CN101638547A - Water-based energy storage luminescence floor coating and preparation method thereof - Google Patents
Water-based energy storage luminescence floor coating and preparation method thereof Download PDFInfo
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- CN101638547A CN101638547A CN200910018326A CN200910018326A CN101638547A CN 101638547 A CN101638547 A CN 101638547A CN 200910018326 A CN200910018326 A CN 200910018326A CN 200910018326 A CN200910018326 A CN 200910018326A CN 101638547 A CN101638547 A CN 101638547A
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- 239000011248 coating agent Substances 0.000 title claims abstract description 40
- 238000000576 coating method Methods 0.000 title claims abstract description 40
- 238000004146 energy storage Methods 0.000 title claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000004020 luminiscence type Methods 0.000 title claims description 23
- 238000002360 preparation method Methods 0.000 title claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 58
- 239000000843 powder Substances 0.000 claims abstract description 22
- 150000001412 amines Chemical class 0.000 claims abstract description 18
- 239000002904 solvent Substances 0.000 claims abstract description 15
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 14
- 239000007787 solid Substances 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000004593 Epoxy Substances 0.000 claims description 41
- 229920005989 resin Polymers 0.000 claims description 34
- 239000011347 resin Substances 0.000 claims description 34
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- 238000012986 modification Methods 0.000 claims description 19
- 230000004048 modification Effects 0.000 claims description 19
- 239000006185 dispersion Substances 0.000 claims description 14
- 239000006184 cosolvent Substances 0.000 claims description 11
- 238000012856 packing Methods 0.000 claims description 11
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 10
- 239000012046 mixed solvent Substances 0.000 claims description 9
- 239000013530 defoamer Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 7
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 claims description 7
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 6
- -1 rare earth ion Chemical class 0.000 claims description 5
- 150000001408 amides Chemical class 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 claims description 3
- 150000008431 aliphatic amides Chemical group 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 229920003180 amino resin Polymers 0.000 claims description 3
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 238000006266 etherification reaction Methods 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 229920002521 macromolecule Polymers 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920005646 polycarboxylate Polymers 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 2
- 239000003973 paint Substances 0.000 abstract description 7
- 239000003822 epoxy resin Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
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- 239000000945 filler Substances 0.000 abstract description 3
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- 239000000853 adhesive Substances 0.000 description 2
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- 239000003513 alkali Substances 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
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- 231100000252 nontoxic Toxicity 0.000 description 2
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- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
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- 239000004922 lacquer Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
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Landscapes
- Paints Or Removers (AREA)
Abstract
本发明公开了一种水性蓄能发光地坪涂料，由主剂和胺类固化剂组成，主剂由下述组分组成：环氧树脂、表面改性的夜光粉、固体填料、助剂和溶剂，方法是先将改性后的夜光粉、环氧树脂、固体填料、助剂、溶剂按上述比例混合均匀，研磨，得水性蓄能发光地坪涂料主剂，然后在涂装时，将主剂与胺类固化剂按比例混合均匀即可。The invention discloses a water-based energy-storage luminous floor coating, which is composed of a main agent and an amine curing agent. The main agent is composed of the following components: epoxy resin, surface-modified luminous powder, solid filler, auxiliary agent and Solvent, the method is to first mix the modified luminous powder, epoxy resin, solid filler, additives, and solvent according to the above ratio, and grind to obtain the main agent of water-based energy storage luminous floor paint. The main agent and the amine curing agent can be mixed evenly in proportion.
Description
Technical field
The present invention relates to the terrace paint technical field, relate in particular to a kind of water-based energy storage luminescence floor coating and preparation method thereof.
Background technology
Terrace paint is applied in large-scale public places such as factory, school, hospital, office widely as one of emerging material of construction.Epoxy flooring coating becomes one of terrace paint kind with fastest developing speed because paint film has excellent chemical resistance, smooth bright and clean, ornamental advantage such as strong.The main type of epoxy flooring coating has solvent-free gravity flow flat pattern, high solid solvent-borne type, conduction type, colored mortar type and aqueous epoxy floor coating etc. at present.Current, have excellent wear-resisting property, painting cost is low, economizes on resources, eco-friendly terrace paint has stronger competitive power on market.
Long after glow luminous material belongs to a kind of of embedded photoluminescent material, after being subjected to irradiations such as natural light, light, UV-light, luminous energy is stored, the mode with fluorescence discharges lentamente after stopping illumination, reach several hours to tens hours time of releasing at the dark place, claim luminescent powder again.Spectrum property that it is good and distinctive long afterglow property get more and more people's extensive concerning day by day and study.Long after glow luminous material has been used in the coating aspect, as the patent CN1230576A " a kind of luminescent coating " of Lu Wei.But Shang Weijian has the coating of the band noctilucence that uses on epoxide terrace.
Summary of the invention
The problem that the present invention is directed to the prior art existence provides a kind of water-based energy storage luminescence floor coating, the luminous in the dark longer duration of this coating, and the toxicological harmless effect, and be difficult for aging.
The problem that the present invention is directed to the prior art existence provides a kind of preparation method of water-based energy storage luminescence floor coating.
For achieving the above object, technical scheme of the present invention is: a kind of water-based energy storage luminescence floor coating, form by host and amine curing agent, and by weight, described host is made up of following component:
Resins, epoxy 40-60 part
Luminescent powder 6-35 part of surface modification
Solid packing 10-25 part
Auxiliary agent 4-10 part
Solvent 15-30 part;
Amine curing agent 8-32 part.
Described Resins, epoxy is E-51 Resins, epoxy or E-54 Resins, epoxy.
The luminescent powder filler of described surface modification is the alkali earth metal aluminate long after glow luminous material that contains rare earth ion, and fineness is carried out surface modification by silane coupling agent and made more than 500 orders.
Described silane coupling agent is the silane coupling agent that contains vinyl.
Described solid packing is a talcum powder.
Described auxiliary agent is made up of following components by part by weight:
Dispersion agent 1.0-2.0 part flow agent 0.5-1.0 part defoamer 1.0-1.5 part
Cosolvent 1.0-2.5 part photostabilizer 0.1-1.5 part.
Described dispersion agent is selected macromolecule dispersing agent or polycarboxylate dispersion agent or both mixtures for use; Described flow agent adopts fluorine-carbon modified polyacrylate flow agent; Described defoamer adopts non-silicon defoamer; Described cosolvent is the butanols modified aminoresin of low degree of etherification.
Described solvent is the mixed solvent of ethanol, methylcarbonate and pimelinketone, and the weight ratio of described mixed solvent is 1: 1: 1.
Described amine curing agent is aliphatic amide, aliphatic cyclic amine or polymeric amide, is the 10-20% of host gross weight.
The method for preparing above-mentioned coating is: earlier the luminescent powder after the modification, Resins, epoxy, solid packing, auxiliary agent, solvent are mixed according to the above ratio, grind, water-based energy storage luminescence floor coating host, then when application, host and amine curing agent mixed in proportion get final product.
The beneficial effect that the present invention produces is: owing to use alkali earth metal aluminate to be phosphorescent pigment, behind ultraviolet ray or sun exposure, luminous longer duration in night or dark can reach more than 10 hours.So the epoxy floor material of band noctilucence can be accepted uviolizing by day and hold light, in the environment of dark, can self send colored radiance, can be widely used in family, factory, school, hospital, office and large-scale public place etc., play the effect of save energy.
Because Resins, epoxy has following performance: toxicological harmless effect own, and also it is various informative, it is convenient to solidify, adhesive power is strong, shrinkability is low, mechanical property is good, good insulation preformance, stable chemical performance, dimensional stabilizing and have good fungus resistance energy.So the Resins, epoxy after solidifying usually has good alkali resistance, acid resistance and solvent resistance.And above-mentioned many performances is comprehensive, make Resins, epoxy have outstanding stability and weather resistance, and amine curing agent adopts polymeric amide to have nontoxic, light weight, good physical strength, wear resistance and erosion resistance preferably, so be difficult for wearing out, can prolong the work-ing life of epoxide terrace by this coating.
Embodiment
Embodiment one:
A kind of water-based energy storage luminescence floor coating is made up of host and amine curing agent, and by weight, described host is made up of following component:
6 parts of the luminescent powders of 40 parts of surface modifications of Resins, epoxy
4 parts of 10 parts of auxiliary agents of solid packing
15 parts of solvents;
8 parts of amine curing agents.
Wherein, auxiliary agent is made up of following components by part by weight:
1.0 parts of 0.7 part of defoamers of 1.0 parts of flow agents of dispersion agent
0.3 part of 1.0 parts of photostabilizer of cosolvent.
The luminescent powder of surface modification prepares by the following method: earlier luminescent powder is carried out surface modification with silane coupling agent: with 60 kilograms of long-afterglow luminescent powders, 18 kilograms of silane coupling agents, 180 kilograms of concentration is 99.9% ethanol, stir fast, excess ethanol (the ethanol reusable edible that steams) is removed in evaporation, can obtain 80 kilograms of the long-afterglow luminescent powder of fineness more than 500 orders of modification.Wherein, silane coupling agent is the silane coupling agent that contains vinyl.
Then the luminescent powder after the modification, Resins, epoxy, solid packing, auxiliary agent, solvent are mixed according to the above ratio, grind, water-based energy storage luminescence floor coating host, then when application, host and amine curing agent mixed in proportion get final product.
Wherein, above-mentioned Resins, epoxy is owing to have a following performance: toxicological harmless effect own, and also it is various informative, it is convenient to solidify, adhesive power is strong, shrinkability is low, mechanical property is good, good insulation preformance, stable chemical performance, dimensional stabilizing and have good fungus resistance energy.So the epoxy-resin systems after solidifying usually has good alkali resistance, acid resistance and solvent resistance.And behind above-mentioned many performance synthesises, make Resins, epoxy have outstanding stability and weather resistance, so be difficult for wearing out, can prolong the work-ing life of epoxide terrace by this coating.
Described solid packing is a talcum powder.Because good physics, chemical propertys such as talcum has oilness, anti-sticks, helps that stream, resistivity against fire, resistance to acid, insulativity, fusing point height, chemical torpescence, opacifying power are good, softness, good luster, adsorptive power are strong.Can improve the performance of goods by talcum powder, and the radiating condition when improving resin solidification.
Described dispersion agent is selected macromolecule dispersing agent or polycarboxylate dispersion agent or both mixtures for use; Described flow agent adopts fluorine-carbon modified polyacrylate flow agent; Described defoamer adopts non-silicon defoamer; Described cosolvent is the butanols modified aminoresin of low degree of etherification.Wherein, can stop by photostabilizer to cause goods aged free radical reaction, destroy thereby make goods exempt from ultraviolet ray.
Described solvent is the mixed solvent of ethanol, methylcarbonate and pimelinketone, and the weight ratio of described mixed solvent is 1: 1: 1, can certainly adopt ethanol, methylcarbonate, hexone etc. separately.
Described solidifying agent is aliphatic amide, aliphatic cyclic amine or polymeric amide, and consumption is the 10-20% of host gross weight.。It is solidifying agent that the present invention preferentially adopts low molecular polyamides, and it has nontoxic, light weight, good physical strength, wear resistance and erosion resistance preferably, and result of use is good.
Embodiment two:
A kind of water-based energy storage luminescence floor coating is made up of host and amine curing agent, and by weight, described host is made up of following component:
20.5 parts of the luminescent powders of 50 parts of surface modifications of Resins, epoxy
7 parts of 17.5 parts of auxiliary agents of solid packing
22.5 parts of solvents;
20 parts of amine curing agents.
Wherein, auxiliary agent is made up of following components by part by weight:
1.25 parts of 1.0 parts of defoamers of 1.5 parts of flow agents of dispersion agent
1.5 parts of 1.75 parts of photostabilizers of cosolvent.
Preparation method and embodiment one are basic identical, do not repeat them here.
Embodiment three:
A kind of water-based energy storage luminescence floor coating is made up of host and amine curing agent, and by weight, described host is made up of following component:
35 parts of the luminescent powders of 60 parts of surface modifications of Resins, epoxy
8.5 parts of 25 parts of auxiliary agents of solid packing
30 parts of solvents;
32 parts of amine curing agents.
Wherein, auxiliary agent is made up of following components by part by weight:
1.5 parts of 1.0 parts of defoamers of 2.0 parts of flow agents of dispersion agent
1.5 parts of 2.5 parts of photostabilizers of cosolvent.
Preparation method and embodiment one are basic identical, do not repeat them here.
Resins, epoxy can adopt the mixture of E-51 Resins, epoxy or E-54 Resins, epoxy or E-51 Resins, epoxy and E-54 Resins, epoxy.Each experimental result is as follows:
(1) when adopting E-51 Resins, epoxy, with 100 parts E-51 Resins, epoxy, the long-afterglow luminescent powder of 20 parts of surface modifications, 30 parts of talcum powder, 2 parts of flow agents, 3 parts of defoamers, 2 parts of dispersion agents, 3 parts of cosolvent, 2 parts of photostabilizers, 30 parts of mixed solvents (by ethanol: methylcarbonate: the weight ratio of pimelinketone is that preparation in 1: 1: 1 get) mix, and grind, must master grind.Stir and promptly get epoxy flooring coating host.Solidifying agent is selected the low molecular polyamides solidifying agent for use, and consumption is 30 parts.Use the D65 light source, behind the 100lx irradiation 15min, with luminous twilight sunset test after-glow brightness, the result is as follows:
(2) when adopting E-54 Resins, epoxy, with 120 parts E-54 Resins, epoxy, the long-afterglow luminescent powder of 25 parts of surface modifications, fineness 500 purpose weight are 30 parts talcum powder, 2 parts of flow agents, 3 parts of defoamers, 2.5 parts of dispersion agents, 3 parts of cosolvent, 2 parts of photostabilizers, 45 parts of mixed solvents (by ethanol: methylcarbonate: the weight ratio of pimelinketone is that preparation in 1: 1: 1 get) mix, and grind, must master grind.Stir and promptly get epoxy flooring coating host.Solidifying agent is selected the low molecular polyamides solidifying agent for use, and consumption is 40 parts.Use the D65 light source, behind the 100lx irradiation 15min, with luminous twilight sunset test after-glow brightness, the result is as follows:
(3) when adopting the mixture of E-51 Resins, epoxy and E-54 Resins, epoxy, with 120 parts E-51 Resins, epoxy and the mixture of E-54 Resins, epoxy (E-51: the E-54 weight ratio is 1: 1), the long-afterglow luminescent powder of 30 parts of surface modifications, fineness 500 purpose weight are 30 parts talcum powder, 2.5 part flow agent, 3 parts of defoamers, 2 parts of dispersion agents, 3 parts of cosolvent, 2 parts of photostabilizers, 45 parts of mixed solvents (by ethanol: methylcarbonate: the weight ratio of pimelinketone is that preparation in 1: 1: 1 get) mix, and grind, must master grind.Stir and promptly get epoxy flooring coating host.Solidifying agent is selected the low molecular polyamides solidifying agent for use, and consumption is 40 parts.Use the D65 light source, behind the 100lx irradiation 15min, with luminous twilight sunset test after-glow brightness, the result is as follows:
Water-based energy storage luminescence floor coating preparation method provided by the invention, carry out surface modification by luminescent powder, the host of forming epoxy flooring coating, improved the consistency of inorganic luminescent powder and Resins, epoxy, in coating, be uniformly dispersed, be easy to construction, and the lacquer painting after the construction can continue the longer afterglow time; Adopt this method that coating is had and continue long fluorescent lifetime; And inorganic long-afterglow material and epoxy resin compatibility are good, and terrace paint is easy to construction, and persistence is long.
Claims (10)
1. water-based energy storage luminescence floor coating, it is characterized in that: be made up of host and amine curing agent, by weight, described host is made up of following component:
Resins, epoxy 40-60 part
Luminescent powder 6-35 part of surface modification
Solid packing 10-25 part
Auxiliary agent 4-10 part
Solvent 15-30 part;
Amine curing agent 8-32 part.
2. water-based energy storage luminescence floor coating according to claim 1 is characterized in that: described Resins, epoxy is E-51 Resins, epoxy or E-54 Resins, epoxy.
3. water-based energy storage luminescence floor coating according to claim 1, it is characterized in that: the luminescent powder of described surface modification is the alkali earth metal aluminate long after glow luminous material that contains rare earth ion, fineness is carried out surface modification by silane coupling agent and is made more than 500 orders.
4. water-based energy storage luminescence floor coating according to claim 3 is characterized in that: described silane coupling agent is the silane coupling agent that contains vinyl.
5. water-based energy storage luminescence floor coating according to claim 1 is characterized in that: described solid packing is a talcum powder.
6. water-based energy storage luminescence floor coating according to claim 1 is characterized in that: described auxiliary agent is made up of following components by part by weight:
Dispersion agent 1.0-2.0 part flow agent 0.5-1.0 part defoamer 1.0-1.5 part
Cosolvent 1.0-2.5 part photostabilizer 0.1-1.5 part.
7. water-based energy storage luminescence floor coating according to claim 6 is characterized in that: described dispersion agent is selected macromolecule dispersing agent or polycarboxylate dispersion agent or both mixtures for use; Described flow agent adopts fluorine-carbon modified polyacrylate flow agent; Described defoamer adopts non-silicon defoamer; Described cosolvent is the butanols modified aminoresin of low degree of etherification.
8. water-based energy storage luminescence floor coating according to claim 1 is characterized in that: described solvent is the mixed solvent of ethanol, methylcarbonate and pimelinketone, and the weight ratio of described mixed solvent is 1: 1: 1.
9. water-based energy storage luminescence floor coating according to claim 1 is characterized in that: described amine curing agent is aliphatic amide, aliphatic cyclic amine or polymeric amide.
10. the preparation method of water-based energy storage luminescence floor coating according to claim 1, it is characterized in that: earlier the luminescent powder after the modification, Resins, epoxy, solid packing, auxiliary agent, solvent are mixed according to the above ratio, grind, get water-based energy storage luminescence floor coating host, then when application, host and amine curing agent mixed in proportion get final product.
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| CN200910018326A CN101638547A (en) | 2009-08-29 | 2009-08-29 | Water-based energy storage luminescence floor coating and preparation method thereof |
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| CN200910018326A CN101638547A (en) | 2009-08-29 | 2009-08-29 | Water-based energy storage luminescence floor coating and preparation method thereof |
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| CN102587255A (en) * | 2012-02-25 | 2012-07-18 | 福州皇家地坪有限公司 | Silicofluoride elastic terrace and manufacturing method thereof |
| CN102953533A (en) * | 2012-10-26 | 2013-03-06 | 浙江未来家木业有限公司 | Noctilucent floor board processing technology |
| CN103061487A (en) * | 2012-10-26 | 2013-04-24 | 浙江未来家木业有限公司 | Processing technique of noctilucent glazing floors |
| CN103232185A (en) * | 2013-05-08 | 2013-08-07 | 福州皇家地坪有限公司 | Terrace jointing material and application thereof |
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- 2009-08-29 CN CN200910018326A patent/CN101638547A/en active Pending
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| CN102587255A (en) * | 2012-02-25 | 2012-07-18 | 福州皇家地坪有限公司 | Silicofluoride elastic terrace and manufacturing method thereof |
| CN102953533A (en) * | 2012-10-26 | 2013-03-06 | 浙江未来家木业有限公司 | Noctilucent floor board processing technology |
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Application publication date: 20100203 |