CN102091339A - Method for enabling oxygen active particle to form hydroxyl radical in gas - Google Patents
Method for enabling oxygen active particle to form hydroxyl radical in gas Download PDFInfo
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- CN102091339A CN102091339A CN2010105671358A CN201010567135A CN102091339A CN 102091339 A CN102091339 A CN 102091339A CN 2010105671358 A CN2010105671358 A CN 2010105671358A CN 201010567135 A CN201010567135 A CN 201010567135A CN 102091339 A CN102091339 A CN 102091339A
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- 239000007789 gas Substances 0.000 title claims abstract description 55
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 52
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 239000001301 oxygen Substances 0.000 title claims abstract description 51
- 239000002245 particle Substances 0.000 title claims abstract description 50
- 238000000034 method Methods 0.000 title claims abstract description 26
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 title 1
- 230000000694 effects Effects 0.000 claims abstract description 45
- 238000006243 chemical reaction Methods 0.000 claims abstract description 28
- 239000003999 initiator Substances 0.000 claims abstract description 14
- 239000003054 catalyst Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- -1 hydroxyl radical free radical Chemical class 0.000 claims description 11
- 230000005684 electric field Effects 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- OUUQCZGPVNCOIJ-UHFFFAOYSA-N hydroperoxyl Chemical group O[O] OUUQCZGPVNCOIJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003344 environmental pollutant Substances 0.000 abstract description 23
- 231100000719 pollutant Toxicity 0.000 abstract description 23
- 238000000746 purification Methods 0.000 abstract description 17
- 230000003647 oxidation Effects 0.000 abstract description 11
- 238000007254 oxidation reaction Methods 0.000 abstract description 11
- 230000008030 elimination Effects 0.000 abstract description 8
- 238000003379 elimination reaction Methods 0.000 abstract description 8
- 239000002250 absorbent Substances 0.000 abstract description 4
- 230000002745 absorbent Effects 0.000 abstract description 4
- 239000003638 chemical reducing agent Substances 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 230000035484 reaction time Effects 0.000 abstract 2
- 238000005516 engineering process Methods 0.000 description 8
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 7
- 239000000356 contaminant Substances 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 241000700605 Viruses Species 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229910017053 inorganic salt Inorganic materials 0.000 description 2
- 150000002896 organic halogen compounds Chemical class 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000033116 oxidation-reduction process Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 description 1
- 201000002909 Aspergillosis Diseases 0.000 description 1
- 208000036641 Aspergillus infections Diseases 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 241000589248 Legionella Species 0.000 description 1
- 208000007764 Legionnaires' Disease Diseases 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241000194017 Streptococcus Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical class ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 230000002498 deadly effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- FRCCEHPWNOQAEU-UHFFFAOYSA-N heptachlor Chemical compound ClC1=C(Cl)C2(Cl)C3C=CC(Cl)C3C1(Cl)C2(Cl)Cl FRCCEHPWNOQAEU-UHFFFAOYSA-N 0.000 description 1
- 206010022000 influenza Diseases 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- LCCNCVORNKJIRZ-UHFFFAOYSA-N parathion Chemical compound CCOP(=S)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 LCCNCVORNKJIRZ-UHFFFAOYSA-N 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Treating Waste Gases (AREA)
Abstract
一种氧活性粒子在气体中形成羟基自由基方法，属于气体电离放电、等离子体化学和环境工程应用技术领域。其特征是浓度为1×107/cm3～4×1018/cm3氧活性粒子〔O2 +、O3、O(1D)、O(3P)〕注入气道或反应器中，其中O2 +与气体中H2O反应生成HO2 -引发剂，氧活性粒子与引发剂HO2 -进行等离子体反应生成·OH，其反应时间为1μs～1ms；·OH氧化消除气体中污染物，其反应时间在0.01s～10s。本发明的效果和益处是解决了目前气体消除污染物存在的问题，实现了不用催化剂、吸收剂和还原剂，不对环境产生任何负面影响的气体净化的新方法。
The invention discloses a method for oxygen active particles to form hydroxyl radicals in gas, which belongs to the technical fields of gas ionization discharge, plasma chemistry and environmental engineering application. It is characterized by the concentration of 1×10 7 /cm 3 ~4×10 18 /cm 3 oxygen active particles [O 2 + , O 3 , O( 1 D), O( 3 P)] injected into the airway or reactor , where O 2 + reacts with H 2 O in the gas to generate HO 2 - initiator, oxygen active particles react with the initiator HO 2 - to generate ·OH in a plasma reaction, and the reaction time is 1μs~1ms; ·OH oxidation eliminates the gas For pollutants, the reaction time is between 0.01s and 10s. The effect and benefit of the present invention is to solve the existing problems of gas elimination of pollutants, realize a new method of gas purification without catalyst, absorbent and reducing agent, and without any negative impact on the environment.
Description
Technical field
The invention belongs to gas ionization discharge, plasma chemistry and environmental project applied technical field, relate to oxygen activity particle formation hydroxyl free based method in the gas.
Background technology
There are contaminants of chemical origin and biological pollutant in the gas.Chemical pollutant is meant aromatic compound (toluene, dimethylbenzene, paracide etc.), organohalogen compounds (tetrachloroethylene, chloromethanes etc.); Alcohols (methanol, ethanol, chloro ethanol etc.); Ketone (acetone, methyl ethyl ketone etc.); Aldehydes (formaldehyde, acetaldehyde etc.); Esters (ethyl acetate); Ethers (methyl ether, ether, propyl ether, basic ether, propyl ether); Organohalogen compounds (Niran, paracide, heptachlor etc.).Biological pollutant is meant antibacterial, mycete, streptococcus, Sour lung legionella and dirt demodicid mite etc., and inorganic pollution such as gaseous sulfur dioxide, nitrogen oxide.Usually adopt purification methods such as absorption, photocatalysis, anion, ozone.Effective, feasible method is the ozone purification method in these methods.Because the ozone oxidation reduction potential is 2.07V, is selective decomposition, oxidize contaminants, can only handle part pollutant in the gas phase; It and pollutant reaction speed constant only are 10
-1L mols～10
2L mols, ozone is killed the aspergillosis time and is reached about 100min in gas phase, as seen, the most effective in the existing gas purification technique is the ozone gas purification techniques, but this technology remains in following weak point, oxidation-reduction potential only is 2.07V; Reaction rate constant is too low, only is 10
-1L mols～10
2L mols, than low 7 orders of magnitude of hydroxyl radical free radical OH, ozone is oxidation Decomposition pollutant and the selection killing microorganisms is arranged selectively thus; Reaction rate constant is low, and the response time, visible ozone gas purification method was difficult to satisfy current gas purification needs up to 20min～100min.
Present method for gas purification existing problems:
1) pollutant in the gas is selectively purified.Promptly being that a kind of method for gas purification is administered one or more pollutant, usually is to adopt several air purification method synergism to realize the gas purification purpose;
2) reaction rate constant of existing gas purification technique is very low, and the gas purification response time reaches 20min～100min, is difficult to realize that online fast gas purifies;
3) existing gas cleaning equipment is bulky, one-time investment and operating cost height;
4) need extra catalyst, absorbent, reductant-oxidant etc., so that increase reaction rate and improve selectivity.
Summary of the invention
The objective of the invention is to solve formation hydroxyl free based method weak point in the gaseous state, oxygen activity particle formation hydroxyl free based method in the gas is provided.This invention is the oxygen activity particle (O the high concentration low discharge
2 +, O
3, O (
1D), O (
3P) etc.) in flow in pipes or the container, O in the oxygen activity particle
2 +Generate high initial reaction rate constant 2.2 * 10 with water reaction in the gas
6The hydroperoxyl IONS OF H O of L/mols
2 -Initiator, oxygen activity particle and HO
2 -Carry out plasma reaction and generate active particle group, organic pollution and deadly, deactivation tiny organism, antibacterial and virus in the oxidation Decomposition gas based on OH.Because its reaction rate constant is up to 10
7L mols～10
10L mols, can be in 1ms～10s organic pollution in the oxidation Decomposition gas; Cause death, the small harmful organism of deactivation and virus, realized that quick nothing selects to eliminate gas pollutant; Hydroxyl radical free radical OH oxidizing potential is up to 2.80V, and is almost suitable with fluorine (2.87V), and non-selectivity is eliminated chemistry and biological pollution in the gas, finally resolves into CO
2, H
2O and micro-inorganic salt.Meet Green Chemistry 12 principles, and reach the high-level oxidation technology requirement, the present invention has realized not producing the side-product of any recontaminate without oxidant, catalyst and Reducing agent, environment is not produced gas green, the fast purification new method of any negative effect.
The present invention solves technical scheme that its technology adopts:
The present invention is the O that oxygen activity particle generator 2 is produced
2 +, O
3, O (
1D), O (
3P) etc. oxygen activity particle 6 injects air flue 8 or reactor 10, wherein O
2 +Deng with gas in hydrone generation plasma chemical reaction generate hydroperoxyl ionic initiator HO
2 -, the oxygen activity particle is at initiator HO
2 -Effect forms hydroxyl radical free radical OH down, and its scheme as shown in Figure 1, 2, 3.
The present invention adopts highfield ionic discharge method, and low discharge oxygen is produced high concentration (1 * 10
7/ cm
3～4 * 10
18/ cm
3) O
2 +, O
3, O (
1D), O (
3P) etc. oxygen activity particle 6 injects air flues 8 (or reactor 10), O in the oxygen activity particle
2 +Deng with gas 7 in hydrone generation plasma chemical reaction, generate high concentration (10
7/ cm
3～10
16/ cm
3), high initial reaction rate constant (2.2 * 10
6L/mols) HO
2 -The hydroperoxyl ionic initiator, O
2 +, O
3, O (
1D), O (
3P) oxygen activity particle 6 and initiator HO such as
2 -It is 10 that reaction generates concentration
8/ cm
3～10
17/ cm
3OH, it 0.01s～10s in the time air flue 8 or reactor 10 in pollutant oxidation eliminate, realization is without catalyst, absorbent, Reducing agent and other traditional method synergism, pollutant in the gas 7 are eliminated in the OH oxidation, elimination factor reaches 85%～99.8%, from Fig. 1,2 as seen, forming the OH method and apparatus in air flue or reactor is key technology of the present invention and device.The plasma reaction that active particle of the present invention injects air flue or reactor generates the OH pattern as shown in Figure 3.
This scheme will provide a kind of effective, feasible new equipment, new technique for solving the problem that forms the hydroxyl radical free radical existence at present in gas.Implementing concrete steps of the present invention is:
1. the oxygen activity particle is produced.
Key technology of the present invention is newly to develop to produce high concentration O
2 +, O
3, O (
1D), O (
3The oxygen activity particle generator 2 of oxygen activity particle 6 such as P).It is made up of parts such as discharge plate, earthing pole, dielectric layer and partitions.Discharge electrode, earthing pole are to be processed into titanium or rustless steel, and regulate and control the temperature of plasma process reactor with cooling liquid.
The present invention adopts dielectric impedance highfield ionic discharge method O
2Make concentration and reach 1 * 10
7/ cm
3～4 * 10
18/ cm
3The oxygen activity particle, set up reduced electric field intensity in 0.5mm between discharge electrode and earthing pole～0.01mm discharging gap in 200Td～400Td scope internal ionization discharge field, electronics obtains average energy and reaches 6eV～9eV from electric field, the useful energy (8.4eV～12.5eV) will be deposited on O that wherein most of electron institute has
2On, be enough to O
2Dissociate, be ionized into the high concentration active particle, and the difference orientation generates oxygen activity particle O under the electric pulse field parameter regulation and control
2 +, O
3, O (
1D), O (
3P) etc.Produce oxygen activity particle plasma reaction pattern as shown in Figure 3, O is provided in flue
2 +, O
3, O (
1D), O (
3P) etc. oxygen activity particle 6 concentration reach 1 * 10
7/ cm
3～4 * 10
18/ cm
3
2. initiator HO in air flue 8 or the reactor 10
2 -Formation.O in the oxygen activity particle
2 +Deng with gas 7 in water molecule reaction generate HO
2 -Initiator, its plasma reaction pattern as shown in Figure 3.
H
2O
2With HO
2 -Be in a kind of balancing response state, in air flue or reactor, form initiator HO
2 -Concentration reach 10
7/ cm
3～10
16/ cm
3
3. air flue or reactor OH oxidation destroy contaminants.Form in air flue 8 or the reactor 10 based on the active particle radical oxidation of OH and eliminate pollutant M in the gas, pollutant finally resolve into CO
2, H
2O and micro-inorganic salt.
Effect of the present invention and benefit are that the oxygen activity particle is injected air flue or reactor and gas water molecule reaction generation OH, and this reaction is that high-level oxidation technology is expanded to new gas field from water treatment field.Because its chemical reaction rate is fast, exceed 7 more than the order of magnitude than present method for gas purification, so the chemical time of destroy contaminants only is 0.01s～10s, thereby flow process shortens, equipment reduces, and this will reduce equipment investment and operating cost significantly, cut down the consumption of energy; Realized purifying without the quick green gases of extra catalyst, absorbent and Reducing agent; Reduce operating cost, new environmental pollution has not taken place again, solved the difficult problem of present gas purification technique, thereby accomplished zero environmental, zero waste discharge, reached the high-level oxidation technology principles and requirements; Help solving problems such as the high purification efficiency of China's gas purification energy consumption is low and bulky.
Description of drawings
Fig. 1 is that the oxygen activity particle injects air flue formation hydroxyl radical free radical scheme sketch map.
Fig. 2 forms hydroxyl radical free radical scheme sketch map in the oxygen activity particle injecting reactor.
Fig. 3 is the plasma chemical reaction ideograph that generates OH in air flue or the reactor.
Fig. 4 is the curve chart that oxygen activity particle and pollutant mol ratio n influence the pollution abatement rate.
Fig. 5 is the curve chart that water volume concentration influences destroy contaminants in the air flue.
Fig. 6 is the curve chart of flue-gas temperature to the destroy contaminants influence.
Among the figure: 1. oxygen; 2. oxygen activity particle generator; 3. high tension cable; 4. high-frequency and high-voltage power supply; 5.～220V; 6.O
2 +, O
3, O (
1D), O (
3Oxygen activity particle such as P); 7. gas; 8. air flue; 9. Purge gas; 10. reactor.
The specific embodiment
Be described in detail specific embodiments of the invention below in conjunction with technical scheme and accompanying drawing.
The overall embodiment of the present invention as shown in Figure 1, 2.Forming O after oxygen 1 disassociation, the ionization
2 +, O
3, O (
1D), O (
3The oxygen activity particle generator 2 of oxygen activity particle 6 such as P).The generation hydroxyl radical free radical plasma chemical reaction pattern of oxygen activity particle generation of the present invention and injection air flue 8 or reactor 10 as shown in Figure 3.
The invention process result is shown in Fig. 4～6.From the oxygen activity particle of Fig. 4 and pollutant mol ratio n to the curve of pollutant elimination factor influence as can be known, when oxygen activity particle and pollutant mol ratio were 4, the pollutant elimination factor reached 97.1%; When n=2, elimination factor reaches 91.5%.From Fig. 5 as seen, water volume concentration is lower than at 4% o'clock in the gas, and is bigger to the influence of pollutant elimination factor, when water volume concentration greater than 8% the time, then water volume concentration is to the almost not influence of pollutant elimination factor.From Fig. 6 as seen, when being lower than 60 ℃, gas temperature then the pollutant elimination factor is not almost had influence, linear decline during greater than 70 ℃.
Claims (1)
1. an oxygen activity particle forms the hydroxyl free based method in gas, is the oxygen activity particle (O that gas ionization discharge is produced
2 +, O
3, O (
1D), O (
3P) etc. reinject in the pipeline) or in the container, O wherein
2 +Generate hydroperoxyl ion (HO with water reaction in the gas
2 -) initiator, the oxygen activity particle is at HO
2 -Under the catalyst action, reaction generates hydroxyl radical free radical OH, it is characterized in that:
A: gas water content is 1%～20%, and temperature is at 4 ℃～80 ℃, O
2 +Reacting the reaction of formation speed constant with water in the gas is 2.2 * 10
6The hydroperoxyl ionic initiator of L/mols is worked as O
2 +Concentration is 10
6/ cm
3～10
15/ cm
3The time, HO
2 -Concentration reaches 10
7/ cm
3～10
16/ cm
3
B:O
2By the ionization of dense ionization electric field, be dissociated into oxygen activity particle (O
2 +, O
3, O (
1D), O (
3P) etc.), when ionizing electric field intensity when being 250Td～350Td the oxygen activity particle concentration reach 1 * 10
7/ cm
3～4 * 10
18/ cm
3
C: gas ionization discharge produces the oxygen activity particle concentration and reaches 1 * 10
7/ cm
3～4 * 10
18/ cm
3The time, the oxygen activity particle is at HO
2 -Catalyst action reaction down generates hydroxyl radical free radical OH, and its concentration reaches 10
7/ cm
3～10
18/ cm
3
D: the oxygen activity particle generates the hydroxyl radical free radical time under the hydroperoxyl ionization be 1 μ s～1ms.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105671358A CN102091339A (en) | 2010-11-22 | 2010-11-22 | Method for enabling oxygen active particle to form hydroxyl radical in gas |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105671358A CN102091339A (en) | 2010-11-22 | 2010-11-22 | Method for enabling oxygen active particle to form hydroxyl radical in gas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102091339A true CN102091339A (en) | 2011-06-15 |
Family
ID=44124718
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010105671358A Pending CN102091339A (en) | 2010-11-22 | 2010-11-22 | Method for enabling oxygen active particle to form hydroxyl radical in gas |
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| Country | Link |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1513753A (en) * | 2003-06-13 | 2004-07-21 | 大连海事大学 | A kind of method that hydroxyl oxidizes sulfur dioxide to generate sulfuric acid |
| CN1594136A (en) * | 2004-06-18 | 2005-03-16 | 大连海事大学 | Method for treating red tide by strong oxidative free radical |
| DE10355834A1 (en) * | 2003-11-26 | 2005-07-07 | Steinicke, Eckhard | Mobile, modular apparatus for treating air, useful for eliminating odors of volatile organic compounds, germs and fine particles, includes units for producing ozone or small ions |
| CN101367031A (en) * | 2008-09-12 | 2009-02-18 | 江苏大学 | A device and method for generating hydroxyl radicals by ultrasonic waves in cooperation with strong ionization discharge |
-
2010
- 2010-11-22 CN CN2010105671358A patent/CN102091339A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1513753A (en) * | 2003-06-13 | 2004-07-21 | 大连海事大学 | A kind of method that hydroxyl oxidizes sulfur dioxide to generate sulfuric acid |
| DE10355834A1 (en) * | 2003-11-26 | 2005-07-07 | Steinicke, Eckhard | Mobile, modular apparatus for treating air, useful for eliminating odors of volatile organic compounds, germs and fine particles, includes units for producing ozone or small ions |
| CN1594136A (en) * | 2004-06-18 | 2005-03-16 | 大连海事大学 | Method for treating red tide by strong oxidative free radical |
| CN101367031A (en) * | 2008-09-12 | 2009-02-18 | 江苏大学 | A device and method for generating hydroxyl radicals by ultrasonic waves in cooperation with strong ionization discharge |
Non-Patent Citations (2)
| Title |
|---|
| 白希尧等: "加工羟基的等离子体化学反应过程", 《大连海事大学学报》 * |
| 白敏冬等: "强电离放电模拟烟气脱硫", 《应用化学》 * |
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Application publication date: 20110615 |