CN102232382A - Bactericidal composition containing trifloxystrobin and thiocarbamates - Google Patents
Bactericidal composition containing trifloxystrobin and thiocarbamates Download PDFInfo
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- CN102232382A CN102232382A CN2011100789930A CN201110078993A CN102232382A CN 102232382 A CN102232382 A CN 102232382A CN 2011100789930 A CN2011100789930 A CN 2011100789930A CN 201110078993 A CN201110078993 A CN 201110078993A CN 102232382 A CN102232382 A CN 102232382A
- Authority
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- China
- Prior art keywords
- bacterium ester
- oxime bacterium
- bactericidal composition
- mancozeb
- carbatene
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 36
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 35
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 title claims abstract description 5
- 239000005857 Trifloxystrobin Substances 0.000 title abstract description 4
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 title abstract description 4
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims abstract description 76
- 239000005802 Mancozeb Substances 0.000 claims abstract description 47
- 239000011717 all-trans-retinol Substances 0.000 claims abstract description 38
- 235000019169 all-trans-retinol Nutrition 0.000 claims abstract description 38
- 241000221785 Erysiphales Species 0.000 claims abstract description 14
- 241000233679 Peronosporaceae Species 0.000 claims abstract description 10
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 9
- 235000009566 rice Nutrition 0.000 claims abstract description 9
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 240000007594 Oryza sativa Species 0.000 claims abstract 2
- 150000002148 esters Chemical class 0.000 claims description 109
- 241000894006 Bacteria Species 0.000 claims description 108
- 150000002923 oximes Chemical class 0.000 claims description 108
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 claims description 46
- 241000918585 Pythium aphanidermatum Species 0.000 claims description 2
- 206010039509 Scab Diseases 0.000 claims description 2
- 239000000375 suspending agent Substances 0.000 abstract description 24
- 239000004562 water dispersible granule Substances 0.000 abstract description 18
- 201000010099 disease Diseases 0.000 abstract description 11
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 11
- 239000004480 active ingredient Substances 0.000 abstract description 4
- 239000005809 Metiram Substances 0.000 abstract description 2
- 229920000257 metiram Polymers 0.000 abstract description 2
- 239000000546 pharmaceutical excipient Substances 0.000 abstract 1
- -1 fluoro-m-tolyl Chemical group 0.000 description 23
- 239000003814 drug Substances 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- 240000008067 Cucumis sativus Species 0.000 description 14
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 14
- 238000012360 testing method Methods 0.000 description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 229920002472 Starch Polymers 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 11
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- 239000008107 starch Substances 0.000 description 11
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 230000003449 preventive effect Effects 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 9
- 229910021641 deionized water Inorganic materials 0.000 description 9
- 239000006185 dispersion Substances 0.000 description 9
- 239000008187 granular material Substances 0.000 description 9
- ZEVCJZRMCOYJSP-UHFFFAOYSA-N sodium;2-(dithiocarboxyamino)ethylcarbamodithioic acid Chemical compound [Na+].SC(=S)NCCNC(S)=S ZEVCJZRMCOYJSP-UHFFFAOYSA-N 0.000 description 9
- 239000000575 pesticide Substances 0.000 description 8
- 230000001018 virulence Effects 0.000 description 8
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 7
- 241000209094 Oryza Species 0.000 description 7
- 150000004996 alkyl benzenes Chemical class 0.000 description 7
- 239000003899 bactericide agent Substances 0.000 description 7
- 239000011575 calcium Substances 0.000 description 7
- 229910052791 calcium Inorganic materials 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 230000002195 synergetic effect Effects 0.000 description 7
- 239000005995 Aluminium silicate Substances 0.000 description 6
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- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
- 235000012211 aluminium silicate Nutrition 0.000 description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
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- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 5
- 229940079593 drug Drugs 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
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- 229920001296 polysiloxane Polymers 0.000 description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
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- 229920001732 Lignosulfonate Polymers 0.000 description 4
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
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- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 4
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 4
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- 239000000417 fungicide Substances 0.000 description 4
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- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 4
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- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 3
- 206010059866 Drug resistance Diseases 0.000 description 3
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- 206010067482 No adverse event Diseases 0.000 description 3
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- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
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- 235000010493 xanthan gum Nutrition 0.000 description 3
- 229940082509 xanthan gum Drugs 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Natural products CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 2
- 206010034133 Pathogen resistance Diseases 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- LCTONWCANYUPML-UHFFFAOYSA-N Pyruvic acid Chemical compound CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
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- 239000007884 disintegrant Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 2
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000002070 germicidal effect Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 230000036039 immunity Effects 0.000 description 2
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- 244000052769 pathogen Species 0.000 description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
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- 239000000080 wetting agent Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- JCUDAMKYTWVICI-UHFFFAOYSA-N 4-benzyl-2,3-dimethylphenol Chemical compound C1=C(O)C(C)=C(C)C(CC=2C=CC=CC=2)=C1 JCUDAMKYTWVICI-UHFFFAOYSA-N 0.000 description 1
- 241000235349 Ascomycota Species 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- 241000255789 Bombyx mori Species 0.000 description 1
- GIYOYTQPIBIOOJ-UHFFFAOYSA-N C(N)(=S)[Mn] Chemical compound C(N)(=S)[Mn] GIYOYTQPIBIOOJ-UHFFFAOYSA-N 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241000233654 Oomycetes Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229930182692 Strobilurin Natural products 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- GMSWRMUHJLKEIL-UHFFFAOYSA-N azane;ethene Chemical compound N.C=C GMSWRMUHJLKEIL-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940054066 benzamide antipsychotics Drugs 0.000 description 1
- 150000003936 benzamides Chemical class 0.000 description 1
- HEEYEDNZYXRUQB-UHFFFAOYSA-N benzene;carbamothioic s-acid Chemical class NC(S)=O.C1=CC=CC=C1 HEEYEDNZYXRUQB-UHFFFAOYSA-N 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
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- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 229940125532 enzyme inhibitor Drugs 0.000 description 1
- 239000002532 enzyme inhibitor Substances 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
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- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 description 1
- 229920000940 maneb Polymers 0.000 description 1
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
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- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 229940107700 pyruvic acid Drugs 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a bactericidal composition containing trifloxystrobin and thiocarbamates. Effective active ingredients of the bactericidal composition are (A) the trifloxystrobin and (B) one of metiram, zineb or mancozeb, wherein the weight ratio of the A to the B is 1:1-1:80. Aids and excipients are added into the effective active ingredients to form water dispersible granules, a suspending agent and the like. The bactericidal composition is mainly used for controlling powdery mildew, leaf spot, downy mildew, rust disease, rice blast and the like.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of preparation and application that contains the bactericidal composition of oxime bacterium ester and thiocarbamates.
Technical background
Oxime bacterium ester (trifloxystrobin), molecular formula: C
20H
19F
3N
2O
4, chemical name: methyl (E)-methoxyl group imido grpup-(E)-and α-[1-(α, α-three fluoro-m-tolyl)-ethyleneimino oxygen base]-o-tolyl } ethyl acetate.Oxime bacterium ester class wide-spectrum bactericide is the new fluorine-containing bactericide of successfully developing as the bactericide lead compound from natural products Strobilurins of a class.Characteristics such as having efficient, wide spectrum, protection, treat, root out, infiltration, systemic activity, resistance of rainwater washing against, lasting period are long.To 1,4-demethylation enzyme inhibitor, benzamides, the bacterial strain of dicarboxyl amine and benzimidazole generation resistance is effective, does not have cross resistance with at present existing bactericide.Nearly all Mycophytes (Ascomycetes, Basidiomycetes, Oomycete and Fungi Imperfecti) disease such as powdery mildew, rust, Ying's rot, net blotch, downy mildew, rice blast etc. all there is good activity.To crop safety, because of its at soil, capable of being fast degraded in the water, so environmentally safe.
Carbatene (metiram), chemical name: two (the two thiocarbamate esters) zinc (2+) of three [ammonia] ethene)] [8-connects dithione for tetrahydrochysene-1,4,7-two thiophene diazocines-3], polymer.
Carbatene is a kind of good protective fungicide, belongs to low-toxin farm chemicals.Because wide, the difficult resistance that produces of its bactericidal range, control efficiency obviously is better than other same series bactericidal agents, so consumption is a large tonnage product in the world always.Be the substitute products of present other protective fungicides, effect is remarkable, steady quality, reliable.
Zineb (zineb), molecular formula are C
4H
6N
2S
4Zn, chemical name: zinc ethylenebisdithiocarbamate.
Zineb belongs to the benzene thiocarbamates; it is the protectant that a kind of foliage spray is used; to plant safety; the active ingredient chemical property is more active, easily is oxidized to different thiocyanation compound in water, to the cause of disease thalline contain-enzyme of SH base has had strong inhibitory effects; and the direct kill pathogens spore of energy; suppress the germination of spore, stop in the germ invaded plants body, but very little to the mycelial lethal effect of cause of disease in the invaded plants body.
Mancozeb (mancozeb) molecular formula: C
4H
6N
2S
4MnZn chemical name: the complex salt of two two thiocarbamoyl manganese of ethylene and zinc.
Mancozeb is the complex that maneb and zinc are formed, and belongs to the wider protective fungicide of fungicidal spectrum.It mainly is the oxidation that suppresses pyruvic acid in the thalline.Effective to multiple diseases such as the anthracnose on fruit tree, the vegetables, early blight, simultaneously its normal and systemic fungicide is mixed, and is used for the generation of delaying drug resistance.
No matter be oxime bacterium ester, zineb, Carbatene, mancozeb or other efficient germicides, long-term use separately makes disease develop immunity to drugs easily, causes the problem that dosage strengthens, preventive effect reduces, the lasting period shortens, and is unfavorable for environment sustainable development.And a kind ofly do not have the novel pesticide of cross resistance to prevent and treat pathogen if want newly developed, and then need screen 10,000～1.5 ten thousand compounds, expensive 1～1.5 hundred million dollar, the construction cycle is 6～10 years.And that the active ingredient of the different mechanisms of action is carried out is composite, is to delay the disease method commonly used that develops immunity to drugs, and according to the effect in the production application, judge this composite be synergistic effect or antagonism.Complex role is more significantly filled a prescription, and can obviously improve preventive effect, reduces the dosage of agricultural chemicals greatly, also can enlarge fungicidal spectrum, improves germicidal efficiency.
Oxime bacterium ester is different with the mechanism of action of zineb, Carbatene, mancozeb, and mutually composite have good synergistic effect within the specific limits.And composite about oxime bacterium ester and zineb, Carbatene, mancozeb do not see relevant report at present at home and abroad as yet.
Summary of the invention
The objective of the invention is to propose a kind of generation or delaying drug resistance speed that can prevent disease drug resistance, the bactericidal composition that use cost is low, preventive effect is good.
The present invention is achieved through the following technical solutions:
A kind of bactericidal composition that contains oxime bacterium ester, wherein oxime bacterium ester and Carbatene, zineb or mancozeb weight ratio are 1: 1～1: 80.
The described bactericidal composition that contains oxime bacterium ester, wherein the weight ratio of oxime bacterium ester and Carbatene, zineb or mancozeb be preferably 1: 3～1: 50.
The described bactericidal composition that contains oxime bacterium ester, wherein the weight ratio of oxime bacterium ester and Carbatene, zineb or mancozeb is more preferably 1: 6～1: 30.
The described bactericidal composition that contains oxime bacterium ester, wherein the weight ratio of oxime bacterium ester and Carbatene, zineb or mancozeb is more preferably 1: 6～1: 15.
The described bactericidal composition that contains oxime bacterium ester connection, wherein the effective active component content accounts for 1～90% of gross weight, is preferably 10～80%.
The described bactericidal composition that contains oxime bacterium ester is according to method known in those skilled in the art, adds corresponding additive and filler, make agricultural and go up any formulation that allows, more preferably as: wetting powder, water dispersible granules, suspending agent or suspension emulsion.
Described auxiliary agent has dispersant, wetting agent, disintegrant, binding agent, defoamer, antifreeze, thickener.
Described dispersant is selected from polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, in phonetic one or more of polyoxyethylene carboxylate, ester polyoxyethylene.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described binding agent is selected from: one or more in diatomite, starch, PVA, carboxymethyl (ethyl) cellulose.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described defoamer is selected from: one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound.
Described thickener is selected from: one or more in xanthan gum, polyvinyl alcohol, the polyethylene glycol.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, the glucose.
Described emulsifier is selected from: farming breast 500
#(alkyl benzene calcium sulfonate), 600
#Phosphate (phenyl phenol polyoxy ethyl ether phosphate), farming breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), farming breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), farming breast 1600
#In (phenethyl phenol polyoxy ethyl polypropylene-base ether), the ethylene oxide-propylene oxide block copolymer one or more.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention is mainly used in prevents and treats powdery mildew, leaf spot, rust, downy mildew, glume blight, damping off, rice blast, net blotch, anthracnose, apple scab etc.
Wetting powder the key technical indexes of the present invention:
Table 1
Water dispersible granules the key technical indexes of the present invention:
Table 2
Suspending agent the key technical indexes of the present invention:
Table 3
Suspension emulsion the key technical indexes of the present invention:
Table 4
Beneficial effect of the present invention: (1) present composition effective active composition oxime bacterium ester and Carbatene, zineb or mancozeb belong to the bactericide of two kinds of different mechanisms of action, and both are mixed mutually and can produce conflict; (2) present composition shows good synergistic effect in given scope, and preventive effect is apparently higher than single agent, and dosage is little; (3) the present invention not with an organic solvent is not difficult for producing poisoning, is convenient to transportation and storage; (4) present composition has special efficacy to powdery mildew, leaf spot, downy mildew, rust, rice blast.
Embodiment
To further instruction of the present invention, but the present invention is not limited thereto below in conjunction with embodiment.Percentage in following examples all is weight percentage.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Implementation of an application example one: oxime bacterium ester and Carbatene, zineb or mancozeb are composite to the powdery mildew of cucumber Toxicity Determination
After the effective inhibition concentration scope of each medicament was determined in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament powdery mildew of cucumber.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively oxime bacterium ester and Carbatene, zineb or mancozeb shared ratio in combination
A is an oxime bacterium ester
B is Carbatene, zineb or mancozeb
Result of the test is as shown in the table:
Table 5 oxime bacterium ester, Carbatene and composite toxicity test analysis of results table thereof to powdery mildew of cucumber
As shown in Table 5, oxime bacterium ester, Carbatene are to the EC of powdery mildew of cucumber
50Be respectively 0.61mg/L and 26.38mg/L.The virulence of oxime bacterium ester is higher than the virulence of Carbatene.Oxime bacterium ester and Carbatene were mixed in the scope at 1: 1～1: 80 and all show obvious synergistic effect.Wherein, both mixed synergies in 1: 3～1: 50 scope are comparatively desirable, and mixed synergies is particularly outstanding in 1: 6～1: 15 scope.
Table 6 oxime bacterium ester, zineb and composite toxicity test analysis of results table thereof to powdery mildew of cucumber
As shown in Table 6, oxime bacterium ester, zineb are to the EC of powdery mildew of cucumber
50Be respectively 0.48mg/L and 30.32mg/L.The virulence of oxime bacterium ester is higher than the virulence of zineb.Oxime bacterium ester and zineb were mixed in the scope at 1: 1～1: 80 and all show obvious synergistic effect.Wherein, both mixed synergies in 1: 3～1: 50 scope are comparatively desirable, and mixed synergies is particularly outstanding in 1: 6～1: 15 scope.
Table 7 oxime bacterium ester, mancozeb and composite toxicity test analysis of results table thereof to powdery mildew of cucumber
As shown in Table 7, oxime bacterium ester, mancozeb are to the EC of powdery mildew of cucumber
50Be respectively 0.53mg/L and 35.29mg/L.The virulence of oxime bacterium ester is higher than the virulence of mancozeb.Oxime bacterium ester and mancozeb were mixed in the scope at 1: 1～1: 80 and all show obvious synergistic effect.Wherein, both mixed synergies in 1: 3～1: 50 scope are comparatively desirable, and mixed synergies is particularly outstanding in 1: 6～1: 15 scope.
Implementation of an application example two the implementation of Formulation Example
(1) oxime bacterium ester zineb:
Embodiment 1 80% oxime bacterium ester water dispersion granules agent of dithane
Oxime bacterium ester 10%, zineb 70%, alkylphenol-polyethenoxy are phonetic 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, starch 5%, kaolin 5%, mixed 80% oxime bacterium ester water dispersion granules agent of dithane.
Embodiment 2 70% oxime bacterium ester water dispersion granules agent of dithane
Oxime bacterium ester 10%, zineb 60%, polycarboxylate 3%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, starch 7%, kaolin 10%, the mixed 70% oxime bacterium ester water dispersion granules agent of dithane that gets.
Embodiment 3 62% oxime bacterium ester water dispersion granules agent of dithane
Oxime bacterium ester 2%, zineb 60%, alkylphenol-polyethenoxy are phonetic 5%, dodecyl benzene sulfonate 3%, starch 8%, bentonite 22%, mixed 62% oxime bacterium ester water dispersion granules agent of dithane.
Embodiment 4 40% oxime bacterium ester zineb suspending agents
Oxime bacterium ester 10%, zineb 30%, alkyl benzene sulfonate calcium salt 5%, Sodium Polyacrylate 2%, DBSA 4%, silicone oil 0.1%, xanthan gum 0.3%, phenyl phenol polyoxy ethyl ether 2%, deionized water adds to 100%, the mixed 40% oxime bacterium ester zineb suspending agent that gets.
Embodiment 5 30% oxime bacterium ester zineb suspending agents
Oxime bacterium ester 15%, zineb 15%, polycarboxylate 4%, soapberry powder 5%, silicone compound 0.1%, hydroxyethylcellulose 0.1%, ethylene glycol 2%, alkyl benzene calcium sulfonate 2%, deionized water adds to 100%, the mixed 30% oxime bacterium ester zineb suspending agent that gets.
Embodiment 6 28% oxime bacterium ester zineb suspending agents
Oxime bacterium ester 4%, zineb 24%, polycarboxylate 2%, Nekal BX 2%, C10-20 saturated fat acid compounds 0.1%, polyethylene glycol 0.5%, ethylene glycol 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 1%, deionized water adds to 100%, the mixed 28% oxime bacterium ester zineb suspending agent that gets.
(2) oxime bacterium ester mancozeb
Embodiment 7 80% oxime bacterium ester mancozeb water dispersible granules
Oxime bacterium ester 20%, mancozeb 60%, alkylphenol-polyethenoxy are phonetic 3%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, starch 10%, mixed 80% oxime bacterium ester mancozeb water dispersible granule.
Embodiment 8 60% oxime bacterium ester mancozeb water dispersible granules
Oxime bacterium ester 5%, mancozeb 55%, polycarboxylate 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, starch 7%, kaolin 20%, the mixed 60% oxime bacterium ester mancozeb water dispersible granule that gets.
Embodiment 9 48% oxime bacterium ester mancozeb water dispersible granules
Oxime bacterium ester 8%, mancozeb 40%, alkylphenol-polyethenoxy are phonetic 4%, DBSA 4%, starch 15%, diatomite 22%, mixed 48% oxime bacterium ester mancozeb water dispersible granule.
Embodiment 10 40% oxime bacterium ester mancozeb suspending agents
Oxime bacterium ester 20%, mancozeb 20%, polycarboxylate 4%, soapberry powder 5%, silicone compound 0.1%, hydroxyethylcellulose 0.1%, ethylene glycol 2%, alkyl benzene calcium sulfonate 2%, deionized water adds to 100%, the mixed 40% oxime bacterium ester mancozeb suspending agent that gets.
Embodiment 11 36% oxime bacterium ester mancozeb suspending agents
Oxime bacterium ester 6%, mancozeb 30%, polycarboxylate 2%, Nekal BX 2%, C10-20 saturated fat acid compounds 0.1%, polyethylene glycol 0.5%, ethylene glycol 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 1%, deionized water adds to 100%, the mixed 36% oxime bacterium ester mancozeb suspending agent that gets.
Embodiment 12 15% oxime bacterium ester mancozeb suspending agents
Oxime bacterium ester 5%, mancozeb 10%, polycarboxylate 2%, neopelex 2%, silicone compound 0.1%, polyethylene glycol 0.5%, glycerine 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 1%, deionized water adds to 100%, the mixed 15% oxime bacterium ester mancozeb suspending agent that gets.
(3) oxime bacterium ester Carbatene:
Embodiment 13 80% oxime bacterium ester Carbatene water dispersible granules
Oxime bacterium ester 10%, Carbatene 70%, alkylphenol-polyethenoxy are phonetic 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, starch 5%, kaolin 5%, mixed 80% oxime bacterium ester Carbatene water dispersible granules.
Embodiment 14 70% oxime bacterium ester Carbatene water dispersible granules
Oxime bacterium ester 10%, Carbatene 60%, polycarboxylate 3%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, starch 7%, kaolin 10%, the mixed 70% oxime bacterium ester Carbatene water dispersible granules that gets.
Embodiment 15 62% oxime bacterium ester Carbatene water dispersible granules
Oxime bacterium ester 2%, Carbatene 60%, alkylphenol-polyethenoxy are phonetic 5%, dodecyl benzene sulfonate 3%, starch 8%, bentonite 22%, mixed 62% oxime bacterium ester Carbatene water dispersible granules.
Embodiment 16 40% oxime bacterium ester Carbatene suspending agents
Oxime bacterium ester 20%, Carbatene 20%, alkyl benzene sulfonate calcium salt 5%, Sodium Polyacrylate 2%, DBSA 4%, silicone oil 0.1%, xanthan gum 0.3%, phenyl phenol polyoxy ethyl ether 2%, deionized water adds to 100%, the mixed 40% oxime bacterium ester Carbatene suspending agent that gets.
Embodiment 17 35% oxime bacterium ester Carbatene suspending agents
Oxime bacterium ester 5%, Carbatene 30%, polycarboxylate 4%, soapberry powder 5%, silicone compound 0.1%, hydroxyethylcellulose 0.1%, ethylene glycol 2%, alkyl benzene calcium sulfonate 2%, deionized water adds to 100%, the mixed 35% oxime bacterium ester Carbatene suspending agent that gets.
Embodiment 18 30% oxime bacterium ester Carbatene suspending agents
Oxime bacterium ester 3%, Carbatene 27%, polycarboxylate 2%, Nekal BX 2%, C10-20 saturated fat acid compounds 0.1%, polyethylene glycol 0.5%, ethylene glycol 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 1%, deionized water adds to 100%, the mixed 30% oxime bacterium ester Carbatene suspending agent that gets.
Embodiment uses three bactericidal compositions that contain oxime bacterium ester and prevents and treats the cucumber downy mildew test of pesticide effectiveness
This experimental establishment is in suburb, Tianshui, Gansu Province, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 80% water dispersion granules agent of dithane (commercial), 80% mancozeb wettable powder (commercial), 70% Carbatene water dispersible granules (commercial), 25% oxime bacterium ester suspending agent (commercial).
The investigation cucumber downy mildew state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated the cucumber downy mildew disease index respectively and calculated preventive effect in 7 days, 21 days after the dispenser for the second time.Experimental result is as follows:
Table 8 contains the bactericidal composition control cucumber downy mildew test of pesticide effectiveness of oxime bacterium ester
As can be seen from Table 8, can effectively prevent and treat cucumber downy mildew after oxime bacterium ester and Carbatene, zineb or mancozeb are composite, control efficiency all is better than contrasting medicament, and the lasting period is long.In the test scope of medication target crop is had no adverse effects, preventive effect reaches more than 90%.
Implementation of an application example four: the bactericidal composition control rice blast test of pesticide effectiveness that contains oxime bacterium ester
This experimental establishment is in the Lichuan County, Jiangxi Province, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 80% water dispersion granules agent of dithane (commercial), 80% mancozeb wettable powder (commercial), 70% Carbatene water dispersible granules (commercial), 25% oxime bacterium ester suspending agent (commercial).
Investigation rice blast state of an illness radix before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates disease index respectively and calculates preventive effect in 7 days, 21 days after the dispenser for the second time.Experimental result is as follows:
Table 9 contains the bactericidal composition control rice blast test of pesticide effectiveness of oxime bacterium ester
As can be seen from Table 9, can effectively prevent and treat rice blast after oxime bacterium ester and Carbatene, zineb or mancozeb are composite takes place, control efficiency all is better than contrasting medicament, in this test scope of medication, the target crop is had no adverse effects, and powdery mildew of cucumber had good preventive effect, preventive effect reaches more than 90%.
Implementation of an application example five: the bactericidal composition that contains oxime bacterium ester is prevented and treated the sigatoka test of pesticide effectiveness
This experimental establishment is at Hu County, Shaanxi Province Li Jiacun, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 80% water dispersion granules agent of dithane (commercial), 80% mancozeb wettable powder (commercial), 70% Carbatene water dispersible granules (commercial), 25% oxime bacterium ester suspending agent (commercial).
Investigation sigatoka state of an illness radix, total number of sheets, the sick number of sheets and sick leaf-size class number before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 3 times, investigates disease index respectively and calculates preventive effect in 7 days, 21 days after the dispenser for the second time.Experimental result is as follows:
Table 10 contains the bactericidal composition of oxime bacterium ester and prevents and treats the sigatoka test of pesticide effectiveness
As can be seen from Table 10, can effectively prevent and treat sigatoka after oxime bacterium ester and zineb, Carbatene, mancozeb are composite and take place, control efficiency all is better than contrasting medicament, in this test scope of medication the target crop is had no adverse effects.
Claims (8)
1. bactericidal composition that contains oxime bacterium ester and thiocarbamates is characterized in that bactericidal composition effective active composition (A) oxime bacterium ester and a kind of weight ratio in (B) Carbatene, zineb or the mancozeb are 1: 1～1: 80.
2. bactericidal composition according to claim 1 is characterized in that: wherein (A) oxime bacterium ester is 1: 3～1: 50 with a kind of weight ratio in (B) Carbatene, zineb or the mancozeb.
3. bactericidal composition according to claim 2 is characterized in that: wherein (A) oxime bacterium ester is 1: 6～1: 30 with (B) weight ratio of Carbatene.
4. bactericidal composition according to claim 2 is characterized in that: wherein (A) oxime bacterium ester is 1: 6～1: 30 with (B) weight ratio of zineb.
5. bactericidal composition according to claim 2 is characterized in that: wherein (A) oxime bacterium ester is 1: 6～1: 30 with (B) weight ratio of mancozeb.
6. bactericidal composition according to claim 1 is characterized in that: wherein the effective active component content accounts for 1～90% of gross weight.
7. bactericidal composition according to claim 6 is characterized in that: wherein the effective active component content accounts for 10～80% of gross weight.
8. bactericidal composition according to claim 1 is used to prevent and treat powdery mildew, leaf spot, rust, downy mildew, glume blight, damping off, rice blast, net blotch, anthracnose, the apple scab of crop.
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| CN109601544A (en) * | 2019-01-11 | 2019-04-12 | 兴农药业（中国）有限公司 | A kind of composition pesticide containing Carbatene and trifloxystrobin and its application |
| EP3073826B1 (en) * | 2013-11-26 | 2019-10-30 | UPL Limited | A method for controlling soybean rust |
| CN110710536A (en) * | 2018-07-13 | 2020-01-21 | 江苏龙灯化学有限公司 | Application of bactericidal composition containing trifloxystrobin and mancozeb |
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| CN101069511A (en) * | 2006-05-09 | 2007-11-14 | 陶氏农业科学公司 | Stabilized fungus-killing agent composition |
| CN101253864A (en) * | 2008-03-28 | 2008-09-03 | 中国农业大学 | Bactericidal composition containing mancozeb and methoxyacrylate fungicides |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101069511A (en) * | 2006-05-09 | 2007-11-14 | 陶氏农业科学公司 | Stabilized fungus-killing agent composition |
| CN101253864A (en) * | 2008-03-28 | 2008-09-03 | 中国农业大学 | Bactericidal composition containing mancozeb and methoxyacrylate fungicides |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| EP3073826B1 (en) * | 2013-11-26 | 2019-10-30 | UPL Limited | A method for controlling soybean rust |
| EP4014741A1 (en) * | 2013-11-26 | 2022-06-22 | UPL Ltd | A method for controlling rust |
| CN110710536A (en) * | 2018-07-13 | 2020-01-21 | 江苏龙灯化学有限公司 | Application of bactericidal composition containing trifloxystrobin and mancozeb |
| CN110710536B (en) * | 2018-07-13 | 2021-07-06 | 江苏龙灯化学有限公司 | Application of bactericidal composition containing trifloxystrobin and mancozeb |
| CN109601544A (en) * | 2019-01-11 | 2019-04-12 | 兴农药业（中国）有限公司 | A kind of composition pesticide containing Carbatene and trifloxystrobin and its application |
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