[go: up one dir, main page]

CN101973063B - Method for producing brown attapulgite clay - Google Patents

Method for producing brown attapulgite clay Download PDF

Info

Publication number
CN101973063B
CN101973063B CN2010102402839A CN201010240283A CN101973063B CN 101973063 B CN101973063 B CN 101973063B CN 2010102402839 A CN2010102402839 A CN 2010102402839A CN 201010240283 A CN201010240283 A CN 201010240283A CN 101973063 B CN101973063 B CN 101973063B
Authority
CN
China
Prior art keywords
brown
concavo
convex excellent
convex
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2010102402839A
Other languages
Chinese (zh)
Other versions
CN101973063A (en
Inventor
许庆华
许盛英
汪成军
袁长兵
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Haimen Jiang Yong Investment & Development Co Ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN2010102402839A priority Critical patent/CN101973063B/en
Publication of CN101973063A publication Critical patent/CN101973063A/en
Application granted granted Critical
Publication of CN101973063B publication Critical patent/CN101973063B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a method for producing brown attapulgite clay. Key points of the technical scheme comprise the following steps of: adding brown grainy attapulgite mixtures into an operated horizontal flour mixing machine, slowly adding the gel solution of sodium polyacrylate into the brown grainy attapulgite mixtures and performing stirring to form a brown clod-shaped attapulgite mixture; and spraying methyl silicone oil onto the brown clod-shaped attapulgite mixture, performing kneading to form the brown attapulgite clay semi-finished product, pressing the brown attapulgite clay semi-finished product into a brown flat attapulgite clay and sealing and packaging the brown flat attapulgite clay into the finished product. The brown attapulgite clay has the characteristics of high viscosity, high softness, high plasticity, low shrinkage rate, hardness after being naturally dried, no need of baking, no cracks, non-corrosiveness and no greasy feeling, is mixed for use with the attapulgite clay in other colors to mold lifelike artware with clear patterns and bright colors, and is applied to the molding of the patterns, dies and the artware.

Description

The production method of brown concavo-convex excellent soft ceramic mud
Technical field
The present invention relates to the mud of making pottery, be specifically related to a kind of production method of brown concavo-convex excellent soft ceramic mud.
Background technology
The primary raw material of soft ceramic mud is polyvinyl chloride and calcium carbonate, cohesive is bad under the normal temperature state, long preservation easily wears out and fades, bubble easily during the baking soft ceramic mud,, finished product is burnt and melt if when temperature surpasses 200 ℃, even may cause burning, generate chloride excitant toxic smog, the selling price of soft ceramic mud is higher, is unfavorable for promoting the use of.
The Chinese patent publication number is: CN 101186736, open day: on May 28th, 2008, name is called " a kind of soft ceramic mud and preparation method thereof ", disclose: " a kind of soft ceramic mud and preparation method; it is prepared from by following parts by weight of component: PVC paste resin 15~40, bizinc resin 20~55, calcium carbonate 15~35, plasticizer 0.1~0.4, toner 0.5~0.15, all the other are micro-moisture and impurity ".
The weak point of above-mentioned patent is that the soft ceramic mud primary raw material that this technology is produced is PVC paste resin, bizinc resin and calcium carbonate, and cohesive is bad under the normal temperature state, is unfavorable for making moulding, and bizinc resin belongs to poisonous substance.
The Chinese patent Granted publication number is: CN 1273531, Granted publication day: on September 6th, 2006, name is called " a kind of manufacture method of transparent texture resin clay ", disclose: " a kind of manufacture method of transparent texture resin clay; it is characterized in that: it is at first mixed together by ethylene powder-vinyl acetate copolymer, starch, glycerine, anticorrisive agent, spices and adds water purification again and stir into mud shape thing; and then add atoleine and mix and stir, vacuum-packed finished product ".
The weak point of above-mentioned patent is that the transparent texture resin clay primary raw material that this technology is produced is ethylene powder-vinyl acetate copolymer and starch, ethylene powder-vinyl acetate copolymer has spread effect to eyes and skin, be not suitable for being used to manufacture the raw material of artifacts, need a large amount of starch in this product, be unfavorable for promoting the use of.
Summary of the invention
The objective of the invention is to overcome weak point in the prior art, a kind of production method of brown concavo-convex excellent soft ceramic mud is provided.
The production method of brown concavo-convex excellent soft ceramic mud is: the concavo-convex excellent mixture of brown sand shape is added in the horizontal dough mixer that has turned round, and the Sodium Polyacrylate gel solution slowly added in the concavo-convex excellent mixture of brown sand shape, mix and stir and be the concavo-convex excellent mixture of brown clod shape; Be sprayed on the concavo-convex excellent mixture of brown clod shape with methyl-silicone oil, kneading becomes the semi-finished product of brown concavo-convex excellent soft ceramic mud, is pressed into the brown concavo-convex excellent soft ceramic mud of tabular at last, packs to be finished product.
Brown concavo-convex excellent soft ceramic mud is made up of Concave-convex clay rod powder, white bentonite in powder, sepiolite powder, titanium manganese brown, organic pigment palm fibre, Sodium Polyacrylate, propane diols, methyl-silicone oil and distilled water after purifying.
Use the wet beneficiation craft of concavo-convex rod, the screening of mineral such as the hydromica in the Concave-convex clay rod, quartz, opal and carbonate is got rid of, obtain the Concave-convex clay rod after a kind of purify, the Concave-convex clay rod soil property exquisiteness after the purification, smooth surface, quality is lighter, be viscosity and plasticity when moist, its viscosity can reach more than the 3000mPas, helps the bonding between the raw material, the dry post-shrinkage ratio of Concave-convex clay rod is little, and does not produce be full of cracks; Concave-convex clay rod powder after the described purification is that the Concave-convex clay rod after purifying is carried out abrasive dust, the Concave-convex clay rod powder particles fineness after the purification that the present invention selects for use≤0.074 millimeter.
The white bentonite is the bentonite of a kind of high whiteness and high brightness, have excellent plasticity, caking property and lubricity, help improving the intensity after property bright in luster, plasticity and the air dry of brown concavo-convex excellent soft ceramic mud, the white bentonite in powder grain fineness that the present invention selects for use≤0.074 millimeter.
Sepiolite is a kind of rich fibrous magnesium silicate clay mineral, be light white or canescence, have fine and smooth soft, viscosity is strong, shrinkage factor is low and plasticity the is good characteristics of silky luster, light weight, help improving property bright in luster, gloss and the mouldability of brown concavo-convex excellent soft ceramic mud, sepiolite powder grain fineness≤0.074 that the present invention selects for use millimeter.
The titanium manganese brown is a kind of brown ceramic powder, has high tinting strength, tinting power, good covering power, dispersiveness, light resistance and heat endurance, the titanium manganese brown grain fineness that the present invention selects for use≤0.045 millimeter.
The organic pigment palm fibre is a kind of brown ceramic powder, has the characteristics of lovely luster, strong coloring force, sun-proof function admirable, the organic pigment palm fibre grain fineness that the present invention selects for use≤0.045 millimeter.
The present invention selects titanium manganese brown and organic pigment palm fibre simultaneously for use, can make full use of the advantage of two kinds of browns, helps making the color of brown concavo-convex excellent soft ceramic mud more bright-coloured.
Sodium Polyacrylate is a kind of white powder, odorless, tasteless and nontoxic can be slowly soluble in water, forms extremely sticky transparent gel, have thickening, emulsification, figuration, multiple function such as expanded, stable, can improve the caking property and the ductility of brown concavo-convex excellent soft ceramic mud.
Propane diols is the stable water imbibition liquid of a kind of water white transparency toughness, and is water-soluble, in the present invention as solvent, emulsifying agent, antifreezing agent and lubricant.
Methyl-silicone oil is a kind of water white thick liquid, has colourless, tasteless, not volatile and water-fast characteristics, in the present invention as defoamer, releasing agent, lubricant and optical brightener.
Distilled water is meant with the pure water of distillating method preparation, uses distilled water can effectively improve the viscosity of Sodium Polyacrylate gelinite in the present invention.
The present invention is achieved by following technical proposals:
1, the production method of brown concavo-convex excellent soft ceramic mud is: 1. the concavo-convex excellent mixture of brown sand shape is added in the horizontal dough mixer that has turned round, and the Sodium Polyacrylate gel solution slowly added in the concavo-convex excellent mixture of brown sand shape, mix and stir and be the concavo-convex excellent mixture of brown clod shape; 2. the concavo-convex excellent mixture of brown clod shape is added in the dough kneeding machine, be sprayed on the concavo-convex excellent mixture of brown clod shape with methyl-silicone oil, kneading becomes the semi-finished product of brown concavo-convex excellent soft ceramic mud; 3. brown concavo-convex excellent soft ceramic mud semi-finished product are added in the oodle maker and press repeatedly 2~4 times, be pressed into the brown concavo-convex excellent soft ceramic mud of tabular at last, pack and be finished product.
2, the batching of brown concavo-convex excellent soft ceramic mud is made up of following component by weight percentage: the concavo-convex excellent mixture 60~85% of brown sand shape, Sodium Polyacrylate gel solution 10~35% and methyl-silicone oil 0.1~5%.
The batching of the concavo-convex excellent mixture of described brown sand shape is made up of following component by weight percentage: the Concave-convex clay rod powder 15~45% after the purification, white bentonite in powder 5~25%, sepiolite powder 5~15%, titanium manganese brown 0.01~5%, organic pigment palm fibre 0.01~5% and distilled water 25~65%;
The production method of the concavo-convex excellent mixture of described brown sand shape is: stir in the Concave-convex clay rod powder after will purifying earlier, white bentonite in powder, sepiolite powder, titanium manganese brown and the organic pigment palm fibre adding mixer, be brown powdery attapulgite mixture after stirring, slowly add in the brown powdery attapulgite mixture with distilled water again and stir, brown powdery attapulgite mixture is carried out moistening, through stirring and moistening be the concavo-convex excellent mixture of brown sand shape afterwards;
The batching of described Sodium Polyacrylate gel solution is made up of following component by weight percentage: Sodium Polyacrylate 0.1~5%, propane diols 0.3~25% and distilled water 70~99.6%;
The compound method of described Sodium Polyacrylate gel solution is: earlier Sodium Polyacrylate is added in the propane diols, when Sodium Polyacrylate in propane diols after the moistening dispersion, the common adding in the distilled water, slowly stir, be dissolved in fully in the distilled water up to Sodium Polyacrylate, form the Sodium Polyacrylate gel solution of thickness.
Concave-convex clay rod after the described purification, it is the concavo-convex excellent ore deposit mixture that will contain earth impurity, import in the hydrolytic tank after crushed, soak after 24 hours, dash with high-pressure pump and to turn over, and the sieve of the drum by making with stainless steel steel wire sieve removes the impurity more than 1 millimeter, send in the acclive sedimentation basin, continuation is dashed with high-pressure pump and is turned over, after 12 hours, because the proportion in concavo-convex excellent ore deposit is lighter, its the superiors in whole sediment draws this part concavo-convex excellent ore deposit with slush pump and sends in the flat sedimentation basin, emits unnecessary water after 15 hours, through 2-3 days air dry, take out the Concave-convex clay rod after this part concavo-convex excellent ore deposit is purification;
This technology is to adopt " the concavo-convex excellent wet beneficiation craft " in application on September 18th, 2003 by the inventor, and the Chinese patent Granted publication number is: CN1224463, Granted publication day: on October 26th, 2005.
The brown concavo-convex excellent soft ceramic mud viscosity height that the present invention produces, soft plasticity is good, have that shrinkage factor is little, indeformable, hardening after air dry, do not need to toast, do not produce be full of cracks, not mouldy, never degenerate, not chafe, nontoxic, non-corrosiveness and do not have the characteristics of greasy feeling.
Brown concavo-convex excellent soft ceramic mud mixes use with the concavo-convex excellent soft ceramic mud of other color, can mould clear patterns, lovely luster and effect handicraft true to nature.
Production technology of the present invention is simple, and is with low cost, helps promoting the use of.
Brown concavo-convex excellent soft ceramic mud is applicable to moulds pattern, mould and handicraft.
The specific embodiment
The invention will be further described below in conjunction with embodiment:
1, the production method of brown concavo-convex excellent soft ceramic mud is: 1. the concavo-convex excellent mixture of brown sand shape is added in the horizontal dough mixer that has turned round, and the Sodium Polyacrylate gel solution slowly added in the concavo-convex excellent mixture of brown sand shape, mix and stir and be the concavo-convex excellent mixture of brown clod shape; 2. the concavo-convex excellent mixture of brown clod shape is added in the dough kneeding machine, be sprayed on the concavo-convex excellent mixture of brown clod shape with methyl-silicone oil, kneading becomes the semi-finished product of brown concavo-convex excellent soft ceramic mud; 3. brown concavo-convex excellent soft ceramic mud semi-finished product are added in the oodle maker and press repeatedly 3 times, be pressed into the brown concavo-convex excellent soft ceramic mud of tabular at last, pack and be finished product.
2, the batching of brown concavo-convex excellent soft ceramic mud is made up of following component by weight percentage: the concavo-convex excellent mixture 83% of brown sand shape, Sodium Polyacrylate gel solution 15% and methyl-silicone oil 2%.
The batching of the concavo-convex excellent mixture of described brown sand shape is made up of following component by weight percentage: the Concave-convex clay rod powder 35% after the purification, white bentonite in powder 15%, sepiolite powder 8%, titanium manganese brown 3%, organic pigment palm fibre 1% and distilled water 38%;
The production method of the concavo-convex excellent mixture of described brown sand shape is: stir in the Concave-convex clay rod powder after will purifying earlier, white bentonite in powder, sepiolite powder, titanium manganese brown and the organic pigment palm fibre adding mixer, be brown powdery attapulgite mixture after stirring, slowly add in the brown powdery attapulgite mixture with distilled water again and stir, brown powdery attapulgite mixture is carried out moistening, through stirring and moistening be the concavo-convex excellent mixture of brown sand shape afterwards;
The batching of described Sodium Polyacrylate gel solution is made up of following component by weight percentage: Sodium Polyacrylate 2%, propane diols 6% and distilled water 92%;
The compound method of described Sodium Polyacrylate gel solution is: earlier Sodium Polyacrylate is added in the propane diols, when Sodium Polyacrylate in propane diols after the moistening dispersion, the common adding in the distilled water, slowly stir, be dissolved in fully in the distilled water up to Sodium Polyacrylate, form the Sodium Polyacrylate gel solution of thickness.

Claims (1)

1. the production method of a brown concavo-convex excellent soft ceramic mud, it is characterized in that, 1. the concavo-convex excellent mixture of brown sand shape is added in the horizontal dough mixer that has turned round, and the Sodium Polyacrylate gel solution slowly added in the concavo-convex excellent mixture of brown sand shape, mix and stir and be the concavo-convex excellent mixture of brown clod shape; 2. the concavo-convex excellent mixture of brown clod shape is added in the dough kneeding machine, be sprayed on the concavo-convex excellent mixture of brown clod shape with methyl-silicone oil, kneading becomes the semi-finished product of brown concavo-convex excellent soft ceramic mud; 3. brown concavo-convex excellent soft ceramic mud semi-finished product are added in the oodle maker and press repeatedly 2~4 times, be pressed into the brown concavo-convex excellent soft ceramic mud of tabular at last, pack and be finished product;
The batching of described brown concavo-convex excellent soft ceramic mud is made up of following component by weight percentage: the concavo-convex excellent mixture 60~85% of brown sand shape, Sodium Polyacrylate gel solution 10~35% and methyl-silicone oil 0.1~5%;
The batching of the concavo-convex excellent mixture of described brown sand shape is made up of following component by weight percentage: the Concave-convex clay rod powder 15~45% after the purification, white bentonite in powder 5~25%, sepiolite powder 5~15%, titanium manganese brown 0.01~5%, organic pigment palm fibre 0.01~5% and distilled water 25~65%;
The production method of the concavo-convex excellent mixture of described brown sand shape is: stir in the Concave-convex clay rod powder after will purifying earlier, white bentonite in powder, sepiolite powder, titanium manganese brown and the organic pigment palm fibre adding mixer, be brown powdery attapulgite mixture after stirring, slowly add in the brown powdery attapulgite mixture with distilled water again and stir, brown powdery attapulgite mixture is carried out moistening, through stirring and moistening be the concavo-convex excellent mixture of brown sand shape afterwards;
The batching of described Sodium Polyacrylate gel solution is made up of following component by weight percentage: Sodium Polyacrylate 0.1~5%, propane diols 0.3~25% and distilled water 70~99.6%;
The compound method of described Sodium Polyacrylate gel solution is: earlier Sodium Polyacrylate is added in the propane diols, when Sodium Polyacrylate in propane diols after the moistening dispersion, the common adding in the distilled water, slowly stir, be dissolved in fully in the distilled water up to Sodium Polyacrylate, form the Sodium Polyacrylate gel solution of thickness;
Concave-convex clay rod after the purification, it is the concavo-convex excellent ore deposit mixture that will contain earth impurity, import in the hydrolytic tank after crushed, soak after 24 hours, dash with high-pressure pump and to turn over, and the sieve of the drum by making with stainless steel steel wire sieve removes the impurity more than 1 millimeter, send in the acclive sedimentation basin, continuation is dashed with high-pressure pump and is turned over, after 12 hours, because the proportion in concavo-convex excellent ore deposit is lighter, its the superiors in whole sediment draws this part concavo-convex excellent ore deposit with slush pump and sends in the flat sedimentation basin, emits unnecessary water after 15 hours, through 2-3 days air dry, take out the Concave-convex clay rod after this part concavo-convex excellent ore deposit is purification.
CN2010102402839A 2010-07-30 2010-07-30 Method for producing brown attapulgite clay Expired - Fee Related CN101973063B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010102402839A CN101973063B (en) 2010-07-30 2010-07-30 Method for producing brown attapulgite clay

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010102402839A CN101973063B (en) 2010-07-30 2010-07-30 Method for producing brown attapulgite clay

Publications (2)

Publication Number Publication Date
CN101973063A CN101973063A (en) 2011-02-16
CN101973063B true CN101973063B (en) 2011-07-20

Family

ID=43572985

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010102402839A Expired - Fee Related CN101973063B (en) 2010-07-30 2010-07-30 Method for producing brown attapulgite clay

Country Status (1)

Country Link
CN (1) CN101973063B (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0368507A2 (en) * 1988-11-09 1990-05-16 Engelhard Corporation Stable color dispersions, their preparation and use in ceramic glazes
CN1552529A (en) * 2003-09-18 2004-12-08 许盛英 Buckled rod wetting benefication process
CN1583865A (en) * 2004-06-12 2005-02-23 姚长领 Method for preparing transparent resin clay

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2529810C (en) * 2002-06-17 2011-04-12 American Clay Enterprises, Llc Clay plaster
JP2009227481A (en) * 2008-03-19 2009-10-08 Ube Ind Ltd Hydraulic composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0368507A2 (en) * 1988-11-09 1990-05-16 Engelhard Corporation Stable color dispersions, their preparation and use in ceramic glazes
CN1552529A (en) * 2003-09-18 2004-12-08 许盛英 Buckled rod wetting benefication process
CN1583865A (en) * 2004-06-12 2005-02-23 姚长领 Method for preparing transparent resin clay

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JP特开2009-227481A 2009.10.08

Also Published As

Publication number Publication date
CN101973063A (en) 2011-02-16

Similar Documents

Publication Publication Date Title
CN101973059B (en) Method for producing white attapulgite soft clay
CN101973730B (en) Method for producing attapulgite soft clay
CN101973732B (en) Method for producing golden attapulgite clay
CN101973063B (en) Method for producing brown attapulgite clay
CN101973729B (en) Method for producing red attapulgite soft clay
CN101973065B (en) Method for producing yellow attapulgite polymer clay mud
CN101973060B (en) Production method of fluorescent colour attapulgite clay
CN101875546B (en) Black attapulgite plasticine and production method thereof
CN101973735B (en) Production method for blue attapulgite soft clay
CN101973062B (en) Production method of black attapulgite polymer clay
CN101973064B (en) Method for producing green attapulgite polymer clay
CN101973733B (en) Production method of purple attapulgite soft ceramic clay
CN101973061B (en) Method for producing soft silvery attapulgite clay
CN101973737B (en) Luminous attapulgite soft ceramic powder
CN101973731B (en) Method for producing luminous attapulgite polymer clay
CN101973734B (en) Production method of orange attapulgite clay
CN101875542B (en) Color attapulgite carved oil sludge and production method thereof
CN101973744B (en) Red attapulgite polymer clay powder
CN101973740B (en) Black attapulgite polymer clay powder
CN101973743B (en) Yellow attapulgite polymer clay powder
CN101973742B (en) Blue attapulgite polymer clay powder
CN101973728B (en) Method for using soft attapulgite ceramic powder
CN101973741B (en) Green attapulgite polymer clay powder
CN101973736B (en) Fluorescent colored attapulgite polymer clay powder
CN101973745B (en) White attapulgite soft ceramic powder

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: JIANGSU BAITENG TECHNOLOGY CO., LTD.

Free format text: FORMER OWNER: XU QINGHUA

Effective date: 20120719

C41 Transfer of patent application or patent right or utility model
COR Change of bibliographic data

Free format text: CORRECT: ADDRESS; FROM: 211700 HUAIAN, JIANGSU PROVINCE TO: 213164 CHANGZHOU, JIANGSU PROVINCE

TR01 Transfer of patent right

Effective date of registration: 20120719

Address after: 213164 building four, block B, building 1, Changzhou science and Education City, Jiangsu

Patentee after: Jiangsu 5ipatent Technology Co.,Ltd.

Address before: 211700 Huaian City, Jiangsu province Xuyi County Xu town of Stonebridge Road No. 40

Patentee before: Xu Qinghua

ASS Succession or assignment of patent right

Owner name: HAIMEN JIANGYONG INVESTMENT AND DEVELOPMENT CO., L

Free format text: FORMER OWNER: JIANGSU BAITENG TECHNOLOGY CO., LTD.

Effective date: 20130917

C41 Transfer of patent application or patent right or utility model
COR Change of bibliographic data

Free format text: CORRECT: ADDRESS; FROM: 213164 CHANGZHOU, JIANGSU PROVINCE TO: 226133 NANTONG, JIANGSU PROVINCE

TR01 Transfer of patent right

Effective date of registration: 20130917

Address after: 226133, No. 118, Renmin East Road, Linjiang Town, Haimen, Jiangsu, Nantong

Patentee after: Haimen Jiang Yong Investment & Development Co., Ltd.

Address before: 213164 building four, block B, building 1, Changzhou science and Education City, Jiangsu

Patentee before: Jiangsu 5ipatent Technology Co.,Ltd.

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20110720

Termination date: 20180730

CF01 Termination of patent right due to non-payment of annual fee