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CN101685842B - Optoelectronic semiconductor device - Google Patents

Optoelectronic semiconductor device Download PDF

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CN101685842B
CN101685842B CN 200810165854 CN200810165854A CN101685842B CN 101685842 B CN101685842 B CN 101685842B CN 200810165854 CN200810165854 CN 200810165854 CN 200810165854 A CN200810165854 A CN 200810165854A CN 101685842 B CN101685842 B CN 101685842B
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contact
semiconductor device
opto
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conversion system
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CN101685842A (en
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沈建赋
钟健凯
洪详竣
叶慧君
柯淙凯
林安茹
欧震
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Epistar Corp
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Abstract

An optoelectronic semiconductor device according to an embodiment of the present invention includes an energy conversion system for converting between optical energy and electrical energy, the energy conversion system having a first side; the contact layer is formed on the first side of the energy conversion system and comprises an outer boundary and at least one ohmic contact region, wherein ohmic contact can be formed between the ohmic contact region and the energy conversion system; and two or more discrete regions integrated with the contact layer to form at least one pattern on the energy conversion system.

Description

光电半导体装置Optoelectronic semiconductor device

技术领域 technical field

本发明涉及一种光电半导体装置,尤其关于一种具有接触层与不连续区的光电半导体装置,以及与不连续区相关的图案布局。The present invention relates to an optoelectronic semiconductor device, in particular to an optoelectronic semiconductor device having a contact layer and a discontinuous region, and a pattern layout related to the discontinuous region.

背景技术 Background technique

已知发光二极管的一种结构包含生长基板、n型半导体层、p型半导体层、与位于此二半导体层间的发光层。用以反射源自于发光层光线的反射层会选择性地形成于此结构中。为提高发光二极管的光学、电学、及力学特性的至少其一,一种经适当选择后的材料会用以替代生长基板以作为承载除生长基板外的其他结构的载体,例如:金属或硅可用于取代生长氮化物的蓝宝石基板。生长基板可使用蚀刻、研磨、或激光移除等方式移除。然而,生长基板亦可能被全部或仅部分保留并与载体结合。此外,透光氧化物亦可整合于发光二极管结构中以提升电流分散表现。A known structure of a light-emitting diode includes a growth substrate, an n-type semiconductor layer, a p-type semiconductor layer, and a light-emitting layer between the two semiconductor layers. A reflective layer for reflecting light from the light-emitting layer is optionally formed in the structure. In order to improve at least one of the optical, electrical, and mechanical properties of the light-emitting diode, a properly selected material will be used to replace the growth substrate as a carrier for carrying other structures except the growth substrate, for example: metal or silicon can be used In place of sapphire substrates grown on nitrides. The growth substrate can be removed by etching, grinding, or laser removal. However, it is also possible that the growth substrate is fully or only partially retained and bound to the carrier. In addition, light-transmitting oxides can also be integrated into the LED structure to improve current spreading performance.

本案申请人的第I237903号中国台湾专利中披露一种高发光效率的发光元件100。如图1所示,发光元件100的结构包含蓝宝石基板110、氮化物缓冲层120、n型氮化物半导体叠层130、氮化物多重量子阱发光层140、p型氮化物半导体叠层150、及氧化物透明导电层160。另外,并在p型氮化物半导体叠层150面向氧化物透明导电层160的表面上形成六角锥孔穴构造1501。六角锥孔穴构造1501的内表面较易与如氧化铟锡(ITO)、氧化镉锡、氧化锑锡、氧化铟锌、氧化锌铝、与氧化锌锡等的氧化物透明导电层160形成欧姆接触。因此,发光元件100的顺向电压得以维持于一个较低的水准,且通过六角锥孔穴构造1501也可提升光摘出效率。The Taiwan Patent No. I237903 of the applicant of this case discloses a light-emitting element 100 with high luminous efficiency. As shown in FIG. 1, the structure of the light-emitting element 100 includes a sapphire substrate 110, a nitride buffer layer 120, an n-type nitride semiconductor stack 130, a nitride multiple quantum well light-emitting layer 140, a p-type nitride semiconductor stack 150, and Oxide transparent conductive layer 160 . In addition, a hexagonal pyramid hole structure 1501 is formed on the surface of the p-type nitride semiconductor stack 150 facing the oxide transparent conductive layer 160 . The inner surface of the hexagonal pyramid hole structure 1501 is more likely to form an ohmic contact with an oxide transparent conductive layer 160 such as indium tin oxide (ITO), cadmium tin oxide, antimony tin oxide, indium zinc oxide, zinc aluminum oxide, and zinc tin oxide. . Therefore, the forward voltage of the light emitting device 100 can be maintained at a low level, and the light extraction efficiency can also be improved through the hexagonal pyramid hole structure 1501 .

ITO可通过电子束蒸镀法(Electron Beam Evaporation)或溅镀法(Sputtering)形成于六角锥孔穴构造1501、半导体层或其二者之上。不同制造方式所形成的ITO层所表现出的光学、电学特性、或其二者也可能不尽相同,相关文献可参阅本案申请人的第096111705号中国台湾专利申请案,并援引其为本申请案的一部分。在扫描式电子显微镜(Scanning ElectronMicroscope;SEM)之下,以电子束蒸镀法形成的ITO颗粒1601并未完全填满六孔锥孔穴1501,而呈现出诸多存在于ITO颗粒间的空隙,如图2所示。此些空隙可能使光线被局限其中无法脱离发光元件,而逐渐被周围的ITO所吸收。亦或者因此些空隙中所存在具有小于ITO折射系数的介质,如空气,使得进入ITO的光线会在材料边界处遭遇全反射而无法离开ITO层,而逐渐为ITO所吸收。ITO can be formed on the hexagonal pyramid hole structure 1501, the semiconductor layer or both by electron beam evaporation or sputtering. The optical, electrical properties, or both of the ITO layers formed by different manufacturing methods may also be different. For relevant documents, please refer to the No. 096111705 Taiwan Patent Application of the applicant in this case, and quote it as the present application part of the case. Under the scanning electron microscope (Scanning Electron Microscope; SEM), the ITO particles 1601 formed by the electron beam evaporation method do not completely fill the six-hole cone holes 1501, but present many gaps between the ITO particles, as shown in the figure 2. These voids may make the light confined therein unable to leave the light-emitting element, and gradually absorbed by the surrounding ITO. Or because there is a medium with a refractive index smaller than ITO in these gaps, such as air, the light entering ITO will encounter total reflection at the material boundary and cannot leave the ITO layer, and will be gradually absorbed by ITO.

由C.H.Kuo等于公元2004年在Materials Science and Engineering B所提出”Nitride-based near-ultraviolet LEDs with an ITO transparent contact”一文中曾针对ITO的透射率(transmittance)与波长间的关系进行研究。其发现当波长约低于420nm时,ITO透射率有急遽下降的趋势,在350nm时甚至可能低于70%。对于蓝光波段,ITO具有高于80%的透射率,但是,在近紫外光或紫外光波段的透射率却不尽理想。In the article "Nitride-based near-ultraviolet LEDs with an ITO transparent contact" proposed by C.H.Kuo et al. in Materials Science and Engineering B in 2004, the relationship between the transmittance of ITO and the wavelength was studied. It found that when the wavelength is lower than about 420nm, the transmittance of ITO tends to drop sharply, and may even be lower than 70% at 350nm. For the blue light band, ITO has a transmittance higher than 80%, but the transmittance in the near ultraviolet or ultraviolet band is not ideal.

由是,ITO等透明氧化物作为半导体发光元件常用的材料,对于元件的光学与电学表现上仍有许多的改善空间。Therefore, transparent oxides such as ITO are commonly used materials for semiconductor light-emitting devices, and there is still much room for improvement in the optical and electrical performance of the devices.

发明内容 Contents of the invention

依据本发明一实施例的一种光电半导体装置包括一能量转换系统,可进行光能与电能间的转换,其中能量转换系统包含一第一接触区及一第二接触区;一第一材料区块,形成于能量转换系统的第一接触区之上,并对于一特定光波长可穿透;及一第二材料区块,形成于能量转换系统的第二接触区之上;其中,第一材料区块与第一接触区间的电阻小于第二材料区块与第二接触区间的电阻。An optoelectronic semiconductor device according to an embodiment of the present invention includes an energy conversion system capable of converting light energy to electrical energy, wherein the energy conversion system includes a first contact area and a second contact area; a first material area a block formed on the first contact region of the energy conversion system and transparent to a specific wavelength of light; and a second material block formed on the second contact region of the energy conversion system; wherein the first The resistance between the material block and the first contact region is smaller than the resistance between the second material block and the second contact region.

上述光电半导体装置的其他诸优选实施例如下:光电半导体装置中的第一接触区包括一六角锥型孔穴。光电半导体装置中的第一接触区包括一与第一材料区块形成欧姆接触的表面。光电半导体装置中的第一材料区块与第二材料区块形成为一图案化配置。光电半导体装置中的第二接触区包括一绝缘材。Other preferred embodiments of the optoelectronic semiconductor device described above are as follows: the first contact region in the optoelectronic semiconductor device includes a hexagonal pyramid hole. The first contact region in the optoelectronic semiconductor device includes a surface forming an ohmic contact with the first material block. The first material block and the second material block in the optoelectronic semiconductor device are formed into a patterned configuration. The second contact region in the optoelectronic semiconductor device includes an insulating material.

依据本发明另一实施例的一种光电半导体装置,包括一能量转换系统,用以进行光能与电能间的转换,此能量转换系统具有一第一侧;一接触层,形成于能量转换系统的第一侧,并包括一外边界及至少一欧姆接触区,其中欧姆接触区与能量转换系统间可形成欧姆接触;及二或多个不连续区,与接触层相整合而形成至少一图案于能量转换系统之上。An optoelectronic semiconductor device according to another embodiment of the present invention includes an energy conversion system for converting light energy and electrical energy, the energy conversion system has a first side; a contact layer is formed on the energy conversion system and comprising an outer boundary and at least one ohmic contact region, wherein an ohmic contact can be formed between the ohmic contact region and the energy conversion system; and two or more discontinuous regions integrated with the contact layer to form at least one pattern on the energy conversion system.

上述光电半导体装的其他诸优选实施例如下:Other preferred embodiments of the above-mentioned optoelectronic semiconductor device are as follows:

光电半导体装置的不连续区包括几何、材料、物理特性、及化学特性中至少其一的不连续。或者,不连续区包括一种结构,其在一表面的任一方向上显现出可辨识的一重复性特征。此重复性特征的型态包括定周期、变周期、及准周期(quasiperodicity)中至少其一。或者,不连续区包括一种不规则表面结构。或者,不连续区的尺寸小于或等于一电流分散距离。A discontinuity of an optoelectronic semiconductor device includes a discontinuity in at least one of geometric, material, physical, and chemical properties. Alternatively, a discontinuity comprises a structure that exhibits a recognizable, recurring feature in either direction on a surface. The type of the repetitive feature includes at least one of constant periodicity, variable periodicity, and quasiperodicity. Alternatively, the discontinuity includes an irregular surface structure. Alternatively, the size of the discontinuity is less than or equal to a current spreading distance.

光电半导体装置中的接触层包括氧化铟锡。The contact layer in the optoelectronic semiconductor device comprises indium tin oxide.

光电半导体装置中的欧姆接触区包括至少一凹陷空间,其几何形状包括角锥、圆锥、与平头截体中至少其一。或者,欧姆接触区包括至少一斜面与一平面,其中斜面能与能量转换系统形成较平面为佳的欧姆接触。或者,斜面能与能量转换系统形成欧姆接触,平面不能与能量转换系统形成欧姆接触。或者,斜面能与能量转换系统形成欧姆接触,平面能与能量转换系统形成非欧姆接触或肖特基接触。The ohmic contact area in the optoelectronic semiconductor device includes at least one recessed space, the geometry of which includes at least one of pyramid, cone, and frustum. Alternatively, the ohmic contact region includes at least one slope and a plane, wherein the slope can form better ohmic contact with the energy conversion system than the plane. Alternatively, the inclined plane can form ohmic contact with the energy conversion system, and the flat surface cannot form ohmic contact with the energy conversion system. Alternatively, the sloped surface can form an ohmic contact with the energy conversion system, and the flat surface can form a non-ohmic or Schottky contact with the energy conversion system.

光电半导体装置中较接近外边界的欧姆接触区具有较大的接触面积。或者,欧姆接触区形成于能量转换系统的一外表面上。Ohmic contact regions closer to the outer boundaries in optoelectronic semiconductor devices have larger contact areas. Alternatively, the ohmic contact region is formed on an outer surface of the energy conversion system.

光电半导体装置中的不连续区的至少部分与能量转换系统间不具有欧姆接触区。或者,光电半导体装置中的不连续区中至少其一包括一填充质。At least part of the discontinuity in the optoelectronic semiconductor device has no ohmic contact with the energy conversion system. Alternatively, at least one of the discontinuities in the optoelectronic semiconductor device includes a filler.

光电半导体装置中的能量转换系统包括一过渡层。或者,光电半导体装置还包括一电性接点接近能量转换系统,并与接触层形成电接触。The energy conversion system in an optoelectronic semiconductor device includes a transition layer. Alternatively, the optoelectronic semiconductor device further includes an electrical contact close to the energy conversion system and in electrical contact with the contact layer.

附图说明 Description of drawings

图1显示本案申请人的第I237903号中国台湾专利中所披露的一种高发光效率的发光元件;Figure 1 shows a light-emitting element with high luminous efficiency disclosed in No. I237903 Taiwan Patent of the applicant of this case;

图2为显示扫描式电子显微镜(Scanning Electron Microscope;SEM)下,以电子束蒸镀法形成的ITO颗粒于六孔锥孔穴中的照片;Figure 2 is a photo showing the ITO particles formed by electron beam evaporation in the six-hole cone hole under the scanning electron microscope (Scanning Electron Microscope; SEM);

图3为显示依据本发明一实施例的光电半导体装置的示意图;3 is a schematic diagram showing an optoelectronic semiconductor device according to an embodiment of the present invention;

图4为显示依据本发明一实施例的光电半导体装置的示意图;4 is a schematic diagram showing an optoelectronic semiconductor device according to an embodiment of the present invention;

图5(a)-(c)为显示依据本发明一实施例的光电半导体装置的部分结构的示意图;5(a)-(c) are schematic diagrams showing a partial structure of an optoelectronic semiconductor device according to an embodiment of the present invention;

图6(a)-(c)为显示依据本发明一实施例的光电半导体装置的部分结构的示意图;6(a)-(c) are schematic diagrams showing a partial structure of an optoelectronic semiconductor device according to an embodiment of the present invention;

图7(a)-(c)为显示依据本发明一实施例的光电半导体装置的部分结构的示意图;7(a)-(c) are schematic diagrams showing a partial structure of an optoelectronic semiconductor device according to an embodiment of the present invention;

图8(a)-(c)为显示依据本发明一实施例的光电半导体装置的部分结构的示意图;8(a)-(c) are schematic diagrams showing a partial structure of an optoelectronic semiconductor device according to an embodiment of the present invention;

图9(a)、(b)为显示依据本发明一实施例的光电半导体装置的部分结构的示意图;9(a), (b) are schematic diagrams showing a partial structure of an optoelectronic semiconductor device according to an embodiment of the present invention;

图10(a)-(c)为显示依据本发明一实施例的光电半导体装置的部分结构的示意图;10(a)-(c) are schematic diagrams showing a partial structure of an optoelectronic semiconductor device according to an embodiment of the present invention;

图11(a)、(b)为显示依据本发明一实施例的光电半导体装置的部分结构的俯视图;11(a), (b) are top views showing a partial structure of an optoelectronic semiconductor device according to an embodiment of the present invention;

图12(a)、(b)为显示依据本发明一实施例的光电半导体装置的部分结构的俯视图;12(a), (b) are top views showing a partial structure of an optoelectronic semiconductor device according to an embodiment of the present invention;

图13为显示依据本发明一实施例的光电半导体装置的接触层的俯视图;13 is a top view showing a contact layer of an optoelectronic semiconductor device according to an embodiment of the present invention;

图14为显示依据本发明一实施例的光电半导体装置的接触层的俯视图;及14 is a top view showing a contact layer of an optoelectronic semiconductor device according to an embodiment of the present invention; and

图15为显示依据本发明一实施例的光电半导体装置的接触层的俯视图。15 is a top view showing a contact layer of an optoelectronic semiconductor device according to an embodiment of the present invention.

附图标记说明Explanation of reference signs

10   光电半导体装置    163  外边界10 optoelectronic semiconductor device 163 outer boundary

11   基板              164  开口11 base plate 164 opening

12   过渡层            165  电流阻障区12 Transition layer 165 Current blocking area

13   第一电性层        17   第二电性接点13 The first electrical layer 17 The second electrical contact

14   转换部            171  根部14 conversion part 171 root

15   第二电性层        172  支部15 second electrical layer 172 branch

151  欧姆接触区        173  端部151 ohm contact area 173 end

152  绝缘区            18   第一电性接点152 Insulation area 18 First electrical contact

153  平台              100  发光元件153 platform 100 light emitting element

16   接触层            110  蓝宝石基板16 Contact layer 110 Sapphire substrate

161  不连续区          120  氮化物缓冲层161 Discontinuous region 120 Nitride buffer layer

1611 不连续区          130  n型氮化物半导体叠层1611 discontinuous region 130 n-type nitride semiconductor stack

1612 不连续区          140  氮化物多重量子阱发光层1612 discontinuous region 140 nitride multiple quantum well light-emitting layer

1613 不连续区          150  p型氮化物半导体叠层1613 discontinuous region 150 p-type nitride semiconductor stack

1614 不连续区          1501 六角锥孔穴构造1614 Discontinuous zone 1501 Hexagonal cone cavity structure

1615 不连续区          160  氧化物透明导电层1615 discontinuous region 160 oxide transparent conductive layer

1616 不连续区          1601 ITO颗粒1616 Discontinuous zone 1601 ITO particles

162  填充质162 filler

具体实施方式 Detailed ways

以下配合图示说明本发明的实施例。Embodiments of the present invention are described below with illustrations.

如图3所示的光电半导体装置10包含一个形成于基板11上的半导体系统。半导体系统包含可以进行或诱发光电能转换的半导体元件、装置、产品、电路、或应用。具体而言,半导体系统包含发光二极管(Light-Emitting Diode;LED)、激光二极管(Laser Diode;LD)、太阳能电池(Solar Cell)、液晶显示器(Liquid Crystal Display)、有机发光二极管(Organic Light-EmittingDiode)中至少其一。在本说明书中“半导体系统”一词并非限制该系统内所有次系统或单元皆以半导体材料制成,其他非半导体材料,例如:金属、氧化物、绝缘体等皆可选择性地整合于此半导体系统之中。The optoelectronic semiconductor device 10 shown in FIG. 3 comprises a semiconductor system formed on a substrate 11 . A semiconductor system includes a semiconductor component, device, product, circuit, or application that can perform or induce photoelectric energy conversion. Specifically, semiconductor systems include light-emitting diodes (Light-Emitting Diode; LED), laser diodes (Laser Diode; LD), solar cells (Solar Cell), liquid crystal displays (Liquid Crystal Display), organic light-emitting diodes (Organic Light-Emitting Diode) ) at least one of. The term "semiconductor system" in this specification does not limit all subsystems or units in the system to be made of semiconductor materials, and other non-semiconductor materials, such as: metals, oxides, insulators, etc., can be selectively integrated in this semiconductor in the system.

在本发明的一实施例中,半导体系统最少包含一第一电性层13、一转换部14、以及一第二电性层15。第一电性层13及一第二电性层15中彼此至少二个部分的电性、极性或掺杂物相异、或者分别用以提供电子与空穴的材料单层或多层(“多层”指二层或二层以上,以下同。)若第一电性层13及一第二电性层15由半导导体材料构成,则其电性选择可以为p型、n型、及i型中至少任意二者的组合。转换部14位于第一电性层13及第二电性层15之间,为电能与光能可能发生转换或被诱发转换的区域。电能转变或诱发光能者如发光二极管、液晶显示器、有机发光二极管;光能转变或诱发电能者如太阳能电池、光电二极管。In an embodiment of the present invention, the semiconductor system at least includes a first electrical layer 13 , a conversion portion 14 , and a second electrical layer 15 . At least two parts of the first electrical layer 13 and a second electrical layer 15 have different electrical properties, polarities or dopants, or are used to provide electrons and holes respectively in a single layer or multiple layers ( "Multilayer" refers to two or more layers, the same below.) If the first electrical layer 13 and a second electrical layer 15 are made of semiconductor materials, the electrical selection can be p-type or n-type , and a combination of at least any two of type i. The conversion portion 14 is located between the first electrical layer 13 and the second electrical layer 15 , and is a region where electrical energy and light energy may be converted or induced to be converted. Those that convert electrical energy or induce light energy such as light-emitting diodes, liquid crystal displays, and organic light-emitting diodes; those that convert light energy or induce electrical energy such as solar cells and photodiodes.

以发光二极管而言,转换后光的发光频谱可以通过改变半导体系统中一层或多层的物理或化学配置进行调整。常用的材料如磷化铝镓铟(AlGaInP)系列、氮化铝镓铟(AlGaInN)系列、氧化锌(ZnO)系列等。转换部14的结构如:单异质结构(single heterostructure;SH)、双异质结构(doubleheterostructure;DH)、双侧双异质结构(double-side double heterostructure;DDH)、或多层量子阱(multi-quantum well;MQW)。再者,调整量子阱的对数亦可以改变发光波长。In the case of light-emitting diodes, the emission spectrum of the converted light can be adjusted by changing the physical or chemical configuration of one or more layers in the semiconductor system. Commonly used materials include aluminum gallium indium phosphide (AlGaInP) series, aluminum gallium indium nitride (AlGaInN) series, zinc oxide (ZnO) series, and the like. The structure of the conversion part 14 is such as: single heterostructure (single heterostructure; SH), double heterostructure (double heterostructure; DH), double-side double heterostructure (double-side double heterostructure; DDH), or multilayer quantum well ( multi-quantum well; MQW). Furthermore, adjusting the logarithm of the quantum wells can also change the emission wavelength.

基板11为用以生长或承载半导体系统,适用的材料包含但不限于锗(Ge)、砷化镓(GaAs)、铟化磷(InP)、蓝宝石(Sapphire)、碳化硅(SiC)、硅(Si)、铝酸锂(LiAlO2)、氧化锌(ZnO)、氮化镓(GaN)、氮化铝(AlN)、玻璃、复合材料(Composite)、钻石、CVD钻石、与类钻碳(Diamond-LikeCarbon;DLC)等。The substrate 11 is used to grow or carry semiconductor systems, applicable materials include but not limited to germanium (Ge), gallium arsenide (GaAs), indium phosphorus (InP), sapphire (Sapphire), silicon carbide (SiC), silicon ( Si), lithium aluminate (LiAlO 2 ), zinc oxide (ZnO), gallium nitride (GaN), aluminum nitride (AlN), glass, composite materials (Composite), diamond, CVD diamond, and diamond-like carbon (Diamond-like carbon (Diamond -LikeCarbon; DLC) and more.

基板11与半导体系统之间更可选择性地包含一过渡层12。过渡层12介于二种材料系统之间,使基板的材料系统“过渡”至半导体系统的材料系统。对发光二极管的结构而言,一方面,过渡层12例如缓冲层(Buffer Layer)等用以降低二种材料间晶格不匹配的材料层。另一方面,过渡层12亦可以是用以结合二种材料或二个分离结构的单层、多层或结构,其可选用的材料如:有机材料、无机材料、金属、及半导体等;其可选用的结构如:反射层、导热层、导电层、欧姆接触(ohmic contact)层、抗形变层、应力释放(stressrelease)层、应力调整(stress adjustment)层、接合(bonding)层、波长转换层、及机械固定构造等。A transition layer 12 may optionally be included between the substrate 11 and the semiconductor system. The transition layer 12 is interposed between the two material systems, so as to "transition" the material system of the substrate to the material system of the semiconductor system. For the structure of the light emitting diode, on the one hand, the transition layer 12 such as a buffer layer (Buffer Layer) is a material layer used to reduce the lattice mismatch between the two materials. On the other hand, the transition layer 12 can also be a single layer, multi-layer or structure used to combine two materials or two separate structures, and its optional materials are such as: organic materials, inorganic materials, metals, and semiconductors; Optional structures such as: reflective layer, thermal conductive layer, conductive layer, ohmic contact layer, anti-deformation layer, stress release layer, stress adjustment layer, bonding layer, wavelength conversion layer, and mechanical fixing structure, etc.

第二电性层15上更可选择性地形成一接触层16。接触层16设置于第二电性层15远离转换部14的一侧。具体而言,接触层16可以为光学层、电学层、或其二者的组合。光学层可以改变来自于或进入转换部14的电磁辐射或光线。在此所称的“改变”指改变电磁辐射或光的至少一种光学特性,前述特性包含但不限于频率、波长、强度、通量、效率、色温、演色性(renderingindex)、光场(light field)、及可视角(angle of view)。电学层可以使得接触层16的任一组相对侧间的电压、电阻、电流、电容中至少其一的数值、密度、分布发生变化或有发生变化的趋势。接触层16的构成材料包含氧化物、导电氧化物、透明氧化物、具有50%或以上透射率的氧化物、金属、相对透光金属、具有50%或以上透射率的金属、有机质、无机质、荧光物、磷光物、陶瓷、半导体、掺杂的半导体、及无掺杂的半导体中至少其一。在某些应用中,接触层16的材料为氧化铟锡、氧化镉锡、氧化锑锡、氧化铟锌、氧化锌铝、与氧化锌锡中至少其一。若为相对透光金属,其厚度约为0.005μm~0.6μm,或0.005μm~0.5μm,或0.005μm~0.4μm,或0.005μm~0.3μm,或0.005μm~0.2μm,或0.2μm~0.5μm,或0.3μm~0.5μm,或0.4μm~0.5μm,或0.2μm~0.4μm,或0.2μm~0.3μm。A contact layer 16 can be optionally formed on the second electrical layer 15 . The contact layer 16 is disposed on a side of the second electrical layer 15 away from the converting portion 14 . Specifically, the contact layer 16 may be an optical layer, an electrical layer, or a combination of both. The optical layer may modify electromagnetic radiation or light coming from or entering the conversion portion 14 . "Change" as used herein refers to changing at least one optical characteristic of electromagnetic radiation or light, the aforementioned characteristics including but not limited to frequency, wavelength, intensity, flux, efficiency, color temperature, color rendering (rendering index), light field (light field) field), and angle of view (angle of view). The electrical layer may cause the value, density, distribution, or tendency to change of at least one of voltage, resistance, current, and capacitance between any set of opposite sides of the contact layer 16 . The constituent materials of the contact layer 16 include oxides, conductive oxides, transparent oxides, oxides with a transmittance of 50% or more, metals, relatively transparent metals, metals with a transmittance of 50% or more, organic substances, and inorganic substances. , at least one of phosphors, phosphors, ceramics, semiconductors, doped semiconductors, and undoped semiconductors. In some applications, the material of the contact layer 16 is at least one of indium tin oxide, cadmium tin oxide, antimony tin oxide, indium zinc oxide, zinc aluminum oxide, and zinc tin oxide. If it is a relatively light-transmitting metal, its thickness is about 0.005 μm to 0.6 μm, or 0.005 μm to 0.5 μm, or 0.005 μm to 0.4 μm, or 0.005 μm to 0.3 μm, or 0.005 μm to 0.2 μm, or 0.2 μm to 0.5 μm μm, or 0.3 μm to 0.5 μm, or 0.4 μm to 0.5 μm, or 0.2 μm to 0.4 μm, or 0.2 μm to 0.3 μm.

在某些情况下第二电性层15之上可以形成欧姆接触区151。第二电性层15与接触层16若经由欧姆接触区151直接或间接接触,其间可能形成欧姆接触,或者使得光电半导体装置10的驱动电压(driving voltage)、阈值电压(threshold voltage)及正向电压(forward voltage)中至少其一下降。欧姆接触区151的可能型态为凹陷或凸起。凹陷如图3的欧姆接触区151所例示;凸起如图4的欧姆接触区151所例示。凹陷空间的可能几何形状为角锥、圆锥、平头截体、柱体、圆柱、半球形、不规则体或其任意组合。凸起的可能几何形状为角锥、圆锥、平头截体、柱体、圆柱、半球形、不规则体或其任意组合。此外,欧姆接触区151除如图所示般皆由单一或近似的凸起或凹陷所构成,但并未排除其亦可能由凸起与凹陷的组合所构成。在一特定实施例中,凸起、凹陷空间、或其组合为六角锥。接触层16与欧姆接触区151相接触的至少一部分形成欧姆接触。角锥上的斜面所具有的特定晶格方向或表面能态为造成欧姆接触或较低位能障的可能原因之一。另一方面,第二电性层15表面上未形成欧姆接触区151的部分与接触层16间可能会形成较差的欧姆接触、非欧姆接触、或肖特基(Schottky)接触,然而此部分与接触层16间并不排除有形成欧姆接触的可能。欧姆接触区151的可能形成背景以及某些实施方式可参考本案申请人的第I237903号中国台湾专利,其并援引为本申请案的一部分。In some cases, an ohmic contact region 151 may be formed on the second electrical layer 15 . If the second electrical layer 15 and the contact layer 16 are in direct or indirect contact via the ohmic contact region 151, an ohmic contact may be formed therebetween, or the driving voltage (driving voltage), threshold voltage (threshold voltage) and forward direction of the optoelectronic semiconductor device 10 may be At least one of the forward voltages drops. The possible shape of the ohmic contact region 151 is concave or convex. The depression is illustrated as the ohmic contact area 151 of FIG. 3 ; the protrusion is illustrated as the ohmic contact area 151 of FIG. 4 . The possible geometric shapes of the concave space are pyramids, cones, frustums, cylinders, cylinders, hemispheres, irregular bodies or any combination thereof. Possible geometries for the protrusions are pyramids, cones, frustums, cylinders, cylinders, hemispheres, irregulars or any combination thereof. In addition, the ohmic contact region 151 is formed of a single or similar protrusion or depression as shown in the figure, but it is not excluded that it may also be formed of a combination of protrusions and depressions. In a specific embodiment, the protrusions, the recessed spaces, or a combination thereof are hexagonal pyramids. At least a portion of the contact layer 16 in contact with the ohmic contact region 151 forms an ohmic contact. The specific lattice orientation or surface energy state of the inclined planes on the pyramid is one of the possible reasons for the ohmic contact or lower potential energy barrier. On the other hand, poor ohmic contact, non-ohmic contact, or Schottky (Schottky) contact may be formed between the portion of the surface of the second electrical layer 15 where the ohmic contact region 151 is not formed and the contact layer 16, but this portion The possibility of forming an ohmic contact with the contact layer 16 is not excluded. For the possible formation background of the ohmic contact region 151 and some implementation methods, please refer to the Taiwan Patent No. I237903 of the applicant of the present application, which is incorporated as a part of the present application.

除连续的单层或多层外,接触层16可以为不连续或具有图案的单层或多层。相关专利可参阅本案申请人的第096111705号中国台湾专利申请案,并援引其为本申请案的一部分。“不连续”指几何、材料、物理性质、及化学性质中至少其一的不连续。几何不连续指长度、厚度、深度、宽度、周期、外部形状、及内部结构至少其一的不连续。材料不连续指密度、组成、浓度、及制造方式至少其一的不连续。物理性质不连续指电学、光学、热力、及力学性质中至少其一的不连续。化学性质不连续指掺杂物、活性、酸性、及碱性中至少其一的不连续。如图3及图4中所示,接触层16上形成有不连续区161。若为材料不连续,不连续区161中的材料可能无法与第二电性层15、欧姆接触区151或其二者形成欧姆接触。不连续区161的光学性质亦可能与接触层16相异。光学性质如透射率、折射率、与反射率。通过选择适当的不连续区161材料可以提高离开或进入转换部14的能量流或光强度。例如,不连续区161为空气缺口,来自于转换部14的光线可以经由此空气缺口在不被接触层16吸收之下离开光电半导体装置10。若第一电性层13、转换部14、及第二电性层15至少其一上形成有规则图形结构、不规则图形结构、粗糙化结构、光子晶体、或其任何组合亦可能提高由不连续区161进出的能量流或光强度。如图3与图4所示,若与不连续区161相接触的第二电性层15的材料具有较大的折射率,欧姆接触区151可能破坏光线在此折射率介面处的全反射而提高不连续区161的光摘出。In addition to being a continuous single or multiple layers, the contact layer 16 may be discontinuous or patterned as a single or multiple layers. For relevant patents, please refer to the No. 096111705 Taiwan patent application of the applicant of this case, and quote it as a part of this application. "Discontinuity" refers to a discontinuity in at least one of geometric, material, physical, and chemical properties. Geometric discontinuity refers to a discontinuity in at least one of length, thickness, depth, width, period, external shape, and internal structure. A material discontinuity refers to a discontinuity in at least one of density, composition, concentration, and manufacturing method. A physical property discontinuity refers to a discontinuity in at least one of electrical, optical, thermal, and mechanical properties. A discontinuity in chemical properties refers to a discontinuity of at least one of dopant, activity, acidity, and alkalinity. As shown in FIGS. 3 and 4 , a discontinuous region 161 is formed on the contact layer 16 . If the material is discontinuous, the material in the discontinuous region 161 may not form an ohmic contact with the second electrical layer 15 , the ohmic contact region 151 or both. The optical properties of the discontinuity 161 may also differ from those of the contact layer 16 . Optical properties such as transmittance, refraction, and reflectance. The energy flow or light intensity leaving or entering the conversion portion 14 can be enhanced by selecting an appropriate material for the discontinuity 161 . For example, the discontinuity region 161 is an air gap through which light from the converting portion 14 can leave the optoelectronic semiconductor device 10 without being absorbed by the contact layer 16 . If at least one of the first electrical layer 13, the conversion portion 14, and the second electrical layer 15 is formed with a regular pattern structure, an irregular pattern structure, a roughened structure, a photonic crystal, or any combination thereof, the Energy flow or light intensity into and out of the continuum 161 . As shown in FIG. 3 and FIG. 4, if the material of the second electrical layer 15 in contact with the discontinuous region 161 has a relatively large refractive index, the ohmic contact region 151 may destroy the total reflection of light at this refractive index interface and cause The light extraction of the discontinuity 161 is improved.

若光电半导体装置10为如图3或图4所示的结构,在第二电性层15或接触层16之上可选择性地形成一第二电性接点17,在第一电性层13上可以选择性地形成一第一电性接点18。电性接点为单层或多层的结构,并为光电半导体装置10与外部线路电性相连的介面。电性接点可以通过接线(wiring)与外部线路相连,或直接固着于外部线路之上。If the optoelectronic semiconductor device 10 has the structure shown in Figure 3 or Figure 4, a second electrical contact 17 can be selectively formed on the second electrical layer 15 or the contact layer 16, and a A first electrical contact 18 can be selectively formed on the top. The electrical contact is a single-layer or multi-layer structure, and is an interface for electrically connecting the optoelectronic semiconductor device 10 with external circuits. The electrical contact can be connected to the external circuit through wiring, or directly fixed on the external circuit.

此外,电性接点亦可设置于光电半导体装置10的其他侧。例如,第一电性接点18可设置于第一电性层13、过渡层12、或基板11之下,或设置于第一电性层、过渡层12、及基板11中至少其一的侧面。换言之,第一电性接点18与第二电性接点17分别位于彼此相对或垂直的表面上。在又一实施例中,第二电性接点17可设置于第二电性层的侧面。于再一实施例中,第一电性接点17、第二电性接点18、或其二者可通过穿孔、绝缘材料、或其二者设置于第一电性层、过渡层12、或基板11的侧或表面。In addition, electrical contacts can also be arranged on other sides of the optoelectronic semiconductor device 10 . For example, the first electrical contact 18 may be disposed under the first electrical layer 13, the transition layer 12, or the substrate 11, or disposed on the side of at least one of the first electrical layer, the transition layer 12, and the substrate 11. . In other words, the first electrical contact 18 and the second electrical contact 17 are respectively located on surfaces facing each other or perpendicular to each other. In yet another embodiment, the second electrical contact 17 may be disposed on the side of the second electrical layer. In yet another embodiment, the first electrical contact 17, the second electrical contact 18, or both can be disposed on the first electrical layer, the transition layer 12, or the substrate through through holes, insulating materials, or both. 11 side or surface.

以下介绍电性接点、欧姆接触区与不连续区的数种实施例。图示中虽以第二电性层15与第二电性接点17为例,但并不排除以下实施例亦可以适用于第一电性层13与第一电性接点18,或其他种类的光电半导体装置。Several embodiments of electrical contacts, ohmic contact regions and discontinuous regions are introduced below. Although the illustration takes the second electrical layer 15 and the second electrical contact 17 as an example, it does not exclude that the following embodiments can also be applied to the first electrical layer 13 and the first electrical contact 18, or other types of Optoelectronic semiconductor devices.

如图5所示,接触层16形成于第二电性层15之上,第二电性接点17形成于接触层16之上,不连续区161分布于第二电性接点17的周围。其分布方式当以使来自于电性接点17的电流尽可能地侧向流动至接触层16的外缘,或使得电性接点17下方与接触层16外缘间的电流密度差值百分比小于60%、50%、40%、30%、20%、或10%。例如,电性接点下方的电流密度为xA/cm2,接触层16外缘的电流密度为yA/cm2,其电流密度差值百分比为|x-y|/(x与y中较大者)%。As shown in FIG. 5 , the contact layer 16 is formed on the second electrical layer 15 , the second electrical contact 17 is formed on the contact layer 16 , and the discontinuous area 161 is distributed around the second electrical contact 17 . Its distribution method should make the current from the electrical contact 17 flow laterally to the outer edge of the contact layer 16 as much as possible, or make the current density difference between the lower part of the electrical contact 17 and the outer edge of the contact layer 16 less than 60% %, 50%, 40%, 30%, 20%, or 10%. For example, the current density below the electrical contact is xA/cm 2 , the current density at the outer edge of the contact layer 16 is yA/cm 2 , and the percentage difference in current density is |xy|/(the larger of x and y)% .

图5(a)披露二种不连续区161的型态,此二种型态可以并存或独自存在。第二电性接点17右侧的接触层16未与不连续区161重叠;第二电性接点17左侧的接触层16则与不连续区161重叠,且接触层16与第二电性层15间存在有第三种物质或结构。具体而言,不连续区161或第三种物质或结构为例如空气、氧化物等绝缘材,或相对于接触层为非良导体,或布拉格反射镜(Bragg reflector)、与抗反射(anti-reflection)层。此外,第三种物质的折射系数可以介于第二电性层15与接触层16之间。第二电性接点17下方的接触层16、第二电性层15、转换部14、第一电性层13、过渡层12、及基板11中至少其一更可以选择性地形成绝缘区152以使来自于第二电性接点17的电流向外分散。然而,图示中绝缘区152的位置仅为例示,非用以限制本发明的实施方式。第二电性接点17下方的接触层16、绝缘区152、或其二者约等于或略大于第二电性接点17的尺寸,其中,第二电性接点17下方的接触层16尺寸指位于第二电性接点17周围或下方不连续区161所包围的最小虚拟圆的直径。如图5(b)所示,第二电性接点17埋入接触层16之中。如图5(c)所示,第二电性接点17埋入接触层16之中,且电性接点17与接触层16相接触的任一表面上形成为规则表面结构、不规则表面结构、或其二者以增加电性接点17与接触层16间的接触面积。例如,电性接点17与接触层16间的接触面171形成为粗糙面以增加彼此间的接触面积。较大的接触面积或可增加电性接点17的结构稳固性,或可允许更多的电流通过。FIG. 5( a ) discloses two types of discontinuous regions 161 , and these two types can coexist or exist independently. The contact layer 16 on the right side of the second electrical contact 17 does not overlap the discontinuous region 161; the contact layer 16 on the left side of the second electrical contact 17 overlaps the discontinuous region 161, and the contact layer 16 overlaps the second electrical layer There is a third substance or structure in 15. Specifically, the discontinuous region 161 or the third substance or structure is an insulating material such as air or oxide, or is a poor conductor relative to the contact layer, or a Bragg reflector (Bragg reflector), and an anti-reflection (anti- reflection) layer. In addition, the refractive index of the third substance may be between the second electrical layer 15 and the contact layer 16 . At least one of the contact layer 16 , the second electrical layer 15 , the conversion portion 14 , the first electrical layer 13 , the transition layer 12 , and the substrate 11 below the second electrical contact 17 can optionally form an insulating region 152 In order to disperse the current from the second electrical contact 17 outward. However, the position of the insulating region 152 in the figure is only an example, and is not intended to limit the implementation of the present invention. The contact layer 16 below the second electrical contact 17, the insulating region 152, or both are approximately equal to or slightly larger than the size of the second electrical contact 17, wherein the size of the contact layer 16 below the second electrical contact 17 refers to The diameter of the smallest virtual circle surrounded by the discontinuous area 161 around or below the second electrical contact 17 . As shown in FIG. 5( b ), the second electrical contact 17 is buried in the contact layer 16 . As shown in Figure 5(c), the second electrical contact 17 is embedded in the contact layer 16, and any surface of the electrical contact 17 in contact with the contact layer 16 is formed into a regular surface structure, an irregular surface structure, Or both to increase the contact area between the electrical contact 17 and the contact layer 16 . For example, the contact surface 171 between the electrical contact 17 and the contact layer 16 is formed as a rough surface to increase the contact area between them. A larger contact area may increase the structural stability of the electrical contact 17 or allow more current to pass through.

图6(a)~图6(c)披露另一种电性接点的配置型态,其中不连续区161的配置或实施方式请参考图5的相关说明。第二电性接点17直接形成于第二电性层15之上,换言之,在电性接点17与第二电性层15间没有接触层16。电性接点17与接触层16、第二电性层15、或其二者相接触的任一表面上形成为规则表面结构、不规则表面结构、或其二者以增加电性接点17与其他部分间的接触面积。较大的接触面积或可增加电性接点17的结构稳固性,或可允许更多的电流通过。第二电性接点17下方更可以形成绝缘区152。绝缘区152约等于或略大于第二电性接点17的尺寸。FIG. 6( a ) to FIG. 6( c ) disclose another configuration of electrical contacts, and for the configuration or implementation of the discontinuous region 161 , please refer to the related description of FIG. 5 . The second electrical contact 17 is directly formed on the second electrical layer 15 , in other words, there is no contact layer 16 between the electrical contact 17 and the second electrical layer 15 . The electrical contact 17 is formed into a regular surface structure, an irregular surface structure, or both on any surface that is in contact with the contact layer 16, the second electrical layer 15, or both to increase the contact between the electrical contact 17 and other surfaces. contact area between parts. A larger contact area may increase the structural stability of the electrical contact 17 or allow more current to pass through. An insulating region 152 can be further formed under the second electrical contact 17 . The insulating region 152 is approximately equal to or slightly larger than the size of the second electrical contact 17 .

图7披露依据本发明的另一种实施例的光电半导体装置。在本实施例中,不连续区161中包含填充质162以填充一或多个欧姆接触区151中的至少部分空间。通过调整欧姆接触区151中填充质162分布的图案可以改变来自于或进入转换部14的电磁辐射或光线的光学特性、电学特性、或其二者。填充质162如绝缘材、金属、半导体、掺杂的半导体、波长转换物质中至少的一。绝缘材如氧化物、惰性气体、空气等。波长转换物质如荧光体、磷光体、染料、半导体等。填充质162的折射率亦可以介于其上下物质之间。填充质162若为颗粒,其尺寸应以能够填入欧姆接触区151或小于欧姆接触区151的宽度、深度、或其二者为佳。图7(a)中,与电性接点17下方的接触层16相接的欧姆接触区151中皆填入填充质162。图7(b)中,与电性接点17下方的接触层16相接的部分欧姆接触区151中亦填入填充质162,然其他部分的欧姆接触区151中并未无填充质162存在。如图所示,接触层16的外缘延伸入欧姆接触区151之中。图7(c)中,不连续区161(虚线处)中包含与接触层16相同的物质,但还包含填充质162。FIG. 7 discloses an optoelectronic semiconductor device according to another embodiment of the invention. In this embodiment, the discontinuous region 161 includes a filler 162 to fill at least part of the space in the one or more ohmic contact regions 151 . By adjusting the distribution pattern of the filler 162 in the ohmic contact area 151 , the optical properties, electrical properties, or both of the electromagnetic radiation or light coming from or entering the conversion portion 14 can be changed. The filler 162 is at least one of insulating material, metal, semiconductor, doped semiconductor, and wavelength conversion material. Insulating materials such as oxides, inert gases, air, etc. Wavelength conversion substances such as phosphors, phosphors, dyes, semiconductors, etc. The refractive index of the filler 162 can also be between that of the substances above and below it. If the filler 162 is a particle, its size should preferably be able to fill the ohmic contact region 151 or be smaller than the width, depth, or both of the ohmic contact region 151 . In FIG. 7( a ), the ohmic contact region 151 in contact with the contact layer 16 below the electrical contact 17 is filled with the filler 162 . In FIG. 7( b ), the part of the ohmic contact region 151 in contact with the contact layer 16 below the electrical contact 17 is also filled with the filler 162 , but the other part of the ohmic contact region 151 is not free of the filler 162 . As shown, the outer edge of the contact layer 16 extends into the ohmic contact region 151 . In FIG. 7( c ), the discontinuous region 161 (dotted line) contains the same substance as the contact layer 16 , but also contains a filler 162 .

如图8所示,电性接点17的至少一部分埋入第二电性层15之中。于图8(a)中,不连续区161下方可选择性形成欧姆接触区151、规则表面结构(未显示)、不规则表面结构(未显示)、或其组合。在图8(b)中,不连续区161下方不存在欧姆接触区151。若欧姆接触区151通过外延生长法形成于第二电性层15之上,可以在不连续区161内的欧姆接触区151中填入填充质162以使其平坦化。若欧姆接触区151通过湿蚀刻法、干蚀刻法、或其二混合者形成于第二电性层15之上,可以使用蚀刻掩模覆盖预计形成不连续区161的部分以避免第二电性层15表面被蚀刻。在图8(c)图中,电性接点17与接触层16、第二电性层15、或其二者相接触的任一表面上形成为规则表面结构、不规则表面结构、或其二者以增加电性接点17与其他部分间的接触面积。As shown in FIG. 8 , at least a part of the electrical contact 17 is buried in the second electrical layer 15 . In FIG. 8( a ), an ohmic contact region 151 , a regular surface structure (not shown), an irregular surface structure (not shown), or a combination thereof can be selectively formed under the discontinuous region 161 . In FIG. 8( b ), there is no ohmic contact region 151 below the discontinuity region 161 . If the ohmic contact region 151 is formed on the second electrical layer 15 by epitaxial growth method, the filling material 162 can be filled in the ohmic contact region 151 in the discontinuous region 161 to make it planarized. If the ohmic contact region 151 is formed on the second electrical layer 15 by wet etching, dry etching, or a mixture thereof, an etching mask may be used to cover the portion where the discontinuous region 161 is expected to be formed to avoid the second electrical layer 15. The surface of layer 15 is etched. In FIG. 8(c), the electrical contact 17 is formed as a regular surface structure, an irregular surface structure, or both on any surface that is in contact with the contact layer 16, the second electrical layer 15, or both. Or to increase the contact area between the electrical contact 17 and other parts.

如图9所示,电性接点17的至少一部分埋入第二电性层15之中,且不连续区161下方亦不存在欧姆接触区151。在一实施例中,接触层16先覆盖于形成有欧姆接触区151的第二电性层15的上表面后,再依照预定图案移除接触层16的部分区域直到该些区域内的欧姆接触区151几乎被移除。如此,形成不连续区161与移除欧姆接触区151结合于同一系列的工艺步骤之中。在另一实施例中,如图9(b)所示,不连续区161的任一内表面上可以形成规则表面结构、不规则表面结构、或其二者的结合。电性接点17与接触层16、第二电性层15、或其二者相接触的任一表面上形成为规则表面结构、不规则表面结构、或其二者以增加电性接点17与其他部分间的接触面积。As shown in FIG. 9 , at least a part of the electrical contact 17 is buried in the second electrical layer 15 , and there is no ohmic contact area 151 under the discontinuous area 161 . In one embodiment, after the contact layer 16 covers the upper surface of the second electrical layer 15 with the ohmic contact region 151 formed thereon, part of the contact layer 16 is removed according to a predetermined pattern until the ohmic contact in these regions District 151 was almost removed. In this way, forming the discontinuous region 161 and removing the ohmic contact region 151 are combined in the same series of process steps. In another embodiment, as shown in FIG. 9( b ), a regular surface structure, an irregular surface structure, or a combination thereof may be formed on any inner surface of the discontinuous region 161 . The electrical contact 17 is formed into a regular surface structure, an irregular surface structure, or both on any surface that is in contact with the contact layer 16, the second electrical layer 15, or both to increase the contact between the electrical contact 17 and other surfaces. contact area between parts.

如图10所示,欧姆接触区151以不同尺寸形成于第二电性层15之上,欧姆接触区151的型态可以参考前述的说明。在特定状况下,欧姆接触区151的内表面或外表面的条件决定接触层16与第二电性层15间欧姆接触的质与量。例如,较大范围的表面可以提供较多的面积以形成欧姆接触。图10(a)中,欧姆接触区151的宽度与深度由电性接点17向外逐渐扩大。图10(b)中,电性接点17下与特定位置处的欧姆接触区151中填入填充质162,填充质162的相关事项可参阅前述的说明与图示。图10(c)中,电性接点17下方并未形成欧姆接触区151。在此,“尺寸”包含但不限于长度、宽度、深度、高度、厚度、半径、角度、曲度、间距、面积、体积。As shown in FIG. 10 , the ohmic contact regions 151 are formed on the second electrical layer 15 with different sizes, and the types of the ohmic contact regions 151 can refer to the foregoing description. Under certain conditions, the condition of the inner or outer surface of the ohmic contact region 151 determines the quality and quantity of the ohmic contact between the contact layer 16 and the second electrical layer 15 . For example, a larger extent of the surface may provide more area to form an ohmic contact. In FIG. 10( a ), the width and depth of the ohmic contact region 151 gradually expand outward from the electrical contact 17 . In FIG. 10( b ), the ohmic contact area 151 under the electrical contact 17 and at a specific position is filled with a filler 162 . For related matters of the filler 162 , please refer to the foregoing description and illustration. In FIG. 10( c ), no ohmic contact region 151 is formed under the electrical contact 17 . Here, "dimension" includes but not limited to length, width, depth, height, thickness, radius, angle, curvature, distance, area, volume.

以上图示仅为各个实施例的示意,非用以限制表面结构的形成位置、数量、或型态。“规则表面结构”指一种结构,其在一表面的任一方向上可辨识出重复性特征,此重复性特征的型态可为定周期、变周期、准周期(quasiperodicity)、或其组合。“不规则表面结构”指一种结构,其在一表面的任一方向上无法辨识出重复性特征,此结构或可称为“随机粗糙表面”。The above illustrations are only illustrations of various embodiments, and are not intended to limit the formation positions, quantities, or types of the surface structures. "Regular surface structure" refers to a structure in which repetitive features can be identified in any direction on a surface, and the pattern of the repetitive features can be fixed periodicity, variable periodicity, quasiperodicity, or a combination thereof. "Irregular surface structure" refers to a structure in which no recurring features can be discerned in any direction of a surface, this structure may also be referred to as a "random rough surface".

图11及图12显示光电半导体装置部分区域的俯视图。在图11中,不连续区161的图案为圆形,并可配置如图11(a)的常规阵列,或如图11(b)的交错阵列。符号P1表示圆形的间距,符号D1表示圆形直径。在图12中,不连续区161的图案为正方形,并可配置如图12(a)的常规阵列,或如图12(b)的交错阵列。符号P2表示正方形的间距,符号D2表示正方形的边长。然而不连续区161的形状并不限于此,其他如矩形、菱形、平行四边形、椭圆形、三角形、五角形、六角形、梯形、或不规则形亦可以为本发明所采纳。11 and 12 show top views of partial regions of the optoelectronic semiconductor device. In FIG. 11 , the pattern of the discontinuous regions 161 is circular, and can be arranged in a conventional array as in FIG. 11( a ), or in a staggered array as in FIG. 11( b ). The symbol P1 represents the pitch of the circle, and the symbol D1 represents the diameter of the circle. In FIG. 12, the pattern of the discontinuous regions 161 is a square, and can be arranged in a regular array as in FIG. 12(a), or in a staggered array as in FIG. 12(b). The symbol P2 represents the pitch of the square, and the symbol D2 represents the side length of the square. However, the shape of the discontinuous region 161 is not limited thereto, and other shapes such as rectangle, rhombus, parallelogram, ellipse, triangle, pentagon, hexagon, trapezoid, or irregular shape can also be adopted by the present invention.

表1为数个实验结果的汇整。实验采用中国台湾晶元光电公司所生产的45mil×45mil蓝光裸芯,其结构近似图3的光电半导体装置10,其上并再加工形成如图11(a)、图11(b)、与图12(a)的不连续区与接触层,即圆形常规阵列、圆形交错阵列、与正方形常规阵列。接触层16的材料为电子束蒸镀的氧化铟锡,其颗粒尺寸约为50nm~80nm,折射率约为2。D1、D2、P1、及P2的单位为μm。Vf为正向电压。面积比为不连续区的总面积与接触层面积的百分比。如表1所示,吾人当可发现为获取亮度增加与降低Vf,不连续区的面积必须适当控制。此外,不连续区在接触层中的密度亦为一个控制参数。由X.Guo等人于Applied Physics Letters,Vol.78,No.21,p.3337所提的论文中曾提供计算发光二极管的二个电极间电流分散距离(Ls)的方法,该文献并援引为本申请案的一部分。以上述文献的估算作为假设,不连续区的尺寸若落于电流分散距离的尺度内,电流可通过流经第二电性区跨越一个不连续区后再流入接触层之中。由此,电流可在接触层中传递较远的距离。Table 1 is a compilation of several experimental results. In the experiment, a 45mil×45mil blue-ray bare core produced by China Taiwan Epistar Optoelectronics Co., Ltd. was used. Its structure is similar to that of the photoelectric semiconductor device 10 in FIG. Discontinuities and contact layers of 12(a), namely circular regular arrays, circular staggered arrays, and square regular arrays. The material of the contact layer 16 is indium tin oxide deposited by electron beam, the particle size of which is about 50nm-80nm, and the refractive index is about 2. The unit of D1, D2, P1, and P2 is μm. Vf is the forward voltage. The area ratio is the percentage of the total area of the discontinuity to the area of the contact layer. As shown in Table 1, it can be found that in order to obtain brightness increase and decrease Vf, the area of the discontinuity must be properly controlled. In addition, the density of discontinuities in the contact layer is also a controlling parameter. The method for calculating the current dispersion distance (Ls) between the two electrodes of the light-emitting diode was provided by X.Guo et al. in the paper Applied Physics Letters, Vol.78, No.21, p.3337, which cited part of this application. Based on the estimation in the above literature, if the size of the discontinuity falls within the scale of the current dispersion distance, the current can flow through the second electrical region across a discontinuity and then flow into the contact layer. As a result, current can travel a greater distance in the contact layer.

表1Table 1

本发明的另数个实施例中,接触层16的俯视图如分别如图13~图15所示。标号153表示一平台。然各图中的图案、数量、比例仅为例示,非用以限制本发明的实施方式,其他依照本文所述的准则、原理、原则、指引、或其他教示皆可合理地应用于本发明之中。In several other embodiments of the present invention, the top views of the contact layer 16 are shown in FIGS. 13-15 respectively. Reference numeral 153 denotes a platform. However, the patterns, quantities, and proportions in each figure are only examples, and are not intended to limit the implementation of the present invention. Other principles, principles, principles, guidelines, or other teachings described herein can be reasonably applied to the present invention. middle.

在图13中,第二电性接点17包含根部171、支部172、及端部173,其共同构成一电流网路,导引电流朝向预定的方向。根部171为支部172与端部173外观上的发源处,并通常为外型上的显著点,可作为工艺或检测过程中的基准点,亦常做为与外部电路连接之处。端部173为网路末端部分,即未再有其他分支。支部172介于根部171与端部173之间。任二部彼此电性相连,或者选择性地实体上彼此相连。例如,任二部间可通过外部导线、接触层16、不连续区161、中间材料、或下方区彼此电性相连,其中,“中间材料”指形成于相邻二部间隙中的材料,此中间材料或由与至少一部相异的材料形成,或形成于其他工艺步骤之中;下方区指位于三部中任一部下方可以作为电流通道的电性层或电性区,例如第二电性层15或高掺杂区。In FIG. 13 , the second electrical contact 17 includes a root portion 171 , a branch portion 172 , and an end portion 173 , which together form a current network and guide current toward a predetermined direction. The root 171 is the origin of the appearance of the branch 172 and the end 173, and is usually a prominent point in the appearance, which can be used as a reference point in the process or inspection process, and is often used as a connection with an external circuit. The end part 173 is the end part of the network, that is, there are no other branches. The branch portion 172 is located between the root portion 171 and the end portion 173 . Any two parts are electrically connected to each other, or optionally physically connected to each other. For example, any two parts can be electrically connected to each other through external wires, contact layers 16, discontinuous regions 161, intermediate materials, or lower regions, wherein the "intermediate material" refers to the material formed in the gap between adjacent two parts. The intermediate material is either formed of a material different from at least one part, or formed in other process steps; the lower area refers to the electrical layer or electrical area located below any of the three parts that can serve as a current channel, such as the second The electrical layer 15 or the highly doped region.

在一实施例中,第二电性接点17可仅包含根部171与端部173。在其他实施例中,各个根部171、支部172、及端部173可使用相同或不同的方式与下方材料相连接,连接方式可参考前述诸实施例与图示的描述。此外,各部下方可选择性地形成电流阻障(current blocking)区,以造成电流向下方材料流动的障碍,或调整电流朝向下方流动的形态。电流阻障区通过于目标部下方形成绝缘或不良导电材料以达成上述功效。图示中,根部171、支部172、及端部173的数量、形状、与布局仅为例示,非用以限制本发明。例如,第二电性接点17可包括二或多个根部171,根部171间可选择性形成支部172、端部173、或其二者。一个根部171外可围绕二或多个支部172或端部173。一个支部172上可分支出二或多个端部173。In one embodiment, the second electrical contact 17 may only include a root portion 171 and an end portion 173 . In other embodiments, each root portion 171 , branch portion 172 , and end portion 173 can be connected to the underlying material in the same or different ways, and the connection methods can refer to the descriptions of the aforementioned embodiments and illustrations. In addition, a current blocking region can be selectively formed under each part, so as to create an obstacle for the current to flow to the material below, or to adjust the form of the current flowing downward. The current blocking region achieves the above functions by forming an insulating or poorly conductive material under the target portion. In the figure, the number, shape, and layout of the root portion 171 , the branch portion 172 , and the end portion 173 are only examples, and are not intended to limit the present invention. For example, the second electrical contact 17 may include two or more root portions 171 , and branch portions 172 , end portions 173 , or both may be selectively formed between the root portions 171 . One root 171 may surround two or more branches 172 or ends 173 . Two or more end portions 173 can be branched from one branch portion 172 .

不连续区161自接触层16的外边界163向内形成,且此些不连续区161并未穿越接触层16,亦即,各个不连续区161在外边界163上仅有一个开口164。且二或多个的不连续区161可共用一开口164,如虚线区所示。由俯视图观之,不连续区161可与第二电性接点17相交(未显示)或不相交。当与第二电性接点17相交的不连续区161由绝缘或不良导电材料构成,此相交的不连续区161可与前述的电流阻障区165相整合,如图14斜线(hatch)处所示。图示中电流阻障区165的位置与大小仅为例示,非用以限制本发明的实施。The discontinuous regions 161 are formed inwardly from the outer boundary 163 of the contact layer 16 , and these discontinuous regions 161 do not pass through the contact layer 16 , that is, each discontinuous region 161 has only one opening 164 on the outer boundary 163 . And two or more discontinuous regions 161 can share an opening 164, as shown by the dotted line region. From the top view, the discontinuous region 161 may intersect (not shown) or not intersect with the second electrical contact 17 . When the discontinuous region 161 intersecting with the second electrical contact 17 is made of insulating or poorly conductive material, this intersecting discontinuous region 161 can be integrated with the aforementioned current blocking region 165, as shown in Figure 14 at the hatch shown. The position and size of the current blocking region 165 in the figure are only examples, and are not intended to limit the implementation of the present invention.

在一实施例中,沿着外边界163上任意或部分范围中连续至少三个不连续区161的角度、长度、宽度、深度、与间距中至少一个要素不相同。如图13所示,不连续区1611、1612、与1613具有相同的角度、长度、与宽度,但其间距并不相同,换言之,在不考虑深度的情况下,此区中不连续区161的配置呈现一维度的不规则变化。此不规则变化包括局部或全体的不规则变化,例如,位于两规则变化区之间的不规则变化区。“规则变化”指等比变化或等差变化。又如不连续区1614、1615、与1616具有不同的角度、长度、宽度、与间距。In one embodiment, at least one element of the angle, length, width, depth, and pitch of at least three continuous discontinuous regions 161 in any or part of the range along the outer boundary 163 is different. As shown in Figure 13, the discontinuous regions 1611, 1612, and 1613 have the same angle, length, and width, but their spacing is not the same. The configuration presents irregular changes in one dimension. The irregular changes include local or overall irregular changes, for example, an irregular change area between two regular change areas. "Regular change" means a proportional change or a differential change. In another example, the discontinuities 1614, 1615, and 1616 have different angles, lengths, widths, and spacings.

在图13与图14中,第二电性接点17左右对称(bilateral symmetry)。图15中,第二电性接点17非对称(asymmetry)。图13~图15中第一电性接点18左右对称,但并不限于此,换言之,第一电性接点18亦可为非对称。在一实施例中,不连续区的总体变化趋势符合第二电性接点17的外型,但并不排除少数不连续区161会偏离该变化趋势。如围绕根部171或端部173的二个较长不连续区161中仍间或有长度较短者。在另一实施例中,至少部分不连续区161与第二电性接点17间的间隔约维持于定值或稳定区间内,例如,排列于支部172两侧的各个不连续区161与支部172间的间距即大致相同,亦即间距的大小落于合理的工艺公差范围内。In FIG. 13 and FIG. 14 , the second electrical contact 17 is bilaterally symmetrical. In FIG. 15 , the second electrical contact 17 is asymmetric. In FIGS. 13 to 15 , the first electrical contact 18 is bilaterally symmetrical, but it is not limited thereto. In other words, the first electrical contact 18 can also be asymmetrical. In one embodiment, the overall change trend of the discontinuous area conforms to the shape of the second electrical contact 17 , but it is not ruled out that a few discontinuous areas 161 may deviate from the change trend. For example, among the two longer discontinuous regions 161 surrounding the root portion 171 or the end portion 173 , there may still be a shorter one from time to time. In another embodiment, the distance between at least part of the discontinuous region 161 and the second electrical contact 17 is approximately maintained at a constant value or within a stable range, for example, each discontinuous region 161 and branch 172 arranged on both sides of the branch 172 The spacing between them is roughly the same, that is, the size of the spacing falls within a reasonable process tolerance range.

以上各图示与说明虽仅分别对应特定实施例,然而,各个实施例中所说明或披露的元件、实施方式、设计准则、及技术原理除在彼此显相冲突、矛盾、或难以共同实施之外,本领域的技术人员当可依其所需任意参照、交换、搭配、协调、或合并。Although the above illustrations and descriptions only correspond to specific embodiments, however, the components, implementation methods, design principles, and technical principles described or disclosed in each embodiment are in conflict with each other, contradictory, or difficult to implement together. In addition, those skilled in the art can refer to, exchange, match, coordinate, or merge arbitrarily according to their needs.

虽然本发明已说明如上,然其并非用以限制本发明的范围、实施顺序、或使用的材料与工艺方法。对于本发明所作的各种修饰与变更,皆不脱本发明的精神与范围。Although the present invention has been described above, it is not intended to limit the scope of the present invention, the implementation sequence, or the materials and process methods used. Various modifications and changes made to the present invention do not depart from the spirit and scope of the present invention.

Claims (20)

1. opto-semiconductor device comprises:
One energy conversion system can carry out the conversion between luminous energy and electric energy, and wherein this energy conversion system comprises a surface, one first contact zone and a plurality of second contact zone, and wherein this first contact zone and these a plurality of second contact zones are formed at this surface;
One first material block is formed on this first contact zone of this energy conversion system, and penetrable for a specific wavelength of light; And
A plurality of second material blocks are formed on these a plurality of second contact zones of this energy conversion system;
Wherein, the resistance between this first material block and this first contact zone is less than the resistance between this second material block and this second contact zone.
2. opto-semiconductor device as claimed in claim 1, wherein this first contact zone comprises the tapered hole of a hexagonal.
3. opto-semiconductor device as claimed in claim 1, wherein this first contact zone comprises one and forms the surface of ohmic contact with this first material block.
4. opto-semiconductor device as claimed in claim 1, wherein this first material block and this second material block form patterning configuration.
5. opto-semiconductor device as claimed in claim 1, wherein this second contact zone comprises an insulation material.
6. opto-semiconductor device comprises:
One energy conversion system, in order to carry out the conversion between luminous energy and electric energy, this energy conversion system has one first side;
One electrical contact is arranged on this first side of said energy conversion system;
One contact layer is formed at this first side of this energy conversion system, and comprises an external boundary and at least one ohmic contact regions, wherein can form ohmic contact between this ohmic contact regions and this energy conversion system; And
Two or more locus of discontinuities, become a pattern distribution, make edge outside electric current lateral flow to the contact layer that comes from this electrical contact.
7. opto-semiconductor device as claimed in claim 6, wherein this locus of discontinuity comprise how much, material, physical characteristic, and chemical characteristic in one of which discontinuous at least.
8. opto-semiconductor device as claimed in claim 6, wherein this locus of discontinuity comprises a kind of structure, and it shows cognizable one repeated characteristic on arbitrary direction on a surface.
9. opto-semiconductor device as claimed in claim 8, kenel that wherein should the repeatability characteristic comprise fixed cycle, variable period, and paracycle in one of which at least.
10. opto-semiconductor device as claimed in claim 6, wherein this locus of discontinuity comprises a kind of irregular surface structure.
11. opto-semiconductor device as claimed in claim 6, wherein the size of this locus of discontinuity is less than or equal to an electric current dispersion distance.
12. opto-semiconductor device as claimed in claim 6, wherein this contact layer comprises tin indium oxide.
13. opto-semiconductor device as claimed in claim 6, wherein this ohmic contact regions comprises at least one sinking space, and its geometry comprises pyramid, circular cone, cuts in the body one of which at least with tack.
14. opto-semiconductor device as claimed in claim 6, wherein this ohmic contact regions comprises an at least one inclined-plane and a plane, and wherein this inclined-plane can be good ohmic contact than this plane with this energy conversion system formation.
15. opto-semiconductor device as claimed in claim 6 wherein has bigger contact area than this ohmic contact regions near this external boundary.
16. opto-semiconductor device as claimed in claim 6, wherein this ohmic contact regions is formed on the outer surface of this energy conversion system.
17. opto-semiconductor device as claimed in claim 6 does not wherein have this ohmic contact regions between the part at least of this locus of discontinuity and this energy conversion system.
18. opto-semiconductor device as claimed in claim 6, wherein in this locus of discontinuity at least one of which comprise a chymoplasm.
19. opto-semiconductor device as claimed in claim 6, wherein this energy conversion system comprises a transition zone.
20. opto-semiconductor device as claimed in claim 6 also comprises:
One electrical contact near this energy conversion system, and forms with this contact layer and to electrically contact.
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