CN102126847B - Fireproof quick-drying type spraying material - Google Patents
Fireproof quick-drying type spraying material Download PDFInfo
- Publication number
- CN102126847B CN102126847B CN 201010623696 CN201010623696A CN102126847B CN 102126847 B CN102126847 B CN 102126847B CN 201010623696 CN201010623696 CN 201010623696 CN 201010623696 A CN201010623696 A CN 201010623696A CN 102126847 B CN102126847 B CN 102126847B
- Authority
- CN
- China
- Prior art keywords
- parts
- quick
- water
- spraying material
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
本发明公开一种防火快干型喷涂材料，该喷涂材料按重量份配比由以下组分组成：硅酸盐水泥200份，重质碳酸钙20～40份，添加剂8～30份，速凝剂40～70份，膨润土5～15份，水120～135份；所述添加剂按重量份配比由以下组分组成：木质素磺酸钠5～15份，硬脂酸钙2～8份，羧甲基纤维素钠0.8～2份，烷基苯磺酸钠0.2～2份，石膏粉4～30份，减水剂12～30份，早强剂10～30份。本发明在保持较高表面喷涂强度的基础上，具有喷涂回弹率低的特点，且具有较好的挂壁性与流动性以及较高的韧性，凝结后具有良好的阻燃抗烧能力。The invention discloses a fire-proof and quick-drying spraying material. The spraying material is composed of the following components in proportion by weight: 200 parts of Portland cement, 20-40 parts of heavy calcium carbonate, 8-30 parts of additives, quick-setting 40-70 parts of agent, 5-15 parts of bentonite, 120-135 parts of water; the additive is composed of the following components in proportion by weight: 5-15 parts of sodium lignosulfonate, 2-8 parts of calcium stearate , 0.8-2 parts of sodium carboxymethyl cellulose, 0.2-2 parts of sodium alkylbenzene sulfonate, 4-30 parts of gypsum powder, 12-30 parts of water reducing agent, and 10-30 parts of early strength agent. On the basis of maintaining high surface spraying strength, the invention has the characteristics of low spraying rebound rate, good wall-hanging property, fluidity and high toughness, and good flame-retardant and anti-burning ability after condensation.
Description
Technical field
The present invention relates to a kind of spray material, be specifically related to a kind of fire prevention quick-dry type spray material.
Background technology
At present, in process of coal mining,, need to adopt spray material to carry out tunnel or the filling of longwall face country rock inbreak spatial in order to improve security.In the prior art,, mostly exist toughness index not high enough though spray material is of a great variety, mobile, wall built-up property is relatively poor, does not have problems such as fire-retardant burnback resistance.
Summary of the invention
In order to solve the problems of the technologies described above, the present invention provides a kind of fire prevention quick-dry type spray material.
Its technical solution is:
A kind of fire prevention quick-dry type spray material, this spray material is composed of the following components by weight ratio:
200 parts of silicate cements
20～40 parts of water-ground limestones
8～30 parts of additives
40～70 parts of accelerating chemicalss
5～15 parts of wilkinites
120～135 parts in water,
Said additive is composed of the following components by weight ratio:
5～15 parts of sodium lignosulfonates
2～8 parts of calcium stearates
0.8～2 part of Xylo-Mucine
0.2～2 part of sodium alkyl benzene sulfonate
4～30 parts of terra albas
12～30 parts of water reducers
10～30 parts of hardening accelerator.
Wherein, mainly the acting as of each component in the additive: sodium lignosulfonate is an anionic surface active substances, and cement is had absorption and dissemination, can improve physicals, reduces water simultaneously, improves workability; Calcium stearate is a tensio-active agent, simultaneously the accelerator for hardening effect is arranged also, in the solidification process, produces calcium class material, improves density; Xylo-Mucine is a tensio-active agent, as dispersing material, helps to form water-soluable gel; Sodium alkyl benzene sulfonate is a tensio-active agent, as dispersing material, helps to form water-soluable gel; Terra alba is a flame-retardant composition, plays early strength function simultaneously, improves rheological and wall built-up property; Water reducer is chosen aliphatic high-efficiency water reducing agent, can lower adsorptive power between the silicate cement particle, reduces water consumption, improves workability; Hardening accelerator can shorten set time, improves early strength.The above-mentioned weight part ratio range of the combination of these components and each component; Confirm that through a large amount of tests the present invention is prevented fires, and coating that the quick-dry type spray material forms has the excellent balance of above-mentioned toughness, flowability, wall built-up property and fire-retardant burnback resistance.
Above-mentioned bentonitic weight part proportion optimization is 10～12 parts, and the weight part proportion optimization of above-mentioned calcium stearate is 6～8 parts, and the weight part proportion optimization of above-mentioned terra alba is 6～12 parts.
A kind of preparation method of the quick-dry type spray material of preventing fires may further comprise the steps:
Choosing sodium lignosulfonate, calcium stearate, Xylo-Mucine, sodium alkyl benzene sulfonate, terra alba, water reducer mixes with hardening accelerator and by above-mentioned weight part proportioning and obtains additive; Again additive and water are mixed by above-mentioned weight part proportioning; Silicate cement, water-ground limestone, accelerating chemicals and wilkinite with above-mentioned weight part after mixing is accomplished place mixer in the lump; Mix, the quick-dry type spray material promptly obtains preventing fires.
Useful technique effect of the present invention is:
The present invention is keeping high surfaces to spray on the intensity based, has the low characteristics of spraying rebound degree, and has wall built-up property and flowability and high toughness preferably, has good fire-retardant burnback resistance after condensing; In addition, raw materials used all can the purchase from market of the present invention obtains, wide material sources, and also price is lower.
Embodiment
Embodiment 1
Choosing sodium lignosulfonate 0.25g, calcium stearate 0.1g, Xylo-Mucine 0.04g, sodium alkyl benzene sulfonate 0.01g, terra alba 0.2g, water reducer 0.6g mixes with hardening accelerator 0.5g and by above-mentioned weight part proportioning and obtains additive; Again additive is placed 12g water; Stirred 1 hour; Place mixer in the lump with 20g silicate cement, 2g water-ground limestone, 4g accelerating chemicals and 0.5g wilkinite after mixing completion; Under normal temperature and normal pressure, stirred 4 hours, promptly obtain the quick-dry type spray material of preventing fires.
Embodiment 2
Choosing sodium lignosulfonate 0.25g, calcium stearate 0.1g, Xylo-Mucine 0.04g, sodium alkyl benzene sulfonate 0.01g, terra alba 0.3g, water reducer 0.6g mixes with hardening accelerator 0.5g and by above-mentioned weight part proportioning and obtains additive; Again additive is placed 13.5g water; Stirred 1 hour; Place mixer in the lump with 20g silicate cement, 4g water-ground limestone, 7g accelerating chemicals and 1.5g wilkinite after mixing completion; Under normal temperature and normal pressure, stirred 4 hours, promptly obtain the quick-dry type spray material of preventing fires.
Embodiment 3
Choosing sodium lignosulfonate 0.25g, calcium stearate 0.1g, Xylo-Mucine 0.04g, sodium alkyl benzene sulfonate 0.01g, terra alba 1g, water reducer 0.6g mixes with hardening accelerator 0.5g and by above-mentioned weight part proportioning and obtains additive; Again additive is placed 12g water; Stirred 1 hour; Place mixer in the lump with 20g silicate cement, 2g water-ground limestone, 7g accelerating chemicals and 1g wilkinite after mixing completion; Under normal temperature and normal pressure, stirred 4 hours, promptly obtain the quick-dry type spray material of preventing fires.
Embodiment 4
Choosing sodium lignosulfonate 0.25g, calcium stearate 0.4g, Xylo-Mucine 0.04g, sodium alkyl benzene sulfonate 0.01g, terra alba 1g, water reducer 0.6g mixes with hardening accelerator 0.5g and by above-mentioned weight part proportioning and obtains additive; Again additive is placed 12g water; Stirred 1 hour; Place mixer in the lump with 20g silicate cement, 2g water-ground limestone, 7g accelerating chemicals and 1g wilkinite after mixing completion; Under normal temperature and normal pressure, stirred 4 hours, promptly obtain the quick-dry type spray material of preventing fires.
Embodiment 5
Choosing sodium lignosulfonate 0.25g, calcium stearate 0.2g, Xylo-Mucine 0.1g, sodium alkyl benzene sulfonate 0.1g, terra alba 0.8g, water reducer 0.6g mixes with hardening accelerator 0.5g and by above-mentioned weight part proportioning and obtains additive; Again additive is placed 12g water; Stirred 1 hour; Place mixer in the lump with 20g silicate cement, 2g water-ground limestone, 4g accelerating chemicals and 0.5g wilkinite after mixing completion; Under normal temperature and normal pressure, stirred 4 hours, promptly obtain the quick-dry type spray material of preventing fires.
Comparative Examples 1
Choosing sodium lignosulfonate 0.1g, calcium stearate 0.1g, Xylo-Mucine 0.04g, sodium alkyl benzene sulfonate 0.01g, terra alba 0.1g, water reducer 0.6g mixes with hardening accelerator 0.5g and by above-mentioned weight part proportioning and obtains additive; Again additive is placed 12g water; Stirred 1 hour; Place mixer in the lump with 20g silicate cement, 2g water-ground limestone and 4g accelerating chemicals after mixing completion, under normal temperature and normal pressure, stirred 4 hours, promptly obtain the quick-dry type spray material of preventing fires.
Comparative Examples 2
Choosing sodium lignosulfonate 0.25g, calcium stearate 4g, Xylo-Mucine 0.2g, sodium alkyl benzene sulfonate 0.1g, terra alba 0.5g, water reducer 0.6g mixes with hardening accelerator 0.5g and by above-mentioned weight part proportioning and obtains additive; Again additive is placed 12g water; Stirred 1 hour; Place mixer in the lump with 20g silicate cement, 2g water-ground limestone, 4g accelerating chemicals and 0.2g wilkinite after mixing completion; Under normal temperature and normal pressure, stirred 4 hours, promptly obtain the quick-dry type spray material of preventing fires.
Wall after polishing flat is divided into 7 all identical zones of sizes and shape with instruments such as chalks; Adopt spray gun to be sprayed on the vertical wall respectively gained fire prevention quick-dry type spray material in embodiment 1,2,3,4,5 and the Comparative Examples 1,2 in order then; The distance (in maximum distance) that corresponding spray material moves down on the every wall is measured in timing 10 minutes after 10 minutes, calculate flow velocity; Flow velocity=distance/10min; Can judge the wall built-up property of gained spray material in corresponding embodiment or the Comparative Examples according to flow velocity, flow velocity is big more, and wall built-up property is poor more.Test result is listed in table 1.
Choose ganoid plank, be divided into 7 all identical zones of sizes and shape, label is distinguished; Adopt spray gun to be sprayed on the corresponding plank respectively gained fire prevention quick-dry type spray material in embodiment 1,2,3,4,5 and the Comparative Examples 1,2 then, coating thickness is 4mm, solidifies 20min; Spraying face to plank pressurizes gradually then, when slight crack appears in spraying face, stops; And write down this moment applied pressure; The big I of pressure is judged the toughness of gained spray material in corresponding embodiment or the Comparative Examples when slight crack occurring, and the pressure when slight crack occurring is big more, and toughness is strong more.Test result is listed in table 1.
Table 1
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010623696 CN102126847B (en) | 2010-12-30 | 2010-12-30 | Fireproof quick-drying type spraying material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010623696 CN102126847B (en) | 2010-12-30 | 2010-12-30 | Fireproof quick-drying type spraying material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102126847A CN102126847A (en) | 2011-07-20 |
| CN102126847B true CN102126847B (en) | 2012-09-05 |
Family
ID=44265170
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010623696 Expired - Fee Related CN102126847B (en) | 2010-12-30 | 2010-12-30 | Fireproof quick-drying type spraying material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102126847B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103693922A (en) * | 2013-09-16 | 2014-04-02 | 山东科技大学 | Mining spraying material formula and application method |
| CN103613310A (en) * | 2013-11-08 | 2014-03-05 | 安徽省阜南绿原化工有限公司 | Enhanced and toughened water reducing agent |
| CN103613311A (en) * | 2013-11-08 | 2014-03-05 | 安徽省阜南绿原化工有限公司 | Bleed air reduction type water reducing agent of |
| CN103613312A (en) * | 2013-11-08 | 2014-03-05 | 安徽省阜南绿原化工有限公司 | Low viscosity water reducer for coal water slurry |
| CN110386797A (en) * | 2019-08-22 | 2019-10-29 | 山东科技大学 | A kind of slim supporting fire proofing material |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3454410A (en) * | 1965-05-03 | 1969-07-08 | Nasa | Alkali-metal silicate protective coating |
| US5401538A (en) * | 1992-04-16 | 1995-03-28 | W.R. Grace & Co.-Conn. | Sprayable portland cement-based fireproofing compositions |
| CN101074158A (en) * | 2007-07-23 | 2007-11-21 | 康跃金 | Efficient thermal-insulating and anti-cracking daub of crystallized waterproofing |
| CN101173120A (en) * | 2006-11-03 | 2008-05-07 | 洛阳佛尔达消防产品有限公司 | Heat-insulation fire-proof paint special for LT type fire bund and method for producing the same |
| CN101250048A (en) * | 2007-02-25 | 2008-08-27 | 陈雄载 | Heat-proof insulation waterproof dry-mixed mortar and preparation thereof |
| CN101265390A (en) * | 2007-03-13 | 2008-09-17 | 何林道 | Multifunctional drying powder thermal insulation paint |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0699177B2 (en) * | 1990-04-13 | 1994-12-07 | 鹿島建設株式会社 | Fireproof coating |
-
2010
- 2010-12-30 CN CN 201010623696 patent/CN102126847B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3454410A (en) * | 1965-05-03 | 1969-07-08 | Nasa | Alkali-metal silicate protective coating |
| US5401538A (en) * | 1992-04-16 | 1995-03-28 | W.R. Grace & Co.-Conn. | Sprayable portland cement-based fireproofing compositions |
| CN101173120A (en) * | 2006-11-03 | 2008-05-07 | 洛阳佛尔达消防产品有限公司 | Heat-insulation fire-proof paint special for LT type fire bund and method for producing the same |
| CN101250048A (en) * | 2007-02-25 | 2008-08-27 | 陈雄载 | Heat-proof insulation waterproof dry-mixed mortar and preparation thereof |
| CN101265390A (en) * | 2007-03-13 | 2008-09-17 | 何林道 | Multifunctional drying powder thermal insulation paint |
| CN101074158A (en) * | 2007-07-23 | 2007-11-21 | 康跃金 | Efficient thermal-insulating and anti-cracking daub of crystallized waterproofing |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102126847A (en) | 2011-07-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2753978T3 (en) | Light composition of fly ash | |
| CN101445353B (en) | Foaming expansive filling agent used for mine fire prevention | |
| CA2725585C (en) | Mixture, in particular construction material mixture containing furnace slag | |
| CN104446213A (en) | Grouting material employing red mud as raw material | |
| CN102126847B (en) | Fireproof quick-drying type spraying material | |
| CN112500056B (en) | Superfine solid waste base grouting material and preparation method thereof | |
| CN105198273A (en) | Concrete compound type chloride-free early strength agent and preparation method thereof | |
| CN104591680A (en) | Cement-based grouting material with aqueous dispersion resistance and high viscosity | |
| CN103496934A (en) | Phosphogypsum-based surface layer plastering gypsum material and preparation method thereof | |
| CN104045374A (en) | Red mud porous material | |
| CN102101787A (en) | Magnesium cement foam material | |
| CN105272075B (en) | A kind of fireproof heat insulating dry powder and mortar and preparation method thereof | |
| CA2912184A1 (en) | Portland cement free activation of ground granulated blast furnace slag | |
| CN104310837B (en) | A kind of dry powder and mortar and additive thereof | |
| CN104150793A (en) | Geopolymer-based steel slag dry-mixed mortar binder | |
| WO2022229433A1 (en) | Binder composition comprising fine filler and fine ground granulated blast furnace slag | |
| KR20180002288A (en) | Grout material composition and high fluidity-grout material using the same | |
| CN101456697A (en) | Delayed coagulation pumping type three-expansion-source concrete expanding agent | |
| CN112354108B (en) | A kind of mine fire extinguishing gel material and preparation method thereof | |
| CN104973840A (en) | Fireproofing bonding mortar and preparation method and application thereof | |
| CN101353489A (en) | Environment-friendly sound-absorbing tunnel fireproof paint | |
| JP2006131488A (en) | Acid resistant grout composition | |
| KR101380326B1 (en) | Solidified agent composition | |
| CN101898884B (en) | Cement waterproof material and preparation method thereof | |
| CN103951355B (en) | Ultra-fine anti-segregation injecting paste material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120905 Termination date: 20121230 |