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CN102276028A - High pressure electrostatic seawater desalination device based on ion inversion - Google Patents

High pressure electrostatic seawater desalination device based on ion inversion Download PDF

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CN102276028A
CN102276028A CN2011101524250A CN201110152425A CN102276028A CN 102276028 A CN102276028 A CN 102276028A CN 2011101524250 A CN2011101524250 A CN 2011101524250A CN 201110152425 A CN201110152425 A CN 201110152425A CN 102276028 A CN102276028 A CN 102276028A
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collector
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CN102276028B (en
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古亮
刘伟
李山
赵明富
邓易元
陈鸿雁
贺晓蓉
张莲
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Chongqing University of Technology
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Abstract

本发明公开了一种基于离子反转的高压静电型海水淡化器,包括高压正极板、高压负极板、圆筒型离子反转器和绝缘离子收集器;高压正极板与高压负极板平行设置,离子反转器以可旋转的方式设在高压正极板和高压负极板之间,且轴线与高压正极板的板面平行;绝缘离子收集器的横截面为矩形结构,且设在离子反转器的轴线上,两侧面分别与高压正极板和高压负极板平行。该淡化器离子分离能力极强,两电极板平行且带正负高电压,极板间形成强大的高压静电场,增强对离子的分离能力,使盐离子连续不断从低势能位置转移,反转到高电势位置,并汇聚到绝缘离子收集器两侧面上并被去除,使盐水中的离子分离更充分,极大地提高了离子分离效率。

Figure 201110152425

The invention discloses a high-voltage electrostatic seawater desalinator based on ion reversal, which includes a high-voltage positive plate, a high-voltage negative plate, a cylindrical ion inverter and an insulating ion collector; the high-voltage positive plate and the high-voltage negative plate are arranged in parallel, The ion inverter is rotatably arranged between the high-voltage positive plate and the high-voltage negative plate, and the axis is parallel to the plate surface of the high-voltage positive plate; On the axis of , the two sides are parallel to the high-voltage positive plate and the high-voltage negative plate respectively. The ion separation ability of this desalter is extremely strong, the two electrode plates are parallel and carry positive and negative high voltages, a strong high-voltage electrostatic field is formed between the plates, which enhances the separation ability of ions, so that salt ions are continuously transferred from low potential energy positions, reversed to the high potential position, and converge to the two sides of the insulating ion collector and be removed, so that the ions in the brine can be separated more fully, and the ion separation efficiency is greatly improved.

Figure 201110152425

Description

基于离子反转的高压静电型海水淡化器High-voltage electrostatic seawater desalination device based on ion reversal

技术领域 technical field

本发明涉及一种海水淡化器,尤其涉及一种基于离子反转的高压静电型海水淡化器。 The invention relates to a seawater desalinator, in particular to a high-voltage electrostatic seawater desalinator based on ion reversal.

背景技术 Background technique

人类的淡水资源越来越少而需求量越来越大。海水淡化是解决水资源短缺的有效途径。 The fresh water resources of human beings are getting less and less and the demand is increasing. Seawater desalination is an effective way to solve the shortage of water resources.

目前,已有专利表明:把过水管道放在静止强磁场中,盐水在管道内高速流动时,盐水中的正负离子承受方向相反的罗伦兹力而分离,使水得到淡化。但是,要求管道内的海水的流动速度很高,因而需要的水压很大,能量消耗大,效率低。高速流动时其离子承受的罗伦兹力的受力时间短,因而离子分离的时间短,进一步降低了分离效率。 At present, there are patents showing that: when the water pipe is placed in a static strong magnetic field, when the brine flows at high speed in the pipe, the positive and negative ions in the brine are separated by the Lorentz force in the opposite direction, so that the water is desalinated. However, the flow velocity of the seawater in the pipeline is required to be high, so the required water pressure is high, the energy consumption is large, and the efficiency is low. When flowing at high speed, the Lorentz force that the ions bear has a short stress time, so the ion separation time is short, which further reduces the separation efficiency.

另外,目前存在一种电渗析的海水淡化器。其中的电极距离很小,电极之间的电压很小,对海水中离子的吸附力很有限。而且,需要对电极电压进行正负交变,以释放吸附的离子,降低电极腐蚀程度。释放吸附的离子后,盐水浓度提高,应即时排出浓盐水。这种电渗析的海水淡化器,电极电压极性的改变和浓盐水的排出占用了离子分离时间,降低了海水淡化效率;而且电压极性的改变极大地增加了能耗;电极有一定的腐蚀。 In addition, there is currently an electrodialytic seawater desalinator. The distance between the electrodes is very small, the voltage between the electrodes is very small, and the adsorption force for ions in seawater is very limited. Moreover, it is necessary to alternate positive and negative electrode voltages to release adsorbed ions and reduce electrode corrosion. After releasing the adsorbed ions, the brine concentration increases, and the concentrated brine should be discharged immediately. In this electrodialysis seawater desalinator, the change of electrode voltage polarity and the discharge of concentrated brine take up the ion separation time, which reduces the efficiency of seawater desalination; and the change of voltage polarity greatly increases energy consumption; the electrode has certain corrosion .

发明内容 Contents of the invention

为了克服现有的水压大、分离时间短、效率低下、吸附浓度小等不足之处,本发明提供了一种不仅大幅度降低管道水压,降低功耗,而且能极大地提高离子去除浓度,使盐水中的离子分离更充分的基于离子反转的高压静电型海水淡化器。 In order to overcome the existing deficiencies such as high water pressure, short separation time, low efficiency, and small adsorption concentration, the present invention provides a method that not only greatly reduces pipeline water pressure, reduces power consumption, but also greatly increases ion removal concentration. , a high-voltage electrostatic seawater desalinator based on ion reversal that makes the ion separation in brine more complete.

本发明提供的基于离子反转的高压静电型海水淡化器,包括高压正极板、高压负极板、圆筒型的离子反转器和绝缘离子收集器;所述高压正极板与高压负极板平行设置,所述离子反转器以可旋转的方式设在高压正极板和高压负极板之间,且离子反转器的轴线与高压正极板的板面平行;所述绝缘离子收集器的横截面为矩形结构,且设在离子反转器的轴线上,绝缘离子收集器的两侧面分别与高压正极板和高压负极板平行; The high-voltage electrostatic seawater desalinator based on ion reversal provided by the present invention includes a high-voltage positive plate, a high-voltage negative plate, a cylindrical ion inverter and an insulated ion collector; the high-voltage positive plate and the high-voltage negative plate are arranged in parallel , the ion reverser is rotatably arranged between the high-voltage positive plate and the high-voltage negative plate, and the axis of the ion reverser is parallel to the plate surface of the high-voltage positive plate; the cross-section of the insulated ion collector is Rectangular structure, and set on the axis of the ion inverter, the two sides of the insulating ion collector are respectively parallel to the high-voltage positive plate and the high-voltage negative plate;

所述离子反转器的内圆上沿轴向均布设有多个叶片,所述离子反转器的内圆上的叶片沿顺时针方向倾斜设置,离子反转器的内圆在圆周方向上均布设有多个与叶片垂直的圆弧形隔板;所述离子反转器的内圆上由叶片和圆弧形隔板分割为多个凹陷区域; The inner circle of the ion reverser is equipped with a plurality of blades evenly distributed along the axial direction, the blades on the inner circle of the ion reverser are arranged obliquely in the clockwise direction, and the inner circle of the ion reverser is in the circumferential direction A plurality of arc-shaped partitions perpendicular to the blades are evenly distributed; the inner circle of the ion inverter is divided into a plurality of concave regions by the blades and the arc-shaped partitions;

所述绝缘离子收集器的两侧面上分别设有横向隔板和纵向隔板,所述绝缘离子收集器的两侧面由横向隔板和纵向隔板分割为多个内凹区域。 The two sides of the insulating ion collector are respectively provided with transverse partitions and longitudinal partitions, and the two sides of the insulating ion collector are divided into a plurality of concave regions by the transverse partitions and the longitudinal partitions.

本发明的基于离子反转的高压静电型海水淡化器,与现有技术相比,具有如下优点: Compared with the prior art, the high-voltage electrostatic seawater desalinator based on ion reversal of the present invention has the following advantages:

(1)本发明的离子分离能力极强,两电极板平行且带正负高电压,极间形成强大的高压静电场,增强对离子的分离能力。 (1) The ion separation ability of the present invention is extremely strong, the two electrode plates are parallel and carry positive and negative high voltages, a strong high-voltage electrostatic field is formed between the electrodes, and the separation ability for ions is enhanced.

(2)本发明能连续分离离子,采用旋转的离子反转器和绝缘离子收集器,使盐离子连续不断从低势能位置转移、反转到高电势位置,并汇聚到绝缘离子收集器两侧面上并被去除。 (2) The present invention can continuously separate ions, using a rotating ion inverter and an insulating ion collector, so that salt ions are continuously transferred from a low potential energy position, reversed to a high potential position, and converged on both sides of the insulating ion collector on and removed.

(3)电极电压无须交变,这在一定程度上降低了能耗。 (3) The electrode voltage does not need to be alternated, which reduces energy consumption to a certain extent.

(4)应用异性离子的相互吸引的特性,能大幅度提高离子在离子收集板两侧壁上的富集浓度,使盐水中的离子分离更充分,极大地提高了离子分离效率。 (4) Using the mutual attraction characteristics of opposite ions can greatly increase the enrichment concentration of ions on the two side walls of the ion collection plate, make the ion separation in brine more sufficient, and greatly improve the ion separation efficiency.

附图说明 Description of drawings

图1为基于离子反转的高压静电型海水淡化器的结构示意图; Figure 1 is a schematic structural diagram of a high-voltage electrostatic seawater desalinator based on ion inversion;

图2为基于离子反转的高压静电型海水淡化器中离子反转器的局部结构示意图。 Fig. 2 is a schematic diagram of a partial structure of an ion inverter in a high-voltage electrostatic seawater desalinator based on ion inversion.

    附图中: 1—高压正极板; 2—高压负极板; 3—离子反转器; 4—绝缘离子收集器; 5—叶片; 6—弧形隔板; 7—横向隔板; 8—纵向隔板; 9—凸楞。 In the attached drawings: 1—high voltage positive plate; 2—high voltage negative plate; 3—ion inverter; 4—insulated ion collector; 5—blade; 6—arc partition; 7—transverse partition; 8—longitudinal Partition; 9—convex.

具体实施方式 Detailed ways

    下面结合附图和具体实施方式对本发明作进一步详细地说明。   Below in conjunction with accompanying drawing and specific embodiment, the present invention is described in further detail. the

图1为基于离子反转的高压静电型海水淡化器的结构示意图,图2为基于离子反转的高压静电型海水淡化器中离子反转器的局部结构示意图,如图所示。基于离子反转的高压静电型海水淡化器,包括高压正极板1、高压负极板2、圆筒型的离子反转器3和绝缘离子收集器4。高压正极板1与高压负极板2平行设置,离子反转器3以可旋转的方式设在高压正极板1和高压负极板2之间,且离子反转器3的轴线与高压正极板1的板面平行。绝缘离子收集器4的横截面为矩形结构,且设在离子反转器3的轴线上,绝缘离子收集器4的两侧面分别与高压正极板1和高压负极板2平行。圆筒型离子反转器3的一端为盐水进水口,另一端为淡水出水口,阴阳离子由绝缘离子收集器4收集并排出。 Fig. 1 is a schematic structural diagram of a high-voltage electrostatic seawater desalinator based on ion inversion, and Fig. 2 is a schematic diagram of a partial structure of an ion inverter in a high-voltage electrostatic seawater desalinator based on ion inversion, as shown in the figure. A high-voltage electrostatic seawater desalinator based on ion reversal includes a high-voltage positive plate 1 , a high-voltage negative plate 2 , a cylindrical ion reverser 3 and an insulated ion collector 4 . The high-voltage positive plate 1 and the high-voltage negative plate 2 are arranged in parallel, and the ion inverter 3 is arranged between the high-voltage positive plate 1 and the high-voltage negative plate 2 in a rotatable manner, and the axis of the ion inverter 3 is aligned with the high-voltage positive plate 1. The boards are parallel. The cross-section of the insulating ion collector 4 is a rectangular structure and is arranged on the axis of the ion inverter 3 . The two sides of the insulating ion collector 4 are parallel to the high-voltage positive plate 1 and the high-voltage negative plate 2 respectively. One end of the cylindrical ion inverter 3 is a brine water inlet, and the other end is a fresh water outlet, and the anions and cations are collected and discharged by the insulating ion collector 4 .

其中,离子反转器3的内圆上沿轴向均布设有多个叶片5,离子反转器3的内圆在圆周方向上均布设有多个与叶片垂直的圆弧形隔板6,叶片5和圆弧形隔板6的数量可根据实际情况进行确定(如根据离子反转器3的内圆大小进行确定)。离子反转器3的内圆上由叶片5和圆弧形隔板6分割为多个凹陷区域。离子反转器3的内圆上的叶片沿顺时针方向倾斜设置。绝缘离子收集器4的两侧面上分别设有横向隔板7和纵向隔板8,绝缘离子收集器4的两侧面由横向隔板7和纵向隔板8分割为多个内凹区域。凹陷区域和内凹区域用于存储离子,防止水在轴线方向流动时带走离子。 Wherein, the inner circle of the ion inverter 3 is evenly arranged with a plurality of blades 5 along the axial direction, and the inner circle of the ion inverter 3 is evenly arranged with a plurality of arc-shaped partitions 6 perpendicular to the blades in the circumferential direction, The number of blades 5 and arc-shaped partitions 6 can be determined according to actual conditions (for example, determined according to the size of the inner circle of the ion inverter 3 ). The inner circle of the ion inverter 3 is divided into a plurality of concave regions by blades 5 and arc-shaped partitions 6 . The blades on the inner circle of the ion reverser 3 are inclined clockwise. The two sides of the insulating ion collector 4 are respectively provided with a transverse partition 7 and a longitudinal partition 8 , and the two sides of the insulating ion collector 4 are divided into a plurality of concave regions by the transverse partition 7 and the longitudinal partition 8 . The recessed area and the concave area are used to store ions and prevent the water from taking away the ions when it flows in the axial direction.

本实施例中,离子反转器3的内圆和叶片5的两侧壁设有垂直于轴线的凸棱9,防止离子随水的流动被水带出离子反转器3而降低海水的淡化效率。离子反转器3中的盐水流动速度不能太快,海水在离子反转器3内需缓慢流动,以保证最多的离子反转。避免交换的离子被流过的水带到淡水出水口排出。 In this embodiment, the inner circle of the ion reverser 3 and the two side walls of the blades 5 are provided with ribs 9 perpendicular to the axis to prevent the ions from being taken out of the ion reverser 3 by the water along with the flow of water, thereby reducing the desalination of seawater efficiency. The flow rate of the brine in the ion reverser 3 cannot be too fast, and the seawater needs to flow slowly in the ion reverser 3 to ensure the most ion reversal. Prevent the exchanged ions from being brought to the fresh water outlet by the flowing water.

离子反转器3旋转,而高压正极板1和高压负极板2静止,盐水由离子反转器3流入。当高压正极板1和高压负极板2带高压电时,强电场会在两电极之间形成,方向由高压正极板1到高压负极板2。阴离子始终受到向左的电场力,而阳离子始终受到向右的电场力。离子反转器3内盐水中的阴离子在向左电场力的作用下向左边运动,离子反转器3内左侧壁阴离子浓度较高;而阳离子向右运动,离子反转器3内左侧壁阴离子浓度较高。当离子反转器3顺时针旋转时,阴离子由于受到叶片5的限制而随着离子反转器3的旋转而由低电势能位置旋转至高势能位置,并在叶片5一定角度时,被电场力带出,加速并运动到绝缘离子收集器4的右侧壁,富集并被排出,阳离子与阴离子类似。该海水淡化器能高效淡化海水、苦咸水和处理部分工业废水。 The ion reverser 3 rotates, while the high-voltage positive plate 1 and the high-voltage negative plate 2 are stationary, and the brine flows in from the ion reverser 3 . When the high-voltage positive plate 1 and the high-voltage negative plate 2 are charged with high voltage, a strong electric field will be formed between the two electrodes, and the direction is from the high-voltage positive plate 1 to the high-voltage negative plate 2 . Anions always experience a leftward electric field force, while cations always experience a rightward electric field force. The anions in the brine in the ion inverter 3 move to the left under the action of the electric field force to the left, and the anion concentration on the left wall of the ion inverter 3 is relatively high; while the cations move to the right, and the left side of the ion inverter 3 Higher concentration of wall anions. When the ion inverter 3 rotates clockwise, the negative ions rotate from the low potential energy position to the high potential energy position with the rotation of the ion inverter 3 due to the restriction of the blade 5, and when the blade 5 is at a certain angle, the anions are attracted by the electric field force Take out, accelerate and move to the right side wall of the insulating ion collector 4, enrich and be discharged, cations are similar to anions. The seawater desalinator can efficiently desalinate seawater, brackish water and process some industrial waste water.

高压正极板1与高压负极板2之间的静电压在绝缘许可的条件下尽可能大,而距离尽可能小,以提高电场强度而增强离子的电场力,使离子收集浓度提高。离子反转器3上的凸棱9数量尽量多、凸棱壁尽量薄,这样离子反转器3内壁被划分的凹陷区域数量多,增加离子浓度梯度和反转效果。绝缘离子收集器4的壁尽量薄,增加其两侧面异性离子间的吸引力,提高离子的富集浓度。绝缘离子收集器4上设有凸棱,凸棱量尽量多、凸棱壁尽量薄,增加离子浓度梯度和反转效果。 The electrostatic voltage between the high-voltage positive plate 1 and the high-voltage negative plate 2 is as large as possible under the condition of insulation permitting, while the distance is as small as possible, so as to increase the electric field strength and enhance the electric field force of ions, so that the concentration of ion collection is increased. The number of ribs 9 on the ion inverter 3 is as many as possible, and the walls of the ribs are as thin as possible, so that the inner wall of the ion inverter 3 is divided into a large number of recessed areas, increasing the ion concentration gradient and the inversion effect. The wall of the insulating ion collector 4 is as thin as possible to increase the attraction force between opposite ions on its two sides and increase the enrichment concentration of ions. The insulating ion collector 4 is provided with convex ribs, the amount of convex ribs is as large as possible, and the walls of the convex ribs are as thin as possible, so as to increase the ion concentration gradient and reverse effect.

在电场力的作用之下,离子反转器3内对应两侧壁处的离子始终被束缚在离子反转器3的凹陷区域。当离子反转器3顺时针旋转时,由于叶片5、弧形隔板6和凸棱9的共同限制,离子会随着离子反转器3的旋转而被带到绝缘离子收集器4的另一边。在一定角度和电场力的作用下,离子被倾倒出凹陷区域,最后聚集到绝缘离子收集器4侧壁上的内凹区域。绝缘离子收集器4的侧壁上也分布同样的凸棱。离子反转器3使大量离子从低势能位置移动到高势能位置,然后在电场力的作用下,汇聚于绝缘离子收集器两侧壁。 Under the action of the electric field force, the ions at the corresponding two side walls in the ion inverter 3 are always bound in the concave region of the ion inverter 3 . When the ion reverser 3 rotates clockwise, the ions will be brought to the other side of the insulating ion collector 4 along with the rotation of the ion reverser 3 due to the joint limitation of the blade 5, the arc-shaped partition 6 and the rib 9 side. Under the action of a certain angle and electric field force, the ions are poured out of the recessed area, and finally gather in the inner recessed area on the side wall of the insulating ion collector 4 . The same ribs are also distributed on the side walls of the insulating ion collector 4 . The ion inverter 3 moves a large number of ions from a position of low potential energy to a position of high potential energy, and then gathers on both side walls of the insulating ion collector under the action of electric field force.

本发明采用高压静电场的静电引力来强行分离海水中的阴阳离子,极大幅度地提高绝缘离子收集器4上的离子浓度。而绝缘离子收集器4的两侧壁聚集异性离子,它们异性相吸的特性使得绝缘离子收集器4上的离子浓度进一步提高,以上特点可以显著提高海水中离子的分离效率。 The present invention uses the electrostatic attraction of the high-voltage electrostatic field to forcibly separate anion and cation in seawater, and greatly increases the ion concentration on the insulating ion collector 4 . The two sidewalls of the insulating ion collector 4 gather opposite-sex ions, and their opposite-sex attraction characteristics further increase the ion concentration on the insulating ion collector 4. The above characteristics can significantly improve the separation efficiency of ions in seawater.

最后说明的是,以上实施例仅用以说明本发明的技术方案而非限制,尽管参照较佳实施例对本发明进行了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的宗旨和范围,其均应涵盖在本发明的权利要求范围当中。 Finally, it is noted that the above embodiments are only used to illustrate the technical solutions of the present invention without limitation. Although the present invention has been described in detail with reference to the preferred embodiments, those of ordinary skill in the art should understand that the technical solutions of the present invention can be carried out Modifications or equivalent replacements without departing from the spirit and scope of the technical solution of the present invention shall be covered by the claims of the present invention.

Claims (1)

1. the high pressure static electricity type fresh-water generator based on ion inversion is characterized in that: the ion inversion device (3) and the insulation ion collector (4) that comprise high-voltage positive electrode plate (1), high voltage negative plate (2), round tube type; Described high-voltage positive electrode plate (1) be arranged in parallel with high voltage negative plate (2), described ion inversion device (3) rotatably is located between high-voltage positive electrode plate (1) and the high voltage negative plate (2), and the axis of ion inversion device (3) is parallel with the plate face of high-voltage positive electrode plate (1); The cross section of described insulation ion collector (4) is a rectangular configuration, and is located on the axis of ion inversion device (3), and the two sides of insulation ion collector (4) are parallel with high voltage negative plate (2) with high-voltage positive electrode plate (1) respectively;
Be laid with a plurality of blades (5) on the interior circle of described ion inversion device (3) vertically, the blade on the interior circle of described ion inversion device (3) is obliquely installed along clockwise direction; The interior circle of ion inversion device (3) is laid with a plurality of and the vertical circular arc dividing plate of blade (5) (6) in a circumferential direction; Be divided into a plurality of sunk areas by blade (5) and circular arc dividing plate (6) on the interior circle of described ion inversion device (3);
Be respectively equipped with lateral partitions (7) and wash plate (8) on the two sides of described insulation ion collector (4), the two sides of described insulation ion collector (4) are divided into a plurality of indents zone by lateral partitions (7) and wash plate (8).
CN2011101524250A 2011-06-08 2011-06-08 High-voltage electrostatic seawater desalination device based on ion reversal Expired - Fee Related CN102276028B (en)

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CN108101167A (en) * 2018-01-31 2018-06-01 许玉蕊 High-pressure electrostatic sewage-treatment plant
CN108191010A (en) * 2018-01-31 2018-06-22 许玉蕊 Column electrostatic sewage-treatment plant
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CN102583666A (en) * 2012-02-23 2012-07-18 重庆理工大学 High pressure electrostatic type ion spraying type seawater demineralizer and seawater desalination method thereof
CN108101167A (en) * 2018-01-31 2018-06-01 许玉蕊 High-pressure electrostatic sewage-treatment plant
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