CN102326565B - Weeding composition containing beflubutamid and pinoxaden - Google Patents
Weeding composition containing beflubutamid and pinoxaden Download PDFInfo
- Publication number
- CN102326565B CN102326565B CN2011101969127A CN201110196912A CN102326565B CN 102326565 B CN102326565 B CN 102326565B CN 2011101969127 A CN2011101969127 A CN 2011101969127A CN 201110196912 A CN201110196912 A CN 201110196912A CN 102326565 B CN102326565 B CN 102326565B
- Authority
- CN
- China
- Prior art keywords
- beflubutamid
- azoles quinoline
- grass ester
- quinoline grass
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000000203 mixture Substances 0.000 title claims abstract description 36
- 238000009333 weeding Methods 0.000 title abstract description 9
- 239000005597 Pinoxaden Substances 0.000 title abstract description 5
- MGOHCFMYLBAPRN-UHFFFAOYSA-N pinoxaden Chemical compound CCC1=CC(C)=CC(CC)=C1C(C1=O)=C(OC(=O)C(C)(C)C)N2N1CCOCC2 MGOHCFMYLBAPRN-UHFFFAOYSA-N 0.000 title abstract description 5
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- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 218
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to weeding composition containing beflubutamid and pinoxaden, which is mainly characterized by containing 1 percent to 70 percent of beflubutamid, 1 percent to 50 percent of pinoxaden, auxiliary agent and other excipients. The weeding composition can be made into wettable powder, water dispersion granule, suspending agent, suspension emulsion, micro emulsion and water emulsion. The weeding composition can be used for preventing weeds in wheat field.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to the Herbicidal combinations of a kind of beflubutamid and azoles quinoline grass ester, be used to preventing and treating the common weeds of wheatland.
Background technology
The direction of pesticide developing was to embody efficient, low toxicity, low-residual and pollution-free in recent years.Be embodied in pursuit " three height ", namely (1) is safe, and this not only requires toxicity low, residual low, and nuisanceless; (2) biologically active is high; (3) selectivity is high.Therefore continue to improve the performance of current Pesticidal products, reach efficient, low toxicity, free of contamination requirement.So, select the agricultural chemicals of composite mixture just to become current first-selection and a kind of effective approach, the agricultural chemicals that is performance complement by the proportioning of adjusting different agricultural chemicals obtains best synergistic effect.
Beflubutamid (beflubufamid), molecular formula: C
18H
17F
4NO
2, molecular weight: 355.33.Beflubutamid is the benzene oxanamide class weed killer herbicide by the exploitation of Ube industry company, be mainly used in wheat paddock seedling rear defence except important broad leaved weed and grassy weed, with the isoproturon mix weeding, have better effect, because its lasting period is moderate, on succession crop without impact.
Azoles quinoline grass ester (pinoxaden), molecular formula: C
23H
32N
24, chemical name: 2,2-dimethyl-propiolic acid 8-(2,6-diethyl-4-methyl-phenyl)-9-oxygen-1,2,4,5-4 hydrogen-9H-pyrazoles [1,2-d] [Isosorbide-5-Nitrae, 5] oxygen phenodiazine Zhuo-7-base ester, azoles quinoline grass ester is acetyl-CoA carboxylase inhibitor class weed killer herbicide, and medicine can be absorbed by grass cutting blade, then conducts to meristematic tissue, the lipid that suppresses somatoblast is synthetic, causes weeds death.After general dispenser, 48 hours susceptible weeds stop growing, and in 1～2 week, grass cutting blade starts jaundice, and in 3～4 weeks, weeds are thoroughly dead.The reaction velocity that after dispenser, weeds are injured is relevant with weather conditions, weeds kind, growth conditions etc.This medicine is safe to barley.(low temperature or high humidity) dispenser under the bad climate condition, temporary transient chlorosis symptom may appear in barley leaves, does not grow and ultimate output but do not affect its normal growth.Medicine is fast in degraded in soil, seldom by root absorption, only has very low soil activation, on succession crop without impact.Resistance of rainwater washing against, after dispenser, 1 hour chance rain does not affect herbicidal effect substantially.
In recent years, people are frequent to be used and has concurrently to the safety of useful crop with to the so-called selective herbicide of the herbicidal effect of undesirable plant, even but have the weed killer herbicide of high selectivity, because of various conditions such as the kind of meteorological condition, soil condition, crop, chemicals treatment periods, sometimes also produce poisoning in use.People are studying the use of the various poisoning palliatives of the such state of affairs of not expecting of reply.At present, China also comparatively payes attention to aspect the mixed research of weed killer herbicide, is widely regarded as one of important measures of rationally use of weed killer herbicide, has worked out a series of Herbicidal compositions, has obtained greater advance.
My company also is devoted to the research and development of Herbicidal compositions.At present, about beflubutamid, have no report to the relevant composite product of azoles quinoline grass ester.
Summary of the invention
The purpose of this invention is to provide a kind of Herbicidal combinations that contains beflubutamid of preventing and treating weeds of wheat.
Technical scheme of the present invention is:
The Herbicidal combinations of a kind of containing beflubutamid and azoles quinoline grass ester, it is characterized in that: Herbicidal combinations contains beflubutamid 1～70%, azoles quinoline grass ester 1～50%, auxiliary agent and excipient surplus.
The Herbicidal combinations of described containing beflubutamid and azoles quinoline grass ester is characterized in that: in Herbicidal combinations, contain beflubutamid 5～50%, azoles quinoline grass ester 2～30%, auxiliary agent and excipient surplus.
The Herbicidal combinations of described containing beflubutamid and azoles quinoline grass ester is characterized in that: in Herbicidal combinations, contain beflubutamid 10～40%, azoles quinoline grass ester 5～20%, auxiliary agent and excipient surplus.
The Herbicidal combinations of described containing beflubutamid and azoles quinoline grass ester, it is characterized in that: the formulation of Herbicidal combinations is selected from: wetting powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, aqueous emulsion.
Described auxiliary agent and excipients comprise: dispersant, wetting agent, disintegrant, emulsifier, solvent, antifreeze, defoamer, thickener, filler, deionized water.
The Herbicidal combinations of described containing beflubutamid and azoles quinoline grass ester is characterized in that: while making wetting powder, comprise following constituent content: beflubutamid 1～70%, azoles quinoline grass ester 1～50%, dispersant 5～10%, wetting agent 2～10%, filler 8～91%.
Beflubutamid, azoles quinoline grass ester, dispersant, wetting agent, filler are mixed, mix in mixed cylinder, mix again after airslide disintegrating mill is pulverized, namely can be made into beflubutamid azoles quinoline grass ester wetting powder product.
The Herbicidal combinations of described containing beflubutamid and azoles quinoline grass ester weed killer herbicide is characterized in that: when composition is made water dispersible granules, comprise following constituent content: beflubutamid 1～70%, azoles quinoline grass ester 1～50%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, filler 10～93%.
Beflubutamid, azoles quinoline grass ester, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needed through air-flow crushing together, obtain the materials of granulating.By item quantitatively send in the fluidized bed granulation dryer through granulation and drying after, make beflubutamid azoles quinoline grass ester water dispersible granules product.
The Herbicidal combinations of described containing beflubutamid and azoles quinoline grass ester is characterized in that: when composition is made suspending agent, comprise following constituent content: beflubutamid 1～50%, azoles quinoline grass ester 1～40%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%, emulsifier 0.5%～5%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze, emulsifier in above-mentioned formulation material are mixed through high speed shear, add beflubutamid, azoles quinoline grass ester ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make beflubutamid azoles quinoline grass ester suspending agent product.
The Herbicidal combinations of described containing beflubutamid and azoles quinoline grass ester, it is characterized in that: when composition is made suspension emulsion, comprise following constituent content: beflubutamid 1～50%, azoles quinoline grass ester 1～40%, emulsifier 2～12%, dispersant 2～10%, defoamer 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, deionized water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in above-mentioned formulation material are mixed through high speed shear, add the former medicine of beflubutamid, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the beflubutamid suspending agent, then by the former medicine of azoles quinoline grass ester, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make beflubutamid azoles quinoline grass ester suspension emulsion product.
The Herbicidal combinations of described containing beflubutamid and azoles quinoline grass ester is characterized in that: comprise while making microemulsion: beflubutamid 1～50%, azoles quinoline grass ester 1～40%, solvent 3～30%, emulsifier 3～15%, antifreeze 1～4%, defoamer 0.01～1%, thickener 0.2～2%, deionized water add to 100%.
Former medicine is dissolved in the reactor that solvent and cosolvent are housed; After anion emulsifier, nonionic emulsifier and stabilizing agent, antifreeze, water being joined in the reactor that above-mentioned solution is housed, give strong the mixing and homogenize, finally obtain the as clear as crystal beflubutamid azoles quinoline grass ester microemulsion product of outward appearance.
The Herbicidal combinations of described containing beflubutamid and azoles quinoline grass ester comprises while it is characterized in that making aqueous emulsion: beflubutamid 1～50%, azoles quinoline grass ester 1～40%, solvent 3～30%, emulsifier 1～8%, antifreeze 1～4%, defoamer 0.01～1%, thickener 0.2～2%, deionized water add to 100%.
Beflubutamid in formula, azoles quinoline grass ester, solvent, emulsifier are added together, make to be dissolved into even oil phase; Water, antifreeze, defoamer, thickener are mixed, become the homogeneous water; Under high-speed stirred, water is added to oil phase or oil phase is added to water, after good dispersion, make beflubutamid azoles quinoline grass ester aqueous emulsion product.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the alkylaryl APEO, aliphatic alcohol polyethenoxy base ether, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, one or more during the ester polyoxyethylene is phonetic.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, tea are withered, one or more in silkworm excrement, soapberry powder.
Described disintegrant is selected from: one or more in sodium bicarbonate, sodium carbonate, bentonite, urea, ammonium sulfate, glucose, aluminium chloride.
Described solvent is selected from: DMF, cyclohexanone, methyl alcohol, ethanol, 3-methyl cyclohexanol ketenes, NOP, N-pyrrolidones, propyl alcohol, butanols, ethylene glycol, diethylene glycol, ethylene glycol monomethyl ether, butyl ether, ethyl acetate, vegetable oil, acetonitrile.
Described emulsifier is selected from: agriculture breast 500
#(alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600
#Phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, agriculture breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), agriculture breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), peaceful breast 36
#(phenethyl fluosite polyoxy ethyl ether), agriculture breast 1600
#(phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), agriculture breast 33
#(alkylaryl polyoxyethylene polyoxypropylene ether), agriculture breast 34
#One or more in (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), AEO series (fatty alcohol-polyoxyethylene ether).
Described antifreeze is selected from: one or more in glycerine, ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20One or more in saturated fat acids (as capric acid) and acid amides, silicone oil, silicone compound.
Described thickener is selected from: xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol, gelatin, melon glue, gum Arabic, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin,, one or more in PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Herbicidal combinations of the present invention compared with prior art, produces following beneficial effect:
Herbicide mixture is one of important measures in the weeds comprehensive regulation, by the mixed of weed killer herbicide, can enlarge herbicidal spectrum, improve herbicidal effect, extend the optimum period for applying fertilizer, reduce poisoning, reduce residual activity, delay the drug-fast generation of weed killer herbicide and development, to wheat weeds such as wheat straw, amur foxtail, Alopecurus, hard grass, the Wang grass, the caput grass, Veronica, broadcast the ma wormwood artemisia, green foxtail, clearvers, wild oat, benbie, field viola, lamb's-quarters, shepherd's purse, corn spurrey, puncture, amaranth, conical silene herb, dayflower, black nightshade, Siberian cocklebur, salsola collina, corn gromwell, field bindweed, the common weeds such as corn-bind are remarkably productive.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Embodiment
Below in conjunction with embodiment to further instruction of the present invention.
Implementation of an application example one:
Beflubutamid and azoles quinoline grass ester are mixed to the active determination test report of weeds of wheat
Test objective: measured beflubutamid and azoles quinoline grass ester and different blended combo thereof and close the herbicidal effect to clearvers under the greenhouse pot culture condition, and estimated its synergy, for formulation development and the agriculture chemical registration field control effectiveness test of Mixed Pharmacy provides scientific basis.
For trying target: clearvers (Rubiaceae Galium).
Test medicine: beflubutamid (beflubufamid) 97% former medicine, azoles quinoline grass ester (pinoxaden) 95% former medicine, agricultural chemicals Co., Ltd of U.S. nation provides by Shaanxi.
The medicament configuration:
Beflubutamid solution: accurately take the former medicine of 0.0445g97% beflubutamid, dissolve with 1mLDMF, add the clear water 400mL that contains the 0.1%TWEEN80 emulsifier, stir, be configured to beflubutamid 170g (a.i./hm
2) solution, then be diluted to 115g (a.i./hm with clear water
2), 75g (a.i./hm
2) concentration is standby.
Azoles quinoline grass ester solution: accurately take the former medicine of 0.01204g95% azoles quinoline grass ester, dissolve with 1mLDMF, add the clear water 400mL that contains the 0.1%TWEEN80 emulsifier, stir, be configured to azoles quinoline grass ester 45g (a.i./hm
2) solution, then be diluted to 35g (a.i./hm with clear water
2), 20g (a.i./hm
2) concentration is standby.
Blank solution: 1mLDMF adds the water of 400mL 0.1%TWEEN80 emulsifier.
Test method: adopt potted plant cauline leaf facture (NY/T 1155.4-2006): at the in-built quantitative soil of the polypots of high 6cm, diameter 9cm, will be for 15～20 sowings of examination target weed seed in polypots, after covering the fine earth that 0.5～1cm is thick, be placed on cultivation in greenhouse, treat that weeds grew to for 2～5 leaf phases and carry out cauline leaf spraying processing, every alms bowl spraying liquid 1mL, every processing repeats 4 times, and establishes the contrast that is treated to that does not contain medicament.After processing, the examination material is placed in the greenhouse in and cultivates, the growing state of routine observation target weeds, and be injured symptom and growth inhibition situation of range estimation target after 15d, and claim acrial part fresh weight or strain fresh weight, with the toxicity action of form fresh weight inhibiting rate evaluation medicament to the target weeds.
Investigation method:
Range estimation target be injured symptom and growth inhibition situation are processed after 15d in test, and claim to calculate fresh weight inhibiting rate (%) by the acrial part fresh weight.
The synergy evaluation method:
According to the Gowing method, estimate weed killer herbicide mode of application (NY/T 1155.7-2006), its formula is as follows:
E
0＝X+Y-XY/100
In formula, X is beflubutamid fresh weight inhibiting rate to target weeds when alone with certain dosage; Y is azoles quinoline grass ester fresh weight inhibiting rate to target weeds when alone with certain dosage; E
0During for two kinds of pharmacy mix of beflubutamid and azoles quinoline grass ester to the theoretical value of target weeds fresh weight inhibiting rate; When E is two kinds of pharmacy mix of beflubutamid and azoles quinoline grass ester to the measured value of target weeds fresh weight inhibiting rate.
Evaluation criterion: work as E-E
0In the time of>10%, be expressed as synergistic effect, as-10%≤E-E
0In the time of≤10%, be expressed as summation action, work as E-E
0In the time of<-10%, be expressed as antagonism.
Table 1 beflubutamid and azoles quinoline grass ester and the toxicity test result of combination to clearvers that be mixed thereof
Table 1 beflubutamid and azoles quinoline grass ester and the toxicity test result of combination to clearvers that be mixed thereof
Evaluating drug effect: beflubutamid and azoles quinoline grass ester and the composition that is mixed thereof to the herbicidal effect measurement result of clearvers in Table 1.Visible, beflubutamid and azoles quinoline grass ester shows synergistic effect to clearvers, its E-E with 75+20,75+35,75+45,115+20,115+35,115+45,170+20,170+35, the 170+45 composition that is mixed
0Value is greater than respectively 10%.
Application Example two: beflubutamid and the relevant composite product embodiments of azoles quinoline grass ester (following content is folding hundred percentage compositions).
Embodiment 140% beflubutamid azoles quinoline grass ester wetting powder
Beflubutamid 30%, azoles quinoline grass ester 10%, polycarboxylate 7%, neopelex 5%, attapulgite add to 100%, and mixture carries out air-flow crushing, make 40% beflubutamid azoles quinoline grass ester wetting powder.
Embodiment 260% beflubutamid azoles quinoline grass ester wetting powder
Beflubutamid 10%, azoles quinoline grass ester 50%, alkyl benzene sulfonate calcium salt 8%, Nekal BX 6%, bentonite add to 100%, and mixture carries out air-flow crushing, make 60% beflubutamid azoles quinoline grass ester wetting powder.
Embodiment 371% beflubutamid azoles quinoline grass ester wetting powder
Beflubutamid 70%, azoles quinoline grass ester 1%, lignosulfonates 7%, soapberry powder 5%, kaolin add to 100%, and mixture carries out air-flow crushing, make 71% beflubutamid azoles quinoline grass ester wetting powder.
Embodiment 4 45% beflubutamid azoles quinoline grass ester water dispersible granules
Beflubutamid 40%, azoles quinoline grass ester 5%, octylphenol polyethylene oxyethylene group ether sulfate 8%, lauryl sodium sulfate 6%, urea 2%, bentonite add to 100%, mix and make 45% beflubutamid azoles quinoline grass ester water dispersible granules.
Embodiment 5 65% beflubutamid azoles quinoline grass ester water dispersible granules
Beflubutamid 45%, azoles quinoline grass ester 20%, ester polyoxyethylene are phonetic 7%, wetting and penetrating agent F 5%, ammonium sulfate 2.8%, diatomite add to 100%, mix and make 65% beflubutamid azoles quinoline grass ester water dispersible granules.
Embodiment 6 80% beflubutamid azoles quinoline grass ester water dispersible granules
Beflubutamid 50%, azoles quinoline grass ester 30%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, silkworm excrement 4%, aluminium chloride 3%, white carbon add to 100%, mix and make 80% beflubutamid azoles quinoline grass ester water dispersible granules.
Embodiment 7 15% beflubutamid azoles quinoline grass ester suspending agents
Beflubutamid 10%, azoles quinoline grass ester 5%, alkylnaphthalene sulfonate 7%, sldium lauryl sulfate 5%, silicone oil 0.3%, diethylene glycol (DEG) 2.5%, xanthans 1.2%, deionized water adds to 100%, mixes and makes 15% beflubutamid azoles quinoline grass ester suspending agent.
Embodiment 8 32% beflubutamid azoles quinoline grass ester suspending agents
Beflubutamid 24%, azoles quinoline grass ester 8%, alkyl benzene sulfonate calcium salt 6%, wetting and penetrating agent F 5%, C
10～20Saturated fat acids 0.1%, hydroxyethylcellulose 0.9%, polyethylene glycol 2.2%, deionized water add to 100%, mix and make 32% beflubutamid azoles quinoline grass ester suspending agent.
Embodiment 9 50% beflubutamid azoles quinoline grass ester suspending agents
Beflubutamid 35%, azoles quinoline grass ester 15%, lignosulfonates 7%, spaonin powder 3%, silicone compound 0.4%, Magnesiumaluminumsilicate 0.7%, propane diols 2.5%, deionized water add to 100%, mix and make 50% beflubutamid azoles quinoline grass ester suspending agent.
Embodiment 10 11% beflubutamid azoles quinoline grass ester suspension emulsions
Beflubutamid 1%, azoles quinoline grass ester 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, sorbitan monostearate 8%, C
8～10Aliphatic alcohols 0.2%, methylcellulose 1.1%, triethylene glycol 2.8%, water adds to 100%, and the aforementioned formula material is mixed, and namely makes 11% beflubutamid azoles quinoline grass ester suspension emulsion.
Embodiment 11 45% beflubutamid azoles quinoline grass ester suspension emulsions
Beflubutamid 35%, azoles quinoline grass ester 10%, polycarboxylate 7%, Nekal BX 4%, alkyl biphenyl ether disulfonic acid magnesium salts 6%, silicone compound 0.3%, CMC 0.8%, triethylene glycol 2%, water add to 100%, mix and make 45% beflubutamid azoles quinoline grass ester suspension emulsion.
Embodiment 12 20% beflubutamid azoles quinoline grass ester aqueous emulsions
Beflubutamid 18%, azoles quinoline grass ester 2%, cyclohexanone 5%, ethylene glycol monomethyl ether 4%, polyoxyethylene nonylphenol ether phosphate 6%, ethylene glycol 2.3%, xanthans 1.3%, silicone 0.1%, water is mended to 100%, makes 20% beflubutamid azoles quinoline grass ester aqueous emulsion.
Embodiment 13 25% beflubutamid azoles quinoline grass ester aqueous emulsions
Beflubutamid 20%, azoles quinoline grass ester 5%, acetone 8%, ethyl acetate 3%, alkylaryl polyoxyethylene poly-oxygen propylene aether 7%, glycerine 2%, polyvinyl alcohol 1.2%, C
8～10Aliphatic alcohols 0.3%, water are mended to 100%, make 25% beflubutamid azoles quinoline grass ester aqueous emulsion.
Embodiment 14 10% beflubutamid azoles quinoline grass ester microemulsions
Beflubutamid 5%, azoles quinoline grass ester 5%, 3-methyl cyclohexanol ketenes 6%, vegetable oil 5%, polyethylene glycol 2.6%, sorbitan fatty acid ester APEO 6%, methylcellulose 0.9%, silicone oil 0.2%, water supply 100%, make 10% beflubutamid azoles quinoline grass ester microemulsion.
Embodiment 15 40% beflubutamid azoles quinoline grass ester microemulsions
Beflubutamid 30%, azoles quinoline grass ester 10%, N-pyrrolidones 7%, toluene 6%, triethylene glycol 3%, Magnesiumaluminumsilicate 0.8%, castor oil polyoxyethylene ether 8%, silicone oil 0.4%, water supply 100%, make 40% beflubutamid azoles quinoline grass ester microemulsion.
Application Example three: beflubutamid and azoles quinoline grass ester control weeds of wheat field control effectiveness test
The control medicament: the complex composition of beflubutamid and azoles quinoline grass ester, by the research and development of Shaanxi agricultural chemicals Co., Ltd of U.S. nation, produced;
Contrast medicament: 20% beflubutamid suspending agent (commercial);
5% azoles quinoline grass emulsifiable concentrate (commercial).
If artificial weeding and clear water control treatment.
Using method: every mu be watered 35 liters after evenly cauline leaf sparge in each community
Spraying time: next year wheat turn green, the weeds 2-5 leaf phase, carry out cauline leaf spraying 1 time.
Dispenser place: Fuyang City Linquan County, Anhui Province
Investigation method and drug effect are calculated
Investigation weeds object is: the weeds such as Veronica, green foxtail, clearvers, the fresh weight preventive effect of 10 days, 30 days preventive effects of the strain to weeds and 30 days after the investigation medicine.
The visual test medicament occurs without poisoning wheat.
Test results and analysis are respectively in Table 2.
The table 2 beflubutamid azoles quinoline grass ester control weeds of wheat test of pesticide effectiveness
Table 2 beflubutamid azoles quinoline grass ester and the built composition for preventing and controlling weeds of wheat test of pesticide effectiveness thereof
Ester is composite that the weeds such as wheat paddock Veronica, green foxtail, clearvers are had to good control efficiency for beflubutamid and azoles quinoline grass as shown in Table 2, preventive effect is better than the single dose preventive effect, with contrast medicament, artificial weeding, remarkable with respect to the rate of growth difference of clear water control treatment, and have quick-acting and lasting effect preferably, in this experimental drug scope, to wheat safety.
Application Example four: beflubutamid and azoles quinoline grass ester control weeds of wheat field control effectiveness test
The control medicament: the complex composition of beflubutamid and azoles quinoline grass ester, by the research and development of Shaanxi agricultural chemicals Co., Ltd of U.S. nation, produced;
Contrast medicament: 20% beflubutamid suspending agent (commercial);
5% azoles quinoline grass emulsifiable concentrate (commercial).
If artificial weeding and clear water control treatment.
Using method: every mu be watered 35 liters after evenly cauline leaf sparge in each community
Spraying time: after next year, wheat turned green, the weeds 2-5 leaf phase, carry out cauline leaf spraying 1 time.
Dispenser place: Weinan City Dengcheng County, Shaanxi Province
Investigation method and drug effect are calculated
Investigation weeds object is: the weeds such as clearvers, wild oat, amur foxtail, the fresh weight preventive effect of 10 days, 30 days preventive effects of the strain to weeds and 30 days after the investigation medicine.
The visual test medicament occurs without poisoning wheat.
Test results and analysis are respectively in Table 3.
Ester is composite that wheat paddock clearvers, wild oat, amur foxtail etc. are had to good control efficiency for beflubutamid and azoles quinoline grass as shown in Table 3, preventive effect is better than the single dose preventive effect, with contrast medicament, artificial weeding, remarkable with respect to the rate of growth difference of clear water control treatment, and have quick-acting and lasting effect preferably, in this experimental drug scope, to wheat safety.
Claims (4)
1. the Herbicidal combinations of a containing beflubutamid and azoles quinoline grass ester, it is characterized in that: Herbicidal combinations effective active composition is comprised of beflubutamid and azoles quinoline grass ester, wherein the content of beflubutamid is 10 ~ 40%, and the content of azoles quinoline grass ester is that weight ratio is 5 ~ 20%, the auxiliary agent surplus.
2. the Herbicidal combinations of containing beflubutamid according to claim 1 and azoles quinoline grass ester, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion or aqueous emulsion.
3. the Herbicidal combinations of containing beflubutamid according to claim 1 and azoles quinoline grass ester is for preventing and treating the application of wheat weeds.
4. application according to claim 3 is characterized in that: described wheat weeds is that wheat straw, amur foxtail, hard Cao, Wang grass, caput are careless, Veronica, broadcast ma wormwood artemisia, green foxtail, clearvers, wild oat, benbie, field viola, lamb's-quarters, shepherd's purse, corn spurrey, puncture, amaranth, conical silene herb, dayflower, black nightshade, Siberian cocklebur, salsola collina, corn gromwell, field bindweed or corn-bind.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101969127A CN102326565B (en) | 2011-07-14 | 2011-07-14 | Weeding composition containing beflubutamid and pinoxaden |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101969127A CN102326565B (en) | 2011-07-14 | 2011-07-14 | Weeding composition containing beflubutamid and pinoxaden |
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| Publication Number | Publication Date |
|---|---|
| CN102326565A CN102326565A (en) | 2012-01-25 |
| CN102326565B true CN102326565B (en) | 2013-11-27 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2011101969127A Expired - Fee Related CN102326565B (en) | 2011-07-14 | 2011-07-14 | Weeding composition containing beflubutamid and pinoxaden |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018119338A1 (en) | 2016-12-22 | 2018-06-28 | Fmc Corporation | Mixtures of beflubutamid or optically enriched forms thereof with a second herbicide |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105519531A (en) * | 2014-09-28 | 2016-04-27 | 南京华洲药业有限公司 | Clodinafop-propargyl and beflubutamid containing weeding composition and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0901753A1 (en) * | 1996-02-09 | 1999-03-17 | Ube Industries, Ltd. | Herbicidal composition |
| EP2514313A1 (en) * | 2007-08-27 | 2012-10-24 | Dow AgroSciences LLC | Synergistic herbicidal composition containing certain pyridine or pyrimidine carboxylic acids and certain cereal and rice herbicides |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0913587A2 (en) * | 2008-06-05 | 2015-08-25 | Basf Se | Composition, pesticidal agent, method for controlling phytopathogenic harmful funds, seed, use of one compound and another compound, and, composition. |
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2011
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0901753A1 (en) * | 1996-02-09 | 1999-03-17 | Ube Industries, Ltd. | Herbicidal composition |
| EP2514313A1 (en) * | 2007-08-27 | 2012-10-24 | Dow AgroSciences LLC | Synergistic herbicidal composition containing certain pyridine or pyrimidine carboxylic acids and certain cereal and rice herbicides |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018119338A1 (en) | 2016-12-22 | 2018-06-28 | Fmc Corporation | Mixtures of beflubutamid or optically enriched forms thereof with a second herbicide |
| US11950597B2 (en) | 2016-12-22 | 2024-04-09 | Fmc Corporation | Mixtures of beflubutamid or optically enriched forms thereof with a second herbicide |
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| Publication number | Publication date |
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| CN102326565A (en) | 2012-01-25 |
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