CN101857763A - Heavy anti-corrosion clinkery epoxy powder coating - Google Patents
Heavy anti-corrosion clinkery epoxy powder coating Download PDFInfo
- Publication number
- CN101857763A CN101857763A CN200910097616A CN200910097616A CN101857763A CN 101857763 A CN101857763 A CN 101857763A CN 200910097616 A CN200910097616 A CN 200910097616A CN 200910097616 A CN200910097616 A CN 200910097616A CN 101857763 A CN101857763 A CN 101857763A
- Authority
- CN
- China
- Prior art keywords
- corrosion
- powder coating
- epoxy
- heavy anti
- clinkery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004593 Epoxy Substances 0.000 title claims abstract description 28
- 239000000843 powder Substances 0.000 title claims abstract description 26
- 239000011248 coating agent Substances 0.000 title claims abstract description 25
- 238000000576 coating method Methods 0.000 title claims abstract description 25
- 238000005260 corrosion Methods 0.000 title claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000000945 filler Substances 0.000 claims abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 229920005989 resin Polymers 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 239000004843 novolac epoxy resin Substances 0.000 claims description 5
- 238000010521 absorption reaction Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 229960001866 silicon dioxide Drugs 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000011863 silicon-based powder Substances 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 abstract description 4
- 229920000647 polyepoxide Polymers 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000005536 corrosion prevention Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000035939 shock Effects 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229940106691 bisphenol a Drugs 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 150000002118 epoxides Chemical group 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- -1 phenol phenolic aldehyde Chemical class 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention relates to a heavy anti-corrosion clinkery epoxy powder coating, which comprises the following components in part by weight: 100 parts of epoxy resin, 20 to 30 parts of curing agent, 2 to 5 parts of flatting agent and 40 to 70 parts of filler. The heavy anti-corrosion clinkery epoxy powder coating is mainly applied in the field of pipeline corrosion prevention and has the advantages of high toughness, high impact resistance, simple preparation process and suitability for mass production.
Description
Technical field
The present invention relates to pipeline corrosion protection clinkery epoxy powder coating technical field, be specifically related to a kind of heavy anti-corrosion clinkery epoxy powder coating.
Background technology
Heavy anti-corrosion clinkery epoxy powder coating, claim clinkery epoxy powder coating (FBE) again, be a kind of be that carrier transports and dispersed solids coating with the air, it is coated on the surface of steel workpiece of preheating, fusing, levelling, solidify to form uniform coating, English name is FBE.It is mainly used in pipeline corrosion protection, be a kind ofly do not contain solvent, with the film forming new anti-corrosion coating of powder melts, in the pipeline coating procedure, do not exist VOC to pollute, curing speed is fast, long service life.At that time because the condition harshness of natural gas line construction by land, circumstance complication, higher to chemical property, mechanical and physical performance and the spraying application performance demands thereof of heavy anti-corrosion clinkery epoxy powder coating, the especially shock resistance of FBE, snappiness.
Existing FBE coating material production generally adopts and is solid-state bisphenol A epoxide resin or epoxy Dyhard RU 100 powder coating under the room temperature, exist shortcomings such as degree of crosslinking is low, levelling property difference, contradiction after also existing film forming to solidify between hardness and shock resistance, the snappiness, though so at present done a few thing aspect toughness reinforcing at clinkery epoxy powder coating, but be cost with expendable material intensity, modulus and thermotolerance usually, make its physics, mechanics and thermal characteristics be subjected to very big influence, even take into account the problems referred to above, toughening effect is also not obvious.
Summary of the invention
The technical problem that the present invention solves is to overcome the above-mentioned deficiency of prior art, and a kind of shock resistance height, heavy anti-corrosion clinkery epoxy powder coating that flexility is good are provided.
In order to solve the problems of the technologies described above, technical scheme of the present invention is: a kind of heavy anti-corrosion clinkery epoxy powder coating, form by the component of following parts by weight: Resins, epoxy 100 weight parts, solidifying agent 20～30 weight parts, flow agent 2～5 weight parts, filler 40～70 weight parts.
Above-mentioned Resins, epoxy is that weight ratio is 0.3～3: 1 novolac epoxy resin and the mixture of Resins, epoxy E-12.
Above-mentioned solidifying agent is JECP-02B or JECP-02B solidifying agent.
Above-mentioned flow agent is the polyacrylate flow agent of GLP588 silicon-dioxide absorption or the polyacrylate flow agent of the ultra-fine high dispersive silicon-dioxide absorption of GLP788.
Above-mentioned filler is that weight ratio is active micro silicon powder, mica powder, gas-phase silica, process white=15: 7.5: 1: 40 mixture.
Advantage of the present invention: E-12 Resins, epoxy is typical base-material, existing bisphenol-A phenolic composition has phenol phenolic aldehyde composition again in the linear phenolic epoxy resin molecule, there are a plurality of epoxide groups in the molecule, have that degree of crosslinking height, hardness of film height, wear resistance are good, the characteristics of favorable anti-corrosion effect; The adding of solidifying agent can make the molecule crosslinked macromole that reticulates structure of linear loop epoxy resins, thereby shows the inherent premium properties; Add flow agent and can improve appearance of coat, enhanced flow levelling; The tenacity of powder coating of the present invention, coating good toughness, shock resistance height can satisfy the requirement for anticorrosion of buried pipeline, and technology is simple, is suitable for scale production, and other performances meet SY/T 0315-97 index request.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail, but the present invention not only is confined to following examples.
Embodiment 1
Active micro silicon powder 15g, mica powder 7.5g, gas-phase silica 1g, process white 40g are joined the mixture that mixing 30min obtains mixing in high-speed mixer.
With novolac epoxy resin 60g, Resins, epoxy E-12 40g, solidifying agent JECP-02B30g, flow agent GLP5884g, said mixture joins and mixes 2min in the high-speed mixer then; The pre-mixing material adds forcing machine and melt extrudes, 90 ℃ of feeding section temperature, 100 ℃ of melt zone temperature, 110 ℃ of mixing sections, 100 ℃ of discharging sections, the forcing machine rotating speed is controlled at 80rpm, compressing tablet, cooling, fragmentation on air-cooled track type compressing tablet crusher obtain product through pulverizing, classification, cyclonic separator separation and screening in pulverising mill, removed fine powder by cyclonic separation, product granularity control: 150 μ m oversize powders≤3%, 250 μ m oversize powder≤0.2%.
Embodiment 2
Add novolac epoxy resin 75g, Resins, epoxy E-1225g, solidifying agent JECP-02B 20g, flow agent GLP5885g, other are with embodiment 1.
Embodiment 3
Add novolac epoxy resin 25g, Resins, epoxy E-12 75g, solidifying agent JECP-02B 25g, flow agent GLP588 3g, other are with embodiment 1.
Claims (5)
1. heavy anti-corrosion clinkery epoxy powder coating, it is characterized in that: the component by following parts by weight is formed: Resins, epoxy 100 weight parts, solidifying agent 20～30 weight parts, flow agent 2～5 weight parts, filler 40～70 weight parts.
2. heavy anti-corrosion clinkery epoxy powder coating according to claim 1 is characterized in that: described Resins, epoxy is that weight ratio is 0.3～3: 1 novolac epoxy resin and the mixture of Resins, epoxy E-12.
3. heavy anti-corrosion clinkery epoxy powder coating according to claim 1 is characterized in that: described solidifying agent is JECP-02B or JECP-02B solidifying agent.
4. heavy anti-corrosion clinkery epoxy powder coating according to claim 1 is characterized in that: described flow agent is the polyacrylate flow agent of GLP588 silicon-dioxide absorption or the polyacrylate flow agent of the ultra-fine high dispersive silicon-dioxide absorption of GLP788.
5. heavy anti-corrosion clinkery epoxy powder coating according to claim 1 is characterized in that: described filler is that weight ratio is active micro silicon powder, mica powder, gas-phase silica, process white=15: 7.5: 1: 40 mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910097616A CN101857763A (en) | 2009-04-11 | 2009-04-11 | Heavy anti-corrosion clinkery epoxy powder coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910097616A CN101857763A (en) | 2009-04-11 | 2009-04-11 | Heavy anti-corrosion clinkery epoxy powder coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101857763A true CN101857763A (en) | 2010-10-13 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910097616A Pending CN101857763A (en) | 2009-04-11 | 2009-04-11 | Heavy anti-corrosion clinkery epoxy powder coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101857763A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103497639A (en) * | 2013-09-24 | 2014-01-08 | 安徽锐视光电技术有限公司 | High-toughness high-leveling powder coating |
| CN103540220A (en) * | 2013-09-26 | 2014-01-29 | 上海海隆石油化工研究所 | Wear-resistant epoxy powder coating for pipeline |
| CN105754454A (en) * | 2016-04-21 | 2016-07-13 | 宁波市七彩塑粉有限公司 | Electric insulation anti-corrosion powder coating |
| CN105754455A (en) * | 2016-04-21 | 2016-07-13 | 宁波市七彩塑粉有限公司 | Method for preparing electric insulation anticorrosion powder coating |
| CN106634431A (en) * | 2016-12-20 | 2017-05-10 | 山东东方新材料有限公司 | Superhydrophobic-structure fusion-bonded epoxy powder paint and preparation method thereof |
| CN111073369A (en) * | 2019-11-10 | 2020-04-28 | 六安强力电机有限公司 | Outdoor dustproof anticorrosion three-phase asynchronous motor |
-
2009
- 2009-04-11 CN CN200910097616A patent/CN101857763A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103497639A (en) * | 2013-09-24 | 2014-01-08 | 安徽锐视光电技术有限公司 | High-toughness high-leveling powder coating |
| CN103540220A (en) * | 2013-09-26 | 2014-01-29 | 上海海隆石油化工研究所 | Wear-resistant epoxy powder coating for pipeline |
| CN105754454A (en) * | 2016-04-21 | 2016-07-13 | 宁波市七彩塑粉有限公司 | Electric insulation anti-corrosion powder coating |
| CN105754455A (en) * | 2016-04-21 | 2016-07-13 | 宁波市七彩塑粉有限公司 | Method for preparing electric insulation anticorrosion powder coating |
| CN106634431A (en) * | 2016-12-20 | 2017-05-10 | 山东东方新材料有限公司 | Superhydrophobic-structure fusion-bonded epoxy powder paint and preparation method thereof |
| CN106634431B (en) * | 2016-12-20 | 2019-06-25 | 山东东宏管业股份有限公司 | A kind of clinkery epoxy powder coating and preparation method thereof with super-drainage structure |
| CN111073369A (en) * | 2019-11-10 | 2020-04-28 | 六安强力电机有限公司 | Outdoor dustproof anticorrosion three-phase asynchronous motor |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20101013 |