overall image and reduced image resolution.

另外,一般的立体显示装置,仅能显示立体影像而已,无法针对平面影像与立体影像进行切换,主要原因在于柱状透镜(Lenticular)或光屏障(Barrier)结合在一般的显示器之后,所有的平面影像经过柱状透镜(Lenticular)或光屏障(Barrier)之后,便会被区分为左眼影像与右眼影像,除非是外挂式的立体影像显示模组,在不需要显示立体影像时,将外挂式的立体影像显示模组由显示器上拆卸下来,但此种方式在实际使用时,必须精确的对准位置,才不会产生影像解析度下降或偏斜等问题,因此,便有业者开发出可切换显示立体影像或平面影像的立体影像显示装置。In addition, general stereoscopic display devices can only display stereoscopic images, and cannot switch between planar and stereoscopic images. After passing through a lenticular lens (Lenticular) or a light barrier (Barrier), it will be divided into a left-eye image and a right-eye image, unless it is a plug-in stereoscopic image display module, when it is not necessary to display a stereoscopic image, the plug-in The stereoscopic image display module is disassembled from the display, but when this method is used in practice, it must be precisely aligned to avoid problems such as image resolution degradation or skew. Therefore, some operators have developed a switchable A stereoscopic image display device for displaying stereoscopic images or planar images.

如中国台湾专利公报,公告号第M371902号的“切换2D平面影像/3D立体影像显示画面的显示装置”,其包含一平面显示器以及一视差屏障面板设于该平面显示器的一显示面,其中该视差屏障面板包含一栅栏图案,其包含一第一电变色材料层以及一第二电变色材料层,且于一2D平面影像显示状态时,该栅栏图案、该第一电变色材料层与该第二电变色材料层均为透明,而于一3D立体影像显示状态时,该栅栏图案是为一不透光图案,且该第一电变色材料层是具有一第一颜色,该第二电变色材料层是具有一第二颜色。For example, China Taiwan Patent Gazette, No. M371902 "display device for switching 2D plane image/3D stereoscopic image display screen", which includes a flat display and a parallax barrier panel arranged on a display surface of the flat display, wherein the The parallax barrier panel includes a barrier pattern, which includes a first electrochromic material layer and a second electrochromic material layer, and in a 2D plane image display state, the barrier pattern, the first electrochromic material layer and the second electrochromic material layer The two electrochromic material layers are both transparent, and in a 3D three-dimensional image display state, the fence pattern is an opaque pattern, and the first electrochromic material layer has a first color, and the second electrochromic material layer has a first color. The material layer has a second color.

如中国台湾专利公报,公告号第M368088号的“切换2D平面影像/3D立体影像显示画面的显示装置”,其包含:一第一基板;一视差屏障单元设于第一基板之下方;一彩色滤光单元设于视差屏障单元之下方;一共通电极设于彩色滤光单元之下方;一液晶单元设于共通电极之下方;复数个薄膜晶体管设于液晶单元之下方;一第二基板设于复数个薄膜晶体管之下方;及一光源设于第二基板之下方;通过视差屏障单元进行平面影像与立体影像的调变并减少习知显示装置的厚度及组装成本。For example, China Taiwan Patent Gazette, No. M368088 "display device for switching 2D plane image/3D stereoscopic image display screen", which includes: a first substrate; a parallax barrier unit arranged below the first substrate; a color The filter unit is arranged under the parallax barrier unit; a common electrode is arranged under the color filter unit; a liquid crystal unit is arranged under the common electrode; a plurality of thin film transistors are arranged under the liquid crystal unit; a second substrate is arranged under the liquid crystal unit A plurality of thin film transistors are under the bottom; and a light source is arranged under the second substrate; through the parallax barrier unit, the plane image and the three-dimensional image are modulated and the thickness and assembly cost of the conventional display device are reduced.

上述两篇专利皆是利用电致变色材料来作为显示立体影像的视差屏障装置,但其结构中的共同缺陷,皆缺乏电致变色装置的必要电解质层,因缺乏能提供离子给电致变色层的电解质层,电致变色装置将无法产生氧化或还原的可逆反应而完成着色或去色变化,因此该两篇专利实际上应不可实施;另外,该视差屏障装置的透明电极层与电变色材料层,皆设置为栅栏图案,其制造过程中的分层涂布、溅镀或蚀刻,乃至于各迭层必须准确对位,制程相当的复杂,且全部迭层皆设置为栅栏图案,导致每一栅栏与栅栏中间形成中空区域,将影响整体光线穿透、折射或反射,既使是一般2D显示,也可能影响显示器的影像品质,造成色差或亮度不均等问题,且栅栏间中空区域亦会降低栅栏强度与使用寿命;而M368088专利中另一嵌入液晶显示器基材的结构,是以栅栏图案式的嵌入一绝缘性透明材料中,虽然可缩减立体影像的液晶显示器的厚度,实际上制程亦是相当复杂。Both of the above two patents use electrochromic materials as parallax barrier devices for displaying stereoscopic images, but the common defect in their structures is that they lack the necessary electrolyte layer for electrochromic devices, because they lack the ability to provide ions to the electrochromic layer. electrolyte layer, the electrochromic device will not be able to produce a reversible reaction of oxidation or reduction to complete the coloring or decolorization change, so the two patents should not be implemented in practice; in addition, the transparent electrode layer of the parallax barrier device and the electrochromic material Layers are all set as a fence pattern, layered coating, sputtering or etching in the manufacturing process, so that each stack must be accurately aligned, the manufacturing process is quite complicated, and all stacks are set as a fence pattern, resulting in each A hollow area formed between a fence and the fence will affect the overall light penetration, refraction or reflection. Even for general 2D display, it may affect the image quality of the display, causing problems such as color difference or uneven brightness, and the hollow area between the fences will also be affected. Reduce the strength and service life of the fence; and another structure embedded in the liquid crystal display substrate in the M368088 patent is to embed a fence pattern into an insulating transparent material. Although the thickness of the liquid crystal display with three-dimensional images can be reduced, the actual manufacturing process is also is quite complex.

另外,上述习知技术虽可作平面及立体显示的切换,但对于可任意变换观看视角的手持式装置而言,却无法相应地变换立体显示的角度,而须于固定方向才能观看3D影像。In addition, although the above-mentioned conventional technology can switch between two-dimensional and three-dimensional display, for handheld devices that can freely change viewing angles, the angle of three-dimensional display cannot be changed accordingly, and 3D images must be viewed in a fixed direction.

发明内容 Contents of the invention

有鉴于上述的需求,本发明人精心研究,并积个人从事该项事业的多年经验,终设计出一种崭新的2D/3D影像切换显示装置。In view of the above-mentioned requirements, the inventor of the present invention has studied intensively and accumulated many years of personal experience in this field, and finally designed a brand-new 2D/3D image switching display device.

本发明的一目的,旨在提供一种具有切换2D影像或3D影像显示状态的2D/3D影像切换显示装置。An object of the present invention is to provide a 2D/3D image switching display device capable of switching between 2D image and 3D image display state.

本发明的一目的,旨在提供一种不需额外装设视差屏障遮蔽装置,便可进行2D/3D影像显示的2D/3D影像切换显示装置。An object of the present invention is to provide a 2D/3D image switching display device capable of displaying 2D/3D images without installing an additional parallax barrier shielding device.

本发明的一目的,旨在提供一种显示平面影像时,不会影响到影像解析度的2D/3D影像切换显示装置。An object of the present invention is to provide a 2D/3D image switching display device that does not affect the image resolution when displaying a planar image.

本发明的一目的,旨在提供一种可简化制程的2D/3D影像切换显示装置。An object of the present invention is to provide a 2D/3D image switching display device which can simplify the manufacturing process.

本发明的一目的,旨在提供一种可依照观看角度来调整立体影像显示时所使用的遮光角度的2D/3D影像切换显示装置。An object of the present invention is to provide a 2D/3D image switching display device that can adjust the shading angle used when displaying a stereoscopic image according to the viewing angle.

为达上述目的,本发明2D/3D影像切换显示装置,其是包含一影像显示单元,其用以显示一平面影像与一立体影像,以及一设于该影像显示单元表面的一影像切换单元,该影像切换单元具有两相对应设置的一第一透明基板与一第二透明基板,于该等透明基板相对应的表面分别设置有第一透明导电元件与一第二透明导电元件,且该第二透明基板另一表面用以结合于该影像显示单元表面,再者,于该第一透明基板下方依序设有复数间隔排列的电致变色层与一电解质层,该等电致变色层依据该等第一、第二透明导电元件的电性导通而产生颜色变化。To achieve the above object, the 2D/3D image switching display device of the present invention comprises an image display unit for displaying a plane image and a stereoscopic image, and an image switching unit arranged on the surface of the image display unit, The image switching unit has two correspondingly arranged first transparent substrates and second transparent substrates, first transparent conductive elements and second transparent conductive elements are respectively arranged on the surfaces corresponding to the transparent substrates, and the first transparent conductive elements are arranged respectively. The other surface of the two transparent substrates is used to combine with the surface of the image display unit. Furthermore, a plurality of electrochromic layers arranged at intervals and an electrolyte layer are sequentially arranged under the first transparent substrate. The electrochromic layers are based on The electrical conduction of the first and second transparent conductive elements produces a color change.

另外,为使电致变色层变色时的遮罩效果良好,可于电解质层的两侧设有复数间隔排列的第一电致变色层与第二电致变色层,而该等第一、第二电致变色层的排列方向相同,或为简化整体迭构,该电解质层可完全由第二电致变色层所取代,使该等第二电致变色层兼具补色及提供离子的功能。In addition, in order to make the masking effect of the electrochromic layer good when it changes color, a plurality of first electrochromic layers and second electrochromic layers arranged at intervals can be arranged on both sides of the electrolyte layer, and the first and second electrochromic layers The arrangement directions of the two electrochromic layers are the same, or to simplify the overall stacking, the electrolyte layer can be completely replaced by the second electrochromic layer, so that the second electrochromic layers have both the functions of color supplementation and ion supply.

藉此,该影像显示单元由显示平面影像的状态,转为显示立体影像时,其显示的影像将被区分为左眼影像与右眼影像,此时,该等透明导电元件电性导通,使该电致变色层的颜色,由透明转为不透光的深色遮光区域,且依照该等电致变色层之间格排列状态,于该电致变色层产生间格排列的复数遮光区域,则区分为左眼影像与右眼影像的立体影像,透过遮光区域剔除部份重迭影像区域,于肉眼接收后将不会产生迭纹;再者,一般立体影像显示时,都是于该显示单元上额外增加柱状透镜(Lenticular)或光屏障(Barrier)两种装置,但通过本发明2D/3D影像切换显示装置,于显示立体影像时,便可直接由该显示单元显示已区分为左眼影像与右眼影像的立体影像。Thereby, when the image display unit changes from the state of displaying plane images to displaying stereoscopic images, the displayed images will be divided into left-eye images and right-eye images. At this time, the transparent conductive elements are electrically connected. Make the color of the electrochromic layer change from transparent to opaque dark shading areas, and generate a plurality of shading areas arranged in grids in the electrochromic layer according to the grid arrangement state between the electrochromic layers , the 3D image is divided into the left-eye image and the right-eye image, and part of the overlapping image area is eliminated through the shading area, and no moire will be generated after the naked eye receives it; moreover, when the general 3D image is displayed, it is in Two additional devices, lenticular or barrier, are added to the display unit, but through the 2D/3D image switching display device of the present invention, when displaying a stereoscopic image, it can be directly displayed by the display unit. Stereoscopic image of left-eye image and right-eye image.

应注意的是,于电致变色结构中,电致变色层与电解质层的迭合顺序可互相调换,并不影响电致变色层的变色机制,主要为控制所施加的电压来主导电致变色层的氧化、还原、结构方向改变或相变化反应。并且仅选择本发明2D/3D影像切换显示装置的该等电致变色层作复数间隔排列,而该透明导电元件则不作复数间隔排列设置,或者于同一基材上的制程仅有其中一迭层作复数间隔排列,如此便解决了各迭层的对位问题,因而简化了制程。It should be noted that in the electrochromic structure, the stacking order of the electrochromic layer and the electrolyte layer can be interchanged without affecting the color change mechanism of the electrochromic layer. The main purpose is to control the applied voltage to dominate the electrochromic layer. Oxidation, reduction, structural orientation change or phase change reactions of layers. And only select the electrochromic layers of the 2D/3D image switching display device of the present invention to be arranged in multiple intervals, while the transparent conductive element is not arranged in multiple intervals, or only one of the layers is stacked on the same substrate. Arranging multiple layers at intervals solves the alignment problem of each stacked layer, thus simplifying the manufacturing process.

另外,透过结合两组电致变色装置,再透过感测元件的动作感测,以及控制元件的电路切换,便可在显示立体影像时,当观赏者旋转装置后,会相应的切换视差屏障装置的遮罩角度,因此便能于装置的各方向上观看到立体影像。In addition, by combining two sets of electrochromic devices, through the motion sensing of the sensing element, and the circuit switching of the control element, when displaying a stereoscopic image, when the viewer rotates the device, the parallax will be switched accordingly The shielding angle of the barrier device makes it possible to view stereoscopic images from all directions of the device.

附图说明 Description of drawings

图1为本发明第一较佳实施例的立体分解示意图;Fig. 1 is the three-dimensional exploded schematic view of the first preferred embodiment of the present invention;

图2为本发明第一较佳实施例的动作示意图1;Fig. 2 is a schematic view 1 of the action of the first preferred embodiment of the present invention;

图3为本发明第一较佳实施例的动作示意图2;Fig. 3 is a schematic diagram 2 of the action of the first preferred embodiment of the present invention;

图4为本发明第一较佳实施例的动作示意图3;Fig. 4 is a schematic diagram 3 of the action of the first preferred embodiment of the present invention;

图5为本发明第一较佳实施例的不同层迭组合图1;Fig. 5 is different lamination combination Fig. 1 of the first preferred embodiment of the present invention;

图6为本发明第一较佳实施例的不同层迭组合图2;Fig. 6 is different lamination combination Fig. 2 of the first preferred embodiment of the present invention;

图7为本发明第一较佳实施例的不同层迭组合图3;Fig. 7 is different layered combination Fig. 3 of the first preferred embodiment of the present invention;

图8为本发明第二较佳实施例的立体分解示意图;Fig. 8 is a three-dimensional exploded schematic diagram of a second preferred embodiment of the present invention;

图9为本发明第三较佳实施例的立体分解示意图;Fig. 9 is a three-dimensional exploded schematic diagram of a third preferred embodiment of the present invention;

图10为本发明第三较佳实施例的不同层迭组合图1;Fig. 10 is a different layered combination Fig. 1 of the third preferred embodiment of the present invention;

图11为本发明第三较佳实施例的不同层迭组合图2;Fig. 11 is different layered combination Fig. 2 of the third preferred embodiment of the present invention;

图12为本发明第三较佳实施例的不同层迭组合图3;Fig. 12 is different stacking combination Fig. 3 of the third preferred embodiment of the present invention;

图13为本发明第四较佳实施例的立体分解示意图;Fig. 13 is a three-dimensional exploded schematic diagram of a fourth preferred embodiment of the present invention;

图14为本发明第五较佳实施例的立体分解示意图;Fig. 14 is a perspective exploded schematic diagram of a fifth preferred embodiment of the present invention;

图15为本发明第六较佳实施例的立体分解示意图;Fig. 15 is a perspective exploded schematic diagram of a sixth preferred embodiment of the present invention;

图16为本发明第七较佳实施例的立体分解示意图。Fig. 16 is an exploded perspective view of a seventh preferred embodiment of the present invention.

附图标记说明:Explanation of reference signs:

1-影像显示单元;2-影像切换单元;21-第一透明基板;211-第一透明导电元件;22-第二透明基板;221-第二透明导电元件;23-电致变色层;231-遮光区域;232-第一电致变色层;233-第二电致变色层;24-电解质层;241-第一电解质层;242-第二电解质层;25-第三透明导电层;E-观赏者;L-左眼影像;R-右眼影像。1-image display unit; 2-image switching unit; 21-first transparent substrate; 211-first transparent conductive element; 22-second transparent substrate; 221-second transparent conductive element; 23-electrochromic layer; 231 -shading area; 232-first electrochromic layer; 233-second electrochromic layer; 24-electrolyte layer; 241-first electrolyte layer; 242-second electrolyte layer; 25-third transparent conductive layer; E - viewer; L - image for left eye; R - image for right eye.

具体实施方式 Detailed ways

为使能清楚了解本发明的内容,仅以下列说明搭配图式,敬请参阅。In order to enable a clear understanding of the content of the present invention, only the following descriptions are used together with the drawings, please refer to them.

请参阅图1、2、3、4所示,分别为本发明第一较佳实施例的立体分解示意图与动作示意图1~3,如图所示,本发明2D/3D影像切换显示装置其包括有一影像显示单元1与一影像切换单元2,其中:Please refer to Figures 1, 2, 3, and 4, which are three-dimensional exploded schematic diagrams and action schematic diagrams 1-3 of the first preferred embodiment of the present invention, respectively. As shown in the figure, the 2D/3D image switching display device of the present invention includes There is an image display unit 1 and an image switching unit 2, wherein:

该影像显示单元1是用以显示一平面影像与一立体影像,其显示的立体影像可透过软件、固件或硬件技术产生,例如以软件或固件将平面影像转为包含左眼影像与右眼影像的迭影影像、或者以柱状透镜(Lenticular)或光屏障(Barrier)两种硬件装置将影像区分为左眼影像与右眼影像,但此类立体影像显示技术并非本案技术特征,且早为公开的技术,故在此不再加以叙述;再者,该显示单元1可为液晶显示器(Liquid Crystal Display,LCD)、等离子显示器(Plasma Display Panel,PDP)、表面传导电子发射显示器(Surface conductionElectron-emitter Display,SED)、场发射显示器(Field Emission Display,FED)、真空荧光显示器(Vacuum Fluorescent Display,VFD)、有机发光二极管显示器(Organic Light-Emitting Diode,OLED)或电子纸(E-Paper)其中之一。The image display unit 1 is used to display a planar image and a stereoscopic image. The displayed stereoscopic image can be generated by software, firmware or hardware technology, for example, the planar image is converted into a left-eye image and a right-eye image by software or firmware. The double image of the image, or the two hardware devices of the lenticular lens (Lenticular) or the light barrier (Barrier) to distinguish the image into the left eye image and the right eye image, but this kind of stereoscopic image display technology is not the technical feature of this case, and has long been Disclosed technology, so no longer describe it here; Moreover, the display unit 1 can be a liquid crystal display (Liquid Crystal Display, LCD), a plasma display (Plasma Display Panel, PDP), a surface conduction electron emission display (Surface conductionElectron- emitter Display, SED), field emission display (Field Emission Display, FED), vacuum fluorescent display (Vacuum Fluorescent Display, VFD), organic light-emitting diode display (Organic Light-Emitting Diode, OLED) or electronic paper (E-Paper) among them one.

该影像切换单元2是结合于该影像显示单元1表面,其包括有一第一透明基板21、一第二透明基板22、一电致变色层23与一电解质层24,其中:The image switching unit 2 is combined on the surface of the image display unit 1, and includes a first transparent substrate 21, a second transparent substrate 22, an electrochromic layer 23 and an electrolyte layer 24, wherein:

该第一透明基板21下表面设有一第一透明导电元件211,其可为平板状、薄片状或薄膜状,而该第一透明基板21与该第二透明基板22的材质为塑胶、高分子塑胶、玻璃或为选自树脂、聚乙烯对苯二甲酸酯(PolyethyleneTerephthalate,PET)、聚碳酸酯(Poly Carbonate,PC)、聚乙烯(polyethylene,PE)、聚氯乙烯(Poly Vinyl Chloride,PVC)、聚丙烯(Poly Propylene,PP)、聚苯乙烯(Poly Styrene,PS)、聚甲基丙烯酸甲酯(Polymethylmethacrylate,PMMA)或与其混合物的塑胶聚合物其中之一;以及该第一透明导电元件211与该等第二透明导电元件221的材质为选自氧化铟锡(Indium Tin Oxide,ITO)、氧化铟锌(Indium Zinc Oxide,IZO)、氧化锌铝(Al-doped ZnO,AZO)或氧化锡锑(Antimony Tin Oxide,ATO)所组成的掺杂氧化物(Impurity-DopedOxides)群组其中之一。The lower surface of the first transparent substrate 21 is provided with a first transparent conductive element 211, which can be in the shape of a plate, sheet or film, and the materials of the first transparent substrate 21 and the second transparent substrate 22 are plastic, polymer Plastic, glass or selected from resin, polyethylene terephthalate (PolyethyleneTerephthalate, PET), polycarbonate (Poly Carbonate, PC), polyethylene (polyethylene, PE), polyvinyl chloride (Polyvinyl Chloride, PVC ), polypropylene (Poly Propylene, PP), polystyrene (Poly Styrene, PS), polymethylmethacrylate (Polymethylmethacrylate, PMMA) or one of the plastic polymers blended therewith; and the first transparent conductive element 211 and the second transparent conductive elements 221 are made of indium tin oxide (Indium Tin Oxide, ITO), indium zinc oxide (Indium Zinc Oxide, IZO), zinc aluminum oxide (Al-doped ZnO, AZO) or oxide One of the group of Impurity-DopedOxides composed of Antimony Tin Oxide (ATO).

该电致变色层23是复数间隔排列设于该第二透明基板22上方,而覆盖于该等第二透明导电元件221表面,其设置方法可依下列方式制备:如溶胶凝胶法(sol-gel)、真空溅镀(sputtering)法、电镀(plating)法、网印、喷涂、阳极氧化法(Anodizing)、光聚合法(photopolymerization)、激光蚀刻法等;而该电致变色层23的材质主要为选自阳极变色(anodic coloration)、阴极变色(cathodiccoloration)或阴/阳极变色(cathodic/anodic coloration)所组成的过渡金属元素氧化物或其它有机化合物群组其中之一,一般而言,阳极变色(anodic coloration)材料主要为选自氧化铬(Cr2O3)、氧化镍(NiOx)、氧化铱(IrO2)、氧化锰(MnO2)、亚铁氰化铁Fe4[Fe(CN)6]3或氢氧化镍Ni(OH)2所组成的阳极变色(anodic coloration)过渡金属元素氧化物或其它有机化合物;阴极变色(cathodic coloration)材料主要为选自氧化钨(WO3)、氧化钼(MoO3)、氧化铌(Nb2O3)、氧化钛(TiO2)、钛酸锶(SrTiO3)、所组成的阴极变色(cathodiccoloration)过渡金属元素氧化物或其它有机化合物;而阴/阳极变色(cathodic/anodic coloration)材料主要为选自五氧化二钒(V2O5)、氧化铑(Rh2O3)或氧化钴(CoOx)所组成的阴/阳极变色(cathodic/anodic coloration)过渡金属元素氧化物或其它有机化合物,另外还有亦可作为固态电解质、离子传导层的五氧化二钽(Ta2O5)等过渡金属元素氧化物。The electrochromic layer 23 is arranged at intervals above the second transparent substrate 22, and covers the surface of the second transparent conductive elements 221, and its setting method can be prepared in the following manner: such as sol-gel method (sol-gel method). gel), vacuum sputtering (sputtering) method, electroplating (plating) method, screen printing, spray coating, anodizing method (Anodizing), photopolymerization method (photopolymerization), laser etching method, etc.; and the material of the electrochromic layer 23 It is mainly one of the transition metal element oxides or other organic compounds selected from the group consisting of anodic coloration, cathodic coloration or cathodic/anodic coloration. Generally speaking, the anode The anodic coloration material is mainly selected from chromium oxide (Cr 2 O 3 ), nickel oxide (NiO x ), iridium oxide (IrO 2 ), manganese oxide (MnO 2 ), ferrocyanide Fe 4 [Fe( CN) 6 ] 3 or nickel hydroxide Ni(OH) 2 composed of anodic coloration (anodic coloration) transition metal element oxides or other organic compounds; cathodic coloration (cathodic coloration) materials are mainly selected from tungsten oxide (WO 3 ) , molybdenum oxide (MoO 3 ), niobium oxide (Nb 2 O 3 ), titanium oxide (TiO 2 ), strontium titanate (SrTiO 3 ), cathodiccoloration transition metal element oxides or other organic compounds; The cathodic/anodic coloration material is mainly composed of vanadium pentoxide (V 2 O 5 ), rhodium oxide (Rh 2 O 3 ) or cobalt oxide (CoO x ) cathodic/anodic coloration) oxides of transition metal elements or other organic compounds, and oxides of transition metal elements such as tantalum pentoxide (Ta 2 O 5 ) that can also be used as solid electrolytes and ion-conducting layers.

而不同过渡金属氧化物为电致变色材料的分类,列举部份常见的如下表所示:As for the classification of different transition metal oxides as electrochromic materials, some common ones are listed in the following table:

Figure BSA00000208168600061
Figure BSA00000208168600061

该电解质层24为设于该电致变色层23与该第一透明基板21之间,其主要目的在提供及传导离子给该电致变色层23,可为液态或固态的电解质,但是液态电解质在元件封装上有溢漏的问题,故一般均使用固态电解质,本发明的电解质层24的其中一实施例为固态电解质,较佳地是为一质子交换膜(ProtonExchange Membrane),而可为离子聚合物薄膜(Ionomer membrane)、有机/无机混成薄膜(Organic-Inorganic hybrid membrane)或酸/碱高分子薄膜(Membrane based on polymer and oxo-acids)其中之一,其中该离子聚合物薄膜可为一聚全氟磺酸(polymerized perfluorosulfonic acid,PFSA)膜;若为液态电解质,则可选用高氯酸锂(LiClO4)、氢氧化钾(KOH)、氢氧化钠(NaOH)或硅酸钠等。The electrolyte layer 24 is located between the electrochromic layer 23 and the first transparent substrate 21, and its main purpose is to provide and conduct ions to the electrochromic layer 23. It can be a liquid or solid electrolyte, but the liquid electrolyte There is a problem of leakage in the component package, so generally solid electrolytes are used. One embodiment of the electrolyte layer 24 of the present invention is a solid electrolyte, preferably a proton exchange membrane (ProtonExchange Membrane), which can be ionic One of polymer membrane (Ionomer membrane), organic/inorganic hybrid membrane (Organic-Inorganic hybrid membrane) or acid/alkali polymer membrane (Membrane based on polymer and oxo-acids), wherein the ionic polymer membrane can be a Polymerized perfluorosulfonic acid (PFSA) membrane; if it is a liquid electrolyte, lithium perchlorate (LiClO 4 ), potassium hydroxide (KOH), sodium hydroxide (NaOH) or sodium silicate can be used.

此类的电致变色材料,是指材料经由施加一电位后产生氧化或还原的可逆反应而导致颜色的变化。该电致变色层23的工作原理起因于电致变色材料内过渡金属元素离子价态发生变化,造成染色和褪色反应。当施加一偏压于该电致变色层23,原先储存在该电解质层24内的离子会扩散移动至该电致变色层23,同时电子也将经由该第一透明导电元件221注入该电致变色层23以保持变色层的电中性,电子与离子同时注入该电致变色层23后,逐渐改变该电致变色层23材料的氧化还原状态,进而使该电致变色层23的折射率及穿透率随之改变,此为染色过程,此过程可在数秒至一分钟内完成,因此,在“图3”中可清楚看出,该电致变色层23由透明转为染色状态,形成不透光的遮光区域231,又当施加于该电致变色层23的偏压消失后,该电致变色层23由染色状态转为透明状态,此为阳极变色的方式。This type of electrochromic material refers to a material that undergoes a reversible reaction of oxidation or reduction after an electric potential is applied, resulting in a color change. The working principle of the electrochromic layer 23 is that the valence state of transition metal element ions in the electrochromic material changes, resulting in dyeing and fading reactions. When a bias voltage is applied to the electrochromic layer 23, the ions originally stored in the electrolyte layer 24 will diffuse and move to the electrochromic layer 23, and electrons will also be injected into the electrochromic layer 23 through the first transparent conductive element 221. The color-changing layer 23 is to maintain the electrical neutrality of the color-changing layer. After electrons and ions are injected into the electrochromic layer 23 at the same time, the redox state of the material of the electrochromic layer 23 is gradually changed, and then the refractive index of the electrochromic layer 23 is increased. And the transmittance changes thereupon, this is a dyeing process, and this process can be completed within a few seconds to one minute, therefore, in " Fig. 3 ", it can be clearly seen that the electrochromic layer 23 changes from transparent to a dyed state, An opaque light-shielding region 231 is formed, and when the bias voltage applied to the electrochromic layer 23 disappears, the electrochromic layer 23 changes from a dyed state to a transparent state, which is an anodic color change method.

相反地,当一反向电压或零偏压施加于该电致变色层23时,离子将沿相反路径由该电致变色层23返回该电解质层24,则该电致变色层23还原为原来的无色状态,此为褪色过程;因此,在“图4”中可清楚看出,该电致变色层23由染色状态的不透光的遮光区域231转为透明状态,又当施加于该电致变色层23的偏压消失后,该电致变色层23由透明状态转为染色状态,还原不透光的遮光区域231,此为阴极变色的方式。Conversely, when a reverse voltage or zero bias is applied to the electrochromic layer 23, ions will return to the electrolyte layer 24 from the electrochromic layer 23 along the opposite path, and the electrochromic layer 23 returns to its original state. Therefore, it can be clearly seen in "Fig. 4" that the electrochromic layer 23 turns from the opaque light-shielding region 231 in the dyed state to a transparent state, and when applied to the electrochromic layer 23 After the bias voltage of the electrochromic layer 23 disappears, the electrochromic layer 23 changes from a transparent state to a dyed state, and restores the opaque light-shielding region 231 , which is a way of cathodic discoloration.

由于该等电致变色层23为复数间隔排列的方式设置于该第二透明基板22上表面,且该电致变色层23为设于该等第二透明导电元件221上,因此,该第一透明导电元件211与该等第二透明导电元件221电性导通后,该等电致变色层23产生颜色变换,因此产生复数间隔排列的不透光的遮光区域231,则该影像显示单元1于显示处理过后的多重影像(区分为左眼影像L与右眼影像R)时,透过该等遮光区域231剔除部份重迭影像区域,于肉眼接收后将不会产生迭纹;再者,一般立体影像显示时,都是于该显示单元上额外增加柱状透镜(Lenticular)或光屏障(Barrier)两种装置,但通过本发明2D/3D影像切换显示装置,于显示立体影像时,便可直接由该显示单元显示已区分为左眼影像与右眼影像的立体影像。Since the electrochromic layers 23 are arranged on the upper surface of the second transparent substrate 22 in a plurality of intervals, and the electrochromic layers 23 are arranged on the second transparent conductive elements 221, therefore, the first After the transparent conductive element 211 is electrically connected to the second transparent conductive elements 221, the electrochromic layers 23 produce color changes, thus producing a plurality of opaque light-shielding regions 231 arranged at intervals, and the image display unit 1 When displaying the processed multiple images (divided into left-eye image L and right-eye image R), through the shading areas 231 to remove some overlapping image areas, no moire will be generated after being received by the naked eye; moreover Generally, when displaying a stereoscopic image, two additional devices, a lenticular lens (Lenticular) or a light barrier (Barrier), are added to the display unit, but through the 2D/3D image switching display device of the present invention, when displaying a stereoscopic image, it is convenient The stereoscopic image which has been divided into left-eye image and right-eye image can be directly displayed by the display unit.

请参阅“图5、6、7”所示,为本发明第一较佳实施例的不同层迭组合图,如图所示,该第一透明导电元件211可为复数间隔排列设于第一透明基板21之下表面,或该第二透明导电元件221复数间隔排列设于第二透明基板22之上表面,亦或是该第一、第二透明导电元件211、221皆复数间隔排列地设于第一、第二透明基板21、22的表面,而其排列方向是相同于电致变色层23的排列方向,该等结构仅为第一实施例的其他变化组合,但为简化制程,最佳做法只需电致变色层23作复数间隔排列的设于层状结构中,已可达到良好的变色机制及遮罩效果。Please refer to "Figures 5, 6, 7", which are diagrams of different stacked combinations of the first preferred embodiment of the present invention. The lower surface of the transparent substrate 21, or the second transparent conductive elements 221 are arranged at multiple intervals on the upper surface of the second transparent substrate 22, or the first and second transparent conductive elements 211, 221 are arranged at plural intervals. On the surfaces of the first and second transparent substrates 21, 22, the arrangement direction is the same as the arrangement direction of the electrochromic layer 23. These structures are only other combinations of the first embodiment, but in order to simplify the manufacturing process, the best In a good practice, only a plurality of electrochromic layers 23 arranged at intervals in a layered structure can achieve a good color-changing mechanism and masking effect.

另外,为使第一透明导电元件211不受电解质侵蚀,于其表面进一步可设有一保护层(图未示),或为使该电致变色层23不因电解质而水解以及增加使用寿命,于该电致变色层23与该电解质层24之间进一步亦设有一保护层(图未示),其中,该保护层之材质为选自二氧化硅(SiO2)、三氧化二铝(Al2O3)、四甲基二硅氧烷(tetramethyldisiloxane,TMDSO,C4H14OSi2)或其它碳-硅-氧薄膜(carbon-silicon-oxide layer)等,并以电镀法或溅镀法等方式设于上述迭层中。In addition, in order to prevent the first transparent conductive element 211 from being corroded by the electrolyte, a protective layer (not shown) can be further provided on its surface, or to prevent the electrochromic layer 23 from being hydrolyzed by the electrolyte and increase the service life, A protective layer (not shown) is further provided between the electrochromic layer 23 and the electrolyte layer 24, wherein the material of the protective layer is selected from silicon dioxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), tetramethyldisiloxane (tetramethyldisiloxane, TMDSO, C 4 H 14 OSi 2 ) or other carbon-silicon-oxide film (carbon-silicon-oxide layer), etc., and electroplating or sputtering, etc. The method is set in the above stack.

请参阅“图8”所示,为本发明第二较佳实施例的立体分解示意图,如图所示,本发明第二较佳实施例相较于前述第一较佳实施例,其不同点在于,该电解质层24为复数间隔排列设于该第一透明基板21与该电致电色层23之间,然该电解质层24作如此设置方式,较佳的应用是将该电解质层24作为电致变色层23的辅助变色功能,以有效的加深穿透率的对比度,意即该电解质层可选用电致变色材料,其材料可选自阳极变色(anodic coloration)、阴极变色(cathodiccoloration)或阴/阳极变色(cathodic/anodic coloration)所组成的过渡金属元素氧化物或其它有机化合物群组其中之一,一般而言,阳极变色(anodic coloration)材料主要为选自氧化铬(Cr2O3)、氧化镍(NiOx)、氧化铱(IrO2)、氧化锰(MnO2)、亚铁氰化铁Fe4[Fe(CN)6]3或氢氧化镍Ni(OH)2所组成的阳极变色(anodic coloration)过渡金属元素氧化物;阴极变色(cathodic coloration)材料主要为选自氧化钨(WO3)、氧化钼(MoO3)、氧化铌(Nb2O3)、氧化钛(TiO2)、钛酸锶(SrTiO3)所组成的阴极变色(cathodic coloration)过渡金属元素氧化物;而阴/阳极变色(cathodic/anodic coloration)材料主要为选自五氧化二钒(V2O5)、氧化铑(Rh2O3)或氧化钴(CoOx)所组成的阴/阳极变色(cathodic/anodic coloration)过渡金属元素氧化物,另外还有亦可作为固态电解质、离子传导层的五氧化二钽(Ta2O5)等过渡金属元素氧化物;另外,若该电解质层24作为辅助变色层,当电致变色层23选用阴极变色的材料,辅助变色层则需使用阳极变色的材料,反之亦然,因此当电致变色层23染色时,辅助变色层也进行染色,而当电致变色层23褪色时,辅助变色层亦进行褪色反应。Please refer to "Fig. 8", which is a three-dimensional exploded schematic view of the second preferred embodiment of the present invention. As shown in the figure, the second preferred embodiment of the present invention is different from the aforementioned first preferred embodiment. That is, the electrolyte layer 24 is arranged at intervals between the first transparent substrate 21 and the electrochromic layer 23, but the electrolyte layer 24 is arranged in such a way that the preferred application is to use the electrolyte layer 24 as an electrochromic layer. The auxiliary discoloration function of the chromogenic layer 23 is to effectively deepen the contrast of the transmittance, which means that the electrolyte layer can be selected from electrochromic materials, and its material can be selected from anode coloration (anodic coloration), cathode coloration (cathodic coloration) or cathode color change. One of the transition metal element oxides or other organic compounds composed of cathodic/anodic coloration. Generally speaking, the anodic coloration (anodic coloration) material is mainly selected from chromium oxide (Cr 2 O 3 ) , nickel oxide (NiO x ), iridium oxide (IrO 2 ), manganese oxide (MnO 2 ), ferric ferrocyanide Fe 4 [Fe(CN) 6 ] 3 or nickel hydroxide Ni(OH) 2 Anodic coloration transition metal oxides; cathodic coloration materials are mainly selected from tungsten oxide (WO 3 ), molybdenum oxide (MoO 3 ), niobium oxide (Nb 2 O 3 ), titanium oxide (TiO 2 ), strontium titanate (SrTiO 3 ) composed of cathodic coloration (cathodic coloration) transition metal element oxides; and cathodic/anodic coloration (cathodic/anodic coloration) materials are mainly selected from vanadium pentoxide (V 2 O 5 ) , rhodium oxide (Rh 2 O 3 ) or cobalt oxide (CoO x ) is composed of cathodic/anodic coloration transition metal element oxides, and there are also pentoxides that can also be used as solid electrolytes and ion-conducting layers. Ditantalum (Ta 2 O 5 ) and other transition metal element oxides; in addition, if the electrolyte layer 24 is used as an auxiliary color-changing layer, when the electrochromic layer 23 is selected from cathodic color-changing materials, the auxiliary color-changing layer needs to use anodic color-changing materials. Vice versa, therefore, when the electrochromic layer 23 is dyed, the auxiliary color-changing layer is also dyed, and when the electrochromic layer 23 fades, the auxiliary color-changing layer also undergoes a fading reaction.

请参阅“图9”所示,为本发明第三较佳实施例的立体分解示意图,如图所示,本发明第三较佳实施例相较于前述第一较佳实施例,其不同点在于,该电致变色层23与该电解质层24的设置位置相互对调,但其达成的功效与各组成结构的特性,仍相同于前述第一较佳实施例,在此不再赘述。Please refer to "Fig. 9", which is a three-dimensional exploded schematic view of the third preferred embodiment of the present invention. As shown in the figure, the third preferred embodiment of the present invention is different from the aforementioned first preferred embodiment. That is, the positions of the electrochromic layer 23 and the electrolyte layer 24 are reversed, but the functions achieved and the characteristics of each component structure are still the same as those of the first preferred embodiment, and will not be repeated here.

另外,为使第二透明导电元件221不受电解质侵蚀,于其表面进一步可设有一保护层(图未示),或为使该电致变色层23不因电解质而水解以及增加使用寿命,于该电致变色层23与该电解质层24之间进一步亦设有一保护层(图未示),其中,该保护层之材质为选自二氧化硅(SiO2)、三氧化二铝(Al2O3)、四甲基二硅氧烷(C4H14OSi2)或其它碳-硅-氧薄膜等,并以电镀法或溅镀法等方式设于上述迭层中。In addition, in order to prevent the second transparent conductive element 221 from being eroded by the electrolyte, a protective layer (not shown) can be further provided on its surface, or to prevent the electrochromic layer 23 from being hydrolyzed by the electrolyte and increase the service life, A protective layer (not shown) is further provided between the electrochromic layer 23 and the electrolyte layer 24, wherein the material of the protective layer is selected from silicon dioxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), tetramethyldisiloxane (C 4 H 14 OSi 2 ) or other carbon-silicon-oxygen thin films, etc., and are provided in the above-mentioned laminated layers by electroplating or sputtering.

请参阅“图10、11、12”所示,为本发明第三较佳实施例的不同层迭组合图,如图所示,该第一透明导电元件211可为复数间隔排列设于第一透明基板21的下表面,或该第二透明导电元件221复数间隔排列设于第二透明基板22的上表面,亦或是该第一、第二透明导电元件211、221皆复数间隔排列地设于第一、第二透明基板21、22的表面,而其排列方向是相同于电致变色层23的排列方向。Please refer to "Fig. 10, 11, 12", which are diagrams of different stacked combinations of the third preferred embodiment of the present invention. The lower surface of the transparent substrate 21, or the second transparent conductive elements 221 are arranged at multiple intervals on the upper surface of the second transparent substrate 22, or the first and second transparent conductive elements 211, 221 are arranged at plural intervals. On the surfaces of the first and second transparent substrates 21 and 22 , the arrangement direction thereof is the same as the arrangement direction of the electrochromic layer 23 .

请参阅“图13”所示,为本发明第四较佳实施例的立体分解示意图,如图所示,该电解质层24是呈复数间隔排列设于该第二透明基板22与该电致变色层23之间,然该电解质层24作如此设置方式,其较佳的应用是将该电解质层24作为电致变色层23的辅助变色功能,以有效的加深穿透率的对比度,意即该电解质层可选用电致变色材料,相较于第三实施例是电解质层24与电致变色层23位置互调,而其达成的功效与各组成结构的特性,则相同于前述第二较佳实施例,在此不再赘述。Please refer to "Fig. 13", which is a three-dimensional exploded schematic view of the fourth preferred embodiment of the present invention. As shown in the figure, the electrolyte layer 24 is arranged in a plurality of intervals and arranged on the second transparent substrate 22 and the electrochromic Between layers 23, however, the electrolyte layer 24 is arranged in this way, and its preferred application is to use the electrolyte layer 24 as an auxiliary color-changing function of the electrochromic layer 23, so as to effectively deepen the contrast of the transmittance, which means that the The electrochromic material can be selected for the electrolyte layer. Compared with the third embodiment, the position of the electrolyte layer 24 and the electrochromic layer 23 is intermodulated, and the functions achieved and the characteristics of each composition structure are the same as those of the second preferred embodiment described above. The embodiment will not be repeated here.

如“图14”所示,为本发明第五较佳实施例的立体分解示意图,相较于上述第一~四较佳实施例,其设置目的是为了达其更佳的遮光效果,因此于本实施例中是增设另一电致变色层,其结构包括:一影像显示单元1,是用以显示一平面影像与一立体影像,一影像切换单元2,是结合于该影像显示单元1表面,该影像切换单元2包括有:一第一透明基板21,其表面设有第一透明导电元件211,一第二透明基板22,与该第一透明基板21相对应的表面设有第二透明导电元件221,而另一表面用以结合该影像显示单元1表面,一第一电致变色层232,是复数间隔排列设于该第一透明基板21的下表面,一第二电致变色层233,是复数间隔排列设于该第二透明基板22的上表面,一电解质层24,是设于该等第一电致变色层232与该等第二电致变色层233之间;其中,该等第一电致变色层232与该等第二电致变色层233是朝相同排列方向设置,并且依据该第一、第二透明导电元件211、221的电性导通而使该等第一、第二电致变色层232、233产生颜色变化,意即,当该等第一电致变色层232染色时,该等第二电致变色层233亦染色,而当该等第一电致变色层232褪色时,该等第二电致变色层233亦褪色,值得注意的是,该等第一电致变色层232选用阴极变色的材料,第二电致变色层233则需使用阳极变色的材料,反之亦然,其达成的功效与各组成结构的特性,仍相同于前述各较佳实施例,于此不再赘述。As shown in "Fig. 14", it is a three-dimensional exploded schematic view of the fifth preferred embodiment of the present invention. Compared with the above-mentioned first to fourth preferred embodiments, its setting purpose is to achieve a better light-shielding effect, so in In this embodiment, another electrochromic layer is added, and its structure includes: an image display unit 1, which is used to display a plane image and a three-dimensional image, and an image switching unit 2, which is combined on the surface of the image display unit 1 , the image switching unit 2 includes: a first transparent substrate 21, the surface of which is provided with a first transparent conductive element 211, a second transparent substrate 22, and a surface corresponding to the first transparent substrate 21 is provided with a second transparent The conductive element 221, and the other surface is used to combine the surface of the image display unit 1, a first electrochromic layer 232, which is arranged at intervals on the lower surface of the first transparent substrate 21, and a second electrochromic layer 233 is a plurality of intervals arranged on the upper surface of the second transparent substrate 22, and an electrolyte layer 24 is arranged between the first electrochromic layers 232 and the second electrochromic layers 233; wherein, The first electrochromic layers 232 and the second electrochromic layers 233 are arranged in the same arrangement direction, and the first and second transparent conductive elements 211, 221 are electrically connected to make the first electrochromic layers 233 1. The second electrochromic layers 232, 233 produce color changes, that is, when the first electrochromic layers 232 are dyed, the second electrochromic layers 233 are also dyed, and when the first electrochromic layers When the color of the electrochromic layer 232 fades, the color of the second electrochromic layers 233 also fades. It is worth noting that the first electrochromic layers 232 use cathodic color-changing materials, while the second electrochromic layers 233 need to use anode materials. The color-changing material, and vice versa, the effect achieved and the characteristics of each component structure are still the same as those of the above-mentioned preferred embodiments, and will not be repeated here.

另外,为使透明导电元件211、221不受电解质侵蚀,于其表面进一步可设有一保护层(图未示),或为使该等电致变色层232、233不因电解质而水解以及增加使用寿命,于该等电致变色层232、233与该电解质层24之间进一步亦设有一保护层(图未示),其中,该保护层之材质为选自二氧化硅(SiO2)、三氧化二铝(Al2O3)、四甲基二硅氧烷(C4H14OSi2)或其它碳-硅-氧薄膜等,并以电镀法或溅镀法等方式设于上述迭层中。In addition, in order to prevent the transparent conductive elements 211, 221 from being corroded by the electrolyte, a protective layer (not shown) can be further provided on the surface thereof, or to prevent the electrochromic layers 232, 233 from being hydrolyzed by the electrolyte and to increase the usage A protective layer (not shown) is further provided between the electrochromic layers 232, 233 and the electrolyte layer 24, wherein the material of the protective layer is selected from silicon dioxide (SiO 2 ), three Aluminum oxide (Al 2 O 3 ), tetramethyldisiloxane (C 4 H 14 OSi 2 ) or other carbon-silicon-oxygen films, etc., and are placed on the above stacked layers by electroplating or sputtering middle.

请参阅“图15”所示,为本发明第六较佳实施例的立体分解示意图,如图所示,本发明2D/3D影像切换显示装置其包括有一影像显示单元1与一影像切换单元2,该影像切换单元2包括:一第一透明基板21、一第二透明基板22、一第一电致变色层232、第一电解质层241、第二电致变色层233、第二电解质层242以及一第三透明导电层25,其中,该第一透明基板21之下表面设有第一透明导电元件211以及该第二透明基板22之上表面设有第二透明导电元件221,而该第一电致变色层232是朝第一排列方向呈复数间隔排列设于该第一透明基板21下表面,且为覆盖于该第一透明导电元件211之上,再于该第一电致变色层232之下表面设置该第一电解质层241,而该第二电致变色层233是朝第二排列方向呈复数间隔排列设于该第二透明基板22上表面,且为覆盖于该第二透明导电元件221之上,再于该第二电致变色层233之上表面设置该第二电解质层242,另外,该第三透明导电层25是设于该第一电解质层241与该第二电解质层242之间,并电性连接该第一透明导电元件211与该第二透明导电元件221,因此,该第一电致变色层232依第一透明导电元件211与该第三透明导电层25的电性导通而产生颜色变化,而该第二电致变色层233则依第二透明导电元件221与该第三透明导电层25的电性导通而产生颜色变化。Please refer to "Fig. 15", which is a perspective exploded view of the sixth preferred embodiment of the present invention. As shown in the figure, the 2D/3D image switching display device of the present invention includes an image display unit 1 and an image switching unit 2 , the image switching unit 2 includes: a first transparent substrate 21, a second transparent substrate 22, a first electrochromic layer 232, a first electrolyte layer 241, a second electrochromic layer 233, a second electrolyte layer 242 And a third transparent conductive layer 25, wherein, the lower surface of the first transparent substrate 21 is provided with a first transparent conductive element 211 and the upper surface of the second transparent substrate 22 is provided with a second transparent conductive element 221, and the first An electrochromic layer 232 is arranged on the lower surface of the first transparent substrate 21 in a plurality of intervals toward the first arrangement direction, and covers the first transparent conductive element 211, and then on the first electrochromic layer The first electrolyte layer 241 is arranged on the lower surface of the substrate 232, and the second electrochromic layer 233 is arranged on the upper surface of the second transparent substrate 22 in a plurality of intervals toward the second arrangement direction, and covers the second transparent substrate 22. On the conductive element 221, the second electrolyte layer 242 is arranged on the upper surface of the second electrochromic layer 233. In addition, the third transparent conductive layer 25 is arranged on the first electrolyte layer 241 and the second electrolyte layer. layer 242, and electrically connect the first transparent conductive element 211 and the second transparent conductive element 221, therefore, the first electrochromic layer 232 depends on the first transparent conductive element 211 and the third transparent conductive layer 25 The color of the second electrochromic layer 233 changes according to the electrical conduction between the second transparent conductive element 221 and the third transparent conductive layer 25 .

上述的第一、第二电致变色层232、233其设置方法如前述实施例的设置方式,是选自溶胶凝胶法(sol-gel)、真空溅镀(sputtering)法、电镀(plating)法、网印、喷涂、阳极氧化法、光聚合法、激光蚀刻法等方式设置于各基板上,而该第一、第二电致变色层232、233的材料可选自阳极变色(anodic coloration)、阴极变色(cathodic coloration)或阴/阳极变色(cathodic/anodic coloration)所组成的过渡金属元素氧化物或其它有机化合物群组其中之一,另外,该第一、第二电解质层241、242的材质可选择液态电解质或固态电解质,但若为使该第一、第二电解质层241、242除提供离子的功能外,也能同时具有辅助变色的功能,则该电解质层的材质如前述第二较佳实施例所述,可选用电致变色材料,当电致变色层23选用阴极变色的材料,辅助变色层则需使用阳极变色的材料,反之亦然,因此当电致变色层23染色时,辅助变色层也进行染色,而当电致变色层23褪色时,辅助变色层亦进行褪色反应,而该第一、第二电解质层241、242则相应于第一、第二电致变色层232、233的设置位置及方向而呈复数间隔排列的设置于各迭层中,使得各层的电致变色层于产生遮光区域后,可以达到更佳的遮光效果。The above-mentioned first and second electrochromic layers 232, 233 are set up in the same way as in the previous embodiment, and are selected from the sol-gel method (sol-gel), vacuum sputtering (sputtering) method, electroplating (plating) method, screen printing, spray coating, anodic oxidation method, photopolymerization method, laser etching method, etc., are arranged on each substrate, and the materials of the first and second electrochromic layers 232, 233 can be selected from anodic coloration (anodic coloration) ), cathodic coloration (cathodic coloration) or cathodic/anodic coloration (cathodic/anodic coloration) transition metal element oxides or other organic compound groups, in addition, the first and second electrolyte layers 241, 242 The material of the electrolyte layer can be liquid electrolyte or solid electrolyte, but if the first and second electrolyte layers 241, 242 can not only provide the function of ions, but also have the function of assisting discoloration, the material of the electrolyte layer is as the above-mentioned first As described in the second preferred embodiment, electrochromic materials can be selected. When the electrochromic layer 23 is selected from cathodic color-changing materials, the auxiliary color-changing layer needs to use anodic color-changing materials, and vice versa. Therefore, when the electrochromic layer 23 is dyed , the auxiliary color-changing layer is also dyed, and when the electrochromic layer 23 fades, the auxiliary color-changing layer also undergoes a fading reaction, and the first and second electrolyte layers 241, 242 correspond to the first and second electrochromic layers. The positions and directions of the layers 232 and 233 are arranged in multiple intervals in each stacked layer, so that the electrochromic layer of each layer can achieve a better light-shielding effect after generating a light-shielding area.

该第六实施例的设置方式,是结合两组电致变色装置,目的是为了使显示装置可依照观赏者E观看角度来调整立体影像显示时所使用的遮光角度,因此该等第一电致变色层232朝第一排列方向作复数间隔排列设置,而第二电致变色层233朝第二排列方向作复数间隔排列设置,且该第一排列方向与该第二排列方向以互为直角为最佳设置角度,该等第一电致变色层232与该等第二电致变色层233是各别依据电压控制而产生复数间隔排列的遮光区域,应注意的是,该第三透明导电层25即代表一第三透明基板之上表面或下表面设有一第三透明导电元件,或该第三透明基板之上表面设有一第三透明导电元件,而该第三透明基板之下表面设置有一第四透明导电元件,以使该第一电致变色层依该第一透明导电元件与该第三透明导电元件的电性导通而产生颜色变化,而该第二电致变色层依该第二透明导电元件与该第四透明导电元件的电性导通而产生颜色变化。。The setting method of the sixth embodiment is to combine two sets of electrochromic devices. The color-changing layer 232 is arranged in plural intervals toward the first arrangement direction, and the second electrochromic layer 233 is arranged in plural intervals in the second arrangement direction, and the first arrangement direction and the second arrangement direction are at right angles to each other. Optimum setting angle, the first electrochromic layers 232 and the second electrochromic layers 233 respectively produce a plurality of light-shielding regions arranged at intervals according to voltage control. It should be noted that the third transparent conductive layer 25 means that a third transparent conductive element is provided on the upper or lower surface of a third transparent substrate, or a third transparent conductive element is provided on the upper surface of the third transparent substrate, and a third transparent conductive element is provided on the lower surface of the third transparent substrate. The fourth transparent conductive element, so that the color of the first electrochromic layer changes according to the electrical conduction between the first transparent conductive element and the third transparent conductive element, and the second electrochromic layer changes according to the electrical conduction between the first transparent conductive element and the third transparent conductive element. The second transparent conductive element is electrically connected to the fourth transparent conductive element to produce a color change. .

其操作原理是该显示装置具有一感测元件(图未示)以及一控制元件(图未示),该感测元件与该控制元件彼此电性连接,其中,该感测元件可为一陀螺仪(Gyroscope),而该控制元件则分别与该第一透明导电元件211、该第二透明导电元件221与第三透明导电层25电性连接,其中,该感测元件用以感测该显示装置的旋转方向(如水平或垂直),并将其感测信号传给控制元件,再透过控制元件切换该第一、第二透明导电元件211、221、第三透明导电层25的电压,以使该第一电致变色层232与该第二电致变色层233改变其状态而变色,举例说明,当影像显示单元1以第一排列方向正对观赏者E,则朝第一排列方向设置的该等第一电致变色层232着色,而使该影像显示单元1的影像经过该等第一电致变色层232所形成的视差屏障后,在第一排列方向上形成该立体影像;但当该影像显示单元1改以第二排列方向正对观赏者E,则控制元件控制第一、第二透明导电元件211、221及第三透明导电层25的电压切换,使该第一电致变色层232、该第一电解质层241的状态改变,使原已着色的第一电致变色层232去色,而使该第二电致变色层233着色,因此,当影像经过该等第二电致变色层233所形成的视差屏障后,在第二排列方向上形成该立体影像,若观赏者E欲恢复平面影像显示,则控制第一、第二透明导电元件211、221及第三透明导电层25的电压切换,使该等第一、第二电致变色层232、233皆为褪色,则该影像显示单元1则由立体影像显示切换为平面影像显示。Its operating principle is that the display device has a sensing element (not shown) and a control element (not shown), the sensing element and the control element are electrically connected to each other, wherein the sensing element can be a gyroscope instrument (Gyroscope), and the control element is electrically connected to the first transparent conductive element 211, the second transparent conductive element 221 and the third transparent conductive layer 25, wherein the sensing element is used to sense the display The rotation direction of the device (such as horizontal or vertical), and send the sensing signal to the control element, and then switch the voltage of the first, second transparent conductive elements 211, 221, and the third transparent conductive layer 25 through the control element, To make the first electrochromic layer 232 and the second electrochromic layer 233 change their state and change color. The first electrochromic layers 232 are colored so that the image of the image display unit 1 passes through the parallax barrier formed by the first electrochromic layers 232 to form the stereoscopic image in the first arrangement direction; But when the image display unit 1 is changed to face the viewer E in the second arrangement direction, the control element controls the voltage switching of the first and second transparent conductive elements 211, 221 and the third transparent conductive layer 25, so that the first voltage The states of the first electrochromic layer 232 and the first electrolyte layer 241 are changed to decolorize the originally colored first electrochromic layer 232 and to color the second electrochromic layer 233. Therefore, when the image passes through the first electrochromic layer 232 After the parallax barrier formed by the two electrochromic layers 233, the stereoscopic image is formed in the second arrangement direction. The voltage switching of the transparent conductive layer 25 causes the first and second electrochromic layers 232 and 233 to fade, and the image display unit 1 switches from stereoscopic image display to planar image display.

请参阅“图16”所示,为本发明第七较佳实施例的立体分解示意图,如图所示,本实施例相较于第六较佳实施例,其不同之处在于,该第一电致变色层232与该第一电解质层241的设置位置互换,而该第二电致变色层233与该第二电解质层242的设置位置互换,其所欲达成的功效、组成材料的特性以及依照观看角度来调整立体影像显示时所使用的遮光角度的操作原理,皆相同于前述第六较佳实施例,只是上述的第六、第七较佳实施例的两组电致变色装置,其迭构顺序不一定要相同,因各电致变色层是各自受电压控制,只要组合后,其第一电致变色层232与第二电致变色层233的第一排列方向与第二排列方向不同向即可,因此两组迭构中的电解质层与电致变色层的设置顺序,可为相同或不同,则皆应属于本发明的范畴。Please refer to "Fig. 16", which is a three-dimensional exploded schematic view of the seventh preferred embodiment of the present invention. As shown in the figure, this embodiment differs from the sixth preferred embodiment in that the first The positions of the electrochromic layer 232 and the first electrolyte layer 241 are exchanged, and the positions of the second electrochromic layer 233 and the second electrolyte layer 242 are exchanged. The characteristics and the operation principle of adjusting the shading angle used when the stereoscopic image is displayed according to the viewing angle are the same as the sixth preferred embodiment above, except that the two groups of electrochromic devices of the sixth and seventh preferred embodiments are the same , the stacking order does not have to be the same, because each electrochromic layer is controlled by voltage separately, as long as after the combination, the first arrangement direction of the first electrochromic layer 232 and the second electrochromic layer 233 is the same as that of the second electrochromic layer. The arrangement directions can be different. Therefore, the order of arrangement of the electrolyte layer and the electrochromic layer in the two sets of stacks can be the same or different, and all of them should belong to the scope of the present invention.

以上所述者,仅为本发明的较佳实施例而已,并非用以限定本发明实施的范围;任何熟习此技艺者,在不脱离本发明的精神与范围下所作的均等变化与修饰,皆应涵盖于本发明的专利范围内。The above are only preferred embodiments of the present invention, and are not intended to limit the scope of the present invention; any equivalent changes and modifications made by those skilled in the art without departing from the spirit and scope of the present invention are all Should be covered within the patent scope of the present invention.

综上所述,本发明的2D/3D影像切换显示装置,是具有专利的创造性,及对产业的利用价值;申请人依专利法的规定,提起发明专利的申请。To sum up, the 2D/3D image switching display device of the present invention has the inventiveness of the patent and the utility value to the industry; the applicant files an application for the invention patent in accordance with the provisions of the Patent Law.

Claims (85)

1. a 2D/3D image switching display device is characterized in that, comprising:
One image display cell is in order to show a flat image and a stereopsis;
One image switch unit is to be incorporated into this image display cell surface, and it includes:
One first transparency carrier, its surface are provided with one first transparent conductive element;
One second transparency carrier is to be provided with one second transparent conductive element with this corresponding surface of first transparency carrier, and another surface is in order to be incorporated into this image display cell surface;
One electrochromic layer is to be plural number to be located at this second transparency carrier surface with being spaced, and it produces change color according to electrically conducting of this first, second transparent conductive element;
One dielectric substrate is to be located between these electrochromic layers and this first transparency carrier.
2. 2D/3D image switching display device according to claim 1; It is characterized in that, this image display cell be LCD, plasma display, surface-conduction-electron emission display, Field Emission Display, vacuum fluorescent display, organic light emitting diode display or Electronic Paper one of them.
3. 2D/3D image switching display device according to claim 1; It is characterized in that, the material of this first transparency carrier and this second transparency carrier be plastic cement, high molecular weight plastic, glass or for the plastic polymer that is selected from resin, polyethylene terephthalate, polycarbonate, tygon, PVC, polypropylene, polystyrene, polymethylmethacrylate or its potpourri one of them.
4. 2D/3D image switching display device according to claim 1; It is characterized in that, the mode that this electrochromic layer is located at this second transparency carrier upper surface for be selected from sol-gal process, vacuum splashing and plating method, wire mark, spraying, anodizing, light polymerization method, electrochemical plating or laser-induced thermal etching method one of them.
5. 2D/3D image switching display device according to claim 1; It is characterized in that, the material of this electrochromic layer be selected from group that anode variable color, negative electrode variable color, the moon/anode variable color oxidation of interim metal or organic compound form one of them.
6. 2D/3D image switching display device according to claim 5 is characterized in that the material of this electrochromic layer is for being selected from chromium oxide (Cr 2O 3), nickel oxide (NiO x), yttrium oxide (IrO 2), manganese oxide (MnO 2), hydroxide nickel (OH) 2, tantalum pentoxide (Ta 2O 5) or ferric ferrocyanide Fe 4[Fe (CN) 6] 3The anode variable color oxidation of interim metal of being formed.
7. 2D/3D image switching display device according to claim 5 is characterized in that the material of this electrochromic layer is for being selected from tungsten oxide (WO 3), molybdena (MoO 3), niobium oxide (Nb 2O 3), titanium dioxide (TiO 2), strontium titanates (SrTiO 3) or tantalum pentoxide (Ta 2O 5) the negative electrode variable color oxidation of interim metal formed.
8. 2D/3D image switching display device according to claim 5 is characterized in that the material of this electrochromic layer is for being selected from vanadium oxide (V 2O 2), rhodium oxide (Rh 2O 3) or cobalt oxide (CoO x) the moon/anode variable color oxidation of interim metal of being formed.
9. 2D/3D image switching display device according to claim 1 is characterized in that this dielectric substrate is liquid electrolyte or solid electrolyte.
10. 2D/3D image switching display device according to claim 9; It is characterized in that; This dielectric substrate is a solid electrolyte, and for be selected from ionomer film, organic/inorganic blend together film or PEM group that acid/the alkali macromolecule membrane is formed one of them.
11. 2D/3D image switching display device according to claim 10 is characterized in that the material that this dielectric substrate is is a PEM, and for gathering perfluoro sulfonic acid membrane.
12. 2D/3D image switching display device according to claim 1; It is characterized in that; This first transparency carrier lower surface further is provided with this first transparent conductive element with the plural number mode of being spaced; And being same as the orientation of this electrochromic layer, its orientation can be horizontal direction or homeotropic alignment direction.
13. 2D/3D image switching display device according to claim 1; It is characterized in that; This second transparency carrier upper surface further is provided with this second transparent conductive element with the plural number mode of being spaced; And being same as the orientation of this electrochromic layer, its orientation can be horizontal direction or homeotropic alignment direction.
14. 2D/3D image switching display device according to claim 1; It is characterized in that; This first transparency carrier lower surface further is provided with this first transparent conductive element with the plural number mode of being spaced; And this second transparency carrier upper surface further is provided with this second transparent conductive element with the plural number mode of being spaced, and these first, second transparent conductive element are the orientations that are same as this electrochromic layer, and its orientation can be horizontal direction or homeotropic alignment direction.
15. 2D/3D image switching display device according to claim 1; It is characterized in that; This dielectric substrate is to be spaced mode with plural number; Be located between this first transparent conductive element and this electrochromic layer, and be same as the orientation of this electrochromic layer, its orientation can be horizontal direction or homeotropic alignment direction.
16. 2D/3D image switching display device according to claim 15; It is characterized in that; This dielectric substrate can be electrochromic layer, its material be selected from group that anode variable color, negative electrode variable color, the moon/anode variable color oxidation of interim metal or organic compound form one of them.
17. 2D/3D image switching display device according to claim 16 is characterized in that the material of this electrochromic layer is for being selected from chromium oxide (Cr 2O 3), nickel oxide (NiO x), yttrium oxide (IrO 2), manganese oxide (MnO 2), hydroxide nickel (OH) 2, tantalum pentoxide (Ta 2O 5) or ferric ferrocyanide Fe 4[Fe (CN) 6] 3The anode variable color oxidation of interim metal of being formed.
18. 2D/3D image switching display device according to claim 16 is characterized in that the material of this electrochromic layer is for being selected from tungsten oxide (WO 3), molybdena (MoO 3), niobium oxide (Nb 2O 3), titanium dioxide (TiO 2), strontium titanates (SrTiO 3) or tantalum pentoxide (Ta 2O 5) the negative electrode variable color oxidation of interim metal formed.
19. 2D/3D image switching display device according to claim 16 is characterized in that the material of this electrochromic layer is for being selected from vanadium oxide (V 2O 2), rhodium oxide (Rh 2O 3) or cobalt oxide (CoO x) the moon/anode variable color oxidation of interim metal of being formed.
20. 2D/3D image switching display device according to claim 1 is characterized in that, further has a protective seam between this first transparent conductive element and this dielectric substrate.
21. 2D/3D image switching display device according to claim 1 is characterized in that, further has a protective seam between this electrochromic layer and this dielectric substrate.
22., it is characterized in that the material of this protective seam comprises silicon dioxide (SiO for being selected from according to claim 20 or 21 described 2D/3D image switching display devices 2), alundum (Al (Al 2O 3), tetramethyl disiloxane (C 4H 14OSi 2) at interior carbon-silicon-oxygen film.
23. a 2D/3D image switching display device is characterized in that, comprising:
One image display cell is in order to show a flat image and a stereopsis;
One image switch unit is to be incorporated into this image display cell surface, and it includes:
One first transparency carrier, its surface are provided with one first transparent conductive element;
One second transparency carrier is to be provided with one second transparent conductive element with this corresponding surface of first transparency carrier, and another surface is in order to be incorporated into this image display cell surface;
One electrochromic layer is to be plural number to be located at this first transparency carrier lower surface with being spaced, and it produces change color according to electrically conducting of this first, second transparent conductive element;
One dielectric substrate is to be located between this electrochromic layer and this second transparency carrier.
24. 2D/3D image switching display device according to claim 23; It is characterized in that, this image display cell can be LCD, plasma display, surface-conduction-electron emission display, Field Emission Display, vacuum fluorescent display, organic light emitting diode display or Electronic Paper one of them.
25. 2D/3D image switching display device according to claim 23; It is characterized in that, the material of this first transparency carrier and this second transparency carrier be plastic cement, high molecular weight plastic, glass or for the plastic polymer that is selected from resin, polyethylene terephthalate, polycarbonate, tygon, PVC, polypropylene, polystyrene, polymethylmethacrylate or its potpourri one of them.
26. 2D/3D image switching display device according to claim 23; It is characterized in that, the mode that this electrochromic layer is located at this first transparency carrier upper surface for be selected from sol-gal process, vacuum splashing and plating method, wire mark, spraying, anodizing, light polymerization method, electrochemical plating or laser-induced thermal etching method one of them.
27. 2D/3D image switching display device according to claim 23; It is characterized in that, the material of this electrochromic layer be selected from group that anode variable color, negative electrode variable color, the moon/anode variable color oxidation of interim metal or organic compound form one of them.
28. 2D/3D image switching display device according to claim 27 is characterized in that the material of this electrochromic layer is for being selected from chromium oxide (Cr 2O 3), nickel oxide (NiO x), yttrium oxide (IrO 2), manganese oxide (MnO 2), hydroxide nickel (OH) 2, tantalum pentoxide (Ta 2O 5) or ferric ferrocyanide Fe 4[Fe (CN) 6] 3The anode variable color oxidation of interim metal of being formed.
29. 2D/3D image switching display device according to claim 27 is characterized in that the material of this electrochromic layer is for being selected from tungsten oxide (WO 3), molybdena (MoO 3), niobium oxide (Nb 2O 3), titanium dioxide (TiO 2), strontium titanates (SrTiO 3) or tantalum pentoxide (Ta 2O 5) the negative electrode variable color oxidation of interim metal formed.
30. 2D/3D image switching display device according to claim 27 is characterized in that the material of this electrochromic layer is for being selected from vanadium oxide (V 2O 2), rhodium oxide (Rh 2O 3) or cobalt oxide (CoO x) the moon/anode variable color oxidation of interim metal of being formed.
31. 2D/3D image switching display device according to claim 23 is characterized in that this dielectric substrate is liquid electrolyte or solid electrolyte.
32. 2D/3D image switching display device according to claim 31; It is characterized in that; This dielectric substrate is a solid electrolyte, and can be selected from ionomer film, organic/inorganic blend together film or PEM group that acid/the alkali macromolecule membrane is formed one of them.
33. 2D/3D image switching display device according to claim 32 is characterized in that the material that this dielectric substrate is is a PEM, and for gathering perfluoro sulfonic acid membrane.
34. 2D/3D image switching display device according to claim 23; It is characterized in that; This first transparency carrier lower surface further is provided with this first transparent conductive element with the plural number mode of being spaced; And being same as the orientation of this electrochromic layer, its orientation can be horizontal direction or homeotropic alignment direction.
35. 2D/3D image switching display device according to claim 23; It is characterized in that; This second transparency carrier upper surface further is provided with this second transparent conductive element with the plural number mode of being spaced; And being same as the orientation of this electrochromic layer, its orientation can be horizontal direction or homeotropic alignment direction.
36. 2D/3D image switching display device according to claim 23; It is characterized in that; This first transparency carrier lower surface further is provided with this first transparent conductive element with the plural number mode of being spaced; And this second transparency carrier upper surface further is provided with this second transparent conductive element with the plural number mode of being spaced, and this first, second transparent conductive element is the orientation that is same as this electrochromic layer, and its orientation can be horizontal direction or homeotropic alignment direction.
37. 2D/3D image switching display device according to claim 23; It is characterized in that; This dielectric substrate is to be spaced mode with plural number; Be located between this second transparent conductive element and this electrochromic layer, and be same as the orientation of this electrochromic layer, its orientation can be horizontal direction or homeotropic alignment direction.
38. according to the described 2D/3D image of claim 37 switching display device; It is characterized in that; This dielectric substrate can be electrochromic layer, its material be selected from group that anode variable color, negative electrode variable color, the moon/anode variable color oxidation of interim metal or organic compound form one of them.
39., it is characterized in that the material of this electrochromic layer is for being selected from chromium oxide (Cr according to the described 2D/3D image of claim 38 switching display device 2O 3), nickel oxide (NiO x), yttrium oxide (IrO 2), manganese oxide (MnO 2), hydroxide nickel (OH) 2, tantalum pentoxide (Ta 2O 5) or ferric ferrocyanide Fe 4[Fe (CN) 6] 3The anode variable color oxidation of interim metal of being formed.
40., it is characterized in that the material of this electrochromic layer is for being selected from tungsten oxide (WO according to the described 2D/3D image of claim 38 switching display device 3), molybdena (MoO 3), niobium oxide (Nb 2O 3), titanium dioxide (TiO 2), strontium titanates (SrTiO 3) or tantalum pentoxide (Ta 2O 5) the negative electrode variable color oxidation of interim metal formed.
41., it is characterized in that the material of this electrochromic layer is for being selected from vanadium oxide (V according to the described 2D/3D image of claim 38 switching display device 2O 2), rhodium oxide (Rh 2O 3) or cobalt oxide (CoO x) the moon/anode variable color oxidation of interim metal of being formed.
42. 2D/3D image switching display device according to claim 23 is characterized in that, further has a protective seam between this second transparent conductive element and this dielectric substrate.
43. 2D/3D image switching display device according to claim 23 is characterized in that, further has a protective seam between this electrochromic layer and this dielectric substrate.
44., it is characterized in that the material of this protective seam comprises silicon dioxide (SiO for being selected from according to claim 42 or 43 described 2D/3D image switching display devices 2), alundum (Al (Al 2O 3), tetramethyl disiloxane (C 4H 14OSi 2) at interior carbon-silicon-oxygen film.
45. a 2D/3D image switching display device is characterized in that, comprising:
One image display cell is in order to show a flat image and a stereopsis;
One image switch unit is to be incorporated into this image display cell surface, and it includes:
One first transparency carrier, its surface are to be provided with first transparent conductive element;
One second transparency carrier is to be provided with second transparent conductive element with this corresponding surface of first transparency carrier, and another surface is in order to be incorporated into this image display cell surface;
One first electrochromic layer is that plural number is spaced and is located at this first transparency carrier lower surface;
One second electrochromic layer; Be that plural number is spaced and is located at this second transparency carrier upper surface; Its orientation is same as this first electrochromic layer, and makes this first, second electrochromic layer produce change color according to electrically conducting of this first, second transparent conductive element;
One dielectric substrate is to be located between this first electrochromic layer and this second electrochromic layer.
46. according to the described 2D/3D image of claim 45 switching display device; It is characterized in that, this image display cell be LCD, plasma display, surface-conduction-electron emission display, Field Emission Display, vacuum fluorescent display, organic light emitting diode display or Electronic Paper one of them.
47. according to the described 2D/3D image of claim 45 switching display device; It is characterized in that, the material of this first transparency carrier and this second transparency carrier be plastic cement, high molecular weight plastic, glass or for the plastic polymer that is selected from resin, polyethylene terephthalate, polycarbonate, tygon, PVC, polypropylene, polystyrene, polymethylmethacrylate or its potpourri one of them.
48. according to the described 2D/3D image of claim 45 switching display device; It is characterized in that, this first electrochromic layer be located at mode that this first transparency carrier lower surface and this second electrochromic layer be located at this second transparency carrier upper surface for be selected from sol-gal process, vacuum splashing and plating method, electrochemical plating, wire mark, spraying, anodizing, light polymerization method or laser-induced thermal etching method one of them.
49. according to the described 2D/3D image of claim 45 switching display device; It is characterized in that, the material of this first, second electrochromic layer be selected from group that anode variable color, negative electrode variable color, the moon/anode variable color oxidation of interim metal or organic compound form one of them.
50., it is characterized in that the material of this first, second electrochromic layer is for being selected from chromium oxide (Cr according to the described 2D/3D image of claim 49 switching display device 2O 3), nickel oxide (NiO x), yttrium oxide (IrO 2), manganese oxide (MnO 2), hydroxide nickel (OH) 2, tantalum pentoxide (Ta 2O 5) or ferric ferrocyanide Fe 4[Fe (CN) 6] 3The anode variable color oxidation of interim metal of being formed.
51., it is characterized in that the material of this first, second electrochromic layer is for being selected from tungsten oxide (WO according to the described 2D/3D image of claim 49 switching display device 3), molybdena (MoO 3), niobium oxide (Nb 2O 3), titanium dioxide (TiO 2), strontium titanates (SrTiO 3) or tantalum pentoxide (Ta 2O 5) the negative electrode variable color oxidation of interim metal formed.
52., it is characterized in that the material of this first, second electrochromic layer is for being selected from vanadium oxide (V according to the described 2D/3D image of claim 49 switching display device 2O 2), rhodium oxide (Rh 2O 3) or cobalt oxide (CoO x) the moon/anode variable color oxidation of interim metal of being formed.
53., it is characterized in that this dielectric substrate is liquid electrolyte or solid electrolyte according to the described 2D/3D image of claim 45 switching display device.
54. according to the described 2D/3D image of claim 53 switching display device; It is characterized in that; This dielectric substrate is a solid electrolyte, and for be selected from ionomer film, organic/inorganic blend together film or PEM group that acid/the alkali macromolecule membrane is formed one of them.
55., it is characterized in that the material that this dielectric substrate is is a PEM according to the described 2D/3D image of claim 54 switching display device, and for gathering perfluoro sulfonic acid membrane.
56. according to the described 2D/3D image of claim 45 switching display device; It is characterized in that; This dielectric substrate is to be spaced mode with plural number; Be located between this first, second electrochromic layer, and be same as the orientation of this first, second electrochromic layer, its orientation can be horizontal direction or homeotropic alignment direction.
57., it is characterized in that further having a protective seam between this first, second transparent conductive element and this dielectric substrate respectively according to the described 2D/3D image of claim 45 switching display device.
58., it is characterized in that further having a protective seam between this first, second electrochromic layer and this dielectric substrate respectively according to the described 2D/3D image of claim 45 switching display device.
59., it is characterized in that the material of this protective seam comprises silicon dioxide (SiO for being selected from according to claim 57 or 58 described 2D/3D image switching display devices 2), alundum (Al (Al 2O 3), tetramethyl disiloxane (C 4H 14OSi 2) at interior carbon-silicon-oxygen film.
60. a 2D/3D image switching display device is characterized in that, comprising:
One image display cell is in order to show a flat image and a stereopsis;
One image switch unit is to be incorporated into this image display cell surface, and it includes:
One first transparency carrier, its surface are to be provided with first transparent conductive element;
One second transparency carrier is to be provided with second transparent conductive element with this corresponding surface of first transparency carrier, and another surface is in order to be incorporated into this image display cell surface;
One first electrochromic layer is to be plural number to be spaced and to be located at this first transparency carrier lower surface towards the first order direction;
One first dielectric substrate is to be located at this first electrochromic layer lower surface;
One second electrochromic layer is to be plural number to be spaced and to be located at this second transparency carrier upper surface towards the second order direction;
One second dielectric substrate is to be located at surface on this second electrochromic layer; And
One the 3rd transparency conducting layer; Be to be located between this first dielectric substrate and this second dielectric substrate; And electrically connect this first transparent conductive element and this second transparent conductive element; So that this first electrochromic layer produces change color according to this first transparent conductive element and the 3rd electrically conducting of transparency conducting layer, and this second electrochromic layer is complied with this second transparent conductive element and the 3rd electrically conducting of transparency conducting layer and produce change color.
61., it is characterized in that the 3rd transparency conducting layer has one the 3rd transparency carrier according to the described 2D/3D image of claim 60 switching display device, and be provided with one the 3rd transparent conductive element at the upper surface of the 3rd transparency carrier.
62., it is characterized in that the 3rd transparency conducting layer has one the 3rd transparency carrier according to the described 2D/3D image of claim 60 switching display device, and be provided with one the 3rd transparent conductive element at the lower surface of the 3rd transparency carrier.
63. according to the described 2D/3D image of claim 60 switching display device; It is characterized in that; The 3rd transparency conducting layer has one the 3rd transparency carrier; And the surface is provided with one the 3rd transparent conductive element on the 3rd transparency carrier; And the surface is provided with one the 4th transparent conductive element under the 3rd transparency carrier, so that this first electrochromic layer produces change color according to this first transparent conductive element and the 3rd electrically conducting of transparent conductive element, and this second electrochromic layer is complied with this second transparent conductive element and the 4th electrically conducting of transparent conductive element and produce change color.
64., it is characterized in that this first order direction is vertical each other with this second order direction according to the described 2D/3D image of claim 60 switching display device.
65. according to the described 2D/3D image of claim 60 switching display device; It is characterized in that; This first dielectric substrate is to be spaced mode with plural number, is located between this first electrochromic layer and this transparency conducting layer, and is same as the orientation of this first electrochromic layer.
66. according to the described 2D/3D image of claim 65 switching display device; It is characterized in that, the material of these dielectric substrates be selected from group that anode variable color, negative electrode variable color or the moon/anode variable color oxidation of interim metal or organic compound form one of them.
67. according to the described 2D/3D image of claim 60 switching display device; It is characterized in that; This second dielectric substrate is to be spaced mode with plural number, is located between this second electrochromic layer and this transparency conducting layer, and is same as the orientation of this second electrochromic layer.
68. according to the described 2D/3D image of claim 67 switching display device; It is characterized in that, the material of these dielectric substrates be selected from group that anode variable color, negative electrode variable color, the moon/anode variable color oxidation of interim metal or organic compound form one of them.
69. according to the described 2D/3D image of claim 60 switching display device; It is characterized in that this device further has a sensing element and a control element, this sensing element and this control element are electrically connected to each other; This control element then electrically connects with this first transparent conductive element, transparency conducting layer and this second transparent conductive element respectively; Wherein, this sensing element is in order to the rotation direction of this display device of sensing, and after its sensing signal passed to control element; See through the voltage that control element switches this two transparent conductive element, so that this first electrochromic layer and this second electrochromic layer change its state and variable color.
70. according to the described 2D/3D image of claim 69 switching display device, wherein, this sensing element is to be a gyroscope.
71., it is characterized in that when this first electrochromic layer is painted, and this second electrochromic layer discolors according to the described 2D/3D image of claim 60 switching display device, otherwise when first electrochromic layer discolors, and this second electrochromic layer is painted.
72., it is characterized in that when stereopsis showed that switching to flat image shows, then this first electrochromic layer and this second electrochromic layer were all the reaction of discoloring according to the described 2D/3D image of claim 60 switching display device.
73. a 2D/3D image switching display device is characterized in that it comprises:
One image display cell is in order to show a flat image and a stereopsis;
One image switch unit is to be incorporated into this image display cell surface, and it includes:
One first transparency carrier, its surface are to be provided with first transparent conductive element;
One second transparency carrier is to be provided with second transparent conductive element with this corresponding surface of first transparency carrier, and another surface is in order to be incorporated into this image display cell surface;
One first dielectric substrate is to be located at this first transparency carrier lower surface;
One first electrochromic layer is to be plural number to be spaced and to be located at this first electrolyte lower surface towards the first order direction;
One second dielectric substrate is to be located at surface on this second transparency carrier;
One second electrochromic layer is to be plural number to be spaced and to be located at this second electrolyte upper surface towards the second order direction; And
One the 3rd transparency conducting layer; Be to be located between this first, second electrochromic layer; And electrically connect this first transparent conductive element and this second transparent conductive element; So that this first electrochromic layer produces change color according to this first transparent conductive element and the 3rd electrically conducting of transparency conducting layer, and this second electrochromic layer is complied with this second transparent conductive element and the 3rd electrically conducting of transparency conducting layer and produce change color.
74., it is characterized in that the 3rd transparency conducting layer has one the 3rd transparency carrier according to the described 2D/3D image of claim 73 switching display device, and the surface is provided with one the 3rd transparent conductive element on the 3rd transparency carrier.
75., it is characterized in that the 3rd transparency conducting layer has one the 3rd transparency carrier according to the described 2D/3D image of claim 73 switching display device, and the surface is provided with one the 3rd transparent conductive element under the 3rd transparency carrier.
76. according to the described 2D/3D image of claim 73 switching display device; It is characterized in that; The 3rd transparency conducting layer has one the 3rd transparency carrier; And the surface is provided with one the 3rd transparent conductive element on the 3rd transparency carrier; And the surface is provided with one the 4th transparent conductive element under the 3rd transparency carrier, so that this first electrochromic layer produces change color according to this first transparent conductive element and the 3rd electrically conducting of transparent conductive element, and this second electrochromic layer is complied with this second transparent conductive element and the 4th electrically conducting of transparent conductive element and produce change color.
77., it is characterized in that this first order direction is vertical each other with this second order direction according to the described 2D/3D image of claim 73 switching display device.
78. according to the described 2D/3D image of claim 73 switching display device; It is characterized in that; This first dielectric substrate is to be spaced mode with plural number, is located between this first electrochromic layer and this first transparency conducting layer, and is same as the orientation of this first electrochromic layer.
79. according to the described 2D/3D image of claim 78 switching display device; It is characterized in that, the material of this first dielectric substrate be selected from group that anode variable color, negative electrode variable color, the moon/anode variable color oxidation of interim metal or organic compound form one of them.
80. according to the described 2D/3D image of claim 73 switching display device; It is characterized in that; This second dielectric substrate is to be spaced mode with plural number, is located between this second electrochromic layer and this second transparency conducting layer, and is same as the orientation of this second electrochromic layer.
81. 0 described 2D/3D image switching display device according to Claim 8; It is characterized in that, the material of this second dielectric substrate be selected from group that anode variable color, negative electrode variable color or the moon/anode variable color oxidation of interim metal or organic compound form one of them.
82. according to the described 2D/3D image of claim 73 switching display device; It is characterized in that this device further has a sensing element and a control element, this sensing element and this control element are electrically connected to each other; This control element then electrically is connected with this first transparent conductive element, this second transparent conductive element and the 3rd transparency conducting layer respectively; Wherein, this sensing element is in order to the rotation direction of this display device of sensing, and after its sensing signal passed to control element; See through the voltage that control element switches this two transparent conductive element, so that this first electrochromic layer and this second electrochromic layer change its state and variable color.
83. 2 described 2D/3D image switching display devices according to Claim 8, wherein, this sensing element is to be a gyroscope.
84., it is characterized in that when this first electrochromic layer is painted, and this second electrochromic layer discolors according to the described 2D/3D image of claim 73 switching display device, otherwise when first electrochromic layer discolors, and this second electrochromic layer is painted.
85. according to the described 2D/3D image of claim 73 switching display device, when stereopsis showed that switching to flat image shows, then this first electrochromic layer and this second electrochromic layer were all the reaction of discoloring.
CN2010102386554A 2010-07-26 2010-07-26 2D/3D image switching display device Pending CN102338960A (en)

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