CN107646837A - A kind of green and environment-friendly pesticide spray adjuvantses composition - Google Patents
A kind of green and environment-friendly pesticide spray adjuvantses composition Download PDFInfo
- Publication number
- CN107646837A CN107646837A CN201610597280.8A CN201610597280A CN107646837A CN 107646837 A CN107646837 A CN 107646837A CN 201610597280 A CN201610597280 A CN 201610597280A CN 107646837 A CN107646837 A CN 107646837A
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- CN
- China
- Prior art keywords
- composition
- spray
- spray adjuvantses
- agricultural chemicals
- adjuvantses
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000007921 spray Substances 0.000 title claims abstract description 74
- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 239000000575 pesticide Substances 0.000 title claims abstract description 31
- 239000003905 agrochemical Substances 0.000 claims abstract description 27
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 11
- 239000003292 glue Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 238000009472 formulation Methods 0.000 claims abstract description 6
- 230000002363 herbicidal effect Effects 0.000 claims abstract description 5
- 239000002917 insecticide Substances 0.000 claims abstract description 5
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 239000003899 bactericide agent Substances 0.000 claims abstract description 4
- 239000005648 plant growth regulator Substances 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims abstract description 4
- 239000004009 herbicide Substances 0.000 claims abstract 3
- 239000004615 ingredient Substances 0.000 claims abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 16
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 7
- 229920001285 xanthan gum Polymers 0.000 claims description 7
- 239000005452 food preservative Substances 0.000 claims description 5
- 235000019249 food preservative Nutrition 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 239000005711 Benzoic acid Substances 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 235000010233 benzoic acid Nutrition 0.000 claims description 4
- 235000010199 sorbic acid Nutrition 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 3
- 239000004530 micro-emulsion Substances 0.000 claims description 3
- 239000004334 sorbic acid Substances 0.000 claims description 3
- 229940075582 sorbic acid Drugs 0.000 claims description 3
- 239000004563 wettable powder Substances 0.000 claims description 3
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 claims description 2
- 241000206575 Chondrus crispus Species 0.000 claims description 2
- 244000303965 Cyamopsis psoralioides Species 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 229920000161 Locust bean gum Polymers 0.000 claims description 2
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- 229940095100 fulvic acid Drugs 0.000 claims description 2
- 239000002509 fulvic acid Substances 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 125000005456 glyceride group Chemical group 0.000 claims description 2
- 235000010420 locust bean gum Nutrition 0.000 claims description 2
- 239000000711 locust bean gum Substances 0.000 claims description 2
- 239000001814 pectin Substances 0.000 claims description 2
- 235000010987 pectin Nutrition 0.000 claims description 2
- 229920001277 pectin Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 2
- 229930182490 saponin Natural products 0.000 claims description 2
- 150000007949 saponins Chemical class 0.000 claims description 2
- 229920002148 Gellan gum Polymers 0.000 claims 2
- 229920002752 Konjac Polymers 0.000 claims 2
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 claims 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims 1
- 229920001817 Agar Polymers 0.000 claims 1
- 235000016068 Berberis vulgaris Nutrition 0.000 claims 1
- 241000335053 Beta vulgaris Species 0.000 claims 1
- 244000241257 Cucumis melo Species 0.000 claims 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 claims 1
- 239000001879 Curdlan Substances 0.000 claims 1
- 229920002558 Curdlan Polymers 0.000 claims 1
- 229920002581 Glucomannan Polymers 0.000 claims 1
- 240000006240 Linum usitatissimum Species 0.000 claims 1
- 235000004431 Linum usitatissimum Nutrition 0.000 claims 1
- 229920002774 Maltodextrin Polymers 0.000 claims 1
- 239000005913 Maltodextrin Substances 0.000 claims 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 claims 1
- 235000010489 acacia gum Nutrition 0.000 claims 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims 1
- 239000008272 agar Substances 0.000 claims 1
- 235000010419 agar Nutrition 0.000 claims 1
- 125000005233 alkylalcohol group Chemical group 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims 1
- 235000015165 citric acid Nutrition 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 235000019316 curdlan Nutrition 0.000 claims 1
- 229940078035 curdlan Drugs 0.000 claims 1
- 235000004426 flaxseed Nutrition 0.000 claims 1
- 235000010492 gellan gum Nutrition 0.000 claims 1
- 239000000216 gellan gum Substances 0.000 claims 1
- 229940046240 glucomannan Drugs 0.000 claims 1
- 229940035034 maltodextrin Drugs 0.000 claims 1
- 235000012054 meals Nutrition 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229950008882 polysorbate Drugs 0.000 claims 1
- 229920000136 polysorbate Polymers 0.000 claims 1
- 239000003755 preservative agent Substances 0.000 claims 1
- 230000002335 preservative effect Effects 0.000 claims 1
- 235000010413 sodium alginate Nutrition 0.000 claims 1
- 239000000661 sodium alginate Substances 0.000 claims 1
- 229940005550 sodium alginate Drugs 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 239000012752 auxiliary agent Substances 0.000 abstract description 31
- 230000000694 effects Effects 0.000 abstract description 9
- 238000001704 evaporation Methods 0.000 abstract description 8
- 230000008020 evaporation Effects 0.000 abstract description 7
- 238000003892 spreading Methods 0.000 abstract description 4
- 230000007480 spreading Effects 0.000 abstract description 4
- 230000002708 enhancing effect Effects 0.000 abstract description 3
- 150000003217 pyrazoles Chemical class 0.000 description 9
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical class CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 description 8
- 239000005784 Fluoxastrobin Substances 0.000 description 8
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 230000008021 deposition Effects 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000009736 wetting Methods 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- 239000003595 mist Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 231100000572 poisoning Toxicity 0.000 description 4
- 230000000607 poisoning effect Effects 0.000 description 4
- 240000008067 Cucumis sativus Species 0.000 description 3
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004895 liquid chromatography mass spectrometry Methods 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000010773 plant oil Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000010336 energy treatment Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229940068977 polysorbate 20 Drugs 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 150000003398 sorbic acids Chemical class 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/34—Nitriles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of preparation and application of pesticide spray assistant composition, the spray adjuvantses are mainly made up of natural edible glue (containing its raw material) and environment-friendly type surfactant, have the characteristics of green, safe and pollution-free.The auxiliary agent is applied to all kinds of formulation agricultural chemicals, has the adhesion of enhancing decoction and wettability, increases agricultural chemicals spreading area, delay spray evaporation speed, reduce the effect of droplet drift, it is possible to increase pesticide control effect, reduces applications of pesticide cost.The auxiliary agent has wide range of applications, and can be used cooperatively with the various farm chemical ingredients such as herbicide, insecticide, bactericide and plant growth regulator.
Description
Technical field
The present invention relates to a kind of preparation and application of green and environment-friendly pesticide spray adjuvantses composition, said composition is applied to remove
Careless agent, insecticide, bactericide and plant growth regulator pesticide synergistic application, belong to insecticides adjuvant technical field.
Background technology
Agricultural chemicals in use always there is effective rate of utilization it is low the problem of.It is estimated that sprayed from spraying equipment
The agricultural chemicals gone only has 25%~50% can deposit on crop leaf, and the medicament less than 1% can be deposited on target pest, only
0.03% medicament really plays insecticidal action.Agricultural chemicals drift, volatilization and loss are the main reason for causing agricultural chemicals to lose, and are improved
Agricultural chemicals utilization rate it is necessary to reduce agricultural chemicals from spray tank into target transmittance process because drifting about, evaporating and blade face is lost in and brought
Loss, it is exactly to add spray adjuvantses in pesticide spray liquid to solve this problem most efficient method.Agricultural chemicals adds spray adjuvantses
Medical liquid surface tension can be reduced afterwards, extended droplet moisture preserving time, increased spreading area and resistance of rainwater washing against of the decoction on blade face
Ability, playing prevents float of mist droplet, enhancing plate-out ability, sorbefacient effect, promotes the new technologies such as accuracy pesticide applying, decrement dispenser
Popularization and application.
The most widely used pesticide spray auxiliary agent of existing market has nonionic surfactants, organic silicon, plant
Oils and mineral oils etc., but its applicability is restricted Shortcomings part by auxiliary agent physicochemical property.Nonionic surfactants
Auxiliary agent easily fails under high temperature, drought condition；Organic silicon auxiliary agent is only applicable to the scopes of pH 5~9, in meta-acid, meta-alkali solution
In degrade rapidly, and in hot environment using easily produce poisoning；Vegetable oil is with mineral oil due to immiscible, it is necessary to add with water
Emulsifying agent is prepared into emulsion and could used as spray adjuvantses.
Surfactant is the important component of pesticide spray auxiliary agent, plays the effects such as emulsification, scattered, infiltration, solubilising.Surface
The addition of activating agent can be greatly lowered the surface tension of decoction, enhancing medicament the wet spreading of plant or insect body surface with
And adhesive force, so as to improve drug effect.For many years, domestic market major part pesticide surfactant process raw material using nonyl phenol as
It is main, belong to the auxiliary chemicals product for limiting use in the world, its a large amount of use forms very big prestige to ecological environment and health
The side of body.
The invention provides a kind of new pesticide synergistic technical scheme, the problem of existing spray adjuvantses are present is overcome.Should
Scheme can not only increase spreading area of the pesticide droplet on blade face, delay the evaporation rate of spray droplet, reduce droplet drift,
Improve drug effect to play, and auxiliary agent is mainly made up of natural food material and environment-friendly type surfactant, green, the peace of product
Entirely, environment-friendly advantage protrudes.
The content of the invention
The present invention provides a kind of one or more of mixtures by natural edible glue or its raw material, with environment-friendly type surface-active
The agricultural chemicals synergist composition that agent, food preservative and water etc. are mixed, said composition are directly mixed with all kinds of formulation agricultural chemicals
Close and use, by strengthening spray liquid adhesion and wetting action, reduce droplet evaporation capacity, increase medicinal liquid osmosis speed and infiltration capacity,
Reach and extend pesticide efficacy release time, reduce Pesticide use amount, improve the purpose of pesticide efficacy.The present invention applies model
Enclose extensively, synergistic effect is respectively provided with to the class agricultural chemicals such as weeding, desinsection, sterilization and plant growth regulating.
The present invention provides a kind of agricultural chemicals synergist composition to achieve the above object, and said composition is by 0.01%-20%
One or more natural edible glue (containing its raw material) combination structure costing formula basis, it is possible to additionally incorporate 1-40% environment-friendly type table
Face activating agent, 1%-10% food preservative and 50%-95% water.Natural edible glue (containing its raw material) conduct in the present invention
Thickener.Natural edible glue or its raw material play increase system viscosity by the synergy with environment-friendly type surfactant,
Promote decoction in target plant moistened surface spread and infiltration, increase hold-up, extend drug action time and anti-rain drop erosion
Effect, additionally it is possible to regulate and control spray droplet size, reduce decoction and evaporate and avoid drifting about.The agricultural chemicals synergist is added with many
In 1% food preservative, it is rotten to prevent that the edible glue in auxiliary agent from degrading.In agricultural production, the synergistic composition is pressed one
Certainty ratio is added in agricultural chemicals, can reduce Pesticide use amount more than 30%.
The present invention has advantages below：(1) synergistic effect is notable, the auxiliary agent can strengthen decoction plant surface wetting,
Adhesion and permeance property, retard evaporation speed, are greatly improved the utilization of pesticide active ingredient.(2) green safe, the auxiliary agent uses
Food additives are primary raw material, have good bioavilability and compatibility, avoid organosilicon and azone analog assistant from using
During existing allergy risk.(3) environmentally friendly, spray droplet size can be controlled in suitable scope by adding the auxiliary agent,
Poisoning and environmental pollution caused by avoiding agricultural chemicals drift.(4) have wide range of applications, accommodate and missible oil, suspending agent, wettable powder
The different formulations of pesticide buckets such as agent, suspension emulsion, microemulsion, aqueous emulsion, aqua are mixed to be used, especially with missible oil, microemulsion, suspension emulsion,
Aqueous emulsion, the mixing of aqua are better.(5) Pesticide use cost is saved, Pesticide use amount can be reduced using the auxiliary agent, especially
It is to subtract to apply high price agricultural chemicals remarkable in economical benefits.
Brief description of the drawings
Fig. 1 is the blade surface precipitation capacity that different content is formulated spray adjuvantses.
Fig. 2 is the blade surface precipitation capacity rate of recovery that different content is formulated spray adjuvantses.
Embodiment
The present invention is better understood by means of following embodiments, these embodiments are only used for illustrating the present invention, no
Limitation of the present invention should be interpreted.
A kind of preparation of pesticide spray auxiliary agent of embodiment 1
A kind of pesticide spray auxiliary agent is made up of by weight percentage following component：Xanthans 0.2%, alkyl-glucoside
5%, sorbic acid 2%, water 92.8%.
Exemplified by preparing 1 kilogram of pesticide spray auxiliary agent, specific preparation process is as follows：
The first step：928 grams of water are added in reactor, reactor is heated to 15-100 using 10 DEG C/min programming rate
DEG C, it is well mixed with being slowly added to 2 grams of xanthan rubber powders under 500-800rpm/min mechanical agitation speed conditions.
Second step：50 grams of alkyl-glucosides are added in reactor under the reaction temperature and mixed with xanthans
It is even.
3rd step：20 grams of sorbic acids are added into xanthans and alkyl-glucoside mixture, continue to mix to
Room temperature is naturally cooled to after even to get product.
A kind of Herbicidal combinations of 2 spray adjuvantses containing synergy of embodiment
Xanthans 0.2g, alkyl-glucoside 5g, sorbic acid 2g, water 92.8g are taken, is prepared using the method for embodiment 1
100g spray adjuvantses, 5g spray adjuvantses and 16mL ammonium glyphosates (aqua) plus 1L water is taken to be mixed with to obtain Herbicidal combinations.
A kind of Pesticidal combination of 3 spray adjuvantses containing synergy of embodiment
Edible gelatin 5g, AEO 15g, benzoic acid 2g, water 78g are taken, is prepared into using the method for embodiment 1
To 100g spray adjuvantses, 10g spray adjuvantses and 1.6mL effective cypermethrins (missible oil) plus 1L water is taken to be mixed with to obtain desinsection group
Compound.
A kind of bactericidal composition of 4 spray adjuvantses containing synergy of embodiment
Carragheen 1g, Tea Saponin and the mixture of fulvic acid 1: 1 (wt%) 25g, citric acid 2g, water 72g are taken, using embodiment
100g spray adjuvantses are prepared in 1 method, take 50g spray adjuvantses and 1.6mL pyrazoles Fluoxastrobin (missible oil) plus 1L water to be mixed with
Obtain bactericidal composition.
A kind of bactericidal composition of 5 spray adjuvantses containing synergy of embodiment
Locust bean gum 5g, fatty glyceride 20g, citric acid 2g, water 73g are taken, 100g is prepared using the method for embodiment 1
Spray adjuvantses, 30g spray adjuvantses and 1g Fluoxastrobins (wettable powder) plus 1L water is taken to be mixed with to obtain bactericidal composition.
A kind of bactericidal composition of 6 spray adjuvantses containing synergy of embodiment
Xanthans and pectin mixture 10g, isomeric alcohol polyethenoxy ether 15g, benzoic acid 2g, water 73g are taken, using embodiment
100g spray adjuvantses are prepared in 1 method, take 15g spray adjuvantses and 4mL Bravos (suspending agent) plus 1L water to be mixed with to obtain
Bactericidal composition.
A kind of plant coutrol composition of 7 spray adjuvantses containing synergy of embodiment
Guar bean flour 12g, polysorbate 20 g, benzoic acid 2g, water 66g are taken, 100g is prepared using the method for embodiment 1
Spray adjuvantses, 20g spray adjuvantses and 10mL cycocels (aqua) plus 1L water is taken to be mixed with to obtain plant coutrol composition.
The application method of agricultural chemicals synergist of the present invention is：The agricultural chemicals for preparing to use first is diluted to the medicine of required ratio
Liquid, then the builder is proportionally added into pesticide solution and stirred.
The mist droplet particle size measure of spread of embodiment 8
Decoction droplet using laser particle analyzer to formula spray adjuvantses described in addition different content percentage embodiment 2-7
Particle diameter distribution is determined, with D50 values (meso-position radius, representing that cumulative distribution percentage reaches particle size values corresponding when 50%)
It is compared for grain size characteristic index, as a result as shown in table 1.
Table 1. adds influence of the different content Percent Spray auxiliary agent to mist droplet particle size
After the as shown by data of table 1 adds spray adjuvantses of the present invention, pesticide droplet particle diameter significantly increases, and can promote decoction
Blade face is settled down to quickly, is advantageous to control drift.Mist droplet particle size size is suitable simultaneously, avoids because droplets particles are excessive, adhesive force
Loss is tumbled caused by difference.
The evaporation experiment of embodiment 9
By 100 μ l added with formula spray adjuvantses described in 5% (wt%) embodiment 2-7 and organosilicon, azone spray adjuvantses
And the pyrazoles Fluoxastrobin decoction dropwise addition for being not added with spray adjuvantses determines mass change of the decoction with time lengthening on slide
Value, as a result as shown in table 2.
The droplet of table 2. evaporates speed comparative experiments
The as shown by data of table 2 adds spray adjuvantses of the present invention compared with being not added with auxiliary agent, addition organosilicon and azone auxiliary agent
Decoction evaporation rate has obvious reduction, contributes to reduction decoction that evaporation occurs in spray process and scatters and disappears.
The wettability of embodiment 10 is evaluated
To being formulated spray adjuvantses and organosilicon, azone spray adjuvantses and the grass for being not added with spray adjuvantses described in embodiment 2-7
Sweet phosphine decoction wettability is evaluated, and the assay method of indices is as follows：
Surface tension：Using platinum plate suspension ring method.When medical liquid surface tension is less than target surface free energy, decoction ability
Soak and sprawl in target surface.
Dynamic contact angle：Determined using contact angle instrument.Energy of wetting of the small decoction of dynamic contact angle to selected target
Power is strong.
Wetting time：Determined with reference to canvas pellet method.The short decoction of wetting time is advantageous to extend decoction on target
Action time.
As a result it is as shown in table 3.
The spray adjuvantses wettability of table 3. is evaluated
The as shown by data of table 3 spray adjuvantses of the present invention have low surface tension, contact surface compared with organosilicon and azone auxiliary agent
The long-pending small and short advantageous characteristic of wetting time.
The sedimentation experiment of embodiment 11
By the pyrazoles Fluoxastrobin decoction added with formula spray adjuvantses described in different content percentage embodiment 4 in identical bar
The blade surface of fixed-area is quantitatively sprayed onto under part, it is phonetic using pyrazoles on LC-MS method measure blade face after naturally dry
The deposition of bacterium ester, using chromatographic peak area as decoction deposition size reduced parameter, as a result as shown in Figure 1.
Fig. 1 as shown by data adds the pyrazoles Fluoxastrobin decoction deposition highest of 5% auxiliary agent of the present invention, than being not added with auxiliary agent pair
More than 30% is had more according to a group deposition, 20%-30% is had more than organosilicon and azone auxiliary agent control group deposition.
The antiscour of embodiment 12 is tested
By the pyrazoles Fluoxastrobin decoction added with formula spray adjuvantses described in different content percentage embodiment 4 in identical bar
The blade surface of fixed-area is quantitatively sprayed onto under part, after naturally dry, a half vane carries out deposition determination experiment, another
Half vane, to trickling, carries out antiscour experiment in its surface basis weight spray water, is surveyed after naturally dry using LC-MS method
The residual quantity of pyrazoles Fluoxastrobin on blade face is determined, by the ratio between pyrazoles Fluoxastrobin residual quantity chromatographic peak area and deposition chromatographic peak area
(rate of recovery) is used as auxiliary agent erosion resistibility reduced parameter, as a result as shown in Figure 2.
Fig. 2 as shown by data adds the pyrazoles Fluoxastrobin decoction rate of recovery highest of 5% auxiliary agent of the present invention, than being not added with auxiliary agent pair
More than 40% is had more according to a group rate of recovery, 10%-20% is had more than organosilicon and the azone auxiliary agent control group rate of recovery.Illustrate to use this
Invention spray adjuvantses have significant erosion resistibility.
The synergy spray adjuvantses application experiment of embodiment 13
Bravo bactericidal composition is prepared as described in embodiment 6, formulation rate is 20g/ mus, carries out preventing and treating powdery mildew of cucumber
Effect experiment.Control group：Organic silicon, azone, plant oil auxiliary agent, experimental result are as shown in table 4.
Dispenser next day is observed, and obvious poisoning occur in the cucumber leaves of 5% benefit energy treatment region, are observed after 7 days and find that benefit can be located
The cucumber leaves 70%-80% of reason dries up, or even whole strain is dead.Other auxiliary agents do not have poisoning.In terms of prevention effect, use
The auxiliary agent of embodiment 6 improves 40.9% than not adding assistant, and 16.4-36.2% is improved than control auxiliary agent.Pesticide spray of the present invention helps
The prevention effect of agent is significantly better than non-adding assistant and addition conven-tional adjuvants.
Influence of the 4. different spray adjuvantses of table to pesticide control effect
Note：Investigate data and take 3 repetition laboratory mean values
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to most
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the skill of the present invention
Art scheme is modified or equivalent substitution, and without departing from the objective and scope of technical solution of the present invention, it all should cover in this hair
Among bright right.
Claims (13)
- A kind of 1. spray adjuvantses composition, it is characterised in that：Said composition is 0.01%-20% comprising mass percent (wt%) Natural edible glue, 1-40% surfactant, 1%-10% food preservative and 50%-95% water.
- 2. spray adjuvantses composition according to claim 1, it is characterised in that：The natural edible glue is：Sodium alginate, Agar, gelatin, pectin, xanthans, Arabic gum, furcellaran, bassora gum, locust bean gum, carragheen, gellan, gellan gum, melon That bean gum, konjaku glucomannan, curdlan, maltodextrin, linseed meal, oatmeal, beet pulp, konjaku flour, cluster bean One or more combinations in powder.
- 3. spray adjuvantses composition according to claim 1, the surfactant is alkyl-glucoside, poly alkyl alcohol One or more groups in oxygen vinethene, isomeric alcohol polyethenoxy ether, fatty glyceride, polysorbate, Tea Saponin, fulvic acid Close.
- 4. spray adjuvantses composition according to claim 1, the food preservative be sorbic acid, benzoic acid, citric acid, One or more combinations in dehydroactic acid.
- 5. a kind of agricultural chemicals synergist, including the spray adjuvantses composition described in claim 1.
- 6. agricultural chemicals synergist according to claim 5, it is characterised in that：The spray adjuvantses composition is applied to difference The formulations of pesticide, the formulations of pesticide include one kind in missible oil, wettable powder, microemulsion, suspension emulsion, aqueous emulsion and aqua More than.
- 7. agricultural chemicals synergist according to claim 5, it is characterised in that：The spray adjuvantses composition is applied to difference Farm chemical ingredients are prepared, and the farm chemical ingredients prepare the one kind included in herbicide, insecticide, bactericide, plant growth regulator More than.
- 8. the agricultural chemicals synergist according to claim 5 or 7, it is characterised in that：The spray adjuvantses composition is applied to When herbicide is prepared in processing, its mass percent (wt%) is 0.1%-10%.
- 9. the agricultural chemicals synergist according to claim 5 or 7, it is characterised in that：The spray adjuvantses composition is applied to When insecticide is prepared in processing, its mass percent (wt%) is 0.1%-10%.
- 10. the agricultural chemicals synergist according to claim 5 or 7, it is characterised in that：The spray adjuvantses composition is applied to When bactericide is prepared in processing, its mass percent (wt%) is 0.1%-10%.
- 11. the agricultural chemicals synergist according to claim 5 or 7, it is characterised in that：The spray adjuvantses composition is applied to When plant growth regulator is prepared in processing, its mass percent (wt%) is 0.1%-10%.
- 12. according to the agricultural chemicals synergist described in claim 5-7 any one, it is characterised in that：The spray adjuvantses combination The mass percent of thing is (wt%) 0.1%-8%.
- 13. the preparation method of the spray adjuvantses composition according to claim 1-4 any one, it is characterised in that the side Method comprises the following steps：Add water in reactor, reactor is heated to 15-100 DEG C, is stirred with 500-800rpm/min machinery Edible glue or its raw material, surfactant, preservative are sequentially added under the conditions of mix rotating speed in proportion, after stirring and dissolving is well mixed Natural cooling.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108293990A (en) * | 2018-03-14 | 2018-07-20 | 安徽农业大学 | A kind of pesticide spray special synergistic agent and the preparation method and application thereof |
| CN108935494A (en) * | 2018-06-02 | 2018-12-07 | 允发化工（上海）有限公司 | A kind of abamectin emulsifiable concentrate and its preparation and application |
| CN113180039A (en) * | 2021-05-06 | 2021-07-30 | 苏州嘉佑生物科技有限公司 | Special auxiliary agent for unmanned aerial vehicle plant protection and flying prevention and preparation method and application thereof |
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| DE2556656A1 (en) * | 1975-12-16 | 1977-06-30 | Tama Flex Sansho Inc | Additives for sprayable aq. agricultural compsns. - contain sorbitol, nonionic surfactant and hydrophobic oil, and give a stable, adherent aerosol |
| CN101637172A (en) * | 2009-06-12 | 2010-02-03 | 深圳诺普信农化股份有限公司 | Insecticidal/acaricidal composition having lufenuron and tebufenozide |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108293990A (en) * | 2018-03-14 | 2018-07-20 | 安徽农业大学 | A kind of pesticide spray special synergistic agent and the preparation method and application thereof |
| CN108293990B (en) * | 2018-03-14 | 2021-02-12 | 安徽农业大学 | Special synergist for pesticide spray and preparation method and application thereof |
| CN108935494A (en) * | 2018-06-02 | 2018-12-07 | 允发化工（上海）有限公司 | A kind of abamectin emulsifiable concentrate and its preparation and application |
| CN113180039A (en) * | 2021-05-06 | 2021-07-30 | 苏州嘉佑生物科技有限公司 | Special auxiliary agent for unmanned aerial vehicle plant protection and flying prevention and preparation method and application thereof |
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