CN101824332A - Comprehensive utilization production equipment for renewable energy sources of waste plastics, tires and waste engine oil - Google Patents
Comprehensive utilization production equipment for renewable energy sources of waste plastics, tires and waste engine oil Download PDFInfo
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- CN101824332A CN101824332A CN201010190012A CN201010190012A CN101824332A CN 101824332 A CN101824332 A CN 101824332A CN 201010190012 A CN201010190012 A CN 201010190012A CN 201010190012 A CN201010190012 A CN 201010190012A CN 101824332 A CN101824332 A CN 101824332A
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- 239000002699 waste material Substances 0.000 title claims abstract description 55
- 239000004033 plastic Substances 0.000 title claims abstract description 30
- 229920003023 plastic Polymers 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title abstract description 31
- 239000010705 motor oil Substances 0.000 title abstract description 11
- 239000003245 coal Substances 0.000 claims abstract description 28
- 238000005336 cracking Methods 0.000 claims abstract description 24
- 238000011084 recovery Methods 0.000 claims abstract description 11
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 75
- 239000003921 oil Substances 0.000 claims description 52
- 230000007613 environmental effect Effects 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 24
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- 238000010438 heat treatment Methods 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 230000006837 decompression Effects 0.000 claims description 13
- 238000004821 distillation Methods 0.000 claims description 13
- 239000000654 additive Substances 0.000 claims description 12
- 239000006229 carbon black Substances 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 11
- 238000001914 filtration Methods 0.000 claims description 10
- 239000000446 fuel Substances 0.000 claims description 10
- 238000003860 storage Methods 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 239000013043 chemical agent Substances 0.000 claims description 8
- 238000002485 combustion reaction Methods 0.000 claims description 8
- 239000010865 sewage Substances 0.000 claims description 8
- -1 tire Substances 0.000 claims description 8
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 239000011847 coal-based material Substances 0.000 claims description 6
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- 238000006297 dehydration reaction Methods 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 239000010410 layer Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000003786 synthesis reaction Methods 0.000 claims description 6
- 239000000428 dust Substances 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000292 calcium oxide Substances 0.000 claims description 4
- 235000012255 calcium oxide Nutrition 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 238000005261 decarburization Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 239000000295 fuel oil Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 239000000779 smoke Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 239000003738 black carbon Substances 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 239000002283 diesel fuel Substances 0.000 claims description 3
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 238000002309 gasification Methods 0.000 claims description 3
- 238000007689 inspection Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 239000011229 interlayer Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 239000003209 petroleum derivative Substances 0.000 claims description 3
- 239000002912 waste gas Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 230000017525 heat dissipation Effects 0.000 claims description 2
- 238000005191 phase separation Methods 0.000 claims description 2
- 238000007790 scraping Methods 0.000 claims description 2
- 239000010913 used oil Substances 0.000 claims 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 5
- 239000005864 Sulphur Substances 0.000 claims 5
- 239000000567 combustion gas Substances 0.000 claims 5
- 239000003292 glue Substances 0.000 claims 4
- 230000001939 inductive effect Effects 0.000 claims 3
- 230000001105 regulatory effect Effects 0.000 claims 3
- 238000003756 stirring Methods 0.000 claims 3
- 239000004615 ingredient Substances 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 239000003610 charcoal Substances 0.000 claims 1
- 235000019504 cigarettes Nutrition 0.000 claims 1
- 230000009977 dual effect Effects 0.000 claims 1
- 239000000796 flavoring agent Substances 0.000 claims 1
- 235000019634 flavors Nutrition 0.000 claims 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims 1
- 239000013502 plastic waste Substances 0.000 claims 1
- 239000013535 sea water Substances 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 238000013022 venting Methods 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 abstract description 14
- 239000011593 sulfur Substances 0.000 abstract description 14
- 238000010248 power generation Methods 0.000 abstract description 10
- 238000004064 recycling Methods 0.000 abstract description 9
- 238000000197 pyrolysis Methods 0.000 description 9
- 238000010586 diagram Methods 0.000 description 8
- 238000005262 decarbonization Methods 0.000 description 5
- 239000002893 slag Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000004061 bleaching Methods 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- 238000004227 thermal cracking Methods 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 230000002431 foraging effect Effects 0.000 description 2
- 238000007602 hot air drying Methods 0.000 description 2
- 239000000411 inducer Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000010920 waste tyre Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G1/00—Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general
- C01G1/10—Sulfates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
技术领域technical field
本发明公开一套废旧塑料、轮胎、废机油的再生能源综合利用生产装备,特别是该装备在全程的生产过程中所产生的各类物质直接通过设备的互联系统将所有剩余渣、气、水等全部造成具较大经济价值的产品。The invention discloses a set of production equipment for comprehensive utilization of renewable energy for waste plastics, tires, and waste engine oil. In particular, all kinds of substances produced by the equipment during the entire production process are directly converted to all remaining slag, gas, and water through the interconnection system of the equipment. All of these result in products with greater economic value.
背景技术Background technique
随着环保工业的持续发展,已将环保处理的实质应用日趋商业化方向,发展废旧塑料、轮胎、废机油的再生资源利用也趋向成熟,但是这些项目现时大部分都是在单一利用和发展,在再生利用过程中的剩余产物没有进行循环利用的全面思考。例如:以单一废旧塑料、轮胎炼油设备为例,大多数的设备基本没有考虑到真正的尾气环保处理,也没有考虑到热气回收再利用的课题,对于炼油的剩余物粗杂黑的安全环保处理更是轻描淡说或根本置于不理。在废旧塑料、轮胎炼油所产生的可燃气体(无毒气体),只是回炉燃烧,但是在实在生产中,当产生气体的时间与用于裂解炉的燃烧时间是两个概念,根本在气体回炉燃烧至裂解完成的这一时间内,气体的回烧量只有三分之二,剩余的可燃烧气体就只能向天排放,从上述所指出的环保再生设备,其实还是不环保的,可能再次造成二次污染问题,同时把大量有经济价值的可再利用资源白白浪费,的确是一种缺陷。本发明的再生能源综合利用生产装备,一般来说,包括有裂解催化炉,该裂解催化炉是卧式内置可顺逆旋转360度,并带自动随机刮壁式反应釜,如申请人在先申请的专利申请号为CN201010148298.2及CN201010147465.1的申请文件中所提到的反应釜刮壁器和与其配合的一种卧式废旧塑料、轮胎裂解炉;同时,该裂解炉体接有的尾气环保装置系统如申请人在先申请的专利申请号为CN201010168879.2的申请文件中提到的燃料裂解炉尾气处理系统;以及为了确保燃气安全运动而设置有附设双重水封安全装置的水洗器,具体结构在发明人在先申请且已授权的专利号为CN200510037543.1的申请文件中所提及;另外,该系统设备中用到的蒸馏催化塔的加热方式采用可控硅中频加热方法,具体结构在发明人直属子公司在先申请且已授权的专利号为CN200510101143.2的申请文件中所提及;该系统设备中用到的环保高能低硫煤系统具体使用方法在申请人在先申请的专利申请号为CN201010148172.5的申请文件中已经提及。With the continuous development of the environmental protection industry, the practical application of environmental protection treatment has become increasingly commercialized, and the development of recycled resource utilization of waste plastics, tires, and waste engine oil has also become mature. However, most of these projects are currently in the single use and development. The remaining products in the recycling process have not been fully considered for recycling. For example: Taking a single waste plastic and tire refining equipment as an example, most of the equipment basically did not consider the real exhaust gas environmental protection treatment, nor did it consider the issue of hot gas recovery and reuse, and the safety and environmental protection treatment of rough and black oil refining residues It is an understatement or simply ignored. The combustible gas (non-toxic gas) produced in waste plastics and tire oil refining is only returned to the furnace for combustion, but in actual production, the time when the gas is produced and the time used for the combustion of the cracking furnace are two concepts, and the gas is returned to the furnace for combustion. During the time until the cracking is completed, only two-thirds of the gas will burn back, and the remaining combustible gas can only be discharged to the sky. From the above-mentioned environmentally friendly regeneration equipment, it is actually not environmentally friendly, and may cause serious damage to the environment again. The problem of secondary pollution and the waste of a large amount of economically valuable reusable resources are indeed a defect. The production equipment for the comprehensive utilization of renewable energy of the present invention generally includes a cracking catalytic furnace, which is a horizontal built-in and can rotate 360 degrees forward and reverse, and is equipped with an automatic random wall scraping type reactor, as the applicant first The applied patent application number is CN201010148298.2 and CN201010147465.1 mentioned in the application documents of the reactor wall scraper and a kind of horizontal waste plastics and tire pyrolysis furnace matched with it; meanwhile, the pyrolysis furnace body is connected with Exhaust gas environmental protection device system, such as the fuel cracking furnace exhaust gas treatment system mentioned in the application document of the applicant's previous patent application number CN201010168879.2; and a water scrubber with a double water seal safety device in order to ensure the safe movement of gas , the specific structure is mentioned in the patent application document CN200510037543.1 that the inventor applied for earlier and has been authorized; in addition, the heating method of the distillation catalytic tower used in the system equipment adopts the silicon controlled medium frequency heating method, The specific structure is mentioned in the patent application document CN200510101143.2 which was first applied by the inventor's direct subsidiary company; The patent application number of the application is already mentioned in the application documents of CN201010148172.5.
发明内容Contents of the invention
本发明的目的在于解决现有再生环保设备的缺陷问题,而提供一整套废旧塑料、轮胎、废机油的再生资源综合利用的生产设备,该设备能够较充分的利用再生能源,使渣、水、气、热能循环发展利用,形成具有可观经济价值的循环环保生产链,大大改变了现有装备的单项功能。The purpose of the present invention is to solve the defects of the existing renewable environmental protection equipment, and provide a complete set of production equipment for the comprehensive utilization of renewable resources of waste plastics, tires, and waste engine oil. The circular development and utilization of gas and heat energy form a circular and environmentally friendly production chain with considerable economic value, which greatly changes the single function of existing equipment.
为实现上述目的,本发明采用了下述技术方案:To achieve the above object, the present invention adopts the following technical solutions:
这种废旧塑料、轮胎、废机油的再生能源综合利用生产装备,包括相互配合的主体设备、第二级装置、第三极装置、裂解炉尾气处理环保系统、可燃气体发电的再利用系统、热气回收系统以及环保高能低硫煤系统。This production equipment for the comprehensive utilization of renewable energy from waste plastics, tires, and waste engine oil includes the main equipment, the second-level device, the third-level device, the environmental protection system for the tail gas treatment of the pyrolysis furnace, the reuse system for combustible gas power generation, and the hot gas Recovery system and environmentally friendly high-energy low-sulfur coal system.
其中所述的主体设备包括:由输送带为起点,将石油产品废弃物输送到由路轨移动的气压式自动进料机,将原料推进裂解催化炉进行裂解催化得到油气混合物,该裂解催化炉带有一个自动随机设置的带有刮壁刀的反应釜,同时炉体接有裂解尾气环保装置系统,随之后级设备顺序为气蜡油分离器作为由裂解催化炉所产生油气里蜡油首次分离工具,再依次连接有第一级冷凝器、水封式气油分离器、水封安全装置、水封式负压装置、重油承载容器,当油气混合物经卧式冷凝器进入混合油承载容器,未能液化的可燃气体随之进入立式燃气中和水洗器),该水洗器附设双重水封安全装置,可燃气体经水洗器水洗后进入可燃气体发电的再利用系统。The main equipment mentioned therein includes: starting from the conveyor belt, the petroleum product waste is transported to the pneumatic automatic feeder moved by the rail, and the raw material is pushed into the cracking catalytic furnace for cracking and catalysis to obtain an oil-gas mixture. The cracking catalytic furnace belt There is a reaction kettle with a scraper that is automatically and randomly set, and the furnace body is connected with a pyrolysis tail gas environmental protection device system, and then the sequence of subsequent equipment is a gas wax oil separator as the first separation of wax oil in the oil and gas produced by the cracking catalytic furnace The tool is connected in turn with the first-stage condenser, water-sealed gas-oil separator, water-sealed safety device, water-sealed negative pressure device, and heavy oil holding container. When the oil-gas mixture enters the mixed oil holding container through the horizontal condenser, The unliquefied combustible gas then enters the vertical gas neutralization water washer), the water washer is equipped with a double water seal safety device, and the combustible gas enters the reuse system of combustible gas power generation after being washed by the water washer.
所述的第二级装置包括蒸馏催化塔,该设备的被蒸馏物来自于主体设备中的混合油承载容器中的混合油,蒸馏催化塔的加热方式采用可控硅中频加热方法,有一中频加热装置与蒸馏催化塔相连,当裂解后的废旧塑料油、轮胎油或者废机油进入蒸馏塔处理后根据各种物料的不同气化温度的切线进入立式冷凝器再经水封安全器,进入柴、汽油承载容器。The second-stage device includes a distillation catalytic tower. The distillate of this equipment comes from the mixed oil in the mixed oil holding container in the main equipment. The heating method of the distillation catalytic tower adopts a silicon controlled medium frequency heating method. There is an intermediate frequency heating The device is connected to the distillation catalytic tower. When the cracked waste plastic oil, tire oil or waste engine oil enters the distillation tower for treatment, it enters the vertical condenser according to the tangent of different gasification temperatures of various materials, and then passes through the water seal safety device, and then enters the diesel , Gasoline carrying container.
所述的第三级装置是柴油精练机汽油脱胶设备,该设备由第一级化学脱碳除杂合成器为起点,经除碳精漂器、脱蜡除胶器,所述第二级装置中的柴、汽油承载容器中的油品经输入管道进入该脱蜡除胶器,该脱蜡除胶器为圆桶锥形搅拌器,搅器内设有立向挡板,底部设有鼓动沸腾装置,搅拌流型以切流方式搅动;所需添加的化学剂装置设置于添加剂容器内,并分为化学剂添加区及碱性液体添加区,经处理后的有用物再输送到渣液分离机,该机滤目从200目至350目,经过滤过的流体输送到精炼油合成罐,该罐的工作形式分开二级过滤,第一级为逆向加压力过滤,第二级为顺向过滤,此二级的过滤层均设置有过滤介质承载孔板,其过滤介质为固体粒状物,被过滤物所要添加化学剂添加物置于添加剂容器内,经以上处理之后所得油品经检查合格后进入油库储存区,同时由各个精炼阶段所产生的废料由专用输送装置输送至环保高能低硫煤系统再利用,经各个精炼阶段所产生的废气、废味经专用排气管道通过水浴池及活性碳过滤器排出。The third-level device is a diesel refiner gasoline degumming equipment, which starts from the first-level chemical decarburization and impurity removal synthesizer, and through the carbon removal and fine bleaching device, the dewaxing and degumming device, the second-level device The oil in the diesel and gasoline carrying container enters the dewaxing and degumming device through the input pipeline. The dewaxing and degumming device is a drum-conical agitator with a vertical baffle inside the agitator and an agitator at the bottom. Boiling device, the agitation flow is agitated in a tangential flow mode; the chemical agent device to be added is set in the additive container, and is divided into a chemical agent addition area and an alkaline liquid addition area, and the treated useful substances are then transported to the slag liquid Separator, the filter mesh of this machine is from 200 mesh to 350 mesh, and the filtered fluid is sent to the refined oil synthesis tank. The working form of this tank is divided into two stages of filtration. Directional filtration, the secondary filter layer is equipped with a filter medium bearing orifice plate, the filter medium is solid granular matter, the chemical additives to be added to the filtered material are placed in the additive container, and the oil obtained after the above treatment is qualified by inspection After entering the oil depot storage area, at the same time, the waste generated by each refining stage is transported to the environmental protection high-energy low-sulfur coal system by a special conveying device for reuse. The waste gas and waste odor generated by each refining stage pass through the water bath and the Activated carbon filter exhaust.
所述的脱碳除杂合成器、除碳精漂器、脱蜡除胶器下端均连接废渣排除管道并采用压缩空气压送往环保高能低硫煤系统,在渣液分离机至精炼油合成罐之间同样设置有添加剂容器。The lower ends of the decarbonization and impurity removal synthesizer, decarbonization fine bleaching device, and dewaxing and degumming device are all connected to the waste residue removal pipeline and sent to the environmental protection high-energy low-sulfur coal system by compressed air pressure, and are synthesized from the slag-liquid separator to the refined oil Additive containers are likewise arranged between the tanks.
所述的裂解炉尾气处理环保装置系统与热裂解炉的排烟口相连,该系统包括有带多重水帘排气管道,该多重水帘排气管道的排气口连接炉体燃烧室,中间装有热气水缓冲室,缓冲室下部装有双重湿碳粒过滤器,另一端连接双塔型湿式气固分离器,气固分离器尾端由管道连接引风器,下端由管道连接引风器的后部分水管,引水管利用引风器的压力将水气推入设备尾部的烟囱,烟囱由三部分组成,下部为圆桶罐状体的水气分离器,中为用于气相分离的热交换器,上部为排气管道,该管道中部装有碱性水液喷淋器。The cracking furnace tail gas treatment environmental protection device system is connected with the smoke exhaust port of the thermal cracking furnace. The system includes an exhaust pipe with multiple water curtains. The exhaust port of the multiple water curtain exhaust pipes is connected to the combustion chamber of the furnace body. Equipped with a hot air water buffer chamber, the lower part of the buffer chamber is equipped with a double wet carbon particle filter, and the other end is connected to a double-tower wet gas-solid separator. The rear part of the water pipe, the water pipe uses the pressure of the air guide to push the water vapor into the chimney at the end of the equipment. The chimney is composed of three parts. The upper part of the heat exchanger is an exhaust pipe, and the middle part of the pipe is equipped with an alkaline water sprayer.
所述的可燃气体发电再利用系统连接于主体设备中的燃气管道,经专用燃气压缩机将燃气压缩到0.5MPA同时起到第一级燃气脱水作用时,再将气体送到第二级专用燃气压缩机,此压缩机再将燃气压缩至1MPA同时起到第二次燃气脱水作用时,将可燃气体送到燃气储存容器,储存器设置有两个出气口,一个出气口通往主体设备的热裂解炉作为该炉的燃料,其气体通过方法是经二次减压送出,第一次减压是经减压设备减压到0.4-0.5MPA,再经第二个减压设备由0.4-0.5MPA减至0.1-0.2MPA送到炉膛燃烧;另一个出气口通往气体燃料发电机(42),其可燃气体通过方法是经另一减压设备减压到0.1-0.5MPA后再进入气体燃料发电机,发电机采用机械内混方式。The combustible gas power generation and reuse system is connected to the gas pipeline in the main equipment, and the gas is compressed to 0.5MPA by a dedicated gas compressor and at the same time plays the role of dehydration of the first-stage gas, and then the gas is sent to the second-stage special gas Compressor, when this compressor compresses the gas to 1MPA and at the same time performs the second gas dehydration function, it sends the combustible gas to the gas storage container. The storage is equipped with two gas outlets, one of which leads to the heat of the main equipment The cracking furnace is used as the fuel of the furnace, and its gas is sent out through the second decompression. The first decompression is decompressed to 0.4-0.5MPA through the decompression equipment, and then the pressure is reduced from 0.4-0.5 MPA through the second decompression equipment. The MPA is reduced to 0.1-0.2MPA and sent to the furnace for combustion; the other gas outlet leads to the gas fuel generator (42), and its combustible gas passes through another decompression device to depressurize to 0.1-0.5MPA before entering the gas fuel Generator, generator adopts mechanical internal mixing method.
所述的热气回收系统由发电机工作运行所产生的炽热气体通过气-水交换器对热气收集,该气-水交换器采用导热管导热式,通过导热管以铜的传热系统1000倍以上导热至循环水中,热水经热泵送到风柜,再由风柜通过热空气输出管将120度以上的热空气送到环保高能低硫煤系统的烘干设备利用,所经过热交换的发电机热空气再经热交换器降温后,经烟气道排出。In the hot gas recovery system, the hot gas generated by the operation of the generator is collected through the gas-water exchanger. The gas-water exchanger adopts the heat conduction type of the heat conduction tube, and the heat transfer system of copper through the heat conduction tube is more than 1000 times The heat conducts to the circulating water, the hot water is sent to the wind cabinet by the heat pump, and then the hot air above 120 degrees is sent by the wind cabinet to the drying equipment of the environmental protection high-energy low-sulfur coal system through the hot air output pipe. The machine-heated air is then cooled by the heat exchanger and then discharged through the flue gas channel.
所述的导热管道是若干真空热导管,在真空导热管一端设置有金属散热轮,在相邻真空热导管之间设置有烟水隔层以及保温层,所述的气-水交换器一端设置有热气引入管以及消声器,底部设置有碳尘清洁口,并在设置热气引入管的一端设置有污水排放口,以及循环热水管用以连接热泵与气-水热交换器,所述的热交换器设置于气-水热交换器的相对设置污水排放口另一端,该热交换器上下端设置有循环冷水出口,上端设置有循环冷水入口,同时该端通过设置有循环热水管与风柜相连。The heat conduction pipes are a plurality of vacuum heat pipes, a metal cooling wheel is arranged at one end of the vacuum heat conduction pipes, a smoke-water interlayer and an insulation layer are arranged between adjacent vacuum heat pipes, and one end of the air-water exchanger is arranged There is a hot gas introduction pipe and a muffler, a carbon dust cleaning port is provided at the bottom, and a sewage discharge port is provided at one end of the hot gas introduction pipe, and a circulating hot water pipe is used to connect the heat pump and the air-water heat exchanger. The heat exchange The air-water heat exchanger is installed at the opposite end of the sewage discharge port. The upper and lower ends of the heat exchanger are provided with a circulating cold water outlet, and the upper end is provided with a circulating cold water inlet. At the same time, this end is provided with a circulating hot water pipe and a wind cabinet. connected.
所述的环保高能低硫煤系统将废塑料、废轮胎、炼油过程中所不能气化的余渣即粗黑碳再利用,包括有将粗碳黑进行陈化的人工陈化器,再经热蒸气处理器处理,再将处理过的粗炭黑作为主料,在其中添加配伍物料,配伍材料为原煤、二茂铁、六次甲基四铵、氢氧化钠、生石灰和黏结剂,形成煤基料,其中主料在煤基料中所占的重量百分比为45%-60%;然后将煤基料制成成品煤,所述的粗碳黑通过地搅龙及碳黑输入带输送。The environment-friendly high-energy low-sulfur coal system reuses waste plastics, waste tires, and the residue that cannot be gasified during the oil refining process, that is, coarse black carbon. It includes an artificial aging device for aging coarse carbon black, and then Treated in a hot steam processor, and then use the treated coarse carbon black as the main material, add compatible materials to it, the compatible materials are raw coal, ferrocene, hexamethylenetetraammonium, sodium hydroxide, quicklime and binder to form Coal-based material, wherein the weight percentage of the main material in the coal-based material is 45%-60%; then the coal-based material is made into finished coal, and the coarse carbon black is conveyed by the ground auger and the carbon black input belt .
通过上述技术方案从而该发明具有下述有益效果:Thus the invention has the following beneficial effects through the above technical scheme:
将现有设备的单项性进行整合,相对现有单项技术的单一环保生产概念来说,能够有效杜绝环保生产后的剩余物对土地及空气环境造成的二次污染,或者是因为单一环保方式生产前的更具危害性的污染;本发明的系统装备是一组循环环保生产及再利用设备,从第一次的环保生产到剩余渣物及有害气体、高温气体再作第二次的环保生产再利用,能够起到真正废弃物环保生产循环经济链,可能达到或达到无污水排放、无烟尘排放、无室温排放、无有害气体排放、无恶臭、无刺激性气味排放、噪音低、自产能源循环利用的良好的有益效果。Integrating the individuality of the existing equipment, compared with the single environmental protection production concept of the existing single technology, can effectively prevent the secondary pollution of the land and air environment caused by the residue after the environmental protection production, or because of the single environmental protection mode of production The more harmful pollution before; the system equipment of the present invention is a group of circular environmental protection production and recycling equipment, from the first environmental protection production to the remaining slag, harmful gas and high temperature gas for the second environmental protection production Reuse can play a real circular economic chain of waste environmental protection production, which may achieve or achieve no sewage discharge, no smoke and dust discharge, no room temperature discharge, no harmful gas discharge, no foul smell, no irritating odor discharge, low noise, self-produced Good beneficial effect of energy recycling.
附图说明Description of drawings
图1为本这种废旧塑料、轮胎、废机油的再生能源综合利用生产装备整体图。Figure 1 is an overall diagram of the production equipment for the comprehensive utilization of renewable energy such as waste plastics, tires, and waste engine oil.
图2为图1中主体设备的主体视图。FIG. 2 is a front view of the main device in FIG. 1 .
图3图2中主体设备的另一视图。Figure 3 Another view of the main device in Figure 2.
图4A是图1反应釜的截面图。FIG. 4A is a cross-sectional view of the reactor shown in FIG. 1 .
图4B是与图4A配合的裂解炉图。Fig. 4B is a cracking furnace diagram coordinated with Fig. 4A.
图5为第三级装置是柴油精练机汽油脱胶设备图。Fig. 5 is a diagram of gasoline degumming equipment for a diesel refiner in the third stage.
图6为裂解炉尾气处理环保装置系统图。Figure 6 is a system diagram of an environmental protection device for cracking furnace tail gas treatment.
图7为图6中烟囱图。Figure 7 is a diagram of the chimney in Figure 6 .
图8为热气回收系统图。Figure 8 is a diagram of the hot gas recovery system.
图9为可燃气体发电再利用系统图。Fig. 9 is a diagram of a combustible gas power generation and reuse system.
图10为环保高能低硫煤系统图。Figure 10 is a system diagram of environmentally friendly high-energy low-sulfur coal.
具体实施方式Detailed ways
下面结合附图对本发明作出进一步的说明。The present invention will be further described below in conjunction with the accompanying drawings.
如图1至图10所示,这种废旧塑料、轮胎、废机油的再生能源综合利用生产装备,包括相互配合的主体设备、第二级装置、第三极装置、裂解炉尾气处理环保系统、可燃气体发电的再利用系统、热气回收系统以及环保高能低硫煤系统。As shown in Figures 1 to 10, the production equipment for the comprehensive utilization of renewable energy for waste plastics, tires, and waste engine oil includes cooperating main equipment, second-level devices, third-level devices, cracking furnace tail gas treatment environmental protection systems, Combustible gas power generation reuse system, hot gas recovery system, and environmentally friendly high-energy low-sulfur coal system.
其中所述的主体设备包括:由输送带2为起点,将石油产品废弃物输送到由路轨移动的气压式自动进料机1,将原料推进裂解催化炉3进行裂解催化得到油气混合物,该裂解催化炉带有一个自动随机设置的带有刮壁刀4的反应釜5,同时炉体接有裂解尾气环保装置系统,随之后级设备顺序为气蜡油分离器6作为由裂解催化炉所产生油气里蜡油首次分离工具,再依次连接有第一级冷凝器7、水封式气油分离器8、水封安全装置9、水封式负压装置10、重油承载容器11,当油气混合物经卧式冷凝器12进入混合油承载容器13,未能液化的可燃气体随之进入立式燃气中和水洗器14,该水洗器附设双重水封安全装置15,可燃气体经水洗器水洗后进入可燃气体发电的再利用系统。The main equipment described therein includes: starting from the conveyor belt 2, the petroleum product waste is transported to the pneumatic
所述的第二级装置包括蒸馏催化塔16,该设备的被蒸馏物来自于主体设备中的混合油承载容器13中的混合油,蒸馏催化塔的加热方式采用可控硅中频加热方法,有一中频加热装置17与蒸馏催化塔相连,当裂解后的废旧塑料油、轮胎油或者废机油进入蒸馏塔处理后根据各种物料的不同气化温度的切线进入立式冷凝器18再经水封安全器19,进入柴、汽油承载容器20。The second-stage device includes a distillation
所述的第三级装置是柴油精练机汽油脱胶设备,该设备由第一级化学脱碳除杂合成器21为起点,经除碳精漂器22、脱蜡除胶器23,所述第二级装置中的柴、汽油承载容器11中的油品经输入管道进入该脱蜡除胶器,该脱蜡除胶器为圆桶锥形搅拌器,搅器内设有立向挡板,底部设有鼓动沸腾装置,搅拌流型以切流方式搅动;所需添加的化学剂装置设置于添加剂容器24内,并分为化学剂添加区及碱性液体添加区,经处理后的有用物再输送到渣液分离机25,该机滤目从200目至350目,经过滤过的流体输送到精炼油合成罐26,该罐的工作形式分开二级过滤,第一级为逆向加压力过滤,第二级为顺向过滤,此二级的过滤层均设置有过滤介质承载孔板,其过滤介质为固体粒状物,被过滤物所要添加化学剂添加物置于添加剂容器24内,经以上处理之后所得油品经检查合格后进入油库储存区,同时由各个精炼阶段所产生的废料由专用输送装置输送至环保高能低硫煤系统再利用,经各个精炼阶段所产生的废气、废味经专用排气管道通过水浴池及活性碳过滤器排出。Described tertiary device is diesel oil refiner gasoline degumming equipment, and this equipment is starting point by first-stage chemical decarburization and
所述的脱碳除杂合成器21、除碳精漂器22、脱蜡除胶器23下端均连接废渣排除管道49并采用压缩空气50压送往环保高能低硫煤系统,在渣液分离机至精炼油合成罐26之间同样设置有添加剂容器24。The lower ends of the decarbonization and
所述的裂解炉尾气处理环保装置系统与热裂解炉的排烟口相连,该系统包括有带多重水帘排气管道27,该多重水帘排气管道的排气口连接炉体燃烧室,中间装有热气水缓冲室28,缓冲室下部装有双重湿碳粒过滤器29,另一端连接双塔型湿式气固分离器30,气固分离器尾端由管道连接引风器31,下端由管道连接引风器的后部分水管,引水管利用引风器的压力将水气推入设备尾部的烟囱32,烟囱由三部分组成,下部为圆桶罐状体的水气分离器33,中为用于气相分离的热交换器34,上部为排气管道35,该管道中部装有碱性水液喷淋器36。Described pyrolysis furnace tail gas treatment environmental protection device system is connected with the exhaust outlet of thermal cracking furnace, and this system includes the
所述的可燃气体发电再利用系统连接于主体设备中的燃气管道37,经专用燃气压缩机将燃气压缩到0.5MPA同时起到第一级燃气脱水作用时,再将气体送到第二级专用燃气压缩机38,此压缩机再将燃气压缩至1MPA同时起到第二次燃气脱水作用时,将可燃气体送到燃气储存容器39,储存器设置有两个出气口,一个出气口通往主体设备的热裂解炉作为该炉的燃料,其气体通过方法是经二次减压送出,第一次减压是经减压设备40减压到0.4-0.5MPA,再经第二个减压设备41由0.4-0.5MPA减至0.1-0.2MPA送到炉膛燃烧;另一个出气口通往气体燃料发电机42,其可燃气体通过方法是经另一减压设备减压到0.1-0.5MPA后再进入气体燃料发电机,发电机采用机械内混方式。The combustible gas power generation and reuse system is connected to the
所述的热气回收系统由发电机42工作运行所产生的炽热气体通过气-水交换器43对热气收集,该气-水交换器采用导热管导热式,通过导热管51以铜的传热系统1000倍以上导热至循环水中,热水经热泵44送到风柜45,再由风柜通过热空气输出管62将120度以上的热空气送到环保高能低硫煤系统的烘干设备利用,所经过热交换的发电机热空气再经热交换器46降温后,经烟气道63排出。In the hot gas recovery system, the hot gas generated by the
所述的导热管道是若干真空热导管51,在真空导热管一端设置有金属散热枪54,在相邻真空热导管之间设置有烟水隔层55以及保温层64,所述的气-水交换器43一端设置有热气引入管52以及消声器53,底部设置有碳尘清洁口56,并在设置热气引入管的一端设置有污水排放口57,以及循环热水管58用以连接热泵44与气-水热交换器43,所述的热交换器46设置于气-水热交换器的相对设置污水排放口另一端,该热交换器上下端设置有循环冷水出口59,上端设置有循环冷水入口60,同时该端通过设置有循环热水管61与风柜相连。The heat conduction pipes are several
所述的环保高能低硫煤系统将废塑料、废轮胎、炼油过程中所不能气化的余渣即粗黑碳再利用,包括有将粗碳黑进行陈化的人工陈化器47,再经热蒸气处理器48处理,再将处理过的粗炭黑作为主料,在其中添加配伍物料,配伍材料为原煤、二茂铁、六次甲基四铵、氢氧化钠、生石灰和黏结剂,形成煤基料,其中主料在煤基料中所占的重量百分比为45%-60%;然后将煤基料制成成品煤,所述的粗碳黑通过地搅龙64及碳黑输入带65输送。The environment-friendly high-energy low-sulfur coal system reuses waste plastics, waste tires, and residues that cannot be gasified during the oil refining process, that is, coarse black carbon, and includes an artificial aging
在具体的生产利用过程中,第一阶段,将含水量40%的废旧塑料经热空气烘干设备烘干后,含水量减少为20%,其热空气来源于图8热气回收系统,具体收集工作由热能收集器66进行处理,经烘干后的废旧塑料经输送带源源不断送入热裂解炉3,送料量为14吨(以两条炉计算),从加热开始至裂解完成,所用燃油1100Kg,附加材料为铝、锌及氧化钙等催化剂,其比例为所加入原料去水分后重量的平均1.5%,设备用电为336度,生产周期时间为28小时,生产气、柴油混合油11.62吨,裂解剩余物即粗炭黑为60Kg,此粗炭黑连同在热裂解炉的尾气环保处理系统所收的湿碳粉送至高能低硫煤生产系统作再利用处理,同时通过炼油过程中所产生的可燃气体约872m3,此可燃气Co20-24%、二氧化碳Co21-3%、氢气H28-12%、CmHn主要为甲烷3-4.2%等,该可燃气经清洁除焦油及压缩送入燃气储存容器39作为燃气发电用途。In the specific production and utilization process, in the first stage, after the waste plastics with a water content of 40% are dried by hot air drying equipment, the water content is reduced to 20%. The hot air comes from the hot air recovery system in Figure 8, and the specific collection The work is processed by the
第二阶段,经过裂解后的混合油进入第二级装置,该系统日处理量为14吨,该装置的加热工具为可控硅中频加热设备110KW,将生产的气、柴油混合油切线后所需用电750度。In the second stage, the cracked mixed oil enters the second-stage device. The daily processing capacity of the system is 14 tons. The heating tool of the device is a 110KW thyristor intermediate frequency heating equipment. Need electricity 750 degrees.
第三阶段,经第二级装置处理后,将馏分中的柴、汽油送入精炼装置处理,经清洁、除味、脱色、脱胶、脱蜡等工序,所得柴、汽油的总量为10.67吨,柴油经处理合成后可到达国II标准,汽油为93#汽油,在处理过程中的剩余物经碱化处理,利用全密封的输送工具一般为管道送入高能低硫煤生产系统作再利用处理。In the third stage, after being treated by the second-stage device, the diesel and gasoline in the distillate are sent to the refining device for processing. After cleaning, deodorization, decolorization, degumming, dewaxing and other processes, the total amount of diesel and gasoline obtained is 10.67 tons , Diesel oil can reach National II standard after treatment and synthesis. Gasoline is 93# gasoline. The residues in the processing process are alkalized and sent to the high-energy low-sulfur coal production system for reuse by using fully sealed transportation tools. deal with.
第四阶段,由燃气储存容器输出的可燃气体经减压后进入内混式燃气发电机,具体可采用济南柴油发电机厂500KW/h产品,上述经所述的第二阶段处理后的872m3可燃气可发电3925度,在发电过程中产生的热气经热回收再利用系统换成热空气,连同热裂解炉的尾气处理剩余热水热换成热空气联合送入第一阶段中起始的热空气烘干设备再用。In the fourth stage, the combustible gas output from the gas storage container enters the internal mixing gas generator after decompression. Specifically, the 500KW/h product of Jinan Diesel Generator Factory can be used. The 872m 3 of the above-mentioned second stage treatment The combustible gas can generate electricity at 3925 degrees. The hot gas generated during the power generation process is converted into hot air through the heat recovery and reuse system, and the remaining hot water from the tail gas treatment of the pyrolysis furnace is converted into hot air and sent to the initial stage of the first stage. Hot air drying equipment for reuse.
本实施以废旧塑料炼油为例,凡有与之原理和基本结构与本实施例相同或近似的,均在本发明保护范围之内。This implementation takes oil refining of waste plastics as an example, and all those with the same or similar principle and basic structure as this embodiment are within the protection scope of the present invention.
与现有技术相比,将现有设备的单项性进行整合,相对现有单项技术的单一环保生产概念来说,能够有效杜绝环保生产后的剩余物对土地及空气环境造成的二次污染,或者是因为单一环保方式生产前的更具危害性的污染;本发明的系统装备是一组循环环保生产及再利用设备,从第一次的环保生产到剩余渣物及有害气体、高温气体再作第二次的环保生产再利用,能够起到真正废弃物环保生产循环经济链,可能达到或达到无污水排放、无烟尘排放、无室温排放、无有害气体排放、无恶臭、无刺激性气味排放、噪音低、自产能源循环利用的良好的有益效果。Compared with the existing technology, the individuality of the existing equipment is integrated, compared with the single environmental protection production concept of the existing single technology, it can effectively prevent the secondary pollution caused by the residue after the environmental protection production to the land and air environment, Or because of the more harmful pollution before the production of a single environmental protection method; the system equipment of the present invention is a group of recycling environmental protection production and recycling equipment, from the first environmental protection production to the recycling of residual slag and harmful gases and high-temperature gases For the second environmental protection production reuse, it can play a real circular economic chain of waste environmental protection production, and may achieve or achieve no sewage discharge, no smoke and dust discharge, no room temperature discharge, no harmful gas discharge, no foul smell, no irritating smell Good beneficial effects of emission, low noise, self-generated energy recycling.
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