CN101906002B - Pesticide fertilizer and application thereof as well as preparation methods of grain-type pesticide fertilizer and powder-type pesticide fertilizer - Google Patents
Pesticide fertilizer and application thereof as well as preparation methods of grain-type pesticide fertilizer and powder-type pesticide fertilizer Download PDFInfo
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- CN101906002B CN101906002B CN201010239865.5A CN201010239865A CN101906002B CN 101906002 B CN101906002 B CN 101906002B CN 201010239865 A CN201010239865 A CN 201010239865A CN 101906002 B CN101906002 B CN 101906002B
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 167
- 238000002360 preparation method Methods 0.000 title claims abstract description 51
- 239000000575 pesticide Substances 0.000 title abstract description 11
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 claims abstract description 55
- 239000011573 trace mineral Substances 0.000 claims abstract description 42
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 42
- 239000005875 Acetamiprid Substances 0.000 claims abstract description 41
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 claims abstract description 39
- 241000244206 Nematoda Species 0.000 claims abstract description 28
- 239000003814 drug Substances 0.000 claims description 161
- 239000000203 mixture Substances 0.000 claims description 60
- 238000009472 formulation Methods 0.000 claims description 57
- 239000002245 particle Substances 0.000 claims description 47
- 239000002904 solvent Substances 0.000 claims description 36
- NWWZPOKUUAIXIW-DHZHZOJOSA-N (E)-thiamethoxam Chemical compound [O-][N+](=O)/N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-DHZHZOJOSA-N 0.000 claims description 35
- 239000013543 active substance Substances 0.000 claims description 31
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 30
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 26
- 239000012452 mother liquor Substances 0.000 claims description 26
- 239000002594 sorbent Substances 0.000 claims description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 23
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 18
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 18
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 16
- -1 phosphoric Substances 0.000 claims description 16
- 239000004323 potassium nitrate Substances 0.000 claims description 15
- 235000010333 potassium nitrate Nutrition 0.000 claims description 15
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 14
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 14
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 14
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 14
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 13
- 239000011591 potassium Substances 0.000 claims description 13
- 229910052700 potassium Inorganic materials 0.000 claims description 13
- 239000006229 carbon black Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 229910019142 PO4 Inorganic materials 0.000 claims description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 10
- 239000010452 phosphate Substances 0.000 claims description 10
- 239000005995 Aluminium silicate Substances 0.000 claims description 9
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 9
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 9
- DHHVKJOKPFJOJF-UHFFFAOYSA-N [Mn].[Na].[Na] Chemical compound [Mn].[Na].[Na] DHHVKJOKPFJOJF-UHFFFAOYSA-N 0.000 claims description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims description 9
- 235000019270 ammonium chloride Nutrition 0.000 claims description 9
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 9
- 239000004327 boric acid Substances 0.000 claims description 9
- 235000010338 boric acid Nutrition 0.000 claims description 9
- 239000004202 carbamide Substances 0.000 claims description 9
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 9
- 229910000396 dipotassium phosphate Inorganic materials 0.000 claims description 9
- 235000019797 dipotassium phosphate Nutrition 0.000 claims description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 9
- 239000001508 potassium citrate Substances 0.000 claims description 9
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 9
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 9
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 9
- 235000011151 potassium sulphates Nutrition 0.000 claims description 9
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 9
- 235000015870 tripotassium citrate Nutrition 0.000 claims description 9
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 238000005469 granulation Methods 0.000 claims description 7
- 230000003179 granulation Effects 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 238000004090 dissolution Methods 0.000 claims description 6
- 239000000618 nitrogen fertilizer Substances 0.000 claims description 6
- 239000002686 phosphate fertilizer Substances 0.000 claims description 6
- 229940072033 potash Drugs 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- 235000015320 potassium carbonate Nutrition 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- KSHPUQQHKKJVIO-UHFFFAOYSA-N [Na].[Zn] Chemical compound [Na].[Zn] KSHPUQQHKKJVIO-UHFFFAOYSA-N 0.000 claims description 4
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- ATSGLBOJGVTHHC-UHFFFAOYSA-N bis(ethane-1,2-diamine)copper(2+) Chemical compound [Cu+2].NCCN.NCCN ATSGLBOJGVTHHC-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 2
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 claims description 2
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 2
- 239000011790 ferrous sulphate Substances 0.000 claims description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 2
- 235000019357 lignosulphonate Nutrition 0.000 claims description 2
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- NEUOBESLMIKJSB-UHFFFAOYSA-J tetrasodium;tetraacetate Chemical compound [Na+].[Na+].[Na+].[Na+].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O NEUOBESLMIKJSB-UHFFFAOYSA-J 0.000 claims description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 2
- 229960001763 zinc sulfate Drugs 0.000 claims description 2
- 239000005906 Imidacloprid Substances 0.000 abstract description 13
- 229940056881 imidacloprid Drugs 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 9
- 241000607479 Yersinia pestis Species 0.000 abstract description 6
- 230000002265 prevention Effects 0.000 abstract description 5
- 230000008569 process Effects 0.000 abstract description 4
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 abstract 3
- 239000005660 Abamectin Substances 0.000 abstract 3
- 239000005941 Thiamethoxam Substances 0.000 abstract 3
- 229950008167 abamectin Drugs 0.000 abstract 3
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 abstract 3
- 230000000361 pesticidal effect Effects 0.000 abstract 2
- 239000002689 soil Substances 0.000 abstract 2
- 238000013329 compounding Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 229960001484 edetic acid Drugs 0.000 description 11
- 239000003153 chemical reaction reagent Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 230000000857 drug effect Effects 0.000 description 10
- 239000000843 powder Substances 0.000 description 9
- NVTRPRFAWJGJAJ-UHFFFAOYSA-L EDTA monocalcium salt Chemical compound [Ca+2].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O NVTRPRFAWJGJAJ-UHFFFAOYSA-L 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 8
- 238000001035 drying Methods 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 240000008042 Zea mays Species 0.000 description 5
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 5
- 235000005822 corn Nutrition 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 241000238631 Hexapoda Species 0.000 description 3
- 241000243785 Meloidogyne javanica Species 0.000 description 3
- 206010062701 Nematodiasis Diseases 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 241001136249 Agriotes lineatus Species 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 241000243771 Bursaphelenchus xylophilus Species 0.000 description 1
- 241001481710 Cerambycidae Species 0.000 description 1
- 241000254171 Curculionidae Species 0.000 description 1
- 241000289763 Dasygaster padockina Species 0.000 description 1
- 241000399949 Ditylenchus dipsaci Species 0.000 description 1
- 241000482313 Globodera ellingtonae Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000241125 Gryllotalpa gryllotalpa Species 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 241000238814 Orthoptera Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 239000011363 dried mixture Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003971 tillage Methods 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- NBIIXXVUZAFLBC-HOSYLAQJSA-K trioxido(oxo)-$l^{5}-phosphane Chemical compound [O-][32P]([O-])([O-])=O NBIIXXVUZAFLBC-HOSYLAQJSA-K 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Abstract
The invention provides a pesticide fertilizer and application thereof. The pesticide fertilizer is prepared from the following components in percentage by weight: 0.1-1 percent of abamectin, 1-10 percent of imidacloprid and/or acetamiprid and/or thiamethoxam, 15-40 percent of great amount of element fertilizer, 1-5 percent of trace element fertilizer and 44-72.4 percent of carrier. By compounding the abamectin, the imidacloprid and/or the acetamiprid and/or the thiamethoxam, a great amount of element fertilizer and the trace element fertilizer, the pesticide fertilizer effectively improves the pesticide effects of the abamectin, the imidacloprid and/or the acetamiprid and/or the thiamethoxam on nematodes and soil pests and takes the effect of promoting the growth of crops. Because of the excellent performance and the pesticide effects, the pesticide fertilizer can be applied to the prevention of the nematodes and the soil pests. The invention also provides preparation methods of a grain-type pesticide fertilizer and a powder-type pesticide fertilizer, which have simple process and easily controlled conditions and are suitable for industrial production.
Description
Technical field
The invention belongs to pesticide preparation field, relate in particular to the fertile preparation method of a kind of medicine fertilizer and application thereof, particle formulation medicine fertilizer and powder-type medicine.
Background technology
Plant nematode in the world many countries and regions occurs and causes harm, and kind is varied.In the world, the generation of plant nematode with harm along with the development of agroforestry and the variation of tillage and cultivation system day by day serious.According to estimates, it is 12.3% that plant nematode is caused the year rate of loss of world staple crops, surpasses 1,000 hundred million dollars, and actual loss is considerably beyond estimation.At present the harmful nematode of plant is approximately had to kind more than 3000, in China, mainly contain root knot nematode, Cyst nematode, pine wood nematode, sweet potato stem nematode etc.After nematodiasiss occurs, the general underproduction 10% left and right, serious in more than 75%, even total crop failure.
In recent years, vegetable destructive soil-inhabiting insects harm is on the rise, and is difficult to control, to vegetable grower, brings larger financial loss.Subterranean pest-insect kind is a lot, mainly comprises that cutworm, grub, mole cricket, wireworm, root maggot, root aphid, root weevil, root are chrysomelid, root longicorn, cricket etc.Its host types is complicated, how at spring and autumn, to cause harm, and the seed of the crop of mainly causing harm, underground part and subaerial rhizome portion.Often cause and hinder root, dead seedling, so that the disconnected ridge that is short of seedling.Most subterranean pest-insects have more stable ecotope, a little less than life cycle long, transport property, also have with ground temperature and change vertical movable feature, in spring, two seasons of autumn, form hazard boom.
At present the medicament kind of control nematode and subterranean pest-insect is more, but general problem is that the problems such as a large amount of chemical pesticides makes environment and the interior toxic substance of plant materials is residual are particularly outstanding.Therefore, develop the more efficient subterranean pest-insect of more environmental protection and control of nematode medicament and become the task of top priority.
Summary of the invention
In view of this, the invention provides and a kind ofly can effectively promote at least one in Provado, acetamiprid, Diacloden, Avrmectin, to nematode or/and the drug effect of subterranean pest-insect, and it is fertile that crop is played to the medicine of accretion.
The present invention also provides above-mentioned medicine fertilizer preventing and treating subterranean pest-insect or/and the application in nematode.
The technical solution adopted in the present invention is:
A kind of medicine is fertile, the component that comprises following weight percentage:
Avrmectin 0.1%～1%
In Provado, acetamiprid, Diacloden at least one 1%～10%
Macroelement fertilizer 15%～40%
Trace element fertilizer 1%～5%
Carrier 44%～72.4%.
And the fertile preparation method of a kind of particle formulation medicine, comprises the steps:
By fertile each component concentration of particle formulation medicine, take at least one in Provado, acetamiprid, Diacloden, Avrmectin, macroelement fertilizer, trace element fertilizer, solvent, tensio-active agent, sorbent material and carrier, wherein, by gross weight 100%, in Provado, acetamiprid, Diacloden at least one 1%～10%, Avrmectin 0.1%～1%, macroelement fertilizer 15%～40%, trace element fertilizer 1%～5%, solvent 5%～15%, tensio-active agent 5%～10%, sorbent material 0.5%～2%, carrier 44%～72.4%;
By in Provado, acetamiprid, Diacloden at least one, solvent, Avrmectin, tensio-active agent mixed dissolution, be mixed with mother liquor;
By the mother liquor of above-mentioned preparation mix with macroelement fertilizer, trace element fertilizer, sorbent material, carrier, granulation, obtain described particle formulation medicine fertile.
And the fertile preparation method of a kind of powder-type medicine, comprises the steps:
By fertile each component concentration of powder-type medicine, take at least one in Provado, acetamiprid, Diacloden, Avrmectin, macroelement fertilizer, trace element fertilizer, solvent, tensio-active agent and sorbent material, wherein, by gross weight 100%, in Provado, acetamiprid, Diacloden at least one 1%～10%, Avrmectin 0.1%～1%, macroelement fertilizer 15%～40%, trace element fertilizer 1%～5%, solvent 5%～15%, tensio-active agent 5%～10%, sorbent material 0.5%～2%, carrier 44%～72.4%;
By in Provado, acetamiprid, Diacloden at least one, solvent, Avrmectin, tensio-active agent mixed dissolution, be mixed with mother liquor;
Dry after the mother liquor of above-mentioned preparation is mixed with macroelement fertilizer, trace element fertilizer, sorbent material, carrier, pulverizing, obtain described powder-type medicine fertile.
And above-mentioned medicine fertilizer is being prevented and treated subterranean pest-insect or/and the application in nematode.
Medicine fertilizer of the present invention by Provado, acetamiprid, Diacloden at least one, Avrmectin and macroelement fertilizer and trace element fertilizer composite, effectively promoted Avrmectin, Provado and/or acetamiprid and/or the drug effect of Diacloden to nematode and subterranean pest-insect, and crop has been played to the medicine fertilizer of accretion.Because medicine fertilizer, particle formulation medicine fertilizer and powder-type medicine fertilizer have aforementioned premium properties and drug effect, make medicine fertilizer, particle formulation medicine fertilizer or powder-type medicine fertilizer preventing and treating subterranean pest-insect or/and apply in nematode.Preparation technology fertile and powder-type medicine fertilizer is simple for particle formulation medicine, and condition is easily controlled, and is suitable for suitability for industrialized production.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
A kind of medicine that the present embodiment provides is fertile, the component that comprises following weight percentage:
Avrmectin 0.1%～1%
In Provado, acetamiprid, Diacloden at least one 1%～20%
Macroelement fertilizer 15%～40%
Trace element fertilizer 1%～5%
Carrier 44%～72.4%.
Further, above-mentioned Avrmectin weight percentage in described medicine fertilizer is preferably 0.5%; In Provado, acetamiprid, Diacloden, at least one weight percentage in described medicine fertilizer is preferably 5%.At least one component preferred content in this Avrmectin and Provado, acetamiprid, Diacloden, can make the drug effect of this medicine fertilizer reach optimum level.
Further, above-mentioned macroelement fertilizer is preferably at least one in nitrogenous fertilizer, phosphate fertilizer or potash fertilizer, and at least one element in the nitrogen element in described nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, phosphoric, potassium element preferably accounts for 5%～20% of the fertile gross weight of described medicine; Trace element in described trace element fertilizer is preferably at least one in copper, iron, manganese, zinc, molybdenum, boron, and this trace element preferably accounts for 0.5%～2% of the fertile gross weight of described medicine; Described carrier is preferably at least one in kaolin, diatomite, nakrite, or at least one in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, potassium sulfate, saltpetre or Tripotassium Citrate.The existence of this macroelement fertilizer and trace element fertilizer component, in Provado, acetamiprid, Diacloden at least one, Avrmectin component is combined, when improving Avrmectin, Provado and/or acetamiprid and/or Diacloden component drug effect, for farm crop provide nutrient support.
Further, above-mentioned macroelement fertilizer is preferably at least one in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, potassium sulfate, saltpetre or Tripotassium Citrate; Described trace element fertilizer is preferably at least one in Sodium orthomolybdate, four water ammonium molybdates, zinc sulfate, manganous sulfate, copper sulfate, ferrous sulfate, boric acid, four water eight Sodium Tetraboratees, ethylenediamine tetraacetic acid (EDTA) zinc sodium, calcium disodium edathamil, ethylenediamine tetraacetic acid (EDTA) manganese disodium or cupric ethylene diamine tetraacetate sodium.
Further, above-mentioned medicine fertilizer preferably includes particle formulation medicine fertilizer and powder-type medicine fertilizer.
When above-mentioned medicine fertilizer is particle formulation medicine fertilizer, in described particle formulation medicine fertilizer, macroelement fertilizer preferably accounts for 15%～40% of the fertile gross weight of described medicine, and described particle formulation medicine fertilizer also can comprise the preferred ingredient of following weight percent:
Solvent 5%～15%
Tensio-active agent 5%～10%
Sorbent material 0.5%～2%
Wherein, described carrier is at least one in kaolin, diatomite, nakrite.
Therefore,, when above-mentioned medicine fertilizer is particle formulation medicine fertilizer, the recipe ingredient of the fertile weight percent of this particle formulation medicine can be expressed as follows:
Avrmectin 0.1%～1%
In Provado, acetamiprid, Diacloden at least one 1%～10%
Macroelement fertilizer 15%～40%
Trace element fertilizer 1%～5%
Solvent 5%～15%
Tensio-active agent 5%～10%
Sorbent material 0.5%～2%
Carrier 44%～72.4%,
Wherein, described carrier is at least one in kaolin, diatomite, nakrite.
The fertile Preparation Method of above-mentioned particle formulation medicine, preferably includes following steps:
S11. by fertile each component concentration of described particle formulation medicine, take at least one in Provado, acetamiprid, Diacloden, Avrmectin, macroelement fertilizer, trace element fertilizer, solvent, tensio-active agent, sorbent material and filler;
S12. by Provado, acetamiprid, Diacloden at least one, solvent, Avrmectin, tensio-active agent mixed dissolution, be mixed with mother liquor;
S13. the mother liquor of above-mentioned preparation mixed with macroelement fertilizer, trace element fertilizer, sorbent material, filler, then carry out granulation, obtain described particle formulation medicine fertile.
In the fertile preparation method's of above-mentioned particle formulation medicine S11 step, described carrier is preferably at least one in kaolin, diatomite, nakrite, because kaolin, diatomite, nakrite is insoluble or be slightly soluble in water, usings them as carrier, can conveniently prepare particle formulation fertilizer.
In the fertile preparation method's of above-mentioned particle formulation medicine S12 step, each component is mixed preferably employing agitating procedure, and each component is mixed.
In the fertile preparation method's of above-mentioned particle formulation medicine S13 step, each component is mixed preferably employing agitating procedure, and each component is mixed.Prilling process can adopt the conventional prilling process of the art, is preferably a kind of in extruder grain, mist projection granulating, rotation granulation, fluidized bed prilling.
When above-mentioned medicine fertilizer is powder-type medicine fertilizer, described powder-type medicine fertilizer also can comprise the preferred ingredient of following weight percent:
Solvent 5%～15%
Tensio-active agent 5%～10%
Sorbent material 0.5%～2%.
Wherein, described carrier is at least one in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, potassium sulfate, saltpetre or Tripotassium Citrate.
Therefore,, when above-mentioned medicine fertilizer is powder-type medicine fertilizer, the recipe ingredient of the fertile weight percent of this powder-type medicine can be expressed as follows:
Avrmectin 0.1%～1%
In Provado, acetamiprid, Diacloden at least one 1%～10%
Macroelement fertilizer 15%～40%
Trace element fertilizer 1%～5%
Solvent 5%～15%
Tensio-active agent 5%～10%
Sorbent material 0.5%～2%
Carrier 44%～72.4%,
Wherein, described carrier is at least one in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, potassium sulfate, saltpetre or Tripotassium Citrate.
The fertile Preparation Method of above-mentioned powder-type medicine, preferably includes following steps:
S21. by fertile each component concentration of powder-type medicine, take at least one in Provado, acetamiprid, Diacloden, Avrmectin, macroelement fertilizer, trace element fertilizer, solvent, tensio-active agent, sorbent material and carrier;
S22. by Provado, acetamiprid, Diacloden at least one, solvent, Avrmectin, tensio-active agent mixed dissolution, be mixed with mother liquor;
S23. dry after the mother liquor of above-mentioned preparation being mixed with macroelement fertilizer, trace element fertilizer, sorbent material and carrier, pulverizing, obtain described powder-type medicine fertile.
In the fertile preparation method's of above-mentioned particle formulation medicine S11 step, described carrier is preferably at least one in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, potassium sulfate, saltpetre or Tripotassium Citrate, because ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, potassium sulfate, saltpetre or Tripotassium Citrate solvability are good, using them as carrier, can conveniently prepare powder-type fertilizer.
In the fertile preparation method's of above-mentioned powder-type medicine S22 step, each component is mixed preferably employing agitating procedure, and each component is mixed.
In the fertile preparation method's of above-mentioned powder-type medicine S23 step, each component is mixed preferably employing agitating procedure, and each component is mixed; Drying process can adopt pulvis or the conventional type of heating of particle formulation agricultural chemicals, as Exposure to Sunlight, dry, the mode such as oven for drying, dry temperature is not preferably destroyed composition in powder-type medicine fertilizer and is as the criterion; Disintegrating process is that dried mixture is pulverized, and by the art common method, pulverizes.
Because the material of the carrier of above-mentioned powder-type medicine fertilizer is the macroelement class fertilizer of solubility, therefore, the fertile solubility property of this powder-type medicine is good.
Further, in above-mentioned particle formulation medicine fertilizer and powder-type medicine fertilizer and preparation method thereof, solvent is preferably one or more in 200# solvent oil, N-Methyl pyrrolidone, isopropylcarbinol, methyl phenyl ketone, this solvent must exist, and makes related component in particle formulation medicament fertilizer formulation fully dissolve and each component is fully disperseed; Described tensio-active agent is preferably one or more in JFC, 603# tensio-active agent, 600# tensio-active agent, alkylphenol polyoxyethylene or its phosphoric acid ester, fatty alcohol-polyoxyethylene ether, sulfonated lignin, naphthalenesulfonate formaldehyde condensation compound, wherein, all commercially available acquisitions of JFC, 603# tensio-active agent, 600# tensio-active agent; Described sorbent material preferably but be not limited only to white carbon black.The interpolation of this tensio-active agent and sorbent material, effectively improved dispersiveness and the homogeneity of fertile and fertile each component of powder-type medicine of particle formulation medicine, effectively improved the stability of the fertile and powder-type medicine fertilizer drug effect of particle formulation medicine.
Known from the above mentioned, preparation technology fertile and powder-type medicine fertilizer is simple for particle formulation medicine, and condition is easily controlled, and is suitable for suitability for industrialized production.
Medicine fertilizer described in the present embodiment by Provado, acetamiprid, Diacloden at least one, Avrmectin and macroelement fertilizer and trace element fertilizer composite, effectively promoted Avrmectin, Provado and/or acetamiprid and/or the drug effect of Diacloden to nematode and subterranean pest-insect, and crop has been played to the medicine fertilizer of accretion.
Because medicine fertilizer, particle formulation medicine fertilizer and powder-type medicine fertilizer have aforementioned premium properties and drug effect, make medicine fertilizer, particle formulation medicine fertilizer or powder-type medicine fertilizer preventing and treating subterranean pest-insect or/and apply in nematode.Medicine fertilizer in use, is preferably executed with seed dressing, spraying, seed manure, punching or is drenched and the mode such as execute for the control of nematode and subterranean pest-insect on corn, wheat, soybean, peanut and vegetables.
By a plurality of embodiment, illustrate below that the present embodiment medicine is fertile different to be formed and preparation method thereof, with and the aspect such as performance.
Embodiment 1
The preparation of 10.1% A Wei acetamiprid particle formulation medicine fertilizer, its formula is as follows:
Avrmectin 0.1%
Acetamiprid 10%
N-Methyl pyrrolidone 10%
Fatty alcohol-polyoxyethylene ether 7%
Ammonium sulfate 15%
Potassium primary phosphate 32%
Four water eight Sodium Tetraboratees 3%
Ethylenediamine tetraacetic acid (EDTA) zinc sodium 2%
Four water ammonium molybdates 1%
White carbon black 1.5%
Kaolin surplus
Its preparation method is: first with solvent N-Methyl pyrrolidone, the former medicine of Avrmectin, the former medicine of acetamiprid and tensio-active agent fatty alcohol-polyoxyethylene ether dissolved and make mother liquor, obtained mother liquor and ammonium sulfate, potassium primary phosphate, four water eight Sodium Tetraboratees, ethylenediamine tetraacetic acid (EDTA) zinc sodium, four water ammonium molybdates, white carbon black, kaolin being carried out to granulation in fluidized bed prilling mode and obtain for preventing and treating the particle formulation medicine containing 10.1% A Wei acetamiprid of subterranean pest-insect and nematode fertile.
Embodiment 2
The preparation of 3% A Wei Diacloden particle formulation medicine fertilizer, its formula is as follows:
Avrmectin 1%
Diacloden 2%
N-Methyl pyrrolidone 8%
Alkylphenol polyoxyethylene 6%
Primary ammonium phosphate 35%
Saltpetre 15%
Boric acid 5%
Ethylenediamine tetraacetic acid (EDTA) manganese disodium 3%
Sodium orthomolybdate 1%
Calcium disodium edathamil 5%
White carbon black 1.5%
Diatomite surplus
Its preparation method is: first with solvent N-Methyl pyrrolidone, the former medicine of Avrmectin, the former medicine of Diacloden and tensio-active agent alkylphenol polyoxyethylene dissolved and make mother liquor, obtained mother liquor and primary ammonium phosphate, saltpetre, boric acid, ethylenediamine tetraacetic acid (EDTA) manganese disodium, Sodium orthomolybdate, calcium disodium edathamil, white carbon black, diatomite being carried out to granulation in fluidized bed prilling mode and obtain for preventing and treating the particle formulation medicine containing 3% A Wei Diacloden of subterranean pest-insect and nematode fertile.
Embodiment 3
The preparation of 5.5% A Wei imidacloprid soluble powder formulation medicine fertilizer, its formula is as follows:
Avrmectin 0.5%
Provado 5%
N-Methyl pyrrolidone 10%
Alkylphenol polyoxyethylene 6%
Primary ammonium phosphate 35%
Saltpetre 15%
Boric acid 2%
Ethylenediamine tetraacetic acid (EDTA) manganese disodium 2%
Sodium orthomolybdate 1%
Calcium disodium edathamil 5%
White carbon black 1%
Ammonium sulfate surplus
Its preparation method is: first with solvent N-Methyl pyrrolidone, the former medicine of Avrmectin, the former medicine of Provado and surface-active agent alkylphenol polyoxyethylene dissolved and make mother liquor, obtained mother liquor and macroelement fertilizer, trace element fertilizer, carrier are carried out to combination drying and pulverize obtaining for preventing and treating the fertilizer of the soluble powder formulation medicine containing 5.5% A Wei Provado of subterranean pest-insect and nematode.
Embodiment 4
The preparation of 5.5% A Wei Provado particle formulation medicine fertilizer, its formula is as follows:
Avrmectin 0.5%
Provado 5%
N-Methyl pyrrolidone 10%
Alkylphenol polyoxyethylene 6%
Primary ammonium phosphate 35%
Saltpetre 15%
Boric acid 2%
Ethylenediamine tetraacetic acid (EDTA) manganese disodium 2%
Sodium orthomolybdate 1%
Calcium disodium edathamil 5%
White carbon black 1%
Diatomite surplus
Its preparation method is: first with solvent N-Methyl pyrrolidone, the former medicine of Avrmectin, the former medicine of Provado and surface-active agent alkylphenol polyoxyethylene dissolved and make mother liquor, obtained mother liquor and macroelement fertilizer, trace element fertilizer, white carbon black, diatomite being carried out to granulation in fluidized bed prilling mode and obtain for preventing and treating the fertile containing 5.5% A Wei Provado particle formulation medicine of subterranean pest-insect and nematode.
Embodiment 5
The preparation of 8.1% A Wei imidacloprid soluble powder formulation medicine fertilizer, its formula is as follows:
Avrmectin 0.1%
Provado 8%
N-Methyl pyrrolidone 10%
Alkylphenol polyoxyethylene 7%
Primary ammonium phosphate 15%
Saltpetre 35%
Boric acid 8%
Ethylenediamine tetraacetic acid (EDTA) manganese disodium 3%
Sodium orthomolybdate 1%
Calcium disodium edathamil 2%
White carbon black 1%
Ammonium sulfate surplus
Its preparation method is: first with solvent N-Methyl pyrrolidone, the former medicine of Avrmectin, the former medicine of Provado and surface-active agent alkylphenol polyoxyethylene dissolved and make mother liquor, obtained mother liquor and macroelement fertilizer, trace element fertilizer, carrier are carried out to combination drying and pulverize obtaining for preventing and treating the fertilizer of the soluble powder formulation medicine containing 8.1% A Wei Provado of subterranean pest-insect and nematode.
Embodiment 6
The preparation of 8% A Wei Provado-acetamiprid medicine fertilizer, its formula is as follows:
Avrmectin 1%
Provado 0.3%
Acetamiprid 0.7%
Primary ammonium phosphate 15%
Saltpetre 15%
Boric acid 8%
Ethylenediamine tetraacetic acid (EDTA) manganese disodium 3%
Sodium orthomolybdate 1%
Calcium disodium edathamil 2%
White carbon black 1%
Nakrite surplus
Its preparation method is: by formula, first with the solvent N-Methyl pyrrolidone that accounts for the fertile gross weight 15% of medicine, the former medicine of Avrmectin, the former medicine of Provado and the surface-active agent alkylphenol polyoxyethylene that accounts for the fertile gross weight 5% of medicine dissolved and make mother liquor, obtained mother liquor and macroelement fertilizer, trace element fertilizer, carrier being carried out to combination drying and pulverize obtaining containing A Wei Provado-acetamiprid medicine fertilizer of 8% for preventing and treating subterranean pest-insect and nematode.
Embodiment 7
The preparation of 10.1% A Wei Provado-acetamiprid-Diacloden medicine fertilizer, its formula is as follows:
Avrmectin 0.1%
Provado 8%
Acetamiprid 1%
Diacloden 1%
Primary ammonium phosphate 15%
Boric acid 10%
Ethylenediamine tetraacetic acid (EDTA) manganese disodium 3%
Sodium orthomolybdate 1%
Calcium disodium edathamil 2%
White carbon black 1%
Ammonium sulfate surplus
Its preparation method is: by formula, first with the solvent N-Methyl pyrrolidone that accounts for the fertile gross weight 5% of medicine, the former medicine of Avrmectin, the former medicine of Provado and the surface-active agent alkylphenol polyoxyethylene that accounts for the fertile gross weight 10% of medicine dissolved and make mother liquor, obtained mother liquor and macroelement fertilizer, trace element fertilizer, carrier being carried out to combination drying and pulverize obtaining for preventing and treating subterranean pest-insect and nematode containing A Wei Provado-acetamiprid-Diacloden medicine fertilizer medicine fertilizer of 10.1%.
Drug effect comparative example 1
The soluble powder formulation medicine containing 5.5% A Wei Provado of embodiment 3 preparation fertile with common 5.5% A Wei imidacloprid emulsion to root knot nematode, controlling underground pest effect and to the comparison of crop yield effect:
1) reagent agent:
A. the soluble powder formulation medicine containing 5.5% A Wei Provado of embodiment 3 preparations is fertile;
B. common 5.5% A Wei imidacloprid emulsion, by gross weight 100%, its component is: Avrmectin 0.5%, Provado 5%, N-Methyl pyrrolidone 10%, alkylphenol polyoxyethylene 15%, surplus are water.
2) test method:
By the soluble powder formulation medicine containing 5.5% A Wei Provado of embodiment 3 preparation fertile (reagent agent A) with common 5.5% A Wei imidacloprid emulsion (reagent agent B) to there being the test of obvious nematodiasiss and subterranean pest-insect insect pest to prevent and treat with corn field, prevention effect is as following table 1:
The comparative efficacy test of table 1 reagent agent A and reagent agent B
According to experimental result, the soluble powder formulation medicine fertilizer containing 5.5% A Wei Provado with embodiment 3 preparations is better than 5.5% traditional A Wei imidacloprid emulsion on to the prevention effect of corn nematode and subterranean pest-insect, and the soluble powder formulation medicine fertilizer containing 5.5% A Wei Provado of embodiment 3 preparations simultaneously can make crop yield more than 30%.
Drug effect comparative example 2
The particle formulation medicine containing 5.5% A Wei Provado of embodiment 4 preparation fertile with common 5.5% A Wei imidacloprid emulsion to root knot nematode, controlling underground pest effect and to the comparison of crop yield effect:
1) reagent agent:
A. the particle formulation medicine containing 5.5% A Wei Provado of embodiment 4 preparations is fertile;
B. common 5.5% A Wei imidacloprid emulsion, by gross weight 100%, its component is: Avrmectin 0.5%, Provado 5%, N-Methyl pyrrolidone 10%, alkylphenol polyoxyethylene 15%, surplus are water.
2) test method:
By the particle formulation medicine containing 5.5% A Wei Provado of embodiment 4 preparation fertile (reagent agent A) with common 5.5% A Wei imidacloprid emulsion (reagent agent B) to there being the test of obvious nematodiasiss and subterranean pest-insect insect pest to prevent and treat with corn field, prevention effect is as following table 2:
The comparative efficacy test of table 2 reagent agent A and reagent agent B
According to experimental result, the particle formulation medicine fertilizer containing 5.5% A Wei Provado with embodiment 4 preparations is better than 5.5% traditional A Wei imidacloprid emulsion on to the prevention effect of corn nematode and subterranean pest-insect, and the particle formulation medicine fertilizer containing 5.5% A Wei Provado of embodiment 4 preparations simultaneously can make crop yield more than 30%.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any modifications of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.
Claims (11)
1. a medicine fertilizer, described medicine fertilizer is used for preventing and treating nematode and subterranean pest-insect, the component that it comprises following weight percentage:
Described macroelement fertilizer is at least one in nitrogenous fertilizer, phosphate fertilizer or potash fertilizer;
Trace element in described trace element fertilizer is at least one in copper, iron, manganese, zinc, molybdenum, boron;
Described solvent is one or more in 200# solvent oil, N-Methyl pyrrolidone, isopropylcarbinol, methyl phenyl ketone;
When described medicine fertilizer is particle formulation medicine fertilizer, described carrier is at least one in kaolin, diatomite, nakrite; Or when described medicine fertilizer is powder-type medicine fertilizer, described carrier is at least one in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, potassium sulfate, saltpetre or Tripotassium Citrate.
2. medicine according to claim 1 is fertile, it is characterized in that: described Avrmectin weight percentage in described medicine fertilizer is 0.5%.
3. medicine according to claim 1 is fertile, it is characterized in that: in described Provado, acetamiprid, Diacloden, at least one weight percentage in described medicine fertilizer is 5%.
4. medicine according to claim 1 is fertile, it is characterized in that: at least one element in the nitrogen element in described nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, phosphoric, potassium element accounts for 5%～20% of the fertile gross weight of described medicine:
Described trace element accounts for 0.5%～2% of the fertile gross weight of described medicine.
5. fertile according to the medicine described in claim 1 or 4, it is characterized in that: described macroelement fertilizer is at least one in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, potassium sulfate, saltpetre or Tripotassium Citrate;
Described trace element fertilizer is at least one in Sodium orthomolybdate, four water ammonium molybdates, zinc sulfate, manganous sulfate, copper sulfate, ferrous sulfate, boric acid, four water eight Sodium Tetraboratees, ethylenediamine tetraacetic acid (EDTA) zinc sodium, ethylenediamine tetraacetic acid (EDTA) manganese disodium or cupric ethylene diamine tetraacetate sodium.
6. medicine according to claim 1 is fertile, it is characterized in that: described medicine fertilizer is that particle formulation medicine fertilizer or powder-type medicine are fertile..
7. medicine according to claim 6 is fertile, it is characterized in that: described medicine is fertile in particle formulation medicine is fertile,
Described carrier is at least one in kaolin, diatomite, nakrite.
8. medicine according to claim 6 is fertile, it is characterized in that: described medicine is fertile in powder-type medicine is fertile, described in
Sorbent material 1%～2%;
Described carrier is at least one in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, potassium sulfate, saltpetre or Tripotassium Citrate.
9. fertile according to the medicine described in claim 7 or 8, it is characterized in that: described tensio-active agent is one or more in JFC, 603# tensio-active agent, 600# tensio-active agent, alkylphenol polyoxyethylene or its phosphoric acid ester, fatty alcohol-polyoxyethylene ether, sulfonated lignin, naphthalenesulfonate formaldehyde condensation compound;
Described sorbent material is white carbon black.
10. the fertile preparation method of particle formulation medicine, described medicine fertilizer is used for preventing and treating nematode and subterranean pest-insect, comprises the steps:
By fertile each component concentration of particle formulation medicine, take at least one in Provado, acetamiprid, Diacloden, Avrmectin, macroelement fertilizer, trace element fertilizer, solvent, tensio-active agent, sorbent material and carrier, wherein, by gross weight 100%, in Provado, acetamiprid, Diacloden at least one 1%～10%, Avrmectin 0.1%～1%, macroelement fertilizer 15%～40%, trace element fertilizer 1%～5%, solvent 5%～15%, tensio-active agent 5%～10%, sorbent material 0.5%～2%, carrier 44%～72.4%;
By in Provado, acetamiprid, Diacloden at least one, solvent, Avrmectin, tensio-active agent mixed dissolution, be mixed with mother liquor;
By the mother liquor of above-mentioned preparation mix with macroelement fertilizer, trace element fertilizer, sorbent material, carrier, granulation, obtain described particle formulation medicine fertile;
Wherein, described macroelement fertilizer is at least one in nitrogenous fertilizer, phosphate fertilizer or potash fertilizer;
Trace element in described trace element fertilizer is at least one in copper, iron, manganese, zinc, molybdenum, boron;
Described solvent is one or more in 200# solvent oil, N-Methyl pyrrolidone, isopropylcarbinol, methyl phenyl ketone.
11. 1 kinds of fertile preparation methods of powder-type medicine, described medicine fertilizer is used for preventing and treating nematode and subterranean pest-insect, comprises the steps:
By fertile each component concentration of powder-type medicine, take at least one in Provado, acetamiprid, Diacloden, Avrmectin, macroelement fertilizer, trace element fertilizer, solvent, tensio-active agent and sorbent material, wherein, by gross weight 100%, in Provado, acetamiprid, Diacloden at least one 1%～10%, Avrmectin 0.1%～1%, macroelement fertilizer 15%～40%, trace element fertilizer 1%～5%, solvent 5%～15%, tensio-active agent 5%～10%, sorbent material 0.5%～2%, carrier 44%～72.4%:
By in Provado, acetamiprid, Diacloden at least one, solvent, Avrmectin, tensio-active agent mixed dissolution, be mixed with mother liquor;
Dry after the mother liquor of above-mentioned preparation is mixed with macroelement fertilizer, trace element fertilizer, sorbent material, carrier, pulverizing, obtain described powder-type medicine fertile;
Wherein, described macroelement fertilizer is at least one in nitrogenous fertilizer, phosphate fertilizer or potash fertilizer;
Trace element in described trace element fertilizer is at least one in copper, iron, manganese, zinc, molybdenum, boron;
Described solvent is one or more in 200# solvent oil, N-Methyl pyrrolidone, isopropylcarbinol, methyl phenyl ketone.
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Effective date of registration: 20160829 Address after: 518102 Xixiang Reservoir Road, Shenzhen, Guangdong, No. 113, No. Patentee after: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. Patentee after: Shenzhen elephant industry Ltd. Address before: 518102 Xixiang Reservoir Road, Shenzhen, Guangdong, No. 113, No. Patentee before: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. |
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Address after: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee after: Shenzhen Novozon Crop Science Co.,Ltd. Country or region after: China Patentee after: Shenzhen elephant industry Ltd. Address before: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee before: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. Country or region before: China Patentee before: Shenzhen elephant industry Ltd. |