CN103098818B - Pesticide compound mixture containing clothianidin and monosultap and pesticide fertilizer and production method thereof - Google Patents
Pesticide compound mixture containing clothianidin and monosultap and pesticide fertilizer and production method thereof Download PDFInfo
- Publication number
- CN103098818B CN103098818B CN201310000726.0A CN201310000726A CN103098818B CN 103098818 B CN103098818 B CN 103098818B CN 201310000726 A CN201310000726 A CN 201310000726A CN 103098818 B CN103098818 B CN 103098818B
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- clothianidin
- sugarcane
- pesticide
- desinsection list
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a pesticide compound mixture containing clothianidin and monosultap and a pesticide fertilizer and a production method thereof, wherein the pesticide fertilizer consists of pesticide active ingredients, fertilizers, inert fillers, adhesives and dispersion agents. The pesticide compound mixture containing clothianidin and monosultap and the pesticide fertilizer and the production method thereof provided by the invention have the advantages that the pesticide active ingredients, namely clothianidin and monosultap, are compounded to have an obvious synergism effect, the using amount and the using times of the pesticide are obviously reduced, the cost is lowered, also the drug resistance generation of pests can be delayed, and meanwhile the insecticidal spectrum is expanded. The pesticide fertilizer also is good, has the functions of insecticide and nutrition supply, relieves the labor intensity, reduces labor times of farmers, reduces the agriculture input for users, and meanwhile also plays a positive acceleration effect for agriculture production and income increasing. The pesticide compound mixture and the pesticide fertilizer can be applied to preventing and treating stem borers, ceratovacuna lanigera zehntner, thrips serrata kobus, alissonotum impressicolle arrow and cerambycidae.
Description
Technical field
The present invention relates to a kind of agriculture chemical compounding mixture, particularly taking clothianidin and desinsection list as pesticide activity component, integrate medicine fertilizer and the production method thereof of desinsection, nutritive effect, this agriculture chemical compounding mixture and insecticide fertilizer can be used for preventing and treating the Sugarcane Pests such as sugarcane borer, sugar cane cottony aphid, Sugarcane Thrips, sugarcane tortoise, sugarcane root prionid.
Background technology
Sugarcane is the important economic crops of China, and its vegetative period is long, and output is high, and it is many that absorb nutrient whole breeding time, is one of crop that fertilizer requirement is larger.People have also taken away nitrogen phosphorus potassium a large amount of in soil in sugarcane in results, so the need of production artificially applying fertilizer of sugarcane.In sugarcane production process, except needing a large amount of fertilizer, also need Sugarcane Pests to prevent and treat.Sugarcane borer, sugarcane tortoise, sugar cane cottony aphid, Sugarcane Thrips, sugarcane root prionid are the primary pest in sugarcane production, improperly will cause sugarcane to drop in production over a large area and reduce sugarcane quality if prevented and treated.In the control of Sugarcane Pests, sugarcane grower often uses high-toxic pesticide to prevent and treat, and the intoxication accident causing is every year of common occurrence, and therefore China has put into effect a series of high-toxic pesticide policies of using that limit.Face the situation of comprehensive forbidding for high-toxic pesticides such as terbufos, carbofuran, thimets, the novel pesticide of good, efficient, the low toxicity of absorption, environmental protection substitutes high-toxic pesticide seeming very urgent in sugarcane production at present in develop and spread.Wherein, neonicotine pesticide clothianidin and sandworm toxin insecticide desinsection list are two very important kinds in low-toxin farm chemicals.
Desinsection list, english common name: Molosultap, chemical name is 2-N, N dimethylamine base-1-sodium thiosulfate base-3-propane thiosulfate, CA registration number: 29547-00-0, molecular formula C
5h
14o
7s
4na, molecular weight 333.4, being the analog of artificial synthetic nereistoxin, is acetylcholine inhibitor, have stronger tag, stomach toxicity and interior suction conduction, without residual hazard, free from environmental pollution, be the comparatively ideal medicament of current comprehensive regulation insect pest, particularly sugarcane borer etc. is had to special efficacy, also can prevent and treat sugarcane aphid, thrips etc., be an extremely successful example of the synthetic exploitation of China's chemobionics.Clothianidin, english common name: Clothiandin, chemical name is (E)-1-(the chloro-1,3-thiazoles-5-of 2-ylmethyl)-3-methyl-2-2-nitroguanidine, CA registration number: 210880-92-5, molecular formula C
6h
8clN
5o
2s, molecular weight 249.7, it is the important kind in second generation anabasine insecticide, for nicotinic acid nAChR ligands inhibitor, have stronger tag, stomach toxicity and interior suction conduction, under low-down dosage, the suckings pest such as woolly aphid to harm sugarcane, thrips, mealybug are efficient, sugarcane tortoise, day bovine, termite, locust grasshopper class and snout moth's larva etc. are also had to very high preventive effect simultaneously, belong to public nuisance-free agricultural chemicals.But the price of clothianidin is relatively high, limit it and further applied, therefore in using method, need to improve, as add other active component or synergistic component, to reduce the dosage in production, reduce cost accounting.In agricultural production, it should be noted that the generation that prevents pest resistance to insecticide, a kind of effective method is to carry out composite with two kinds of different insecticides simultaneously.Adopt the different pesticide compositional of the mode of action also to demonstrate synergistic effect, mixture to the inhibitory action of insect the desired value higher than each component independent role in mixture, be the target of exploitation pesticide compositional preparation.
In agricultural production, people also wish that a pesticidal preparations once uses and can play desinsection and nutrient supply function simultaneously, and two, field operating procedure is united two into one, and save labour, time, the energy, reduce agriculture production cost.Therefore to possess the fertile preparation of medicine of desinsection and nutrient supply function very necessary simultaneously in exploitation.
By Indexing of Scien. and Tech. Literature, we find the following Chinese patent about sugarcane insecticide fertilizer, for example: patent " a kind of sugarcane foliage medicinal fertilizer formulation " (application number: 200710066471), disclose a kind of sugarcane foliage medicinal fertilizer formulation and production method.The production method of this sugarcane foliage medicinal fertilizer is: first add by mass percentage following former powder: 95% Imidacloprid 10%, 95% desinsection list 75%, 98% cartap 15%, after fully mixing, add with the kaolin of former medicine equivalent as packing agent again and be equivalent to the wetting agent of former medicine 2%, then crushing, stirring mixes; Then in agitator, adding by mass percentage zinc sulphate 40%, manganese sulphate 20%, borax 36%, ammonium molybdate 3.5% and 0.5% gibberellin is growth regulator; Agricultural chemicals and micro-fertilizer are mixed in the ratio of 1: 2, form medicine fertilizer.After 200 times of this sugarcane foliage medicinal fertilizer dilute with waters, be sprayed on sugarcane plant blade face.After spray medicine, 1 day sugar cane cottony aphid control efficiency reaches more than 96%, after 3 days, reaches 100%, sugarcane borer ovum and larva is had to certain control action simultaneously, reduces the withered heart seedling in field; After Foliage Absorption, it is green that Sugarcane Leaves turns, and output improves 15%, and field hammer degree improves 0.2%.The Fang Feng of the applicant Chemical Industry Inst., Guangxi Zhuang Autonomous Region, Lai Kaiping, Ye Yiqiang, Huang Kelin, Mo Ping Rong, Wang Jun also discloses " a kind of sugarcane insecticide fertilizer and production method thereof " (application number: 200910114621.1), described medicine fertilizer comprises insecticidal constituent and the npk fertilizer of carbosulfan and worm hydrazides, trace element and stabilizing agent, this sugarcane insecticide fertilizer is to sugarcane borer, the control efficiency of sugarcane tortoise all exceedes 80%, do not execute compared with the control treatment of insecticide with not applying fertilizer yet, sugarcane yield all increases substantially, volume increase all exceedes 40%.At present, about the sugarcane pesticide-fertilizer product and the correlative study that contain clothianidin and desinsection list there is not yet report.Patent CN102696586A and CN102696587A mention and use nicotinic insecticide (clothianidin-containing) and sandworm toxin insecticide (containing desinsection list) to carry out composite, but the content that unexposed clothianidin and desinsection list are concrete, and application technology after clothianidin and desinsection list composite and outstanding advantages thereof are also there are no report.
Summary of the invention
The object of this invention is to provide that a kind of interior absorption is good, efficient, low-residual, be difficult for producing the compounded preparation of pesticide of resistance, and complex preparation is combined with fertilizer science and a kind of insecticide fertilizer granule of developing, in agricultural production, applied once not only can apply fertilizer but also can kill on sugarcane field and soil insect, overcome that user under prior art condition wants twice or the way of use of insecticide and fertilizer repeatedly, saved time and manually.
Agriculture chemical compounding mixture of the present invention, comprises clothianidin, desinsection list, can also comprise auxiliary material.
Agriculture chemical compounding mixture of the present invention, taking this mixture as benchmark, the weight percentage of clothianidin and desinsection list is 21～65%, and wherein the weight proportion of clothianidin and desinsection list is 1: 4 to 1: 24, and all the other are auxiliary material.
In insecticide fertilizer of the present invention, agriculture chemical compounding mixture weight percentage composition is 10%～95%, and weight of fertilizer percentage composition is 5%～90%.
In insecticide fertilizer of the present invention, taking the fertile gross weight of medicine as benchmark, the weight percentage of clothianidin is 0.01%～1%, and the weight percentage of desinsection list is for being 0.1%～5.0%.
Auxiliary material described in agriculture chemical compounding mixture of the present invention is two or more in inert filler, adhesive and dispersant.
Fertilizer of the present invention is one or more in nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, composite fertilizer, moderate-element fertilizer, trace element fertilizer, alga fertilizer, humic acid fertilizer, amino acid fertilizer.
Inert filler of the present invention be silica sand, diatomite, bentonite, kaolin, attapulgite, clay, white carbon, precipitated calcium carbonate, talcum powder and zeolite one or more.
Adhesive of the present invention be in cellulose and modifier, starch and modifier thereof, rosin and modifier thereof, paraffin and modifier thereof, natural plant gum, animal glue, sulphur, pitch, polyvinyl alcohol, polyvinyl acetate, gypsum and sodium silicate one or more.
Dispersant of the present invention is one or more in lauryl sodium sulfate, lauryl alcohol sodium sulphate, dodecyl sulphate calcium, neopelex, sodium butylnaphthalenesulfonate, sodium lignin sulfonate, sodium methylene bis-naphthalene sulfonate, calcium lignosulfonate, polyethers ichthyodin, fatty alcohol-polyoxyethylene ether sodium sulfonate, alkanolamide sodium sulfonate of ethoxylated.
The production method of agriculture chemical compounding mixture of the present invention: after clothianidin, desinsection list and auxiliary material are weighed, mix and obtain product.
The production method of insecticide fertilizer of the present invention, weighs agriculture chemical compounding mixture and fertilizer, adopts one or more in extruder grain, rolling granulation, coating pelletizing technique, obtains pesticide-fertilizer product.
Agriculture chemical compounding mixture of the present invention and insecticide fertilizer can be prevented and treated the Sugarcane Pests such as sugarcane borer, sugar cane cottony aphid, Sugarcane Thrips, sugarcane tortoise, sugarcane root prionid.
Agriculture chemical compounding mixture and insecticide fertilizer of the present invention can be used alone, and are also used in conjunction with other agricultural chemicals or fertilizer according to actual needs.
The present invention has following remarkable result:
(1) by composite to clothianidin and desinsection list, mutually there is synergistic effect, not only kept the plurality of advantages of former agricultural chemicals single dose, but also each component working concentration in the situation that activity is not lost in mixture is reduced, thereby the activity of mixture is increased.
(2) by composite to clothianidin and desinsection list, make insect be difficult to eliminate the impact of two kinds of mode of action different insecticides on it simultaneously, delay the individual generation of pesticide resistance in insect colony.
(3) by composite to clothianidin and desinsection list, can expand insecticidal spectrum, make product can prevent and treat multiple Sugarcane Pests simultaneously.
(4) the present invention is a kind of fertile preparation of medicine of efficiently killing soil insect.Clothianidin and desinsection Dan Jun have good interior suction conductivity, be easy to be transmitted to each position of plant by the Root Absorption of sugarcane, thereby the insect of cause harm sugarcane acrial part and under ground portion is all played to killing action.
(5) the fertile preparation of a kind of medicine that the present invention develops by the combination of sciences of insecticide and fertilizer, has alleviated peasant's labour intensity and work number of times, and the production that reduces peasant drops into, and also agriculture increasing both production and income is also played to positive facilitation simultaneously.
Embodiment
Following examples only play the effect being described further to the present invention, other replacement that those skilled in the art carry out the present invention and amendment are all within protection scope of the present invention.In embodiment, each component proportioning is all weight percentage below.
Embodiment 1 (3.6% clothianidin desinsection list fertilizer granules)
Clothianidin 0.15%, desinsection list 3.45%, fertilizer is trace element fertilizer, comprise trbasic zinc phosphate, copper sulphate, iron sulfate, manganese sulphate, boric acid, sodium tetraborate, ammonium molybdate, wherein zinc content 0.4%, copper content 0.4%, iron content 0.2%, manganese content 0.4%, boron content 0.5%, molybdenum content 0.1%, starch sulfate 10%, neopelex 5%, sodium lignin sulfonate 5%, surplus is diatomite.Clothianidin, desinsection list, neopelex, sodium lignin sulfonate and diatomite with the abundant efflorescence of cracker and mix, are formed to certain density pesticide activity component premix.Trbasic zinc phosphate, copper sulphate, iron sulfate, manganese sulphate, boric acid, sodium tetraborate, ammonium molybdate with diatomite with the abundant efflorescence of cracker and mix, form certain density trace element fertilizer premix.Starch sulfate is mixed by weight at 1: 2 to fully gelatinization at 80 DEG C with water.After pesticide activity component premix, trace element fertilizer premix are fully mixed, in Squeezinggranulator, make the fertile particle of medicine with adding together with starch sulfate after gelatinization, after drying, cooling, screening, inspection, carry out finished product packing.
Embodiment 2 (5.4% clothianidin desinsection list fertilizer granules)
Clothianidin 0.6%, desinsection list 4.8%, fertilizer is trace element fertilizer, comprise zinc sulphate, trbasic zinc phosphate, manganese sulphate, boric acid, sodium tetraborate, ammonium molybdate, wherein zinc content 0.2%, boron content 0.6%, manganese content 0.2%, molybdenum content 0.2%, dodecyl sulphate calcium 4%, calcium lignosulfonate 5%, surplus is attapulgite.Clothianidin, desinsection list, zinc sulphate, trbasic zinc phosphate, manganese sulphate, boric acid, sodium tetraborate, ammonium molybdate, dodecyl sulphate calcium, calcium lignosulfonate and attapulgite with the abundant efflorescence of cracker and mix, are formed to the fertile premix of medicine.Fertile medicine premix is made to the fertile particle of medicine with adding together with appropriate water in granulating disc, after drying, cooling, screening, inspection, carry out finished product packing.
Embodiment 3 (6% clothianidin desinsection list fertilizer granules)
Clothianidin 1.0%, desinsection list 5.0%, talcum powder 4%, gum Arabic 10%, lauryl alcohol sodium sulphate 3%, sodium butylnaphthalenesulfonate 6%, surplus is potassium fulvate.Clothianidin, desinsection list, potassium fulvate, lauryl alcohol sodium sulphate, sodium butylnaphthalenesulfonate with talcum powder with the abundant efflorescence of cracker and mix, form the fertile premix of medicine.Gum Arabic is mixed by weight with water at 1: 2, at 80 DEG C, fully dissolve.Fertile medicine premix is made to the fertile particle of medicine with adding together with gum Arabic after dissolving in Squeezinggranulator, after drying, cooling, screening, inspection, carry out finished product packing.
Embodiment 4 (0.36% clothianidin desinsection list fertilizer granules)
Clothianidin 0.02%, desinsection 10.34 %, kaolin 2.64%, ammonium sulfate 18%, urea 28%, potassium sulfate 18%, superphosphate 18%, paraffin 8%, dodecyl sulphate calcium 2%, calcium lignosulfonate 5%.Clothianidin, desinsection list, kaolin, ammonium sulfate, urea, potassium sulfate, superphosphate, dodecyl sulphate calcium and calcium lignosulfonate are pulverized and mixed, drop in roller pelletizer and make the fertile particle of medicine, with the paraffin dressing of melting.To be cooled, screening, inspection after carry out finished product packing.
Embodiment 5 (0.45% clothianidin desinsection list fertilizer granules)
Clothianidin 0.05%, desinsection list 0.4%, zeolite 2.48%, sulphur 7%, alkanolamide sodium sulfonate of ethoxylated 2%, surplus is urea.First clothianidin, the alone zeolite adsorption of desinsection, then add urea and alkanolamide sodium sulfonate of ethoxylated to pulverize and mix, drop in roller pelletizer and make the fertile particle of medicine, with the sulphur dressing of melting.To be cooled, screening, inspection after carry out finished product packing.
Embodiment 6 (0.52% clothianidin desinsection list fertilizer granules)
Clothianidin 0.04%, desinsection list 0.48%, white carbon 5.48%, urea 20%, rosin 8%, sodium butylnaphthalenesulfonate 2%, fatty alcohol-polyoxyethylene ether sodium sulfonate 4%, surplus is alga fertilizer.First clothianidin, the alone white carbon of desinsection are adsorbed, then add urea, lauryl sodium sulfate, polyethers ichthyodin and alga fertilizer to pulverize and mix, drop in granulating disc and make the fertile particle of medicine, with the rosin dressing of melting.To be cooled, screening, inspection after carry out finished product packing.
Embodiment 7 (0.69% clothianidin desinsection list fertilizer granules)
Clothianidin 0.03%, desinsection list 0.66%, perlite 7%, fused calcium magnesium phosphate 10%, urea 30%, rosin 12%, lauryl sodium sulfate 3%, polyethers ichthyodin 3%, surplus is amino acid fertilizer.First clothianidin, the alone perlite of desinsection are adsorbed, then add successively fused calcium magnesium phosphate, amino acid fertilizer, urea, lauryl sodium sulfate, polyethers ichthyodin to pulverize and mix, drop in granulating disc and make the fertile particle of medicine, with the rosin dressing of melting.To be cooled, screening, inspection after carry out finished product packing.
Embodiment 8 (0.84% clothianidin desinsection list fertilizer granules)
Clothianidin 0.04%, desinsection list 0.8%, bentonite 6.16%, fused calcium magnesium phosphate 20%, urea 20%, potassium sulfate 20%, humic acid 18%, rosin 10%, lauryl sodium sulfate 2%, fatty alcohol-polyoxyethylene ether sodium sulfonate 3%.First clothianidin, the alone bentonite absorption of desinsection; add successively again fused calcium magnesium phosphate, urea, potassium sulfate, humic acid, lauryl sodium sulfate and fatty alcohol-polyoxyethylene ether sodium sulfonate to pulverize and mix; drop in granulating disc and make the fertile particle of medicine, with the rosin dressing of melting.To be cooled, screening, inspection after carry out finished product packing.
Embodiment 9 (21% clothianidin desinsection list wetting powder)
Clothianidin 4%, desinsection list 17%, sodium lignin sulfonate 7%, sodium methylene bis-naphthalene sulfonate 3%, surplus is talcum powder.Clothianidin, desinsection list, sodium lignin sulfonate, sodium methylene bis-naphthalene sulfonate and talcum powder are mixed, then the material after mixing is added and in airslide disintegrating mill, is crushed to fineness and reaches 325 orders, carry out after the assay was approved finished product packing.
Embodiment 10 (36% clothianidin desinsection list wetting powder)
Clothianidin 1.5%, desinsection list 34.5%, lauryl sodium sulfate 5%, polyethers ichthyodin 4%, surplus is kaolin.Clothianidin, desinsection list, lauryl sodium sulfate, polyethers ichthyodin and kaolin are mixed, then the material after mixing is added and in airslide disintegrating mill, is crushed to fineness and reaches 325 orders, carry out after the assay was approved finished product packing.
Embodiment 11 (51% clothianidin desinsection list wetting powder)
Clothianidin 3%, desinsection list 48%, alkanolamide sodium sulfonate of ethoxylated 7%, calcium lignosulfonate 3%, surplus is attapulgite.Clothianidin, desinsection list, alkanolamide sodium sulfonate of ethoxylated, calcium lignosulfonate and attapulgite are mixed, then the material after mixing is added and in airslide disintegrating mill, is crushed to fineness and reaches 325 orders, carry out after the assay was approved finished product packing.
Embodiment 12 (65% clothianidin desinsection list wetting powder)
Clothianidin 5%, desinsection list 60%, lauryl sodium sulfate 5%, sodium butylnaphthalenesulfonate 7%, surplus is bentonite.Clothianidin, desinsection list, lauryl sodium sulfate, sodium butylnaphthalenesulfonate and bentonite are mixed, then the material after mixing is added and in airslide disintegrating mill, is crushed to fineness and reaches 325 orders, carry out after the assay was approved finished product packing.
Embodiment 13 (the composite Toxicity Determination to sugar cane cottony aphid of desinsection list and anabasine insecticide)
Using sugar cane cottony aphid Ceratovacuna lanigera 3 age nymph as target, pass through indoor biometrics, specify desinsection list and clothianidin, Diacloden Thiamethoxam, thiacloprid Thiacloprid, Imidacloprid Imidacloprid, Acetamiprid Acetamiprid, Nitenpyram Nitenpyram, synergy situation after several anabasine insecticides such as MTI-446 Dinotefuran are composite, test method is with reference to farm-chemical indoor determination test rule NYT1154.4-2006 and NYT1154.7-2006, every processing repeats for 4 times, 15 examination worms of every repetition, if be not treated to blank containing medicament.Calculate co-toxicity coefficient according to Sun-Johnson method, carry out synegism evaluation according to co-toxicity coefficient, if co-toxicity coefficient > 120 is synergistic effect, if 120 >=co-toxicity coefficient > 80 is summation action, if co-toxicity coefficient≤80 are antagonism, the results are shown in Table 1.
The composite co-toxicity coefficient to sugar cane cottony aphid of table 1 desinsection list and anabasine insecticide
Desinsection list and several anabasine insecticide are composite as seen from the table, and the each proportioning of mixture, to the co-toxicity coefficient of sugar cane cottony aphid is all greater than more than 80, does not occur antagonism, illustrate desinsection list and anabasine insecticide composite be feasible.Compared with other combination, when desinsection list and clothianidin are composite, co-toxicity coefficient is higher, when desinsection list: have synergistic effect, wherein desinsection list when clothianidin > 1: 4: clothianidin is all greater than 200 at 24: 1～16: 1 o'clock co-toxicity coefficients, and synergistic effect is combined apparently higher than other.
Embodiment 14 (the composite Toxicity Determination to sugar cane cottony aphid of clothianidin and sandworm toxin insecticide)
On the basis of embodiment 13, taking clothianidin as main reagent agent, still using sugar cane cottony aphid 3 age nymph as target, by indoor biometrics, specify the synergy situation of several sandworm toxin insecticides such as clothianidin and desinsection list, dimehypo Bisultap, cartap Cartap, thiocyclam Thiocyclam, bensultap Bensultap after composite.Test method and synegism evaluation, with embodiment 13, the results are shown in Table 2.
Table 2 clothianidin and sandworm toxin insecticide composite to sugar cane cottony aphid its malicious coefficient
Clothianidin and sandworm toxin insecticide are composite as seen from the table, and the each proportioning of mixture, to the co-toxicity coefficient of sugar cane cottony aphid is all greater than more than 80, does not occur antagonism, illustrate clothianidin and neires toxin several pesticides composite be feasible.Other combination is compared, when clothianidin and desinsection list are composite, co-toxicity coefficient is higher, when clothianidin: all have synergistic effect, wherein clothianidin when desinsection monoamine < 4: 1: desinsection monoamine is all greater than 200 at 1: 12～1: 24 o'clock co-toxicity coefficient, and synergistic effect is combined apparently higher than other.
Embodiment 15 (the composite Toxicity Determination to several Sugarcane Pests of clothianidin and desinsection list)
By indoor biometrics, specify the composite rear synergy situation to several sugarcane primary pests of clothianidin and desinsection list.According to the effective object of clothianidin and desinsection list, fall into line dark fund tortoise plastron Alissonotum impressicolle and 2 instar larvaes of sugarcane root prionid Dorysthenes granulosus and the adult of sugarcane abdomen tooth thrips Fulmekiola serratus as target using chilo infuscatellus Chilotraea influscatellus, sugarcane, test clothianidin and the desinsection list mixture virulence to examination worm, test method and synegism evaluation, with embodiment 13, the results are shown in Table 3.
The composite co-toxicity coefficient to chilo infuscatellus, prominent back of the body sugarcane tortoise, sugar cane cottony aphid and sugarcane root prionid of table 3 clothianidin and desinsection list
The co-toxicity coefficient that the composite each proportioning of clothianidin and desinsection list falls into line dark fund tortoise plastron, sugarcane abdomen tooth thrips and these several sugarcane primary pests of sugarcane root prionid to chilo infuscatellus, sugarcane as seen from the table is all greater than 120, there is synergistic effect, illustrate that mixture is to trying the inhibitory action of worm higher than the desired value of clothianidin in mixture and desinsection list independent role, therefore clothianidin and desinsection list are composite is feasible.
Embodiment 16 (field medicine effect test of the sugarcane insecticide fertilizer of clothianidin-containing and desinsection list and manure trial)
Embodiment 1～4 and the prepared product of embodiment 6 are carried out to field medicine effect test and manure trial.Test method and effect assessment are with reference to pesticide field efficacy medicine test criterion GB/T 17980.61-2004, GB/T 17980.62-2004 and GB/T 17980.63-2004.Wherein preventing and kill off the field experiment of sugarcane borer (sociales are chilo infuscatellus), sugarcane woolly aphid, Sugarcane Thrips (sociales are sugarcane abdomen tooth thrips) carries out at Wuming County doube bridge town, Guangxi sugarcane field; Little Pingyang town sugarcane field carries out in Laibin city of Guangxi to prevent and kill off the field experiment of sugarcane tortoise (sociales be sugarcane fall in line dark fund tortoise plastron); Preventing and kill off the field experiment of sugarcane root prionid carries out at Wa Tang town, Guigang, Guangxi sugarcane field.After off-test, add up the sugarcane yield of each test region, average and survey product.Test point following processing: 1. with the prepared product of embodiment 1 (i.e. 3.6% clothianidin desinsection list fertilizer granules) and 50kg composite fertilizer (N content 18%, P
2o
5content 10%, K
2o content is 12%, Hereinafter the same) mixes to apply as base manure afterwards; 2. mix and apply as base manure afterwards using the prepared product of embodiment 2 (i.e. 5.4% clothianidin desinsection list fertilizer granules) and 50kg composite fertilizer; 3. mix and apply as base manure afterwards using the prepared product of embodiment 3 (i.e. 6% clothianidin desinsection list fertilizer granules) and 50kg composite fertilizer; 4. directly apply as base manure using the prepared product of embodiment 4 (i.e. 0.36% clothianidin desinsection list fertilizer granules), use 50kg for every mu.5. directly apply as base manure using the prepared product of embodiment 6 (i.e. 0.52% clothianidin desinsection list fertilizer granules), use 35kg for every mu.6. mix and apply as base manure afterwards using the prepared product of embodiment 9 (i.e. 21% clothianidin desinsection list wetting powder) and 50kg composite fertilizer; 7. mix and apply as base manure afterwards using the prepared product of embodiment 10 (i.e. 36% clothianidin desinsection list wetting powder) and 50kg composite fertilizer; 8. mix and apply as base manure afterwards using the prepared product of embodiment 11 (i.e. 51% clothianidin desinsection list wetting powder) and 50kg composite fertilizer; 9. mix and apply as base manure afterwards using the prepared product of embodiment 12 (i.e. 65% clothianidin desinsection list wetting powder) and 50kg composite fertilizer; Contrast insecticide is 3.6% clothianidin granule, 3.6% granular insecticide and 5% carbofuran granule, respectively contrast insecticide and 50kg composite fertilizer is mixed to apply as base manure afterwards when use.Each processing established equal 3 repetitions above, and every repetitive administration area is 1 mu, and every mu of pesticide activity component is 0.18kg (pure).Remaining farming operation is carried out routinely.Result of the test is as table 4.
Land for growing field crops drug effect and the fertilizer efficiency (2011 year) of table 4 test medicine to several Sugarcane Pests
In the field in different sugarcanes district, application test result shows, apply product of the present invention as base manure the control efficiency of sugarcane borer, sugarcane tortoise, sugar cane cottony aphid, Sugarcane Thrips and sugarcane root prionid is all exceeded to 81%, under same concentrations, its drug effect is all good than using separately clothianidin, desinsection list and carbofuran granule.After the fertile processing of medicine of the present invention, sugarcane yield is also better than the processing of each contrast insecticide+composite fertilizer.Also do not execute compared with the blank processing of insecticide with not applying fertilizer, sugarcane yield all increases substantially, and volume increase all exceedes 42%.
Embodiment 17 (field medicine effect test of the sugarcane insecticide fertilizer of clothianidin-containing and desinsection list and manure trial)
Embodiment 5, embodiment 7 and the prepared product of embodiment 8 are carried out to field medicine effect test and manure trial.Test method and effect assessment are with reference to pesticide field efficacy medicine test criterion GB/T 17980.61-2004 and GB/T17980.62-2004.Test is carried out at Wuming County Xian Hu town, Guangxi sugarcane field, and primary pest is sugarcane borer (sociales are chilo infuscatellus), sugarcane woolly aphid, Sugarcane Thrips (sociales are sugarcane abdomen tooth thrips).After off-test, add up the sugarcane yield of each test region, average and survey product.Test point following processing: 1. apply as topdressing when the large ridging of sugarcane using the prepared product of embodiment 5 (i.e. 0.45% clothianidin desinsection list fertilizer granules); 2. apply as topdressing when the large ridging of sugarcane using the prepared product of embodiment 7 (i.e. 0.69% clothianidin-desinsection list fertilizer granules); 3. apply as topdressing when the large ridging of sugarcane using the prepared product of embodiment 8 (i.e. 0.84% clothianidin desinsection list fertilizer granules).Contrast insecticide is 3.6% clothianidin granule, 3.6% granular insecticide and 5% carbofuran granule, respectively contrast insecticide and 50kg composite fertilizer is mixed in the time of the large ridging of sugarcane, to apply as the fertilizer that topdresses equally afterwards when use.Each processing established equal 3 repetitions above, and every repetitive administration area is 1 mu, and every mu of pesticide activity component is 0.18kg (pure).Remaining farming operation is carried out routinely.Result of the test is as table 5.
Land for growing field crops drug effect and the fertilizer efficiency (2011 year) of table 5 test medicine to several Sugarcane Pests
Field application test result shows, in the time of the large ridging of sugarcane, apply embodiment 5, embodiment 7 as topdressing and the prepared pesticide-fertilizer product of embodiment 8 all exceedes 83% to the control efficiency of sugarcane borer, sugar cane cottony aphid and Sugarcane Thrips, under same concentrations, its drug effect is all good than using separately clothianidin, desinsection list and carbofuran granule.After the fertile processing of medicine of the present invention, sugarcane yield is also better than the processing of each contrast insecticide+composite fertilizer.Also do not execute compared with the blank processing of insecticide with not applying fertilizer, sugarcane yield increases substantially equally, and volume increase all exceedes 44%.
Sugarcane special medicated fertilizer granule of the present invention is the fertile preparation of compound medicine that adopts the insecticide of clothianidin and two kinds of different mechanisms of action of desinsection list to process, said preparation toxicity is low, drug effect ideal, be one of ideal substitute kind of terbufos, the contour malicious granular pesticide of carbofuran, meet field fertilization needs simultaneously.
Claims (11)
1. an agriculture chemical compounding mixture, is characterized in that: its main active is clothianidin and desinsection list, and the weight percentage of clothianidin and desinsection list is 21-65%, and wherein the weight proportion of clothianidin and desinsection list is 1: 4 to 1: 24, and all the other are auxiliary material; Described auxiliary material is two or three in inert filler, adhesive and dispersant.
2. an insecticide fertilizer that comprises agriculture chemical compounding mixture claimed in claim 1, is characterized in that: the composite mixture weight percentage composition of the fertile Pesticides of described medicine is 10%-95%, and weight of fertilizer percentage composition is 5%-90%.
3. insecticide fertilizer as claimed in claim 2, is characterized in that: taking the fertile gross weight of medicine as benchmark, the weight percentage of clothianidin is 0.01%-1%, and the weight percentage of desinsection list is 0.1%-5.0%.
4. insecticide fertilizer as claimed in claim 2, is characterized in that: described fertilizer is one or more in nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, composite fertilizer, moderate-element fertilizer, trace element fertilizer, alga fertilizer, humic acid fertilizer, amino acid fertilizer.
5. agriculture chemical compounding mixture as claimed in claim 1, is characterized in that: described inert filler be in silica sand, diatomite, bentonite, kaolin, attapulgite, clay, white carbon, precipitated calcium carbonate, talcum powder and zeolite one or more.
6. agriculture chemical compounding mixture as claimed in claim 1, is characterized in that: described adhesive be in cellulose and modifier, starch and modifier thereof, rosin and modifier thereof, paraffin and modifier thereof, natural plant gum, animal glue, sulphur, pitch, polyvinyl alcohol, polyvinyl acetate, gypsum and sodium silicate one or more.
7. agriculture chemical compounding mixture as claimed in claim 1, is characterized in that: described dispersant is one or more in lauryl sodium sulfate, lauryl alcohol sodium sulphate, dodecyl sulphate calcium, neopelex, sodium butylnaphthalenesulfonate, sodium lignin sulfonate, sodium methylene bis-naphthalene sulfonate, calcium lignosulfonate, polyethers ichthyodin, fatty alcohol-polyoxyethylene ether sodium sulfonate, alkanolamide sodium sulfonate of ethoxylated.
8. the production method of agriculture chemical compounding mixture as claimed in claim 1, is characterized in that, after clothianidin, desinsection list and auxiliary material are weighed, mixes and obtains product.
9. the purposes of agriculture chemical compounding mixture as claimed in claim 1 aspect the agricultural chemicals for preventing and treating sugarcane borer, sugar cane cottony aphid, Sugarcane Thrips, sugarcane tortoise and sugarcane root prionid.
10. the production method of insecticide fertilizer as claimed in claim 2, is characterized in that, agriculture chemical compounding mixture and fertilizer are weighed, and adopts one or more in extruder grain, rolling granulation, coating pelletizing technique, obtains granule product.
The purposes of 11. insecticide fertilizers as claimed in claim 2 aspect the agricultural chemicals for the preparation of control sugarcane borer, sugar cane cottony aphid, Sugarcane Thrips, sugarcane tortoise and sugarcane root prionid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310000726.0A CN103098818B (en) | 2013-01-04 | 2013-01-04 | Pesticide compound mixture containing clothianidin and monosultap and pesticide fertilizer and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310000726.0A CN103098818B (en) | 2013-01-04 | 2013-01-04 | Pesticide compound mixture containing clothianidin and monosultap and pesticide fertilizer and production method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103098818A CN103098818A (en) | 2013-05-15 |
| CN103098818B true CN103098818B (en) | 2014-11-19 |
Family
ID=48307277
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310000726.0A Expired - Fee Related CN103098818B (en) | 2013-01-04 | 2013-01-04 | Pesticide compound mixture containing clothianidin and monosultap and pesticide fertilizer and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103098818B (en) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103708978B (en) * | 2013-12-25 | 2016-07-13 | 广西农战士高工效农业技术有限公司 | A kind of organic-inorganic pestsides synthesis sustained-controll-release fertiliser |
| CN104041509A (en) * | 2014-04-30 | 2014-09-17 | 北海市农业科学研究所 | Fertilizer mixing medicament for control of corn pests and application thereof |
| CN104151087B (en) * | 2014-09-02 | 2016-08-24 | 联保作物科技有限公司 | A kind of medicine fertilizer slow-release preparation and preparation method thereof and application process |
| CN104151088B (en) * | 2014-09-02 | 2016-12-07 | 联保作物科技有限公司 | A kind of medicine fertilizer slow-release preparation, its preparation method and application process |
| CN105384502A (en) * | 2015-11-10 | 2016-03-09 | 无锡市路华肥料科技有限公司 | Fertilizer for preventing cotton aphids |
| CN105777406A (en) * | 2016-05-25 | 2016-07-20 | 广西金穗农药有限公司 | Pesticide and fertilizer mixture containing clothianidin |
| CN107827624A (en) * | 2017-12-20 | 2018-03-23 | 青岛住商中农肥料有限公司 | A kind of Synergistic slow release urea and its preparation technology |
| CN110577432A (en) * | 2018-06-09 | 2019-12-17 | 王忠厚 | Formula of water-soluble silicon fertilizer taking Chinese herbal medicines as additives |
| CN112293194A (en) * | 2020-11-04 | 2021-02-02 | 中诚国联（河南）生物科技有限公司 | Application of pesticide-fertilizer granules containing clothianidin and monosultap to sugarcane |
| CN112430157A (en) * | 2020-12-04 | 2021-03-02 | 中诚国联（河南）生物科技有限公司 | Preparation method and application of high-tower pesticide-fertilizer granules for preventing and treating soil insects |
| CN112521211A (en) * | 2020-12-04 | 2021-03-19 | 中诚国联（河南）生物科技有限公司 | High-tower pesticide-fertilizer containing dinotefuran and monosultap and application thereof |
| CN112430156A (en) * | 2020-12-04 | 2021-03-02 | 中诚国联（河南）生物科技有限公司 | Preparation method and application of high-tower pesticide-fertilizer granules for preventing and treating piercing-sucking pests |
| CN112956480A (en) * | 2021-02-04 | 2021-06-15 | 四川眉山凯尔化工有限公司 | Pesticide raw material formula |
| CN112661574A (en) * | 2021-02-04 | 2021-04-16 | 赤天化科技集团有限公司 | High-tower pesticide-fertilizer containing clothianidin and dinotefuran and preparation method thereof |
| CN112707765A (en) * | 2021-02-06 | 2021-04-27 | 广西植保农药厂有限公司 | Lodging-resistant sugarcane pesticide fertilizer |
| CN114304176A (en) * | 2021-12-10 | 2022-04-12 | 赤天化科技集团有限公司 | Insecticidal composition containing monosultap and application thereof |
| CN114451409A (en) * | 2022-01-24 | 2022-05-10 | 赤天化科技集团有限公司 | Clothianidin-containing seed treatment suspending agent and preparation method thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IE71183B1 (en) * | 1988-12-27 | 1997-01-29 | Takeda Chemical Industries Ltd | Guanidine derivatives their production and insecticides |
| CN1054729C (en) * | 1994-03-27 | 2000-07-26 | 重庆市植物保护植物检疫站 | Process for preparing granular insecticide |
| JP4841856B2 (en) * | 2005-03-31 | 2011-12-21 | 株式会社堀場製作所 | Clotheneidine and dinotefuran hapten compounds, antibodies, hybridomas and measuring means, measuring kits or measuring methods thereof |
| CN101422160B (en) * | 2008-11-13 | 2011-08-10 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing clothianidin |
| CN101642097A (en) * | 2009-09-07 | 2010-02-10 | 山东农业大学 | Clothianidin sustained and controlled release granule composite |
| CN102696587B (en) * | 2012-06-15 | 2014-03-26 | 河南好年景生物发展有限公司 | Compound controlled-release granular pesticide preparation and preparation method thereof |
-
2013
- 2013-01-04 CN CN201310000726.0A patent/CN103098818B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN103098818A (en) | 2013-05-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103098818B (en) | Pesticide compound mixture containing clothianidin and monosultap and pesticide fertilizer and production method thereof | |
| CN103360162B (en) | A kind of Sugarcane sustained-release granular medicinal fertilizer | |
| CN101709016B (en) | Sugarcane insecticide fertilizer and production method thereof | |
| CN101323547A (en) | Medicine fertilizer granular formulation for killing molluscous harmful to rice and manufacturing method thereof | |
| CN103864516A (en) | Special multi-resistance drug fertilizer for super rice and preparation method thereof | |
| EP2683247B1 (en) | An agrochemical composition comprising zinc, sulfur and a pesticidal active ingredient | |
| CN102249799A (en) | Method for controlling crop diseases with shenqinmycin and shenqinmycin preparation | |
| CN102992900A (en) | Pesticide-fertilizer composition containing nereistoxin and pyrethroid pesticides | |
| CN103130568A (en) | Thiamethoxam insecticide-fertilizer mixture and preparing method thereof | |
| CN103288557A (en) | Mixture of secondary element fertilizer and pesticide | |
| CN106747919A (en) | A kind of desinsection slow releasing medicinal fertilizer and preparation method thereof | |
| CN104163726A (en) | Pesticide fertilizer slow-release preparation, and preparation method and application method thereof | |
| CN103102219A (en) | Pesticide-fertilizer mixer for controlling rice pests | |
| CN104193540A (en) | Pesticidal disease protecting and nutrient pesticide fertilizer and application thereof, and pesticidal disease protecting and nutrient pesticide fertilizer slow release formulation and application thereof | |
| CN104151088B (en) | A kind of medicine fertilizer slow-release preparation, its preparation method and application process | |
| CN106857653A (en) | Soluble granule and its application process for preventing and treating root disease | |
| CN104522045A (en) | Pesticide composition, sustained-release pesticidal fertilizer, and preparation methods thereof | |
| CN104126605A (en) | Compound pesticide | |
| CN104672025A (en) | Chlorantraniliprole-containing pesticide fertilizer composition | |
| CN105541506A (en) | Paddy-field pesticide-fertilizer sustained release granules and preparing method and application method thereof | |
| CN104446984A (en) | Special fertilizer for chenopodium quinoa and preparation method thereof | |
| CN104397030B (en) | A kind of granular pesticide containing humic acid and ethiprole | |
| CN106348936A (en) | Multifunctional pesticide fertilizer and preparation method thereof | |
| CN105660677A (en) | Insecticide composition, sustained-release medical fertilizer and insecticide | |
| CN109054843A (en) | A kind of soil conditioner and preparation method and its application as pesticide synergistic agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141119 |