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CN102061211B - Integral purified integration system and process of lignite in cement production through catalytic mild pyrolysis - Google Patents

Integral purified integration system and process of lignite in cement production through catalytic mild pyrolysis Download PDF

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CN102061211B
CN102061211B CN201110005446XA CN201110005446A CN102061211B CN 102061211 B CN102061211 B CN 102061211B CN 201110005446X A CN201110005446X A CN 201110005446XA CN 201110005446 A CN201110005446 A CN 201110005446A CN 102061211 B CN102061211 B CN 102061211B
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coal
lignite
drying
cement
crusher
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CN102061211A (en
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滕英跃
刘全生
智科端
何润霞
周晨亮
宋银敏
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Inner Mongolia University of Technology
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Abstract

本发明公开了一种水泥生产中一体化褐煤催化轻度热解提质集成系统及工艺,其系统包括有水泥烧成系统,破碎机,预烘干机,辊压机,催化剂储仓,烘干破碎机,垂直烘干筒,旋风分离器;其工艺依次包括有如下步骤:(1)褐煤原煤初步破碎成煤块;(2)煤块预干燥及辊压破碎成煤粒;(3)煤粒经烘干破碎机破碎成煤粉;(4)细煤粉经垂直烘干筒换热干燥、提质;(5)提质褐煤在旋风分离器与气体分离,得提质褐煤成品。本发明的优点在于,充分利用了水泥生产中余热,节能降耗,并减少二氧化碳排放;本发明利用水泥生产中原有工艺设备,不需额外增加设备,投资少,收益大,每年可以给2500T/d水泥生产线节约1000万元。

Figure 201110005446

The invention discloses an integrated lignite catalyzed mild pyrolysis upgrading integrated system and process in cement production. Dry crusher, vertical drying drum, and cyclone separator; the process includes the following steps in sequence: (1) raw lignite coal is initially crushed into coal blocks; (2) coal blocks are pre-dried and rolled into coal particles; (3) The coal particles are broken into coal powder by the drying crusher; (4) the fine coal powder is dried and upgraded by heat exchange through the vertical drying cylinder; (5) the upgraded lignite is separated from the gas in the cyclone separator to obtain the upgraded lignite product. The advantage of the present invention is that it makes full use of the waste heat in cement production, saves energy and reduces consumption, and reduces carbon dioxide emissions; the present invention utilizes the original process equipment in cement production, does not need additional equipment, has less investment and large income, and can give 2500T/ d The cement production line saves 10 million yuan.

Figure 201110005446

Description

水泥生产中一体化褐煤催化轻度热解提质集成系统及工艺Integrated lignite catalytic mild pyrolysis upgrading integrated system and process in cement production

技术领域 technical field

本发明涉及一种褐煤催化轻度热解提质集成系统及工艺,特别涉及一种利用水泥烧成系统产生的废气,对褐煤进行分级提质的一体化集成系统及工艺。The invention relates to an integrated system and process for catalytic mild pyrolysis and upgrading of lignite, in particular to an integrated integrated system and process for classifying and upgrading lignite by using waste gas generated by a cement burning system.

背景技术 Background technique

据统计,全世界褐煤储量约26229亿吨,约占世界煤炭总储量的24.4%。中国已经发现的褐煤资源量为2100亿吨,约占中国煤炭保有资源量的13%。由于褐煤形成距地表很浅,适于露天开采,因此价格低廉。但是褐煤也存在以下突出的问题:According to statistics, the world's lignite reserves are about 2622.9 billion tons, accounting for about 24.4% of the world's total coal reserves. China has discovered lignite resources of 210 billion tons, accounting for about 13% of China's coal reserves. Because lignite is formed very shallow from the surface, it is suitable for open-pit mining, so it is cheap. But lignite also has the following outstanding problems:

1、水分高,热值低,褐煤一般含水量介于30%到65%之间,一般热值在3000kcal/kg左右;2、密度低,易风化,遇水自燃,销售半径一般不超过300公里。为了解决上述问题,世界上许多公司开展了褐煤干燥与提质改性研究,少数工艺已经开始工业化,大部分还在试验研究阶段。1. High moisture and low calorific value. Lignite generally has a water content between 30% and 65%, and its general calorific value is about 3000kcal/kg; 2. Low density, easy to weather, spontaneous combustion when exposed to water, and the sales radius generally does not exceed 300 kilometer. In order to solve the above problems, many companies in the world have carried out research on lignite drying and upgrading. A few processes have begun to be industrialized, and most of them are still in the experimental research stage.

褐煤干燥脱水的技术很多,大致分为机械脱水、蒸发脱水和非蒸发脱水三种。机械脱水技术已在选煤厂广泛应用,脱水机械如浓缩机、振动滤网、圆盘过滤机等,但其处理能力和脱水效率尚难适应褐煤脱水的要求。蒸发脱水以流化床干燥技术为代表,将成熟的流化技术用于褐煤脱水,它们大部分都是相对低温干燥工艺,干燥介质为热烟道气。利用烟道气与褐煤直接接触使之受热,水分蒸发干燥,效率差。褐煤的燃点较低,干燥过程中常常因局部过热,使煤质变差,控制不好还会引起爆炸。这类工艺温度较低,不会永久的改变煤的结构,获得煤的特性像海绵,一旦重新处于潮湿的空气或水中,又会迅速吸收失去的水分。非蒸发脱水法以高温高压蒸汽干燥技术为代表,该技术投资大,设备要求高,企业难以承受,实现工业化较为困难。There are many techniques for lignite drying and dehydration, which can be roughly divided into three types: mechanical dehydration, evaporative dehydration and non-evaporative dehydration. Mechanical dehydration technology has been widely used in coal preparation plants. Dehydration machinery such as thickeners, vibrating screens, disc filters, etc., but its processing capacity and dehydration efficiency are still difficult to meet the requirements of lignite dehydration. Evaporative dehydration is represented by fluidized bed drying technology, and mature fluidized technology is used for lignite dehydration. Most of them are relatively low-temperature drying processes, and the drying medium is hot flue gas. The flue gas is directly contacted with the lignite to make it heated, and the water evaporates and dries, so the efficiency is poor. The ignition point of lignite is low, and the coal quality is often deteriorated due to local overheating during the drying process. If the control is not good, it will cause an explosion. This type of process is relatively low temperature and does not permanently change the structure of the coal, resulting in coal with sponge-like properties that quickly absorb lost moisture once it is re-exposed to humid air or water. The non-evaporative dehydration method is represented by high-temperature and high-pressure steam drying technology. This technology requires large investment and high equipment requirements, which is difficult for enterprises to bear and it is difficult to realize industrialization.

总之,现有褐煤的提质技术存在以下缺点:1、现有褐煤的提质技术需要单独提供热源,能耗高,提高了生产成本,增加二氧化碳的排放;2、在现有的提质技术的生产过程中,会产生较多的煤焦油,这样不仅会堵塞提质工艺管道,还使得提质褐煤热值低;3、现有技术褐煤提质,利用的热烟气含氧量较高,褐煤提质容易产生爆炸;4、有些技术需要高压,增加了设备的投资和技术要求,投资规模大,设备要求高,企业难以承受,实现工业化较为困难;In short, the existing lignite upgrading technology has the following disadvantages: 1. The existing lignite upgrading technology needs to provide a separate heat source, high energy consumption, increased production costs, and increased carbon dioxide emissions; 2. In the existing lignite upgrading technology During the production process, more coal tar will be produced, which will not only block the upgrading process pipeline, but also make the upgraded lignite calorific value low; , lignite upgrading is prone to explosion; 4. Some technologies require high pressure, which increases equipment investment and technical requirements. The large investment scale and high equipment requirements are difficult for enterprises to bear, and it is difficult to realize industrialization;

发明内容 Contents of the invention

本发明的第一个目的在于提供一种水泥生产中一体化褐煤催化轻度热解提质集成系统。The first object of the present invention is to provide an integrated lignite catalytic mild pyrolysis upgrading integrated system in cement production.

本发明的第二个目的在于提供一种利用水泥生产中一体化褐煤催化轻度热解提质集成系统进行褐煤提质的工艺。The second object of the present invention is to provide a process for upgrading lignite quality by utilizing the integrated system of catalytic mild pyrolysis upgrading of lignite in cement production.

本发明的第一个目的由如下技术方案实施:一种水泥生产中一体化褐煤催化轻度热解提质集成系统,其包括有水泥烧成系统,破碎机,预烘干机,辊压机,催化剂储仓,烘干破碎机,垂直烘干筒,旋风分离器;The first object of the present invention is implemented by the following technical scheme: an integrated lignite catalytic mild pyrolysis upgrading integrated system in cement production, which includes a cement burning system, a crusher, a pre-dryer, and a roller press , catalyst storage bin, drying crusher, vertical drying drum, cyclone separator;

其中所述水泥烧成系统的冷却熟料的冷却器通过管道与所述预烘干机连接,所述水泥烧成系统的水泥窑尾通过管道与所述烘干破碎机连接,所述破碎机、所述预烘干机、所述辊压机、所述烘干破碎机、所述垂直烘干筒、所述旋风分离器分别依次相连,所述催化剂储仓与所述辊压机相连接。Wherein the clinker cooling cooler of the cement burning system is connected with the pre-dryer through a pipeline, and the cement kiln tail of the cement burning system is connected with the drying crusher through a pipeline, and the crusher , the pre-dryer, the roller press, the drying crusher, the vertical drying cylinder, and the cyclone separator are respectively connected in sequence, and the catalyst storage bin is connected with the roller press .

其还包括有研磨装置,煤粒分级装置,煤粉喂料装置,收尘器和水回收装置;其中所述旋风分离器,所述煤粒分级装置,所述煤粉喂料装置分别依次相连,所述研磨装置和所述煤粒分级装置连接成一个循环回路,所述旋风分离器与所述收尘器连接,所述收尘器,所述水回收装置,所述研磨装置分别依次相连构成一个循环回路;所述煤粉喂料装置与所述水泥烧成系统的煤粉燃烧器,或水泥烧成系统的煤粉燃烧器和分解炉相连。It also includes a grinding device, a coal particle classification device, a pulverized coal feeding device, a dust collector and a water recovery device; wherein the cyclone separator, the coal particle classification device, and the pulverized coal feeding device are connected in sequence , the grinding device and the coal particle classifying device are connected to form a circulation loop, the cyclone separator is connected to the dust collector, the dust collector, the water recovery device, and the grinding device are respectively connected in sequence A circulation loop is formed; the pulverized coal feeding device is connected with the pulverized coal burner of the cement burning system, or the pulverized coal burner of the cement burning system is connected with the calciner.

所述研磨装置为球磨机、砾磨机、磨煤机、立磨或风扇磨中的任意一种。The grinding device is any one of a ball mill, a pebble mill, a coal mill, a vertical mill or a fan mill.

所述预烘干机为回转式烘干机,立式烘干机或管式烘干机中的任意一种。The pre-dryer is any one of a rotary dryer, a vertical dryer or a tube dryer.

本发明的第二个目的由如下技术方案实施,一种利用一体化褐煤催化轻度热解提质集成系统进行褐煤催化轻度热解提质的工艺,其依次包括有如下步骤:(1)褐煤原煤初步破碎成煤块;(2)煤块预干燥及辊压破碎成煤粒;(3)煤粒经烘干破碎机破碎成煤粉;(4)细煤粉经垂直烘干筒换热干燥、提质;(5)提质褐煤在旋风分离器与气体分离,得提质褐煤成品;其中,The second object of the present invention is implemented by the following technical scheme, a process for utilizing the integrated lignite catalytic mild pyrolysis upgrading integrated system to carry out lignite catalytic mild pyrolysis upgrading, which includes the following steps in turn: (1) The lignite raw coal is initially crushed into coal blocks; (2) the coal blocks are pre-dried and rolled into coal particles; (3) the coal particles are crushed into coal powder by a drying crusher; (4) the fine coal powder is replaced by a vertical drying cylinder Thermal drying and upgrading; (5) The upgraded lignite is separated from the gas in the cyclone separator to obtain the finished product of the upgraded lignite; wherein,

(1)褐煤原煤初步破碎成煤块:将含有15-60%水分的褐煤原煤放入破碎机内破碎成至少小于40mm的煤块;(1) The lignite raw coal is initially broken into coal lumps: the lignite raw coal containing 15-60% moisture is put into a crusher and broken into coal lumps at least less than 40mm;

(2)煤块预干燥及辊压破碎成煤粒:经所述破碎机破碎的煤块进入预烘干机,同时将来自水泥烧成系统的冷却熟料的冷却器的至少高于180℃的废气吹入所述预烘干机预干燥,使得所述煤块至少提高至105℃,所述煤块和废气同时进入辊压机破碎,并将催化剂储仓内的催化剂按0.5~6%质量百分比向所述辊压机内添加,用以降低煤焦油的产率,煤块成为煤粒,得煤粒小于0.9mm的占20~30%,煤粒小于2mm占65~80%,其余煤粒大于2mm;(2) Coal block pre-drying and roll crushing into coal particles: the coal block crushed by the crusher enters the pre-dryer, and at the same time, the temperature of the cooler for cooling clinker from the cement burning system is at least higher than 180°C The exhaust gas is blown into the pre-dryer for pre-drying, so that the coal block is raised to at least 105°C, and the coal block and exhaust gas enter the roller press for crushing at the same time, and the catalyst in the catalyst storage bin is compressed by 0.5-6%. The mass percentage is added to the roller press to reduce the yield of coal tar. The coal lumps become coal particles, and the coal particles smaller than 0.9mm account for 20-30%, and the coal particles smaller than 2mm account for 65-80%. Coal particles larger than 2mm;

(3)煤粒经烘干破碎机破碎成煤粉:煤粒随气体从所述辊压机输送到烘干破碎机,将来自所述水泥烧成系统的水泥窑尾的大于260℃废气进入所述烘干破碎机,煤粒在所述烘干破碎机内进一步干燥破碎、分散,得到粒度小于1mm的细煤粉,细煤粉随烟气吹入垂直烘干筒;(3) The coal particles are broken into coal powder by the drying crusher: the coal particles are transported from the roller press to the drying crusher along with the gas, and the waste gas greater than 260°C from the cement kiln tail of the cement burning system enters In the drying crusher, the coal particles are further dried, crushed and dispersed in the drying crusher to obtain fine coal powder with a particle size of less than 1mm, and the fine coal powder is blown into the vertical drying cylinder along with the flue gas;

(4)细煤粉经垂直烘干筒换热干燥、提质:细煤粉进入所述垂直烘干筒中,进行换热干燥、提质,水分降至5~10%;(4) The fine coal powder passes through the vertical drying drum for heat exchange drying and upgrading: the fine coal powder enters the vertical drying drum for heat exchange drying and quality upgrading, and the moisture is reduced to 5-10%;

(5)提质褐煤在旋风分离器与气体分离,得提质褐煤成品:气体携带细煤粉进入旋风分离器,换热、气固分离,得含水分率为质量百分比5%-10%提质褐煤成品,分离出的气体排空。(5) The upgraded lignite is separated from the gas in the cyclone separator to obtain an upgraded lignite product: the gas carries fine coal powder into the cyclone separator for heat exchange and gas-solid separation to obtain a moisture content of 5%-10% by mass. High-quality lignite products, and the separated gas is evacuated.

其还依次包括有(6)废气处理和利用;(7)提质褐煤成品的研磨与分级;(8)粒度小于200目的提质褐煤成品供所述水泥烧成系统利用;It also sequentially includes (6) waste gas treatment and utilization; (7) grinding and grading of the upgraded lignite product; (8) the upgraded lignite product with a particle size of less than 200 meshes for use by the cement firing system;

其中所述(6)废气处理和利用:来自所述旋风分离器的废烟气经收尘器收尘,分离出的细煤粉输送到煤粉喂料装置,除尘后的烟气通入水回收装置,经所述水回收装置干燥后一部分通入研磨装置,另一部分含尘量小于50mg/Nm3达到环保要求的废气排空;Wherein (6) waste gas treatment and utilization: the waste flue gas from the cyclone separator is dust-collected through the dust collector, and the separated fine coal powder is transported to the coal powder feeding device, and the flue gas after dust removal is passed into water for recovery device, after being dried by the water recovery device, part of it is passed into the grinding device, and the other part of the waste gas with a dust content of less than 50 mg/ Nm meets environmental protection requirements;

(7)提质褐煤成品的研磨与分级:来自所述旋风分离器的煤粉经煤粒分级装置筛选后,粒度大于200目的煤粉送入所述研磨装置,在来自所述水回收装置废气的作用下进行研磨,研磨后的煤粉返回所述煤粒分级装置,与所述煤粒分级装置中的煤粉混合,再次进行筛选,废气排入所述收尘器中收尘,经所述煤粒分级装置筛选后粒度小于200目的提质褐煤成品送入所述煤粉喂料装置;(7) Grinding and classification of upgraded lignite finished products: after the coal powder from the cyclone separator is screened by the coal particle classification device, the coal powder with a particle size greater than 200 mesh is sent to the grinding device, and the waste gas from the water recovery device is Grinding under the action of the coal particle classification device, the ground coal powder is returned to the coal particle classification device, mixed with the coal powder in the coal particle classification device, and screened again, and the exhaust gas is discharged into the dust collector to collect dust. After being screened by the coal particle classification device, the upgraded lignite finished product with a particle size of less than 200 mesh is sent to the pulverized coal feeding device;

(8)粒度小于200目的提质褐煤成品供所述水泥烧成系统利用:通过煤粉喂料装置将研磨、分级后的提质褐煤成品送入所述水泥烧成系统的煤粉燃烧器,或水泥烧成系统的煤粉燃烧器和分解炉,供燃烧使用。(8) The upgraded lignite finished product with a particle size of less than 200 meshes is used for the cement burning system: the ground and graded upgraded lignite finished product is sent to the pulverized coal burner of the cement burning system through a pulverized coal feeding device, Or the pulverized coal burner and calciner of the cement firing system for combustion.

所述步骤(2)中的催化剂为碳酸钾、或碳酸钙,或氧化钙,或氢氧化钙任意一种或几种的组合。添加催化剂用以抑制煤焦油的生成,避免由于生成煤焦油而造成管路堵塞,保证装置的长期稳定运行。The catalyst in the step (2) is potassium carbonate, or calcium carbonate, or calcium oxide, or any one or combination of calcium hydroxide. Catalysts are added to inhibit the generation of coal tar, avoid pipeline blockage caused by the generation of coal tar, and ensure long-term stable operation of the device.

本发明的优点在于,(1)利用水泥生产废烟气,不需单独提供热源,可降低成本,节约资源,提质褐煤成品水分降至5~10%,热值提升至4800kcal/kg以上,满足水泥生产对燃煤的热值要求;(2)添加催化剂用以抑制提质过程中煤焦油的生成,避免由于生成煤焦油而造成管路堵塞,保证装置的长期稳定运行;(3)利用水泥生产乏氧废烟气预热煤块,提高煤块温度,增加烟气中水蒸气含量,降低了提质褐煤过程中褐煤燃烧爆炸的危险性;(4)使提质褐煤成品在乏氧气氛下继续研磨,可得满足水泥烧成系统燃烧器及分解炉对煤粉细度的要求,同时合理处理废气,降低了废气的含尘量、温度,使之满足排放标准,使得水泥生产中的营运成本和投资大大降低;(5)本发明不需特殊技术要求设备,投资少,收益大,每年可以为2500T/d水泥生产线节约1000万元。The advantages of the present invention are: (1) Utilizing cement to produce waste flue gas does not need to provide a separate heat source, which can reduce costs and save resources, and the moisture content of the upgraded lignite product is reduced to 5-10%, and the calorific value is increased to more than 4800kcal/kg. Meet the calorific value requirements of cement production for coal combustion; (2) add catalysts to inhibit the generation of coal tar during the upgrading process, avoid pipeline blockage caused by the generation of coal tar, and ensure long-term stable operation of the device; (3) utilize Preheat coal with anoxic waste flue gas from cement production, increase the temperature of coal, increase the water vapor content in the flue gas, and reduce the risk of lignite combustion and explosion in the process of upgrading lignite; (4) make the finished product of upgraded lignite Continuous grinding under the atmosphere can meet the fineness requirements of the cement burning system burner and calciner for coal powder. At the same time, the exhaust gas can be reasonably treated to reduce the dust content and temperature of the exhaust gas, so that it can meet the emission standards and make the cement production process more efficient. (5) the present invention does not require special technical requirements equipment, has low investment and large income, and can save 10 million yuan for a 2500T/d cement production line every year.

附图说明Description of drawings

图1为实施例1,水泥生产中一体化褐煤催化轻度热解提质集成系统示意图。Fig. 1 is a schematic diagram of embodiment 1, an integrated lignite catalytic light pyrolysis upgrading integrated system in cement production.

图2为实施例2利用实施例1水泥生产中一体化褐煤催化轻度热解提质集成系统进行褐煤催化轻度热解提质的工艺流程示意图。Fig. 2 is a schematic diagram of the technological process of using the integrated brown coal catalytic mild pyrolysis upgrading integrated system in the cement production of Example 1 to carry out lignite catalytic mild pyrolysis upgrading in Example 2.

图3为实施例3,水泥生产中一体化褐煤催化轻度热解提质集成系统示意图。Fig. 3 is a schematic diagram of embodiment 3, an integrated lignite catalytic mild pyrolysis upgrading integrated system in cement production.

图4为实施例4利用实施例3水泥生产中一体化褐煤催化轻度热解提质集成系统进行褐煤催化轻度热解提质的工艺流程示意图。Fig. 4 is a schematic diagram of the process flow of using the integrated lignite catalytic mild pyrolysis upgrading integrated system in the cement production of Example 3 to carry out lignite catalytic mild pyrolysis upgrading in Example 4.

多级预热器1、分解炉2、水泥烧成系统3、煤粉燃烧器4、冷却机5、破碎机6、预烘干机7、辊压机8、烘干破碎机9、垂直烘干筒10、旋风分离器11、研磨装置12、煤粒分级装置13、煤粉喂料装置14、收尘器15、煤仓16、水回收装置17、催化剂储仓18。Multi-stage preheater 1, decomposition furnace 2, cement burning system 3, pulverized coal burner 4, cooler 5, crusher 6, pre-dryer 7, roller press 8, drying crusher 9, vertical drying Dry cylinder 10, cyclone separator 11, grinding device 12, coal particle classification device 13, coal powder feeding device 14, dust collector 15, coal bunker 16, water recovery device 17, catalyst storage bin 18.

具体实施方式 Detailed ways

实施例1:如图1所示,水泥生产中一体化褐煤催化轻度热解提质集成系统,其包括有水泥烧成系统3,破碎机6,预烘干机7,辊压机8,催化剂储仓18,烘干破碎机9,垂直烘干筒10,旋风分离器11,煤仓16;Embodiment 1: As shown in Figure 1, the integrated lignite catalytic mild pyrolysis upgrading integrated system in cement production includes a cement burning system 3, a crusher 6, a pre-dryer 7, a roller press 8, Catalyst storage bin 18, drying crusher 9, vertical drying cylinder 10, cyclone separator 11, coal bunker 16;

其中水泥烧成系统3的冷却熟料的冷却器—冷却机5通过管道与预烘干机7连接,水泥烧成系统3的水泥窑尾—多级预热器1通过管道与烘干破碎机9连接,破碎机6、预烘干机7、辊压机8、烘干破碎机9、垂直烘干筒10、旋风分离器11、煤仓16分别依次相连,催化剂储仓18与辊压机8相连接。Among them, the cooler for cooling the clinker of the cement burning system 3 - the cooler 5 is connected to the pre-dryer 7 through the pipeline, and the cement kiln tail of the cement burning system 3 - the multi-stage preheater 1 is connected to the drying crusher through the pipeline 9 connections, crusher 6, pre-dryer 7, roller press 8, drying crusher 9, vertical drying cylinder 10, cyclone separator 11, coal bunker 16 are connected in sequence, catalyst storage bin 18 is connected with the roller press 8 phase connections.

水泥烧成系统3为悬浮预热器窑,其包括有多级预热器1、分解炉2及煤粉燃烧器4、冷却机5,其中水泥烧成系统3的冷却熟料的冷却器为冷却机5,水泥烧成系统3的水泥窑尾为多级预热器1。The cement burning system 3 is a suspension preheater kiln, which includes a multi-stage preheater 1, a decomposition furnace 2, a pulverized coal burner 4, and a cooler 5, wherein the cooler for cooling the clinker of the cement burning system 3 is The cooler 5 and the cement kiln tail of the cement burning system 3 are multi-stage preheaters 1 .

预烘干机7为回转式烘干机。The pre-dryer 7 is a rotary dryer.

利用上述水泥生产中一体化褐煤催化轻度热解提质集成系统进行褐煤催化轻度热解提质的工艺,其依次包括有如下步骤:Using the above-mentioned integrated lignite catalytic mild pyrolysis and upgrading integrated system in cement production to carry out the process of lignite catalytic mild pyrolysis upgrading, which sequentially includes the following steps:

(1)褐煤原煤初步破碎成煤块:将含有15-60%水分的褐煤原煤放入破碎机6内破碎成至少小于40mm的煤块;(1) The lignite raw coal is initially broken into coal lumps: the lignite raw coal containing 15-60% moisture is put into the crusher 6 and broken into coal lumps at least less than 40mm;

(2)煤块预干燥及辊压破碎成煤粒:经破碎机6破碎的煤块进入预烘干机7,同时将来自水泥烧成系统3的冷却机5的至少高于180℃的废气吹入预烘干机7预干燥,使得煤块至少提高至105℃,煤块和废气同时进入辊压机8破碎,并将催化剂储仓18内的催化剂按0.5%质量百分比向辊压机8内添加,得煤粒小于0.9mm的占20~30%,煤粒小于2mm占65~80%,其余煤粒大于2mm;共中催化剂为碳酸钾、碳酸钙和氧化钙按任意比的混合物。(2) Coal block pre-drying and rolling crushing into coal particles: the coal block crushed by the crusher 6 enters the pre-dryer 7, and at the same time, the waste gas from the cooler 5 of the cement burning system 3 is at least higher than 180°C Blow into the pre-dryer 7 for pre-drying, so that the coal block is raised to at least 105°C, and the coal block and waste gas enter the roller press 8 to be crushed at the same time, and the catalyst in the catalyst storage bin 18 is sent to the roller press 8 at a rate of 0.5% by mass. Internally added, coal particles smaller than 0.9mm account for 20-30%, coal particles smaller than 2mm account for 65-80%, and the remaining coal particles are larger than 2mm; the total catalyst is a mixture of potassium carbonate, calcium carbonate and calcium oxide in any ratio.

(3)煤粒经烘干破碎机9破碎成煤粉:煤粒随气体从辊压机8输送到烘干破碎机9,将来自水泥烧成系统3的多级预热装置1的大于260℃废气进入烘干破碎机9,煤粒在烘干破碎机9内进一步干燥破碎、分散,得到粒度小于1mm的细煤粉,细煤粉随烟气吹入垂直烘干筒10;(3) The coal particles are broken into coal powder by the drying crusher 9: the coal particles are transported from the roller press 8 to the drying crusher 9 along with the gas, and the coal particles from the multi-stage preheating device 1 of the cement burning system 3 are more than 260 ℃ The waste gas enters the drying crusher 9, and the coal particles are further dried, crushed and dispersed in the drying crusher 9 to obtain fine coal powder with a particle size of less than 1 mm, which is blown into the vertical drying cylinder 10 along with the flue gas;

(4)细煤粉经垂直烘干筒10换热干燥、提质:细煤粉进入垂直烘干筒10中,进行换热干燥、提质,水分降至5~10%;(4) The fine coal powder passes through the vertical drying cylinder 10 for heat exchange drying and upgrading: the fine coal powder enters the vertical drying cylinder 10 for heat exchange drying and quality upgrading, and the moisture is reduced to 5-10%;

(5)提质褐煤在旋风分离器11与气体分离,得提质褐煤成品:气体携带细煤粉进入旋风分离器11,换热、气固分离,得含水分率为质量百分比5%-10%提质褐煤成品,并将提质褐煤成品运送到煤仓16中,分离出的气体排空。(5) The upgraded lignite is separated from the gas in the cyclone separator 11 to obtain an upgraded lignite product: the gas carries fine coal powder into the cyclone separator 11 for heat exchange and gas-solid separation to obtain a moisture content of 5%-10% by mass % upgraded lignite finished product, and the upgraded lignite finished product is transported in the coal bunker 16, and the separated gas is emptied.

实施例2:水泥生产中一体化褐煤催化轻度热解提质集成系统,其包括有水泥烧成系统3,破碎机6,预烘干机7,辊压机8,催化剂储仓18,烘干破碎机9,垂直烘干筒10,旋风分离器11,研磨装置12,煤粒分级装置13,煤粉喂料装置14,收尘器15和水回收装置17;其中水泥烧成系统3的冷却熟料的冷却器—冷却机5通过管道与预烘干机7连接,水泥烧成系统3的水泥窑尾—多级预热器1通过管道与烘干破碎机9连接,破碎机6、预烘干机7、辊压机8、烘干破碎机9、垂直烘干筒10、旋风分离器11分别依次相连,催化剂储仓18与辊压机8相连接,旋风分离器11,煤粒分级装置13,煤粉喂料装置14分别依次相连,研磨装置12和煤粒分级装置13连接成一个循环回路,旋风分离器11与收尘器15连接,收尘器15,水回收装置17,研磨装置12分别依次相连构成一个循环回路;煤粉喂料装置14与水泥烧成系统3的煤粉燃烧器4和分解炉2相连。Embodiment 2: Integrated lignite catalytic mild pyrolysis upgrading integrated system in cement production, which includes cement burning system 3, crusher 6, pre-dryer 7, roller press 8, catalyst storage bin 18, oven Dry crusher 9, vertical drying cylinder 10, cyclone separator 11, grinding device 12, coal particle classification device 13, coal powder feeding device 14, dust collector 15 and water recovery device 17; wherein the cement firing system 3 The cooler for cooling the clinker—the cooler 5 is connected to the pre-dryer 7 through pipelines, the cement kiln tail of the cement firing system 3—the multistage preheater 1 is connected to the drying crusher 9 through pipelines, and the crushers 6, The pre-dryer 7, roller press 8, drying crusher 9, vertical drying cylinder 10, and cyclone separator 11 are respectively connected in sequence, the catalyst storage bin 18 is connected with the roller press 8, the cyclone separator 11, and the coal particle The classifying device 13 and the pulverized coal feeding device 14 are respectively connected successively, the grinding device 12 and the coal particle classifying device 13 are connected to form a circulation loop, the cyclone separator 11 is connected with the dust collector 15, the dust collector 15, the water recovery device 17, The grinding devices 12 are respectively connected in sequence to form a circulation loop; the pulverized coal feeding device 14 is connected with the pulverized coal burner 4 and the calciner 2 of the cement firing system 3 .

水泥烧成系统3为新型干法窑烧成系统,其包括有多级预热器1、冷却机5、分解炉2和煤粉燃烧器4,水泥烧成系统3的冷却熟料的冷却器为新型干法窑烧成系统的冷却机5,水泥烧成系统3的水泥窑尾为新型干法窑烧成系统的多级预热器1。The cement firing system 3 is a new type dry process kiln firing system, which includes a multi-stage preheater 1, a cooler 5, a calciner 2 and a pulverized coal burner 4, and a cooler for cooling clinker in the cement firing system 3 It is the cooler 5 of the new dry kiln firing system, and the cement kiln tail of the cement firing system 3 is the multi-stage preheater 1 of the new dry kiln firing system.

预烘干机7为立式烘干机。The pre-dryer 7 is a vertical dryer.

研磨装置12为球磨机。The grinding device 12 is a ball mill.

利用上述水泥生产中一体化褐煤催化轻度热解提质集成系统进行褐煤催化轻度热解提质工艺,其依次包括有如下步骤:Using the above-mentioned integrated brown coal catalytic mild pyrolysis upgrading integrated system in cement production to carry out the lignite catalytic mild pyrolysis upgrading process, which includes the following steps in sequence:

(1)褐煤原煤初步破碎成煤块:将含有15-60%水分的褐煤原煤放入破碎机6内破碎成至少小于40mm的煤块;(1) The lignite raw coal is initially broken into coal lumps: the lignite raw coal containing 15-60% moisture is put into the crusher 6 and broken into coal lumps at least less than 40mm;

(2)煤块预干燥及辊压破碎成煤粒:经破碎机6破碎的煤块进入预烘干机7,同时将来自水泥烧成系统3的冷却机5的至少高于180℃的废气吹入预烘干机7预干燥,使得煤块至少提高至105℃,煤块和废气同时进入辊压机8破碎,并将催化剂储仓18内的催化剂按6%质量百分比向辊压机8内添加,得煤粒小于0.9mm的占20~30%,煤粒小于2mm占65~80%,其余煤粒大于2mm;共中催化剂为碳酸钾、碳酸钙和氧化钙按任意比的混合物。(2) Coal block pre-drying and rolling crushing into coal particles: the coal block crushed by the crusher 6 enters the pre-dryer 7, and at the same time, the waste gas from the cooler 5 of the cement burning system 3 is at least higher than 180°C Blow into the pre-dryer 7 for pre-drying, so that the coal block is raised to at least 105°C, and the coal block and waste gas enter the roller press 8 to be crushed simultaneously, and the catalyst in the catalyst storage bin 18 is sent to the roller press 8 by 6% by mass. Internally added, coal particles smaller than 0.9mm account for 20-30%, coal particles smaller than 2mm account for 65-80%, and the remaining coal particles are larger than 2mm; the total catalyst is a mixture of potassium carbonate, calcium carbonate and calcium oxide in any ratio.

(3)煤粒经烘干破碎机9破碎成煤粉:煤粒随气体从辊压机8输送到烘干破碎机9,将来自水泥烧成系统3的多级预热装置1的大于260℃废气进入烘干破碎机9,煤粒在烘干破碎机9内进一步干燥破碎、分散,得到粒度小于1mm的细煤粉,细煤粉随烟气吹入垂直烘干筒10;(3) The coal particles are broken into coal powder by the drying crusher 9: the coal particles are transported from the roller press 8 to the drying crusher 9 along with the gas, and the coal particles from the multi-stage preheating device 1 of the cement burning system 3 are more than 260 ℃ The waste gas enters the drying crusher 9, and the coal particles are further dried, crushed and dispersed in the drying crusher 9 to obtain fine coal powder with a particle size of less than 1 mm, which is blown into the vertical drying cylinder 10 along with the flue gas;

(4)细煤粉经垂直烘干筒10换热干燥、提质:细煤粉进入垂直烘干筒10中,进行换热干燥、提质,水分降至5~10%;(4) The fine coal powder passes through the vertical drying cylinder 10 for heat exchange drying and upgrading: the fine coal powder enters the vertical drying cylinder 10 for heat exchange drying and quality upgrading, and the moisture is reduced to 5-10%;

(5)提质褐煤在旋风分离器11与气体分离,得提质褐煤成品:气体携带细煤粉进入旋风分离器11,换热、气固分离,得含水分率为质量百分比5%-10%提质褐煤成品,并将提质褐煤成品送到煤粒分级装置13中,分离出的气体通入收尘器15。(5) The upgraded lignite is separated from the gas in the cyclone separator 11 to obtain an upgraded lignite product: the gas carries fine coal powder into the cyclone separator 11 for heat exchange and gas-solid separation to obtain a moisture content of 5%-10% by mass % upgraded lignite finished product, and the upgraded lignite finished product is sent to the coal particle classification device 13, and the separated gas is passed into the dust collector 15.

(6)废气处理和利用:来自旋风分离器11的废烟气经收尘器15收尘,分离出的细煤粉输送到煤粉喂料装置14,除尘后的烟气通入水回收装置17,经水回收装置17干燥后一部分通入研磨装置12,另一部分含尘量小于50mg/Nm3达到环保要求的废气排空;(6) Waste gas treatment and utilization: the waste flue gas from the cyclone separator 11 is collected by the dust collector 15, and the separated fine coal powder is transported to the coal powder feeding device 14, and the dust-removed flue gas is passed into the water recovery device 17 After being dried by the water recovery device 17 , part of it is passed into the grinding device 12, and the other part is emptied of waste gas with a dust content of less than 50 mg/Nm that meets environmental protection requirements;

(7)提质褐煤成品的研磨与分级:来自旋风分离器11的煤粉经煤粒分级装置13筛选后,粒度大于200目的煤粉送入研磨装置12,在来自水回收装置17废气的作用下进行研磨,研磨后的煤粉返回煤粒分级装置13,与煤粒分级装置13中的煤粉混合,再次进行筛选,废气排入收尘器15中收尘,经煤粒分级装置13筛选后粒度小于200目的提质褐煤成品送入煤粉喂料装置14;(7) Grinding and classification of upgraded lignite finished products: after the coal powder from the cyclone separator 11 is screened by the coal particle classification device 13, the coal powder with a particle size greater than 200 mesh is sent into the grinding device 12, and the waste gas from the water recovery device 17 The pulverized coal after grinding is returned to the coal particle classification device 13, mixed with the coal powder in the coal particle classification device 13, and screened again, and the waste gas is discharged into the dust collector 15 to collect dust, and is screened by the coal particle classification device 13 The finished product of upgraded lignite with a particle size of less than 200 meshes is sent to the pulverized coal feeding device 14;

(8)粒度小于200目的提质褐煤成品供水泥烧成系统3利用:通过煤粉喂料装置14将研磨、分级后的提质褐煤成品送入水泥烧成系统3的煤粉燃烧器4和分解炉2,供燃烧使用。(8) The upgraded lignite finished product with a particle size of less than 200 meshes is used for the cement burning system 3: the pulverized coal burner 4 and the pulverized coal burner 4 of the cement burning system 3 are fed with the pulverized coal feeding device 14 through the pulverized coal feeding device 14 and the upgraded lignite finished product is sent to the cement burning system 3 Calciner 2, for combustion use.

所述步骤(2)中的催化剂为碳酸钙、氧化钙和氢氧化钙按任意比的混合物。The catalyst in the step (2) is a mixture of calcium carbonate, calcium oxide and calcium hydroxide in any ratio.

实施例3:实施例1水泥生产中一体化褐煤催化轻度热解提质集成系统中,水泥烧成系统还可以为立波尔窑,其包括有立波尔预热机、冷却机和煤粉燃烧器,其中水泥烧成系统3的冷却熟料的冷却器为立波尔窑的冷却机,水泥烧成系统3的水泥窑尾为立波尔预热机。Embodiment 3: in the integration system of lignite catalytic mild pyrolysis upgrading in the cement production of embodiment 1, the cement firing system can also be a Liboer kiln, which includes a Liboer preheater, a cooling machine and a coal kiln. Powder burner, wherein the clinker cooling cooler of the cement firing system 3 is the cooler of the Liber kiln, and the cement kiln tail of the cement firing system 3 is the Liber preheater.

预烘干机7为立式烘干机。The pre-dryer 7 is a vertical dryer.

实施例1步骤(2)中,催化剂储仓18内的催化剂还可以按3%质量百分比向辊压机8内添加。In step (2) of Example 1, the catalyst in the catalyst storage bin 18 can also be added to the roller press 8 at a rate of 3% by mass.

实施例4:实施例2水泥生产中一体化褐煤催化轻度热解提质集成系统中,水泥烧成系统还可以为带加热器湿法窑,其包括有加热器、冷却机和煤粉燃烧器,其中水泥烧成系统3的冷却熟料的冷却器为带加热器湿法窑的冷却机,水泥烧成系统3的水泥窑尾为带加热器湿法窑的加热器。煤粉喂料装置14与水泥烧成系统3的煤粉燃烧器4相连。Example 4: In Example 2, in the integrated lignite catalytic mild pyrolysis upgrading integrated system in cement production, the cement firing system can also be a wet process kiln with a heater, which includes a heater, a cooler and a pulverized coal combustion Among them, the clinker cooling cooler of the cement firing system 3 is a cooler of a wet kiln with a heater, and the tail of the cement kiln of the cement firing system 3 is a heater of a wet kiln with a heater. The pulverized coal feeding device 14 is connected with the pulverized coal burner 4 of the cement burning system 3 .

预烘干机7为管式烘干机。The pre-dryer 7 is a tubular dryer.

研磨装置12为风扇磨。The grinding device 12 is a fan mill.

实施例2步骤(2)中,催化剂储仓18内的催化剂还可以按4%质量百分比向辊压机8内添加。In step (2) of Example 2, the catalyst in the catalyst storage bin 18 can also be added to the roller press 8 at a rate of 4% by mass.

Claims (5)

1. An integrated lignite catalytic mild pyrolysis upgrading integrated system in cement production is characterized by comprising a cement firing system, a crusher, a pre-dryer, a roller press, a catalyst storage bin, a drying crusher, a vertical drying cylinder and a cyclone separator;
the cooler for cooling clinker of the cement burning system is connected with the pre-dryer through a pipeline, the cement kiln tail of the cement burning system is connected with the drying crusher through a pipeline, the crusher, the pre-dryer, the roller press, the drying crusher, the vertical drying cylinder and the cyclone separator are sequentially connected, and the catalyst storage bin is connected with the roller press.
2. The integrated lignite catalytic mild pyrolysis upgrading system in cement production according to claim 1, further comprising a grinding device, a coal particle grading device, a pulverized coal feeding device, a dust collector and a water recovery device; the cyclone separator, the coal particle grading device and the coal powder feeding device are sequentially connected, the grinding device and the coal particle grading device are connected into a circulation loop, the cyclone separator is connected with the dust collector, the water recovery device and the grinding device are sequentially connected to form a circulation loop; the pulverized coal feeding device is connected with the pulverized coal burner of the cement burning system or the pulverized coal burner of the cement burning system and the decomposing furnace.
3. The integrated lignite catalytic mild pyrolysis upgrading system in cement production according to claim 1, wherein the pre-dryer is any one of a rotary dryer, a vertical dryer or a tubular dryer.
4. A process for carrying out lignite catalytic mild pyrolysis upgrading by utilizing an integrated lignite catalytic mild pyrolysis upgrading integrated system is characterized by sequentially comprising the following steps of: (1) primarily crushing raw lignite into coal blocks; (2) pre-drying and rolling and crushing the coal blocks into coal particles; (3) crushing the coal particles into coal powder by a drying crusher; (4) the fine coal powder is subjected to heat exchange drying and quality improvement through a vertical drying cylinder; (5) separating the upgraded lignite from gas in a cyclone separator to obtain an upgraded lignite finished product; wherein,
(1) primarily crushing raw lignite into coal blocks: putting raw lignite containing 15-60% of moisture into a crusher to be crushed into coal blocks at least smaller than 40 mm;
(2) pre-drying and rolling and crushing coal blocks into coal particles: feeding the coal blocks crushed by the crusher into a pre-dryer, blowing waste gas at least higher than 180 ℃ from a cooler for cooling clinker of a cement sintering system into the pre-dryer for pre-drying so as to at least increase the temperature of the coal blocks to 105 ℃, feeding the coal blocks and the waste gas into a roller press for crushing, and adding a catalyst in a catalyst storage bin into the roller press according to the mass percentage of 0.5-6% to obtain 20-30% of coal particles smaller than 0.9mm, 65-80% of coal particles smaller than 2mm and the rest of coal particles larger than 2 mm; the catalyst is any one or the combination of more of potassium carbonate, calcium oxide or calcium hydroxide;
(3) crushing the coal particles into coal powder by a drying crusher: conveying the coal particles with gas from the roller press to a drying crusher, feeding waste gas with the temperature of more than 260 ℃ from the tail of a cement kiln of the cement burning system into the drying crusher, further drying, crushing and dispersing the coal particles in the drying crusher to obtain fine coal powder with the particle size of less than 1mm, and blowing the fine coal powder into a vertical drying cylinder along with flue gas;
(4) the fine coal powder is subjected to heat exchange drying and quality improvement through a vertical drying cylinder: feeding the fine coal powder into the vertical drying cylinder, and performing heat exchange drying and quality improvement until the water content is reduced to 5-10%;
(5) separating the upgraded lignite from gas in a cyclone separator to obtain an upgraded lignite finished product: the gas carrying the fine coal powder enters a cyclone separator, heat exchange and gas-solid separation are carried out to obtain an upgraded lignite finished product with the moisture content of 5-10% by mass, and the separated gas is emptied.
5. The process for upgrading the lignite catalytic mild pyrolysis by utilizing the integrated lignite catalytic mild pyrolysis upgrading system according to claim 4, which is characterized by further comprising (6) waste gas treatment and utilization; (7) grinding and grading the upgraded lignite finished product; (8) the upgraded lignite finished product with the granularity of less than 200 meshes is used by the cement burning system;
wherein the (6) exhaust gas treatment and utilization: the waste flue gas from the cyclone separator is collected by a dust collector, the separated fine coal powder is conveyed to a coal powder feeding device, the flue gas after dust removal is introduced into a water recovery device, and one part of the flue gas after drying by the water recovery device is introduced into a grinding deviceThe other part of the dust content is less than 50mg/Nm3Exhaust gas evacuation meeting the environmental protection requirement is achieved;
(7) grinding and grading the upgraded lignite finished product: after the pulverized coal from the cyclone separator is screened by a coal particle grading device, the pulverized coal with the particle size of more than 200 meshes is sent to the grinding device and ground under the action of the waste gas from the water recovery device, the ground pulverized coal returns to the coal particle grading device to be mixed with the pulverized coal in the coal particle grading device, screening is carried out again, the waste gas is discharged into the dust collector to collect dust, and the upgraded lignite finished product with the particle size of less than 200 meshes is sent to the pulverized coal feeding device after being screened by the coal particle grading device;
(8) the upgraded lignite finished products with the granularity of less than 200 meshes are supplied to the cement burning system for utilization: and feeding the ground and graded upgraded lignite finished products into a pulverized coal burner of the cement burning system or the pulverized coal burner and a decomposing furnace of the cement burning system through a pulverized coal feeding device for combustion.
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