CN102030594A - Silicon-calcium-iron-potassium biological magnetic fertilizer - Google Patents
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Abstract
本发明公开了一种硅钙铁钾生物磁化肥,是将硅酸盐矿物质、火电厂等排放废物粉煤灰、硫铁矿灰、腐植酸进行一定的配比,并结合生物技术、磁化技术生产出的一种颗粒状的多元生物磁化肥。其主要成分包括:有效硅(SiO2)≥30%、有效钙(CaO)≥20%、Fe≥12%、K≥5%、Mg≥3%,其他中微量元素≥8%、有机质≥10%、有益生物菌≥2亿个/克(二次发酵后),其他中微量元素包括Zn、B、Mo、Se等。该肥可以有效提高作物对化肥的吸收率,减少化肥的使用量,抑制农作物对重金属、硝态氮、农药的吸收,净化和修复土壤,降低农作物病害发生,对解决农药污染、土壤板结、水体富营养化等环境问题以及提高农作物产品品质和食品安全等也有着重要的作用。
The invention discloses a silicon-calcium-iron-potassium bio-magnetic fertilizer, which mixes silicate minerals, waste fly ash, pyrite ash, and humic acid in a certain ratio, and combines biotechnology, magnetization A granular multi-component biomagnetic fertilizer produced by the technology. Its main components include: available silicon (SiO 2 ) ≥ 30%, available calcium (CaO) ≥ 20%, Fe ≥ 12%, K ≥ 5%, Mg ≥ 3%, other trace elements ≥ 8%, organic matter ≥ 10% %, beneficial biological bacteria ≥ 200 million/gram (after secondary fermentation), other medium and trace elements include Zn, B, Mo, Se, etc. The fertilizer can effectively improve the absorption rate of crops to chemical fertilizers, reduce the use of chemical fertilizers, inhibit the absorption of heavy metals, nitrate nitrogen, and pesticides by crops, purify and restore soil, reduce the occurrence of crop diseases, and solve pesticide pollution, soil compaction, and water bodies. Environmental issues such as eutrophication and improving crop product quality and food safety also play an important role.
Description
技术领域technical field
本发明涉及一种磁化肥,尤其涉及一种硅钙铁钾生物磁化肥。The invention relates to a magnetized fertilizer, in particular to a silicon-calcium-iron-potassium biological magnetized fertilizer.
背景技术Background technique
磁化肥是一种新型肥料,具有良好的经济、社会和生态效益,日益受到人们的重视。磁化肥是以土壤磁学和生物磁学为依据,以粉煤灰等为磁性载体与常规肥料加工成的一种低成本高效益新型肥料,经过磁化后的肥料不仅可以改善土壤的物理化学性状,增加土壤团里结构,而且能有效提高植物对营养的吸收,提高肥料本身利用率,进而能大幅提高作物的产量和品质。Magnetic fertilizer is a new type of fertilizer, which has good economic, social and ecological benefits, and is increasingly valued by people. Magnetized fertilizer is based on soil magnetism and biomagnetism, and is a low-cost, high-efficiency new type of fertilizer processed with fly ash as a magnetic carrier and conventional fertilizers. The magnetized fertilizer can not only improve the physical and chemical properties of the soil , increase the structure of the soil mass, and can effectively improve the absorption of nutrients by plants, improve the utilization rate of fertilizer itself, and thus greatly improve the yield and quality of crops.
目前市场上大多数的磁化肥因其养分结构配比不合理、复合性不高、生物活性不足、磁化肥的肥力不足、养分剩磁的稳定性不高、磁与肥的互促优势欠突出,使用效果没有达到预期的效果。Most of the magnetic fertilizers currently on the market are due to their unreasonable nutrient structure ratio, low compounding, insufficient biological activity, insufficient fertility of magnetic fertilizers, low stability of nutrient residual magnetism, and the mutual promotion advantages of magnetism and fertilizers are not outstanding. , the use effect did not achieve the expected effect.
发明内容Contents of the invention
本发明的目的是提供一种营养品种丰富、能够改土养土、物化指标稳定、互促作用优良的硅钙铁钾生物磁化肥。The object of the present invention is to provide a silicon-calcium-iron-potassium biomagnetic fertilizer which is rich in nutrient varieties, capable of improving and nourishing soil, stable in physical and chemical indicators, and excellent in mutual promotion.
本发明的目的是通过以下技术方案实现的:The purpose of the present invention is achieved through the following technical solutions:
本发明的硅钙铁钾生物磁化肥,包括以下组份:The silicon-calcium-iron-potassium biomagnetic fertilizer of the present invention comprises the following components:
硅酸盐矿物质、粉煤灰、硫铁矿灰、腐植酸、复合菌种;Silicate minerals, fly ash, pyrite ash, humic acid, compound bacteria;
所述硅酸盐矿物质的营养成份包括:有效硅SiO252%、有效钙CaO25%、Fe10%、K 7.2%,还包括微量元素B、Zn、Mo、Se;The nutrients of the silicate minerals include: 52% of available silicon SiO 2 , 25% of available calcium CaO, 10% of Fe, 7.2% of K, and trace elements B, Zn, Mo, Se;
所述复合菌种是由山东多利德生物科技有限公司生产的拟康氏木霉和枯草芽孢杆菌;The composite bacterial species is Trichoderma pseudoconii and Bacillus subtilis produced by Shandong Dolide Biotechnology Co., Ltd.;
该肥磁化过程选择的磁化强度磁场强度200-500A/m,磁化时间4-8秒,激磁功率1-5KW;The magnetization magnetic field strength selected in the fertilizer magnetization process is 200-500A/m, the magnetization time is 4-8 seconds, and the excitation power is 1-5KW;
上述的百分比为质量百分比。The above-mentioned percentages are percentages by mass.
由上述本发明提供的技术方案可以看出,本发明所述的硅钙铁钾生物磁化肥,由于包括硅酸盐矿物质、粉煤灰、硫铁矿灰、腐植酸、菌种等;硅酸盐矿物质的营养成份包括:有效硅SiO2、有效钙CaO、Fe、K、Mg,还包括微量元素B、Zn、Mo、Se等;菌种包括拟康氏木霉和枯草芽孢杆菌。将硅酸盐矿物质、生物肥技术及磁化技术整合到一起,营养品种丰富、作物专性强、物化指标稳定、互促作用优良。As can be seen from the technical scheme provided by the present invention above, the silicon-calcium-iron-potassium biomagnetic fertilizer of the present invention includes silicate minerals, fly ash, pyrite ash, humic acid, bacterial classification, etc.; The nutrients of salt minerals include: available silicon SiO 2 , available calcium CaO, Fe, K, Mg, and trace elements B, Zn, Mo, Se, etc.; bacteria include Trichoderma pseudoconii and Bacillus subtilis. Integrating silicate minerals, bio-fertilizer technology and magnetization technology, it has rich nutritional varieties, strong crop specificity, stable physical and chemical indicators, and excellent mutual promotion.
附图说明Description of drawings
图1为本发明硅钙铁钾生物磁化肥的配置流程图。Fig. 1 is the configuration flowchart of silicon calcium iron potassium biomagnetic fertilizer of the present invention.
具体实施方式Detailed ways
本发明的硅钙铁钾生物磁化肥,其较佳的具体实施方式,包括以下组份:The silicon-calcium-iron-potassium biomagnetic fertilizer of the present invention, in its preferred embodiment, comprises the following components:
硅酸盐矿物质、粉煤灰、硫铁矿灰、腐植酸、复合菌种;Silicate minerals, fly ash, pyrite ash, humic acid, compound bacteria;
所述硅酸盐矿物质的营养成份包括:有效硅SiO252%、有效钙CaO25%、Fe10%、K 7.2%,还包括微量元素B、Zn、Mo、Se;The nutrients of the silicate minerals include: 52% of available silicon SiO 2 , 25% of available calcium CaO, 10% of Fe, 7.2% of K, and trace elements B, Zn, Mo, Se;
所述复合菌种是由山东多利德生物科技有限公司生产的拟康氏木霉和枯草芽孢杆菌;The composite bacterial species is Trichoderma pseudoconii and Bacillus subtilis produced by Shandong Dolide Biotechnology Co., Ltd.;
该肥磁化过程选择的磁化强度磁场强度200-500A/m,磁化时间4-8秒,激磁功率1-5KW;The magnetization magnetic field strength selected in the fertilizer magnetization process is 200-500A/m, the magnetization time is 4-8 seconds, and the excitation power is 1-5KW;
上述的百分比为质量百分比。The above-mentioned percentages are percentages by mass.
具体实施例中,硅钙铁钾生物磁化肥组份的质量配比为每1000Kg硅钙铁钾生物磁化肥中含有:In a specific embodiment, the mass ratio of the silicon-calcium-iron-potassium bio-magnetic fertilizer component is to contain in every 1000Kg of the silicon-calcium-iron-potassium biomagnetic fertilizer:
硅酸盐矿物质:500Kg;Silicate minerals: 500Kg;
粉煤灰:280Kg;Fly ash: 280Kg;
硫铁矿灰:100Kg;Pyrite ash: 100Kg;
腐植酸:100Kg;Humic acid: 100Kg;
复合菌种:20Kg。Composite bacteria: 20Kg.
上述硅钙铁钾生物磁化肥的性能指标包括:The performance indicators of the above-mentioned silicon-calcium-iron-potassium biomagnetic fertilizer include:
有效硅SiO2≥30%;Effective silicon SiO 2 ≥ 30%;
有效钙CaO≥20%;Effective calcium CaO≥20%;
Fe≥12%;Fe≥12%;
K≥5%;K≥5%;
Mg≥3%;Mg≥3%;
其他中微量元素≥8%;Other medium and trace elements ≥ 8%;
有机质≥10%;Organic matter ≥ 10%;
有益生物菌≥2亿个/克;Beneficial biological bacteria ≥ 200 million/g;
颗粒度2~5mm;Particle size 2~5mm;
水份≤5%;Moisture ≤5%;
剩磁强度≥600nT。Remanence intensity ≥ 600nT.
硅酸盐矿物质在造粒程序中,可以采用滚筒蒸汽造粒,保证颗粒度在2~5mm。In the granulation process of silicate minerals, drum steam granulation can be used to ensure that the particle size is 2-5mm.
本发明将磁性载体(粉煤灰和硫铁矿)加入矿质离子丰富的硅钙盐矿物质和有机质,并注入扩大后的共生拟康氏木霉和枯草芽孢杆菌,将土壤生物磁学理论、生物肥技术与磁化技术相结合,营养品种丰富、作物专性强、物化指标稳定、互促作用优良。解决了市场上大多数的磁化肥因其养分组成配比不合理、复合性不高、磁化肥的肥力不足、养分剩磁的稳定性及造粒质量差、磁与肥的互促优势欠突出、使用效果达不到预期的效果等问题。In the present invention, magnetic carriers (fly ash and pyrite) are added to silicon-calcium salt mineral matter and organic matter rich in mineral ions, and injected into the enlarged symbiotic Trichoderma pseudoconii and Bacillus subtilis, and the soil biomagnetism theory, The combination of biological fertilizer technology and magnetization technology has rich nutritional varieties, strong crop specificity, stable physical and chemical indicators, and excellent mutual promotion. It solves the problem of most magnetic fertilizers on the market due to their unreasonable nutrient composition ratio, low compounding, insufficient fertility of magnetic fertilizers, poor stability of nutrient residual magnetism and poor granulation quality, and the mutual promotion advantages of magnetism and fertilizers are not outstanding. , The use effect can not achieve the expected effect and other problems.
如图1所示,是本发明的磁化肥的配置流程图。As shown in Figure 1, it is a configuration flow chart of the magnetic fertilizer of the present invention.
本发明的主要成份为硅酸盐矿物质、粉煤灰、硫铁矿灰、有机质和生物菌,它兼具养分、剩磁和改土多重功能。养分配比与剩磁量的选择决定其对作物营养效能及改良土壤的完善程度。The main components of the invention are silicate minerals, fly ash, pyrite ash, organic matter and biological bacteria, and it has multiple functions of nutrition, remanence and soil improvement. The choice of nutrient distribution ratio and remanent magnetism determines its degree of perfection for crop nutritional efficiency and soil improvement.
该磁化肥经过在山东省潍坊市凌河、石埠子、召忽等乡镇大姜、水稻、小麦、玉米、棉花、果树及盐碱地树木生长试验后发现与其他磁化肥相比其效能有:Compared with other magnetic fertilizers, the magnetic fertilizer has been tested on the growth of ginger, rice, wheat, corn, cotton, fruit trees and trees in saline-alkali land in Linghe, Shibuzi, Zhaohu and other townships in Weifang City, Shandong Province. Compared with other magnetic fertilizers, it has:
提供植物生长所需主要物质及中微量元素:有效硅(SiO2)、有效钙(CaO)、Fe、K及B、Mg、Zn、Mo、Se等,经过微生物及磁化作用后,土壤物理化学性质得到较大程度改善,改良植物生长的微环境。Provide the main substances and trace elements needed for plant growth: available silicon (SiO 2 ), available calcium (CaO), Fe, K and B, Mg, Zn, Mo, Se, etc. After microorganisms and magnetization, soil physical and chemical The properties are greatly improved, and the microenvironment for plant growth is improved.
抗倒伏,抗重茬,抗病虫害,抗污染:作物施硅钙铁钾磁化肥后,作物茎秆表皮能够提前硅质化,茎壁加厚,体内茎脉、茎管增粗,茎壁加厚,茎腔增大,利于营养成份及水分的运输,同时叶片角度减小,增加通风透光性,扩大光和面积,冠层光合作用提高10%以上,特别是水稻、小麦一类作物及大葱实验中效果最为明显。棉花用硅施肥后,产生一种较强的硅化细胞,使病菌不易侵蚀,害虫不易喷噬。在我们的实验中,棉花铃蕾及早吸收硅元素后,表皮硬度增加,所以早期棉铃虫不易啃食,减少虫害和落蕾。硅钙肥的硅酸根离子与汞、铅等重金属发生化学反应,形成新的化台物沉淀下来、不易被作物吸收,同时能够增强根系氧化能力,避免锰中毒和重金属的污染。Anti-lodging, anti-heavy cropping, anti-disease and insect pests, anti-pollution: After the crops are fertilized with silicon-calcium-iron-potassium magnetic fertilizers, the epidermis of the crop stems can be silicified in advance, the stem walls are thickened, and the stem veins and tubes in the body are thickened, and the stem walls are thickened , the stem cavity is enlarged, which is conducive to the transportation of nutrients and water, and the angle of the leaves is reduced, which increases the ventilation and light transmission, expands the light and area, and increases the photosynthesis of the canopy by more than 10%, especially for rice, wheat and other crops and green onions The effect is most obvious in the experiment. After cotton is fertilized with silicon, a strong silicified cell is produced, which makes it difficult for germs to erode and pests to phagocytize. In our experiment, after the cotton boll buds absorb silicon early, the hardness of the epidermis increases, so the early cotton bollworms are not easy to eat, reducing insect damage and bud drop. The silicate ions of silicon-calcium fertilizer chemically react with heavy metals such as mercury and lead to form new compounds that precipitate and are not easily absorbed by crops. At the same time, they can enhance the oxidation ability of roots and avoid manganese poisoning and heavy metal pollution.
拟康氏木霉和枯草芽孢杆共生菌群:施用后能固氮、解磷、解钾,为作物提供大量营养物质,能提高地温,迅速缓解土壤板结状况,改善土壤理化性状,增加土壤团粒结构,提高土壤保温、保肥、透气性能,吸收能力增强,分解残留的农药防止土壤盐渍化,解决重茬病问题,有效控制或避免病虫害的发生,减少农药的使用量,提高肥料的利用效率从而可减少农民朋友的投资成本。Trichoderma pseudoconii and Bacillus subtilis symbiotic flora: After application, it can fix nitrogen, decompose phosphorus and potassium, provide a large amount of nutrients for crops, increase ground temperature, quickly relieve soil compaction, improve soil physical and chemical properties, and increase soil aggregate structure , improve soil heat preservation, fertilizer retention, air permeability, enhanced absorption capacity, decompose residual pesticides to prevent soil salinization, solve the problem of heavy cropping diseases, effectively control or avoid the occurrence of pests and diseases, reduce the use of pesticides, and improve the utilization efficiency of fertilizers. It can reduce the investment cost of farmers' friends.
合理调节作物不同时期对养分的需求、改良土壤物理化学性质:土壤经适宜的磁场处理可明显改变其持水特性和供水能力,可使土壤形成较大颗粒的微团聚体,改善土壤结构,同时降低土壤的粘性和膨胀性,增加土壤可溶性营养物质含量,调节土壤酸碱平衡,有效降低盐碱土壤中全盐含量。硅钙等物质和菌种能活化土壤中磷钾等营养元素,破除土壤中难溶性磷的转化,利于作物吸收、促进磷在植物体能的运输,提高结实率。磁化后的硅钙肥物质保留一定的剩磁,其中的铁磁性物质可以矫正土壤酸碱度,土壤中的水分可使Fe2O3逐渐形成Fe(OH)3,可使PH很好的稳定在6.5-7.5之间,而且能够使盐碱土壤全盐量降低22.1%(北京林业大学十一五困难立地造林盐碱地造林项目中得出),抑制土壤有害病菌,如霉菌、根腐菌等。Reasonably adjust the nutrient requirements of crops in different periods and improve the physical and chemical properties of the soil: After the soil is treated with a suitable magnetic field, its water holding characteristics and water supply capacity can be significantly changed, and the soil can form larger particle micro-aggregates to improve the soil structure. Reduce the viscosity and expansibility of the soil, increase the content of soluble nutrients in the soil, adjust the acid-base balance of the soil, and effectively reduce the total salt content in saline-alkali soil. Substances such as silicon and calcium and bacterial strains can activate nutrients such as phosphorus and potassium in the soil, break the transformation of insoluble phosphorus in the soil, facilitate crop absorption, promote the transportation of phosphorus in plant energy, and increase the rate of seed setting. The magnetized silicon-calcium fertilizer material retains a certain amount of remanence, and the ferromagnetic material in it can correct the pH of the soil, and the moisture in the soil can make Fe 2 O 3 gradually form Fe(OH) 3 , which can stabilize the pH at 6.5 Between -7.5, and can reduce the total salt content of saline-alkali soil by 22.1% (obtained from the afforestation project of Beijing Forestry University on difficult sites during the 11th Five-Year Plan), and inhibit harmful soil bacteria, such as mold and root rot.
影响土壤微生物微环境促进植物生长发育:土壤中存在不同种类的趋磁性微生物菌如球菌、芽孢菌、固氮菌、螺旋菌、酵素菌等,其体内均可合成并携带具有单磁畴大小范围的铁磁(Fe3O4)微晶体粒,外界磁场变化时,可增加其活力,加速土壤中有机质分解。磁场还直接影响蛋白质和酶的活性,磁化肥活性使得原子中电子自转方向发生变化,使金属离子活化度增加,提高了酶的活性,加速土壤有机质类养分的分解,利于作物吸收。Affect the microenvironment of soil microorganisms to promote plant growth and development: There are different types of magnetotactic microorganisms in the soil, such as cocci, spores, nitrogen-fixing bacteria, spirochetes, enzyme bacteria, etc., which can synthesize and carry molecules with a single magnetic domain size range. Ferromagnetic (Fe 3 O 4 ) microcrystalline particles can increase their vitality and accelerate the decomposition of organic matter in soil when the external magnetic field changes. The magnetic field also directly affects the activity of proteins and enzymes. The activity of magnetized fertilizers changes the rotation direction of electrons in atoms, increases the activation degree of metal ions, improves the activity of enzymes, and accelerates the decomposition of soil organic matter nutrients, which is beneficial to crop absorption.
提高产量,改善农产品品质:该肥可以使蔬菜瓜果糖分和维生素、花生脂肪、小麦蛋白质含量明显提高,还可以增强桃梨等水果的硬度,在苹果等水果表皮形成硅化细胞,提高着色度。经过在山东省潍坊市石埠子镇苹果、草莓、大樱桃基地实验中发现,长期使用硅钙铁钾磁化肥后果实的形状、色泽都得到较大改善,含糖量平均可提高15%,使用该肥的水果普遍得到经销商的喜爱,销售价格也比较高,同时果品在耐贮性上也得到加大提高,便于运输。Increase yield and improve the quality of agricultural products: This fertilizer can significantly increase the sugar and vitamin content of vegetables and fruits, peanut fat, and wheat protein content. After experiments in the apple, strawberry, and big cherry bases in Shibuzi Town, Weifang City, Shandong Province, it was found that after long-term use of silicon-calcium-iron-potassium magnetic fertilizers, the shape and color of the fruits have been greatly improved, and the sugar content can be increased by an average of 15%. Fruits using this fertilizer are generally favored by dealers, and the sales price is relatively high. At the same time, the fruit's storage resistance is also improved, which is convenient for transportation.
具体实验数据如下:The specific experimental data are as follows:
1、盐碱地造林,实验选用当地乡土树种白蜡、国槐,使用各种肥料生长半年后降盐及促进生长情况统计:1. For afforestation on saline-alkali land, the experiment selected local native tree species white wax and Chinese pagoda tree, and used various fertilizers to reduce salt and promote growth after half a year of growth statistics:
(1)白蜡实验对比:(1) white wax experiment comparison:
(2)国槐实验对比:(2) Guohuai experiment comparison:
2、在山东省潍坊市凌河蔬菜基地大姜试验地对比试验:2. Contrastive experiment in ginger experiment field in Linghe Vegetable Base, Weifang City, Shandong Province:
(1)小型拱棚实验结果:(1) Experimental results of small arch shed:
由以上数据可以看出:在小拱棚蔬菜基地大姜实验中,硅钙铁钾生物磁化肥比普通肥料平均增产1523Kg,平均增长率为25.3%。From the above data, it can be seen that in the ginger experiment in the small shed vegetable base, the silicon-calcium-iron-potassium biomagnetic fertilizer increased the yield by an average of 1523Kg compared with ordinary fertilizers, and the average growth rate was 25.3%.
(2)大型拱棚实验结果:(2) Experimental results of large arch shed:
由以上数据可以看出:在大拱棚蔬菜基地大姜实验中,硅钙铁钾生物磁化肥比普通肥料平均增产1482Kg,平均增长率为20.1%。From the above data, it can be seen that in the large ginger experiment in the vegetable base of the big shed, the silicon-calcium-iron-potassium bio-magnetic fertilizer increased the yield by an average of 1482Kg compared with ordinary fertilizers, and the average growth rate was 20.1%.
3.大葱试验地不同肥料实验结果对比如下:3. The test results of different fertilizers in the green onion test field are compared as follows:
由以上数据可以看出:在大葱蔬菜基地实验中,硅钙铁钾生物磁化肥比普通肥料平均增产1315-1546Kg,平均增长率为17.2%-26.0%。From the above data, it can be seen that in the green onion vegetable base experiment, the silicon-calcium-ferric-potassium biomagnetic fertilizer increased the yield by an average of 1315-1546Kg compared with ordinary fertilizers, and the average growth rate was 17.2%-26.0%.
4.水稻产区肥料试验对比:4. Comparison of fertilizer tests in rice producing areas:
由以上数据可以看出:在水稻田实验中,硅钙铁钾生物磁化肥比其他肥料平均增产50Kg,平均增长率为8.1%。From the above data, it can be seen that in the rice field experiment, the silicon-calcium-ferric-potassium bio-magnetic fertilizer has an average yield increase of 50Kg compared with other fertilizers, and the average growth rate is 8.1%.
5.小麦产区肥料试验对比:5. Comparison of fertilizer tests in wheat producing areas:
由以上数据可以看出:在小麦实验中,硅钙铁钾生物磁化肥比其他肥料平均增产38Kg,平均增长率为10.2%。It can be seen from the above data that in the wheat experiment, the silicon-calcium-ferric-potassium biomagnetic fertilizer increased the yield by an average of 38Kg compared with other fertilizers, and the average growth rate was 10.2%.
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明披露的技术范围内,可轻易想到的变化或替换,都应涵盖在本发明的保护范围之内。The above is only a preferred embodiment of the present invention, but the scope of protection of the present invention is not limited thereto. Any person familiar with the technical field can easily conceive of changes or changes within the technical scope disclosed in the present invention. Replacement should be covered within the protection scope of the present invention.
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