CN101502260A - Highly-effective pesticide spread moistening osmotic agent - Google Patents
Highly-effective pesticide spread moistening osmotic agent Download PDFInfo
- Publication number
- CN101502260A CN101502260A CNA2009101275481A CN200910127548A CN101502260A CN 101502260 A CN101502260 A CN 101502260A CN A2009101275481 A CNA2009101275481 A CN A2009101275481A CN 200910127548 A CN200910127548 A CN 200910127548A CN 101502260 A CN101502260 A CN 101502260A
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- CN
- China
- Prior art keywords
- surfactant
- moistening
- highly
- effective pesticide
- osmotic agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000575 pesticide Substances 0.000 title claims abstract description 22
- 239000002357 osmotic agent Substances 0.000 title claims description 14
- 239000004094 surface-active agent Substances 0.000 claims abstract description 22
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 9
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 7
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 7
- 239000003960 organic solvent Substances 0.000 claims abstract description 5
- 239000000945 filler Substances 0.000 claims abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- -1 Alkylpyridyl halide Chemical class 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 3
- 125000006177 alkyl benzyl group Chemical group 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 3
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims description 2
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000003973 alkyl amines Chemical class 0.000 claims description 2
- 239000007859 condensation product Substances 0.000 claims description 2
- 239000012766 organic filler Substances 0.000 claims description 2
- 239000001384 succinic acid Substances 0.000 claims description 2
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 2
- GYICYQJEVCIYJY-UHFFFAOYSA-N thiophen-1-ylidenemethanone Chemical compound O=C=S1C=CC=C1 GYICYQJEVCIYJY-UHFFFAOYSA-N 0.000 claims description 2
- 125000005526 alkyl sulfate group Chemical group 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 5
- 230000000361 pesticidal effect Effects 0.000 abstract description 5
- 238000009736 wetting Methods 0.000 abstract description 5
- 239000007788 liquid Substances 0.000 abstract description 3
- 230000035515 penetration Effects 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract 3
- 230000000996 additive effect Effects 0.000 abstract 3
- 230000000149 penetrating effect Effects 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 1
- 230000001256 tonic effect Effects 0.000 abstract 1
- 239000003905 agrochemical Substances 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 7
- 239000002671 adjuvant Substances 0.000 description 6
- 239000002917 insecticide Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000012856 packing Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- 235000014347 soups Nutrition 0.000 description 2
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000008051 alkyl sulfates Chemical group 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 239000001120 potassium sulphate Substances 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses a highly effective pesticide spreading wetting penetrating agent which is prepared by mixing the surfactant, the additive and emulsifying agent, wherein the contents of each component are as follows according to the weight percentage: 30-60% of surfactant, 30-60% of additive and 4-180% of emulsifying agent. The surfactant is anionic surfactant, cationic surfactant or non-tonic surfactant. The additive is organic solvent or filling agent. The highly effective pesticide spreading wetting penetrating agent according to the invention has the advantages of simple preparing technique, wide application sphere, convenient use, stronger spreading wetting penetrability, promotion of pesticide liquid penetration through the target ceraceous layer, greatly enhanced pesticide activity, excellent economic benefit and social benefit.
Description
Technical field
The present invention relates to technical field of pesticide, be specifically related to a kind of highly-effective pesticide spread moistening osmotic agent that can increase pesticide activity.
Background technology
In the face of the serious day by day environmental pollution in the whole world; environmental protection worldwide has been subjected to paying attention to widely; various countries have also formulated the laws and regulations of many strictnesses thus, wherein, and at the safety of agricultural chemicals with prevent that the rule and standard of pesticide pollution environment have been subjected to paying close attention to widely in recent years.
Agricultural chemicals is well-known to the effect of agricultural high yield, but the influence of environmental pollution also is very important.Follow the proposition of environmentally friendly agricultural chemicals or environmentally friendly type agricultural chemicals, development environmental protection type agricultural chemical preparation becomes the main flow of current pesticide industry.Under this development trend, insecticides adjuvant must adapt to the trend of environmental protection type agricultural chemical preparation as the important component part in the preparation processing.
Which kind of insecticide-applying way no matter, target has only contact and absorbed agricultural chemicals just can make drug effect be brought into play, the state of this contact and absorption always with soup can be smoothly target itself reach surrounding space adhere to, hold stay, wetting, spread and infiltration have direct relation.Insecticides adjuvant does not originally have biologically active on one's body, but can strengthen the control efficiency of agricultural chemicals.The wet malleability of utilizing auxiliary agent that agricultural chemicals is strengthened on target can and increase hold-up, strengthens agent molecule arranging exhibits on blade face or polypide, promotes the absorption of medicament, thereby reaches the enhancing control efficiency.
Insecticides adjuvant is in the preparation of the formulations of pesticide and give aspect such as the best effectiveness of active ingredient and play a part important.Main auxiliary agent related in the form formula has: the antipoison of dispersant, wetting agent, emulsifier, synergist, bleeding agent, spreader-sticker, sticker, stabilizing agent, thickener, film forming agent, anticoalescent, anti-caking agent, disintegrant, defoamer, anti-drift agent, antistatic agent, poisoning palliative, weed killer herbicide and propellant etc.
The development of China's insecticides adjuvant is from emulsifier research, exploitation, but over all, except that emulsifier, other insecticides adjuvant kind is few, and some auxiliary agent is still blank.China's insecticides adjuvant is big with the developed countries gap on the kind quality and quantity, has restricted the raising of China's pesticidal preparations quality and the development of novel form.
Summary of the invention
The purpose of this invention is to provide a kind of highly-effective pesticide spread moistening osmotic agent that can increase pesticide activity, it can reduce surface tension of liquid effectively, reduces solid/liquid interfaces tension force, change drop at the lip-deep contact angle of target, the wet malleability that agricultural chemicals is strengthened on target can and increase hold-up, strengthen agent molecule arranging exhibits on blade face or polypide, promote the absorption of medicament, thereby reach the enhancing control efficiency.
The technical solution adopted in the present invention is:
A kind of highly-effective pesticide spread moistening osmotic agent is formed through being mixed with by surfactant, auxiliary agent and emulsifier, and wherein each components contents is by weight percentage: surfactant 30～60%, auxiliary agent 30～60%, emulsifier 4～18%.Described surfactant is anion surfactant, cationic surfactant or non-ionic surface active agent; Described auxiliary agent is organic solvent or filler.
Described anion surfactant is alkyl sulfate, alkylbenzenesulfonate, fatty alcohol-polyoxyethylene ether formaldehyde condensation products, succinic acid half ester sulfonate, fatty acid or fatty acid ester sulphate.
Described cationic surfactant is alkyl benzyl dimethyl ammonium chloride, Alkylpyridyl halide or alkyl amine oxide.
Described non-ionic surface active agent is alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, aliphatic acid polyethenoxy monoester, azone, thiophene ketone or organosilicon.
Described organic solvent is dimethylbenzene, acetone, ethanol, ethyl acetate or cyclohexanone.
Described filler is kaolin, diatomite, bentonite, white carbon or concavo-convex rod.
In order to increase useful effect of the present invention better, described surfactant is to be mixed by anion surfactant and non-ionic surface active agent, and wherein its proportioning is 1:5～5:1 by weight.
Described surfactant is to be mixed by cationic surfactant and non-ionic surface active agent, and wherein its proportioning is 1:5～5:1 by weight.
Highly-effective pesticide spread moistening osmotic agent preparation technology provided by the present invention is simple, equipment investment is few, can be used in Multiple Pesticides and the various preparation, applied widely, easy to use, have the stronger wetting penetration of opening up, promote soup quick penetration target wax coat, pesticide activity is strengthened greatly, have good economic benefit and social benefit.
Embodiment
The invention will be further described with non-limiting embodiment below.
Embodiment one
Get sodium alkyl sulfate 50g, dimethylbenzene 40g, calcium dodecyl benzene sulfonate 10g, mix, packing makes finished product.
Embodiment two
Get fatty acid ester potassium sulphate 30, alkylphenol polyoxyethylene 20g, ethanol 45g, dibenzyl xenyl APEO 5g, mix, packing makes finished product.
Embodiment three
Get alkyl benzyl dimethyl ammonium chloride 20g, fatty alcohol-polyoxyethylene ether 40g, ethanol 30g, alkyl phenol polyoxyethylene polyoxypropylene ether 10g, mix, packing makes finished product.
Embodiment four
Get alkylphenol polyoxyethylene 40g, kaolin 45g, calcium dodecyl benzene sulfonate 15g, mix, packing makes finished product.
Embodiment five
Get organosilicon 50g, bentonite 40g, phenethyl phenyl APEO 10g, mix, packing makes finished product.
Claims (8)
1, a kind of highly-effective pesticide spread moistening osmotic agent, it is characterized in that: formed through being mixed with by surfactant, auxiliary agent and emulsifier, wherein each components contents is by weight percentage: surfactant 30～60%, auxiliary agent 30～60%, emulsifier 4～18%; Described surfactant is anion surfactant, cationic surfactant or non-ionic surface active agent; Described auxiliary agent is organic solvent or filler.
2, highly-effective pesticide spread moistening osmotic agent according to claim 1 is characterized in that: described anion surfactant is alkyl sulfate, alkylbenzenesulfonate, fatty alcohol-polyoxyethylene ether formaldehyde condensation products, succinic acid half ester sulfonate, fatty acid or fatty acid ester sulphate.
3, highly-effective pesticide spread moistening osmotic agent according to claim 1 is characterized in that: described cationic surfactant is alkyl benzyl dimethyl ammonium chloride, Alkylpyridyl halide or alkyl amine oxide.
4, highly-effective pesticide spread moistening osmotic agent according to claim 1 is characterized in that: described non-ionic surface active agent is alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, aliphatic acid polyethenoxy monoester, azone, thiophene ketone or organosilicon.
5, highly-effective pesticide spread moistening osmotic agent according to claim 1 is characterized in that: described organic solvent is dimethylbenzene, acetone, ethanol, ethyl acetate or cyclohexanone.
6, highly-effective pesticide spread moistening osmotic agent according to claim 1 is characterized in that: described filler is kaolin, diatomite, bentonite, white carbon or concavo-convex rod.
7, highly-effective pesticide spread moistening osmotic agent according to claim 1 is characterized in that: described surfactant is to be mixed by anion surfactant and non-ionic surface active agent, and wherein its proportioning is 1:5～5:1 by weight.
8, highly-effective pesticide spread moistening osmotic agent according to claim 1 is characterized in that: described surfactant is to be mixed by cationic surfactant and non-ionic surface active agent, and wherein its proportioning is 1:5～5:1 by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009101275481A CN101502260A (en) | 2009-03-13 | 2009-03-13 | Highly-effective pesticide spread moistening osmotic agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009101275481A CN101502260A (en) | 2009-03-13 | 2009-03-13 | Highly-effective pesticide spread moistening osmotic agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101502260A true CN101502260A (en) | 2009-08-12 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2009101275481A Pending CN101502260A (en) | 2009-03-13 | 2009-03-13 | Highly-effective pesticide spread moistening osmotic agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101502260A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103493804A (en) * | 2013-09-30 | 2014-01-08 | 浙江海正化工股份有限公司 | Compound pesticide wetting agent and application of compound pesticide wetting agent in preparation of pesticide preparations |
| CN103814893A (en) * | 2014-03-13 | 2014-05-28 | 中国农科院植保所廊坊农药中试厂 | Compound pesticide synergist and application of compound pesticide synergist in pesticide preparations |
| CN107041366A (en) * | 2016-12-14 | 2017-08-15 | 东至绿洲环保化工有限公司 | A kind of bleeding agent added applied to agricultural chemicals |
| CN111134122A (en) * | 2018-11-06 | 2020-05-12 | 中国科学院化学研究所 | An efficient spreader that promotes the complete spreading of water droplets on superhydrophobic surfaces |
| CN111233551A (en) * | 2020-02-11 | 2020-06-05 | 济南艾高特生物技术有限公司 | Compound for improving utilization rate of pesticide and fertilizer, preparation method and application thereof |
| CN114190372A (en) * | 2020-09-17 | 2022-03-18 | 广州斯宾科技有限公司 | An ion suspension synergist for disinfection equipment |
-
2009
- 2009-03-13 CN CNA2009101275481A patent/CN101502260A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103493804A (en) * | 2013-09-30 | 2014-01-08 | 浙江海正化工股份有限公司 | Compound pesticide wetting agent and application of compound pesticide wetting agent in preparation of pesticide preparations |
| CN103814893A (en) * | 2014-03-13 | 2014-05-28 | 中国农科院植保所廊坊农药中试厂 | Compound pesticide synergist and application of compound pesticide synergist in pesticide preparations |
| CN107041366A (en) * | 2016-12-14 | 2017-08-15 | 东至绿洲环保化工有限公司 | A kind of bleeding agent added applied to agricultural chemicals |
| CN111134122A (en) * | 2018-11-06 | 2020-05-12 | 中国科学院化学研究所 | An efficient spreader that promotes the complete spreading of water droplets on superhydrophobic surfaces |
| CN111134122B (en) * | 2018-11-06 | 2021-07-27 | 中国科学院化学研究所 | An efficient spreader that promotes the complete spreading of water droplets on superhydrophobic surfaces |
| CN111233551A (en) * | 2020-02-11 | 2020-06-05 | 济南艾高特生物技术有限公司 | Compound for improving utilization rate of pesticide and fertilizer, preparation method and application thereof |
| CN111233551B (en) * | 2020-02-11 | 2022-05-13 | 济南艾高特生物技术有限公司 | Compound for improving utilization rate of pesticide and fertilizer, preparation method and application thereof |
| CN114190372A (en) * | 2020-09-17 | 2022-03-18 | 广州斯宾科技有限公司 | An ion suspension synergist for disinfection equipment |
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Open date: 20090812 |