CN101999400A - Cyhalofop-butyl-containing weeding composition - Google Patents
Cyhalofop-butyl-containing weeding composition Download PDFInfo
- Publication number
- CN101999400A CN101999400A CN2010105773830A CN201010577383A CN101999400A CN 101999400 A CN101999400 A CN 101999400A CN 2010105773830 A CN2010105773830 A CN 2010105773830A CN 201010577383 A CN201010577383 A CN 201010577383A CN 101999400 A CN101999400 A CN 101999400A
- Authority
- CN
- China
- Prior art keywords
- butyl
- cyhalofop
- anilofos
- clomazone
- herbicidal combinations
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005502 Cyhalofop-butyl Substances 0.000 title claims abstract description 165
- TYIYMOAHACZAMQ-CQSZACIVSA-N Cyhalofop-butyl Chemical group C1=CC(O[C@H](C)C(=O)OCCCC)=CC=C1OC1=CC=C(C#N)C=C1F TYIYMOAHACZAMQ-CQSZACIVSA-N 0.000 title claims abstract description 129
- 239000000203 mixture Substances 0.000 title abstract description 45
- 238000009333 weeding Methods 0.000 title abstract description 7
- 239000005499 Clomazone Chemical group 0.000 claims abstract description 53
- 239000004480 active ingredient Substances 0.000 claims abstract description 42
- NXQDBZGWYSEGFL-UHFFFAOYSA-N Anilofos Chemical group COP(=S)(OC)SCC(=O)N(C(C)C)C1=CC=C(Cl)C=C1 NXQDBZGWYSEGFL-UHFFFAOYSA-N 0.000 claims abstract description 37
- KIEDNEWSYUYDSN-UHFFFAOYSA-N clomazone Chemical group O=C1C(C)(C)CON1CC1=CC=CC=C1Cl KIEDNEWSYUYDSN-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 20
- 239000000546 pharmaceutical excipient Substances 0.000 claims abstract description 19
- 230000002363 herbicidal effect Effects 0.000 claims description 75
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 claims description 59
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- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 description 1
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- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a cyhalofop-butyl-containing weeding composition, which is mainly characterized by comprising 1 to 60 percent of active ingredient A, namely cyhalofop-butyl, 1 to 60 percent of active ingredient B, auxiliary agents and other excipients, wherein the active ingredient B is anilofos, oxaziclomefone or clomazone. The composition can be prepared into wettable powder, water dispersible granules, a suspending agent, suspension emulsion, microemulsion and aqueous emulsion. The weeding composition is used for preventing and controlling annual gramineous weeds in a paddy field.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of Herbicidal combinations that contains effective constituents A cyhalofop-butyl and active ingredient B, be used to prevent and treat paddy field barnyard grass grass, moleplant seed, grassy weed.
Background technology
The direction of pesticide developing was to embody efficient, low toxicity, low-residual and pollution-free in recent years.Be embodied in pursuit " three height ", promptly (1) is safe, and this not only requires toxicity low, and is residual low, and nuisanceless; (2) biologically active height; (3) selectivity height.Therefore continue to improve the performance of present Pesticidal products, reach efficient, low toxicity, free of contamination requirement.So, select the agricultural chemicals of composite mixture just to become current first-selection and a kind of valid approach, be that the agricultural chemicals of performance complement obtains best synergistic effect by the proportioning of adjusting different agricultural chemicals.
Cyhalofop-butyl (cyhalofop-butyl), molecular formula: C
20H
20FNO
4, relative molecular mass 357.4.It is the aryloxy carboxylic acid weed killer herbicide of LG-DOW agricultural science company exploitation.Seem unique kind that paddy rice is had tight security in the fragrant phenoxy propionic acid class weed killer herbicide, inhale conductivity in having, blade and the leaf sheath carried by plant absorb, the phloem conduction accumulates the meristem zone in plant corpus, always acetyl-CoA carboxylase, fatty acid is synthesized to be stopped, the division of cell can not normally be carried out, and film system etc. contains ester structure and destroys, and causes plant death at last.In the paddy rice body, cyhalofop-butyl can be degraded to the diacid attitude to the acetyl-CoA carboxylase non-activity rapidly, and paddy rice is had safety highly, and degraded rapidly in soil and in the typical paddy field water either.Be mainly used in the control grassy weed, not only the barnyard grass natural plant height imitated, also can prevent and treat weeds such as moleplant seed, lady's-grass.
Anilofos (anilofos), molecular formula: C
13H
19ClNO
3PS, relative molecular mass 367.8 is weed killer herbicides of Sanofi-Aventis's exploitation.Anilofos belongs to cell division inhibitor, be interior suction conduction selective herbicide, medicament mainly in the young shoot by plant and the ground stem absorb, suppress cell division and elongation, weeds are subjected to grow behind the medicine and stop, blade is dark green, sometimes decolouring, blade shortens and thick, very easily fractures, young leaves is difficult for extracting out, and whole at last strain is withered.
Oxazine humulone (oxaziclomefone), molecular formula: C
20H
19Cl
2NO
2, relative molecular mass 376.3 is the weed killer herbicides by Sanofi-Aventis's exploitation.Clomazone is mainly used in broad leaved weed, sedge weed and Echinochloa weeds, to rice safety.
Clomazone (clomazone), molecular formula: C
12H
14ClNO
2, relative molecular mass 239.7 also is clomazone, is the weed killer herbicide of FMC Corp.'s exploitation.Clomazone is the carotenoid biosynthesis inhibitor, and is synthetic by suppressing pentylene compound, hinders carrot and chlorophyllous biosynthesis, absorbs, upwards dredges, and diffuse to leaf portion through xylem through plant roots, young shoot.Though sensitive plant can be unearthed in rudiment, owing to do not have pigment to form Bai Miao, and dead in a short time.
The chemical composition of each weed killer herbicide, structure and physicochemical property all are distinguishing.Therefore, they kill careless ability and scope is also different.It is narrower that some weed killer herbicide kills the grass spectrum, but have one's own knack, and can eradicate the weeds that are difficult to eliminate with other weed killer herbicide.
Nineteen fifty-five has the people to report that Amrol can increase the prevent and kill off effect beginning of dalapon to the stone thatch, after, along with further developing of weed killer herbicide production and application, using with gradually between the weed killer herbicide grows up.China also comparatively payes attention to using with aspect the research of weed killer herbicide, is recognized extensively that to do be one of important measures of rationally using of weed killer herbicide, has worked out a series of Herbicidal compositions, has obtained bigger progress.
My company also is devoted to the research and development of Herbicidal compositions.At present, do not appear in the newspapers about the relevant composite product of cyhalofop-butyl with anilofos, clomazone Huo oxazine humulone.
Summary of the invention
The Herbicidal combinations that contains cyhalofop-butyl that the purpose of this invention is to provide a kind of paddy field weed control.
Technical scheme of the present invention is:
A kind of Herbicidal combinations that contains effective constituents A cyhalofop-butyl and active ingredient B, it is characterized in that: Herbicidal combinations contains effective constituents A cyhalofop-butyl 1～60%, active ingredient B1～60%, auxiliary agent and other excipient surpluses.
The described Herbicidal combinations that contains effective constituents A cyhalofop-butyl and active ingredient B, it is characterized in that: active ingredient B is selected from: anilofos, oxazine humulone, clomazone.
The described Herbicidal combinations that contains effective constituents A cyhalofop-butyl and active ingredient B, it is characterized in that: Herbicidal combinations contains effective constituents A cyhalofop-butyl 1～60%, anilofos 1～60%, auxiliary agent and excipient.
The described Herbicidal combinations that contains effective constituents A cyhalofop-butyl and active ingredient B, it is characterized in that: Herbicidal combinations contains effective constituents A cyhalofop-butyl 2～40%, anilofos 2～40%, auxiliary agent and excipient.
The described Herbicidal combinations that contains effective constituents A cyhalofop-butyl and active ingredient B, it is characterized in that: Herbicidal combinations contains cyhalofop-butyl 2～20%, anilofos 2～40%, auxiliary agent and excipient.
The described Herbicidal combinations that contains cyhalofop-butyl and anilofos is characterized in that: the formulation of Herbicidal combinations is selected from: wetting powder, aqueous emulsion, microemulsion, oil-suspending agent.
The described Herbicidal combinations that contains effective constituents A cyhalofop-butyl and active ingredient B is characterized in that: Herbicidal combinations contains effective constituents A cyhalofop-butyl 1～60% ， oxazine humulone 1～60%, auxiliary agent and excipient.
The described Herbicidal combinations that contains cyhalofop-butyl and active ingredient B is characterized in that: Herbicidal combinations contains cyhalofop-butyl 2～40% ， oxazine humulones 2～40%, auxiliary agent and excipient.
The described Herbicidal combinations that contains cyhalofop-butyl and active ingredient B is characterized in that: Herbicidal combinations contains cyhalofop-butyl 2～20% ， oxazine humulones 2～20%, auxiliary agent and excipient.
Describedly contain cyhalofop-butyl Yu the Herbicidal combinations of oxazine humulone is characterized in that: the formulation of Herbicidal combinations is selected from: wetting powder, water dispersible granules, oil-suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
The described Herbicidal combinations that contains effective constituents A cyhalofop-butyl and active ingredient B is characterized in that: Herbicidal combinations contains effective constituents A cyhalofop-butyl 1～60% ， clomazone 1～60%, auxiliary agent and excipient.
The described Herbicidal combinations that contains cyhalofop-butyl and active ingredient B is characterized in that: Herbicidal combinations contains cyhalofop-butyl 2～40% ， clomazone 2～40%, auxiliary agent and excipient.
The described Herbicidal combinations that contains cyhalofop-butyl and active ingredient B is characterized in that: Herbicidal combinations contains cyhalofop-butyl 2～20% ， clomazone 2～20%, auxiliary agent and excipient.
Describedly contain cyhalofop-butyl Yu the Herbicidal combinations of clomazone is characterized in that: the formulation of Herbicidal combinations is selected from: wetting powder, oil-suspending agent, aqueous emulsion, microemulsion.
Described auxiliary agent and excipients comprise: dispersant, wetting agent, disintegrant, emulsifier, solvent, antifreeze, defoamer, thickener, filler, deionized water.
The described Herbicidal combinations that contains cyhalofop-butyl and active ingredient B is characterized in that: comprise following constituent content when making wetting powder: effective constituents A cyhalofop-butyl 1～60%, active ingredient B1～60%, dispersant 5～10%, wetting agent 2～10%, filler 8～90%.
Effective constituents A cyhalofop-butyl, active ingredient B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into cyhalofop-butyl active ingredient B wetting powder product.
The described Herbicidal combinations that contains cyhalofop-butyl and active ingredient B is characterized in that: comprise following constituent content when composition is made water dispersible granules: cyhalofop-butyl 1～60%, active ingredient B 1～60%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, filler 10～90%.
Cyhalofop-butyl, active ingredient B, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes cyhalofop-butyl active ingredient B water dispersible granules product.
The described Herbicidal combinations that contains cyhalofop-butyl and active ingredient B is characterized in that: comprise following constituent content when composition is made oil-suspending agent: cyhalofop-butyl 1～40%, active ingredient B 1～40%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, emulsifier 0.5%～8%, appearance agent add to 100%.
The former medicine of effective constituents A, thickener, defoamer, solvent are joined in the sand milling axe after metering, adding emulsifier, after being ground to certain fineness, material is inputed to storage tank, put after metering to the average blender, with the former medicine of quantitative active ingredient B, and emulsifier and certain amount of solvent join in the average blender, after homogenizer disperseed mixing, sample analysis was after product is qualified, the packing warehouse-in makes cyhalofop-butyl active ingredient B oil-suspending agent product.
The described Herbicidal combinations that contains cyhalofop-butyl and active ingredient B, it is characterized in that: comprise following constituent content when composition is made suspension emulsion: cyhalofop-butyl 1～40%, active ingredient B1～40%, emulsifier 2～12%, dispersant 2～10%, defoamer 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, deionized water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear, add the former medicine of active components A, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the cyhalofop-butyl suspending agent, then with the former medicine of active component B, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.
The described Herbicidal combinations that contains cyhalofop-butyl and active ingredient B is characterized in that: comprise when making microemulsion: cyhalofop-butyl 1～40%, active ingredient B 1～40%, solvent 3～30%, emulsifier 3～15%, antifreeze 1～4%, defoamer 0.01～1%, thickener 0.2～2%, deionized water add to 100%.
Former medicine is dissolved in the reactor that solvent and cosolvent are housed; Mix strongly after joining anion emulsifier, nonionic emulsifier and stabilizing agent, antifreeze, water in the reactor that above-mentioned solution is housed and homogenize, obtain the as clear as crystal cyhalofop-butyl active ingredient B microemulsion of outward appearance at last.
The described Herbicidal combinations that contains cyhalofop-butyl and active ingredient B comprises when it is characterized in that making aqueous emulsion: cyhalofop-butyl 1～40%, active ingredient B1～40%, solvent 3～30%, emulsifier 1～8%, antifreeze 1～4%, defoamer 0.01～1%, thickener 0.2～2%, deionized water add to 100%.
Cyhalofop-butyl, active ingredient B, solvent, emulsifier in the prescription are added together, make and be dissolved into even oil phase; Water, antifreeze, defoamer, thickener are mixed, become the homogeneous water; Under high-speed stirred, water is added oil phase or oil phase is added water, make cyhalofop-butyl active ingredient B aqueous emulsion product behind the good dispersion.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, during the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, the glucose.
Described solvent is selected from: N, dinethylformamide, cyclohexanone, methyl alcohol, ethanol, 3-methyl cyclohexanol ketenes, N-octylpyrrolidone, N-pyrrolidones, propyl alcohol, butanols, ethylene glycol, diethylene glycol, ethylene glycol monomethyl ether, butyl ether, ethyl acetate, vegetable oil, acetonitrile.
Described emulsifier is selected from: farming breast 500
#(alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600
#Phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), farming breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), peaceful breast 36
#(phenethyl fluosite polyoxy ethyl ether), farming breast 1600
#(phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), farming breast 33
#(alkylaryl polyoxyethylene polyoxypropylene ether), farming breast 34
#In (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), the AEO series (the pure APEO of fat) one or more.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (as capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Herbicidal combinations of the present invention compared with prior art produces following beneficial effect:
So herbicide mixture is one of important measures in the weeds comprehensive regulation, can enlarge herbicidal spectrum, improve herbicidal effect, prolong the optimum period for applying fertilizer, reduce poisoning, reduce residual activity, delay drug-fast generation of weed killer herbicide and development by using with of weed killer herbicide, remarkably productive to paddy rice barnyard grass grass, moleplant seed, grassy weed.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention.
Implementation of an application example one:
Cyhalofop-butyl and active ingredient B are mixed to the active determination test report of rice weed
Test objective: under the appearance condition of pot, measured cyhalofop-butyl and active ingredient B and different blended combo thereof and closed herbicidal effect, and estimated its synergy, for the formulation development and the agriculture chemical registration field control effectiveness test of Mixed Pharmacy provides scientific basis to the barnyard grass grass.
For trying target: barnyard grass (Echinochloa crusgalli L.).
Test medicine: cyhalofop-butyl (cyhalofop-butyl) 97.4% former medicine; anilofos (anilofos) 90% former medicine oxazine humulone (oxaziclomefone) 96.5% former medicine ， clomazone (clomazone) 95% former medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
The medicament configuration:
Cyhalofop-butyl solution: accurately take by weighing the former medicine of 0.0195g97.4% cyhalofop-butyl, with the 0.2mLDMF dissolving, add the clear water 400mL that contains the 0.1%TWEEN80 emulsifier, stir, be configured to cyhalofop-butyl 75g a.i./ha solution, again with clear water be diluted to 45,15a.i./ha concentration is standby.
Anilofos solution: accurately take by weighing the former medicine of 0.064g90% anilofos, with the 0.2mLDMF dissolving, add the clear water 400mL that contains the 0.1%TWEEN80 emulsifier, stir, be configured to anilofos 225g a.i./ha solution, again with clear water be diluted to 150,75a.i./ha concentration is standby.
Oxazine humulone solution: accurately take by weighing the former medicine of 0.0132g96.5% oxazine humulone, with the 0.2mLDMF dissolving, add the clear water 400mL that contains the 0.1%TWEEN80 emulsifier, stir, Pei Zhi Cheng oxazine humulone 50g a.i./ha solution, again with clear water be diluted to 30,10a.i./ha concentration is standby.
Clomazone solution: accurately take by weighing the former medicine of 0.020g95% clomazone, with the 0.2mLDMF dissolving, add the clear water 400mL that contains the 0.1%TWEEN80 emulsifier, stir, be configured to clomazone 75g a.i./ha solution, again with clear water be diluted to 40,15a.i./ha concentration is standby.
Blank solution: 0.2mLDMF adds the water of 80mL 0.1%TWEEN80 emulsifier.
Test method: adopt potted plant cauline leaf facture (NY/T 1155.4-2006): the amount of setting soil in the polypots of high 6cm, diameter 9cm, will be in polypots for 15～20 sowings of examination target weed seed, be placed on cultivation in the greenhouse after covering the thick fine earth of 0.5～1cm, treat that weeds grew to for 2～4 leaf phases and carry out cauline leaf spraying processing, every alms bowl spraying liquid 1mL, every processing repeats 4 times, and establishes the contrast that is treated to that does not contain medicament.Handle the back examination and just place in the greenhouse in and cultivate, the growing state of routine observation target weeds, be injured symptom and growth inhibition situation of range estimation target behind the 15d, and title acrial part fresh weight or strain fresh weight are with the toxicity action of form fresh weight inhibiting rate evaluation medicament to the target weeds.
Investigation method:
Range estimation target be injured symptom and growth inhibition situation are handled behind the 15d in test, and claim to calculate fresh weight inhibiting rate (%) by the acrial part fresh weight.
The synergy evaluation method:
Estimate weed killer herbicide synergy mode (NY/T 1155.7-2006) according to the Gowing method, its formula is as follows:
E
0＝X+Y-XY/100
In the formula, X is that cyhalofop-butyl is with the fresh weight inhibiting rate of certain dosage list time spent to the target weeds; Y is that anilofos is with the fresh weight inhibiting rate of certain dosage list time spent to the target weeds; E
0During for cyhalofop-butyl and two kinds of pharmacy mix of anilofos to the theoretical value of target weeds fresh weight inhibiting rate; When E is cyhalofop-butyl and two kinds of pharmacy mix of anilofos to the measured value of target weeds fresh weight inhibiting rate.
Evaluation criterion: work as E-E
0Be expressed as synergistic effect at＞10% o'clock, as 10%≤E-E
0Be expressed as summation action, and worked as E-E in≤10% o'clock
0Be expressed as antagonism at＜-10% o'clock.
Table 1 cyhalofop-butyl and anilofos and the toxicity test result of combination that be mixed thereof to barnyard grass
Table 1 cyhalofop-butyl and anilofos and the toxicity test result of combination that be mixed thereof to barnyard grass
Evaluating drug effect: cyhalofop-butyl and anilofos and the composition that is mixed thereof see Table 1 to the herbicidal effect measurement result of barnyard grass.As seen, cyhalofop-butyl and anilofos show synergistic effect to the barnyard grass grass, its E-E with 15+75,15+150,15+225,45+75,45+150,45+225,75+75, the 75+150 composition that is mixed
0Value is respectively 17.34,14.77,11.08,18.43,17.02,12.15,16.16,11.63, with the 75+225 composition that is mixed the barnyard grass grass is shown addition, and is wherein best to the effect of barnyard grass with the composition that is mixed of 45+75, its E-E
0Value is 18.43.
Table 2 cyhalofop-butyl is Yu the oxazine humulone and the toxicity test result of combination to barnyard grass that be mixed thereof
Table 2 cyhalofop-butyl is Yu the oxazine humulone and the toxicity test result of combination to barnyard grass that be mixed thereof
Evaluating drug effect: cyhalofop-butyl is Yu the oxazine humulone and the composition that is mixed thereof see Table 2 to the herbicidal effect measurement result of barnyard grass.As seen, cyhalofop-butyl is with the oxazine humulone shows synergistic effect to the barnyard grass grass, its E-E with 15+10,15+30,15+50,15+10,45+30,45+50,45+10, the 45+30 composition that is mixed
0Value shows addition with the 75+50 composition that is mixed to the barnyard grass grass respectively greater than 10%, and is wherein best to the effect of barnyard grass with the composition that is mixed of 15+30, its E-E
0Value is 19.00.
Table 3 cyhalofop-butyl is Yu the clomazone and the toxicity test result of combination to barnyard grass that be mixed thereof
Table 3 cyhalofop-butyl is Yu the clomazone and the toxicity test result of combination to barnyard grass that be mixed thereof
Evaluating drug effect: cyhalofop-butyl is Yu the clomazone and the composition that is mixed thereof see Table 3 to the herbicidal effect measurement result of barnyard grass.As seen, cyhalofop-butyl is with clomazone shows synergistic effect to the barnyard grass grass, its E-E with 15+15,15+45,15+75,45+15,45+45,45+75,75+15, the 75+45 composition that is mixed
0Value shows addition with the 75+75 composition that is mixed to the barnyard grass grass respectively greater than 10%, and is wherein best to the effect of barnyard grass with the composition that is mixed of 45+45, its E-E
0Value is 18.15.
Application Example two: the cyhalofop-butyl composite product embodiments (following content be folding hundred percentage compositions) of being correlated with.
Embodiment 170% cyhalofop-butyl anilofos wetting powder
Cyhalofop-butyl 15%, anilofos 55%, polycarboxylate 4%, alkyl benzene sulfonate calcium salt 2%, soapberry powder 5%, bentonite add to 100%, and mixture carries out comminution by gas stream, make 70% cyhalofop-butyl anilofos wetting powder.
Embodiment 280% cyhalofop-butyl anilofos wetting powder
Cyhalofop-butyl 20%, anilofos 60%, polycarboxylate 5%, lauryl sodium sulfate 3%, spaonin powder 2%, kaolin add to 100%, and mixture carries out comminution by gas stream, make 80% cyhalofop-butyl anilofos wetting powder.
Embodiment 342% cyhalofop-butyl anilofos aqueous emulsion
Cyhalofop-butyl 2%, anilofos 40%, 3-methyl cyclohexanol ketenes 8%, vegetable oil 12%, alkyl benzene calcium sulfonate 4%, phenyl phenol polyoxy ethyl ether 2%, ethylene glycol 3%, silicone defoamer 0.05%, xanthans 0.8%, deionized water add to 100%, the mixed 42% cyhalofop-butyl anilofos aqueous emulsion that gets.
Embodiment 425% cyhalofop-butyl anilofos aqueous emulsion
Cyhalofop-butyl 5%, anilofos 20%, vegetable oil 3%, ethylene glycol 15%, benzyl dimethyl phenol polyoxy ethyl ether 3%, alkylaryl polyoxyethylene poly-oxygen propylene aether 3%, polyvinyl alcohol 2%, C8～10 aliphatic alcohols 0.1%, deionized water add to 100%, the mixed 25% cyhalofop-butyl anilofos aqueous emulsion that gets.
Embodiment 540% cyhalofop-butyl anilofos microemulsion
Cyhalofop-butyl 20%, anilofos 20%, vegetable oil 15%, N-pyrrolidones 8%, phenethyl phenol polyoxy ethyl polypropylene-base ether 10%, silicone compound 0.1%, polyethylene glycol 0.5%, ethylene glycol 3%, deionized water add to 100%, the mixed 40% cyhalofop-butyl anilofos microemulsion that gets.
Embodiment 615% cyhalofop-butyl anilofos microemulsion
Cyhalofop-butyl 1%, anilofos 14%, N, dinethylformamide 14%, phenyl phenol polyoxy ethyl ether 3%, sorbitan monostearate 4%, carboxymethyl cellulose 0.3%, glycerine 2%, deionized water add to 100%, the mixed 15% cyhalofop-butyl anilofos microemulsion that gets.
Embodiment 750% cyhalofop-butyl anilofos oil-suspending agent
Cyhalofop-butyl 18%, anilofos 32%, polycarboxylate 5%, lignosulfonates 4%, silicone defoamer 0.3%, aluminium-magnesium silicate 1%, phenyl phenol polyoxy ethyl ether phosphate 5%, vegetable oil add to 100%, the mixed 50% cyhalofop-butyl anilofos oil-suspending agent that gets.
Embodiment 828% cyhalofop-butyl anilofos oil-suspending agent
Cyhalofop-butyl 8%, anilofos 20%, SDS 10%, draw back powder 5%, silicone oil 0.5%, methylcellulose 0.8%, vegetable oil and add to 100%, make 28% cyhalofop-butyl anilofos oil-suspending agent.
Embodiment 980% cyanogen fluorine Cao Zhi oxazine humulone wetting powder
Cyhalofop-butyl 60%, oxazine humulone 20%, neopelex 10%, bay alcohol radical sodium sulphate 5%, kaolin add to 100%, promptly make 80% cyanogen fluorine grass ester oxazine humulone wetting powder.
Embodiment 1040% cyanogen fluorine Cao Zhi oxazine humulone wetting powder
Cyhalofop-butyl 32%, oxazine humulone 8%, lignosulfonates 6%, tea are withered 4%, kaolin adds to 100%, and mixture carries out comminution by gas stream, makes 40% cyanogen fluorine Cao Zhi oxazine humulone wetting powder.
Embodiment 1180% cyanogen fluorine Cao Zhi oxazine humulone water dispersible granules
Cyhalofop-butyl 20%, oxazine humulone 60%, neopelex 5%, sodium lignin sulfonate 3%, citric acid 3%, polyvinyl alcohol 0.5%, kaolin add to 100%, make 80% cyanogen fluorine Cao Zhi oxazine humulone water dispersible granules.
Embodiment 1250% cyanogen fluorine Cao Zhi oxazine humulone water dispersible granules
Cyhalofop-butyl 30%, oxazine humulone 20%, SDS 10%, sodium lignin sulfonate 2%, ammonium sulfate 4%, polyethylene glycol 0.8%, white carbon add to 100%, make 50% cyanogen fluorine Cao Zhi oxazine humulone water dispersible granules.
Embodiment 1350% cyanogen fluorine Cao Zhi oxazine humulone oil-suspending agent
Cyhalofop-butyl 40%, oxazine humulone 10%, alkyl benzene sulfonate calcium salt 4%, sodium lignin sulfonate 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 4%, silicone oil 0.1%, xanthans 0.3%, vegetable oil adds to 100%, the mixed 50% cyanogen fluorine Cao Zhi oxazine humulone oil-suspending agent that gets.
Embodiment 1430% cyanogen fluorine Cao Zhi oxazine humulone oil-suspending agent
Cyhalofop-butyl 5%, oxazine humulone 25%, polycarboxylate 4%, soapberry powder 5%, silicone compound 0.1%, hydroxyethylcellulose 0.1%, alkyl benzene calcium sulfonate 3%, polyoxyethylene nonylphenol ether 2%, vegetable oil add to 100%, the mixed 30% cyanogen fluorine Cao Zhi oxazine humulone oil-suspending agent that gets.
Embodiment 1548% cyanogen fluorine Cao Zhi oxazine humulone suspension emulsion
Cyhalofop-butyl 10% oxazine humulone 38%, octylphenol polyethylene oxyethylene group ether sulfate 6%, polyoxyethylene carboxylate 5%, sorbitan monostearate 3%, xanthans 2%, propane diols 8%, water adds to 100%, the aforementioned formula material is mixed, promptly make 48% cyanogen fluorine Cao Zhi oxazine humulone suspension emulsion.
Embodiment 1618% cyanogen fluorine Cao Zhi oxazine humulone suspension emulsion
Cyhalofop-butyl 12%, oxazine humulone 6%, alkylbenzenesulfonate 3%, draw back powder 2%, polyvinyl alcohol 2%, water and add to 100% sodium lignin sulfonate 5%, mixed 18% cyanogen fluorine Cao Zhi oxazine humulone suspension emulsion.
Embodiment 1742% cyanogen fluorine Cao Zhi oxazine humulone aqueous emulsion
Cyhalofop-butyl 40%, oxazine humulone 2%, vegetable oil 18%, ethylene glycol 9%, phenyl phenol polyoxy ethyl ether 6%, glycerine 3%, CMC 0.1%, C10-20 saturated fat acid compounds 0.1%, water is mended to 100%, makes 42% cyanogen fluorine Cao Zhi oxazine humulone aqueous emulsion.Embodiment 1811% cyanogen fluorine Cao Zhi oxazine humulone aqueous emulsion
Cyhalofop-butyl 10% ， oxazine humulone 1%, ethylene glycol monomethyl ether 10%, methyl alcohol 8%, 602#8%, butanols 4%, ethylene glycol 9%, xanthans 0.2%, C8-10 aliphatic alcohols compound 0.5%, water is mended to 100%, makes 11% cyanogen fluorine Cao Zhi oxazine humulone aqueous emulsion.
Embodiment 1943% cyanogen fluorine Cao Zhi oxazine humulone microemulsion
Cyhalofop-butyl 35% ， oxazine humulone 8%, cyclohexanone 25%, N-pyrrolidones 4%, phenyl phenol polyoxy ethyl ether phosphate 6%, alkylphenol-formaldehyde resin polyoxy ethyl ether 4%, glycerine 3%, water supplies 100%, makes 43% cyanogen fluorine Cao Zhi oxazine humulone microemulsion.
Embodiment 2020% cyanogen fluorine Cao Zhi oxazine humulone microemulsion
Cyhalofop-butyl 15% oxazine humulone 5%, N-octylpyrrolidone 13%, vegetable oil 12%, cyclohexanone 3%, polyoxyethylene nonylphenol ether phosphate 4%, the pure APEO 3% of fat, silicone defoamer 1%, carboxymethyl cellulose 1%, propane diols 4%, deionized water supply 100%, make 20% cyanogen fluorine Cao Zhi oxazine humulone microemulsion.
Embodiment 2160% cyhalofop-butyl clomazone wetting powder
Cyhalofop-butyl 40%, clomazone 20%, neopelex 8%, draw back powder 5%, kaolin adds to 100%, promptly makes 60% cyhalofop-butyl clomazone wetting powder.
Embodiment 2240% cyhalofop-butyl clomazone wetting powder
Cyhalofop-butyl 35%, clomazone 5%, neopelex 8%, bay alcohol radical sodium sulphate 4%, white carbon add to 100%, make 40% cyhalofop-butyl clomazone wetting powder.
Embodiment 2350% cyhalofop-butyl clomazone oil-suspending agent
Cyhalofop-butyl 35%, clomazone 15%, neopelex 5%, draw back powder 4%, Magnesiumaluminumsilicate 0.5%, organic silicone 0.5%, triethanolamine salt 6%, vegetable oil and add to 100%, make 50% cyhalofop-butyl clomazone oil-suspending agent.
Embodiment 2425% cyhalofop-butyl clomazone oil-suspending agent
Cyhalofop-butyl 5%, clomazone 20%, alkyl benzene sulfonate calcium salt 5%, wetting and penetrating agent F3%, xanthans 0.5%, organic silicone 0.5%, sorbitan monostearate 5%, vegetable oil add to 100%, make 25% cyhalofop-butyl clomazone oil-suspending agent.
Embodiment 2548% cyhalofop-butyl clomazone aqueous emulsion
Cyhalofop-butyl 24%, clomazone 24%, ethyl acetate 18%, vegetable oil 10%, alkyl benzene calcium sulfonate 5%, silicone defoamer 0.4%, polyvinyl alcohol 2%, methylcellulose 0.9%, deionized water adds to 100%, the mixed 48% cyhalofop-butyl clomazone aqueous emulsion that gets.
Embodiment 2638% cyhalofop-butyl clomazone aqueous emulsion
Cyhalofop-butyl 8% ， clomazone 30%, methyl alcohol 16%, ethylene oxide-propylene oxide block copolymer 6%, polyvinyl alcohol 0.8%, silicone oil 1%, polyethylene glycol 3%, deionized water adds to 100%, makes 38% cyhalofop-butyl clomazone aqueous emulsion.
Embodiment 2750% cyhalofop-butyl clomazone microemulsion
Cyhalofop-butyl 29%, clomazone 21%, N-pyrrolidones 7%, vegetable oil 9%, phenyl phenol polyoxy ethyl ether 5%, silicone defoamer 0.4%, ethylene glycol 4%, carboxyethyl cellulose 1.2%, deionized water adds to 100%, the mixed 50% cyhalofop-butyl clomazone microemulsion that gets.
Embodiment 2810% cyhalofop-butyl clomazone microemulsion
Cyhalofop-butyl 2%, clomazone 8%, 3-methyl cyclohexanol ketenes 9%, phenethyl fluosite polyoxy ethyl ether 4%, castor oil polyoxyethylene ether 4%, propane diols 3%, silicone oil 1%, xanthans 0.6%, deionized water adds to 100%, makes 10% cyhalofop-butyl clomazone microemulsion.
Application Example three: cyhalofop-butyl and anilofos control paddy rice annual gramineous weed field control effectiveness test
The table 4 cyhalofop-butyl anilofos control paddy field annual gramineous weed test of pesticide effectiveness
The control medicament: cyhalofop-butyl and anilofos complex composition, produce by Shaanxi Welch Crop Protection Co., Ltd.'s research and development;
Contrast medicament: 18% cyhalofop-butyl missible oil; 30% anilofos missible oil;
If artificial weeding and clear water control treatment.
Using method: convert behind 30 liters in the water evenly that cauline leaf sparges in each sub-district for every mu
Spraying time: on June 25th, 2010,, the field annual gramineous weed 2-4 leaf phase, carry out cauline leaf spraying 1 time in the paddy rice 4-6 leaf phase.
Investigation method and drug effect are calculated
Investigation weeds object is: annual gramineous weeds such as barnyard grass grass, moleplant seed, Paspalum distichum, investigate back 15 days, 30 days to strain preventive effect of weeds and 30 days fresh weight preventive effect.
The visual test medicament does not have poisoning to paddy rice to be taken place.
The table 4 cyhalofop-butyl anilofos built composition for preventing and controlling paddy field annual gramineous weed test of pesticide effectiveness
Cyhalofop-butyl and anilofos are composite as shown in Table 4 has good control efficiency to paddy rice barnyard grass grass, difformed galingale herb, Eclipta prostrata grass, preventive effect is better than single agent preventive effect, and contrast medicament, artificial weeding, with respect to significant difference between the rate of growth of clear water control treatment, and have quick-acting and lasting effect preferably, in this experimental drug scope, to rice safety.
The table 5 cyanogen fluorine Cao Zhi oxazine humulone control paddy field annual gramineous weed test of pesticide effectiveness
The control medicament: cyhalofop-butyl is Yu oxazine humulone complex composition is researched and developed production by Shaanxi Welch Crop Protection Co., Ltd.;
Contrast medicament: 30% oxazine humulone suspending agent;
Behind the rice transplanting 5-7 days, behind the rice striking root before the weeds rudiment, the fertile method dispenser of pesticide-clay mixture method or medicine was evenly spread fertilizer over the fields after mixing thoroughly with corresponding fine earth or fertilizer, and the preceding field of medicine keeps the 3-5cm water layer, and water conservation is 7 days behind the medicine, notes avoiding water layer to flood the paddy rice lobus cardiacus.
The table 5 cyanogen fluorine Cao Zhi oxazine humulone built composition for preventing and controlling paddy field annual gramineous weed test of pesticide effectiveness
Cyhalofop-butyl has good control efficiency Yu the oxazine humulone is composite to paddy rice nutgrass flatsedge, broad leaved weed as shown in Table 5, and paddy rice there is certain volume increase, preventive effect is better than single agent preventive effect, and contrast medicament, artificial weeding, with respect to significant difference between the rate of growth of clear water control treatment, and have quick-acting and lasting effect preferably, in this experimental drug scope, to rice safety.
The table 6 cyhalofop-butyl clomazone control paddy field annual gramineous weed test of pesticide effectiveness
The control medicament: cyhalofop-butyl is Yu the clomazone complex composition is researched and developed production by Shaanxi Welch Crop Protection Co., Ltd.;
Contrast medicament: 48% clomazone missible oil;
Behind the rice transplanting 5-7 days, behind the rice striking root before the weeds rudiment, the fertile method dispenser of pesticide-clay mixture method or medicine was evenly spread fertilizer over the fields after mixing thoroughly with corresponding fine earth or fertilizer, and the preceding field of medicine keeps the 3-5cm water layer, and water conservation is 7 days behind the medicine, notes avoiding water layer to flood the paddy rice lobus cardiacus.
The table 6 cyhalofop-butyl clomazone built composition for preventing and controlling paddy field annual gramineous weed test of pesticide effectiveness
Cyhalofop-butyl has good control efficiency Yu clomazone is composite to paddy rice barnyard grass grass, moleplant seed as shown in Table 6, preventive effect is better than single agent preventive effect, and contrast medicament, artificial weeding, with respect to significant difference between the rate of growth of clear water control treatment, and have quick-acting and lasting effect preferably, in this experimental drug scope, to rice safety.
Claims (8)
1. Herbicidal combinations that contains cyhalofop-butyl, it is characterized in that: Herbicidal combinations contains effective constituents A cyhalofop-butyl 1～60%, and active ingredient B 1～60%, auxiliary agent and other excipient surpluses.
2. the Herbicidal combinations that contains cyhalofop-butyl according to claim 1, it is characterized in that: active ingredient B is selected from: anilofos, oxazine humulone, clomazone.
3. the Herbicidal combinations that contains cyhalofop-butyl according to claim 2 is characterized in that: Herbicidal combinations effective constituents A cyhalofop-butyl 1～60%, anilofos 1～60%, auxiliary agent and excipient.
4. the Herbicidal combinations that contains cyhalofop-butyl according to claim 3 is characterized in that: Herbicidal combinations contains effective constituents A cyhalofop-butyl 2～40%, anilofos 2～40%, auxiliary agent and excipient.
5. the Herbicidal combinations that contains cyhalofop-butyl according to claim 2 is characterized in that: Herbicidal combinations contains cyhalofop-butyl 1～60% ， oxazine humulone 1～60%, auxiliary agent and excipient.
6. the Herbicidal combinations that contains cyhalofop-butyl according to claim 5 is characterized in that: Herbicidal combinations contains cyhalofop-butyl 2～40% ， oxazine humulones 2～40%, auxiliary agent and excipient.
7. the Herbicidal combinations that contains cyhalofop-butyl according to claim 2 is characterized in that: Herbicidal combinations contains cyhalofop-butyl 1～60% ， clomazone 1～60%, auxiliary agent and excipient.
8. the Herbicidal combinations that contains cyhalofop-butyl according to claim 7 is characterized in that: Herbicidal combinations contains cyhalofop-butyl 2～40% ， clomazone 2～40%, auxiliary agent and excipient.
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| CN102860320A (en) * | 2012-10-08 | 2013-01-09 | 陕西省蒲城美尔果农化有限责任公司 | Weeding composite containing cyhalofop-butyl |
| CN102919257A (en) * | 2012-11-14 | 2013-02-13 | 安徽丰乐农化有限责任公司 | Weeding water dispersible granule |
| CN103461350A (en) * | 2013-08-20 | 2013-12-25 | 湖南农大海特农化有限公司 | Weeding composition containing oxaziclomefone and cyhalofop-butyl |
| CN103461365A (en) * | 2013-08-20 | 2013-12-25 | 湖南农大海特农化有限公司 | Pesticide composition for preventing and killing paddy field weeds |
| CN104920447A (en) * | 2015-07-14 | 2015-09-23 | 联保作物科技有限公司 | Rice field weeding composition, weed killer and application thereof |
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| CN101433198A (en) * | 2008-12-02 | 2009-05-20 | 安徽华星化工股份有限公司 | Herbicidal composition for rice field |
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| CN101433198A (en) * | 2008-12-02 | 2009-05-20 | 安徽华星化工股份有限公司 | Herbicidal composition for rice field |
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| CN102860320A (en) * | 2012-10-08 | 2013-01-09 | 陕西省蒲城美尔果农化有限责任公司 | Weeding composite containing cyhalofop-butyl |
| CN102919257A (en) * | 2012-11-14 | 2013-02-13 | 安徽丰乐农化有限责任公司 | Weeding water dispersible granule |
| CN103461350A (en) * | 2013-08-20 | 2013-12-25 | 湖南农大海特农化有限公司 | Weeding composition containing oxaziclomefone and cyhalofop-butyl |
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| CN103461365B (en) * | 2013-08-20 | 2016-04-06 | 湖南农大海特农化有限公司 | A kind of composition pesticide preventing and kill off paddy field weed |
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| CN104920447A (en) * | 2015-07-14 | 2015-09-23 | 联保作物科技有限公司 | Rice field weeding composition, weed killer and application thereof |
| CN105211072B (en) * | 2015-08-20 | 2017-08-01 | 浙江天丰生物科学有限公司 | Herbicidal combinations |
| CN105211072A (en) * | 2015-08-20 | 2016-01-06 | 浙江天丰生物科学有限公司 | Herbicidal combinations |
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| CN106376593A (en) * | 2016-11-08 | 2017-02-08 | 陕西上格之路生物科学有限公司 | Three-ingredient weeding composition |
| CN107410316A (en) * | 2017-06-08 | 2017-12-01 | 上海虎印实业有限公司 | A kind of Herbicidal combinations containing clefoxidim and cyhalofop-butyl |
| CN107683855A (en) * | 2017-09-19 | 2018-02-13 | 浙江天丰生物科学有限公司 | A kind of Herbicidal composition for paddy fields |
| CN109691466A (en) * | 2017-10-24 | 2019-04-30 | 佛山市盈辉作物科学有限公司 | A kind of Herbicidal combinations containing anilofos, cyhalofop-butyl and dichloro quinolinic acid |
| CN109769852A (en) * | 2017-11-14 | 2019-05-21 | 佛山市盈辉作物科学有限公司 | A kind of herbicidal composition containing anilofos, cyhalofop-butyl and benzobicylon |
| CN109221202A (en) * | 2018-12-01 | 2019-01-18 | 安徽美程化工有限公司 | A kind of Herbicidal combinations and its application containing penoxsuam, oxaziclomefone and cyhalofop-butyl |
| CN113575582A (en) * | 2021-08-27 | 2021-11-02 | 安徽省圣丹生物化工有限公司 | Synergistic herbicide containing cyhalofop-butyl |
| CN115530161A (en) * | 2022-10-08 | 2022-12-30 | 安徽黑包公有害生物防控有限公司 | Production process of oil suspending agent containing cyhalofop-butyl and oxaziclomefone |
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Address after: 715500 Pucheng County of Shaanxi Province agricultural base industrial park Patentee after: Shaanxi Welch Crop Protection Co., Ltd. Address before: 710075, C, 15 floor, Jinqiao International Plaza, science and technology road, hi tech Zone, Shaanxi, Xi'an Patentee before: Shaanxi Welch Crop Protection Co., Ltd. |
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