CN101973064B - Method for producing green attapulgite polymer clay - Google Patents
Method for producing green attapulgite polymer clay Download PDFInfo
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- CN101973064B CN101973064B CN2010102402985A CN201010240298A CN101973064B CN 101973064 B CN101973064 B CN 101973064B CN 2010102402985 A CN2010102402985 A CN 2010102402985A CN 201010240298 A CN201010240298 A CN 201010240298A CN 101973064 B CN101973064 B CN 101973064B
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- 239000004927 clay Substances 0.000 title claims abstract description 32
- 229960000892 attapulgite Drugs 0.000 title claims abstract description 24
- 229910052625 palygorskite Inorganic materials 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 229920000642 polymer Polymers 0.000 title abstract 11
- 239000000203 mixture Substances 0.000 claims abstract description 53
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 32
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 32
- 238000003756 stirring Methods 0.000 claims abstract description 22
- 239000000047 product Substances 0.000 claims abstract description 8
- 239000011265 semifinished product Substances 0.000 claims abstract description 8
- 239000000919 ceramic Substances 0.000 claims description 36
- 239000000843 powder Substances 0.000 claims description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- 239000004576 sand Substances 0.000 claims description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 18
- 239000012153 distilled water Substances 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 12
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 11
- 238000000746 purification Methods 0.000 claims description 11
- 239000000440 bentonite Substances 0.000 claims description 10
- 229910000278 bentonite Inorganic materials 0.000 claims description 10
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 10
- 239000004113 Sepiolite Substances 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 229910052624 sepiolite Inorganic materials 0.000 claims description 9
- 235000019355 sepiolite Nutrition 0.000 claims description 9
- 229920002545 silicone oil Polymers 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 5
- 238000004898 kneading Methods 0.000 claims description 4
- 238000004062 sedimentation Methods 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 230000003301 hydrolyzing effect Effects 0.000 claims description 2
- 230000008676 import Effects 0.000 claims description 2
- 239000013049 sediment Substances 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 230000007306 turnover Effects 0.000 claims description 2
- 239000002932 luster Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- 238000007493 shaping process Methods 0.000 abstract 2
- NCWQJOGVLLNWEO-UHFFFAOYSA-N methylsilicon Chemical compound [Si]C NCWQJOGVLLNWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 238000007789 sealing Methods 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000001737 promoting effect Effects 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000009967 tasteless effect Effects 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241001062009 Indigofera Species 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000011022 opal Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a method for producing green attapulgite polymer clay, the technical scheme thereof is characterized by adding green sand-grain shaped attapulgite mixture to a running horizontal type flour-mixing machine, slowly adding sodium polyacrylate sol-gel to the green sand-grain shaped attapulgite mixture, and stirring the mixture to obtain green massive attapulgite mixture; spraying methyl silicon oil on the green massive attapulgite mixture, and rubbing the sprayed mixture to obtain the semi-finished product of the green attapulgite polymer clay; and finally suppressing the green attapulgite polymer clay to form the flat green attapulgite polymer clay, and sealing and packaging the flat green attapulgite polymer clay to obtain the finished product. The green attapulgite polymer clay has the advantages of high viscosity, good soft plasticity, and small contractibility rate; in addition, the green attapulgite polymer clay is hardened after being subject to air dry, in no need of baking, and has nonoccurrence of cracks, no corrosiveness and non-greasy feeling. The green attapulgite polymer clay is mixed with other colorific attapulgite polymer clay for use, thus being capable of shaping artwares with clear patterns, fresh and lovely luster and vivid effect; and the green attapulgite polymer clay is suitable for the shaping of patterns, moulds and artwares.
Description
Technical field
The present invention relates to the mud of making pottery, be specifically related to the production method of the concavo-convex excellent soft ceramic mud of a kind of green.
Background technology
The primary raw material of soft ceramic mud is polyvinyl chloride and calcium carbonate, cohesive is bad under the normal temperature state, long preservation easily wears out and fades, bubble easily during the baking soft ceramic mud,, finished product is burnt and melt if when temperature surpasses 200 ℃, even may cause burning, generate chloride excitant toxic smog, the selling price of soft ceramic mud is higher, is unfavorable for promoting the use of.
The Chinese patent publication number is: CN 101186736, open day: on May 28th, 2008, name is called " a kind of soft ceramic mud and preparation method thereof ", disclose: " a kind of soft ceramic mud and preparation method; it is prepared from by following parts by weight of component: PVC paste resin 15～40, bizinc resin 20～55, calcium carbonate 15～35, plasticizer 0.1～0.4, toner 0.5～0.15, all the other are micro-moisture and impurity ".
The weak point of above-mentioned patent is that the soft ceramic mud primary raw material that this technology is produced is PVC paste resin, bizinc resin and calcium carbonate, and cohesive is bad under the normal temperature state, is unfavorable for making moulding, and bizinc resin belongs to poisonous substance.
The Chinese patent Granted publication number is: CN 1273531, Granted publication day: on September 6th, 2006, name is called " a kind of manufacture method of transparent texture resin clay ", disclose: " a kind of manufacture method of transparent texture resin clay; it is characterized in that: it is at first mixed together by ethylene powder-vinyl acetate copolymer, starch, glycerine, anticorrisive agent, spices and adds water purification again and stir into mud shape thing; and then add atoleine and mix and stir, vacuum-packed finished product ".
The weak point of above-mentioned patent is that the transparent texture resin clay primary raw material that this technology is produced is ethylene powder-vinyl acetate copolymer and starch, ethylene powder-vinyl acetate copolymer has spread effect to eyes and skin, be not suitable for being used to manufacture the raw material of artifacts, need a large amount of starch in this product, be unfavorable for promoting the use of.
Summary of the invention
The objective of the invention is to overcome weak point in the prior art, the production method of the concavo-convex excellent soft ceramic mud of a kind of green is provided.
The production method of green concavo-convex excellent soft ceramic mud is: the concavo-convex excellent mixture of green sand shape is added in the horizontal dough mixer that has turned round, and the Sodium Polyacrylate gel solution slowly added in the concavo-convex excellent mixture of green sand shape, mix and stir and be the concavo-convex excellent mixture of green clod shape; Be sprayed on the concavo-convex excellent mixture of green clod shape with methyl-silicone oil, kneading becomes the semi-finished product of green concavo-convex excellent soft ceramic mud, is pressed into the green concavo-convex excellent soft ceramic mud of tabular at last, packs to be finished product.
Green concavo-convex excellent soft ceramic mud is green by Concave-convex clay rod powder, white bentonite in powder, sepiolite powder, anatase thpe white powder, the compound iron after purifying, Sodium Polyacrylate, propane diols, methyl-silicone oil and distilled water are formed.
Use the wet beneficiation craft of concavo-convex rod, the screening of mineral such as the hydromica in the Concave-convex clay rod, quartz, opal and carbonate is got rid of, obtain the Concave-convex clay rod after a kind of purify, the Concave-convex clay rod soil property exquisiteness after the purification, smooth surface, quality is lighter, be viscosity and plasticity when moist, its viscosity can reach more than the 3000mPas, helps the bonding between the raw material, the dry post-shrinkage ratio of Concave-convex clay rod is little, and does not produce be full of cracks; Concave-convex clay rod powder after the described purification is that the Concave-convex clay rod after purifying is carried out abrasive dust, the Concave-convex clay rod powder particles fineness after the purification that the present invention selects for use≤0.074 millimeter.
The white bentonite is the bentonite of a kind of high whiteness and high brightness, have excellent plasticity, caking property and lubricity, help improving the intensity after property bright in luster, plasticity and the air dry of green concavo-convex excellent soft ceramic mud, the white bentonite in powder grain fineness that the present invention selects for use≤0.074 millimeter.
Sepiolite is a kind of rich fibrous magnesium silicate clay mineral, be light white or canescence, have fine and smooth soft, viscosity is strong, shrinkage factor is low and plasticity the is good characteristics of silky luster, light weight, help improving property bright in luster, gloss and the mouldability of green concavo-convex excellent soft ceramic mud, sepiolite powder grain fineness≤0.074 that the present invention selects for use millimeter.
Anatase thpe white powder has excellent water dispersible and remarkable optical property, form and aspect stability, size distribution is good, characteristics with high glaze, high reducing power, high covering power, anatase thpe white powder grain fineness≤0.005 that the present invention selects for use millimeter helps improving the property bright in luster of green concavo-convex excellent soft ceramic mud.
Compound iron is green to be to be mixed with iron oxide yellow and organic pigment phthalocyanine indigo plant to form, bright-colored, and fast light preferably, weather-proof, acidproof and alkali resistance are arranged, nontoxic, dispersed fabulous in water-based system, price is relatively cheap, the green grain fineness of compound iron that the present invention selects for use≤0.045 millimeter.
Sodium Polyacrylate is a kind of white powder, odorless, tasteless and nontoxic can be slowly soluble in water, forms extremely sticky transparent gel, have thickening, emulsification, figuration, multiple function such as expanded, stable, can improve the caking property and the ductility of green concavo-convex excellent soft ceramic mud.
Propane diols is the stable water imbibition liquid of a kind of water white transparency toughness, and is water-soluble, in the present invention as solvent, emulsifying agent, antifreezing agent and lubricant.
Methyl-silicone oil is a kind of water white thick liquid, has colourless, tasteless, not volatile and water-fast characteristics, in the present invention as defoamer, releasing agent, lubricant and optical brightener.
Distilled water is meant with the pure water of distillating method preparation, uses distilled water can effectively improve the viscosity of Sodium Polyacrylate gelinite in the present invention.
The present invention is achieved by following technical proposals:
1, the production method of green concavo-convex excellent soft ceramic mud is: 1. the concavo-convex excellent mixture of green sand shape is added in the horizontal dough mixer that has turned round, and the Sodium Polyacrylate gel solution slowly added in the concavo-convex excellent mixture of green sand shape, mix and stir and be the concavo-convex excellent mixture of green clod shape; 2. the concavo-convex excellent mixture of green clod shape is added in the dough kneeding machine, be sprayed on the concavo-convex excellent mixture of green clod shape with methyl-silicone oil, kneading becomes the semi-finished product of green concavo-convex excellent soft ceramic mud; 3. the concavo-convex excellent soft ceramic mud semi-finished product of green are added in the oodle maker and press repeatedly 2～4 times, be pressed into the green concavo-convex excellent soft ceramic mud of tabular at last, pack and be finished product.
2, the batching of green concavo-convex excellent soft ceramic mud is made up of following component by weight percentage: the concavo-convex excellent mixture 60～85% of green sand shape, Sodium Polyacrylate gel solution 10～35% and methyl-silicone oil 0.1～5%.
The batching of the concavo-convex excellent mixture of described green sand shape is made up of following component by weight percentage: the Concave-convex clay rod powder 15～45% after the purification, white bentonite in powder 5～20%, sepiolite powder 5～15%, anatase thpe white powder 0.1～10%, compound iron green 0.01～8% and distilled water 25～65%;
The production method of the concavo-convex excellent mixture of described green sand shape is: stir in the green adding mixer of the Concave-convex clay rod powder after will purifying earlier, white bentonite in powder, sepiolite powder, anatase thpe white powder and compound iron, be green powdery attapulgite mixture after stirring, slowly add in the green powdery attapulgite mixture with distilled water again and stir, green powdery attapulgite mixture is carried out moistening, through stirring and moistening be the concavo-convex excellent mixture of green sand shape afterwards;
The batching of described Sodium Polyacrylate gel solution is made up of following component by weight percentage: Sodium Polyacrylate 0.1～5%, propane diols 0.3～25% and distilled water 70～99.6%;
The compound method of described Sodium Polyacrylate gel solution is: earlier Sodium Polyacrylate is added in the propane diols, when Sodium Polyacrylate in propane diols after the moistening dispersion, the common adding in the distilled water, slowly stir, be dissolved in fully in the distilled water up to Sodium Polyacrylate, form the Sodium Polyacrylate gel solution of thickness.
Concave-convex clay rod after the described purification, it is the concavo-convex excellent ore deposit mixture that will contain earth impurity, import in the hydrolytic tank after crushed, soak after 24 hours, dash with high-pressure pump and to turn over, and the sieve of the drum by making with stainless steel steel wire sieve removes the impurity more than 1 millimeter, send in the acclive sedimentation basin, continuation is dashed with high-pressure pump and is turned over, after 12 hours, because the proportion in concavo-convex excellent ore deposit is lighter, its the superiors in whole sediment draws this part concavo-convex excellent ore deposit with slush pump and sends in the flat sedimentation basin, emits unnecessary water after 15 hours, through 2-3 days air dry, take out the Concave-convex clay rod after this part concavo-convex excellent ore deposit is purification;
This technology is to adopt " the concavo-convex excellent wet beneficiation craft " in application on September 18th, 2003 by the inventor, and the Chinese patent Granted publication number is: CN1224463, Granted publication day: on October 26th, 2005.
The green concavo-convex excellent soft ceramic mud viscosity height that the present invention produces, soft plasticity is good, have that shrinkage factor is little, indeformable, hardening after air dry, do not need to toast, do not produce be full of cracks, not mouldy, never degenerate, not chafe, nontoxic, non-corrosiveness and do not have the characteristics of greasy feeling.
Green concavo-convex excellent soft ceramic mud mixes use with the concavo-convex excellent soft ceramic mud of other color, can mould clear patterns, lovely luster and effect handicraft true to nature.
Production technology of the present invention is simple, and is with low cost, helps promoting the use of.
Green concavo-convex excellent soft ceramic mud is applicable to moulds pattern, mould and handicraft.
The specific embodiment
The invention will be further described below in conjunction with embodiment:
1, the production method of green concavo-convex excellent soft ceramic mud is: 1. the concavo-convex excellent mixture of green sand shape is added in the horizontal dough mixer that has turned round, and the Sodium Polyacrylate gel solution slowly added in the concavo-convex excellent mixture of green sand shape, mix and stir and be the concavo-convex excellent mixture of green clod shape; 2. the concavo-convex excellent mixture of green clod shape is added in the dough kneeding machine, be sprayed on the concavo-convex excellent mixture of green clod shape with methyl-silicone oil, kneading becomes the semi-finished product of green concavo-convex excellent soft ceramic mud; 3. the concavo-convex excellent soft ceramic mud semi-finished product of green are added in the oodle maker and press repeatedly 3 times, be pressed into the green concavo-convex excellent soft ceramic mud of tabular at last, pack and be finished product.
2, the batching of green concavo-convex excellent soft ceramic mud is made up of following component by weight percentage: the concavo-convex excellent mixture 76% of green sand shape, Sodium Polyacrylate gel solution 22% and methyl-silicone oil 2%.
The batching of the concavo-convex excellent mixture of described green sand shape is made up of following component by weight percentage: the Concave-convex clay rod powder 34% after the purification, white bentonite in powder 14%, sepiolite powder 10%, anatase thpe white powder 3%, compound iron green 3% and distilled water 36%;
The production method of the concavo-convex excellent mixture of described green sand shape is: stir in the green adding mixer of the Concave-convex clay rod powder after will purifying earlier, white bentonite in powder, sepiolite powder, anatase thpe white powder and compound iron, be green powdery attapulgite mixture after stirring, slowly add in the green powdery attapulgite mixture with distilled water again and stir, green powdery attapulgite mixture is carried out moistening, through stirring and moistening be the concavo-convex excellent mixture of green sand shape afterwards;
The batching of described Sodium Polyacrylate gel solution is made up of following component by weight percentage: Sodium Polyacrylate 2%, propane diols 8% and distilled water 90%;
The compound method of described Sodium Polyacrylate gel solution is: earlier Sodium Polyacrylate is added in the propane diols, when Sodium Polyacrylate in propane diols after the moistening dispersion, the common adding in the distilled water, slowly stir, be dissolved in fully in the distilled water up to Sodium Polyacrylate, form the Sodium Polyacrylate gel solution of thickness.
Claims (1)
1. the production method of the concavo-convex excellent soft ceramic mud of green, it is characterized in that, 1. the concavo-convex excellent mixture of green sand shape is added in the horizontal dough mixer that has turned round, and the Sodium Polyacrylate gel solution slowly added in the concavo-convex excellent mixture of green sand shape, mix and stir and be the concavo-convex excellent mixture of green clod shape; 2. the concavo-convex excellent mixture of green clod shape is added in the dough kneeding machine, be sprayed on the concavo-convex excellent mixture of green clod shape with methyl-silicone oil, kneading becomes the semi-finished product of green concavo-convex excellent soft ceramic mud; 3. the concavo-convex excellent soft ceramic mud semi-finished product of green are added in the oodle maker and press repeatedly 2～4 times, be pressed into the green concavo-convex excellent soft ceramic mud of tabular at last, pack and be finished product;
The batching of the concavo-convex excellent soft ceramic mud of described green is made up of following component by weight percentage: the concavo-convex excellent mixture 60～85% of green sand shape, Sodium Polyacrylate gel solution 10～35% and methyl-silicone oil 0.1～5%;
The batching of the concavo-convex excellent mixture of described green sand shape is made up of following component by weight percentage: the Concave-convex clay rod powder 15～45% after the purification, white bentonite in powder 5～20%, sepiolite powder 5～15%, anatase thpe white powder 0.1～10%, compound iron green 0.01～8% and distilled water 25～65%;
The production method of the concavo-convex excellent mixture of described green sand shape is: stir in the green adding mixer of the Concave-convex clay rod powder after will purifying earlier, white bentonite in powder, sepiolite powder, anatase thpe white powder and compound iron, be green powdery attapulgite mixture after stirring, slowly add in the green powdery attapulgite mixture with distilled water again and stir, green powdery attapulgite mixture is carried out moistening, through stirring and moistening be the concavo-convex excellent mixture of green sand shape afterwards;
The batching of described Sodium Polyacrylate gel solution is made up of following component by weight percentage: Sodium Polyacrylate 0.1～5%, propane diols 0.3～25% and distilled water 70～99.6%;
The compound method of described Sodium Polyacrylate gel solution is: earlier Sodium Polyacrylate is added in the propane diols, when Sodium Polyacrylate in propane diols after the moistening dispersion, the common adding in the distilled water, slowly stir, be dissolved in fully in the distilled water up to Sodium Polyacrylate, form the Sodium Polyacrylate gel solution of thickness;
Concave-convex clay rod after the purification, it is the concavo-convex excellent ore deposit mixture that will contain earth impurity, import in the hydrolytic tank after crushed, soak after 24 hours, dash with high-pressure pump and to turn over, and the sieve of the drum by making with stainless steel steel wire sieve removes the impurity more than 1 millimeter, send in the acclive sedimentation basin, continuation is dashed with high-pressure pump and is turned over, after 12 hours, because the proportion in concavo-convex excellent ore deposit is lighter, its the superiors in whole sediment draws this part concavo-convex excellent ore deposit with slush pump and sends in the flat sedimentation basin, emits unnecessary water after 15 hours, through 2-3 days air dry, take out the Concave-convex clay rod after this part concavo-convex excellent ore deposit is purification.
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