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CN101831555A - Method for producing artificial rich iron ore from nickel smelting waste slag by utilizing new sintering process - Google Patents

Method for producing artificial rich iron ore from nickel smelting waste slag by utilizing new sintering process Download PDF

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Publication number
CN101831555A
CN101831555A CN201010177843A CN201010177843A CN101831555A CN 101831555 A CN101831555 A CN 101831555A CN 201010177843 A CN201010177843 A CN 201010177843A CN 201010177843 A CN201010177843 A CN 201010177843A CN 101831555 A CN101831555 A CN 101831555A
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waste
iron
slag
nickel smelting
waste slag
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CN101831555B (en
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牛庆君
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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Abstract

The invention relates to a method for producing artificial rich iron ore for ironmaking from nickel smelting waste slag, in particular to a method for producing artificial rich iron ore from nickel smelting waste slag by utilizing a new sintering process. The method is characterized by comprising the following steps: a, pouring nickel smelting waste slag at 1100-1300 DEG C into a hot slag bag, shaking the bag for 5-15 minutes, and standing for 10-20 minutes; b, transferring the rest of the waste slag in the hot slag bag into another hot slag bag; c, adding a ferrous raw material into the hot slag bag filled with most of the waste slag, wherein the ferrous raw material accounts for 30-100 wt% of the waste slag in the hot slag bag; and d, pouring out the waste slag added with the ferrous raw material, and cooling. By fully utilizing the sensible heat produced by the emission of the nickel smelting waste slag, the method removes the impurities to purify the waste slag, recycles the ferrous metals and saves the heat energy, thereby obtaining the novel artificial rich iron ore product.

Description

Utilize nickel smelting waste slag to produce the method for artificial high-grad iron ore deposit by new sintering process
Technical field
The present invention relates to a kind ofly, especially utilize nickel smelting waste slag to produce the method for artificial high-grad iron ore deposit by new sintering process with the get rich method of iron ore of nickel smelting waste slag production ironmaking personnel selection.
Background technology
Nickel smelting waste slag is a kind of solid slag of discharging during the Metal smelting of non-ferrous metallurgical enterprise nickel is produced, a kind of iron and steel resource of uniqueness especially.Not only contain a large amount of ferrous metal (about 34%-45%), silicon-dioxide, calcium oxide, magnesium oxide in the nickel smelting waste slag, and also have metal such as minor amount of nickel, copper, cobalt, lead, zinc and non-metallic element sulphur etc., the nickel smelting waste slag of enormous amount is done the additive replacement iron ore for the cement mill except that a small amount of at present, and all the other are all fully developed.Temperature was at 1100 ℃-1300 ℃ when the pyrogenic process nickel smelting waste slag discharged in addition, and the sensible heat after the slag discharging is not utilized effectively, and has caused a large amount of thermal waste.
At present, reclaiming metal from nickel smelting waste slag has several different methods, and wherein commonly used have the hot method of charcoal, fuming process, electric dilution method, a flotation process etc., utilizes nickel smelting waste slag to reclaim ferrous metal, and also existing abroad proven technique technology is used for reference.But, to end up till now, these technical matters processing costs are generally too high, cause its economic benefit too poor, and especially aspect saving energy and reduce the cost, various economic targets are very poor, and therefore, these technology seldom are employed so far.
Iron and steel enterprise is the energy consumption rich and influential family, with traditional SINTERING PRODUCTION technology powdered iron ore is carried out agglomeration and become an indispensable important production process in the ferrous metallurgy industry, specifically be with various powdery iron-containing raw materials, allocate an amount of fuel and flux into, add an amount of water, on agglomerating plant, make material that a series of physicochemical change take place through mixing with after making ball, mineral powder granular is cohered caked process, wherein the sintering circuit energy consumption accounts for 10% in ton steel comprehensive energy consumption, be only second to the ironmaking operation, therefore, reduce the sintering circuit energy consumption, can effectively reduce a ton steel comprehensive energy consumption.
Summary of the invention
The purpose of this invention is to provide a kind of method of utilizing nickel smelting waste slag to produce artificial high-grad iron ore deposit by new sintering process, can provide a kind of approach that effectively utilizes to nickel smelting waste slag, the sensible heat that can also make full use of nickel smelting waste slag replaces conventional sintering fuel to carry out sintering process, thereby effectively saved the required energy consumption of sintering process, also avoided environmental pollution.
For achieving the above object, the technical solution used in the present invention is:
A kind of method of utilizing nickel smelting waste slag to produce artificial high-grad iron ore deposit by new sintering process is characterized in that, comprises the steps:
A, temperature is poured in the warm sludge bag at 1100-1300 ℃ nickel smelting waste slag, through leaving standstill 10-20 minute after 5-15 minute the shaking ladle vibration;
B, the showy slag that the waste the superiors in the warm sludge bag are accounted for waste cumulative volume 3-8% are partly removed, and keep the bottom slag part that waste orlop in the warm sludge bag accounts for waste cumulative volume 3-8%, and the rest part of waste in the warm sludge bag is transferred in another warm sludge bag;
C, add iron-bearing material in the above-mentioned warm sludge bag that most of waste is housed, the consumption of iron-bearing material is the 30-100% of waste gross weight in this warm sludge bag, stirs afterwards, and iron-bearing material is evenly melted in waste;
D, the waste that will add iron-bearing material are again poured out postcooling and are got final product.
Thereby the bottom slag that wherein the warm sludge bag orlop that keeps among the step b is accounted for waste cumulative volume 3-8% partly carries out remainder after the secondary ore dressing adds recycling in the waste among the step a.
Utilize its heat energy that stand-by iron-bearing material is carried out heating, drying to reduce moisture content and to increase temperature when wherein waste cools off in the steps d.
Wherein the iron-holder of iron-bearing material is 60-65%, and iron-bearing material is at least a in the smart powder of iron, iron scale and the high-grad iron ore deposit powder.
The waste that wherein will add iron-bearing material in the steps d pour into the mould internal cooling or cylinder iron machine carry out broken again after the ingot bar cooling, screening and finishing can be used.
The product of the inventive method can be directly used in iron-smelting raw material, the irony material in producing as iron alloy, and alternative agglomerate, oxide pellet, steel cuttings, iron scale, production cost is lower, and more energy-conserving and environment-protective are a kind of new ferriferous raw materials;
Sensible heat when the inventive method has made full use of the nickel smelting waste slag discharging to the waste purification and impurity removal, reclaims ferrous metal, save heat energy, thereby obtained a kind of novel artificial high-grad iron ore deposit product, the nickel smelting waste slag of serious environment pollution has been turned waste into wealth, turned harm into good, fully utilized resource to greatest extent, not only meet national industrial policies, and save energy, reduce and pollute, for energy-saving and emission-reduction, developing a circular economy has very big meaning.The experiment proved that, the enriched ore ferrous grade that the inventive method is produced can reach 49-55%, meet request of national standard, because wherein contain the minor amount of nickel metallic element and ordinary sinter ore deposit, acid pellet are compared, this product physical strength height, anti-knocking property are good, good permeability is particularly suitable as the raw material of ironmaking, stainless steel and weathering steel, and the working of a furnace of blast furnace, electric furnace is more smooth and easy, stable when using this raw material.Simultaneously, also can be used as the ferriferous raw material in the iron alloy production, result of use is better, more energy-conservation than effects such as ordinary oxygen pellet, steel cuttings, iron scales in ferrosilicon, ferromanganese, ferrochrome production, cost is lower.
Embodiment
The inventive method still is in molten state after being particularly suitable for smelting, and typical temperature is at 1100-1300 ℃ nickel smelting waste slag, if cooled waste then needs to reheat, its economic benefit obviously can obviously descend.After the showy slag that the warm sludge bag the superiors account for waste cumulative volume 3-8% among the step b is partly removed in addition, can make additive for the cement mill and replace iron ore to use.
Because the sintering circuit energy consumption accounts for 10% in ton steel comprehensive energy consumption, the inventive method has been saved this part energy consumption fully, the environmental pollutions such as flue dust of also having avoided this part operation to cause simultaneously.
In the inventive method iron-bearing material is added waste, the ferrous metasilicate alkalescence of molten state is increased relatively, acidity weakens, thus transition is a kind of people of hot-melting type (iron) mineral products of getting rich.
The iron-bearing material iron-holder of using in the inventive method is 60-65%, iron-bearing material is at least a in the smart powder of iron, iron scale and the high-grad iron ore deposit powder, the following examples provide the example of independent use above-mentioned raw materials respectively, but through evidence, any two or all three kinds in the above-mentioned raw materials also are suitable for the arbitrary proportion mixing.
Embodiment 1
A, temperature is poured in the warm sludge bag at 1200 ℃ nickel smelting waste slag, through leaving standstill 15 minutes after 10 minutes the shaking ladles vibration;
B, the showy slag that the warm sludge bag the superiors are accounted for waste cumulative volume 5% are partly removed, and keep the bottom slag part that warm sludge bag orlop accounts for waste cumulative volume 5%, and rest part in the warm sludge bag is transferred in another warm sludge bag;
C, to add iron-holder in the above-mentioned warm sludge bag that most of waste is housed be 62% the smart powder of iron, the consumption of the smart powder of iron be in this warm sludge bag the waste gross weight 50%, stir afterwards, iron essence powder is evenly melted in waste;
That d, the waste that will add the smart powder of iron are again poured into is broken again after the mould internal cooling, screening and finishing promptly can be used as the qualified artificial high-grad iron ore deposit of finished product and use.
Iron-bearing material adopts the smart powder of iron in the present embodiment, the bottom slag that the warm sludge bag orlop that keeps among the step b can be accounted for waste cumulative volume 5% partly carries out the secondary ore dressing in addition, obtain wherein more valuable metal, reuse in the waste among the remainder adding step a, if this part noble metal content more also can be abandoned certainly, can also recycle its heat energy that distributes when waste cools off in steps d stand-by iron-bearing material is carried out heating, drying to reduce moisture content and to increase temperature, the cold water of can also heating is hot water etc.
Embodiment 2
A, temperature is poured in the warm sludge bag at 1100 ℃ nickel smelting waste slag, through leaving standstill 10 minutes after 5 minutes the shaking ladles vibration;
B, the showy slag that the warm sludge bag the superiors are accounted for waste cumulative volume 3% are partly removed, and keep the bottom slag part that warm sludge bag orlop accounts for waste cumulative volume 3%, and rest part in the warm sludge bag is transferred in another warm sludge bag;
C, to add iron-holder in the above-mentioned warm sludge bag that most of waste is housed be 60% iron scale, and the consumption of iron scale be 30% of the interior waste gross weight of this warm sludge bag, stirs afterwards, and iron scale is evenly melted in waste;
D, will add iron scale again waste cylinder iron machine carry out broken again after the ingot bar cooling, screening and finishing and promptly can be used as the qualified artificial high-grad iron ore deposit of finished product and use.
Iron-bearing material adopts iron scale in the present embodiment, and the bottom slag that the warm sludge bag orlop that keeps among the step b can be accounted for waste cumulative volume 3% in addition partly carries out the secondary ore dressing, and rest part is identical with embodiment 1.
Embodiment 3
A, temperature is poured in the warm sludge bag at 1300 ℃ nickel smelting waste slag, through leaving standstill 20 minutes after 15 minutes the shaking ladles vibration;
B, the showy slag that the warm sludge bag the superiors are accounted for waste cumulative volume 8% are partly removed, and keep the bottom slag part that warm sludge bag orlop accounts for waste cumulative volume 8%, and rest part in the warm sludge bag is transferred in another warm sludge bag;
C, to add iron-holder in the above-mentioned warm sludge bag that most of waste is housed be 65% high-grad iron ore deposit powder, and the consumption of high-grad iron ore deposit powder be 100% of the interior waste gross weight of this warm sludge bag, stirs afterwards, and the high-grad iron ore deposit powder is evenly melted in waste;
D, will add the high-grad iron ore deposit powder again waste cylinder iron machine carry out broken again after the ingot bar cooling, screening and finishing and promptly can be used as the qualified artificial high-grad iron ore deposit of finished product and use.
Iron-bearing material adopts the high-grad iron ore deposit powder in the present embodiment, and the bottom slag that the warm sludge bag orlop that keeps among the step b can be accounted for waste cumulative volume 8% in addition partly carries out the secondary ore dressing, and rest part is identical with embodiment 1.

Claims (5)

1. a method of utilizing nickel smelting waste slag to produce artificial high-grad iron ore deposit by new sintering process is characterized in that, comprises the steps:
A, temperature is poured in the warm sludge bag at 1100-1300 ℃ nickel smelting waste slag, through leaving standstill 10-20 minute after 5-15 minute the shaking ladle vibration;
B, the showy slag that the waste the superiors in the warm sludge bag are accounted for waste cumulative volume 3-8% are partly removed, and keep the bottom slag part that waste orlop in the warm sludge bag accounts for waste cumulative volume 3-8%, and the rest part of waste in the warm sludge bag is transferred in another warm sludge bag;
C, add iron-bearing material in the above-mentioned warm sludge bag that most of waste is housed, the consumption of iron-bearing material is the 30-100% of waste gross weight in this warm sludge bag, stirs afterwards, and iron-bearing material is evenly melted in waste;
D, the waste that will add iron-bearing material are again poured out postcooling and are got final product.
2. the method for utilizing nickel smelting waste slag to produce artificial high-grad iron ore deposit by new sintering process as claimed in claim 1 is characterized in that: add recycling in the waste among the step a thereby the bottom slag that the warm sludge bag orlop that keeps among the step b accounts for waste cumulative volume 3-8% is partly carried out remainder after the secondary ore dressing.
3. the method for utilizing nickel smelting waste slag to produce artificial high-grad iron ore deposit by new sintering process as claimed in claim 1 is characterized in that: utilize its heat energy that stand-by iron-bearing material is carried out heating, drying to reduce moisture content and to increase temperature when wherein waste cools off in the steps d.
4. the method for utilizing nickel smelting waste slag to produce artificial high-grad iron ore deposit by new sintering process as claimed in claim 1, it is characterized in that: wherein the iron-holder of iron-bearing material is 60-65%, and iron-bearing material is at least a in the smart powder of iron, iron scale and the high-grad iron ore deposit powder.
5. the method for utilizing nickel smelting waste slag to produce artificial high-grad iron ore deposit by new sintering process as claimed in claim 1 is characterized in that: the waste that wherein will add iron-bearing material in the steps d pour into the mould internal cooling or cylinder iron machine carry out broken again after the ingot bar cooling, screening and finishing can be used.
CN2010101778430A 2010-05-20 2010-05-20 Method for producing artificial rich iron ore by using nickel smelting waste slag through sintering process Expired - Fee Related CN101831555B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102212711A (en) * 2011-06-08 2011-10-12 鞍山鑫普新材料有限公司 Method for treating hydrogen storage alloy waste residues
CN103667684A (en) * 2013-12-24 2014-03-26 云南文山斗南锰业股份有限公司 Block-shaping method for ore powder material

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001247922A (en) * 2000-03-03 2001-09-14 Nippon Mining & Metals Co Ltd Operating method of copper smelting furnace
JP2005330541A (en) * 2004-05-20 2005-12-02 Nippon Mining & Metals Co Ltd Dissolution treatment method of hydrous fine iron-containing material in copper PS converter
JP2007204826A (en) * 2006-02-03 2007-08-16 Nikko Kinzoku Kk Industrial waste melting process
CN101545042A (en) * 2009-02-09 2009-09-30 牛庆君 Method for producing microalloy ferro-silicon by using a ferrous metasilicate electric stove integral deoxidation and reduction

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001247922A (en) * 2000-03-03 2001-09-14 Nippon Mining & Metals Co Ltd Operating method of copper smelting furnace
JP2005330541A (en) * 2004-05-20 2005-12-02 Nippon Mining & Metals Co Ltd Dissolution treatment method of hydrous fine iron-containing material in copper PS converter
JP2007204826A (en) * 2006-02-03 2007-08-16 Nikko Kinzoku Kk Industrial waste melting process
CN101545042A (en) * 2009-02-09 2009-09-30 牛庆君 Method for producing microalloy ferro-silicon by using a ferrous metasilicate electric stove integral deoxidation and reduction

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102212711A (en) * 2011-06-08 2011-10-12 鞍山鑫普新材料有限公司 Method for treating hydrogen storage alloy waste residues
CN103667684A (en) * 2013-12-24 2014-03-26 云南文山斗南锰业股份有限公司 Block-shaping method for ore powder material
CN103667684B (en) * 2013-12-24 2016-04-20 云南文山斗南锰业股份有限公司 Ore powder becomes block method

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