CN101564203A - Method for manufacturing pineapple leaf fiber antibiosis health-protection socks - Google Patents
Method for manufacturing pineapple leaf fiber antibiosis health-protection socks Download PDFInfo
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- 239000000835 fiber Substances 0.000 title claims abstract description 62
- 235000007119 Ananas comosus Nutrition 0.000 title claims abstract description 60
- 238000000034 method Methods 0.000 title claims abstract description 35
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 244000099147 Ananas comosus Species 0.000 title 1
- 230000003115 biocidal effect Effects 0.000 title 1
- 241000234671 Ananas Species 0.000 claims abstract description 59
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 26
- 238000009987 spinning Methods 0.000 claims abstract description 17
- 238000005406 washing Methods 0.000 claims abstract description 9
- 229920000742 Cotton Polymers 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 7
- 239000012209 synthetic fiber Substances 0.000 claims abstract description 6
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 6
- 238000009941 weaving Methods 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
- 238000004043 dyeing Methods 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 10
- 238000000605 extraction Methods 0.000 claims description 9
- 239000004753 textile Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 239000000985 reactive dye Substances 0.000 claims description 6
- 238000007790 scraping Methods 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 5
- 238000009736 wetting Methods 0.000 claims description 5
- 239000000284 extract Substances 0.000 claims 1
- 241000894006 Bacteria Species 0.000 abstract description 5
- 241000233866 Fungi Species 0.000 abstract description 3
- 244000005700 microbiome Species 0.000 abstract description 3
- 102000011782 Keratins Human genes 0.000 abstract description 2
- 108010076876 Keratins Proteins 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 238000000354 decomposition reaction Methods 0.000 abstract description 2
- 210000004243 sweat Anatomy 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 6
- 238000009960 carding Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 2
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 2
- 235000009120 camo Nutrition 0.000 description 2
- 235000005607 chanvre indien Nutrition 0.000 description 2
- 239000011487 hemp Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 208000014770 Foot disease Diseases 0.000 description 1
- 208000008454 Hyperhidrosis Diseases 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 206010047601 Vitamin B1 deficiency Diseases 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000000022 bacteriostatic agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 208000002894 beriberi Diseases 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 208000013460 sweaty Diseases 0.000 description 1
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Abstract
本发明公开了一种菠萝叶纤维抗菌保健袜子的制造方法，它包括以下工序：纺纱-染色-织袜，所述纺纱工艺流程为：开松-给湿-混棉-开清棉-梳棉-并条-粗纱-细纱，其特征在于：所述纺纱所用的材料为菠萝叶纤维、棉纤维和合成纤维，其中，菠萝叶纤维重量份的含量占10～60％，其它纤维占40～90％。由于纺纱所用的材料中包含菠萝叶纤维，使该袜子不仅具有柔软爽滑，穿着舒适的特点，而且还具有良好的吸湿放湿透气性能和强大的天然杀菌抑菌功能，可有效杀灭足部细菌、抑制真菌和微生物的生长，使汗液、角质蛋白分解活动大大降低，从而有效防止脚臭。经大量试穿证明，菠萝叶纤维袜连续穿着六天，甚至十余天，不洗不换而不臭。The invention discloses a method for manufacturing pineapple leaf fiber antibacterial health care socks, which comprises the following steps: spinning-dyeing-socks weaving, the spinning process is: opening-wetting-mixing-opening and cleaning- Carding-drawing-roving-spun yarn is characterized in that: the materials used for the spinning are pineapple leaf fiber, cotton fiber and synthetic fiber, wherein the content of pineapple leaf fiber by weight accounts for 10-60%, and other fibers account for 40-90%. Because the material used in spinning contains pineapple leaf fiber, the socks are not only soft, smooth, and comfortable to wear, but also have good moisture absorption, moisture release and breathability, and strong natural antibacterial and antibacterial functions, which can effectively kill bacteria. Foot bacteria, inhibit the growth of fungi and microorganisms, greatly reduce sweat and keratin decomposition activities, thus effectively preventing foot odor. It has been proven by a large number of try-ons that the pineapple leaf fiber socks can be worn continuously for six days, or even more than ten days, without washing or changing without smelling.
Description
技术领域 technical field
本发明涉及一种袜子的制造方法，具体是一种菠萝叶纤维抗菌保健袜子的制造方法。The invention relates to a method for manufacturing socks, in particular to a method for manufacturing pineapple leaf fiber antibacterial health care socks.
背景技术 Background technique
菠萝叶纤维是从菠萝叶片中提取出来的天然植物纤维。有关研究表明，这种纤维经加工处理后，外观洁白，柔软爽滑，手感如蚕丝似亚麻，纤维组织内部特殊的超细微孔结构，具有较一般麻更快速吸收和蒸发水分的性能，是一种优异的天然保健新型纺织材料。其开发利用引起了世界范围的极大关注，目前，日本、菲律宾、印度和台湾都在积极开发菠萝叶纤维产品。Pineapple leaf fiber is a natural plant fiber extracted from pineapple leaves. Relevant studies have shown that after the fiber is processed, its appearance is white, soft and smooth, and it feels like silk like flax. The special ultra-fine microporous structure inside the fiber tissue has the performance of absorbing and evaporating water faster than ordinary hemp. An excellent new textile material for natural health care. Its development and utilization have attracted great attention worldwide. At present, Japan, the Philippines, India and Taiwan are all actively developing pineapple leaf fiber products.
在日常生活中，不少人深受脚部多汗、脚臭，甚至脚气等足疾的困扰。目前市场上大多数防臭袜都是将各种抗菌剂通过化学的或物理的方法结合在袜类织物上，以其药物作用达到抗菌除臭的目的。经几次水洗后，抗菌物质便逐渐减少，耐洗涤性不佳，抗菌效果也不理想。In daily life, many people suffer from foot diseases such as sweaty feet, foot odor, and even beriberi. Most of the anti-odor socks on the market are to combine various antibacterial agents on the hosiery fabric by chemical or physical methods, and achieve the purpose of antibacterial and deodorizing with its drug effect. After several times of washing, the antibacterial substances will gradually decrease, the washing resistance is not good, and the antibacterial effect is not ideal.
发明内容 Contents of the invention
为了克服上述之不足，本发明的目的在于提供一种天然抗菌并且抗菌效果好的菠萝叶纤维抗菌保健袜子的制造方法。In order to overcome above-mentioned deficiencies, the object of the present invention is to provide a kind of manufacture method of natural antibacterial and good pineapple leaf fiber antibacterial health socks of antibacterial effect.
为解决上述技术问题，本发明所采用的技术方案是：一种菠萝叶纤维抗菌保健袜子的制造方法，它包括以下工序：纺纱——染色——织袜，所述纺纱工艺流程为：开松——给湿——混棉——开清棉——梳棉——并条——粗纱——细纱，其特征在于：所述纺纱所用的材料为菠萝叶纤维、其它纺织纤维，其中，菠萝叶纤维重量份的含量占10～60％，其它纺织纤维占40～90％。In order to solve the above-mentioned technical problems, the technical solution adopted in the present invention is: a kind of manufacture method of pineapple leaf fiber antibacterial health care socks, which comprises the following steps: spinning—dyeing—weaving socks, and the spinning process flow is: Opening—wetting—mixing cotton—opening and cleaning—carding—drawing—roving—spun yarn, characterized in that: the materials used for spinning are pineapple leaf fibers and other textile fibers, Among them, the pineapple leaf fiber accounts for 10-60% by weight, and other textile fibers account for 40-90%.
所述其它纺织纤维是棉纤维或合成纤维。The other textile fibers are cotton fibers or synthetic fibers.
所述纺纱所用的材料中，菠萝叶纤维最佳的重量份的含量占20～40％，其它纺织纤维的含量为60～80％。Among the materials used for spinning, the optimum content of pineapple leaf fiber is 20-40% by weight, and the content of other textile fibers is 60-80%.
所述菠萝叶纤维的提取方法是：所述菠萝叶纤维的提取是以菠萝叶片为原料通过专用的菠萝叶刮麻机对其进行提取。The extraction method of the pineapple leaf fiber is as follows: the extraction of the pineapple leaf fiber is to extract the pineapple leaf through a special pineapple leaf scraping machine as raw material.
所述纺纱的给湿工序中，给湿乳剂的用量为菠萝叶纤维重量的2～6％，给湿乳剂与水混合的重量比为1∶5～15。In the wetting process of spinning, the amount of the wetting emulsion used is 2-6% of the weight of the pineapple leaf fiber, and the weight ratio of the wetting emulsion mixed with water is 1:5-15.
所述染色工艺流程中：上染的浴比1∶40～60，活性染料5～20％，NaCl 15～70g/L，活性染料和NaCl是在水加热升温的过程中分三次加入的，水温达到60～80℃后，保温20～25分钟；所述碱性固色工艺中：所用的NaCO3为5～20g/L，固色时间为90～120分钟。皂洗工艺中，所用的NaCO3为0.5g/L。热洗水温为50～70℃，固色剂的用量0.6～1.5g/L，柔软剂用量1～2g/L。In the dyeing process flow: the bath ratio of dyeing is 1:40-60, the reactive dye is 5-20%, and NaCl is 15-70g/L. The reactive dye and NaCl are added in three times during the process of heating the water. After reaching 60-80°C, keep warm for 20-25 minutes; in the alkaline color-fixing process: the NaCO 3 used is 5-20 g/L, and the color-fixing time is 90-120 minutes. In the soaping process, the NaCO3 used is 0.5g/L. The temperature of hot washing water is 50-70°C, the dosage of color fixing agent is 0.6-1.5g/L, and the dosage of softener is 1-2g/L.
经国家棉纺织产品质量监督检验中心和地方检测机构分别按国际标准和我国卫生标准检验证明，菠萝叶纤维含有天然杀菌、抑菌物质，可有效杀灭细菌、抑制真菌和微生物的生长。而菠萝叶纤维的抗菌性来自纤维自身的天然杀菌抑菌物质，不受外部环境影响，可保持持久的抗菌功效。The National Cotton Textile Product Quality Supervision and Inspection Center and local testing agencies have tested and proved that pineapple leaf fiber contains natural bactericidal and bacteriostatic substances, which can effectively kill bacteria and inhibit the growth of fungi and microorganisms. The antibacterial property of pineapple leaf fiber comes from the natural bactericidal and antibacterial substances of the fiber itself, which is not affected by the external environment and can maintain a long-lasting antibacterial effect.
本发明的有益效果在于：由于纺纱所用的材料中包含菠萝叶纤维，使该袜子不仅具有柔软爽滑，穿着舒适的特点，而且还具有良好的吸湿放湿透气性能和强大的天然杀菌抑菌功能，可有效杀灭足部细菌、抑制真菌和微生物的生长，使汗液、角质蛋白分解活动大大降低，从而有效防止脚臭。经大量试穿证明，菠萝麻袜连续穿着六天，甚至十余天，不洗不换而不臭。The beneficial effect of the invention is that: because the material used for spinning contains pineapple leaf fiber, the socks not only have the characteristics of softness, smoothness, and comfort, but also have good moisture absorption, moisture release, breathability and strong natural antibacterial and antibacterial properties. Bacteria function, can effectively kill foot bacteria, inhibit the growth of fungi and microorganisms, greatly reduce the decomposition of sweat and keratin, thus effectively preventing foot odor. It has been proven by a large number of try-ons that pineapple hemp socks can be worn continuously for six days, or even more than ten days, without washing or changing without smelling.
具体实施例 specific embodiment
实施例1：一种菠萝叶纤维抗菌保健袜子的制造方法，该方法包括以下工序：菠萝叶纤维提取——脱胶-纺纱——染色——织袜。菠萝叶纤维提取采用的原料是菠萝叶片，采用的提取方法是通过专用的菠萝叶刮麻机提取，专用的菠萝叶刮麻机我们已申请专利，在此不再详述。脱胶方法采用传统的化学脱胶。所述纺纱是由菠萝叶纤维、棉纤维和合成纤维混纺，其中菠萝叶纤维的含量占10％(重量份)，其它纤维占90％。Embodiment 1: A kind of manufacture method of pineapple leaf fiber antibacterial health socks, the method comprises the following steps: pineapple leaf fiber extraction——degumming—spinning—dyeing—socks weaving. The raw material used for the extraction of pineapple leaf fiber is pineapple leaves, and the extraction method adopted is to extract through a special pineapple leaf scraping machine. We have applied for a patent for the dedicated pineapple leaf scraping machine, and will not describe it in detail here. The degumming method adopts traditional chemical degumming. The spinning is blended with pineapple leaf fiber, cotton fiber and synthetic fiber, wherein the content of pineapple leaf fiber accounts for 10% (by weight), and other fibers account for 90%.
纺纱工艺流程为：开松——给湿——混棉——开清棉——梳棉——并条——粗纱——细纱，其中，给湿工艺中，给湿乳剂的用量为菠萝叶纤维重量的2％，乳剂与水的混合比例为1∶5。The spinning process is: opening - wet - blending - opening and cleaning - carding - drawing - roving - spun yarn, wherein, in the wet process, the amount of wet emulsion is pineapple 2% of leaf fiber weight, the mixing ratio of emulsion and water is 1:5.
染色工艺流程为：上染——碱性固色——水洗——皂洗——热洗——加固色剂、柔软剂。其中，上染工艺中：浴比为1∶40，温度为60～80℃，活性染料为(重量份)5％，NaCl 15g/L；碱性固色工艺中，所用的NaCO3为5g/L，固色时间为120分钟；皂洗工艺中，所用的NaCO3为0.5g/L。热洗水温为50℃，固色剂的用量0.6g/L，柔软剂用量1g/L。The dyeing process is: dyeing—alkaline color fixing—water washing—soaping—hot washing—color fixing agent and softener. Wherein, in the dyeing process: the bath ratio is 1:40, the temperature is 60-80°C, the reactive dye is (parts by weight) 5%, NaCl 15g/L; in the alkaline color-fixing process, the NaCO used is 5g /L L, the color fixing time is 120 minutes; in the soaping process, the NaCO 3 used is 0.5g/L. The hot washing water temperature is 50°C, the amount of color fixing agent is 0.6g/L, and the amount of softener is 1g/L.
实施例2：一种菠萝叶纤维抗菌保健袜子的制造方法，该方法包括以下工序：菠萝叶纤维提取——脱胶-纺纱——染色——织袜。菠萝叶纤维提取采用的原料是菠萝叶片，采用的提取方法是通过菠萝叶刮麻机提取。脱胶方法采用传统的化学脱胶。所述纺纱是由菠萝叶纤维、棉纤维和合成纤维混纺，其中菠萝叶纤维的含量占60％(重量份)，其它纤维占40％。Embodiment 2: A manufacturing method of pineapple leaf fiber antibacterial health care socks, the method comprises the following steps: pineapple leaf fiber extraction——degumming—spinning—dyeing—socks weaving. The raw material used in pineapple leaf fiber extraction is pineapple leaves, and the extraction method adopted is to extract through a pineapple leaf scraping machine. The degumming method adopts traditional chemical degumming. The spinning is blended with pineapple leaf fiber, cotton fiber and synthetic fiber, wherein the content of pineapple leaf fiber accounts for 60% (parts by weight), and other fibers account for 40%.
纺纱工艺流程为：开松——给湿——混棉——开清棉——梳棉——并条——粗纱——细纱，其中，给湿工艺中，给湿乳剂的用量为菠萝叶纤维重量的6％，乳剂与水的混合比例为1∶15。The spinning process is: opening - wet - blending - opening and cleaning - carding - drawing - roving - spun yarn, wherein, in the wet process, the amount of wet emulsion is pineapple 6% of leaf fiber weight, the mixing ratio of emulsion and water is 1:15.
染色工艺流程为：上染-碱性固色-水洗-皂洗-热洗——加固色剂、柔软剂。其中，上染工艺中，浴比为1∶60，温度为60～80℃，活性染料为(重量份)20％，NaCl 70g/L；碱性固色工艺中，所用的NaCO3为20g/L，固色时间为90分钟；皂洗工艺中，所用的NaCO3为0.5g/L。热洗水温为70℃，固色剂的用量1.5g/L，柔软剂用量2g/L。The dyeing process is: dyeing-alkaline color fixing-washing-soaping-hot washing-color-fixing agent and softener. Wherein, in the dyeing process, the bath ratio is 1:60, the temperature is 60-80°C, the reactive dye is (parts by weight) 20%, and NaCl 70g/L; in the alkaline color-fixing process, the NaCO used is 20g /L L, the color fixing time is 90 minutes; in the soaping process, the NaCO 3 used is 0.5g/L. The hot washing water temperature is 70°C, the amount of color fixing agent is 1.5g/L, and the amount of softener is 2g/L.
实施例3：一种菠萝叶纤维抗菌保健袜子的制造方法，该方法包括以下工序：菠萝叶纤维提取——脱胶-纺纱——染色——织袜。菠萝叶纤维提取采用的原料是菠萝叶片，采用的提取方法是通过菠萝叶刮麻机提取。脱胶方法采用传统的化学脱胶。所述纺纱是由菠萝叶纤维、棉纤维和合成纤维混纺，其中菠萝叶纤维的含量占30％(重量份)，其它纤维占70％。Embodiment 3: A kind of manufacturing method of pineapple leaf fiber antibacterial health socks, the method comprises the following steps: pineapple leaf fiber extraction——degumming—spinning—dyeing—socks weaving. The raw material used in pineapple leaf fiber extraction is pineapple leaves, and the extraction method adopted is to extract through a pineapple leaf scraping machine. The degumming method adopts traditional chemical degumming. The spinning is blended with pineapple leaf fiber, cotton fiber and synthetic fiber, wherein the content of pineapple leaf fiber accounts for 30% (by weight), and other fibers account for 70%.
纺纱工艺流程为：开松——给湿——混棉——开清棉——梳棉——并条——粗纱——细纱，其中，给湿工艺中，给湿乳剂的用量为菠萝叶纤维重量的4％，乳剂与水的混合比例为1∶10。The spinning process is: opening - wet - blending - opening and cleaning - carding - drawing - roving - spun yarn, wherein, in the wet process, the amount of wet emulsion is pineapple 4% of leaf fiber weight, the mixing ratio of emulsion and water is 1:10.
染色工艺流程为：上染-碱性固色-水洗-皂洗-热洗——加固色剂、柔软剂。其中，上染工艺中，浴比为1∶50，温度为60～80℃，活性染料为(重量份)12％，NaCl为42g/L；碱性固色工艺中，所用的NaCO3为12g/L，固色时间为105分钟；皂洗工艺中，所用的NaCO3为0.5g/L。热洗水温为60℃，固色剂的用量1.0g/L，柔软剂用量1.5g/L。The dyeing process is: dyeing-alkaline color fixing-washing-soaping-hot washing-color-fixing agent and softener. Wherein, in the dyeing process, the bath ratio is 1:50, the temperature is 60-80°C, the reactive dye is (parts by weight) 12%, and NaCl is 42g/L; in the alkaline color-fixing process, the NaCO used is 12g /L, the color fixing time is 105 minutes; in the soaping process, the NaCO 3 used is 0.5g/L. The hot washing water temperature is 60°C, the amount of color fixing agent is 1.0g/L, and the amount of softener is 1.5g/L.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102733024A (en) * | 2011-04-01 | 2012-10-17 | 上海水星家用纺织品股份有限公司 | Preparation method and application for pineapple fiber yarns |
| CN102805428A (en) * | 2012-08-27 | 2012-12-05 | 中国热带农业科学院农业机械研究所 | Pineapple leaf fiber socks relieving diabetic feet and application thereof |
| CN103504665A (en) * | 2013-10-24 | 2014-01-15 | 吴江市曼特思纺织有限公司 | Multifunctional antibacterial deodorant fabric |
| CN103510244A (en) * | 2013-09-29 | 2014-01-15 | 吴江市凌通纺织整理有限公司 | Multifunctional kapok fiber fabric |
| CN103668671A (en) * | 2013-12-04 | 2014-03-26 | 苏州新米纺织咨询服务有限公司 | Weight-reducing cellulose acetate fiber fabric |
| CN104060379A (en) * | 2014-06-25 | 2014-09-24 | 江苏东源纺织科技实业有限公司 | Production process of natural health-care anti-bacterial knitted fabric |
| CN106854784A (en) * | 2016-12-18 | 2017-06-16 | 佛山潮伊汇服装有限公司 | The preparation method of arghan mixed yarn and arghan mixed yarn |
| CN107173914A (en) * | 2017-07-14 | 2017-09-19 | 盐城工业职业技术学院 | Shoe-pad and its preparation technology |
-
2009
- 2009-05-20 CN CNA2009100396173A patent/CN101564203A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102733024A (en) * | 2011-04-01 | 2012-10-17 | 上海水星家用纺织品股份有限公司 | Preparation method and application for pineapple fiber yarns |
| CN102805428A (en) * | 2012-08-27 | 2012-12-05 | 中国热带农业科学院农业机械研究所 | Pineapple leaf fiber socks relieving diabetic feet and application thereof |
| CN103510244A (en) * | 2013-09-29 | 2014-01-15 | 吴江市凌通纺织整理有限公司 | Multifunctional kapok fiber fabric |
| CN103504665A (en) * | 2013-10-24 | 2014-01-15 | 吴江市曼特思纺织有限公司 | Multifunctional antibacterial deodorant fabric |
| CN103668671A (en) * | 2013-12-04 | 2014-03-26 | 苏州新米纺织咨询服务有限公司 | Weight-reducing cellulose acetate fiber fabric |
| CN104060379A (en) * | 2014-06-25 | 2014-09-24 | 江苏东源纺织科技实业有限公司 | Production process of natural health-care anti-bacterial knitted fabric |
| CN104060379B (en) * | 2014-06-25 | 2016-03-02 | 江苏东源纺织科技实业有限公司 | The production technology of natural health antibiosis knitting face fabric |
| CN106854784A (en) * | 2016-12-18 | 2017-06-16 | 佛山潮伊汇服装有限公司 | The preparation method of arghan mixed yarn and arghan mixed yarn |
| CN107173914A (en) * | 2017-07-14 | 2017-09-19 | 盐城工业职业技术学院 | Shoe-pad and its preparation technology |
| CN107173914B (en) * | 2017-07-14 | 2020-06-02 | 盐城工业职业技术学院 | Shoe pad and preparation process thereof |
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Application publication date: 20091028 |