CN101643558B - Vaporized insect-proof mother grain capable of suppressing insect growth in fur - Google Patents
Vaporized insect-proof mother grain capable of suppressing insect growth in fur Download PDFInfo
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- CN101643558B CN101643558B CN2009100749315A CN200910074931A CN101643558B CN 101643558 B CN101643558 B CN 101643558B CN 2009100749315 A CN2009100749315 A CN 2009100749315A CN 200910074931 A CN200910074931 A CN 200910074931A CN 101643558 B CN101643558 B CN 101643558B
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- 241000238631 Hexapoda Species 0.000 title claims abstract description 35
- 239000004698 Polyethylene Substances 0.000 claims abstract description 16
- -1 polyethylene Polymers 0.000 claims abstract description 16
- 229920000573 polyethylene Polymers 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 13
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 241000723346 Cinnamomum camphora Species 0.000 claims abstract description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229930008380 camphor Natural products 0.000 claims abstract description 5
- 230000008569 process Effects 0.000 claims abstract description 5
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims abstract description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229960000846 camphor Drugs 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000005469 granulation Methods 0.000 claims abstract description 4
- 230000003179 granulation Effects 0.000 claims abstract description 4
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract 7
- 238000003756 stirring Methods 0.000 claims abstract 3
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 claims abstract 2
- 238000002309 gasification Methods 0.000 claims abstract 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000000077 insect repellent Substances 0.000 claims 1
- 238000004806 packaging method and process Methods 0.000 abstract description 2
- 231100000053 low toxicity Toxicity 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 241000607479 Yersinia pestis Species 0.000 description 4
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 210000004681 ovum Anatomy 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 239000005952 Aluminium phosphide Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 239000005935 Sulfuryl fluoride Substances 0.000 description 2
- 241000267822 Trogoderma granarium Species 0.000 description 2
- 241000778089 Trogoderma variabile Species 0.000 description 2
- PPNXXZIBFHTHDM-UHFFFAOYSA-N aluminium phosphide Chemical compound P#[Al] PPNXXZIBFHTHDM-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000001311 chemical methods and process Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OBTWBSRJZRCYQV-UHFFFAOYSA-N sulfuryl difluoride Chemical compound FS(F)(=O)=O OBTWBSRJZRCYQV-UHFFFAOYSA-N 0.000 description 2
- 208000024891 symptom Diseases 0.000 description 2
- 229960004418 trolamine Drugs 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- 241001289510 Attagenus unicolor Species 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 1
- 206010012735 Diarrhoea Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001177117 Lasioderma serricorne Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229940123973 Oxygen scavenger Drugs 0.000 description 1
- 241000270295 Serpentes Species 0.000 description 1
- 229920006387 Vinylite Polymers 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002316 fumigant Substances 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003534 oscillatory effect Effects 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
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Abstract
本发明公开了一种可抑制毛皮中昆虫生长的气化性防虫母粒，主要由樟脑、拟除虫菊酯、苯甲酸盐、邻苯二甲酸二丁酯和三乙醇胺等组成，将防虫剂按一定比例与聚乙烯在高速搅拌机中高速搅拌5分钟，搅拌过程中应保持高速搅拌机温度在60℃，冷却后，将混合物加入双螺杆造粒机中造粒，得到气化性防虫母粒。该气化性防虫母粒可以与乙烯基树脂混合，加工成所需要的各种应用形式，如膜、棒、蜂窝状等。而且该气化性防虫母粒毒性较低，对人体影响较小，可用于各种毛皮制品的防虫包装。The invention discloses a gasified anti-insect masterbatch which can inhibit the growth of insects in fur. It is mainly composed of camphor, pyrethroids, benzoate, dibutyl phthalate and triethanolamine. Stir a certain proportion with polyethylene in a high-speed mixer for 5 minutes at high speed. During the mixing process, the temperature of the high-speed mixer should be kept at 60°C. After cooling, the mixture is added to a twin-screw granulator for granulation to obtain gasified insect-resistant masterbatch. The gasified anti-insect masterbatch can be mixed with vinyl resin and processed into various application forms, such as film, rod, honeycomb and so on. Moreover, the gasification insect-proof masterbatch has low toxicity and little impact on human body, and can be used for insect-proof packaging of various fur products.
Description
Affiliated technical field
The present invention relates to a kind of composition that suppresses the vaporized insect-proof mother of insect growth in the fur and preparation method thereof, belong to the Biofunctional materials technical field.
Background technology
Along with the raising gradually of living standards of the people, people daily live, with, use the more and more of fur goods in wearing, fur goods is good looking appearance but also durable not only, has improved the class that people live greatly.But the fur goods estivate is the problem that makes many people's headaches, because the high temperature humidity in summer, the fur goods keeping is not good at just may occurring phenomenon mouldy, rotten, " snake ", has had a strong impact on being extensive use of of fur goods.
For various museums, a large amount of animal or plant specimen of depositing and the book document data in Library, Vermins-proof mildew-proof also is a very important job.Up to the present, the also good without comparison way of the Vermins-proof mildew-proof of zoological specimens in domestic many museums, some adopts a kind of aerosol of import, and toxicity is bigger, and operation is frequent, uses very inconvenient.
From the kind of insect, the insect of harm sample shop sample mainly contains kinds such as lasioderma serricorne, Trogoderma variabile Ballion, the black worm of rice, attagenus piceus.
In order to tackle these insects, China most of sample shop is generally adopted at present and is thrown in wormer, purifying treatment, chemicals immersion, smears or with methods such as chemical agents sample carried out fumigation and kill.Sample before putting in storage is carried out purifying treatment, in order to avoid bring new worm source into, that generally uses has physical methods such as cryogenic freezing, baking oven for heating.Chemical process is with poisonous pharmaceutical chemicals sample to be fumigated, smeared or soaks.Smear and soak medicine commonly used mercury chloride, formalin, santochlor etc. are arranged.The medicine that fumigant insect killing is commonly used has aluminium phosphide, prussic acid, monobromethane, sulfuryl fluoride, santochlor, dithiocarbonic anhydride, sulfuryl fluoride, aluminium phosphide, phosphuret-(t)ed hydrogen etc.The sample shop that has we can say that insect pest problem in sample shop is not solved at home yet because the input deficiency only use mercury chloride insect protected and desinsection, but the effect of these methods is not remarkable.
Methods such as gamma radiation desinsection, microwave desinsection, gas regulation processing, electronic insect-killing and light wave insecticidal are also used in external many samples shop in research except purifying method, chemical processes such as employing cryogenic freezing.Gamma radiation and microwave all have limitation, can only be used for a small amount of sample, and gamma radioactive method expense costliness, used by country's restriction.Microwave box heating is inhomogeneous during microwave desinsection, and each corner temperature in the case is different, and insect can not all kill, and some sample also can explosion in the treating processes, and sample is damaged, and effect is undesirable.It is that damaged by vermin sample is placed in the oxygen barrier film sack that gas regulation is handled, and with oxygen scavenger oxygen content in the bag is reduced to below 0.1%, or is processing 7-21 days in the nitrogen environment of 60% carbonic acid gas or 99.9%, kill pests safely and effectively in concentration.Electronic insect-killing is slightly to bombard with low-energy electron in radiation devices, and light wave insecticidal is to use the near-infrared light waves detection scanning, only is used to kill foodstuff pests such as cereal, effectively kill pests in the Germany and the U.S. at present.The 3 kinds of methods in back had both been protected environment, and were with low cost, do not damage sample again, and the insect protected that is used for sample should be effective.But at present that is that all right is ripe for technology, also needs long research, could confirm its effect.
In most of museums, more valuable sample is all taked independent packaging and storing, the method of best like this Vermins-proof mildew-proof is not that whole indoor environment is handled, but should handle the small packages environment, that is to say and develop a kind of effective insect protected wrapping material, this material being made into small packages, sample is packed separately, is the most feasible present method.
Summary of the invention
The objective of the invention is to study a kind of composition that suppresses the vaporized insect-proof mother of insect growth in the fur and preparation method thereof.
Insect-proof agent in this vaporized insect-proof mother mainly is made up of camphor, pyrethroid, benzoate, dibutyl phthalate and trolamine etc.; insect-proof agent was stirred 5 minutes in the homogenizer high speed with polyethylene by a certain percentage; should keep the homogenizer temperature at 60 ℃ in the whipping process; after the cooling; mixture is added granulation in the dual-screw pelletizer, obtain vaporized insect-proof mother.Wherein each component content ratio is:
Camphor 6%
Benzoate 6%
Nano-calcium carbonate 5%
Polyethylene 70%
Each component total amount is 100%.
Embodiment 1: get 6 parts of camphors, 5 parts of santochlor, 6 parts of benzoates, 2 parts of dibutyl phthalates, 4 parts of trolamines, 2 parts of polyethylene waxs, 5 parts of nano-calcium carbonates, 70 parts of polyethylene.
With benzoate WZJ-6J type oscillatory type supper micron mill micronizing 60min; sample is crossed 500 mesh sieves; according to the above ratio each composition being added the homogenizer high speed stirred 5 minutes; should keep the homogenizer temperature at 60 ℃ in the whipping process; after the cooling, mixture is added granulation in the dual-screw pelletizer.The tablets press processing parameter: gradient increases successively from the opening for feed to the head temperature, 90 ℃ of opening for feed temperature, 160 ℃ of head temperatures.
Embodiment 2: get 10 parts of master batches among the embodiment 1, mix with 90 parts of polyethylene, blow out the insect protected film in blow moulding machine, directly use.
Comparative example: with the polyethylene film of embodiment 2 same thickness.
The insect protected performance of the foregoing description is verified by following test.
1, the killing effect of high instar larvae is tested
(1) insect protected film and polyethylene film are cut into suitable size, are attached to the inwall of 1000 ml beakers, rim of a cup seals (the scotch tape center has 1 centimetre of circular hole of a diameter to be used for carrying out gaseous interchange with the external world) with scotch tape.Testing apparatus figure sees Figure of description 1, and wherein Reference numeral 1 is a ventilating pit; Mark 2 is an insect; Mark 3 is the 1000ml beaker; Mark 4 is insect protected film or polyethylene film; Mark 5 is the seal interface.
(2) preparation supplies to try insect: close, the active healthy and strong high instar larvae of the bodily form of picking sufficient amount (the about 0.5cm length of Trogoderma variabile Ballion, the about 1.0cm length of black wool khapra beetle), per 10 is in one group of input 1000ml wide-necked bottle.
Observed and recorded: routine observation record insect death toll.Dead insect has following features: rocking not reaction for a long time such as health, foot, bristle under the situation of bottle; Polypide is dry, hardening or flatly contract, colour-darkening.The insect that does not have death but poisoned has following symptoms: health twists, rolls, afterbody has diarrhoea shape remains.Then all are normal not have the insect that poisons.
The observed and recorded result shows after 10 days: toxicity symptom has all appearred in two kinds of insects in insect protected film beaker, the insect death more than 50%.Two kinds of insect no abnormality seens in the polyethylene film beaker.
2, vermins-proof effect test
Prepare two blocks of furs, be of a size of 10cm*10cm, in every block of fur, put into 10 of black wool khapra beetle worm's ovums, be respectively charged into then in the sack that insect protected film and polyethylene film make, put into 30 ℃ of thermostat containers and deposit.After half a year, take out to check, find that worm's ovum is hatched in the polyethylene film sack, and longly be adult, and the worm's ovum in insect protected film sack has also been hatched, but adult do not occurred.
Comprehensive above-mentioned test, the major advantage of this product is:
1. a kind of vaporized insect-proof mother that prevents the growth of insect in the fur, processing and forming technology is simple, and sterilant toxicity contained in interior is low, and vermins-proof effect is good.
2. the vaporized insect-proof mother of being developed can be mixed with Vinylite, makes various amelioration products easy to use, is used for the Vermins-proof mildew-proof that museum etc. locates various fur goodss.
Description of drawings: Fig. 1 is vermins-proof effect testing apparatus figure.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100749315A CN101643558B (en) | 2009-07-20 | 2009-07-20 | Vaporized insect-proof mother grain capable of suppressing insect growth in fur |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100749315A CN101643558B (en) | 2009-07-20 | 2009-07-20 | Vaporized insect-proof mother grain capable of suppressing insect growth in fur |
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| Publication Number | Publication Date |
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| CN101643558A CN101643558A (en) | 2010-02-10 |
| CN101643558B true CN101643558B (en) | 2011-04-06 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102492205B (en) * | 2011-12-09 | 2013-03-27 | 徐建明 | Household purifying film |
| CN103215751B (en) * | 2012-01-19 | 2017-05-03 | 佛山市南海必得福无纺布有限公司 | Preparation method of long-acting insect prevention and mosquito repelling PP (Polypropylene) non-woven fabric |
| CN104558744A (en) * | 2013-10-21 | 2015-04-29 | 广东美的厨房电器制造有限公司 | Master batch for plastic product as well as preparation method, plastic product and preparation method of master batch |
| CN105330946A (en) * | 2015-12-03 | 2016-02-17 | 张家港市秀华塑料厂 | Agricultural insect-resistant greenhouse film formulation |
| CN106750769A (en) * | 2016-12-06 | 2017-05-31 | 淄博龙沙高分子材料科技有限公司 | Grain storage bag Chinese herbal medicine insect prevention masterbatch |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5591727A (en) * | 1990-09-12 | 1997-01-07 | Perycut-Chemie Ag | Insecticidal composition |
| CN1148061A (en) * | 1995-06-21 | 1997-04-23 | Fmc有限公司 | Pyrethroid-containing crop protection bags |
| US20050154214A1 (en) * | 1998-11-10 | 2005-07-14 | Thomas Heidemann | Silver- and vanadium-containing multimetal oxide and its use |
-
2009
- 2009-07-20 CN CN2009100749315A patent/CN101643558B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5591727A (en) * | 1990-09-12 | 1997-01-07 | Perycut-Chemie Ag | Insecticidal composition |
| CN1148061A (en) * | 1995-06-21 | 1997-04-23 | Fmc有限公司 | Pyrethroid-containing crop protection bags |
| US20050154214A1 (en) * | 1998-11-10 | 2005-07-14 | Thomas Heidemann | Silver- and vanadium-containing multimetal oxide and its use |
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