CN102321377A - Mildewproof plastic wood decorative plate and preparation method thereof - Google Patents
Mildewproof plastic wood decorative plate and preparation method thereof Download PDFInfo
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- CN102321377A CN102321377A CN201110231757A CN201110231757A CN102321377A CN 102321377 A CN102321377 A CN 102321377A CN 201110231757 A CN201110231757 A CN 201110231757A CN 201110231757 A CN201110231757 A CN 201110231757A CN 102321377 A CN102321377 A CN 102321377A
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- going mouldy
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
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- Mechanical Engineering (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention relates to a plastic wood material, and especially relates to a mildewproof plastic wood decorative plate and a preparation method thereof. The preparation method of the invention comprises the following steps: modifying rice chaff powder by ACQ, mixing plastic particles, maleic anhydride grafted plastic particles, calcium stearate, and short glass fibers, performing extrusion and granulation to obtain modified plastic particles; uniformly stirring the modified plastic particles, the modified rice chaff powder, a mildewproof antibacterial agent, calcium carbonate powder, terpenes resin, and an anti-oxidant, performing extrusion and granulation to obtain the mildewproof plastic wood composite material particles; and finally performing extrusion molding of the mildewproof plastic wood particles to obtain the mildewproof plastic wood plates. The mildewproof plastic wood plate of the invention is convenient for production and manufacture, has low cost, is environment friendly, is mildewproof, does not mildew or decay during application, has long service life, and is widely applicable to various situations such as decoration, municipal gardens, docks and wharves.
Description
Technical field
The present invention relates to a kind of Wood plastic composite, particularly relate to a kind of anti-going mouldy and mould wooden dalle and preparation method thereof.
Background technology
Wood plastic composite is to be raw material with natural fiber, plastics and particular adhesive, is the type material that means are produced with high polymer alloy technology, modern computer production unit etc.The sheet material that utilizes Wood plastic composite to make has following characteristics: raw material sources extensively, environmental friendliness, renewable, can be recycled; Nontoxic, do not contain formaldehyde, the no obnoxious flavour in heating back is beneficial to health; Receive thermally-stabilisedly, can not be out of shape; Energy-conserving and environment-protective, woodiness touch is strong, and the utmost point is seemingly wooden, back to nature.Be applicable to industry and civil applications fields such as door and window, floor, furniture, template, pallet, corridor, automotive upholstery, coastal waters building, it can substitute timber, plastics and part aluminium matter and steel product.But Wood plastic composite has been owing to filled a large amount of vegetable fibres, though vegetable fibre acts on by plastic overmold and by coupling agent or compatilizer, thereby do not have pure plant fiber so easily by infection such as mould and wood-rotting fungis; But make moist or when suddenly soaking when overcast and rainy; Wood plastic composite still can cause Wood plastic composite to go mouldy for fungi provides good living environment, and the mechanical property of material descends gradually; Even rot, shorten its work-ing life greatly.Simultaneously, going mouldy to make Wood plastic composite surface produce macroscopic mould spot, influences that it is attractive in appearance.So, invent a kind of novel plastic wood composite board, it is very necessary to make it have the anti-characteristic of going mouldy.
Summary of the invention
The objective of the invention is provides a kind of anti-going mouldy to mould wooden dalle and preparation method thereof to above-mentioned weak point.
The objective of the invention is to realize through following technical scheme:
A kind of anti-going mouldy moulded wooden dalle, formed by the feedstock production that comprises following parts by weight:
The modification rice husk meal is meant and took by weighing rice husk meal and wood preservative ACQ by weight 100: 1 respectively, and by weight AGQ: tap water is to adopt tap water dilution ACQ at 1: 100, then rice husk meal is inserted in the diluent; Sealing pressurization 1MPa; Constant voltage 10 minutes, release, washing is to neutral; After the drying, screening obtains the modification rice husk meal.
A kind of anti-going mouldy of the present invention moulded wooden dalle, and wherein said rice husk meal particle diameter order number is 60 orders-100 orders.
A kind of anti-going mouldy of the present invention moulded wooden dalle, and wherein said plastic pellet adopts a kind of in Vilaterm, Vestolen PP 7052, the PS.
A kind of anti-going mouldy of the present invention moulded wooden dalle, and wherein said maleic anhydride graft plastic pellet is a kind of in maleic anhydride grafted polyethylene, maleic anhydride inoculated polypropylene, the maleic anhydride graft PS, and it selects for use corresponding with plastic pellet; Be that plastic pellet is when being Vilaterm; Select maleic anhydride grafted polyethylene for use, when plastic pellet is Vestolen PP 7052, select maleic anhydride inoculated polypropylene for use; When plastic pellet is PS, select the maleic anhydride graft PS for use.
A kind of anti-going mouldy of the present invention moulded wooden dalle, and wherein said antimildew and antibacterial agent is that commercially available model is the antiseptic-germicide of RHA-MT1, belongs to compound of benzene nitriles, active ingredient content 96%.
A kind of anti-going mouldy of the present invention moulded wooden dalle, and wherein said wood preservative ACQ is meant the cuprammonium quaternary ammonium salt antiseptics for wood, and its effective constituent is made up of copper and dodecylbenzyl alkyl dimethyl ammonium chloride, and the content of activeconstituents is 15%.
A kind of anti-going mouldy of the present invention moulded wooden dalle, and wherein said Paris white is meant the light calcium carbonate powder, 0.02 micron-0.1 micron of particle size range.
A kind of anti-going mouldy of the present invention moulded wooden dalle, and wherein said chopped glass fiber length is 3 millimeters-4 millimeters.
A kind of anti-going mouldy of the present invention moulded wooden dalle; Wherein said oxidation inhibitor is β-(3; The 5-di-tert-butyl-hydroxy phenyl) one or both in the positive octadecanol ester of propionic acid, butyl hydroxy toluene, four [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester.
Preferably, a kind of anti-going mouldy moulded wooden dalle, formed by the feedstock production that comprises following parts by weight:
More preferably, a kind of anti-going mouldy moulded wooden dalle, formed by the feedstock production that comprises following parts by weight:
A kind of anti-going mouldy of the present invention moulded the preparation method of wooden dalle, and it may further comprise the steps:
(1), took by weighing rice husk meal and wood preservative ACQ respectively by weight 100: 1;
(2), by weight ACQ: water is to adopt water dilution ACQ at 1: 100, then rice husk meal is inserted in the diluent, sealing pressurization 1MPa, constant voltage 10 minutes, release, washing are to neutral, after the drying, screening obtains the modification rice husk meal;
(3), take by weighing each raw material by formula ratio;
(4), plastic pellet, maleic anhydride graft plastic pellet, calcium stearate, chopped glass fiber placed in the mechanical stirring kettle stirred 1-3 minute, extruding pelletization, 160 ℃-200 ℃ of extruder barrel temperature, 170 ℃-210 ℃ of die head temperatures obtain the modified plastics particle;
(5), above-mentioned modified plastics particle, modification rice husk meal, antimildew and antibacterial agent, Paris white, terpine resin, oxidation inhibitor are placed in the mechanical stirring kettle and mechanical stirring 3-5 minute once more;
(6), behind the mixing, adopt forcing machine to carry out melt blending and granulation, 165 ℃-195 ℃ of extruder barrel temperature, 170 ℃-205 ℃ of die head temperatures obtain the anti-Wood plastic composite particle that goes mouldy;
(7), adopt machine with the anti-Wood plastic composite sheet material that goes mouldy of the anti-Wood plastic composite particle extrusion moulding of going mouldy of gained, 160 ℃-190 ℃ of extruder barrel temperature, 165 ℃-205 ℃ of die head temperatures, i.e. completion.
A kind of anti-going mouldy of the present invention moulded wooden dalle, and it is convenient to manufacture, and traditional wood-plastic composite material manufacturing technique need not to improve and promptly can be used for its production and processing, and mechanization degree is higher in the production process, and required labor force is less, and production cost is low.Anti-going mouldy moulded wooden dalle and compared with common plastics sheet material, and used amount of plastic reduces, and friendly more to environment, modulus is higher, and rigidity is bigger, and creep resistance can be carried out utilization of waste material to this industrial or agricultural scrap stock of rice husk meal simultaneously more, reduction products material cost; Anti-going mouldy moulded wooden dalle and compared with other Wood plastic composite, prevents more going mouldy, and it is rotten in use can not go mouldy, thereby longer service life, can be widely used in fitting-up, municipal gardens, the many occasions of dock.
Embodiment
Below adopt embodiment to specify a kind of anti-going mouldy of the present invention and mould wooden dalle and preparation method thereof.
Embodiment 1
(1), took by weighing rice husk meal and wood preservative ACQ respectively by weight 100: 1;
(2), by weight ACQ: water is to adopt water dilution ACQ at 1: 100, then rice husk meal is inserted in the diluent, sealing pressurization 1MPa, constant voltage 10 minutes, release, washing are to neutral, after the drying, screening obtains the modification rice husk meal;
(3), take by weighing each raw material by formula ratio;
(4), plastic pellet, maleic anhydride graft plastic pellet, calcium stearate, chopped glass fiber placed in the mechanical stirring kettle stirred 2 minutes, extruding pelletization, 180 ℃ of extruder barrel temperature, 190 ℃ of die head temperatures obtain the modified plastics particle;
(5), above-mentioned modified plastics particle, modification rice husk meal, antimildew and antibacterial agent, Paris white, terpine resin, oxidation inhibitor are placed in the mechanical stirring kettle and mechanical stirring 4 minutes once more;
(6), behind the mixing, adopt forcing machine to carry out melt blending and granulation, 180 ℃ of extruder barrel temperature, 190 ℃ of die head temperatures obtain the anti-Wood plastic composite particle that goes mouldy;
(7), adopt machine with the anti-Wood plastic composite sheet material that goes mouldy of the anti-Wood plastic composite particle extrusion moulding of going mouldy of gained, 175 ℃ of extruder barrel temperature, 185 ℃ of die head temperatures, i.e. completion.
Embodiment 2
(1), took by weighing rice husk meal and wood preservative ACQ respectively by weight 100: 1;
(2), by weight ACQ: water is to adopt water dilution ACQ at 1: 100, then rice husk meal is inserted in the diluent, sealing pressurization 1MPa, constant voltage 10 minutes, release, washing are to neutral, after the drying, screening obtains the modification rice husk meal;
(3), take by weighing each raw material by formula ratio;
(4), plastic pellet, maleic anhydride graft plastic pellet, calcium stearate, chopped glass fiber placed in the mechanical stirring kettle stirred 1 minute, extruding pelletization, 160 ℃ of extruder barrel temperature, 170 ℃ of die head temperatures obtain the modified plastics particle;
(5), above-mentioned modified plastics particle, modification rice husk meal, antimildew and antibacterial agent, Paris white, terpine resin, oxidation inhibitor are placed in the mechanical stirring kettle and mechanical stirring 3 minutes once more;
(6), behind the mixing, adopt forcing machine to carry out melt blending and granulation, 165 ℃ of extruder barrel temperature, 170 ℃ of die head temperatures obtain the anti-Wood plastic composite particle that goes mouldy;
(7), adopt machine with the anti-Wood plastic composite sheet material that goes mouldy of the anti-Wood plastic composite particle extrusion moulding of going mouldy of gained, 160 ℃ of extruder barrel temperature, 165 ℃ of die head temperatures, i.e. completion.
Embodiment 3
(1), took by weighing rice husk meal and wood preservative ACQ respectively by weight 100: 1;
(2), by weight ACQ: water is to adopt water dilution ACQ at 1: 100, then rice husk meal is inserted in the diluent, sealing pressurization 1MPa, constant voltage 10 minutes, release, washing are to neutral, after the drying, screening obtains the modification rice husk meal;
(3), take by weighing each raw material by formula ratio;
(4), plastic pellet, maleic anhydride graft plastic pellet, calcium stearate, chopped glass fiber placed in the mechanical stirring kettle stirred 3 minutes, extruding pelletization, 200 ℃ of extruder barrel temperature, 210 ℃ of die head temperatures obtain the modified plastics particle;
(5), above-mentioned modified plastics particle, modification rice husk meal, antimildew and antibacterial agent, Paris white, terpine resin, oxidation inhibitor are placed in the mechanical stirring kettle and mechanical stirring 5 minutes once more;
(6), behind the mixing, adopt forcing machine to carry out melt blending and granulation, 195 ℃ of extruder barrel temperature, 205 ℃ of die head temperatures obtain the anti-Wood plastic composite particle that goes mouldy;
(7), adopt machine with the anti-Wood plastic composite sheet material that goes mouldy of the anti-Wood plastic composite particle extrusion moulding of going mouldy of gained, 190 ℃ of extruder barrel temperature, 205 ℃ of die head temperatures, i.e. completion.
Embodiment 4
(1), took by weighing rice husk meal and wood preservative ACQ respectively by weight 100: 1;
(2), by weight ACQ: water is to adopt water dilution ACQ at 1: 100, then rice husk meal is inserted in the diluent, sealing pressurization 1MPa, constant voltage 10 minutes, release, washing are to neutral, after the drying, screening obtains the modification rice husk meal;
(3), take by weighing each raw material by formula ratio;
(4), plastic pellet, maleic anhydride graft plastic pellet, calcium stearate, chopped glass fiber placed in the mechanical stirring kettle stirred 2 minutes, extruding pelletization, 180 ℃ of extruder barrel temperature, 210 ℃ of die head temperatures obtain the modified plastics particle;
(5), above-mentioned modified plastics particle, modification rice husk meal, antimildew and antibacterial agent, Paris white, terpine resin, oxidation inhibitor are placed in the mechanical stirring kettle and mechanical stirring 5 minutes once more;
(6), behind the mixing, adopt forcing machine to carry out melt blending and granulation, 195 ℃ of extruder barrel temperature, 190 ℃ of die head temperatures obtain the anti-Wood plastic composite particle that goes mouldy;
(7), adopt machine with the anti-Wood plastic composite sheet material that goes mouldy of the anti-Wood plastic composite particle extrusion moulding of going mouldy of gained, 190 ℃ of extruder barrel temperature, 205 ℃ of die head temperatures, i.e. completion.
Embodiment 5
(1), took by weighing rice husk meal and wood preservative ACQ respectively by weight 100: 1;
(2), by weight ACQ: water is to adopt water dilution ACQ at 1: 100, then rice husk meal is inserted in the diluent, sealing pressurization 1MPa, constant voltage 10 minutes, release, washing are to neutral, after the drying, screening obtains the modification rice husk meal;
(3), take by weighing each raw material by formula ratio;
(4), plastic pellet, maleic anhydride graft plastic pellet, calcium stearate, chopped glass fiber placed in the mechanical stirring kettle stirred 3 minutes, extruding pelletization, 160 ℃ of extruder barrel temperature, 190 ℃ of die head temperatures obtain the modified plastics particle;
(5), above-mentioned modified plastics particle, modification rice husk meal, antimildew and antibacterial agent, Paris white, terpine resin, oxidation inhibitor are placed in the mechanical stirring kettle and mechanical stirring 3 minutes once more;
(6), behind the mixing, adopt forcing machine to carry out melt blending and granulation, 165 ℃ of extruder barrel temperature, 170 ℃ of die head temperatures obtain the anti-Wood plastic composite particle that goes mouldy;
(7), adopt machine with the anti-Wood plastic composite sheet material that goes mouldy of the anti-Wood plastic composite particle extrusion moulding of going mouldy of gained, 175 ℃ of extruder barrel temperature, 165 ℃ of die head temperatures, i.e. completion.
Embodiment 6
(1), took by weighing rice husk meal and wood preservative ACQ respectively by weight 100: 1;
(2), by weight ACQ: water is to adopt water dilution ACQ at 1: 100, then rice husk meal is inserted in the diluent, sealing pressurization 1MPa, constant voltage 10 minutes, release, washing are to neutral, after the drying, screening obtains the modification rice husk meal;
(3), take by weighing each raw material by formula ratio;
(4), plastic pellet, maleic anhydride graft plastic pellet, calcium stearate, chopped glass fiber placed in the mechanical stirring kettle stirred 2.5 minutes, extruding pelletization, 185 ℃ of extruder barrel temperature, 185 ℃ of die head temperatures obtain the modified plastics particle;
(5), above-mentioned modified plastics particle, modification rice husk meal, antimildew and antibacterial agent, Paris white, terpine resin, oxidation inhibitor are placed in the mechanical stirring kettle and mechanical stirring 4.5 minutes once more;
(6), behind the mixing, adopt forcing machine to carry out melt blending and granulation, 182 ℃ of extruder barrel temperature, 200 ℃ of die head temperatures obtain the anti-Wood plastic composite particle that goes mouldy;
(7), adopt machine with the anti-Wood plastic composite sheet material that goes mouldy of the anti-Wood plastic composite particle extrusion moulding of going mouldy of gained, 185 ℃ of extruder barrel temperature, 180 ℃ of die head temperatures, i.e. completion.
Sample was placed in the brown rot fungus gloeophyllum trabeum after 3 months, and through detecting the effect of the proof embodiment of the invention 1, its detected result is following below:
Above result shows that the present invention has the significantly anti-corrosive effect of going mouldy.
Claims (10)
1. anti-going mouldy moulded wooden dalle and preparation method thereof, formed by the feedstock production of following parts by weight:
The modification rice husk meal is meant and took by weighing rice husk meal and wood preservative ACQ by weight 100: 1 respectively, and by weight ACQ: tap water is to adopt tap water dilution ACQ at 1: 100, then rice husk meal is inserted in the diluent; Sealing pressurization 1MPa, constant voltage 10 minutes, release; Washing is to neutral; After the drying, screening obtains the modification rice husk meal, and modification rice husk meal particle diameter order number is 60 orders-100 orders.
2. a kind of anti-going mouldy according to claim 1 moulded wooden dalle and preparation method thereof, formed by the feedstock production of following parts by weight:
3. a kind of anti-going mouldy according to claim 2 moulded wooden dalle and preparation method thereof, formed by the feedstock production of following parts by weight:
4. mould wooden dalle and preparation method thereof according to described a kind of anti-the going mouldy of the arbitrary claim of claim 1-3, it is characterized in that described plastic pellet adopts a kind of in Vilaterm, Vestolen PP 7052, the PS; Described maleic anhydride graft plastic pellet is a kind of in maleic anhydride grafted polyethylene, maleic anhydride inoculated polypropylene, the maleic anhydride graft PS; It selects for use corresponding with plastic pellet, when promptly plastic pellet is Vilaterm, selects maleic anhydride grafted polyethylene for use; When plastic pellet is Vestolen PP 7052; Select maleic anhydride inoculated polypropylene for use, when plastic pellet is PS, select the maleic anhydride graft PS for use.
5. mould wooden dalle and preparation method thereof according to described a kind of anti-the going mouldy of the arbitrary claim of claim 1-3, it is characterized in that described antimildew and antibacterial agent is that commercially available model is the antiseptic-germicide of RHA-MT1, belongs to compound of benzene nitriles, active ingredient content 96%.
6. mould wooden dalle and preparation method thereof according to described a kind of anti-the going mouldy of the arbitrary claim of claim 1-3; It is characterized in that described wood preservative ACQ is meant the cuprammonium quaternary ammonium salt antiseptics for wood; Its effective constituent is made up of copper and dodecylbenzyl alkyl dimethyl ammonium chloride, and the content of activeconstituents is 15%.
7. mould wooden dalle and preparation method thereof according to described a kind of anti-the going mouldy of the arbitrary claim of claim 1-3, it is characterized in that described Paris white is the light calcium carbonate powder, 0.02 micron-0.1 micron of particle size range.
8. mould wooden dalle and preparation method thereof according to described a kind of anti-the going mouldy of the arbitrary claim of claim 1-3, it is characterized in that described chopped glass fiber length is 3 millimeters-4 millimeters.
9. mould wooden dalle and preparation method thereof according to described a kind of anti-the going mouldy of the arbitrary claim of claim 1-3; It is characterized in that described oxidation inhibitor is β-(3; The 5-di-tert-butyl-hydroxy phenyl) one or both in the positive octadecanol ester of propionic acid, butyl hydroxy toluene, four [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester.
10. mould wooden dalle and preparation method thereof according to described a kind of anti-the going mouldy of the arbitrary claim of claim 1-3, it is characterized in that its preparation process is:
(1), took by weighing rice husk meal and wood preservative ACQ respectively by weight 100: 1;
(2), by weight ACQ: water is to adopt water dilution ACQ at 1: 100, then rice husk meal is inserted in the diluent, sealing pressurization 1MPa, constant voltage 10 minutes, release, washing are to neutral, after the drying, screening obtains the modification rice husk meal;
(3), take by weighing each raw material by formula ratio;
(4), plastic pellet, maleic anhydride graft plastic pellet, calcium stearate, chopped glass fiber placed in the mechanical stirring kettle stirred 1-3 minute, extruding pelletization, 160 ℃-200 ℃ of extruder barrel temperature, 170 ℃-210 ℃ of die head temperatures obtain the modified plastics particle;
(5), above-mentioned modified plastics particle, modification rice husk meal, antimildew and antibacterial agent, Paris white, terpine resin, oxidation inhibitor are placed in the mechanical stirring kettle and mechanical stirring 3-5 minute once more;
(6), behind the mixing, adopt forcing machine to carry out melt blending and granulation, 165 ℃-195 ℃ of extruder barrel temperature, 170 ℃-205 ℃ of die head temperatures obtain anti-going mouldy and mould the multiple material particle of wood;
(7), adopt machine with the anti-Wood plastic composite sheet material that goes mouldy of the anti-Wood plastic composite particle extrusion moulding of going mouldy of gained, 160 ℃-190 ℃ of extruder barrel temperature, 165 ℃-205 ℃ of die head temperatures, i.e. completion.
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| CN2011102317578A CN102321377B (en) | 2011-08-15 | 2011-08-15 | Mildewproof plastic wood decorative plate and preparation method thereof |
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Cited By (7)
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| CN102746684A (en) * | 2012-07-25 | 2012-10-24 | 江苏森诺塑胶科技有限公司 | Mildew-proof plastic-wood composite sheet and preparation method thereof |
| CN104231650A (en) * | 2014-09-20 | 2014-12-24 | 鑫盛(湖州)塑木科技有限公司 | Compound modified plastic-wood composite material board and preparation method thereof |
| CN104448871A (en) * | 2014-11-11 | 2015-03-25 | 南京工业职业技术学院 | Antibacterial anti-mildew plastic and wood composite material plate and preparation method thereof |
| CN106479207A (en) * | 2016-11-08 | 2017-03-08 | 佛山市炬业科技有限公司 | A kind of composite for making fungus-proof antisepsis door-plate and preparation method thereof |
| CN106519473A (en) * | 2016-11-17 | 2017-03-22 | 过冬 | Engineering plastic and preparation method |
| CN107892822A (en) * | 2017-11-28 | 2018-04-10 | 阜阳市鸿泰装饰材料有限公司 | A kind of antibacterial, which is preapred for an unfavorable turn of events, shapes the preparation method of wooden dalle |
| CN111484750A (en) * | 2020-05-13 | 2020-08-04 | 江苏郁林生塑木科技有限公司 | Antibacterial plastic-wood composite material plate and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102746684A (en) * | 2012-07-25 | 2012-10-24 | 江苏森诺塑胶科技有限公司 | Mildew-proof plastic-wood composite sheet and preparation method thereof |
| CN104231650A (en) * | 2014-09-20 | 2014-12-24 | 鑫盛(湖州)塑木科技有限公司 | Compound modified plastic-wood composite material board and preparation method thereof |
| CN104448871A (en) * | 2014-11-11 | 2015-03-25 | 南京工业职业技术学院 | Antibacterial anti-mildew plastic and wood composite material plate and preparation method thereof |
| CN106479207A (en) * | 2016-11-08 | 2017-03-08 | 佛山市炬业科技有限公司 | A kind of composite for making fungus-proof antisepsis door-plate and preparation method thereof |
| CN106519473A (en) * | 2016-11-17 | 2017-03-22 | 过冬 | Engineering plastic and preparation method |
| CN107892822A (en) * | 2017-11-28 | 2018-04-10 | 阜阳市鸿泰装饰材料有限公司 | A kind of antibacterial, which is preapred for an unfavorable turn of events, shapes the preparation method of wooden dalle |
| CN114958023A (en) * | 2017-11-28 | 2022-08-30 | 阜阳市鸿泰装饰材料有限公司 | Antibacterial anti-deformation plastic-wood decorative plate and preparation method thereof |
| CN111484750A (en) * | 2020-05-13 | 2020-08-04 | 江苏郁林生塑木科技有限公司 | Antibacterial plastic-wood composite material plate and preparation method thereof |
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|---|---|
| CN102321377B (en) | 2013-01-02 |
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